CN113105698A - Wear-resistant material with thermal response and self-lubricating performance and preparation method thereof - Google Patents

Wear-resistant material with thermal response and self-lubricating performance and preparation method thereof Download PDF

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CN113105698A
CN113105698A CN202110360110.9A CN202110360110A CN113105698A CN 113105698 A CN113105698 A CN 113105698A CN 202110360110 A CN202110360110 A CN 202110360110A CN 113105698 A CN113105698 A CN 113105698A
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fluid
wear
self
resistant material
lubricating
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CN113105698B (en
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殷先泽
申晖
杨诗文
王罗新
王桦
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Wuhan Textile University
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Wuhan Textile University
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C08K3/041—Carbon nanotubes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C08K3/042—Graphene or derivatives, e.g. graphene oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Lubricants (AREA)

Abstract

The invention relates to a wear-resistant material with thermal response and self-lubricating property and a preparation method thereof, and the method comprises the following steps: 1. dissolving a high polymer and a nano fluid prepared by an ion exchange method into an organic mixed solvent, and uniformly stirring to obtain a mixed solution, wherein the mass concentration of the nano fluid in the mixed solution is 10-30%, and the mass concentration of the high polymer is 10-30%; 2. and injecting the mixed solution into a mold, and air-drying at room temperature to obtain the wear-resistant material with thermal response and self-lubricating property. The inorganic-organic combined special structure of the nano fluid is utilized, so that inorganic particles in the lubricating film can isolate direct contact of a friction pair to reduce loss of the friction pair, and meanwhile, the self-repairing function of surface scratches is also filled, so that the wear-resistant material has thermal response and self-lubricating performance, namely lubricating substances can be secreted automatically in the using process, additional lubricating liquid is not needed, the use is convenient, and the wear-resistant effect is good.

Description

Wear-resistant material with thermal response and self-lubricating performance and preparation method thereof
Technical Field
The invention relates to the field of wear-resistant materials, in particular to a wear-resistant material with thermal response and self-lubricating performance and a preparation method thereof.
Background
Along with the development of industry and the increasing of people's demand, the promotion of output has proposed more efficient requirement to the production and processing of machine, friction widely exists in industrial production as a common physical phenomenon, the existence of frictional force leads to the transfer of the object surface product thing of interact, cause the loss of mechanical contact surface, the ageing unnecessary consumption that causes manpower and materials of having accelerated machinery, manufacturing cost has been improved, bring adverse effect for industrial production, call for responding to the environmental protection simultaneously for solving this problem, it is imperative that the energy consumption is reduced to promote mechanical wearability increase of service life. The original mechanical lubricity and wear resistance are improved mainly by adding a lubricant between friction surfaces to achieve the lubricating effect, and the lubricating layer is required to be continuously added to a friction center due to the loss of the lubricant caused by the operation and extrusion of machinery, so that the mechanical self-lubrication cannot be realized, and the working efficiency is low. The polymer with good tribology performance and lower cost is gradually developed in the field of lubrication, the mechanical property of the polymer is weak, a low friction mechanism of solid lubrication of the polymer relates to failure of an internal interface, the polymer can be enhanced by introducing the inorganic nanoparticles, the modified inorganic nanoparticles have a lubricating effect and zero vapor pressure, the nanoparticles can be used as a stressed support, the mutual contact of friction pairs is isolated, the abrasion of the friction pairs is reduced, the polymer has the function of in-situ wear repair, and the polymer is a good lubricant.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides a wear-resistant material with thermal response and self-lubricating property and a preparation method thereof.
The technical scheme for solving the technical problems is as follows:
the preparation method of the wear-resistant material with thermal response and self-lubricating performance comprises the following steps:
step 1, dissolving a high polymer and a nano fluid prepared by an ion exchange method in an organic solvent, and uniformly stirring to obtain a mixed solution, wherein the mass concentration of the nano fluid in the mixed solution is 10-30%, and the mass concentration of the high polymer is 10-30%;
and 2, injecting the mixed solution into a mold, and airing at room temperature to obtain the wear-resistant material with thermal response and self-lubricating performance.
Further, the polymer in step 1 is any one of polystyrene, polymethyl methacrylate and polyvinylidene fluoride.
Further, the nano fluid prepared by the ion exchange method in the step 2 adopts halloysite fluid and SiO2Fluid like, TiO2Any one of the quasi-fluid and the graphene-based fluid.
The wear-resistant material with thermal response and self-lubricating property is prepared by any one of the methods.
The invention has the beneficial effects that: the solid surface has the tendency of reducing the surface energy, the Brownian motion of fluid as a substance with lower surface energy is accelerated under the thermal stimulation, more nano-fluid is gathered on the solid surface to play a lubricating role, and the inorganic-organic combined special structure of the nano-fluid ensures that inorganic particles in the lubricating film can isolate the direct contact of a friction pair to reduce the loss of the friction pair and also has the function of filling up the surface scratches and self-repairing.
Drawings
FIG. 1 is a flow chart of the preparation of a fluid-like body;
FIG. 2 is a scanning electron micrograph of the present invention before heat treatment;
FIG. 3 is a scanning electron micrograph of the present invention after heat treatment;
FIG. 4 shows the addition of SiO2And (3) comparing the friction coefficient of the PMMA material after the nano fluid is processed with that of a pure PMMA material.
FIG. 5 shows a nano-fluid SiO2Transmission electron microscopy of DC 5700-NPES.
Detailed Description
The principles and features of this invention are described below in conjunction with examples which are set forth to illustrate, but are not to be construed to limit the scope of the invention.
The preparation method of the wear-resistant material with thermal response and self-lubricating performance comprises the following steps:
step 1, dissolving a high polymer and a nano fluid prepared by an ion exchange method in an organic solvent, and uniformly stirring to obtain a mixed solution, wherein the mass concentration of the nano fluid in the mixed solution is 10-30%, and the mass concentration of the high polymer is 10-30%;
and 2, injecting the mixed solution into a mold, and airing at room temperature to obtain the wear-resistant material with thermal response and self-lubricating performance.
In one embodiment, the polymer in step 1 is any one of polystyrene, polymethyl methacrylate and polyvinylidene fluoride.
As an embodiment, the nano-fluid prepared by the ion exchange method in step 2 is halloysite fluid or SiO2Fluid like, TiO2Any one of the quasi-fluid and the graphene-based fluid.
The wear-resistant material with thermal response and self-lubricating performance is prepared by any one of the methods.
The nano fluid prepared by the ion exchange method can be SiO2、TiO2Carbon black, carbon nanotubes, halloysite, graphene, and other nano-fluids. As shown in FIG. 1, SiO used in this example2The preparation flow chart of the nano fluid is characterized in that the fluid is prepared by adopting an ion exchange method, DC5700 is grafted on the surface of the silicon dioxide nano particle through a covalent bond, and then NPES is grafted through an ion exchange mode. Due to the low surface energy and thermal responsiveness of the nano-class fluid, the nano-class fluid has a tendency to migrate to the surface of the polymer film under thermal stimulation. In the friction process, the generated heat induces the similar fluid to migrate out of the interior of the polymer to supplement the lubricant in time, so that the friction pair is protected, and the energy loss caused by friction is reduced. As shown in FIG. 4, SiO is added to FIG. 42The friction coefficient of the PMMA material added with the nano fluid is obviously reduced compared with that of the pure PMMA material.
The surface appearances of PS and PMMA doped fluid and un-doped fluid after film forming are shown in FIG. 2, the observation of the surface appearances shows that the fluid content of the PMMA surface is more than that of PS, the polarity of PMMA is greater than that of PS, the surface energy of PMMA is greater than that of PS, more fluid is adsorbed on the surface of solid in order to reduce the surface energy, meanwhile, benzene rings in PS molecules block the migration of the fluid, so that the fluid content of the PMMA surface is more than that of PS, and the effect of controlling the fluid release speed can be achieved by applying substrates with different polarities.
As can be seen from fig. 3, the surface morphology of the PS and PMMA doped fluid and undoped fluid after the film formation and the heat treatment, fluid particles appear on the PS surface without fluid particles originally, indicating that the fluid has responsiveness to heat.
The higher the class fluid concentration is, the thicker the lubricating layer is, different types of class fluids have different functions simultaneously, silicon dioxide can play the reinforcing effect, titanium dioxide class fluid plays the effect of absorbing ultraviolet rays, halloysite has better adsorption performance, can adsorb the carbon that the friction produced, the expansion of microcrack in the combined material can effectually be hindered to graphite oxide class fluid, has higher thermal conductivity to help the heat loss that the friction in-process produced simultaneously. Therefore, different fluid-like preparations can be selected according to the use scene of the wear-resistant material.
As shown in FIG. 4, it can be seen that after the polymer PMMA substrate is rubbed for 1800s under the action of 50N, the friction coefficient of the polymer PMMA substrate doped with 10 wt% of DC5700-NPES organic matter is reduced by 6.9% compared with that of the undoped polymer substrate, the friction coefficient of the polymer PMMA substrate doped with 30 wt% of DC5700-NPES organic matter is reduced by 8.6%, and the friction coefficient of the polymer PMMA substrate doped with 30% of organic matter is reduced by only 1.7% compared with that of the polymer PMMA substrate doped with 10% of organic matter. It shows that the friction coefficient of the polymer film is reduced with the increase of the content of the organic matters, but the pure organic matters have little effect on improving the friction performance of the polymer. When 5 wt% of SiO containing inorganic substance is added to the polymer2At DC5700-NPES, the coefficient of friction of the film is reduced by 62.1% compared with that of the undoped polymer; when 50 wt% SiO is added to the polymer2The friction coefficient at DC5700-NPES decreased by 75.9%. The coefficient of friction of the fluid-like polymer at 50 wt.% was reduced by 13.8% compared to the fluid-like polymer at 5 wt.%, when this was done with SiO2Increased coefficient of friction reduction of the content of-DC 5700-NPES, and also indicates fluid-like SiO2The DC5700-NPES has more advantages in improving the friction performance of the polymer compared with the pure organic DC5700-NPES, and the friction coefficient of the polymer is reduced along with the increase of the content of the fluid-like substance, and the friction performance is enhanced along with the increase of the content of the fluid-like substance. In general, fluid-like SiO with inorganic core2The advantageous application of DC5700-NPES compared to organic DC5700-NPES is to improve the tribological properties of polymers.
FIG. 5 shows a nano-fluid SiO2Transmission Electron microscopy of DC5700-NPES, monodisperse at the microscopic level, indicating that we are dealing with nano-SiO2The modification prevents the agglomeration of the nano particles, so that the nano particles can be better dispersed in a polymer matrix, and the influence of mechanical property damage caused by easy agglomeration of the nano particles is improved.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that fall within the spirit and principle of the present invention are intended to be included therein.

Claims (4)

1. The preparation method of the wear-resistant material with thermal response and self-lubricating performance is characterized by comprising the following steps of:
step 1, dissolving a high polymer and a nano fluid prepared by an ion exchange method in an organic solvent, and uniformly stirring to obtain a mixed solution, wherein the mass concentration of the nano fluid in the mixed solution is 10-30%, and the mass concentration of the high polymer is 10-30%;
and 2, injecting the mixed solution into a mold, and airing at room temperature to obtain the wear-resistant material with thermal response and self-lubricating performance.
2. The method for preparing a wear-resistant material with thermal response and self-lubricating property as claimed in claim 1, wherein the high polymer in step 1 is any one of polystyrene, polymethyl methacrylate and polyvinylidene fluoride.
3. The method for preparing a wear-resistant material with thermal response and self-lubricating property according to claim 1, wherein the nano-fluid prepared by the ion exchange method in the step 2 is halloysite fluid or SiO fluid2Fluid like, TiO2Any one of the quasi-fluid and the graphene-based fluid.
4. A wear resistant material having thermal response and self-lubricating properties, characterized by being prepared by the method of any one of the preceding claims 1 to 3.
CN202110360110.9A 2021-04-02 2021-04-02 Wear-resistant material with thermal response and self-lubricating performance and preparation method thereof Active CN113105698B (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4289859A (en) * 1980-06-02 1981-09-15 Dow Corning Corporation Non-bleeding transparent silicone additives for plastics
US20050123758A1 (en) * 2001-12-28 2005-06-09 Farshad Ghasripoor Self-lubricating plastics material for sealing elements
CN103602040A (en) * 2013-11-25 2014-02-26 大连路阳科技开发有限公司 Self-lubricating wear-resistant polyether-ether-ketone slip sheet and formula and preparation method thereof
CN105131333A (en) * 2015-09-21 2015-12-09 武汉纺织大学 Preparation method of carbon black fluid
CN108085089A (en) * 2017-12-07 2018-05-29 中国科学院兰州化学物理研究所 A kind of solvent-free silica nanometer class fluid and its application
CN108102138A (en) * 2016-11-24 2018-06-01 刘芳 A kind of MoS2- PMMA nanocomposites
CN109727787A (en) * 2018-12-26 2019-05-07 东北林业大学 A kind of polyarylether nanometer class fluid polymer electrolyte preparation method
CN111662547A (en) * 2020-06-09 2020-09-15 陕西科技大学 Molybdenum disulfide quantum dot/graphene/polymer-based super-wear-resistant self-lubricating composite material and preparation method and application thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4289859A (en) * 1980-06-02 1981-09-15 Dow Corning Corporation Non-bleeding transparent silicone additives for plastics
US20050123758A1 (en) * 2001-12-28 2005-06-09 Farshad Ghasripoor Self-lubricating plastics material for sealing elements
CN103602040A (en) * 2013-11-25 2014-02-26 大连路阳科技开发有限公司 Self-lubricating wear-resistant polyether-ether-ketone slip sheet and formula and preparation method thereof
CN105131333A (en) * 2015-09-21 2015-12-09 武汉纺织大学 Preparation method of carbon black fluid
CN108102138A (en) * 2016-11-24 2018-06-01 刘芳 A kind of MoS2- PMMA nanocomposites
CN108085089A (en) * 2017-12-07 2018-05-29 中国科学院兰州化学物理研究所 A kind of solvent-free silica nanometer class fluid and its application
CN109727787A (en) * 2018-12-26 2019-05-07 东北林业大学 A kind of polyarylether nanometer class fluid polymer electrolyte preparation method
CN111662547A (en) * 2020-06-09 2020-09-15 陕西科技大学 Molybdenum disulfide quantum dot/graphene/polymer-based super-wear-resistant self-lubricating composite material and preparation method and application thereof

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