CN113123011B - Elastic ribbon with massage function - Google Patents

Elastic ribbon with massage function Download PDF

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Publication number
CN113123011B
CN113123011B CN202110579247.3A CN202110579247A CN113123011B CN 113123011 B CN113123011 B CN 113123011B CN 202110579247 A CN202110579247 A CN 202110579247A CN 113123011 B CN113123011 B CN 113123011B
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fiber
massage
parts
weight
modified
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CN113123011A (en
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郭雄飞
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Jiangxi Xiuli Weaving Belt Co ltd
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Jiangxi Xiuli Weaving Belt Co ltd
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    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04C—BRAIDING OR MANUFACTURE OF LACE, INCLUDING BOBBIN-NET OR CARBONISED LACE; BRAIDING MACHINES; BRAID; LACE
    • D04C1/00—Braid or lace, e.g. pillow-lace; Processes for the manufacture thereof
    • D04C1/02—Braid or lace, e.g. pillow-lace; Processes for the manufacture thereof made from particular materials
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
    • A61N1/00—Electrotherapy; Circuits therefor
    • A61N1/02—Details
    • A61N1/04—Electrodes
    • A61N1/0404—Electrodes for external use
    • A61N1/0472—Structure-related aspects
    • A61N1/0484—Garment electrodes worn by the patient
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
    • A61N1/00—Electrotherapy; Circuits therefor
    • A61N1/18—Applying electric currents by contact electrodes
    • A61N1/32—Applying electric currents by contact electrodes alternating or intermittent currents
    • A61N1/36—Applying electric currents by contact electrodes alternating or intermittent currents for stimulation
    • A61N1/36014—External stimulators, e.g. with patch electrodes
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D01F1/103—Agents inhibiting growth of microorganisms
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D01F1/106—Radiation shielding agents, e.g. absorbing, reflecting agents
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/90—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04C—BRAIDING OR MANUFACTURE OF LACE, INCLUDING BOBBIN-NET OR CARBONISED LACE; BRAIDING MACHINES; BRAID; LACE
    • D04C1/00—Braid or lace, e.g. pillow-lace; Processes for the manufacture thereof
    • D04C1/06—Braid or lace serving particular purposes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34—Polyamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00—Inorganic fibres
    • D10B2101/10—Inorganic fibres based on non-oxides other than metals
    • D10B2101/12—Carbon; Pitch
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/02—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
    • D10B2321/022—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polypropylene
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
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    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
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    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/10—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyurethanes

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  • Heart & Thoracic Surgery (AREA)
  • Artificial Filaments (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention relates to the technical field of woven belts, in particular to an elastic woven belt with a massage function; the elastic woven belt comprises a woven belt body and a massage assembly bonded on the inner side of the woven belt body through a bonding cloth belt; wherein, the mesh belt body is of a weaving structure; the braid body is composed of 35-50 parts by weight of modified PA6 fiber, 15-25 parts by weight of polypropylene fiber, 8-12 parts by weight of modified polyester fiber, 12-18 parts by weight of bamboo charcoal fiber and 4-8 parts by weight of spandex fiber; the massage component comprises a massage electrode plate and a controller electrically connected with the massage electrode plate; the prepared mesh belt has certain massage and health care functions, certain ventilation and sweat absorption performance and comfortable wearing; in addition, the woven belt product has good elastic performance, antibacterial performance and ageing resistance, the service life of the woven belt product is effectively prolonged, and the quality of the woven belt product is guaranteed.

Description

Elastic ribbon with massage function
Technical Field
The invention relates to the technical field of woven belts, in particular to an elastic woven belt with a massage function.
Background
The woven belt is made of various yarns as raw materials into narrow-width fabric or tubular fabric. The woven fabric has various varieties and is widely applied to various industrial departments such as clothes, shoe materials, cases, industry, agriculture, military needs, transportation and the like. In the 30 s, the woven belts were produced by manual workshops and made of cotton threads and linen threads. After the new China is established, the raw materials for the mesh belt are gradually developed into chinlon, vinylon, terylene, polypropylene fiber, spandex, viscose glue and the like to form three major process technologies of weaving, knitting and knitting, and the fabric structure has plain weave, twill, satin, jacquard weave, double layers, multi-layer, tubular and combined weave.
At present, the woven tape is widely applied to clothes conveniently, although nylon, terylene, spandex, polypropylene and bamboo charcoal fiber are often used as materials for preparing the woven tape, the performance and the quality of the woven tape are improved to a certain extent, and the life of people is facilitated. But it also has some disadvantages in itself. For example, the function of the shoe is relatively single, and the elasticity and the air permeability are relatively poor, so that the comfort of wearing is poor.
Disclosure of Invention
Aiming at the defects in the prior art, the invention provides the elastic woven belt with the massage function, and the prepared woven belt not only has certain massage and health care functions, but also has certain ventilation and sweat absorption performances, and is comfortable to wear; in addition, the woven belt product has good elastic performance, antibacterial performance and ageing resistance, the service life of the woven belt product is effectively prolonged, and the quality of the woven belt product is guaranteed.
In order to achieve the purpose, the invention provides the following technical scheme:
an elastic woven belt with a massage function comprises a woven belt body and a massage assembly bonded on the inner side of the woven belt body through a bonding cloth belt; wherein the mesh belt body is of a weaving structure; the braid body is composed of 35-50 parts by weight of modified PA6 fiber, 15-25 parts by weight of polypropylene fiber, 8-12 parts by weight of modified polyester fiber, 12-18 parts by weight of bamboo charcoal fiber and 4-8 parts by weight of spandex fiber; the massage component comprises a massage electrode plate and a controller electrically connected with the massage electrode plate.
Further, the preparation method of the modified PA6 fiber comprises the following steps
I, adding a proper amount of mixed powder into the mixed solution according to the material-liquid ratio of 0.06-0.1 g/mL, uniformly mixing and stirring, raising the temperature of the obtained mixed component to 50-60 ℃, and carrying out heat preservation reaction for 5-8 hours at the temperature; mechanically stirring the mixed components every 1h for 5-10 min in the reaction process; after the reaction is finished, filtering out the mixed powder, and then sequentially washing and drying the mixed powder to obtain a solid substance which is recorded as modified mixed powder;
II, mechanically mixing the PA6 slices with 1.2-2.0% of styrene-maleic anhydride copolymer, 6-8% of modified mixed powder, 0.7-1.5% of polyethylene wax and 0.5-1.2% of butyl hydroxy anisole, and then granulating to prepare PA6 master batch; mixing and melt spinning the obtained PA6 master batch and PA6 slices with the mass being 11-15 times of that of the PA6 master batch; naturally cooling to room temperature to obtain PA6 fiber;
III, soaking the obtained PA6 fiber in an aqueous solution of an ultraviolet absorbent with the concentration of 15-25% according to the solid-to-liquid ratio of 0.05-0.1 g/mL, performing ultrasonic dispersion for 5-10 min, and adding a proper amount of acrylic acid to keep the concentration of the acrylic acid at 15-20%; then, sealing, preserving heat and standing the obtained reaction system for 40-50 min at the temperature of 50-60 ℃; then carrying out irradiation reaction for 25-40 min; and taking out the PA6 fiber, and sequentially washing and drying to obtain a finished product of the modified PA6 fiber.
Furthermore, the mixed powder in the step I is prepared from nano medical stone powder with the particle size of 200-300 nm, nano sericite and nano zirconia according to a mass ratio of 1: 0.3-0.5: 0.4-0.7 by mixing.
Furthermore, the preparation method of the mixed solution in the step I comprises the following steps: adding 20-30% of gamma-aminopropyltriethoxysilane and 2.5-4.2% of sodium dodecyl benzene sulfonate into a proper amount of 60-70% ethanol solution, and uniformly mixing by ultrasonic to obtain a mixed solution finished product.
Furthermore, the ultraviolet absorbent used in step III is any one of sodium 2-hydroxy-4-methoxybenzophenone-5-sulfonate and sodium 2, 2 ' -dihydroxy-4, 4 ' -dimethoxybenzophenone-5, 5 ' -disulfonate.
Furthermore, during the irradiation reaction in the step III, the beam intensity is 5-10 mA, the electron beam energy is 1.8Mev, and the dose is 40-120 kGy.
Furthermore, when the modified polyester fiber is prepared by adopting a melt spinning process, the polyester master batch contains 2.5-3.5% of nano-scale calcined diatomite, 1.6-2.2% of nano-silver antibacterial agent and 0.8-1.5% of QCS antistatic agent by mass.
Furthermore, the massage electrode slice is glued on the inner side of the mesh belt body, and the gluing cloth belt is connected with the mesh belt body through a magic tape.
Furthermore, the massage electrode plate is a fish-jump SDP-330 low-frequency pulse physiotherapy instrument patch, and a pocket for holding a controller is arranged at one end part of the adhesive cloth belt matched with the outer side of the braid body; the two free end parts of the mesh belt body are connected through the magic tape.
Advantageous effects
Compared with the known public technology, the technical scheme provided by the invention has the following beneficial effects:
1. the invention firstly puts the nanometer medical stone powder, the nanometer sericite and the nanometer zirconia into the mixed solution made of ethanol, gamma-aminopropyl triethoxysilane and sodium dodecyl benzene sulfonate, and modifies the surface of the nanometer medical stone powder, the nanometer sericite and the nanometer zirconia through the gamma-aminopropyl triethoxysilane, so that the nanometer medical stone powder, the nanometer sericite and the nanometer zirconia are changed from hydrophilicity to hydrophobicity, and the nanometer medical stone powder, the nanometer sericite and the nanometer zirconia are conveniently dispersed in the subsequent organic phase. Then the modified mixed powder is used as a raw material for preparing PA6 master batch, so that the prepared PA6 fiber has certain uvioresistant performance, can release a certain amount of far infrared rays to the outside, has certain health care effect, and is beneficial to the health of human body. Then, the prepared PA6 fiber is soaked in an aqueous solution of an ultraviolet absorbent, ultrasonic dispersion treatment is carried out on the PA6 fiber, so that the water-soluble ultraviolet absorbent can uniformly reside on the surface of the PA6 fiber, a proper amount of acrylic acid is added into the aqueous solution of the ultraviolet absorbent, grafting reaction is carried out between the acrylic acid and the surface of the PA6 fiber, and a three-dimensional network structure is formed on the surface of the PA6 fiber due to the reaction, so that ultraviolet absorbent molecules are effectively fixed on the surface of the PA6 fiber, and the PA6 fiber has a long-acting ultraviolet resistance function. And the aging resistance of the PA6 fiber and the woven tape can be further improved by matching the ultraviolet absorbent with the modified mixed powder, and the service life of the PA6 fiber and the woven tape is further prolonged.
2. The terylene master batch provided by the invention contains a proper amount of nano-scale calcined diatomite, a nano-silver antibacterial agent and a QCS (quaternary ammonium silicate) antistatic agent; the nano-silver antibacterial agent, the modified mixed powder and the bamboo charcoal fiber are mutually cooperated, so that the woven belt prepared by the method has long-acting antibacterial performance. And the nanoscale calcined diatomite, the QCS antistatic agent and the polypropylene fiber are cooperated with one another, so that the antistatic performance of the polyester fiber can be effectively improved, and the comfort level of the woven tape is improved.
3. According to the invention, the modified nylon fiber, the polypropylene fiber, the modified polyester fiber and the bamboo charcoal fiber are used as materials for preparing the woven tape, so that the prepared woven tape not only has good moisture absorption and air permeability, but also has good elastic performance. In addition, the massage component can massage the relevant parts of the human body to a certain degree, so that the fatigue of wearing the mesh belt for a long time is reduced, and the comfort level of the mesh belt is improved.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, it is obvious that the drawings in the following description are only some embodiments of the present invention, and for those skilled in the art, other drawings can be obtained according to the drawings without creative efforts.
FIG. 1 is a schematic structural view of an elastic webbing provided in the present invention;
in the figure: 1-elastic woven belt, 2-woven belt body, 3-adhesive cloth belt, 4-massage component, 5-massage electrode plate and 6-controller.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below. It is to be understood that the embodiments described are only a few embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The present invention will be further described with reference to the following examples.
Example 1
An elastic woven belt 1 with a massage function, wherein the elastic woven belt 1 comprises a woven belt body 2 and a massage assembly 4 which is bonded on the inner side of the woven belt body through a bonding cloth belt 3; wherein the mesh belt body is of a weaving structure; the braid body consists of 35 parts by weight of modified PA6 fiber, 15 parts by weight of polypropylene fiber, 8 parts by weight of modified polyester fiber, 12 parts by weight of bamboo charcoal fiber and 4 parts by weight of spandex fiber; the massage component comprises a massage electrode plate 5 and a controller 6 electrically connected with the massage electrode plate.
The preparation method of the modified PA6 fiber comprises the following steps
I, adding a proper amount of mixed powder into the mixed solution according to the feed-liquid ratio of 0.06g/mL, uniformly mixing and stirring, raising the temperature of the obtained mixed component to 50 ℃, and carrying out heat preservation reaction for 5 hours at the temperature; mechanically stirring the mixed components every 1h for 5min in the reaction process; after the reaction is finished, filtering out the mixed powder, and then sequentially washing and drying the mixed powder to obtain a solid substance which is recorded as modified mixed powder;
II, mechanically mixing the PA6 slices with 1.2-2.0% of styrene-maleic anhydride copolymer, 6% of modified mixed powder, 0.7% of polyethylene wax and 0.5% of butyl hydroxy anisol, and then granulating to prepare PA6 master batches; mixing the obtained PA6 master batch with PA6 slices with the mass being 11 times of that of the PA6 master batch, and carrying out melt spinning; naturally cooling to room temperature to obtain PA6 fiber;
III, soaking the obtained PA6 fiber in an aqueous solution of an ultraviolet absorbent with the concentration of 15% according to the solid-to-liquid ratio of 0.05g/mL, performing ultrasonic dispersion for 5min, and adding a proper amount of acrylic acid to keep the concentration of the acrylic acid at 15%; then sealing, preserving heat and standing the obtained reaction system for 40min at the temperature of 50 ℃; then carrying out irradiation reaction for 25 min; and taking out the PA6 fiber, and sequentially washing and drying to obtain a finished product of the modified PA6 fiber.
In the step I, the mixed powder is prepared from nano medical stone powder with the particle size of 200nm, nano sericite and nano zirconia according to the mass ratio of 1: 0.3: 0.4, and mixing.
The preparation method of the mixed solution in the step I comprises the following steps: adding 20-30% of gamma-aminopropyltriethoxysilane and 2.5% of sodium dodecyl benzene sulfonate into a proper amount of 60% ethanol solution respectively, and performing ultrasonic mixing to obtain a mixed solution finished product.
And the ultraviolet absorbent used in the step III is sodium 2-hydroxy-4-methoxybenzophenone-5-sulfonate.
And during the irradiation reaction in the step III, the beam intensity is 5mA, the electron beam energy is 1.8Mev, and the dose is 40 kGy.
When the modified polyester fiber is prepared by adopting a melt spinning process, the polyester master batch contains 2.5% of nano-scale calcined diatomite, 1.6% of nano-silver antibacterial agent and 0.8% of QCS antistatic agent by mass.
The massage electrode slice 5 is connected with the inner side of the mesh belt body 2 in a gluing mode, and the bonding cloth belt 3 is connected with the mesh belt body 2 through a magic tape.
The massage electrode slice 5 is a fish jumping SDP-330 low-frequency pulse physiotherapy instrument patch, and a pocket for holding the controller 6 is arranged at one end part of the adhesive cloth band 3 matched with the outer side of the braid body 2; two free end parts of the mesh belt body 2 are connected through a magic tape.
Example 2
The present embodiment provides an elastic webbing with massage function, which is different from embodiment 1 in that: the specific proportion of each fiber component contained in the mesh belt body is different, and the specific preparation processes of the modified PA6 fiber and the modified polyester fiber are different, and specifically comprise the following steps:
the braid body consists of 40 parts by weight of modified PA6 fiber, 20 parts by weight of polypropylene fiber, 10 parts by weight of modified polyester fiber, 15 parts by weight of bamboo charcoal fiber and 6 parts by weight of spandex fiber;
the preparation method of the modified PA6 fiber comprises the following steps
I, adding a proper amount of mixed powder into the mixed solution according to the feed-liquid ratio of 0.08g/mL, uniformly mixing and stirring, raising the temperature of the obtained mixed component to 55 ℃, and carrying out heat preservation reaction for 6 hours at the temperature; mechanically stirring the mixed components every 1h for 8min in the reaction process; after the reaction is finished, filtering out the mixed powder, and then sequentially washing and drying the mixed powder to obtain a solid substance which is recorded as modified mixed powder;
II, mechanically mixing the PA6 slices with 1.6 mass percent of styrene-maleic anhydride copolymer, 7 mass percent of modified mixed powder, 1.2 mass percent of polyethylene wax and 1.0 mass percent of butyl hydroxy anisol, and then granulating to prepare PA6 master batches; mixing the obtained PA6 master batch with PA6 slices with the mass 13 times of that of the PA6 master batch, and carrying out melt spinning; naturally cooling to room temperature to obtain PA6 fiber;
III, soaking the obtained PA6 fiber in an aqueous solution of an ultraviolet absorbent with the concentration of 20% according to the solid-to-liquid ratio of 0.07g/mL, performing ultrasonic dispersion for 8min, and adding a proper amount of acrylic acid to keep the concentration of the acrylic acid at 18%; then sealing, preserving heat and standing the obtained reaction system for 45min at the temperature of 55 ℃; then carrying out irradiation reaction for 35 min; and taking out the PA6 fiber, and sequentially washing and drying to obtain a finished product of the modified PA6 fiber.
In the step I, the mixed powder is prepared from nano medical stone powder with the particle size of 250nm, nano sericite and nano zirconia according to the mass ratio of 1: 0.4: 0.6, and mixing.
The preparation method of the mixed solution in the step I comprises the following steps: adding 25 mass percent of gamma-aminopropyl triethoxysilane and 2.5-4.2 mass percent of sodium dodecyl benzene sulfonate into a proper amount of 65 mass percent ethanol solution respectively, and performing ultrasonic mixing to obtain a mixed solution finished product.
And the ultraviolet absorbent used in the step III is 2, 2 ' -dihydroxy-4, 4 ' -dimethoxy benzophenone-5, 5 ' -sodium disulfonate.
And during the irradiation reaction in the step III, the beam intensity is 8mA, the electron beam energy is 1.8Mev, and the dose is 80 kGy.
When the modified polyester fiber is prepared by adopting a melt spinning process, the polyester master batch contains 3.0 percent of nano-scale calcined diatomite, 2.0 percent of nano-silver antibacterial agent and 1.2 percent of QCS antistatic agent by mass.
Example 3
The present embodiment provides an elastic webbing with massage function, which is different from embodiment 1 in that: the specific proportion of each fiber component contained in the mesh belt body is different, and the specific preparation processes of the modified PA6 fiber and the modified polyester fiber are different, and specifically comprise the following steps:
the braid body consists of 50 parts by weight of modified PA6 fiber, 25 parts by weight of polypropylene fiber, 12 parts by weight of modified polyester fiber, 18 parts by weight of bamboo charcoal fiber and 8 parts by weight of spandex fiber;
the preparation method of the modified PA6 fiber comprises the following steps
I, adding a proper amount of mixed powder into the mixed solution according to the feed-liquid ratio of 0.1g/mL, uniformly mixing and stirring, raising the temperature of the obtained mixed components to 60 ℃, and carrying out heat preservation reaction for 8 hours at the temperature; mechanically stirring the mixed components every 1h for 10min in the reaction process; after the reaction is finished, filtering out the mixed powder, and then sequentially washing and drying the mixed powder to obtain a solid substance which is recorded as modified mixed powder;
II, mechanically mixing the PA6 slices with 2.0% of styrene-maleic anhydride copolymer, 8% of modified mixed powder, 1.5% of polyethylene wax and 1.2% of butyl hydroxy anisol by mass, and then granulating to prepare PA6 master batch; mixing the obtained PA6 master batch with PA6 slices with the mass 15 times of that of the PA6 master batch, and carrying out melt spinning; naturally cooling to room temperature to obtain PA6 fiber;
III, soaking the obtained PA6 fiber in an aqueous solution of an ultraviolet absorbent with the concentration of 25% according to the solid-to-liquid ratio of 0.1g/mL, performing ultrasonic dispersion for 10min, and adding a proper amount of acrylic acid to keep the concentration of the acrylic acid at 20%; then, sealing, preserving heat and standing the obtained reaction system for 50min at the temperature of 60 ℃; then carrying out irradiation reaction for 40 min; and taking out the PA6 fiber, and sequentially washing and drying to obtain a finished product of the modified PA6 fiber.
In the step I, the mixed powder is prepared from nano medical stone powder with the particle size of 300nm, nano sericite and nano zirconia according to the mass ratio of 1: 0.5: 0.7, and mixing.
The preparation method of the mixed solution in the step I comprises the following steps: adding 30 mass percent of gamma-aminopropyl triethoxysilane and 4.2 mass percent of sodium dodecyl benzene sulfonate into a proper amount of ethanol solution with the concentration of 70 percent respectively, and carrying out ultrasonic mixing uniformly to obtain a mixed solution finished product.
And the ultraviolet absorbent used in the step III is sodium 2-hydroxy-4-methoxybenzophenone-5-sulfonate.
And during the irradiation reaction in the step III, the beam intensity is 10mA, the electron beam energy is 1.8Mev, and the dose is 120 kGy.
When the modified polyester fiber is prepared by adopting a melt spinning process, the polyester master batch contains 3.5 percent of nano-scale calcined diatomite, 2.2 percent of nano-silver antibacterial agent and 1.5 percent of QCS antistatic agent by mass.
Comparative example 1
The present embodiment provides an elastic webbing with massage function, which is different from embodiment 1 in that: common PA6 fiber is adopted to replace modified PA6 fiber prepared by the invention;
comparative example 2
The present embodiment provides an elastic webbing with massage function, which is different from embodiment 1 in that: replacing the modified polyester fiber prepared by the invention with common polyester fiber;
performance testing
Taking the same amount of the elastic woven belts prepared in the embodiments 1-3 and the comparative examples 1-2, and carrying out performance detection on each group of elastic woven belt samples according to correspondingly specified detection standards, wherein the detection results of each group of samples are recorded in tables 1 and 2:
TABLE 1
Figure BDA0003085568960000091
By comparing and analyzing the relevant data in table 1, it can be seen that: the woven tape provided by the invention not only has good antibacterial performance, but also has excellent air permeability and antistatic performance, and is very comfortable to wear. The service life of the elastic woven belt is effectively prolonged, and the quality of the elastic woven belt is improved.
TABLE 2
Figure BDA0003085568960000092
Figure BDA0003085568960000101
By comparing and analyzing the relevant data in table 2, it can be seen that: the mesh belt provided by the invention not only has certain massage (fatigue relieving) and health care functions, but also has good elastic performance and lasting anti-aging performance, thereby effectively prolonging the service life and ensuring the quality of the mesh belt. Therefore, the elastic woven belt has wider market prospect and is more suitable for popularization.
The above examples are only intended to illustrate the technical solution of the present invention, but not to limit it; although the present invention has been described in detail with reference to the foregoing embodiments, it will be understood by those of ordinary skill in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some technical features may be equivalently replaced; such modifications and substitutions do not depart from the spirit and scope of the corresponding technical solutions.

Claims (7)

1. An elastic woven belt with a massage function is characterized by comprising a woven belt body and a massage assembly bonded on the inner side of the woven belt body through a bonding cloth belt; wherein the mesh belt body is of a weaving structure; the braid body is composed of 35-50 parts by weight of modified PA6 fiber, 15-25 parts by weight of polypropylene fiber, 8-12 parts by weight of modified polyester fiber, 12-18 parts by weight of bamboo charcoal fiber and 4-8 parts by weight of spandex fiber; the massage component comprises a massage electrode plate and a controller electrically connected with the massage electrode plate;
wherein the preparation method of the modified PA6 fiber comprises the following steps
I, adding a proper amount of mixed powder into the mixed solution according to the material-liquid ratio of 0.06-0.1 g/mL, uniformly mixing and stirring, raising the temperature of the obtained mixed component to 50-60 ℃, and carrying out heat preservation reaction for 5-8 hours at the temperature; mechanically stirring the mixed components every 1h for 5-10 min in the reaction process; after the reaction is finished, filtering out the mixed powder, and then sequentially washing and drying the mixed powder to obtain a solid substance which is recorded as modified mixed powder; in the step I, the mixed powder is prepared from nano medical stone powder with the particle size of 200-300 nm, nano sericite and nano zirconia according to the mass ratio of 1: 0.3-0.5: 0.4-0.7, and mixing;
II, mechanically mixing the PA6 slices with 1.2-2.0% of styrene-maleic anhydride copolymer, 6-8% of modified mixed powder, 0.7-1.5% of polyethylene wax and 0.5-1.2% of butyl hydroxy anisole, and then granulating to prepare PA6 master batch; mixing and melt spinning the obtained PA6 master batch and PA6 slices with the mass being 11-15 times of that of the PA6 master batch; naturally cooling to room temperature to obtain PA6 fiber;
III, soaking the obtained PA6 fiber in an aqueous solution of an ultraviolet absorbent with the concentration of 15-25% according to the solid-to-liquid ratio of 0.05-0.1 g/mL, performing ultrasonic dispersion for 5-10 min, and adding a proper amount of acrylic acid to keep the concentration of the acrylic acid at 15-20%; then, sealing, preserving heat and standing the obtained reaction system for 40-50 min at the temperature of 50-60 ℃; then carrying out irradiation reaction for 25-40 min; and taking out the PA6 fiber, and sequentially washing and drying to obtain a finished product of the modified PA6 fiber.
2. The elastic webbing belt with massage function as claimed in claim 1, wherein the preparation method of the mixed liquid in step i comprises: adding 20-30% of gamma-aminopropyltriethoxysilane and 2.5-4.2% of sodium dodecyl benzene sulfonate into a proper amount of 60-70% ethanol solution, and uniformly mixing by ultrasonic to obtain a mixed solution finished product.
3. The stretch webbing with massage function as claimed in claim 1, wherein: and the ultraviolet absorbent used in the step III is any one of sodium 2-hydroxy-4-methoxybenzophenone-5-sulfonate and sodium 2, 2 ' -dihydroxy-4, 4 ' -dimethoxybenzophenone-5, 5 ' -disulfonate.
4. The stretch webbing with massage function as claimed in claim 1, wherein: and during the irradiation reaction in the step III, the beam intensity is 5-10 mA, the electron beam energy is 1.8Mev, and the dose is 40-120 kGy.
5. The stretch webbing with massage function as claimed in claim 1, wherein: when the modified polyester fiber is prepared by adopting a melt spinning process, the polyester master batch contains 2.5-3.5% of nano-scale calcined diatomite, 1.6-2.2% of nano-silver antibacterial agent and 0.8-1.5% of QCS antistatic agent by mass.
6. The stretch webbing with massage function as claimed in claim 1, wherein: the massage electrode slice is connected to the inner side of the mesh belt body in a gluing mode, and the gluing cloth belt is connected with the mesh belt body through the magic tape.
7. The stretch webbing with massage function as claimed in claim 1, wherein: the massage electrode plate is a fish-jump SDP-330 low-frequency pulse physiotherapy instrument patch, and a pocket for containing a controller is arranged at one end part of the adhesive cloth belt matched with the outer side of the braid body; the two free end parts of the mesh belt body are connected through the magic tape.
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