CN113135751A - Anti-static titanium oxide ceramic and preparation method thereof - Google Patents

Anti-static titanium oxide ceramic and preparation method thereof Download PDF

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CN113135751A
CN113135751A CN202110553410.9A CN202110553410A CN113135751A CN 113135751 A CN113135751 A CN 113135751A CN 202110553410 A CN202110553410 A CN 202110553410A CN 113135751 A CN113135751 A CN 113135751A
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parts
temperature
titanium oxide
oxide ceramic
antistatic
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赵振
马松华
谢洁
咸杏娟
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Yixing Jiurong Special Ceramics Co ltd
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Abstract

The invention relates to an anti-static ceramic, in particular to an anti-static titanium oxide ceramic and a preparation method thereof, wherein the anti-static titanium oxide ceramic is prepared from the following materials in parts by weight: 85-95 parts of titanium dioxide; 3-6 parts of silicon dioxide; 1-5 parts of calcium oxide; 1-4 parts of magnesium oxide. The antistatic titanium oxide ceramic provided by the invention can effectively avoid static electricity generated by spinning, and has the advantages of smooth surface, low friction coefficient, no abrasion to the spinning surface, long service life and difficult heating.

Description

Anti-static titanium oxide ceramic and preparation method thereof
Technical Field
The invention relates to an anti-static ceramic, in particular to an anti-static titanium oxide ceramic and a preparation method thereof.
Background
In the textile production process, static electricity can influence the quality of textile products, even influences the dyeing and finishing technology for example, after the drying, the water content of fabric reduces, and static electricity is difficult for deriving, and the fabric often adsorbs on metal parts, leads to winding disorder. The part of crossing the line in textile production adopts metal to make mostly, and metal parts is processing convenience, but produces static easily to the condition of wearing and tearing spinning takes place easily, still exists because the spinning slides the part at a high speed, leads to the condition that the friction generates heat, causes the temperature higher, influences the quality of spinning, and metal parts's life is short simultaneously.
Disclosure of Invention
In order to solve the problems, the invention provides an anti-static titanium oxide ceramic which is not easy to generate static electricity, has low friction coefficient, no abrasion to the spinning surface and long service life, and the specific technical scheme is as follows:
the antistatic titanium oxide ceramic comprises the following materials in parts by weight: 85-95 parts of titanium dioxide; 3-6 parts of silicon dioxide; 1-5 parts of calcium oxide; 1-4 parts of magnesium oxide.
By adopting the technical scheme, the silicon dioxide, the calcium oxide and the magnesium oxide are used for combustion assistance, so that the titanium dioxide forms a stable structure.
Preferably, 88-92 parts of titanium dioxide; 4-6 parts of silicon dioxide; 3-4 parts of calcium oxide; 2-4 parts of magnesium oxide.
The preparation method of the anti-static titanium oxide ceramic comprises the following steps:
mixing titanium dioxide, silicon dioxide, calcium oxide and magnesium oxide together, carrying out ball milling, adding paraffin, and stirring to obtain wax slurry;
grouting and molding the wax slurry by a die casting machine;
degreasing at high temperature;
high-temperature sintering, wherein hydrogen is introduced during the high-temperature sintering;
and (5) polishing the surface, namely polishing the wire passing surface of the finished product to be smooth.
By adopting the technical scheme, the surface of the finished product has a slight conductive function by sintering under hydrogen, and an anti-static effect is achieved.
The surface smoothness is improved by polishing, the roughness Ra is less than or equal to 0.1, and the yarns are not damaged.
Preferably, the addition amount of the paraffin wax is 10-15 parts.
Preferably, the temperature of the die casting machine is 65-75 ℃.
Preferably, the temperature of the high-temperature degreasing is 900-1100 ℃.
Preferably, the high-temperature sintering temperature is 1250-1350 ℃.
Compared with the prior art, the invention has the following beneficial effects:
the antistatic titanium oxide ceramic provided by the invention can effectively avoid static electricity generated by spinning, and has the advantages of smooth surface, low friction coefficient, no abrasion to the spinning surface, long service life and difficult heating.
Drawings
Fig. 1 is a sectional view of a porcelain eye made of an antistatic titanium oxide ceramic.
Detailed Description
The invention will now be further described with reference to the accompanying drawings.
The antistatic titanium oxide ceramic comprises the following materials in parts by weight: 85-95 parts of titanium dioxide; 3-6 parts of silicon dioxide; 1-5 parts of calcium oxide; 1-4 parts of magnesium oxide.
Silica, calcium oxide and magnesium oxide are used to aid in the sintering process, which results in the formation of a stable structure of titanium dioxide.
The preparation method of the anti-static titanium oxide ceramic comprises the following steps:
mixing titanium dioxide, silicon dioxide, calcium oxide and magnesium oxide together, carrying out ball milling, adding paraffin in an amount of 10-15 parts, and stirring to obtain a wax slurry;
performing slip casting molding on the wax slurry through a die casting machine, wherein the temperature of the die casting machine is 65-75 ℃;
high-temperature degreasing, wherein the temperature of the high-temperature degreasing is 900-1100 ℃;
high-temperature sintering, wherein hydrogen is introduced during the high-temperature sintering, and the temperature of the high-temperature sintering is 1250-1350 ℃;
and (5) polishing the surface, namely polishing the wire passing surface of the finished product to be smooth.
Sintering under hydrogen can make the surface of the finished product have a slight conductive function, and play a role in preventing static electricity.
The surface smoothness is improved by polishing, the roughness Ra is less than or equal to 0.1, and the yarns are not damaged.
Example one
The antistatic titanium oxide ceramic comprises the following materials in parts by weight:
85 parts of titanium dioxide; 3 parts of silicon dioxide; 1 part of calcium oxide; and 1 part of magnesium oxide.
The preparation method of the anti-static titanium oxide ceramic comprises the following steps:
mixing titanium dioxide, silicon dioxide, calcium oxide and magnesium oxide together, carrying out ball milling, adding 10 parts of paraffin, and stirring to obtain wax slurry;
performing slip casting molding on the wax slurry through a die casting machine, wherein the temperature of the die casting machine is 65 ℃;
high-temperature degreasing, wherein the temperature of the high-temperature degreasing is 900 ℃;
high-temperature sintering, wherein hydrogen is introduced during the high-temperature sintering, and the temperature of the high-temperature sintering is 1250 ℃;
and (5) polishing the surface, namely polishing the wire passing surface of the finished product to be smooth.
Example two
The antistatic titanium oxide ceramic comprises the following materials in parts by weight:
95 parts of titanium dioxide; 6 parts of silicon dioxide; 5 parts of calcium oxide; and 4 parts of magnesium oxide.
The preparation method of the anti-static titanium oxide ceramic comprises the following steps:
mixing titanium dioxide, silicon dioxide, calcium oxide and magnesium oxide together, carrying out ball milling, adding 15 parts of paraffin, and stirring to obtain wax slurry;
carrying out slip casting molding on the wax slurry through a die casting machine, wherein the temperature of the die casting machine is 75 ℃;
high-temperature degreasing, wherein the temperature of the high-temperature degreasing is 1100 ℃;
high-temperature sintering, wherein hydrogen is introduced during the high-temperature sintering, and the temperature of the high-temperature sintering is 1350 ℃;
and (5) polishing the surface, namely polishing the wire passing surface of the finished product to be smooth.
EXAMPLE III
The antistatic titanium oxide ceramic comprises the following materials in parts by weight:
88 parts of titanium dioxide; 4 parts of silicon dioxide; 3 parts of calcium oxide; and 2 parts of magnesium oxide.
The preparation method of the anti-static titanium oxide ceramic comprises the following steps:
mixing titanium dioxide, silicon dioxide, calcium oxide and magnesium oxide together, carrying out ball milling, adding 11 parts of paraffin, and stirring to obtain wax slurry;
carrying out slip casting molding on the wax slurry through a die casting machine, wherein the temperature of the die casting machine is 68 ℃;
high-temperature degreasing, wherein the temperature of the high-temperature degreasing is 1000 ℃;
high-temperature sintering, wherein hydrogen is introduced during the high-temperature sintering, and the temperature of the high-temperature sintering is 1300 ℃;
and (5) polishing the surface, namely polishing the wire passing surface of the finished product to be smooth.
Example four
The antistatic titanium oxide ceramic comprises the following materials in parts by weight:
90 parts of titanium dioxide; 5 parts of silicon dioxide; 3 parts of calcium oxide; 3 parts of magnesium oxide.
The preparation method of the anti-static titanium oxide ceramic comprises the following steps:
mixing titanium dioxide, silicon dioxide, calcium oxide and magnesium oxide together, carrying out ball milling, adding 12 parts of paraffin, and stirring to obtain wax slurry;
carrying out slip casting molding on the wax slurry through a die casting machine, wherein the temperature of the die casting machine is 75 ℃;
high-temperature degreasing, wherein the temperature of the high-temperature degreasing is 1080 ℃;
high-temperature sintering, wherein hydrogen is introduced during the high-temperature sintering, and the temperature of the high-temperature sintering is 1290 ℃;
and (5) polishing the surface, namely polishing the wire passing surface of the finished product to be smooth.
EXAMPLE five
The antistatic titanium oxide ceramic comprises the following materials in parts by weight:
92 parts of titanium dioxide; 3.5 parts of silicon dioxide; 4 parts of calcium oxide; 3.5 parts of magnesium oxide.
The preparation method of the anti-static titanium oxide ceramic comprises the following steps:
mixing titanium dioxide, silicon dioxide, calcium oxide and magnesium oxide together, carrying out ball milling, adding 13 parts of paraffin, and stirring to obtain wax slurry;
carrying out slip casting molding on the wax slurry through a die casting machine, wherein the temperature of the die casting machine is 68 ℃;
high-temperature degreasing, wherein the temperature of the high-temperature degreasing is 1050 ℃;
high-temperature sintering, wherein hydrogen is introduced during the high-temperature sintering, and the temperature of the high-temperature sintering is 1290 ℃;
and (5) polishing the surface, namely polishing the wire passing surface of the finished product to be smooth.
EXAMPLE six
The antistatic titanium oxide ceramic comprises the following materials in parts by weight:
94 parts of titanium dioxide; 4.5 parts of silicon dioxide; 2.5 parts of calcium oxide; 2.5 parts of magnesium oxide.
The preparation method of the anti-static titanium oxide ceramic comprises the following steps:
mixing titanium dioxide, silicon dioxide, calcium oxide and magnesium oxide together, carrying out ball milling, adding 14 parts of paraffin, and stirring to obtain paraffin slurry;
carrying out slip casting molding on the wax slurry through a die casting machine, wherein the temperature of the die casting machine is 68 ℃;
high-temperature degreasing, wherein the temperature of the high-temperature degreasing is 980 ℃;
high-temperature sintering, wherein hydrogen is introduced during the high-temperature sintering, and the temperature of the high-temperature sintering is 1320 ℃;
and (5) polishing the surface, namely polishing the wire passing surface of the finished product to be smooth.
EXAMPLE seven
The antistatic titanium oxide ceramic comprises the following materials in parts by weight:
92 parts of titanium dioxide; 6 parts of silicon dioxide; 4 parts of calcium oxide; and 4 parts of magnesium oxide.
The preparation method of the anti-static titanium oxide ceramic comprises the following steps:
mixing titanium dioxide, silicon dioxide, calcium oxide and magnesium oxide together, carrying out ball milling, adding 14 parts of paraffin, and stirring to obtain paraffin slurry;
grouting and molding the wax slurry through a die casting machine, wherein the temperature of the die casting machine is 73 ℃;
high-temperature degreasing, wherein the temperature of the high-temperature degreasing is 950 ℃;
high-temperature sintering, wherein hydrogen is introduced during the high-temperature sintering, and the temperature of the high-temperature sintering is 1280 ℃;
and (5) polishing the surface, namely polishing the wire passing surface of the finished product to be smooth.
As shown in figure 1, the porcelain eye 1 made of the anti-static titanium oxide ceramic is adopted, the hole 11 in the middle is a yarn feeding area, spun yarns penetrate through the hole 11, and due to the fact that the surface is smooth, the friction coefficient is low, the spun yarns are not prone to abrasion, friction heating is avoided, and static electricity cannot be generated due to friction.
The technical principle of the present invention is described above in connection with specific embodiments. The description is made for the purpose of illustrating the principles of the invention and should not be construed in any way as limiting the scope of the invention. Based on the explanations herein, those skilled in the art will be able to conceive of other embodiments of the present invention without inventive step, which shall fall within the scope of the appended claims.

Claims (7)

1. The antistatic titanium oxide ceramic is characterized by comprising the following materials in parts by weight:
85-95 parts of titanium dioxide;
3-6 parts of silicon dioxide;
1-5 parts of calcium oxide;
1-4 parts of magnesium oxide.
2. The antistatic titanium oxide ceramic according to claim 1,
88-92 parts of titanium dioxide;
4-6 parts of silicon dioxide;
3-4 parts of calcium oxide;
2-4 parts of magnesium oxide.
3. The preparation method of the anti-static titanium oxide ceramic is characterized by comprising the following steps:
mixing titanium dioxide, silicon dioxide, calcium oxide and magnesium oxide together, carrying out ball milling, adding paraffin, and stirring to obtain wax slurry;
grouting and molding the wax slurry by a die casting machine;
degreasing at high temperature;
high-temperature sintering, wherein hydrogen is introduced during the high-temperature sintering;
and (5) polishing the surface, namely polishing the wire passing surface of the finished product to be smooth.
4. The method for preparing antistatic titanium oxide ceramic according to claim 3, wherein the amount of paraffin wax added is 10 to 15 parts.
5. The preparation method of the antistatic titanium oxide ceramic according to claim 3, wherein the temperature of the die casting machine is 65-75 ℃.
6. The method for preparing the antistatic titanium oxide ceramic according to claim 3, wherein the temperature of the high temperature degreasing is 900-1100 ℃.
7. The method for preparing the antistatic titanium oxide ceramic according to claim 3, wherein the temperature of the high-temperature sintering is 1250-1350 ℃.
CN202110553410.9A 2021-05-20 2021-05-20 Anti-static titanium oxide ceramic and preparation method thereof Pending CN113135751A (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4110260A (en) * 1975-09-25 1978-08-29 Tokyo Denki Kagaku Kogyo Kabushiki Kaisha (Tdk Electronics Co., Ltd.) Electroconductive composite ceramics
CN103073283A (en) * 2011-11-18 2013-05-01 常熟市创新陶瓷有限公司 Titanium oxide ceramic and preparation method thereof
CN103073284A (en) * 2011-11-21 2013-05-01 常熟市创新陶瓷有限公司 Titanium oxide ceramic and preparation method thereof
CN103732560A (en) * 2011-08-16 2014-04-16 西门子公司 Pressure casting slip and refractory ceramic produced therefrom for gas turbine units
CN104341150A (en) * 2014-09-12 2015-02-11 李正国 Anti-static zirconia ceramic and preparation process thereof
CN108546121A (en) * 2018-06-29 2018-09-18 芜湖市元奎新材料科技有限公司 Zirconium oxide anti-static ceramic and preparation method thereof
CN109437886A (en) * 2018-12-04 2019-03-08 合肥睿涌陶瓷材料科技有限公司 A kind of flame heat spray titanium dioxide base composite ceramic stick and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4110260A (en) * 1975-09-25 1978-08-29 Tokyo Denki Kagaku Kogyo Kabushiki Kaisha (Tdk Electronics Co., Ltd.) Electroconductive composite ceramics
CN103732560A (en) * 2011-08-16 2014-04-16 西门子公司 Pressure casting slip and refractory ceramic produced therefrom for gas turbine units
CN103073283A (en) * 2011-11-18 2013-05-01 常熟市创新陶瓷有限公司 Titanium oxide ceramic and preparation method thereof
CN103073284A (en) * 2011-11-21 2013-05-01 常熟市创新陶瓷有限公司 Titanium oxide ceramic and preparation method thereof
CN104341150A (en) * 2014-09-12 2015-02-11 李正国 Anti-static zirconia ceramic and preparation process thereof
CN108546121A (en) * 2018-06-29 2018-09-18 芜湖市元奎新材料科技有限公司 Zirconium oxide anti-static ceramic and preparation method thereof
CN109437886A (en) * 2018-12-04 2019-03-08 合肥睿涌陶瓷材料科技有限公司 A kind of flame heat spray titanium dioxide base composite ceramic stick and preparation method thereof

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Application publication date: 20210720