CN113122361B - 一种基于黑磷量子点的低成本钛合金水基切削液及其制备方法 - Google Patents
一种基于黑磷量子点的低成本钛合金水基切削液及其制备方法 Download PDFInfo
- Publication number
- CN113122361B CN113122361B CN202110298122.3A CN202110298122A CN113122361B CN 113122361 B CN113122361 B CN 113122361B CN 202110298122 A CN202110298122 A CN 202110298122A CN 113122361 B CN113122361 B CN 113122361B
- Authority
- CN
- China
- Prior art keywords
- black phosphorus
- cutting fluid
- parts
- stirring
- titanium alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical class [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims abstract description 96
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 83
- 239000002173 cutting fluid Substances 0.000 title claims abstract description 82
- 229910001069 Ti alloy Inorganic materials 0.000 title claims abstract description 48
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 238000003756 stirring Methods 0.000 claims abstract description 55
- 239000002096 quantum dot Substances 0.000 claims abstract description 37
- 239000008367 deionised water Substances 0.000 claims abstract description 24
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 24
- 239000011230 binding agent Substances 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- 239000002270 dispersing agent Substances 0.000 claims abstract description 17
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 15
- 239000007864 aqueous solution Substances 0.000 claims abstract description 15
- 239000013556 antirust agent Substances 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 14
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 10
- 238000001816 cooling Methods 0.000 claims abstract description 6
- 238000002604 ultrasonography Methods 0.000 claims abstract description 6
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims abstract 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 20
- 238000000498 ball milling Methods 0.000 claims description 20
- 239000000843 powder Substances 0.000 claims description 17
- 239000007788 liquid Substances 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 11
- 239000002245 particle Substances 0.000 claims description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- -1 phosphate ester Chemical class 0.000 claims description 7
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000012530 fluid Substances 0.000 claims description 6
- 238000005303 weighing Methods 0.000 claims description 6
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 5
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 claims description 5
- 239000012990 dithiocarbamate Substances 0.000 claims description 5
- 239000002244 precipitate Substances 0.000 claims description 5
- 239000000047 product Substances 0.000 claims description 5
- 238000007789 sealing Methods 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 239000006228 supernatant Substances 0.000 claims description 5
- UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 4
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 4
- 235000019441 ethanol Nutrition 0.000 claims description 4
- 239000003960 organic solvent Substances 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 4
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 4
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 4
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 4
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 3
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical group CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000005642 Oleic acid Substances 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims description 3
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
- 229910021538 borax Inorganic materials 0.000 claims description 3
- 229910052681 coesite Inorganic materials 0.000 claims description 3
- 229910052906 cristobalite Inorganic materials 0.000 claims description 3
- KCIDZIIHRGYJAE-YGFYJFDDSA-L dipotassium;[(2r,3r,4s,5r,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl] phosphate Chemical class [K+].[K+].OC[C@H]1O[C@H](OP([O-])([O-])=O)[C@H](O)[C@@H](O)[C@H]1O KCIDZIIHRGYJAE-YGFYJFDDSA-L 0.000 claims description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 3
- 229920001223 polyethylene glycol Polymers 0.000 claims description 3
- 235000019353 potassium silicate Nutrition 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 239000004328 sodium tetraborate Substances 0.000 claims description 3
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 3
- 229910052682 stishovite Inorganic materials 0.000 claims description 3
- 229910052905 tridymite Inorganic materials 0.000 claims description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 2
- HVCOBJNICQPDBP-UHFFFAOYSA-N 3-[3-[3,5-dihydroxy-6-methyl-4-(3,4,5-trihydroxy-6-methyloxan-2-yl)oxyoxan-2-yl]oxydecanoyloxy]decanoic acid;hydrate Chemical compound O.OC1C(OC(CC(=O)OC(CCCCCCC)CC(O)=O)CCCCCCC)OC(C)C(O)C1OC1C(O)C(O)C(O)C(C)O1 HVCOBJNICQPDBP-UHFFFAOYSA-N 0.000 claims description 2
- 229930186217 Glycolipid Natural products 0.000 claims description 2
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 claims description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
- 239000002530 phenolic antioxidant Substances 0.000 claims description 2
- 229940068041 phytic acid Drugs 0.000 claims description 2
- 235000002949 phytic acid Nutrition 0.000 claims description 2
- 239000000467 phytic acid Substances 0.000 claims description 2
- 229920003987 resole Polymers 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 235000016804 zinc Nutrition 0.000 claims description 2
- 239000003112 inhibitor Substances 0.000 claims 1
- 238000012545 processing Methods 0.000 abstract description 4
- 238000005536 corrosion prevention Methods 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- 238000005520 cutting process Methods 0.000 description 30
- 230000000052 comparative effect Effects 0.000 description 20
- 238000012360 testing method Methods 0.000 description 14
- 230000001050 lubricating effect Effects 0.000 description 12
- 239000002105 nanoparticle Substances 0.000 description 12
- 239000011259 mixed solution Substances 0.000 description 7
- 238000003801 milling Methods 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 description 5
- 239000011707 mineral Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 230000007547 defect Effects 0.000 description 4
- 238000001878 scanning electron micrograph Methods 0.000 description 4
- 231100000241 scar Toxicity 0.000 description 4
- 238000001514 detection method Methods 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 238000003912 environmental pollution Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 238000009210 therapy by ultrasound Methods 0.000 description 3
- HJVAFZMYQQSPHF-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;boric acid Chemical compound OB(O)O.OCCN(CCO)CCO HJVAFZMYQQSPHF-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 239000010687 lubricating oil Substances 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 230000003746 surface roughness Effects 0.000 description 2
- 208000032544 Cicatrix Diseases 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000000713 high-energy ball milling Methods 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000003879 lubricant additive Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 150000003109 potassium Chemical class 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 230000037387 scars Effects 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 239000011882 ultra-fine particle Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/085—Phosphorus oxides, acids or salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/087—Boron oxides, acids or salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/10—Compounds containing silicon
- C10M2201/105—Silica
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/12—Glass
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol or ester thereof; bound to an aldehyde, ketonic, ether, ketal or acetal radical
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/08—Amides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/022—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
- C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
- C10M2219/066—Thiocarbamic type compounds
- C10M2219/068—Thiocarbamate metal salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/061—Esters derived from boron
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/10—Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
本发明公开了一种基于黑磷量子点的低成本钛合金水基切削液及其制备方法，该切削液包括以下重量份的组分：黑磷量子点0.02~0.1份、纳米氧化物0.2~1.5份、分散剂2~7份、粘结剂3~5份、极压剂1~2份、防锈剂1~3份、抗氧化剂3~6份、去离子水75.4~89.8份。其制备方法是在去离子水中加入分散剂、粘结剂、防锈剂及极压剂，搅拌至各原料完全溶解后于温控磁力搅拌器上搅拌，温度升至80~100℃时加入黑磷量子点水溶液进行恒温搅拌，温度升至120~150℃时加入纳米氧化物，恒温搅拌60~90min水浴冷却至室温；加入抗氧化剂搅拌10~15min，水浴超声90~120min，最后调节pH值至8~10，即得目标物。本切削液具备适宜的粘度和优良的均匀性、稳定性、防锈防腐性、高温摩擦性能及良好的减磨性能，适用于钛合金加工。
Description
技术领域
本发明属于机械润滑技术领域，具体涉及一种基于黑磷量子点的低成本钛合金水基切削液及其制备方法。
背景技术
钛合金具有强度高、机械性能优异及良好的抗蚀性能成为航空航天中飞机及发动理想的材料，但钛合金切削加工性差，极大地制约了钛合金的应用。钛合金因为导热性差，在切削过程中产生的热量不会迅速传递给工件或被切屑带走，切削区域所产生的温度高达1000℃以上，使刀具的刃口迅速磨损、崩裂和生成积屑瘤，快速出现磨损的刀刃，又使切削区域产生更多的热量，进一步缩短刀具的寿命；钛合金使用温度在600℃以上时，表面会形成硬质氧化层，同时增加了刀具的表面磨损；除此之外钛合金切削过程中产生的切削易与刀具发生黏连，黏连的刀具再次切割工件时脱离并使得刀具产生损坏，最终形成崩刃，极大地降低了刀具的使用寿命。因此，开发一种适用于钛合金切削的切削液是极其重要的。
切削液包括矿物基及水基两类，其中，矿物基切削液虽具有润滑性能好的优点，但在切削过程中，随温度的升高，矿物基切削液的润滑性能会迅速下降。另外，矿物基润滑油在自然环境中可生物降解能力差，进入环境长期存在并最终富集，会产生环境污染，且其中含有一定的有毒或刺激性气味的物质，对人体有害。而水基切削液虽然具有优良的冷却性、清洗性、环保性和安全性等优点，但存在润滑性能差的问题。
本发明旨在提供一种适用于钛合金切削的润滑性能好的低成本新型切削液。
发明内容
本发明的第一目的在于提供一种基于黑磷量子点的低成本钛合金水基切削液，本发明的第二目的在于提供一种基于黑磷量子点的低成本钛合金水基切削液的制备方法。
本发明的第一目的是这样实现的，一种基于黑磷量子点的低成本钛合金水基切削液，包括以下重量份的组分：黑磷量子点0.02~0.1份、纳米氧化物0.2~1.5份、分散剂2~7份、粘结剂3~5份、稳定剂1~2份、极压剂1~2份、防锈剂1~3份、抗氧化剂3~6份、去离子水75.4~89.8份。
本发明的第二目的是这样实现的，一种基于黑磷量子点的低成本钛合金水基切削液的制备方法，具体方法如下：
按照上述质量配比称取原料，在去离子水中加入分散剂、粘结剂、防锈剂、稳定剂及极压剂，搅拌至各原料完全溶解于去离子水中得到基础液，将基础液于温控磁力搅拌器上搅拌，温度升至80~100℃时加入黑磷量子点水溶液，恒温搅拌60~90min；温度升至120~150℃时加入所述纳米氧化物，恒温搅拌60~90min，随后水浴冷却至室温；加入抗氧化剂搅拌10~15min，水浴超声90~120min，最后调节pH值至8~10，即得目标钛合金水基切削液。
本发明制备的切削液以黑磷量子点为主要的极压剂，再添加少量的纳米氧化物颗粒作为抗磨减磨剂，黑磷量子点独特的片层结构可以促进层间滑动减小摩擦，纳米氧化物颗粒如二氧化钛、二氧化硅等可以将滑动摩擦变为滚动摩擦进入起到很好的润滑效果，二者的添加产生协同润滑效应，有效的减少切削过程中的摩擦，从而减少刀具的磨损，本切削液的添加产生的润滑膜能有效缓解钛合金切削黏刀问题最终提高刀具的寿命。本发明切削液为水基切削液，在切削时水的蒸发可以带走热量，因而可以解决局部温度升高的问题，冷却效果好；另外，在钛合金切削过程中添加本发明切削液，产生的润滑膜可隔离刀具与切削件，从而减少可以有效缓解钛合金切削黏刀问题。
本发明切削液基础液中添加了醇类、酰胺类和磷酸酯等物质，使本切削液具有较好的消泡性，可以有效的降低切削液的表面张力，减少泡沫；另外，由于本切削液中黑磷量子点独特的结构及较低含量的磷元素添加剂，使本切削液的极压和抗磨性能得到了极大的提高，从而提高了本切削液的最大无卡咬负荷值。
本发明中，黑磷量子点的原料黑磷是通过高能球磨红磷转化而得，较现有技术其他方法，本发明中用于制备黑磷的原料—红磷成本低廉，且制备黑磷的周期较短，从而大大降低了生产成本；另外，本发明方法制备得到的黑磷量子点缺陷少、表面洁净，且量子点尺寸均一，且对环境污染较小，对操作人员伤害也较小，绿色安全。
本发明的有益效果为：
1）本发明钛合金水基切削液的制备方法简单易操作，其中，制备基础液的各原料可选择种类多、易获得，并且常温下进行混合搅拌即可制得，实用性强，易于扩大生产；另外，在制备过程中，各原料分开添加并充分搅拌使之溶解，使各原料如粘结剂分散均匀并与水充分混合，提高了溶液的均匀性及稳定性。
2）本发明首次在基础液中添加一定量的黑磷量子点及纳米氧化物颗粒来制备切削液，既提高了切削液的润滑性能，又避免了由于纳米氧化物颗粒的添加而造成其充当磨粒增加摩擦副的磨粒磨损的问题。
3）本切削液有效解决了钛合金切削过程中局部切削温度升高、切削刀具磨损严重、钛合金切削黏刀等问题，在提高刀具寿命的同时还解决了传统润滑剂对环境污染和对人体有害等问题，进而实现绿色生产的目标。
4）本切削液具备适宜的粘度和优良的均匀性、稳定性以及防锈防腐性能，还具有较好的高温摩擦性能及良好的减磨性能，适用于钛合金加工，值得进一步推广应用。
附图说明
图1为实施例7-9与对比例1的摩擦磨损曲线图；
图2为对比例1-3与实施例7的摩擦磨损曲线图；
图3为实施例7进行摩擦实验后的TC4盘磨痕的扫描电镜图片；
图4为对比例1进行摩擦实验后的TC4盘磨痕的扫描电镜图片；
图5为对比例2进行摩擦实验后的TC4盘磨痕的扫描电镜图片；
图6为对比例3进行摩擦实验后的TC4盘磨痕的扫描电镜图片。
具体实施方式
下面结合实施例对本发明作进一步的说明，但不以任何方式对本发明加以限制，基于本发明教导所作的任何变换或替换，均属于本发明的保护范围。
本发明一种基于黑磷量子点的钛合金水基切削液，包括以下重量份的组分：黑磷量子点0.02~0.1份、纳米氧化物0.2~1.5份、分散剂2~7份、粘结剂3~5份、极压剂1~2份、防锈剂1~3份、抗氧化剂3~6份、去离子水75.4~89.8份。
所述纳米氧化物为TiO2、SiO2、ZnO、CuO中的一种或多种的组合物。
所述纳米氧化物的粒径为50~100nm。
所述极压剂为磷酸酯、水基硼酸酯、硫化烯烃、二聚酸钾、三乙醇胺硼酸酯中的任意两种或两种以上的组合。
所述粘结剂为丙三醇、油酸、硼酸盐、水玻璃、聚乙烯醇、甲阶酚醛树脂、聚环氧乙烯中的任意两种或两种以上的组合。
所述分散剂为十二烷基苯磺酸钠、六偏磷酸钠、聚乙二醇、十二烷基磺酸钠、三聚磷酸、硬脂酸盐中的任意两种或两种以上的组合，以提高黑磷量子点和纳米氧化物颗粒在水基切削液中的分散稳定性。
所述抗氧化剂为硼砂、三聚磷酸钠、二烷基二硫代磷酸锌、酚类抗氧化剂、胺类抗氧化剂、二烷基二硫代氨基甲酸盐中一种或多种的组合。
所述防锈剂为单乙醇胺、二乙醇胺、三乙醇胺、酰胺、烷基醇酰胺、硅烷偶联剂、糖脂、季戊四醇、肌醇六磷酸酯中任意一种或多种的组合。
本发明一种基于黑磷量子点的钛合金水基切削液的制备方法，具体方法如下：
按照上述质量配比称取原料，在去离子水中加入分散剂、粘结剂、防锈剂及极压剂，搅拌至各原料完全溶解于去离子水中得到基础液，将基础液于温控磁力搅拌器上搅拌，温度升至80~100℃时加入黑磷量子点水溶液，恒温搅拌60~90min；温度升至120~150℃时加入所述纳米氧化物，恒温搅拌60~90min，随后水浴冷却至室温；加入抗氧化剂搅拌10~15min，水浴超声90~120min，最后调节pH值至8~10，即得目标钛合金水基切削液。
所述混合液于温控磁力搅拌器的搅拌速度为60~100转/分钟。
所述基础液制备方法如下：所述基础液制备方法如下：将分散剂加入到去离子水中，搅拌10~15min至完全溶解，再加入粘结剂中的一种、防锈剂及稳定剂，搅拌10~15min后，再加入其他粘结剂，分别搅拌5~10min，最后加入极压剂，搅拌15~30min即得基础液。
所述黑磷量子点水溶液的制备方法如下：将黑磷粉末溶于有机溶剂中混匀后，加入氧化锆球磨罐中，转速450-580r/min球磨20~60h，球磨后得到的产物在转速1500~3000rpm条件下离心15~30min，上清液在10000~15000rpm下离心15~30min，取沉淀物用去离子水清洗2~3次后得到黑磷量子点水溶液。
所述黑磷量子点水溶液中黑磷量子点的质量分数为0.1%-1%。
所述黑磷粉末采用高能球磨红磷转化为黑磷的方法制备而得，具体方法如下：将红磷粉末与直径为10~20mm的氧化锆小球按照球料比为30:1~60:1混合，在真空密封条件下以1000~1250r/min球磨0.5~3h，即得黑磷粉末。
所述有机溶剂为N-甲基吡咯烷酮或二甲基亚砜或乙醇有机溶剂为N-甲基吡咯烷酮或二甲基亚砜或乙醇。
所述水浴超声的功率为100W，超声频率20~30HZ，以使黑磷量子点均匀分散，防止团聚。
实施例1
将2g红磷粉末与直径为10~20mm的氧化锆小球按照球料比为30:1混合，在真空密封条件下以1000r/min球磨3h，得到1.5~1.8g 黑磷粉末。称取黑磷粉末50mg与50mL的N-甲基吡咯烷酮混合加入氧化锆球磨罐中，转速450r/min球磨60h，球磨后得到的产物在转速1500rpm条件下离心30min，取离心后的上清液在转速15000rpm条件下再次离心15min，将离心得到的沉淀物用去离子水清洗3次后得到5ml缺陷少、表面洁净，且量子点尺寸均一的黑磷量子点水溶液。
实施例2
将2g红磷粉末与直径为10~20mm的氧化锆小球按照球料比为60:1混合，在真空密封条件下以1250r/min球磨0.5h，得到1.5~1.8g黑磷粉末。称取黑磷粉末100mg与50mL二甲基亚砜混合加入氧化锆球磨罐中，转速580r/min球磨20h，球磨后得到的产物在转速3000rpm条件下离心15min，取离心后的上清液在转速10000rpm条件下再次离心30min，将离心得到的沉淀物用去离子水清洗2次后得到8ml 缺陷少、表面洁净，且量子点尺寸均一的黑磷量子点水溶液。
实施例3
将2g红磷粉末与直径为10~20mm的氧化锆小球按照球料比为40:1混合，在真空密封条件下以1200r/min球磨2h，得到1.5~1.8g 黑磷粉末。称取黑磷粉末80mg与50mL无水乙醇混合加入氧化锆球磨罐中，转速500r/min球磨40h，球磨后得到的产物在转速2000rpm条件下离心20min，取离心后的上清液在转速12000rpm条件下再次离心20min，将离心得到的沉淀物用去离子水清洗2~3次后得到10ml缺陷少、表面洁净，且量子点尺寸均一的黑磷量子点水溶液。
实施例4
一种低成本黑磷量子点的钛合金水基切削液，包括以下组分(重量比)：其中黑磷量子点0.1份、TiO2纳米颗粒1.5份、分散剂7份、粘结剂5份、极压剂2份、防锈剂3份、抗氧化剂6份、去离子水75.4份。
实施例5
一种低成本黑磷量子点的钛合金水基切削液，包括以下组分(重量比)：其中黑磷量子点0.02份、SiO2纳米颗粒与CuO纳米颗粒各0.1份、分散剂2份、粘结剂3份、极压剂1份、防锈剂1份、抗氧化剂3份、去离子水89.8份。
实施例6
一种低成本黑磷量子点的钛合金水基切削液，包括以下组分(重量比)：其中黑磷量子点0.05份、ZnO纳米颗粒1份、分散剂5份、粘结剂4份、极压剂1.5份、防锈剂2份、抗氧化剂5份、去离子水81.5份。
实施例7
按照实施例4中的切削液原料配比将3份十二烷基苯磺酸钠和4份硬脂酸盐加入到去离子水中，搅拌10~15min后，加入3份丙三醇和3份三乙醇胺，搅拌10~15min，使其完全溶解；再加入2份油酸，搅拌10min，完全溶解后，加入1份磷酸酯和1份二聚酸钾，搅拌30min使完全溶解得到基础液；将基础液置于转速为100转/分钟的温控磁力搅拌器上搅拌，当温度达到100℃时加入加入实施例1制备得到的黑磷量子点水溶液，恒温持续搅拌90min，升温到150℃时加入TiO2纳米颗粒，恒温搅拌90min，加入6份三聚磷酸钠，搅拌10~15min使之完全溶解得到混合溶液；将混合溶液以30HZ频率、100W功率于水浴中超声120min，使黑磷量子点均匀分散，防止团聚，随后调节pH值至8，最终得到基于黑磷量子点的钛合金水基切削液。
实施例8
按照实施例5中的切削液配比将1份六偏磷酸钠和1份三聚磷酸加入到去离子水中，搅拌10min使之完全溶解后，加入1份水玻璃和1份烷基醇酰胺，搅拌10min使之完全溶解后，加入2份硼酸盐搅拌5min，待硼酸盐完全溶解后，加入1份三乙醇胺硼酸酯和0.5份磷酸酯，搅拌15min使完全溶解得到基础液，将基础液溶液置于转速为60转/分钟的温控磁力搅拌器上搅拌，当温度达到80℃时加入实施例2制备得到的黑磷量子点水溶液，恒温持续搅拌60min，升温到120℃时加入SiO2与CuO纳米颗粒，恒温搅拌60min，加入5份二烷基二硫代氨基甲酸盐，搅拌10~15min使之完全溶解得到混合溶液；将混合溶液以20HZ频率、100W功率于水浴中超声90min，使黑磷量子点均匀分散，随后调节pH值至8，最终得到基于黑磷量子点的钛合金水基切削液。
实施例9
按照实施例6中的切削液配比将2份聚乙二醇、2份十二烷基苯磺酸钠和1份三聚磷酸加入到去离子水中，搅拌13min，完全溶解后加入2份聚乙烯醇和2份硅烷偶联剂，搅拌13min，使其完全溶解后加入2份聚环氧乙烯，搅拌8min，完全溶解后加入0.5份二聚酸钾、0.5份水基硼酸脂和0.5份硫化烯烃，搅拌24min，完全溶解后得到基础液，将基础液放在转速为80转/分钟的温控磁力搅拌器上搅拌，当温度达到90℃时加入实施例3制备的黑磷量子点水溶液，恒温持续搅拌75min，升温到135℃时加入ZnO纳米颗粒，恒温搅拌75min，加入2份硼砂和3份二烷基二硫代氨基甲酸盐，搅拌13min完全溶解得到混合溶液；将混合溶液以25HZ频率、100W功率于水浴中超声105min，使黑磷量子点均匀分散，随后调节pH值至8，最终得到基于黑磷量子点的钛合金水基切削液。
对比例1
本对比例不添加任何润滑添加剂及润滑辅助剂，做为实施例7的空白对照。
对比例2
本对比例与实施例7相比，未添加黑磷量子点，除此外的组分及制备方法均相同。
对比例3
本对比例与实施例7相比，未添加TiO2纳米颗粒，除此外的组分及制备方法均相同。
检测例 水基切削液性能检测
1、摩擦系数检测
将实施例7~9、对比例2-3制备的水基切削液进行性能测试，检测方法如下：选用摩擦磨损试验机MS-T3001，摩擦副分别为GCr15轴承钢球和TC4钛合金盘。固定参数为：载荷10N，转速150r/min，旋转直径6mm。实验前分别石油醚和乙醇超声清洗摩擦副，使其表面光洁。待装好试样后，向TC4盘上逐滴滴上少量水基切削液，启动机器旋转，测试时间30min后，试验停止，记录相关摩擦系数曲线；将对比例1进行干摩擦测试，测试方法同上述，不同之处是装好试样后，在TC4盘上不添加任何物质，直接启动机器旋转，测试时间30min后，试验停止，记录相关摩擦系数曲线。检测结果如图1和图2所示。
2、摩擦副表面微观形貌
将实施例7、对比例1-3摩擦实验后的摩擦副表面进行扫描，得到微观形貌扫描图，如图3-6所示。
结果分析：
从图1可知，与对比例1即干摩擦相比，实施例7-9中，由于切削液的添加从而使得摩擦系数大幅度降低。说明本发明方法制备的切削液具有较好的润滑性能，其中，实施例9是所制备的切削液中润滑性能相对最好的切削液。
从图2可知，对比例1即未添加任何物质（干摩擦）的平均摩擦系数相对较高；未添加黑磷量子点的切削液（对比例1）和未添加氧化物纳米颗粒（对比例2）的切削液摩擦系数二者差别不大，变化趋势类似，相对干摩擦（对比例1）有所降低；而添加了实施例7制备的切削液的平均摩擦系数较对比例2-3均有明显降低。
对比摩擦磨损后的微观形貌（图3-6）可以看出，添加了实施例7制备的切削液的摩擦副表面相对平滑，犁沟较浅，磨痕相对较浅；未添加任何物质的摩擦副表面粗糙，具有较深的磨痕；未添加黑磷量子点的磨痕相对较深，而添加黑磷量子点未添加氧化物纳米颗粒的切削液摩擦副表面比未添加黑磷量子点的犁沟浅，摩擦副表面相对较为平滑，说明黑磷量子点的添加能有效的改善摩擦磨损，而黑磷量子点和氧化物纳米颗粒复合后具有更优的摩擦性能。
3、黑磷量子点水基切削液性能指标检测
对实施例7-9制备的黑磷量子点水基切削液的各项性能指标进行检测，检测结果见表1。
表1：实施例7~9制备的黑磷量子点水基切削液性能指标
从表1可知，本发明制备的水基切削液各项性能指标都较优。
4、切削性能测试
选取实施例9制备的黑磷量子点水基切削液与现有工业用切削液进行切削液铣削测试，具体切削液铣削数据对比见表2。
具体方法：
加工材料：TC4钛合金；刀具材质：UMG级超细微粒钨钢，Co=12，粒径0.4μm，刀具直径φ12，四齿；转速1800rad/min；吃刀量0.5mm，铣削面积0.0235m2。
表2不同切削液铣削对比
从表2可知，实施例9制备的切削液在铣削时铣削面粗糙度明显低于现有工业用切削液，且平均切削力也有所降低。低铣削面粗糙度说明采用该切削液有利于得到更好的加工表面质量，较低的平均切削力表明切削过程中对刀具的损耗有所降低。
Claims (9)
1.一种基于黑磷量子点的钛合金水基切削液，其特征在于，原料包括重量份的黑磷量子点0.02~0.1份、纳米氧化物0.2~1.5份、分散剂2~7份、粘结剂3~5份、极压剂1~2份、防锈剂1~3份、抗氧化剂3~6份、去离子水75.4~89.8份；制备方法具体为：按照质量配比称取原料，在去离子水中加入分散剂、粘结剂、防锈剂及极压剂，搅拌至各原料完全溶解于去离子水中得到基础液，将基础液于温控磁力搅拌器上搅拌，温度升至80~100℃时加入黑磷量子点水溶液，恒温搅拌60~90min；温度升至120~150℃时加入所述纳米氧化物，恒温搅拌60~90min，随后水浴冷却至室温；加入抗氧化剂搅拌10~15min，水浴超声90~120min，最后调节pH值至8~10，即得所述钛合金水基切削液。
2.根据权利要求1所述基于黑磷量子点的钛合金水基切削液，其特征在于，所述纳米氧化物为TiO2、SiO2、ZnO、CuO中的一种或多种的组合物。
3.根据权利要求1所述基于黑磷量子点的钛合金水基切削液，其特征在于，所述纳米氧化物的粒径为50~100nm。
4.根据权利要求1所述基于黑磷量子点的钛合金水基切削液，其特征在于，所述极压剂为磷酸酯、水基硼酸酯、硫化烯烃、二聚酸钾、三乙醇胺硼酸酯中的任意两种或两种以上的组合；所述粘结剂为丙三醇、油酸、硼酸盐、水玻璃、聚乙烯醇、甲阶酚醛树脂、聚环氧乙烯中的任意两种或两种以上的组合；所述分散剂为十二烷基苯磺酸钠、六偏磷酸钠、聚乙二醇、十二烷基磺酸钠、三聚磷酸、硬脂酸盐中的任意两种或两种以上的组合；所述抗氧化剂为硼砂、三聚磷酸钠、二烷基二硫代磷酸锌、酚类抗氧化剂、胺类抗氧化剂、二烷基二硫代氨基甲酸盐中的任意1~2种的组合；所述防锈剂为单乙醇胺、二乙醇胺、三乙醇胺、酰胺、烷基醇酰胺、硅烷偶联剂、糖脂、季戊四醇、肌醇六磷酸酯中任意一种或多种的组合。
5.根据权利要求1所述基于黑磷量子点的钛合金水基切削液，其特征在于，所述基础液于温控磁力搅拌器的搅拌速度为60~100r/min。
6.根据权利要求1或5所述基于黑磷量子点的钛合金水基切削液，其特征在于，所述基础液制备方法如下：将分散剂加入到去离子水中，搅拌10~15min至完全溶解，再加入粘结剂中的一种、防锈剂，搅拌10~15min后，再加入其他粘结剂，分别搅拌5~10min，最后加入极压剂，搅拌15~30min即得基础液。
7.根据权利要求1所述基于黑磷量子点的钛合金水基切削液，其特征在于，所述黑磷量子点水溶液的制备方法如下：将黑磷粉末溶于有机溶剂中混匀后，于氧化锆球磨罐中以450-580r/min转速球磨20~60h，球磨后得到的产物在1500~3000rpm转速下离心15~30min，上清液在10000~15000rpm下离心15~30min，取沉淀物用去离子水清洗2~3次后得到黑磷量子点水溶液。
8.根据权利要求7所述基于黑磷量子点的钛合金水基切削液，其特征在于，黑磷粉末的制备方法如下：将红磷粉末与直径为10~20mm的氧化锆小球按照球料比为30:1~60:1混合，在真空密封条件下以1000~1250r/min球磨0.5~3h，即得黑磷粉末。
9.根据权利要求7所述基于黑磷量子点的钛合金水基切削液，其特征在于，所述有机溶剂为N-甲基吡咯烷酮或二甲基亚砜或乙醇。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110298122.3A CN113122361B (zh) | 2021-03-19 | 2021-03-19 | 一种基于黑磷量子点的低成本钛合金水基切削液及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110298122.3A CN113122361B (zh) | 2021-03-19 | 2021-03-19 | 一种基于黑磷量子点的低成本钛合金水基切削液及其制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN113122361A CN113122361A (zh) | 2021-07-16 |
| CN113122361B true CN113122361B (zh) | 2022-07-12 |
Family
ID=76773626
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110298122.3A Active CN113122361B (zh) | 2021-03-19 | 2021-03-19 | 一种基于黑磷量子点的低成本钛合金水基切削液及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113122361B (zh) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106479657A (zh) * | 2016-09-18 | 2017-03-08 | 清华大学天津高端装备研究院 | 一种水基全合成钛合金切削液 |
| US20170174516A1 (en) * | 2015-12-18 | 2017-06-22 | Shenzhen Institutes Of Advanced Technology | Titanium ligand-modified black phosphorus and preparation method and use thereof |
| CN110040703A (zh) * | 2019-04-23 | 2019-07-23 | 清华大学 | 一种羟基化黑磷量子点水基溶液的制备方法和应用 |
| CN110157516A (zh) * | 2019-06-27 | 2019-08-23 | 合肥工业大学 | 纳米二氧化钛/黑磷纳米片复合润滑剂及其制备方法 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110229667B (zh) * | 2019-05-29 | 2022-01-11 | 商丘师范学院 | 一种黑磷量子点、二氧化钛黑磷量子点复合材料及其制备方法和应用 |
-
2021
- 2021-03-19 CN CN202110298122.3A patent/CN113122361B/zh active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20170174516A1 (en) * | 2015-12-18 | 2017-06-22 | Shenzhen Institutes Of Advanced Technology | Titanium ligand-modified black phosphorus and preparation method and use thereof |
| CN106479657A (zh) * | 2016-09-18 | 2017-03-08 | 清华大学天津高端装备研究院 | 一种水基全合成钛合金切削液 |
| CN110040703A (zh) * | 2019-04-23 | 2019-07-23 | 清华大学 | 一种羟基化黑磷量子点水基溶液的制备方法和应用 |
| CN110157516A (zh) * | 2019-06-27 | 2019-08-23 | 合肥工业大学 | 纳米二氧化钛/黑磷纳米片复合润滑剂及其制备方法 |
Non-Patent Citations (2)
| Title |
|---|
| Tribological behavior of black phosphorus nanosheets as water-based lubrication additives;Wang Qingjuan, et al.;《Friction》;20210131;第10卷(第3期);第374-387页 * |
| Tribological properties of black phosphorus nanosheets as oil-based lubricant additives for titanium alloy-steel contacts;Qingjuan Wang, et al.;《royal society open science》;20200916;第7卷;第1-12页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN113122361A (zh) | 2021-07-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Gulzar et al. | Tribological performance of nanoparticles as lubricating oil additives | |
| Rawat et al. | Tribological performance of paraffin grease with silica nanoparticles as an additive | |
| Ouyang et al. | 3D hierarchical porous graphene nanosheets as an efficient grease additive to reduce wear and friction under heavy-load conditions | |
| Shafi et al. | Tribological performance of avocado oil containing copper nanoparticles in mixed and boundary lubrication regime | |
| CN113046163B (zh) | 一种超低摩擦系数水基切削润滑液 | |
| Gupta et al. | Tribological study on rapeseed oil with nano-additives in close contact sliding situation | |
| US20240240103A1 (en) | Graphene-based lubricant additives and lubricants | |
| CN108624389B (zh) | 一种氧化石墨烯水基纳米润滑剂及其制备方法 | |
| Peng et al. | The tribological behavior of modified diamond nanoparticles in liquid paraffin | |
| Pisal et al. | Experimental investigation of tribological properties of engine oil with CuO nanoparticles | |
| CN111171936A (zh) | 一种纳米二氧化钛修饰的氧化石墨烯轧制液及制备方法 | |
| Huang et al. | Roughness-dependent tribological characteristics of water-based GO suspensions with ZrO2 and TiO2 nanoparticles as additives | |
| Singh et al. | Chemical modification of juliflora oil with trimethylolpropane (TMP) and effect of TiO2 nanoparticles concentration during tribological investigation | |
| JP7329375B2 (ja) | 摺動部材および摺動部材の製造方法 | |
| CN113122361B (zh) | 一种基于黑磷量子点的低成本钛合金水基切削液及其制备方法 | |
| Patil et al. | Tribological properties of SiO2 nanoparticles added in SN-500 base oil | |
| Wang et al. | Friction-induced motion evolution of reduced graphene oxide-Al2O3 at contact interface to achieve superior lubrication performance | |
| Ajay Vardhaman et al. | Experimental investigations to enhance the tribological performance of engine oil by using nano-boric acid and functionalized multiwalled carbon nanotubes: A comparative study to assess wear in bronze alloy | |
| Opia et al. | Effect of surfactants on the tribological behavior of organic carbon nanotubes particles additive under boundary lubrication conditions | |
| CN113980545A (zh) | 一种聚醚醚酮/黑磷自润滑复合涂层、复合材料及其制备方法 | |
| CN116496825A (zh) | 一种抗磨减摩润滑油添加剂及使用该添加剂的改性润滑油 | |
| Li et al. | Novel preparation of calcium borate/graphene oxide nanocomposites and their tribological properties in oil | |
| Tsiganov et al. | Synthesis, structure and tribological properties of nanocomposite materials in the system of potassium polytitanate–layered double hydroxide–serpentinite | |
| CN112574804B (zh) | 一种钛合金轧制用黑磷烯水基润滑液及其制备方法 | |
| CN102492523A (zh) | 一种混合纳米润滑脂添加剂及其应用 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240320 Address after: Room 033, F2003, 20th Floor, Building 4-A, Xixian Financial Port, Fengdong New City Energy Jinmao District, Xixian New District, Xi'an City, Shaanxi Province, 710086 Patentee after: Shaanxi Titanium Super Run New Material Technology Co.,Ltd. Country or region after: Zhong Guo Address before: 710055 No. 13, middle section, Yanta Road, Shaanxi, Xi'an Patentee before: XIAN University OF ARCHITECTURE AND TECHNOLOG Country or region before: Zhong Guo |