CN113213627A - Integrated reinforced anaerobic and membrane type photobioreactor - Google Patents

Integrated reinforced anaerobic and membrane type photobioreactor Download PDF

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Publication number
CN113213627A
CN113213627A CN202110701034.3A CN202110701034A CN113213627A CN 113213627 A CN113213627 A CN 113213627A CN 202110701034 A CN202110701034 A CN 202110701034A CN 113213627 A CN113213627 A CN 113213627A
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China
Prior art keywords
reactor
anaerobic
microalgae
membrane
water
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CN202110701034.3A
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Chinese (zh)
Inventor
陈程
李哲
宋广清
唐敏
李�瑞
徐昊
李涛
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Hefei Aoqingyuan Environmental Protection Technology Co ltd
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Hefei Aoqingyuan Environmental Protection Technology Co ltd
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Priority to CN202110701034.3A priority Critical patent/CN113213627A/en
Publication of CN113213627A publication Critical patent/CN113213627A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes
    • C02F3/2813Anaerobic digestion processes using anaerobic contact processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/32Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae
    • C02F3/322Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae use of algae
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F7/00Aeration of stretches of water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/105Phosphorus compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/14Maintenance of water treatment installations
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Abstract

The invention discloses an integrated reinforced anaerobic and membrane type photobioreactor, which comprises an anaerobic reactor and a microalgae reactor, wherein the anaerobic reactor is sequentially provided with an anaerobic granular activated carbon expanded bed and clarified liquid from bottom to top; an aeration device is arranged below the microalgae reactor corresponding to the hollow fiber membrane, the side wall of the microalgae reactor is made of light-transmitting materials, and a plurality of light sources are arranged on the circumferential side of the microalgae reactor. The microalgae reactor further removes nitrogen and phosphorus which cannot be removed by the microalgae in the anaerobic section, and is provided with the hollow fiber membrane which completely intercepts the microalgae, so that the separation of the microalgae and water is realized, and the treatment efficiency is greatly improved. The water flow is filtered through the hollow fiber membrane, and the residual microorganisms, organic matter nutrients and the like in the water are filtered, so that relatively clean water is obtained and is discharged to the clean water tank through the water outlet pipe.

Description

Integrated reinforced anaerobic and membrane type photobioreactor
Technical Field
The invention belongs to the technical field of urban and agricultural domestic sewage treatment equipment, and particularly relates to an integrated reinforced anaerobic membrane type photobioreactor.
Background
The combination of high concentration microalgae culture and wastewater treatment has received increasing attention due to its industrial potential. Microalgae in suspended or attached growth mode have proven effective in removing nutrients and some other contaminants from wastewater. The microalgae biomass produced during wastewater treatment is increasingly considered as a potentially sustainable source for various products such as cosmetics, pigments and biofuels. Microalgae-based wastewater treatment can be accomplished in two engineering systems, including open ponds and photobioreactors. While open ponds are generally easy to design, build and operate, significant limitations associated with this technology include water evaporation, large space requirements, algal culture contamination, and lack of control over operating parameters, whereas photobioreactors have the disadvantages of poor settleability and biomass being easily washed out. With the continued development of these systems, the implementation of the membrane photobioreactor concept recently combines photobioreactors with membrane filtration processes.
Membrane photobioreactors can not only produce high concentrations of biomass but also significantly reduce the nutrients such as nitrogen and phosphorus and the smaller footprint requirements, primarily due to the ability of membrane photobioreactors to independently control Hydraulic Retention Time (HRT) and Solids Retention Time (SRT). The membrane type photobioreactor utilizes autotrophic effect of microalgae, takes carbon dioxide in air as a carbon source, and removes nitrogen and phosphorus in water. Conventional membrane bioreactors typically have anoxic and/or anaerobic zones to achieve complete denitrification/nitrification.
Therefore, the invention mainly solves the problem of water eutrophication caused by low organic matter removal efficiency and incapability of removing N, P in the anaerobic sewage treatment process.
Disclosure of Invention
The invention aims to provide an integrated reinforced anaerobic membrane type photobioreactor, which mainly solves the problem of water eutrophication caused by low organic matter removal efficiency and incapability of removing N, P in the anaerobic sewage treatment process.
In order to solve the technical problems, the invention is realized by the following technical scheme:
an integrated reinforced anaerobic and membrane type photobioreactor comprises an anaerobic reactor and a microalgae reactor;
the anaerobic reactor is sequentially provided with an anaerobic granular activated carbon expanded bed and clarified liquid from bottom to top;
a communicating pipe is arranged between the clarified liquid and the microalgae reactor, a hollow fiber membrane is arranged in the microalgae reactor, the hollow fiber membrane is communicated with a water outlet pipe connected with the outside of the microalgae reactor, and the water outlet pipe is connected with a water pump in series;
an aeration device is arranged below the microalgae reactor corresponding to the hollow fiber membrane, and is communicated with an air inlet pipe;
the side wall of the microalgae reactor is made of light-transmitting materials, and a plurality of light sources are arranged on the circumferential side of the microalgae reactor.
Further, little algae reactor is including the outer container and the inner container that cup joint each other, outer container and inner container upside opening, support through the bracing piece between outer container and the inner container, hollow fiber membrane and aeration equipment all install in the inner container, the side mouth is less than outer container side mouth on the inner container, outer container bottom is connected with the blow off pipe.
Further, the inner container side wall is provided with an interlayer, and the light source is mounted on the interlayer.
Further, a reflecting layer is arranged at the position of the interlayer opposite to the light source.
Further, the mouth part of the inner container is provided with a blocking wall which is in an inverted funnel shape.
Furthermore, a three-way separator is arranged at the position of the anaerobic reactor corresponding to the clarified liquid.
Further, a water distributor is arranged at the bottom of the anaerobic reactor.
Furthermore, sampling points for detecting water quality are arranged on the side walls of the anaerobic reactor and the microalgae reactor.
The invention has the following beneficial effects:
(1) the microalgae reactor further removes nitrogen and phosphorus which cannot be removed by the microalgae in the anaerobic section, and is provided with the hollow fiber membrane which completely intercepts the microalgae, so that the separation of the microalgae and water is realized, and the treatment efficiency is greatly improved. The water flow is filtered through the hollow fiber membrane, and the residual microorganisms, organic matter nutrients and the like in the water are filtered, so that relatively clean water is obtained and is discharged to the clean water tank through the water outlet pipe.
The bioreactor is used for treating the actual effluent of the primary sedimentation tank and mainly aims at rural and urban domestic sewage.
(2) The hollow fiber PVDF membrane component is arranged in the microalgae reactor, the air aeration device is arranged below the membrane component, aeration is carried out in the microalgae reactor to effectively mix algae suspension liquid and provide carbon dioxide as a carbon source of microalgae, oxygen for growing the microalgae is also provided in the aeration process, bubbles formed by aeration not only have the function of mixing the algae in the floating process, but also impact the hollow fiber membrane component to enable mud dirt adsorbed on the surface of the membrane layer to fall off, the membrane flux is improved, and the membrane pollution is reduced. The membrane type photobioreactor is provided with a light source by a plurality of fluorescent lamps, has average light intensity of about 85 mu mol/square meter/second, and is used for providing a light environment for microalgae growth and metabolism.
(3) The oil produced in the microalgae biomass conversion process can be processed into fuel while purifying and improving the cleanliness of water, and a series of health foods or pharmaceuticals can be developed due to the fact that the oil is rich in DHA, EPA and other substances.
Under the mixing action condition of the two reactors, not only can organic matters and nutrients in the water be removed, but also the content of N, P can be reduced by utilizing the further metabolism of microalgae.
Of course, it is not necessary for any product in which the invention is practiced to achieve all of the above-described advantages at the same time.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings used in the description of the embodiments will be briefly introduced below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and it is obvious for those skilled in the art that other drawings can be obtained according to the drawings without creative efforts.
FIG. 1: the invention has a schematic structure.
FIG. 2: the invention relates to a schematic diagram of a matched installation structure of an inner container and an outer container.
In the drawings, the components represented by the respective reference numerals are listed below:
the device comprises an anaerobic reactor 1, a microalgae reactor 2, an anaerobic granular activated carbon expanded bed 11, clarified liquid 12, a communicating pipe 13, a hollow fiber membrane 3, a water outlet pipe 31, a water pump 32, an aeration device 4, an air inlet pipe 41, a light source 5, an outer container 21, an inner container 22, a support rod 20, a drain pipe 24, an interlayer 23, a reflecting layer 51, a baffle wall 25, a three-way separator 14, a water distributor 15 and a sampling point 16.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In the description of the present invention, it is to be understood that the terms "opening," "upper," "lower," "thickness," "top," "middle," "length," "inner," "peripheral," and the like are used in an orientation or positional relationship that is merely for convenience in describing and simplifying the description, and do not indicate or imply that the referenced component or element must have a particular orientation, be constructed and operated in a particular orientation, and thus should not be considered as limiting the present invention.
As shown in fig. 1: the integrated reinforced anaerobic and membrane type photobioreactor comprises an anaerobic reactor 1 and a microalgae reactor 2; microalgae organisms are cultured in the water body in the microalgae reactor.
The anaerobic reactor 1 is sequentially provided with an anaerobic granular activated carbon expanded bed 11 and a clarified liquid 12 from bottom to top; the anaerobic granular activated carbon expanded bed is prepared by attaching and adsorbing anaerobic microorganisms on granular activated carbon, generates biogas through anaerobic fermentation and metabolizes and consumes organic matters and nutrients to obtain a relatively clear water body, wherein the biogas can be used as renewable energy.
The granular activated carbon expanded bed provides a good growing and fixing place for anaerobic microorganisms, and the performance of the granular activated carbon expanded bed on removing organic matters in sewage and producing methane is superior to that of the traditional methane production.
A communicating pipe 13 is arranged between the clarified liquid 12 and the microalgae reactor 2, and the clarified liquid is transferred to the microalgae reactor for further degradation through the overflow effect. The hollow fiber membrane 3 is arranged in the microalgae reactor 2, the hollow fiber membrane 3 is communicated with a water outlet pipe 31 connected with the outside of the microalgae reactor 2, and the water outlet pipe 31 is connected with a water pump 32 in series;
an aeration device 4 is arranged below the microalgae reactor 2 corresponding to the hollow fiber membrane 3, and the aeration device 4 is communicated with an air inlet pipe 41; the air inlet pipe is connected with a fan and used for introducing air.
The side wall of the microalgae reactor 2 is made of light-transmitting materials, such as resin, glass and the like. The microalgae reactor 2 is provided with a plurality of light sources 5 at the circumferential side. The light source is a plurality of vertically arranged LED fluorescent tubes.
The microalgae reactor further removes nitrogen and phosphorus which cannot be removed by the microalgae in the anaerobic section, and is provided with the hollow fiber membrane which completely intercepts the microalgae, so that the separation of the microalgae and water is realized, and the treatment efficiency is greatly improved. The water flow is filtered through the hollow fiber membrane, and the residual microorganisms, organic matter nutrients and the like in the water are filtered, so that relatively clean water is obtained and is discharged to the clean water tank through the water outlet pipe.
The bioreactor is used for treating the actual effluent of the primary sedimentation tank and mainly aims at rural and urban domestic sewage.
The anaerobic granular activated carbon expanded beds were each made of stainless steel STS304, and each anaerobic reactor contained pretreated granular activated carbon accounting for 25% of the effective volume of the reactor. During continuous operation, the expanded bed of granular activated carbon is operated in an expansion mode. The actual town sewage uniformly enters the bottom of the GAC expansion bed through the water inlet distributor. The effluent of the anaerobic reactor overflows into the microalgae reactor for further treatment.
The hollow fiber PVDF membrane component is arranged in the microalgae reactor, the air aeration device is arranged below the membrane component, aeration is carried out in the microalgae reactor to effectively mix algae suspension liquid and provide carbon dioxide as a carbon source of microalgae, oxygen for growing the microalgae is also provided in the aeration process, bubbles formed by aeration not only have the function of mixing the algae in the floating process, but also impact the hollow fiber membrane component to enable mud dirt adsorbed on the surface of the membrane layer to fall off, the membrane flux is improved, and the membrane pollution is reduced. The membrane type photobioreactor is provided with a light source by a plurality of fluorescent lamps, has average light intensity of about 85 mu mol/square meter/second, and is used for providing a light environment for microalgae growth and metabolism.
The oil produced in the microalgae biomass conversion process can be processed into fuel while purifying and improving the cleanliness of water, and a series of health foods or pharmaceuticals can be developed due to the fact that the oil is rich in DHA, EPA and other substances.
Under the mixing action condition of the two reactors, not only can organic matters and nutrients in the water be removed, but also the content of N, P can be reduced by utilizing the further metabolism of microalgae.
As shown in fig. 2: the microalgae reactor 2 comprises an outer container 21 and an inner container 22 which are mutually sleeved, the upper side of the outer container 21 and the upper side of the inner container 22 are opened, the outer container 21 and the inner container 22 are supported by a support rod 20, the support rod is positioned at the bottom of the inner container, the hollow fiber membrane 3 and the aeration device 4 are both arranged on the inner container 22, the upper side opening of the inner container 22 is lower than the upper side opening of the outer container 21, and the bottom of the outer container 21 is connected with a drain pipe 24. The liquid level of the water in the outer container is higher than the opening part of the inner container, the inner container is mounted in the outer container in a suspended mode through the supporting rod, water in the communicating pipe directly enters the inner container, the photocatalytic microalgae metabolism stage occurs in the inner container, more microalgae are generated through microalgae metabolic growth, and residual impurities in the water are intercepted by the hollow fiber membrane to form accumulated dirt on the surface, and the dirt falls off and floats under the aeration effect of the aeration device. Because the interval area between the inner container and the outer container is not provided with floating bubbles, mud dirt at the position is subjected to free sedimentation and finally accumulated at the bottom of the outer container and is discharged through a sewage discharge pipe.
Is favorable for reducing the lumpy sludge in the water body and recovering microalgae metabolites and the like. The bottom of the outer container is funnel-shaped corresponding to the sludge area and is used for concentrating and uniformly discharging sludge.
As shown in fig. 2: the inner container 21 is provided with an interlayer 23 on the side wall, and the light source 5 is mounted on the interlayer 23. One side of the inner container corresponding to the water body is made of transparent material, and the interlayer is a cavity layer.
As shown in fig. 2: the interlayer 23 is provided with a reflective layer 51 at a position facing away from the light source 5. The light source is used for reflecting the back side light source, and the light utilization rate is improved.
As shown in fig. 2: the mouth of the inner container 21 is provided with a barrier wall 25, the barrier wall 25 being in the form of an inverted funnel. The water body between the inner container and the outer container is a centralized settling section, dirt falls onto the retaining wall after settling, and further slides down to the bottom of the outer container. The funnel-shaped structure of the blocking wall is also beneficial to the concentration of bubbles and reduces the rolling effect of the bubbles on the part of water body.
As shown in fig. 1: the anaerobic reactor 1 is provided with a three-way separator 14 corresponding to the position of the clarified liquid 12. For separating gas and liquid.
As shown in fig. 1: the bottom of the anaerobic reactor 1 is provided with a water distributor 15.
As shown in fig. 1: the side walls of the anaerobic reactor 1 and the microalgae reactor 2 are both provided with sampling points 16 for detecting water quality. The water body sampling device is used for sampling water bodies at different positions, and the working efficiency of the reactor is known by detecting the change of the water body.
The reactor employs granular activated carbon GAC carriers instead of conventional anaerobic technology because the biomass attached to GAC is more resistant to temperature fluctuations, shock loading and changes in influent water concentration or composition than conventional suspended biomass. This is an important factor for anaerobic treatment of actual low-concentration town sewage at ambient temperature. In addition, the GAC in the reactor may also promote COD removal and methanogenesis, since GAC and its attached organisms are able to adsorb and biodegrade organic compounds in the wastewater.
GAC has conductive property, and a large amount of electrogenic bacteria such as Geobacter and methanogen hydrogenophilus can be enriched in a biomembrane attached to the GAC to stimulate and generate direct inter-inoculation electron transfer DIET, so that the methanogenesis process is enhanced. The introduction of the GAC can also promote the enrichment of methanogens, promote the co-nutrient metabolism of the volatile fatty acid VFA and improve the methane yield in the anaerobic process.
In the description herein, references to the description of "one embodiment," "an example," "a specific example" or the like are intended to mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above do not necessarily refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
The preferred embodiments of the invention disclosed above are intended to be illustrative only. The preferred embodiments are not intended to be exhaustive or to limit the invention to the precise embodiments disclosed. Obviously, many modifications and variations are possible in light of the above teaching. The embodiments were chosen and described in order to best explain the principles of the invention and the practical application, to thereby enable others skilled in the art to best utilize the invention. The invention is limited only by the claims and their full scope and equivalents.

Claims (8)

1. The integrated reinforced anaerobic membrane type photobioreactor is characterized in that:
comprises an anaerobic reactor (1) and a microalgae reactor (2);
the anaerobic reactor (1) is sequentially provided with an anaerobic granular activated carbon expanded bed (11) and a clarified liquid (12) from bottom to top;
a communicating pipe (13) is arranged between the clarified liquid (12) and the microalgae reactor (2), a hollow fiber membrane (3) is arranged in the microalgae reactor (2), the hollow fiber membrane (3) is communicated with a water outlet pipe (31) connected with the outside of the microalgae reactor (2), and the water outlet pipe (31) is connected with a water pump (32) in series;
an aeration device (4) is arranged below the microalgae reactor (2) corresponding to the hollow fiber membrane (3), and the aeration device (4) is communicated with an air inlet pipe (41);
the side wall of the microalgae reactor (2) is made of light-transmitting materials, and a plurality of light sources (5) are arranged on the circumferential side of the microalgae reactor (2).
2. The integrated reinforced anaerobic, membrane photobioreactor of claim 1, wherein: little algae reactor (2) are including outer container (21) and inner container (22) that cup joint each other, outer container (21) and inner container (22) upside opening, support through bracing piece (20) between outer container (21) and inner container (22), hollow fiber membrane (3) and aeration equipment (4) are all installed in inner container (22), the side mouth is less than outer container (21) side mouth on inner container (22), outer container (21) bottom is connected with blow off pipe (24).
3. The integrated reinforced anaerobic, membrane photobioreactor of claim 2, wherein: an interlayer (23) is arranged on the side wall of the inner container (21), and the light source (5) is installed on the interlayer (23).
4. The integrated reinforced anaerobic, membrane photobioreactor of claim 3, wherein: and a reflecting layer (51) is arranged at the position of the interlayer (23) back to the light source (5).
5. The integrated reinforced anaerobic, membrane photobioreactor of claim 2, wherein: the mouth part of the inner container (21) is provided with a blocking wall (25), and the blocking wall (25) is in an inverted funnel shape.
6. The integrated reinforced anaerobic, membrane photobioreactor according to claim 1 or 2, wherein: the anaerobic reactor (1) is provided with a three-way separator (14) corresponding to the position of the clarified liquid (12).
7. The integrated reinforced anaerobic, membrane photobioreactor according to claim 1 or 2, wherein: the bottom of the anaerobic reactor (1) is provided with a water distributor (15).
8. The integrated reinforced anaerobic, membrane photobioreactor according to claim 1 or 2, wherein: the side walls of the anaerobic reactor (1) and the microalgae reactor (2) are both provided with sampling points (16) for detecting water quality.
CN202110701034.3A 2021-06-22 2021-06-22 Integrated reinforced anaerobic and membrane type photobioreactor Pending CN113213627A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113862113A (en) * 2021-09-10 2021-12-31 中国电建集团华东勘测设计研究院有限公司 Photobioreactor for microalgae culture and application

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113862113A (en) * 2021-09-10 2021-12-31 中国电建集团华东勘测设计研究院有限公司 Photobioreactor for microalgae culture and application

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