CN113202588A - Liquid air energy storage power generation system - Google Patents
Liquid air energy storage power generation system Download PDFInfo
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- CN113202588A CN113202588A CN202110644576.1A CN202110644576A CN113202588A CN 113202588 A CN113202588 A CN 113202588A CN 202110644576 A CN202110644576 A CN 202110644576A CN 113202588 A CN113202588 A CN 113202588A
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- 239000007788 liquid Substances 0.000 title claims abstract description 114
- 238000010248 power generation Methods 0.000 title claims abstract description 76
- 238000004146 energy storage Methods 0.000 title claims abstract description 60
- 238000001179 sorption measurement Methods 0.000 claims abstract description 70
- 239000002808 molecular sieve Substances 0.000 claims abstract description 68
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims abstract description 68
- 238000000034 method Methods 0.000 claims abstract description 42
- 230000008569 process Effects 0.000 claims abstract description 42
- 238000007664 blowing Methods 0.000 claims abstract description 28
- 230000008929 regeneration Effects 0.000 claims abstract description 26
- 238000011069 regeneration method Methods 0.000 claims abstract description 26
- 238000005338 heat storage Methods 0.000 claims description 28
- 230000006835 compression Effects 0.000 claims description 27
- 238000007906 compression Methods 0.000 claims description 27
- 238000004887 air purification Methods 0.000 claims description 8
- 239000007789 gas Substances 0.000 description 9
- 239000012071 phase Substances 0.000 description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 238000009825 accumulation Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- -1 and the like) Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K25/00—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for
- F01K25/08—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours
- F01K25/10—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours the vapours being cold, e.g. ammonia, carbon dioxide, ether
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0407—Constructional details of adsorbing systems
- B01D53/0438—Cooling or heating systems
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D15/00—Adaptations of machines or engines for special use; Combinations of engines with devices driven thereby
- F01D15/10—Adaptations for driving, or combinations with, electric generators
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K3/00—Plants characterised by the use of steam or heat accumulators, or intermediate steam heaters, therein
- F01K3/006—Accumulators and steam compressors
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K3/00—Plants characterised by the use of steam or heat accumulators, or intermediate steam heaters, therein
- F01K3/02—Use of accumulators and specific engine types; Control thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
- B01D2259/40088—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
- B01D2259/4009—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating using hot gas
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Separation By Low-Temperature Treatments (AREA)
Abstract
An embodiment of the present invention provides a liquid air energy storage power generation system, including: the device comprises a liquid air energy storage unit, a liquid air energy release unit, an expansion power generation unit and a molecular sieve adsorption tower automatic regeneration unit. The liquid air energy storage unit comprises a molecular sieve adsorption tower. The automatic regeneration unit of the molecular sieve adsorption tower is connected between the expansion power generation unit and the molecular sieve adsorption tower so as to use the exhaust gas of the expansion power generation unit to carry out the regeneration process of the molecular sieve adsorption tower. Through the structural arrangement, the molecular sieve adsorption tower can perform adsorption work in the liquid air energy storage process; in the process of liquid air energy releasing expansion power generation, the molecular sieve adsorption tower can utilize the exhaust of the expansion power generation unit to carry out cold blowing and hot blowing processes. Therefore, the system can fully utilize cold and heat energy in the process of liquid air energy release expansion power generation to complete the automatic regeneration process of the molecular sieve adsorption tower, and the economical efficiency and the energy utilization efficiency of the system are improved.
Description
Technical Field
The invention relates to the technical field of liquid air energy storage, in particular to a liquid air energy storage power generation system.
Background
In the liquid air energy storage system, as the water vapor and the carbon dioxide are frozen and separated out in the air cooling process, a flow passage of the heat exchanger is blocked, so that the heat exchanger cannot be produced; the accumulation of acetylene in the cold box can lead to the occurrence of an explosion accident. Therefore, before the air enters the cold box for liquefaction, the water vapor, carbon dioxide, acetylene and the like contained in the air need to be removed by a molecular sieve purification system.
The traditional molecular sieve purification system needs to be provided with a refrigerating unit before air is fed, so that air entering the molecular sieve purification system is precooled, and the adsorption capacity of the molecular sieve is increased; when the molecular sieve is regenerated, an electric heater is additionally arranged to heat the regenerated gas so as to carry away impurity gases as much as possible. In the adsorption and regeneration processes, additional equipment and energy consumption are required, and the system has low operation efficiency and poor economical efficiency.
Disclosure of Invention
In order to solve the technical problem, the invention provides a liquid air energy storage power generation system.
The invention provides a liquid air energy storage power generation system, which comprises: the device comprises a liquid air energy storage unit, a liquid air energy release unit, an expansion power generation unit and a molecular sieve adsorption tower automatic regeneration unit.
The liquid air energy storage unit is connected with the liquid air energy release unit. The liquid air energy release unit is connected with the expansion power generation unit so as to use the liquid air to carry out expansion power generation.
Wherein, the liquid air energy storage unit comprises a molecular sieve adsorption tower. The molecular sieve adsorption tower automatic regeneration unit is connected between the expansion power generation unit and the molecular sieve adsorption tower so as to use the exhaust gas of the expansion power generation unit to carry out the regeneration process of the molecular sieve adsorption tower.
According to the liquid air energy storage power generation system provided by the invention, the liquid air energy storage unit further comprises a primary air compressor unit, a precooler, a secondary air compressor unit, a compression heat storage and utilization device, a cold accumulator, a throttling element, a gas-liquid separator and a low-temperature storage tank. The precooler includes a first heat exchange side. The compression heat storage utilization device includes a second heat exchange side. The regenerator includes a third heat exchange side.
Wherein, the outlet of the primary air compressor unit is connected with the inlet of the first heat exchange side of the precooler. And the outlet of the first heat exchange side is connected with the inlet of the molecular sieve adsorption tower. And the outlet of the molecular sieve adsorption tower is connected with the inlet of the secondary air compressor unit. And the outlet of the secondary air compressor unit is connected with the inlet of the second heat exchange side of the compression heat storage and utilization device. And the outlet of the second heat exchange side is connected with the inlet of the third heat exchange side of the cold accumulator. And the outlet of the third heat exchange side is connected with the inlet of the throttling element. The outlet of the throttling element is connected with the inlet of the gas-liquid separator. And a liquid air outlet of the gas-liquid separator is connected with an inlet of the low-temperature storage tank.
According to the liquid air energy storage power generation system provided by the invention, the cold accumulator further comprises a fourth heat exchange side. The precooler also comprises a fifth heat exchange side.
And a gas-phase air outlet of the gas-liquid separator is connected with an inlet of a fourth heat exchange side of the cold accumulator. The outlet of the fourth heat exchange side is connected with the inlet of the fifth heat exchange side of the precooler. And the outlet of the fifth heat exchange side is connected with the inlet of the secondary air compressor unit.
According to the liquid air energy storage and power generation system provided by the invention, the liquid air energy release unit comprises a cryogenic pump. The regenerator further comprises a sixth heat exchange side. The compression heat storage utilization device further comprises a seventh heat exchange side.
Wherein, the outlet of the cryogenic storage tank is connected with the inlet of the cryogenic pump. And the outlet of the cryogenic pump is connected with the inlet of the sixth heat exchange side of the cold accumulator. And the outlet of the sixth heat exchange side is connected with the inlet of the seventh heat exchange side of the compression heat storage and utilization device. And the outlet of the seventh heat exchange side is connected with the expansion power generation unit.
According to the liquid air energy storage power generation system provided by the invention, the expansion power generation unit comprises an air turbine set and a generator.
And an outlet of a seventh heat exchange side of the compression heat storage and utilization device is connected with an air inlet of the air turbine unit through an energy releasing and power generating pipeline. The air turbine set is connected with the generator.
According to the liquid air energy storage power generation system provided by the invention, the energy release power generation pipeline is provided with the first flow control valve.
According to the liquid air energy storage power generation system provided by the invention, the molecular sieve adsorption tower automatic regeneration unit comprises a hot blowing branch pipe. And an exhaust port of the air turbine unit is connected with an exhaust main pipe. The compression heat storage utilization device further comprises an eighth heat exchanging side. And the inlet of the eighth heat exchange side is connected with the exhaust manifold through the hot blowing branch pipe. And a second flow control valve is arranged on the hot blow branch pipe. And an outlet of the eighth heat exchange side is connected with the molecular sieve adsorption tower so as to carry out a hot blowing process.
According to the liquid air energy storage power generation system provided by the invention, the molecular sieve adsorption tower automatic regeneration unit further comprises a cold blowing branch pipe. And the molecular sieve adsorption tower is connected with the exhaust main pipe through the cold blowing branch pipe so as to carry out a cold blowing process. And a third flow control valve is arranged on the cold blow branch pipe.
According to the liquid air energy storage power generation system provided by the invention, the liquid air energy storage unit further comprises an electric motor. The motor is connected with the first-stage air compressor set and the second-stage air compressor set so as to drive the first-stage air compressor set and the second-stage air compressor set to operate.
According to the liquid air energy storage power generation system provided by the invention, the liquid air energy storage unit further comprises an air purification device, and an outlet of the air purification device is connected with an inlet of the primary air compressor unit.
In the liquid air energy storage power generation system provided by the invention, the liquid air energy storage unit is connected with the liquid air energy release unit. The liquid air energy release unit is connected with the expansion power generation unit so as to use the liquid air to carry out expansion power generation. The liquid air energy storage unit comprises a molecular sieve adsorption tower. The molecular sieve adsorption tower automatic regeneration unit is connected between the expansion power generation unit and the molecular sieve adsorption tower so as to use the exhaust gas of the expansion power generation unit to carry out the regeneration process of the molecular sieve adsorption tower.
Through the structural arrangement, the molecular sieve adsorption tower can perform adsorption work in the liquid air energy storage process; in the process of liquid air energy releasing expansion power generation, the molecular sieve adsorption tower can utilize the exhaust of the expansion power generation unit to carry out cold blowing and hot blowing processes. Therefore, the system can fully utilize cold and heat energy in the process of liquid air energy release expansion power generation to complete the automatic regeneration process of the molecular sieve adsorption tower, and the economical efficiency and the energy utilization efficiency of the system are improved.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly introduced below, and it is obvious that the drawings in the following description are some embodiments of the present invention, and for those skilled in the art, other drawings can be obtained according to these drawings without creative efforts.
FIG. 1 is a system diagram of a liquid air energy storage power generation system according to an embodiment of the present invention;
reference numerals:
1: an air purification device; 2: a primary air compressor unit;
3: a precooler; 4: a molecular sieve adsorption tower;
5: a secondary air compressor unit; 6: a compression heat storage utilization device;
7: a regenerator; 8: a throttling element;
9: a gas-liquid separator; 10: a low-temperature storage tank;
11: a cryopump; 12: a first flow control valve;
13: an air turbine unit; 14: a second flow control valve;
15: a third flow rate control valve; 16: an energy releasing and power generating pipeline;
17: hot-blowing the branch pipe; 18: an exhaust manifold;
19: cold-blowing the branch pipe; h1: a first heat exchange side;
h2: a second heat exchange side; h3: a third heat exchange side;
h4: a fourth heat exchange side; h5: a fifth heat exchange side;
h6: a sixth heat exchange side; h7: a seventh heat exchange side;
h8: an eighth heat exchange side; m: an electric motor;
g: an electric generator.
Detailed Description
The embodiments of the present invention will be described in further detail with reference to the drawings and examples. The following examples are intended to illustrate the invention but are not intended to limit the scope of the invention.
In the description of the embodiments of the present invention, it should be noted that the terms "central", "longitudinal" and "longitudinal" are used herein,
Horizontal, up, down, front, back, left, right, vertical and horizontal,
The terms "top," "bottom," "inner," "outer," and the like, as used herein, are used for convenience in describing embodiments of the invention and in order to simplify the description, and are not intended to imply that the referenced devices or elements must be in a particular orientation, constructed and operated in a particular orientation, and are not to be construed as limiting the embodiments of the invention. In addition, the term
"first" and "second" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance.
In the description of the embodiments of the present invention, it should be noted that, unless explicitly stated or limited otherwise, the terms "connected" and "connected" are to be interpreted broadly, and may be, for example, fixedly connected, detachably connected, or integrally connected; can be mechanically or electrically connected; may be directly connected or indirectly connected through an intermediate. Specific meanings of the above terms in the embodiments of the present invention can be understood in specific cases by those of ordinary skill in the art.
In embodiments of the invention, unless expressly stated or limited otherwise, the first feature "on" or "under" the second feature may be directly contacting the first and second features or indirectly contacting the first and second features through intervening media. Also, a first feature "on," "over," and "above" a second feature may be directly or diagonally above the second feature, or may simply indicate that the first feature is at a higher level than the second feature. A first feature being "under," "below," and "beneath" a second feature may be directly under or obliquely under the first feature, or may simply mean that the first feature is at a lesser elevation than the second feature.
In the description herein, references to the description of the term "one embodiment," "some embodiments," "an example," "a specific example," or "some examples," etc., mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of an embodiment of the invention. In this specification, the schematic representations of the terms used above are not necessarily intended to refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples. In addition, without contradiction, those skilled in the art may combine and combine different embodiments or examples and features of different embodiments or examples described in this specification to make the purpose, technical solution, and advantages of the embodiments of the present invention more clear, and the technical solution in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are a part of embodiments of the present invention, but not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The liquid air energy storage power generation system provided by the invention is described in the following with reference to fig. 1. It should be understood that the following description is only exemplary embodiments of the present invention and does not constitute any particular limitation of the present invention.
The invention provides a liquid air energy storage power generation system. As shown in fig. 1, the liquid air energy storage power generation system includes: the device comprises a liquid air energy storage unit, a liquid air energy release unit, an expansion power generation unit and a molecular sieve adsorption tower automatic regeneration unit.
Wherein, the liquid air energy storage unit is connected with the liquid air energy release unit. The liquid air energy release unit is connected with the expansion power generation unit so as to use the liquid air to carry out expansion power generation.
Wherein, the liquid air energy storage unit comprises a molecular sieve adsorption tower 4. The automatic regeneration unit of the molecular sieve adsorption tower is connected between the expansion power generation unit and the molecular sieve adsorption tower 4 so as to use the exhaust gas of the expansion power generation unit to carry out the regeneration process of the molecular sieve adsorption tower 4.
Through the structural arrangement, the molecular sieve adsorption tower 4 can perform adsorption work in the liquid air energy storage process; in the process of liquid air energy releasing expansion power generation, the molecular sieve adsorption tower 4 can utilize the exhaust gas of the expansion power generation unit to carry out cold blowing and hot blowing processes. Therefore, the system can fully utilize cold and heat energy in the process of liquid air energy release expansion power generation to complete the automatic regeneration process of the molecular sieve adsorption tower 4, and the economical efficiency and the energy utilization efficiency of the system are improved.
In one embodiment of the invention, the liquid air energy storage unit further comprises a primary air compressor unit 2, a precooler 3, a secondary air compressor unit 5, a compression heat storage utilization device 6, a cold accumulator 7, a throttling element 8, a gas-liquid separator 9 and a low-temperature storage tank 10. The precooler 3 comprises a first heat exchange side H1. The compression heat storage utilization device 6 includes a second heat exchanging side H2. The regenerator 7 includes a third heat exchanging side H3.
Wherein the outlet of the primary air compressor group 2 is connected with the inlet of the first heat exchanging side H1 of the precooler 3. The outlet of the first heat exchange side H1 is connected with the inlet of the molecular sieve adsorption tower 4. The outlet of the molecular sieve adsorption tower 4 is connected with the inlet of the secondary air compressor unit 5. The outlet of the secondary air compressor group 5 is connected to the inlet of the second heat exchange side H2 of the compression heat storage utilization device 6. The outlet of the second heat exchanging side H2 is connected to the inlet of the third heat exchanging side H3 of the regenerator 7. The outlet of the third heat exchanging side H3 is connected to the inlet of the restriction element 8. The outlet of the throttling element 8 is connected with the inlet of a gas-liquid separator 9. The liquid air outlet of the gas-liquid separator 9 is connected with the inlet of the low-temperature storage tank 10.
In one embodiment of the invention, the liquid air energy storage unit further comprises an electric motor M. The motor M is connected with the first-stage air compressor unit 2 and the second-stage air compressor unit 5 to drive the first-stage air compressor unit 2 and the second-stage air compressor unit 5 to operate.
Further, in yet another embodiment of the present invention, the liquid air energy storage unit further comprises an air purification device 1. The outlet of the air purification device 1 is connected with the inlet of the primary air compressor unit 2.
Specifically, in the liquid air energy storage process, the motor M drives the primary air compressor set 2 and the secondary air compressor set 5 to operate. The air in normal temperature and normal pressure state is purified by the air purification device 1 and then compressed to medium temperature and high pressure state by the first-stage air compressor unit 2.
Air in a medium-temperature and high-pressure state enters the precooler 3 from the inlet of the first heat exchanging side H1. The air cooled by the precooler 3 enters the molecular sieve adsorption tower 4 from the outlet of the first heat exchange side H1 to be subjected to the adsorption process. The air absorbed by the molecular sieve absorption tower 4 enters a secondary air compressor unit 5 to be continuously pressurized. The air pressurized by the secondary air compressor unit 5 enters the compression heat storage and utilization device 6 from the inlet of the second heat exchange side H2, and the compression heat is stored in the compression heat storage and utilization device 6 and cooled to the normal temperature. Air in a normal-temperature and high-pressure state enters the cold accumulator 7 from the outlet of the second heat exchange side H2 and the inlet of the third heat exchange side H3, absorbs cold energy in the cold accumulation medium and is cooled to a low-temperature state. Air in a low-temperature and high-pressure state enters the throttling element 8 from an outlet of the third heat exchange side H3, and gas-liquid two-phase air is generated after the pressure reduction and expansion of the throttling element 8 and enters the gas-liquid separator 9. Wherein, the liquid air flows from the liquid air outlet of the gas-liquid separator 9 and is stored in the low-temperature storage tank 10. Therefore, the energy storage process of the liquid air is completed.
It should be noted here that the present invention is not limited in any way as to the type of the air cleaning device 1. For example, the air cleaning device 1 described above includes a self-cleaning filter.
The primary air compressor unit 2 and the secondary air compressor unit 5 may be in the form of piston type, screw type or centrifugal type. And the primary and secondary air compressor sets 2, 5 may include one or more air compressors. The plurality of air compressors can be connected in series, in parallel or integrated into a corresponding air compressor unit.
The precooler 3 can be in one or a combination of a plurality of shell-and-tube structure, plate-fin structure, wound tube structure and the like, and can also be an air cooling tower.
The compression heat storage and utilization device 6 can be a packed bed type heat accumulator, and can also be a hot water circulation system or a heat conduction oil circulation system.
The regenerator 7 may use one or more of liquid phase (methanol, propane, R123, and the like), solid phase (metal, rock, glass, and the like), or phase change regenerator material, and the like. The liquid or gaseous air directly or indirectly contacts with the cold accumulation medium for heat exchange. The regenerator 7 may be provided in one or more stages.
The throttling element 8 includes, but is not limited to, a cryogenic expander, and the cryogenic expander includes, but is not limited to, a flooded expander or a pure liquid expander.
The cryogenic tank 10 may be a dewar or a cryogenic storage tank.
In one embodiment of the present invention, the regenerator 7 further comprises a fourth heat exchanging side H4. The precooler 3 also comprises a fifth heat exchange side H5.
The gas-phase air outlet of the gas-liquid separator 9 is connected to the inlet of the fourth heat exchanging side H4 of the regenerator 7. The outlet of the fourth heat exchanging side H4 is connected to the inlet of the fifth heat exchanging side H5 of the precooler 3. The outlet of the fifth heat exchange side H5 is connected to the inlet of the secondary air compressor package 5.
In combination with the above embodiment, the gas-phase air separated by the gas-liquid separator 9 flows back into the cold storage device 7 from the gas-phase air outlet of the gas-liquid separator 9 and the inlet of the fourth heat exchanging side H4 to provide cooling energy for the cold storage device 7, then enters the precooler 3 from the outlet of the fourth heat exchanging side H4 and the inlet of the fifth heat exchanging side H5 to cool the air entering the precooler 3 from the primary air compressor unit 2 and raise the temperature, and the air after temperature rise is collected into the secondary air compressor unit 5 to be compressed and reused.
In one embodiment of the present invention, the liquid air discharge unit comprises a cryopump 11. The regenerator 7 further comprises a sixth heat exchanging side H6. The compression heat storage utilization device 6 further includes a seventh heat exchanging side H7.
Wherein, the outlet of the cryogenic tank 10 is connected with the inlet of the cryogenic pump 11. The outlet of the cryopump 11 is connected to the inlet of the sixth heat exchanging side H6 of the regenerator 7. An outlet of the sixth heat exchanging side H6 is connected to an inlet of the seventh heat exchanging side H7 of the compression heat storage utilization device 6. The outlet of the seventh heat exchanging side H7 is connected with an expansion power generation unit.
Further, in one embodiment of the present invention, the expansion power generation unit includes an air turbine unit 13 and a generator G.
The outlet of the seventh heat exchange side H7 of the compression heat storage utilization device 6 is connected to the air inlet of the air turbine unit 13 via the energy release and power generation line 16. The air turbine unit 13 is connected to a generator G.
Further, in one embodiment of the present invention, the first flow control valve 12 is provided on the energy discharge power generation line 16.
Specifically, in the process of liquid air energy release power generation, liquid air in the low-temperature storage tank 10 is pressurized by the low-temperature pump 11 and then enters the cold accumulator 7 from the inlet of the sixth heat exchange side H6, and cold energy is stored in the cold accumulation medium and then is reheated and gasified. The air after being reheated enters the compression heat storage utilization device 6 from the outlet of the sixth heat exchanging side H6 and the inlet of the seventh heat exchanging side H7 to be preheated. The air preheated by the compressed heat storage utilization device 6 enters the air turbine set 13 from the outlet of the seventh heat exchange side H7 through the energy-releasing power generation pipeline 16 to do work, and further drives the generator G to generate power. At the same time, the first flow control valve 12 on the energy release and power generation line 16 can control the flow of air into the air turbine set 13.
It should be noted here that the cryopump 11 may be of a piston type, a centrifugal type, or the like. The air turbine unit 13 may be configured in the form of a radial flow, an axial flow, a radial axial flow, or the like. And air turbine assembly 13 may include one or more air turbines. A plurality of air turbines are connected in series, in parallel, or integrated into an air turbine unit 13.
In one embodiment of the invention, the molecular sieve adsorption column automatic regeneration unit comprises a hot blow line 17. An exhaust manifold 18 is connected to the exhaust port of air turbine unit 13. The compression heat storage utilization device 6 further includes an eighth heat exchanging side H8. The inlet of the eighth heat exchanging side H8 is connected to the exhaust manifold 18 via the hot blast branch pipe 17. The hot blow branch pipe 17 is provided with a second flow control valve 14. The outlet of the eighth heat exchange side H8 is connected with the molecular sieve adsorption tower 4 to carry out a hot blowing process.
In the hot blowing process of the molecular sieve adsorption tower 4, the second flow control valve 14 is opened, and the dry and clean exhaust gas of the air turbine set 13 enters the compression heat storage and utilization device 6 from the inlet of the eighth heat exchange side H8 through the exhaust manifold 18 and the hot blowing branch pipe 17 for preheating, and then enters the molecular sieve adsorption tower 4 from the outlet of the eighth heat exchange side H8 for hot blowing process.
In one embodiment of the invention, the molecular sieve adsorption column automatic regeneration unit further comprises a cold blow branch 19. The molecular sieve adsorption tower 4 is connected with an exhaust manifold 18 through a cold blowing branch pipe 19 to carry out a cold blowing process. The third flow control valve 15 is provided on the cold blow branch pipe 19.
And after the molecular sieve adsorption tower 4 completes the hot blowing process and reaches the desorption standard, opening the third flow control valve 15 and closing the second flow control valve 14 to perform the cold blowing process of the molecular sieve adsorption tower 4. The dry clean exhaust gas of the air turbine unit 13 enters the molecular sieve adsorption tower 4 through the exhaust manifold 18 and the cold blow branch pipe 19 for the cold blow process. Thereby, the automatic regeneration process of the molecular sieve adsorption tower 4 is completed.
According to the embodiments described above, the liquid air energy storage power generation system can realize that the molecular sieve adsorption tower 4 performs adsorption work in the liquid air energy storage process; in the process of liquid air energy release power generation, the exhaust gas of the air turbine set 13 is utilized to carry out cold blowing and hot blowing processes of the molecular sieve adsorption tower 4. Thereby, the molecular sieve adsorption tower 4 can perform the circulation continuous adsorption and regeneration process.
It should be noted here that the first flow control valve 12, the second flow control valve 14, and the third flow control valve 15 include, but are not limited to, pneumatic, electric, or liquid-state driving forms.
Finally, it should be noted that: the above examples are only intended to illustrate the technical solution of the present invention, but not to limit it; although the present invention has been described in detail with reference to the foregoing embodiments, it will be understood by those of ordinary skill in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some technical features may be equivalently replaced; and such modifications or substitutions do not depart from the spirit and scope of the corresponding technical solutions of the embodiments of the present invention.
Claims (10)
1. A liquid air energy storage power generation system, comprising: a liquid air energy storage unit, a liquid air energy release unit, an expansion power generation unit and a molecular sieve adsorption tower automatic regeneration unit,
wherein the liquid air energy storage unit is connected with the liquid air energy release unit, the liquid air energy release unit is connected with the expansion power generation unit so as to use liquid air to perform expansion power generation,
the liquid air energy storage unit comprises a molecular sieve adsorption tower (4), and the automatic regeneration unit of the molecular sieve adsorption tower is connected between the expansion power generation unit and the molecular sieve adsorption tower (4) so as to use the exhaust gas of the expansion power generation unit to carry out the regeneration process of the molecular sieve adsorption tower (4).
2. The liquid air energy storage and power generation system according to claim 1, wherein the liquid air energy storage unit further comprises a primary air compressor set (2), a precooler (3), a secondary air compressor set (5), a compression heat storage and utilization device (6), a cold accumulator (7), a throttling element (8), a gas-liquid separator (9) and a cryogenic storage tank (10), the precooler (3) comprises a first heat exchange side (H1), the compression heat storage and utilization device (6) comprises a second heat exchange side (H2), the cold accumulator (7) comprises a third heat exchange side (H3),
wherein the outlet of the primary air compressor group (2) is connected with the inlet of the first heat exchange side (H1) of the precooler (3), the outlet of the first heat exchange side (H1) is connected with the inlet of the molecular sieve adsorption tower (4), the outlet of the molecular sieve adsorption tower (4) is connected with the inlet of the secondary air compressor unit (5), the outlet of the secondary air compressor unit (5) is connected with the inlet of the second heat exchange side (H2) of the compression heat storage utilization device (6), the outlet of the second heat exchange side (H2) is connected with the inlet of the third heat exchange side (H3) of the cold accumulator (7), the outlet of the third heat exchange side (H3) is connected with the inlet of the throttling element (8), the outlet of the throttling element (8) is connected with the inlet of the gas-liquid separator (9), and a liquid air outlet of the gas-liquid separator (9) is connected with an inlet of the low-temperature storage tank (10).
3. Liquid air energy storage and power generation system according to claim 2, characterized in that the cold accumulator (7) further comprises a fourth heat exchanging side (H4), the precooler (3) further comprises a fifth heat exchanging side (H5),
the gas-phase air outlet of the gas-liquid separator (9) is connected with the inlet of a fourth heat exchange side (H4) of the cold accumulator (7), the outlet of the fourth heat exchange side (H4) is connected with the inlet of a fifth heat exchange side (H5) of the precooler (3), and the outlet of the fifth heat exchange side (H5) is connected with the inlet of the secondary air compressor unit (5).
4. A liquid air energy-storing and generating system according to claim 2, characterized in that the liquid air energy-releasing unit comprises a cryogenic pump (11), the cold accumulator (7) further comprises a sixth heat exchanging side (H6), the compressed heat storage utilization device (6) further comprises a seventh heat exchanging side (H7),
the outlet of the low-temperature storage tank (10) is connected with the inlet of the low-temperature pump (11), the outlet of the low-temperature pump (11) is connected with the inlet of a sixth heat exchange side (H6) of the cold accumulator (7), the outlet of the sixth heat exchange side (H6) is connected with the inlet of a seventh heat exchange side (H7) of the compression heat storage utilization device (6), and the outlet of the seventh heat exchange side (H7) is connected with the expansion power generation unit.
5. The liquid air energy storage and power generation system of claim 4, wherein the expansion and power generation unit comprises an air turbine set (13) and a generator (G),
the outlet of the seventh heat exchange side (H7) of the compression heat storage utilization device (6) is connected with the air inlet of the air turbine set (13) through an energy release power generation pipeline (16), and the air turbine set (13) is connected with the generator (G).
6. The liquid air energy storage power generation system according to claim 5, wherein a first flow control valve (12) is arranged on the energy release power generation pipeline (16).
7. The liquid air energy storage power generation system according to claim 5, wherein the molecular sieve adsorption tower automatic regeneration unit comprises a hot blowing branch pipe (17), an exhaust main pipe (18) is connected to an exhaust port of the air turbine set (13), the compression heat storage utilization device (6) further comprises an eighth heat exchange side (H8), an inlet of the eighth heat exchange side (H8) is connected with the exhaust main pipe (18) through the hot blowing branch pipe (17), a second flow control valve (14) is arranged on the hot blowing branch pipe (17), and an outlet of the eighth heat exchange side (H8) is connected with the molecular sieve adsorption tower (4) to perform a hot blowing process.
8. The liquid air energy-storage power generation system according to claim 5, wherein the molecular sieve adsorption tower automatic regeneration unit further comprises a cold blow branch pipe (19), the molecular sieve adsorption tower (4) is connected with the exhaust main pipe (18) through the cold blow branch pipe (19) to perform a cold blow process, and a third flow control valve (15) is arranged on the cold blow branch pipe (19).
9. The liquid air energy storage and power generation system according to claim 2, wherein the liquid air energy storage unit further comprises an electric motor (M) connected with the primary air compressor set (2) and the secondary air compressor set (5) to drive the primary air compressor set (2) and the secondary air compressor set (5) to operate.
10. The liquid air energy storage and power generation system according to claim 2, characterized in that the liquid air energy storage unit further comprises an air purification device (1), and an outlet of the air purification device (1) is connected with an inlet of the primary air compressor unit (2).
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