CN113194914B - 用于改善沉积的毛发调理组合物 - Google Patents
用于改善沉积的毛发调理组合物 Download PDFInfo
- Publication number
- CN113194914B CN113194914B CN201980084635.5A CN201980084635A CN113194914B CN 113194914 B CN113194914 B CN 113194914B CN 201980084635 A CN201980084635 A CN 201980084635A CN 113194914 B CN113194914 B CN 113194914B
- Authority
- CN
- China
- Prior art keywords
- composition
- trimethyl
- surfactant
- hair
- ammonium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 133
- 230000003750 conditioning effect Effects 0.000 title claims abstract description 51
- 230000008021 deposition Effects 0.000 title claims abstract description 12
- 239000000463 material Substances 0.000 claims abstract description 42
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 37
- 125000002091 cationic group Chemical group 0.000 claims abstract description 30
- 239000004094 surface-active agent Substances 0.000 claims abstract description 30
- 230000008901 benefit Effects 0.000 claims abstract description 29
- 239000011149 active material Substances 0.000 claims abstract description 5
- 229920001296 polysiloxane Polymers 0.000 claims description 46
- -1 dioctylamino Chemical group 0.000 claims description 40
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 claims description 19
- 239000000839 emulsion Substances 0.000 claims description 19
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 16
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 13
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 12
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 9
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 claims description 8
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 5
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 claims description 4
- QIVLQXGSQSFTIF-UHFFFAOYSA-M docosyl(trimethyl)azanium;methyl sulfate Chemical compound COS([O-])(=O)=O.CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C QIVLQXGSQSFTIF-UHFFFAOYSA-M 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical class C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 abstract description 37
- 239000003093 cationic surfactant Substances 0.000 abstract description 18
- 239000003205 fragrance Substances 0.000 abstract description 17
- IUHFWCGCSVTMPG-UHFFFAOYSA-N [C].[C] Chemical group [C].[C] IUHFWCGCSVTMPG-UHFFFAOYSA-N 0.000 abstract description 16
- 229920006395 saturated elastomer Polymers 0.000 abstract description 12
- 210000004761 scalp Anatomy 0.000 abstract description 6
- 150000001449 anionic compounds Chemical group 0.000 abstract description 4
- 229910001412 inorganic anion Chemical group 0.000 abstract description 4
- 150000002891 organic anions Chemical group 0.000 abstract description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 13
- 238000000151 deposition Methods 0.000 description 11
- 150000002191 fatty alcohols Chemical class 0.000 description 11
- 238000011282 treatment Methods 0.000 description 11
- 239000003094 microcapsule Substances 0.000 description 9
- 241000402754 Erythranthe moschata Species 0.000 description 7
- 239000002253 acid Substances 0.000 description 7
- 239000004615 ingredient Substances 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 5
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical class C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 5
- 125000001183 hydrocarbyl group Chemical group 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- ROSDSFDQCJNGOL-UHFFFAOYSA-N protonated dimethyl amine Natural products CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 4
- PQNFLJBBNBOBRQ-UHFFFAOYSA-N indane Chemical compound C1=CC=C2CCCC2=C1 PQNFLJBBNBOBRQ-UHFFFAOYSA-N 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- WWVIUVHFPSALDO-UHFFFAOYSA-N n-[3-(dimethylamino)propyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCCN(C)C WWVIUVHFPSALDO-UHFFFAOYSA-N 0.000 description 4
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 4
- 239000002453 shampoo Substances 0.000 description 4
- 229920005573 silicon-containing polymer Polymers 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 229940022663 acetate Drugs 0.000 description 3
- 125000003368 amide group Chemical group 0.000 description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 3
- 229960003237 betaine Drugs 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
- 125000004185 ester group Chemical group 0.000 description 3
- CCIVGXIOQKPBKL-UHFFFAOYSA-M ethanesulfonate Chemical compound CCS([O-])(=O)=O CCIVGXIOQKPBKL-UHFFFAOYSA-M 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 239000004530 micro-emulsion Substances 0.000 description 3
- 229940049292 n-(3-(dimethylamino)propyl)octadecanamide Drugs 0.000 description 3
- 150000007524 organic acids Chemical class 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- BTSZTGGZJQFALU-UHFFFAOYSA-N piroctone olamine Chemical compound NCCO.CC(C)(C)CC(C)CC1=CC(C)=CC(=O)N1O BTSZTGGZJQFALU-UHFFFAOYSA-N 0.000 description 3
- 125000001453 quaternary ammonium group Chemical group 0.000 description 3
- 238000000518 rheometry Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- OWEGWHBOCFMBLP-UHFFFAOYSA-N 1-(4-chlorophenoxy)-1-(1H-imidazol-1-yl)-3,3-dimethylbutan-2-one Chemical compound C1=CN=CN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 OWEGWHBOCFMBLP-UHFFFAOYSA-N 0.000 description 2
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- YCIXWYOBMVNGTB-UHFFFAOYSA-N 3-Methyl-2-pentyl-2-cyclopentenone Natural products CCCCCC1=C(C)CCC1=O YCIXWYOBMVNGTB-UHFFFAOYSA-N 0.000 description 2
- ZCTQGTTXIYCGGC-UHFFFAOYSA-N Benzyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OCC1=CC=CC=C1 ZCTQGTTXIYCGGC-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 238000012695 Interfacial polymerization Methods 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 229920002396 Polyurea Polymers 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
- 235000011054 acetic acid Nutrition 0.000 description 2
- IGODOXYLBBXFDW-UHFFFAOYSA-N alpha-Terpinyl acetate Chemical compound CC(=O)OC(C)(C)C1CCC(C)=CC1 IGODOXYLBBXFDW-UHFFFAOYSA-N 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 2
- 150000003851 azoles Chemical class 0.000 description 2
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 2
- SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 2
- JOZKFWLRHCDGJA-UHFFFAOYSA-N citronellol acetate Chemical compound CC(=O)OCCC(C)CCC=C(C)C JOZKFWLRHCDGJA-UHFFFAOYSA-N 0.000 description 2
- 229960003344 climbazole Drugs 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- KSMVZQYAVGTKIV-UHFFFAOYSA-N decanal Chemical compound CCCCCCCCCC=O KSMVZQYAVGTKIV-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- HFJRKMMYBMWEAD-UHFFFAOYSA-N dodecanal Chemical compound CCCCCCCCCCCC=O HFJRKMMYBMWEAD-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 125000001033 ether group Chemical group 0.000 description 2
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- 235000011087 fumaric acid Nutrition 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 235000011167 hydrochloric acid Nutrition 0.000 description 2
- 229930002839 ionone Natural products 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- UWKAYLJWKGQEPM-LBPRGKRZSA-N linalyl acetate Chemical compound CC(C)=CCC[C@](C)(C=C)OC(C)=O UWKAYLJWKGQEPM-LBPRGKRZSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- KKBOOQDFOWZSDC-UHFFFAOYSA-N n-[2-(diethylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCN(CC)CC KKBOOQDFOWZSDC-UHFFFAOYSA-N 0.000 description 2
- MNAZHGAWPCLLGX-UHFFFAOYSA-N n-[3-(dimethylamino)propyl]docosanamide Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)NCCCN(C)C MNAZHGAWPCLLGX-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- ZRSNZINYAWTAHE-UHFFFAOYSA-N p-methoxybenzaldehyde Chemical compound COC1=CC=C(C=O)C=C1 ZRSNZINYAWTAHE-UHFFFAOYSA-N 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- MDHYEMXUFSJLGV-UHFFFAOYSA-N phenethyl acetate Chemical compound CC(=O)OCCC1=CC=CC=C1 MDHYEMXUFSJLGV-UHFFFAOYSA-N 0.000 description 2
- SATCULPHIDQDRE-UHFFFAOYSA-N piperonal Chemical compound O=CC1=CC=C2OCOC2=C1 SATCULPHIDQDRE-UHFFFAOYSA-N 0.000 description 2
- 229950001046 piroctone Drugs 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- FGVVTMRZYROCTH-UHFFFAOYSA-N pyridine-2-thiol N-oxide Chemical compound [O-][N+]1=CC=CC=C1S FGVVTMRZYROCTH-UHFFFAOYSA-N 0.000 description 2
- 229960002026 pyrithione Drugs 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 2
- 229940032160 stearamidoethyl diethylamine Drugs 0.000 description 2
- 239000011975 tartaric acid Substances 0.000 description 2
- 235000002906 tartaric acid Nutrition 0.000 description 2
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 2
- 229940088594 vitamin Drugs 0.000 description 2
- 229930003231 vitamin Natural products 0.000 description 2
- 239000011782 vitamin Substances 0.000 description 2
- 235000013343 vitamin Nutrition 0.000 description 2
- 239000001414 (2E)-2-(phenylmethylidene)octanal Substances 0.000 description 1
- XMAYWYJOQHXEEK-OZXSUGGESA-N (2R,4S)-ketoconazole Chemical compound C1CN(C(=O)C)CCN1C(C=C1)=CC=C1OC[C@@H]1O[C@@](CN2C=NC=C2)(C=2C(=CC(Cl)=CC=2)Cl)OC1 XMAYWYJOQHXEEK-OZXSUGGESA-N 0.000 description 1
- HLCSDJLATUNSSI-JXMROGBWSA-N (2e)-3,7-dimethylocta-2,6-dienenitrile Chemical compound CC(C)=CCC\C(C)=C\C#N HLCSDJLATUNSSI-JXMROGBWSA-N 0.000 description 1
- VSRVCSJJKWDZSH-UHFFFAOYSA-N (3-pentyloxan-4-yl) acetate Chemical compound CCCCCC1COCCC1OC(C)=O VSRVCSJJKWDZSH-UHFFFAOYSA-N 0.000 description 1
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 1
- MTDAKBBUYMYKAR-SNVBAGLBSA-N (3r)-3,7-dimethyloct-6-enenitrile Chemical compound N#CC[C@H](C)CCC=C(C)C MTDAKBBUYMYKAR-SNVBAGLBSA-N 0.000 description 1
- VCOCESNMLNDPLX-BTXGZQJSSA-N (3s,6s)-2,2,8,8-tetramethyl-octahydro-1h-2,4a-methanonapthalene-10-one Chemical compound O=C1CCC(C)(C)[C@@]2(C3)C1C(C)(C)[C@H]3CC2 VCOCESNMLNDPLX-BTXGZQJSSA-N 0.000 description 1
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 description 1
- PHIQHXFUZVPYII-ZCFIWIBFSA-N (R)-carnitine Chemical compound C[N+](C)(C)C[C@H](O)CC([O-])=O PHIQHXFUZVPYII-ZCFIWIBFSA-N 0.000 description 1
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- UFLHIIWVXFIJGU-ARJAWSKDSA-N (Z)-hex-3-en-1-ol Chemical compound CC\C=C/CCO UFLHIIWVXFIJGU-ARJAWSKDSA-N 0.000 description 1
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 1
- FSWYUDLVKBSHDX-UHFFFAOYSA-N 1,4,5,8-tetrahydronaphthalene Chemical compound C1C=CCC2=C1CC=CC2 FSWYUDLVKBSHDX-UHFFFAOYSA-N 0.000 description 1
- VPKMGDRERYMTJX-CMDGGOBGSA-N 1-(2,6,6-Trimethyl-2-cyclohexen-1-yl)-1-penten-3-one Chemical compound CCC(=O)\C=C\C1C(C)=CCCC1(C)C VPKMGDRERYMTJX-CMDGGOBGSA-N 0.000 description 1
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 1
- HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 description 1
- FYERTDTXGGOMGT-UHFFFAOYSA-N 2,2-diethoxyethylbenzene Chemical compound CCOC(OCC)CC1=CC=CC=C1 FYERTDTXGGOMGT-UHFFFAOYSA-N 0.000 description 1
- WNJSKZBEWNVKGU-UHFFFAOYSA-N 2,2-dimethoxyethylbenzene Chemical compound COC(OC)CC1=CC=CC=C1 WNJSKZBEWNVKGU-UHFFFAOYSA-N 0.000 description 1
- BEARMGATPGLSKG-UHFFFAOYSA-N 2,6-dimethyloct-7-en-2-yl acetate Chemical compound C=CC(C)CCCC(C)(C)OC(C)=O BEARMGATPGLSKG-UHFFFAOYSA-N 0.000 description 1
- WRFXXJKURVTLSY-UHFFFAOYSA-N 2,6-dimethyloctan-2-ol Chemical compound CCC(C)CCCC(C)(C)O WRFXXJKURVTLSY-UHFFFAOYSA-N 0.000 description 1
- GQDUXZKNWUFJLT-UHFFFAOYSA-N 2-(2-pentylcyclopentyl)acetic acid Chemical compound CCCCCC1CCCC1CC(O)=O GQDUXZKNWUFJLT-UHFFFAOYSA-N 0.000 description 1
- SNOVXNPIRUDJNG-UHFFFAOYSA-N 2-(4-tert-butylphenyl)propanal Chemical compound O=CC(C)C1=CC=C(C(C)(C)C)C=C1 SNOVXNPIRUDJNG-UHFFFAOYSA-N 0.000 description 1
- MJTPMXWJHPOWGH-UHFFFAOYSA-N 2-Phenoxyethyl isobutyrate Chemical compound CC(C)C(=O)OCCOC1=CC=CC=C1 MJTPMXWJHPOWGH-UHFFFAOYSA-N 0.000 description 1
- PJXHBTZLHITWFX-UHFFFAOYSA-N 2-heptylcyclopentan-1-one Chemical compound CCCCCCCC1CCCC1=O PJXHBTZLHITWFX-UHFFFAOYSA-N 0.000 description 1
- FSAMVJAGJWGWTQ-UHFFFAOYSA-N 2-hexadecoxyethanol Chemical compound CCCCCCCCCCCCCCCCOCCO FSAMVJAGJWGWTQ-UHFFFAOYSA-N 0.000 description 1
- RIWRBSMFKVOJMN-UHFFFAOYSA-N 2-methyl-1-phenylpropan-2-ol Chemical compound CC(C)(O)CC1=CC=CC=C1 RIWRBSMFKVOJMN-UHFFFAOYSA-N 0.000 description 1
- BJLRAKFWOUAROE-UHFFFAOYSA-N 2500-83-6 Chemical compound C12C=CCC2C2CC(OC(=O)C)C1C2 BJLRAKFWOUAROE-UHFFFAOYSA-N 0.000 description 1
- DLHQZZUEERVIGQ-UHFFFAOYSA-N 3,7-dimethyl-3-octanol Chemical compound CCC(C)(O)CCCC(C)C DLHQZZUEERVIGQ-UHFFFAOYSA-N 0.000 description 1
- GOLORTLGFDVFDW-UHFFFAOYSA-N 3-(1h-benzimidazol-2-yl)-7-(diethylamino)chromen-2-one Chemical compound C1=CC=C2NC(C3=CC4=CC=C(C=C4OC3=O)N(CC)CC)=NC2=C1 GOLORTLGFDVFDW-UHFFFAOYSA-N 0.000 description 1
- MQBIZQLCHSZBOI-UHFFFAOYSA-N 4-(4-Methyl-3-pentenyl)-3-cyclohexene-1-carboxaldehyde Chemical compound CC(C)=CCCC1=CCC(C=O)CC1 MQBIZQLCHSZBOI-UHFFFAOYSA-N 0.000 description 1
- ORMHZBNNECIKOH-UHFFFAOYSA-N 4-(4-hydroxy-4-methylpentyl)cyclohex-3-ene-1-carbaldehyde Chemical compound CC(C)(O)CCCC1=CCC(C=O)CC1 ORMHZBNNECIKOH-UHFFFAOYSA-N 0.000 description 1
- MBVFRSJFKMJRHA-UHFFFAOYSA-N 4-fluoro-1-benzofuran-7-carbaldehyde Chemical compound FC1=CC=C(C=O)C2=C1C=CO2 MBVFRSJFKMJRHA-UHFFFAOYSA-N 0.000 description 1
- MBZRJSQZCBXRGK-UHFFFAOYSA-N 4-tert-Butylcyclohexyl acetate Chemical compound CC(=O)OC1CCC(C(C)(C)C)CC1 MBZRJSQZCBXRGK-UHFFFAOYSA-N 0.000 description 1
- LJSJTXAZFHYHMM-UHFFFAOYSA-N 7-methyloctyl acetate Chemical compound CC(C)CCCCCCOC(C)=O LJSJTXAZFHYHMM-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- 229920013683 Celanese Polymers 0.000 description 1
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- JOZKFWLRHCDGJA-LLVKDONJSA-N Citronellyl acetate Natural products CC(=O)OCC[C@H](C)CCC=C(C)C JOZKFWLRHCDGJA-LLVKDONJSA-N 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- ACTIUHUUMQJHFO-UHFFFAOYSA-N Coenzym Q10 Natural products COC1=C(OC)C(=O)C(CC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)C)=C(C)C1=O ACTIUHUUMQJHFO-UHFFFAOYSA-N 0.000 description 1
- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000005770 Eugenol Substances 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 239000005792 Geraniol Substances 0.000 description 1
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 description 1
- 102000011782 Keratins Human genes 0.000 description 1
- 108010076876 Keratins Proteins 0.000 description 1
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 239000004368 Modified starch Substances 0.000 description 1
- OKIZCWYLBDKLSU-UHFFFAOYSA-M N,N,N-Trimethylmethanaminium chloride Chemical compound [Cl-].C[N+](C)(C)C OKIZCWYLBDKLSU-UHFFFAOYSA-M 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- FMFHUEMLVAIBFI-BQYQJAHWSA-N [(e)-2-phenylethenyl] acetate Chemical compound CC(=O)O\C=C\C1=CC=CC=C1 FMFHUEMLVAIBFI-BQYQJAHWSA-N 0.000 description 1
- DFPAKSUCGFBDDF-ZQBYOMGUSA-N [14c]-nicotinamide Chemical compound N[14C](=O)C1=CC=CN=C1 DFPAKSUCGFBDDF-ZQBYOMGUSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- JKRWZLOCPLZZEI-UHFFFAOYSA-N alpha-Trichloromethylbenzyl acetate Chemical compound CC(=O)OC(C(Cl)(Cl)Cl)C1=CC=CC=C1 JKRWZLOCPLZZEI-UHFFFAOYSA-N 0.000 description 1
- GUUHFMWKWLOQMM-NTCAYCPXSA-N alpha-hexylcinnamaldehyde Chemical compound CCCCCC\C(C=O)=C/C1=CC=CC=C1 GUUHFMWKWLOQMM-NTCAYCPXSA-N 0.000 description 1
- 229940072717 alpha-hexylcinnamaldehyde Drugs 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- JZQOJFLIJNRDHK-CMDGGOBGSA-N alpha-irone Chemical compound CC1CC=C(C)C(\C=C\C(C)=O)C1(C)C JZQOJFLIJNRDHK-CMDGGOBGSA-N 0.000 description 1
- GUUHFMWKWLOQMM-UHFFFAOYSA-N alpha-n-hexylcinnamic aldehyde Natural products CCCCCCC(C=O)=CC1=CC=CC=C1 GUUHFMWKWLOQMM-UHFFFAOYSA-N 0.000 description 1
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 229920003180 amino resin Polymers 0.000 description 1
- 229920013822 aminosilicone Polymers 0.000 description 1
- 229940062909 amyl salicylate Drugs 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229940007550 benzyl acetate Drugs 0.000 description 1
- 229960002903 benzyl benzoate Drugs 0.000 description 1
- TTZLKXKJIMOHHG-UHFFFAOYSA-M benzyl-decyl-dimethylazanium;chloride Chemical compound [Cl-].CCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 TTZLKXKJIMOHHG-UHFFFAOYSA-M 0.000 description 1
- LCIBGFGHZVRAHD-UHFFFAOYSA-L benzyl-dimethyl-octadecylazanium;sulfate Chemical compound [O-]S([O-])(=O)=O.CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1.CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 LCIBGFGHZVRAHD-UHFFFAOYSA-L 0.000 description 1
- PXFDQFDPXWHEEP-UHFFFAOYSA-M benzyl-dimethyl-octylazanium;chloride Chemical compound [Cl-].CCCCCCCC[N+](C)(C)CC1=CC=CC=C1 PXFDQFDPXWHEEP-UHFFFAOYSA-M 0.000 description 1
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 125000006297 carbonyl amino group Chemical group [H]N([*:2])C([*:1])=O 0.000 description 1
- 150000001767 cationic compounds Chemical class 0.000 description 1
- YMKDRGPMQRFJGP-UHFFFAOYSA-M cetylpyridinium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 YMKDRGPMQRFJGP-UHFFFAOYSA-M 0.000 description 1
- 229960001927 cetylpyridinium chloride Drugs 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 235000000484 citronellol Nutrition 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 235000017471 coenzyme Q10 Nutrition 0.000 description 1
- ACTIUHUUMQJHFO-UPTCCGCDSA-N coenzyme Q10 Chemical compound COC1=C(OC)C(=O)C(C\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CCC=C(C)C)=C(C)C1=O ACTIUHUUMQJHFO-UPTCCGCDSA-N 0.000 description 1
- 239000004064 cosurfactant Substances 0.000 description 1
- BLBJUGKATXCWET-UHFFFAOYSA-N cyclaprop Chemical compound C12CC=CC2C2CC(OC(=O)CC)C1C2 BLBJUGKATXCWET-UHFFFAOYSA-N 0.000 description 1
- ZAKOWWREFLAJOT-UHFFFAOYSA-N d-alpha-Tocopheryl acetate Natural products CC(=O)OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-UHFFFAOYSA-N 0.000 description 1
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 1
- WLCFKPHMRNPAFZ-UHFFFAOYSA-M didodecyl(dimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCC WLCFKPHMRNPAFZ-UHFFFAOYSA-M 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- ZCPCLAPUXMZUCD-UHFFFAOYSA-M dihexadecyl(dimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCC ZCPCLAPUXMZUCD-UHFFFAOYSA-M 0.000 description 1
- 229930008394 dihydromyrcenol Natural products 0.000 description 1
- XSNQECSCDATQEL-UHFFFAOYSA-N dihydromyrcenol Chemical compound C=CC(C)CCCC(C)(C)O XSNQECSCDATQEL-UHFFFAOYSA-N 0.000 description 1
- 229940008099 dimethicone Drugs 0.000 description 1
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 description 1
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- WQXNXVUDBPYKBA-YFKPBYRVSA-N ectoine Chemical compound CC1=[NH+][C@H](C([O-])=O)CCN1 WQXNXVUDBPYKBA-YFKPBYRVSA-N 0.000 description 1
- NYNCZOLNVTXTTP-UHFFFAOYSA-N ethyl 2-(1,3-dioxoisoindol-2-yl)acetate Chemical compound C1=CC=C2C(=O)N(CC(=O)OCC)C(=O)C2=C1 NYNCZOLNVTXTTP-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229960002217 eugenol Drugs 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000013020 final formulation Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- HIGQPQRQIQDZMP-UHFFFAOYSA-N geranil acetate Natural products CC(C)=CCCC(C)=CCOC(C)=O HIGQPQRQIQDZMP-UHFFFAOYSA-N 0.000 description 1
- 229940113087 geraniol Drugs 0.000 description 1
- HIGQPQRQIQDZMP-DHZHZOJOSA-N geranyl acetate Chemical compound CC(C)=CCC\C(C)=C\COC(C)=O HIGQPQRQIQDZMP-DHZHZOJOSA-N 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000003676 hair preparation Substances 0.000 description 1
- 230000003741 hair volume Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- UFLHIIWVXFIJGU-UHFFFAOYSA-N hex-3-en-1-ol Natural products CCC=CCCO UFLHIIWVXFIJGU-UHFFFAOYSA-N 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- WPFVBOQKRVRMJB-UHFFFAOYSA-N hydroxycitronellal Chemical compound O=CCC(C)CCCC(C)(C)O WPFVBOQKRVRMJB-UHFFFAOYSA-N 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 150000002499 ionone derivatives Chemical class 0.000 description 1
- 229960004125 ketoconazole Drugs 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000002356 laser light scattering Methods 0.000 description 1
- SDQFDHOLCGWZPU-UHFFFAOYSA-N lilial Chemical compound O=CC(C)CC1=CC=C(C(C)(C)C)C=C1 SDQFDHOLCGWZPU-UHFFFAOYSA-N 0.000 description 1
- 229930007744 linalool Natural products 0.000 description 1
- UWKAYLJWKGQEPM-UHFFFAOYSA-N linalool acetate Natural products CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 150000007931 macrolactones Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- KHPAAXRLVYMUHU-UHFFFAOYSA-N n-[2-(diethylamino)ethyl]docosanamide Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)NCCN(CC)CC KHPAAXRLVYMUHU-UHFFFAOYSA-N 0.000 description 1
- NCBXVQKSCKRNTB-UHFFFAOYSA-N n-[2-(dimethylamino)ethyl]icosanamide Chemical compound CCCCCCCCCCCCCCCCCCCC(=O)NCCN(C)C NCBXVQKSCKRNTB-UHFFFAOYSA-N 0.000 description 1
- XNJXGLWSAVUJRR-UHFFFAOYSA-N n-[2-(dimethylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCN(C)C XNJXGLWSAVUJRR-UHFFFAOYSA-N 0.000 description 1
- OVCKOYOTKXBZKK-UHFFFAOYSA-N n-[3-(diethylamino)propyl]icosanamide Chemical compound CCCCCCCCCCCCCCCCCCCC(=O)NCCCN(CC)CC OVCKOYOTKXBZKK-UHFFFAOYSA-N 0.000 description 1
- KUIOQEAUQATWEY-UHFFFAOYSA-N n-[3-(diethylamino)propyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCCN(CC)CC KUIOQEAUQATWEY-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000008194 pharmaceutical composition Substances 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 229940081310 piperonal Drugs 0.000 description 1
- 229940081510 piroctone olamine Drugs 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 150000003141 primary amines Chemical group 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000005588 protonation Effects 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 229940032044 quaternium-18 Drugs 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- NPCOQXAVBJJZBQ-UHFFFAOYSA-N reduced coenzyme Q9 Natural products COC1=C(O)C(C)=C(CC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)C)C(O)=C1OC NPCOQXAVBJJZBQ-UHFFFAOYSA-N 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 150000003335 secondary amines Chemical group 0.000 description 1
- VIDTVPHHDGRGAF-UHFFFAOYSA-N selenium sulfide Chemical compound [Se]=S VIDTVPHHDGRGAF-UHFFFAOYSA-N 0.000 description 1
- 229960005265 selenium sulfide Drugs 0.000 description 1
- 230000035910 sensory benefits Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229940070720 stearalkonium Drugs 0.000 description 1
- 229940057981 stearalkonium chloride Drugs 0.000 description 1
- 125000005502 stearalkonium group Chemical group 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- 229960003080 taurine Drugs 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
- 150000003512 tertiary amines Chemical group 0.000 description 1
- YMBCJWGVCUEGHA-UHFFFAOYSA-M tetraethylammonium chloride Chemical compound [Cl-].CC[N+](CC)(CC)CC YMBCJWGVCUEGHA-UHFFFAOYSA-M 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229940042585 tocopherol acetate Drugs 0.000 description 1
- 230000000699 topical effect Effects 0.000 description 1
- AQZSPJRLCJSOED-UHFFFAOYSA-M trimethyl(octyl)azanium;chloride Chemical compound [Cl-].CCCCCCCC[N+](C)(C)C AQZSPJRLCJSOED-UHFFFAOYSA-M 0.000 description 1
- 229940035936 ubiquinone Drugs 0.000 description 1
- 125000004417 unsaturated alkyl group Chemical group 0.000 description 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 1
- 235000012141 vanillin Nutrition 0.000 description 1
- 229940117960 vanillin Drugs 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- ZFNVDHOSLNRHNN-UHFFFAOYSA-N xi-3-(4-Isopropylphenyl)-2-methylpropanal Chemical compound O=CC(C)CC1=CC=C(C(C)C)C=C1 ZFNVDHOSLNRHNN-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
- A61K2800/524—Preservatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/56—Compounds, absorbed onto or entrapped into a solid carrier, e.g. encapsulated perfumes, inclusion compounds, sustained release forms
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
一种引起改善的颗粒有益剂在毛发上的沉积的组合物,其包含:(i)0.01至10重量%的直链阳离子调理表面活性剂;(ii)0.1至10重量%的直链脂肪材料;(iii)颗粒有益剂,选自调理活性物质、头皮活性物质、包封的香味剂、乳化的香味剂及其混合物;(iv)按100%的活性物质计,0.01至5重量%的支链阳离子辅助表面活性剂,其选自结构1、结构2、结构3及其混合物其中:R1、R2、R5和R6包括具有C4‑C20,优选C6‑C18的碳‑碳链长度的饱和或不饱和的直链烷基链;R3和R4包括具有C6‑C22,优选C6‑C12的碳‑碳链长度的饱和或不饱和的直链或支链烷基链;n和m具有范围0‑10,优选选自0和1;p具有范围1‑6,优选选自1和2;R7包括具有C1‑C4,优选C1‑C2的碳‑碳链长度的烷基链;R8包括质子或具有C1‑C4,优选C1‑C2的碳‑碳链长度的烷基链;和X为有机或无机阴离子;其中支链阳离子辅助表面活性剂(iv)与直链阳离子表面活性剂(i)的摩尔比在1:20至1:1的范围内。
Description
技术领域
本发明涉及用于处理毛发的包含支链辅助表面活性剂的调理组合物,其包含待在使用期间沉积到毛发上的有益剂,例如硅酮,且特别是涉及能够使增加量的有益剂沉积的调理组合物。
背景技术
在个人护理组合物如毛发处理组合物中,有益剂的沉积和递送通常是产品性能的关键驱动因素。例如,目前市场上的许多毛发调理剂产品通过在洗涤和护理过程期间将有益剂(例如香味剂材料、硅酮和损坏修复活性物质)沉积到毛发上而起到向毛发递送益处的作用。
然而,用户报告对使用一些组合物所带来的益处水平感到失望。这通常是由于递送到表面的有益剂的量不足引起的。因此,期望的是开发提供有益物质向表面例如毛发的改善递送的组合物。
已知各种类型的支链的阳离子化合物在毛发处理组合物中具有多种益处。
WO 17/172117公开了一种用于处理角质基质的组合物,其包含含有定义的第一季铵化合物和咪唑啉化合物的阳离子试剂、改性淀粉、两种硅烷化合物、阳离子乙烯基吡咯烷酮聚合物和水。据称用该组合物处理的头发具有改善的发量、发体、丰盈感、易于漂洗、快速干燥、保持清洁更长时间和被充分调理。US 2005/175569公开了例如用于调理和定型毛发的化妆品组合物,其包含阳离子表面活性剂,该阳离子表面活性剂可以是季铵盐。
JP 2005-060271公开了一种水性毛发化妆品组合物,其可以包含(A)由通式(1)表示的二甲基聚硅氧烷,(B)由通式(2)表示的二甲基聚硅氧烷,(C)由通式(3)表示的环状二甲基聚硅氧烷,[(B)+(C)]/(A)的比例大于或等于1;和(D)另外的季铵组分。据说该组合物在润湿、漂洗和干燥阶段对毛发提供大量的调理益处。
我们自己的公布申请WO 02/102334和WO 01/43718提供具有清洁和调理性质的水性毛发处理组合物,其包含具有限定的烃基链的季铵基阳离子表面活性剂。
在家庭和个人护理产品中,甘氨酸甜菜碱衍生物是已知的。这些衍生物已经用于毛发应用中以向毛发递送调理益处。
US 2017/087074(Centre National De La Recherche Scientifique)公开了用于化妆品和药物组合物的表面活性剂组合物。该组合物包含与甘氨酸甜菜碱组合的用甘氨酸甜菜碱接枝的烷基聚葡萄糖苷,并且是稳定的。类似的组合物公开在US2017/087077中。
US 2014/246041(Henkel)公开了用于调理毛发的组合物,其含有具有可覆盖甘氨酸甜菜碱衍生物的结构的限定的酯季铵盐,和至少一种选自L-肉碱和/或其盐、和/或牛磺酸和/或其盐、和/或维生素和维生素前体、和/或烟酰胺、和/或泛醌、和/或依克多因(ectoin)的护理提供物质(care-providing substance)。WO13/083349公开了用于调理角蛋白纤维的类似的酯季铵盐。
EP 1016650(Kao)公开了制备甜菜碱烷基酯的方法,所述甜菜碱烷基酯可用于毛发化妆品中以赋予毛发以感觉益处。在制剂实施例中使用鲸蜡醇(来自Kao Corporation)。
US5374421公开了一种用于头发处理的组合物,其含有(a)0.1-10重量%的在分子中具有至少一个烷氧基且熔点不低于30℃的改性硅酮聚合物,(b)0.1-20重量%的阳离子表面活性试剂,(c)0.1-30重量%的油性或脂肪物质,(d)0.1-90重量%的与水相容且其分子具有至少一个羟基的有机液体,和(e)水。鲸蜡硬脂基三甲基氯化铵(Cetostearyltrimethyl ammonium chloride)是阳离子调理材料的示例,并且肉豆蔻基氧基改性的硅酮是颗粒有益剂的示例。
虽然支链的材料在家庭和个人护理产品中是已知的,但是它们尚未被有效地应用以提供有益剂在毛发上的改善的沉积。
产品流变学对于用户是关键属性。然而,我们已经发现,将支链表面活性剂材料加入凝胶网络中破坏了凝胶双层,因此将粘度和屈服应力降低到不可接受的低水平。
尽管有现有技术,但是仍然需要向毛发给予改善的有益剂递送,而不损害用户期望的粘度特性。
我们现在令人惊奇地发现,包含某些支链辅助表面活性剂与限定的直链阳离子表面活性剂的组合的组合物提供了有益剂(例如硅酮,包封的香味剂)沉积的预料不到的极大增强,同时保持优异的产品流变学。
除非另有说明,否则本文中述及的所有百分比都是基于总重量按重量计。
发明内容
因此,提供一种组合物,其包含:
(i)0.01至10重量%的直链阳离子调理表面活性剂;
(ii)0.1至10重量%的直链脂肪材料;
(iii)颗粒有益剂,选自调理活性物质、头皮活性物质、包封的香味剂、乳化的香味剂及其混合物;
(iv)按100%的活性物质计,0.01至5重量%的支链阳离子辅助表面活性剂,其选自结构1、结构2、结构3及其混合物
其中:
·R1、R2、R5和R6包括具有C4-C20,优选C6-C18的碳-碳链长度的饱和或不饱和的直链烷基链;
·R3和R4包括具有C6-C22,优选C6-C12的碳-碳链长度的饱和或不饱和的直链或支链烷基链;
·n和m具有范围0-10,优选选自0和1;
·p具有范围1-6,优选选自1和2;
·R7包括具有C1-C18,优选C1-C4,最优选C1-C2的碳-碳链长度的烷基链;
·R8包括质子或具有C1-C18,优选C1-C4,最优选C1-C2的碳-碳链长度的烷基链;和
·X为有机或无机阴离子;
其中支链阳离子辅助表面活性剂(iv)与直链阳离子表面活性剂(i)的摩尔比在1:20至1:1,优选1:10至1:1,最优选1:5至1:2的范围内。在第二方面,本发明提供了增加颗粒有益剂到毛发上的沉积的方法,其包括将第一方面的组合物施用到毛发上的步骤,所述颗粒有益剂选自调理活性物质、头皮活性物质、包封的香味剂、乳化的香味剂及其混合物。
本发明的方法优选包括从毛发上漂洗所述组合物的额外步骤。
优选地,所述方法是增加到毛发的硅酮沉积的方法,其包括将如本发明第一方面所定义的组合物施用到毛发上并用水漂洗毛发的步骤。
根据本发明的组合物优选配制成用于处理毛发(通常在洗发之后)和随后漂洗的调理剂。
具体实施方式
优选地,处理组合物选自洗去型毛发调理剂、发膜、免洗型调理剂组合物和预处理组合物,更优选选自洗去型毛发调理剂、发膜、免洗型调理剂组合物和预处理组合物,例如油处理,且最优选选自洗去型毛发调理剂、发膜和免洗型调理剂组合物。处理组合物优选选自洗去型毛发调理剂和免洗型调理剂。
用于本发明的洗去型调理剂是通常在洗去之前留在湿发上1-2分钟的调理剂。
用于本发明的发膜是在洗去之前通常留在毛发上3至10分钟,优选3至5分钟,更优选4至5分钟的处理。
用于本发明的免洗型调理剂通常施用于毛发上并留在毛发上超过10分钟,并且优选在洗涤之后施用于毛发上,且不冲洗掉直到下一次洗涤。
直链阳离子调理表面活性剂
调理剂组合物将包含化妆品可接受的且适于局部施用于毛发的直链阳离子调理表面活性剂。
优选地,直链阳离子调理表面活性剂具有式1:N+(R1)(R2)(R3)(R4),其中R1、R2、R3和R4独立地为(C1至C30)烷基或苄基。
在式1中,优选地,R1、R2、R3和R4中的一个、两个或三个独立地为(C4-C30)烷基,而其它R1、R2、R3和R4的一个或多个基团为(C1-C6)烷基或苄基。
更优选地,R1、R2、R3和R4中的一个或两个独立地为(C6-C30)烷基,而其它R1、R2、R3和R4基团为(C1-C6)烷基或苄基。任选地,该烷基可以在烷基链内包含一个或多个酯(-OCO-或-COO-)、酰氨(-NOC-或NCO-)和/或醚(-O-)键。烷基可以任选地用一个或多个羟基取代。烷基可以是直链或支链的,并且对于具有3个或更多个碳原子的烷基,可以是环状的。烷基可以是饱和的或可以含有一个或多个碳-碳双键(例如,油基)。烷基任选地在烷基链上用一个或多个乙烯基氧基来乙氧基化。
用于根据本发明的调理剂组合物的合适的季铵盐是包含12-24个碳原子,优选16-22个碳原子的季铵盐。
用于根据本发明的调理剂组合物中的合适的季胺盐包括鲸蜡基三甲基氯化铵、山嵛基三甲基氯化铵、山嵛基三甲基甲基硫酸铵(Behentrimonium methosulphate)、山嵛基氨丙基二甲基胺、鲸蜡基三甲基氯化铵、鲸蜡基氯化吡啶、四甲基氯化铵、四乙基氯化铵、辛基三甲基氯化铵、十二烷基三甲基氯化铵、十六烷基三甲基氯化铵、辛基二甲基苄基氯化铵、癸基二甲基苄基氯化铵、硬脂基二甲基苄基氯化铵、司拉氯铵(StearalkoniumChloride)、硬脂基苄基二甲基甲基硫酸铵(Stearalkonium methosulphate)、双十二烷基二甲基氯化铵、双十八烷基二甲基氯化铵、牛脂基三甲基氯化铵、二氢化牛脂基二甲基氯化铵(例如,Arquad 2HT/75,来自Akzo Nobel)和椰油三甲基氯化铵。
优选的季胺盐选自山嵛基三甲基氯化铵、山嵛基三甲基甲基硫酸铵、鲸蜡基三甲基氯化铵及其混合物。
用于根据本发明的调理剂中的特别有用的阳离子表面活性剂是鲸蜡基三甲基氯化铵,例如可作为GENAMIN CTAC商购自Hoechst Celanese。用于根据本发明的调理剂中的另一种特别优选的阳离子表面活性剂是山嵛基三甲基氯化铵,例如可作为GENAMIN KDMP商购自Clariant。
其它合适的阳离子表面活性剂包括那些具有CTFA命名Quaternium-5、Quaternium-31和Quaternium-18的材料。任何前述材料的混合物也可以是合适的。
单独或与一种或多种其它阳离子表面活性剂一起用于本发明的一类合适的阳离子表面活性剂的另一个实例是下列(i)和(ii)的组合:
(i)对应于通式(II)的酰胺基胺:
R1CONH(CH2)mN(R2)R3(II)
其中R1为具有10个或更多个碳原子的烃基链,R2和R3独立地选自1-10个碳原子的烃基链,和m为1至约10的整数;和
(ii)酸。
如在本文中所使用的术语烃基链指烷基或烯基链。
优选的酰胺基胺化合物是对应于式(I)的那些,其中
R1为具有约11至约24个碳原子的烃基残基,
R2和R3各自独立地为具有1至约4个碳原子的烃基残基,优选烷基,和m为1至约4的整数。
优选地,R2和R3为甲基或乙基。
优选地,m为2或3,即亚乙基或亚丙基。
本文有用的优选的酰胺基胺包括硬脂酰胺丙基二甲基胺,硬脂酰胺丙基二乙基胺,硬脂酰胺乙基二乙基胺,硬脂酰胺乙基二甲基胺,棕榈酰胺丙基二甲基胺,棕榈酰胺丙基二乙基胺,棕榈酰胺乙基二乙基胺,棕榈酰胺乙基二甲基胺,山嵛酰胺丙基二甲基胺,山嵛酰胺丙基二乙基胺,山嵛酰胺乙基二乙基胺,山嵛酰胺乙基二甲基胺,花生酰胺丙基二甲基胺,花生酰胺丙基二乙基胺,花生酰胺乙基二乙基胺,花生酰胺乙基二甲基胺,及其混合物。
本文有用的特别优选的酰胺基胺是硬脂酰胺丙基二甲基胺,硬脂酰胺乙基二乙基胺及其混合物。
本文有用的可商购酰胺基胺包括:
可获自Inolex(Philadelphia Pennsylvania,USA)的商品名为LEXAMINE S-13和可获自Nikko(Tokyo,Japan)的商品名为AMIDOAMINE MSP的硬脂酰胺丙基二甲基胺;可获自Nikko的商品名为AMIDOAMINE S的硬脂酰胺乙基二乙基胺;可获自Croda(NorthHumberside,England)的商品名为INCROMINE BB的山嵛酰胺丙基二甲基胺;和可获自Scher(Clifton New Jersey,USA)的商品名SCHERCODINE系列的各种酰胺基胺。
酸可以是能够使调理剂组合物中的酰胺基胺质子化的任何有机或无机酸。本文有用的合适的酸包括盐酸,乙酸,酒石酸,富马酸,乳酸,苹果酸,琥珀酸及其混合物。优选地,酸选自乙酸,酒石酸,盐酸,富马酸,乳酸及其混合物。酸的主要作用是使毛发处理组合物中的酰胺基胺质子化,从而在毛发处理组合物中原位形成叔胺盐(TAS)。TAS实际上是非永久性的季铵或假季铵阳离子表面活性剂。
合适地,酸以足以使存在的超过95摩尔%(293K)的酰胺基胺质子化的量被包含。
在用于本发明的调理剂中,基于组合物的总重量,直链阳离子调理表面活性剂的含量通常在阳离子调理表面活性剂总重量的0.01至10%,更优选0.05至7.5%,最优选0.1至5%的范围内。
直链脂肪材料
本发明的组合物包含0.1至10重量%的直链脂肪材料。
在调理组合物中组合使用脂肪材料和阳离子表面活性剂据信是特别有利的,因为这导致形成其中分散有阳离子表面活性剂的结构化的层状或液晶相。
“脂肪材料”是指脂肪醇、烷氧基化脂肪醇、脂肪酸或其混合物。优选地,直链脂肪材料选自脂肪醇和脂肪酸,最优选脂肪醇。
优选地,脂肪材料的烷基链是完全饱和的。代表性的脂肪材料包含8至22个碳原子,更优选16至22个碳原子。
合适的脂肪醇包含8至22个碳原子,优选16至22个碳原子,最优选C16至C18。脂肪醇通常是含有直链烷基的化合物。优选地,烷基是饱和的。优选的脂肪醇的实例包括鲸蜡醇、硬脂醇及其混合物。这些材料的使用也是有利的,因为它们对用于本发明的组合物的总体调理性能作出贡献。
在烷基链中具有约12至约18个碳原子的烷氧基化(例如乙氧基化或丙氧基化)的脂肪醇可用于代替脂肪醇本身或与其一起使用。合适的实例包括乙二醇鲸蜡基醚、聚氧乙烯(2)硬脂基醚、聚氧乙烯(4)鲸蜡基醚及其混合物。
在本发明的调理剂中脂肪材料的含量按总组合物的重量计合适地为0.01至10%、优选0.1至10%、更优选0.1至5%。阳离子表面活性剂与脂肪醇的重量比合适地为10:1至1:10,优选4:1至1:8,最佳为1:1至1:7,例如1:3。
颗粒有益剂
本发明的组合物包含颗粒有益剂。颗粒有益剂优选选自调理活性物质、头皮活性物质、包封的香味剂、乳化的香味剂及其混合物。更优选地,颗粒有益剂选自调理活性物质、包封的香味剂及其混合物。最优选地,颗粒有益剂选自硅酮乳液和包封的香味剂。优选的调理活性物质为硅酮乳液。
优选的硅酮乳液不包括疏水改性,优选地所述硅酮乳液不是肉豆蔻氧基改性的硅酮,最优选地不是肉豆蔻氧基改性的硅酮或鲸蜡氧基改性的硅酮。最优选地,用于本发明的组合物中的硅酮乳液选自聚二甲基硅氧烷、聚二甲基硅氧烷醇、氨端聚二甲基硅氧烷及其混合物的乳液。
颗粒有益剂可以是头皮活性物质,其不溶于本发明的组合物,或者为乳液形式。优选的头皮活性物质选自金属吡啶硫酮、唑类、羟甲辛吡酮(octopirox)(吡罗克酮乙醇胺)、硫化硒、水杨酸以及它们的组合,优选金属吡啶硫酮、唑类和羟甲辛吡酮。唑类抗真菌剂包括酮康唑和氯咪巴唑,优选氯咪巴唑。颗粒有益剂可以是乳化的香味剂或包封的香味剂。为了清楚起见,“香味剂”在本文中也可称为“香料”。以下是可合适地乳化或包封用于本发明的组合物的香料材料。
用于本发明的香料材料的实例包括香叶醇、乙酸香叶酯、里哪醇、乙酸里哪酯、四氢里哪醇、香茅醇、乙酸香茅酯、二氢月桂烯醇、乙酸二氢月桂烯酯、四氢月桂烯醇、萜品醇、乙酸萜品酯、乙酸诺卜酯、2-苯基乙醇、乙酸2-苯基乙酯、苄醇、乙酸苄酯、水杨酸苄酯、乙酸苏合香酯、苯甲酸苄酯、水杨酸戊酯、二甲基苄基-甲醇、乙酸三氯甲基苯基-甲酯、乙酸对叔丁基环己酯、乙酸异壬酯、乙酸岩兰草酯、岩兰草醇、α-己基肉桂醛、2-甲基-3-(对-叔丁基苯基)丙醛、2-甲基-3-(对-异丙基苯基)丙醛、2-(对-叔丁基苯基)丙醛、2,4-二甲基-环己-3-烯基-甲醛(carboxaldehyde)、乙酸三环癸烯酯、丙酸三环癸烯酯、4-(4-羟基-4-甲基戊基)-3-环己烯甲醛、4-(4-甲基-3-戊烯基)-3-环己烯甲醛、4-乙酰氧基-3-戊基-四氢吡喃、3-羧甲基-2-戊基环戊烷、2-正庚基环戊酮、3-甲基-2-戊基-2-环戊烯酮、正癸醛、正十二醛、9-癸烯醇-1、异丁酸苯氧基乙酯、苯基乙醛二甲基缩醛、苯基乙醛二乙基缩醛、香叶基腈、香茅腈、乙酸柏木酯、3-异龙脑基环己醇、柏木基甲基醚、异长叶烷酮(isolongifolanone)、茴香腈、茴香醛、胡椒醛、香豆素、丁香酚、香草醛、二苯醚(diphenyloxide)、羟基香茅醛、紫罗兰酮、甲基紫罗兰酮、异甲基紫罗兰酮、鸢尾酮、顺式-3-己烯醇及其酯、茚满麝香(indan musks)、萘满麝香(tetralin musks)、异色满麝香(isochromanmusks)、大环酮、大内酯麝香(macrolactone musks)、巴西酸乙二醇酯及其混合物。
包封的香味剂优选包含形成微胶囊的聚合物壳(胶囊壁)。微胶囊的聚合物壳可以使用界面聚合制备。
界面聚合是从存在于油相中的至少一种油溶性壁形成材料与存在于水相中的至少一种水溶性壁形成材料的反应产生包封壳。两种壁形成材料之间的聚合反应发生,导致在油相和水相的界面处形成共价键以形成胶囊壁。
优选地,微胶囊的聚合物壳是通过多异氰酸酯与选自聚胺、聚亚胺或其混合物的材料的反应形成的聚脲的氨基塑料树脂。
优选地,微胶囊通过剪切活化;即,它们通过剪切破裂以释放内容物。
一种特别优选的微胶囊具有聚脲壳,如US2013/0330292A1和US2012/0148644A1中所述制备和可从International Flavors&Fragrances Inc获得的。
有利地,聚合物壳占微胶囊的重量的至多20重量%。
通过改变工艺条件,可以以已知方式产生具有期望尺寸的微胶囊。微胶囊通常具有在1至500微米,优选1至300微米,更优选1至50微米,最优选1至10微米范围内的平均直径。如有必要,可以将最初产生的微胶囊过滤或筛选以产生具有更大尺寸均匀性的产品。在根据本发明的典型组合物中,基于组合物的总重量,微胶囊的水平通常在0.2至2重量%,优选0.5至1.5重量%的范围内。
硅酮
本发明的组合物可以含有硅酮调理剂的乳化液滴,所述硅酮调理剂优选为非疏水性改性的。合适的硅酮包括聚二甲基硅氧烷,其具有CTFA名称二甲基硅油。同样适用于本发明的组合物的是具有羟基端基的聚二甲基硅氧烷,其具有CTFA名称聚二甲基硅氧烷醇。优选地,硅酮选自聚二甲基硅氧烷、聚二甲基硅氧烷醇、氨端聚二甲基硅氧烷及其混合物。还优选的是氨基官能化的硅酮与聚二甲基硅氧烷的共混物。
乳化硅酮本身(不是乳液或最终毛发调理组合物)的粘度在25℃下通常为至少10,000cSt,硅酮本身的粘度优选为至少60,000cSt,最优选为至少500,000cSt,理想地至少1,000,000cSt。优选地,为了易于配制,粘度不超过109cSt。
用于本发明的组合物的乳化硅酮通常在组合物中具有小于30微米,优选小于20微米,更优选小于10微米,理想地0.01-1微米的D90硅酮液滴尺寸。具有0.15微米的平均硅酮液滴尺寸(D50)的硅酮乳液通常称为微乳液。硅酮颗粒尺寸可通过激光散射技术的方式测量,例如使用来自Malvern Instruments的2600D粒度分析仪(Particle Sizer)。
合适的预形成乳液的实例包括Xiameter MEM 1785和微乳液DC2-1865,其可获自Dow Corning。这些是聚二甲基硅氧烷醇的乳液/微乳液。交联硅酮胶也可以以预乳化形式获得,这有利于配制方便性。
用于包含在本发明的组合物中的另一类优选的硅酮是氨基官能硅酮。“氨基官能硅酮”是指含有至少一个伯、仲或叔胺基团或季铵基团的硅酮。合适的氨基官能硅酮的实例包括:具有CTFA名称“氨端聚二甲基硅氧烷”的聚硅氧烷。优选的氨端聚二甲基硅氧烷是可商购自Dow Corning的DC 7134。
适用于本发明的氨基官能硅酮的具体实例是氨基硅油DC2-8220、DC2-8166和DC2-8566(均来自Dow Corning)。
合适的季硅酮聚合物(quaternary silicone polymer)描述在EP-A-0530974中。优选的季硅酮聚合物是K3474,来自Goldschmidt。
氨基官能硅油与非离子和/或阳离子表面活性剂的乳液也是合适的。
氨基官能硅酮的预形成乳液也可以从硅油供应商如Dow Corning和GeneralElectric获得。具体实例包括DC939阳离子乳液和非离子乳液DC2-7224、DC2-8467、DC2-8177和DC2-8154(均来自Dow Corning)。
硅酮的总量优选为总组合物的0.1重量%至10重量%,更优选0.1重量%至5重量%,最优选0.25重量%至3重量%,这是合适的水平。
支链阳离子辅助表面活性剂
本发明的组合物包含支链阳离子辅助表面活性剂。
支链阳离子辅助表面活性剂选自结构1、结构2、结构3及其混合物。
其中:
·R1、R2、R5和R6包括具有C4-C20,优选C6-C18的碳-碳链长度的饱和或不饱和的直链烷基链;任选地,R1、R2、R5和R6中至少一个包括选自酯基、和酰胺基、及醚基的基团;
·R3和R4包括具有C6-C22,优选C6-C12的碳-碳链长度的饱和或不饱和的直链或支链烷基链;任选地,R3和R4的至少一个包括酯基或酰胺基;
·n和m具有范围0-10,优选选自0和1;
·p具有范围1-6;
·R7包括具有C1-C4,优选C1-C2的碳-碳链长度的烷基链;
·R8包括质子或具有C1-C4,优选C1-C2的碳-碳链长度的烷基链;和
·X为有机或无机阴离子;
支链阳离子辅助表面活性剂(iv)与直链阳离子表面活性剂(i)的摩尔比在1:20至1:1,优选1:10至1:1,最优选1:5至1:2的范围内。
变量p具有范围1-6,优选选自1和2,最优选1。
在结构1-3中,胺头基(amine head group)在最终制剂内是带电的。但是,原材料包括其中电荷不是永久性的种类,并且可以通过使用强酸在制剂中质子化来诱导。因此,当R8在上述通式中是质子时,该质子可以存在于原材料中或在配制期间变成缔合的。
任选地,R1、R2、R3、R4、R5和R6中的至少一个在烷基链内包含选自酯基(-OCO-或-COO-)、酰胺基(-NOC-或NCO-)和醚基(-O-)的键。
支链辅助表面活性剂的存在量为0.01至5重量%,优选0.1至1重量%,最优选0.2至0.7重量%(按100%活性物质计,且基于总组合物的重量)。
X是有机或无机阴离子。优选地,X包括选自以下的阴离子:卤离子,通式RSO3 -的硫酸根(其中R是具有1-4个碳原子的饱和或不饱和的烷基),和有机酸的阴离子基团。
优选的卤离子选自氟离子、氯离子、溴离子和碘离子。优选的有机酸的阴离子基团选自马来酸根、富马酸根、草酸根、酒石酸根、柠檬酸根、乳酸根和乙酸根。优选的硫酸根是甲磺酸根和乙磺酸根。
最优选地,X-包括选自卤离子、甲磺酸根基团和乙磺酸根基团的阴离子。
在一个优选的实施方式中,
·R1、R2、R5和R6包括具有C6-C18的碳-碳链长度的饱和或不饱和的直链烷基链;
·R3和R4包括具有C6-C12的碳-碳链长度的饱和或不饱和的直链或支链烷基链;
·n和m选自0和1;
·p为1;
·R7包括具有C1-C2碳-碳链长度的烷基链;
·R8包括质子或具有C1-C2的碳-碳链长度的烷基链;和
·X选自卤离子、甲磺酸根和乙磺酸根。
针对结构1的合适材料的一个实例是N,N,N-三甲基-2-辛基十二烷-1-铵甲磺酸盐。
针对结构2的合适材料的一个实例是2-(二辛基氨基)-N,N,N-三甲基-2-氧代乙烷-1-铵甲磺酸盐。
符合结构3的合适材料的实例是2-((2-丁基辛基)氧基)-N,N,N-三甲基-2-氧代乙烷-1-铵甲磺酸盐、2-((2-己基癸基)氧基)-N,N,N-三甲基-2-氧代乙烷-1-铵甲磺酸盐、N,N,N-三甲基-2-((2-辛基十二烷基)氧基)-2-氧代乙烷-1-铵甲磺酸盐、2-((2-癸基十四烷基)氧基)-N,N,N-三甲基-2-氧代乙烷-1-铵甲磺酸盐、2-((2-十二烷基十六烷基)氧基)-N,N,N-三甲基-2-氧代乙烷-1-铵甲磺酸盐和N,N,N-三甲基-2-氧代-2-((2-十四烷基十八烷基)氧基)乙烷-1-铵甲磺酸盐。
组合物流变学
本发明的组合物提供良好的粘度和屈服应力性能。
组合物在25℃和1Hz下具有30-200帕(Pa),最优选40-150Pa峰值的优选屈服应力范围。测量屈服应力的方法使用连接到合适流变仪上的锯齿状平行板几何体,直径40mm,所述流变仪能够施加恒定频率1Hz的振荡,并且振幅扫描在0.1%至2000%的范围内。振幅扫描范围以不超过每十个应变范围十个点来施用,所述应变范围以每振幅不超过4个循环来覆盖。该仪器应当在受控应变下操作,例如使用来自TA Instruments的ARES G2流变仪。该几何体的温度应当通过例如Peltier控制板或再循环浴的方式设定在25℃。通过绘制弹性应力相对于应变幅度的曲线来确定屈服应力,并且在曲线的峰值处,将最大值表述为屈服应力。弹性应力是作为容易从仪器得到的(储能模量)×(应变振幅)的乘积而算出的。
如在30℃下,在Brookfield RVT上使用锭子A或B在0.5rpm下在Helipath支架上测量60秒,组合物具有5,000-750,000厘泊,优选50,000-600,000厘泊,更优选50,000-450,000厘泊的粘度。
优选的调理剂包括调理凝胶相。这些调理剂具有很少或没有囊泡内容物。这样的调理剂和用于制备它们的方法描述在WO2014/016354、WO2014/016353、WO2012/016352和WO2014/016351中。
以组合物的总重量计,这种调理凝胶相包含
i)0.4-8重量%的具有8-22个碳的脂肪醇,
ii)0.1-2重量%的阳离子表面活性剂,
并且该组合物赋予用该组合物处理的毛发以1-250g,优选2-100g,更优选2-50g,甚至更优选5-40g和最优选5-25g的拉动质量(Draw Mass)。
拉动质量是牵拉发束通过梳子或刷子所需的质量。因此,毛发越缠结,拉动发束通过梳子或刷子所需的质量越大,并且毛发的调理水平越高,拉动质量越低。
拉动质量是牵拉发束(例如重量为1至20g,长度为10至30cm,宽度为0.5至5cm)通过梳子或刷子所需的质量,如通过以下测量的:首先将发束置于梳子或刷子上,使得5至20cm的毛发在发束的胶粘末端(glued end)悬垂,然后向悬垂末端增加重量,直到发束经过梳子或刷子下落。
优选地,发束的重量为1-20g,更优选为2-15g,最优选为5-10g。优选地,发束的长度为10-40cm,更优选10-30cm,并且宽度为0.5-5cm,更优选1.5-4cm。
最优选地,拉动质量是牵拉发束(例如重量为10g,长度为20cm,宽度为3cm)通过梳子或刷子所需的质量,如通过以下测量的:首先将发束置于梳子或刷子上,使得20cm的毛发在发束的胶粘末端悬垂,然后向悬垂末端增加重量,直到发束经过梳子或刷子下落。
另外的成分
根据本发明的组合物可以包含对于毛发调理组合物常见的众多成分中的任一种。
另外的成分可包括防腐剂、着色剂、多元醇如甘油和聚丙二醇、螯合剂如EDTA、抗氧化剂如维生素E乙酸酯、香味剂、抗微生物剂和防晒剂。这些成分中的每一种将以有效实现其目的的量存在。通常,这些任选的成分单独地按总组合物的重量计以至多约5%的含量包括。
优选地,所述另外的成分包括香料、防腐剂、着色剂和调理硅酮。
本发明的组合物优选地不含粘度调节剂和增稠剂,例如增稠聚合物。
也可以使用任何上述活性成分的混合物。
通常,这些成分单独地按总组合物的重量计以至多2%,优选至多1%的含量包含。
本发明的实施方式在以下实施例中给出,其中除非另有说明,否则所有的百分比都是基于总重量按重量计。
实施例
实施例1:根据本发明的组合物1-4和比较组合物A
制备以下组合物:
表1:实施例A的组合物(比较)和实施例1-3的组合物(根据本发明)。
使用以下方法制备实施例A和1-3中的调理剂:
1.将表面活性剂和脂肪材料(包括支链材料)加入到合适的容器中,并加热到80℃。
2.在45-70℃之间的温度下,根据所公开的组成,将熔融共混物加入到适量的水中。
3.混合混合物直至不透明且粘稠。
4.然后停止加热,冷却至40℃以下,其余的水与剩余的材料一起加入。
5.最后,在Silverson混合器上以5000rpm高剪切混合该制剂5分钟。
实施例2:用组合物A和1-3处理毛发
使用的毛发是深褐色的欧洲人毛发,发束为5g重、6英寸长。
首先,使用以下方法用清洁洗发剂处理毛发:-
将毛发纤维在流水下保持30秒,以每1g毛发0.1ml洗发剂的剂量施用洗发剂并揉入到毛发中30秒。通过在流水下保持30秒除去过量的泡沫,并重复洗发剂阶段。将毛发在流水下漂洗1分钟。
然后,使用以下方法用组合物处理湿毛发:-
以每1g毛发0.2ml调理剂的剂量将调理剂施用于湿毛发,并按揉到毛发中1分钟。将毛发在流水下漂洗1分钟,并除去过量的水。
实施例3:在用组合物A和1-3处理的毛发上的硅酮沉积和屈服应力
表2:在用实施例A(比较)和实施例1-4(根据本发明)处理的毛发上的屈服应力和沉积的硅酮的量
实施例A | 实施例1 | 实施例2 | 实施例3 | |
成分 | 比较 | 结构1 | 结构2 | 结构3 |
硅酮沉积[ppm] | 431 | 1,565 | 1,185 | 1,354 |
硅酮沉积ST DEV[ppm] | 63 | 344 | 332 | 309 |
屈服应力[Pa](-+10Pa) | 182 | 87 | 55 | 167 |
Claims (12)
1.一种组合物,其包含:
(i)0.01至10重量%的直链阳离子调理表面活性剂,其中所述直链阳离子调理表面活性剂选自山嵛基三甲基氯化铵、山嵛基三甲基甲基硫酸铵、十六烷基三甲基氯化铵及其混合物;
(ii)0.1至10重量%的直链脂肪材料;
(iii)颗粒有益剂,选自调理活性物质,所述调理活性物质是硅酮乳液,其中所述硅酮乳液选自聚二甲基硅氧烷、聚二甲基硅氧烷醇、氨端聚二甲基硅氧烷及其混合物的乳液,其中所述硅酮以总组合物的0.1重量%至10重量%的量存在;
(iv)按100%的活性物质计,0.01至5重量%的支链阳离子辅助表面活性剂,其选自结构1、结构2、结构3及其混合物;其中,结构1是N,N,N-三甲基-2-辛基十二烷-1-铵甲磺酸盐;结构2是2-(二辛基氨基)-N,N,N-三甲基-2-氧代乙烷-1-铵甲磺酸盐;并且结构3选自2-((2-丁基辛基)氧基)-N,N,N-三甲基-2-氧代乙烷-1-铵甲磺酸盐、2-((2-己基癸基)氧基)-N,N,N-三甲基-2-氧代乙烷-1-铵甲磺酸盐、N,N,N-三甲基-2-((2-辛基十二烷基)氧基)-2-氧代乙烷-1-铵甲磺酸盐、2-((2-癸基十四烷基)氧基)-N,N,N-三甲基-2-氧代乙烷-1-铵甲磺酸盐、2-((2-十二烷基十六烷基)氧基)-N,N,N-三甲基-2-氧代乙烷-1-铵甲磺酸盐、N,N,N-三甲基-2-氧代-2-((2-十四烷基十八烷基)氧基)乙烷-1-铵甲磺酸盐及其混合物;
其中支链阳离子辅助表面活性剂(iv)与直链阳离子调理表面活性剂(i)的摩尔比在1:5至1:2的范围内。
2.如权利要求1所述的组合物,其中所述支链阳离子辅助表面活性剂选自N,N,N-三甲基-2-辛基十二烷-1-铵氯化物、2-(二辛基氨基)-N,N,N-三甲基-2-氧代乙烷-1-铵甲磺酸盐、N,N,N-三甲基-2-((2-辛基十二烷基)氧基)-2-氧代乙烷-1-铵甲烷磺酸盐及其混合物。
3.如权利要求1或2所述的组合物,其中所述直链阳离子调理表面活性剂是山嵛基三甲基氯化铵。
4.如权利要求1或2所述的组合物,其中所述硅酮乳液是聚二甲基硅氧烷醇的乳液。
5.如权利要求1或2所述的组合物,其中所述硅酮以总组合物的0.1重量%至5重量%的量存在。
6.如权利要求5所述的组合物,其中所述硅酮以总组合物的0.25重量%至3重量的量存在。
7.如权利要求1或2所述的组合物,其中所述支链阳离子辅助表面活性剂以0.1重量%至2重量%的量存在。
8.如权利要求7所述的组合物,其中所述支链阳离子辅助表面活性剂以0.1重量%至1.0重量%的量存在。
9.如权利要求8所述的组合物,其中所述支链阳离子辅助表面活性剂以0.2重量%至0.7重量%的量存在。
10.如权利要求1或2所述的组合物,其在25℃和1Hz下具有30至200帕(Pa)峰值的范围内的屈服应力。
11.如权利要求10所述的组合物,其中所述屈服应力在40至150Pa峰值的范围内。
12.一种增加颗粒有益剂到毛发上的沉积的方法,其包括将权利要求1至11中任一项定义的组合物施用到毛发上并用水冲洗所述毛发的步骤,其中所述颗粒有益剂选自调理活性物质。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP18214094 | 2018-12-19 | ||
EP18214094.7 | 2018-12-19 | ||
PCT/EP2019/084382 WO2020126660A1 (en) | 2018-12-19 | 2019-12-10 | Hair conditioning composition for improved deposition |
Publications (2)
Publication Number | Publication Date |
---|---|
CN113194914A CN113194914A (zh) | 2021-07-30 |
CN113194914B true CN113194914B (zh) | 2024-03-26 |
Family
ID=64746196
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201980084635.5A Active CN113194914B (zh) | 2018-12-19 | 2019-12-10 | 用于改善沉积的毛发调理组合物 |
Country Status (10)
Country | Link |
---|---|
US (1) | US20220071876A1 (zh) |
EP (1) | EP3897541A1 (zh) |
JP (1) | JP2022514309A (zh) |
CN (1) | CN113194914B (zh) |
AR (1) | AR117723A1 (zh) |
BR (1) | BR112021008300A2 (zh) |
EA (1) | EA202190901A1 (zh) |
PH (1) | PH12021550983A1 (zh) |
WO (1) | WO2020126660A1 (zh) |
ZA (1) | ZA202103147B (zh) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
MX2023007388A (es) * | 2020-12-21 | 2023-07-05 | Unilever Ip Holdings B V | Composicion acondicionadora para el cabello para deposicion mejorada. |
US20240115473A1 (en) * | 2020-12-21 | 2024-04-11 | Conopco, Inc., D/B/A Unilever | Hair conditioning composition for improved deposition |
EP4262701A1 (en) | 2020-12-21 | 2023-10-25 | Unilever IP Holdings B.V. | Hair conditioning composition for improved deposition |
EP4262696A1 (en) | 2020-12-21 | 2023-10-25 | Unilever IP Holdings B.V. | Hair conditioning composition for improved deposition |
WO2023110400A1 (en) | 2021-12-16 | 2023-06-22 | Unilever Ip Holdings B.V. | Hair conditioning composition for improved deposition |
CN118382419A (zh) | 2021-12-16 | 2024-07-23 | 联合利华知识产权控股有限公司 | 用于改善沉积的毛发调理组合物 |
WO2023110686A1 (en) | 2021-12-16 | 2023-06-22 | Unilever Ip Holdings B.V. | Hair conditioning composition for improved deposition |
WO2023110402A1 (en) | 2021-12-16 | 2023-06-22 | Unilever Ip Holdings B.V. | Hair conditioning composition for improved deposition |
WO2023211956A1 (en) * | 2022-04-29 | 2023-11-02 | Stepan Company | Glycine betaine-guerbet alcohol esterquat compositions and methods of making them |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1062836A (zh) * | 1990-12-05 | 1992-07-22 | 普罗格特-甘布尔公司 | 具有硅酮和阳离子表面活性剂调理剂的香波组合物 |
US5374421A (en) * | 1990-08-24 | 1994-12-20 | Kao Corporation | Composition for hair treatment |
CA2373863A1 (en) * | 1999-07-02 | 2001-01-11 | Ananthanarayan Venkateswaran | Hair conditioning composition comprising cationic silicone emulsion |
JP3502680B2 (ja) * | 1995-01-19 | 2004-03-02 | 花王株式会社 | 第4級アンモニウム塩の製造方法 |
CN103002864A (zh) * | 2010-07-08 | 2013-03-27 | 荷兰联合利华有限公司 | 头发护理组合物 |
WO2014091111A2 (fr) * | 2012-12-11 | 2014-06-19 | L'oreal | Composition cosmétique comprenant l'association de tensioactifs non ionique et cationique, et procédé de traitement cosmétique |
WO2015013780A1 (en) * | 2013-08-01 | 2015-02-05 | L' Oreal | Composition comprising an aminosilicone, a cationic surfactant and a cationic associative polymer |
CN104507451A (zh) * | 2012-07-27 | 2015-04-08 | 荷兰联合利华有限公司 | 方法 |
CN113164354A (zh) * | 2018-12-19 | 2021-07-23 | 联合利华知识产权控股有限公司 | 用于改善的沉积的毛发调理组合物 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9116871D0 (en) | 1991-08-05 | 1991-09-18 | Unilever Plc | Hair care composition |
JP3897923B2 (ja) | 1998-12-28 | 2007-03-28 | 花王株式会社 | 毛髪化粧料の製造方法 |
GB9929971D0 (en) | 1999-12-17 | 2000-02-09 | Unilever Plc | Hair treatment composition |
EP1269974A1 (en) | 2001-06-18 | 2003-01-02 | Unilever Plc | Hair styling compositions |
JP4099120B2 (ja) | 2003-08-08 | 2008-06-11 | 花王株式会社 | 毛髪化粧料 |
US20050175569A1 (en) | 2004-01-07 | 2005-08-11 | Geraldine Fack | Cosmetic compositions comprising a cation, a drawing polymer and a thickener, and cosmetic treatment processes |
US20120148644A1 (en) | 2009-09-18 | 2012-06-14 | Lewis Michael Popplewell | Encapsulated Active Materials |
US11311467B2 (en) | 2009-09-18 | 2022-04-26 | International Flavors & Fragrances Inc. | Polyurea capsules prepared with a polyisocyanate and cross-linking agent |
WO2012016352A1 (zh) | 2010-08-03 | 2012-02-09 | Shi Jianmin | 一种湿化瓶及带有该湿化瓶的氧气吸入器 |
DE102011086924A1 (de) | 2011-11-23 | 2013-05-23 | Henkel Ag & Co. Kgaa | Haarkonditionierende Mittel |
WO2013083349A1 (de) | 2011-12-08 | 2013-06-13 | Henkel Ag & Co. Kgaa | Haarpflegemittel |
CN104507452A (zh) | 2012-07-27 | 2015-04-08 | 荷兰联合利华有限公司 | 方法 |
US20150209254A1 (en) | 2012-07-27 | 2015-07-30 | Conopco, Inc., D/B/A Unilever | Process |
FR3013589B1 (fr) | 2013-11-28 | 2017-03-31 | Soc D'exploitation De Produits Pour Les Ind Chimiques Seppic | Composition d'alkyl polyglucosides et d'acides gras cationisees |
FR3013588B1 (fr) | 2013-11-28 | 2017-02-10 | Soc D'exploitation De Produits Pour Les Ind Chimiques Seppic | Nouvelle composition emulsionnante a caractere cationique |
US11642303B2 (en) | 2016-03-31 | 2023-05-09 | L'oreal | Hair care compositions comprising cationic compounds, starch, and silane compounds |
-
2019
- 2019-12-10 JP JP2021535071A patent/JP2022514309A/ja active Pending
- 2019-12-10 BR BR112021008300-6A patent/BR112021008300A2/pt unknown
- 2019-12-10 EP EP19813596.4A patent/EP3897541A1/en active Pending
- 2019-12-10 EA EA202190901A patent/EA202190901A1/ru unknown
- 2019-12-10 WO PCT/EP2019/084382 patent/WO2020126660A1/en unknown
- 2019-12-10 CN CN201980084635.5A patent/CN113194914B/zh active Active
- 2019-12-10 US US17/414,470 patent/US20220071876A1/en active Pending
- 2019-12-19 AR ARP190103752A patent/AR117723A1/es unknown
-
2021
- 2021-04-28 PH PH12021550983A patent/PH12021550983A1/en unknown
- 2021-05-10 ZA ZA2021/03147A patent/ZA202103147B/en unknown
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5374421A (en) * | 1990-08-24 | 1994-12-20 | Kao Corporation | Composition for hair treatment |
CN1062836A (zh) * | 1990-12-05 | 1992-07-22 | 普罗格特-甘布尔公司 | 具有硅酮和阳离子表面活性剂调理剂的香波组合物 |
JP3502680B2 (ja) * | 1995-01-19 | 2004-03-02 | 花王株式会社 | 第4級アンモニウム塩の製造方法 |
CA2373863A1 (en) * | 1999-07-02 | 2001-01-11 | Ananthanarayan Venkateswaran | Hair conditioning composition comprising cationic silicone emulsion |
CN103002864A (zh) * | 2010-07-08 | 2013-03-27 | 荷兰联合利华有限公司 | 头发护理组合物 |
CN104507451A (zh) * | 2012-07-27 | 2015-04-08 | 荷兰联合利华有限公司 | 方法 |
WO2014091111A2 (fr) * | 2012-12-11 | 2014-06-19 | L'oreal | Composition cosmétique comprenant l'association de tensioactifs non ionique et cationique, et procédé de traitement cosmétique |
WO2015013780A1 (en) * | 2013-08-01 | 2015-02-05 | L' Oreal | Composition comprising an aminosilicone, a cationic surfactant and a cationic associative polymer |
CN113164354A (zh) * | 2018-12-19 | 2021-07-23 | 联合利华知识产权控股有限公司 | 用于改善的沉积的毛发调理组合物 |
Non-Patent Citations (1)
Title |
---|
香波中硅油在头发上的沉积作用;姜海燕;杨成;;江南大学学报(自然科学版);20090615(第03期);101-106 * |
Also Published As
Publication number | Publication date |
---|---|
CN113194914A (zh) | 2021-07-30 |
BR112021008300A2 (pt) | 2021-08-03 |
JP2022514309A (ja) | 2022-02-10 |
WO2020126660A1 (en) | 2020-06-25 |
EA202190901A1 (ru) | 2021-09-24 |
ZA202103147B (en) | 2023-03-29 |
EP3897541A1 (en) | 2021-10-27 |
PH12021550983A1 (en) | 2021-11-08 |
US20220071876A1 (en) | 2022-03-10 |
AR117723A1 (es) | 2021-08-25 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN113194914B (zh) | 用于改善沉积的毛发调理组合物 | |
CN113164354B (zh) | 用于改善的沉积的毛发调理组合物 | |
CN113194915A (zh) | 用于改善沉积的毛发调理组合物 | |
CN113194917B (zh) | 用于改善的硅酮沉积的毛发调理组合物 | |
CN115666491B (zh) | 用于改善沉积的毛发调理组合物 | |
CN113194918B (zh) | 用于毛发的沉积体系 | |
EP4167921B1 (en) | Hair conditioning composition for improved deposition | |
RU2804712C2 (ru) | Система осаждения для волос | |
EA044409B1 (ru) | Кондиционирующая композиция для волос для улучшенного осаждения | |
EA045079B1 (ru) | Кондиционирующая композиция для волос для улучшенного осаждения | |
CN115942928A (zh) | 用于改善沉积的毛发调理组合物 | |
CN115697496A (zh) | 用于改善沉积的毛发调理组合物 | |
CN115715182A (zh) | 用于改善沉积的毛发调理组合物 | |
CN115697289A (zh) | 用于改善沉积的毛发调理组合物 | |
EA044973B1 (ru) | Кондиционирующая композиция для волос для улучшенного осаждения силикона | |
EA047249B1 (ru) | Кондиционирующая композиция для волос для улучшенного осаждения благотворно влияющего агента |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |