CN113097530B - Improved connecting piece for flat-plate solid oxide fuel cell stack and thermal management method - Google Patents
Improved connecting piece for flat-plate solid oxide fuel cell stack and thermal management method Download PDFInfo
- Publication number
- CN113097530B CN113097530B CN202110356055.6A CN202110356055A CN113097530B CN 113097530 B CN113097530 B CN 113097530B CN 202110356055 A CN202110356055 A CN 202110356055A CN 113097530 B CN113097530 B CN 113097530B
- Authority
- CN
- China
- Prior art keywords
- partition plate
- gas
- connecting piece
- cell stack
- parallel ribs
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000446 fuel Substances 0.000 title claims abstract description 16
- 239000007787 solid Substances 0.000 title claims abstract description 15
- 238000007726 management method Methods 0.000 title abstract description 14
- 238000005192 partition Methods 0.000 claims abstract description 22
- 238000010521 absorption reaction Methods 0.000 claims abstract description 12
- 239000003054 catalyst Substances 0.000 claims abstract description 12
- 239000000758 substrate Substances 0.000 claims abstract description 10
- 239000007789 gas Substances 0.000 claims description 64
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 17
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 238000000576 coating method Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- 229910021529 ammonia Inorganic materials 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000003487 electrochemical reaction Methods 0.000 claims description 4
- 230000009471 action Effects 0.000 claims description 3
- 239000000956 alloy Substances 0.000 claims description 3
- 229910045601 alloy Inorganic materials 0.000 claims description 3
- 238000009792 diffusion process Methods 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 150000002431 hydrogen Chemical class 0.000 claims 2
- 229910052757 nitrogen Inorganic materials 0.000 claims 2
- 238000009826 distribution Methods 0.000 abstract description 12
- 229910001873 dinitrogen Inorganic materials 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000004020 conductor Substances 0.000 description 2
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
- H01M8/04014—Heat exchange using gaseous fluids; Heat exchange by combustion of reactants
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0267—Collectors; Separators, e.g. bipolar separators; Interconnectors having heating or cooling means, e.g. heaters or coolant flow channels
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
- H01M8/04701—Temperature
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
- H01M8/04701—Temperature
- H01M8/04731—Temperature of other components of a fuel cell or fuel cell stacks
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Fuel Cell (AREA)
Abstract
The invention discloses an improved connecting piece for a flat-plate solid oxide fuel cell stack and a heat management method, wherein the connecting piece comprises a square substrate, a plurality of convex parallel ribs are uniformly arranged on the upper surface of the substrate at intervals along the length direction, a partition plate is respectively arranged between every two adjacent parallel ribs, the lower surface of the partition plate is a heat absorption surface, catalyst Ni is arranged on the lower surface of the partition plate at intervals, and the tail part of the partition plate is provided with an air hole; the flow channel surrounded by the substrate, the partition plate and the parallel ribs is a heat management area, the flow channel surrounded by the partition plate, the parallel ribs and the battery PEN layer is a flow area, the left side of the heat management area is a gas inlet, and the left side of the flow area is a gas outlet. The improved connecting piece is designed by regions, combines the structural design that the catalyst is directionally arranged at the specific position of the heat absorbing surface and the air holes are formed in the tail part of the partition plate, and the components of the mixed gas and the inlet speed are jointly adjusted, so that the nonuniformity of temperature distribution in the cell stack is greatly improved, and the output performance of the cell stack is improved.
Description
Technical Field
The invention relates to a flat-plate solid oxide fuel cell, in particular to an improved connecting piece for a flat-plate solid oxide fuel cell stack, belonging to the technical field of solid oxide fuel cells.
Background
A Solid Oxide Fuel Cell (SOFC) is a device that can directly convert chemical energy into electrical energy, and has the advantages of high energy utilization rate, flexible Fuel and the like. The SOFC unit consists of PEN layers (anode, electrolyte, cathode) and connectors. The connecting piece is a component which is covered outside the cathode and the anode of the SOFC and is carved with a flow passage, and is an important component of the SOFC. The main functions of the connecting piece include: firstly, connecting the anode and the cathode of the adjacent single cell; secondly, the conductor is used for electron transmission between adjacent single cells; and thirdly, the flow channels engraved on the base plate are channels for flowing reactants and products and have the function of distributing gas. The structural design of the connecting member directly affects the output performance and long-term stability of the battery.
For a flat SOFC, the main structure of the current connector is of the parallel straight channel type, as shown in fig. 1. Mainly comprises a gas inlet 1-1, a gas flow passage 1-2, parallel ribs 1-3 and a gas outlet 1-4. The working process is as follows: fuel gas or air enters the connecting piece from the gas inlet 1-1, flows in the gas flow channel 1-2 and diffuses into the porous electrode to react, the generated current is led out of the cell through the parallel ribs 1-3, and the gas generated after the reaction flows out of the cell from the gas outlet 1-4. The connector using parallel straight channels is simple in structure and easy to process, but the connector only has the functions of conducting electricity and providing channels for gas, has limited functions, and causes uneven gas distribution, thereby affecting the overall performance and thermo-mechanical stability of the battery.
At present, research on the connecting piece mainly focuses on improving the uneven gas distribution problem and selecting heat conducting/electric conducting materials, and the development of other functions of the connecting piece is not involved.
Disclosure of Invention
The invention aims to provide an improved connecting piece for a flat-plate type solid oxide fuel cell stack, which can carry out thermal management on the cell stack, reduce the maximum temperature difference in the cell stack and homogenize the temperature distribution of the cell stack.
In order to achieve the purpose, the technical scheme adopted by the invention is as follows: an improved connecting piece for a flat-plate solid oxide fuel cell stack comprises a square base plate, wherein a plurality of convex parallel ribs are uniformly arranged on the upper surface of the base plate at intervals along the length direction, the parallel ribs and the base plate are integrally formed, a groove is formed between every two adjacent parallel ribs, the tail of the groove is closed, a partition plate parallel to the base plate is arranged in the groove, the lower surface of the partition plate is a heat absorption surface, a certain amount of Ni catalyst coating is arranged on the lower surface of the partition plate at intervals, and the tail of the partition plate is provided with air holes for gas flow; the flow channel surrounded by the substrate, the partition plate and the parallel ribs is a heat management area, the flow channel surrounded by the partition plate, the parallel ribs and the battery PEN layer is a flow area, the left side of the heat management area is a gas inlet, and the left side of the flow area is a gas outlet.
Preferably, the improved connecting piece is made of high-temperature-resistant metal or alloy.
Preferably, the pore diameter of the air hole is 0.8-1.2 mm.
The invention also provides a heat management method based on the improved connecting piece for the flat-plate solid oxide fuel cell stack, which is characterized in that ammonia gas/hydrogen gas/nitrogen gas/water vapor mixed gas with a certain temperature is introduced at a gas inlet of the connecting piece at the speed of 1.0-1.2m/s (the proportion of ammonia gas/hydrogen gas/nitrogen gas and water vapor in the mixed gas is 12% -10%: 83% -85%: 5%), ammonia gas in the mixed gas enters a catalyst Ni coating arranged at a heat absorption surface through diffusion, and is cracked and absorbed under the action of a catalyst Ni to absorb heat, so that the cell stack is rapidly cooled; the cracked mixed gas flows to the flow area through the air holes, and the mixed gas diffuses into the PEN layer porous electrode to perform electrochemical reaction while flowing in the flow area and generate electric energy; the reacted gas flows to the gas outlet of the connecting piece along the flow area and flows out of the connecting piece.
Preferably, the mixed gas is introduced at a speed of 1m/s, the mole fraction of ammonia in the mixed gas is 10%, and the mole fraction of hydrogen in the mixed gas is 85%.
Compared with the prior art, the improved connecting piece is designed with a regional function, the heat absorption principle that the reaction speed of the ammonia cracking endothermic reaction is positively correlated with the temperature (namely, the higher the temperature, the more the heat absorption capacity), the structural design that the catalyst is directionally arranged at the specific position of the heat absorption surface and the air holes are formed at the tail part of the partition plate, and the combined regulation of the mixed gas component and the inlet speed are combined, so that the accurate matching and control of the local electrochemical reaction and the local heat absorption capacity in the flat SOFC battery stack are finally realized, the nonuniformity of the temperature distribution in the battery stack is greatly improved, and the output performance of the battery stack is improved.
Drawings
Fig. 1 is a schematic structural diagram of a currently existing SOFC connection;
FIG. 2 is a schematic structural view of an improved connector according to the present invention;
fig. 3 is a schematic representation of a two-dimensional structure of a SOFC unit incorporating the improved connector of the present invention;
FIG. 4 is the maximum temperature difference of the cell at different gas compositions and velocities at the inlet using the connector of the present invention at a cell voltage of 0.8V;
FIG. 5 is the maximum temperature difference of the cell at different gas compositions and velocities at the inlet using the connector of the present invention at a cell voltage of 0.9V;
FIG. 6 is a graph of the average current density of the cell at various gas compositions and velocities at the inlet using the connector of the present invention at a cell voltage of 0.8V;
FIG. 7 is a graph of the average current density of the cell at various gas compositions and velocities at the inlet using the connector of the present invention at a cell voltage of 0.9V;
fig. 8 is a two-dimensional temperature profile of a SOFC unit without the use of the connectors of the present invention, with only 5 times the amount of air introduced into the cathode;
fig. 9 is a two-dimensional temperature profile of a SOFC unit using the improved connector of the present invention;
in the figure, 1-1 gas inlet, 1-2 gas flow channels, 1-3 parallel ribs and 1-4 gas outlet; 2-1 gas inlet, 2-2 gas flow channel, 2-3 parallel rib, 2-4 base plate, 2-5 gas outlet and 2-6 baffle plate; 3-1 heat management area, 3-2 air holes, 3-3 flow area, 3-4 battery PEN layer, 3-5 cathode flow channel and 3-6 heat absorption surface.
Detailed Description
The invention is described in further detail below with reference to the figures and specific examples.
As shown in fig. 2 to 3, the present invention provides an improved connector for a flat plate type solid oxide fuel cell stack, which comprises a square base plate 2-4, a plurality of convex parallel ribs 2-3 are uniformly arranged on the upper surface of the base plate 2-4 along the length direction at intervals, the parallel ribs 2-3 and the base plate 2-4 are integrally formed, a groove is formed between two adjacent parallel ribs 2-3, the tail part of the groove is closed, a clapboard 2-6 parallel to the substrate 2-4 is arranged in the groove, the lower surface of the separator 2-6 is a heat absorption surface 3-6, a certain amount of catalyst Ni coatings are arranged on the lower surface of the separator 2-6 at intervals, the tail part of the separator 2-6 is provided with air holes 3-2 for gas flow, and the aperture of the air holes is preferably set to be 0.8-1.2 mm; the flow channel surrounded by the substrate 2-4, the partition plate 2-6 and the parallel ribs 2-3 is a heat management area 3-1, the flow channel surrounded by the partition plate 2-6, the parallel ribs 2-3 and the battery PEN layer 3-4 is a flow area 3-3, the left side of the heat management area 3-1 is a gas inlet 2-1, and the left side of the flow area 3-3 is a gas outlet 2-5.
In order to adapt to the working environment of the battery, the improved connecting piece is made of high-temperature-resistant metal or alloy.
The invention also provides a flat SOFC battery stack comprising the improved connecting piece. And assembling the connecting piece and the battery PEN layer into a battery unit, and stacking layer by layer to assemble a battery stack.
In the working process of the cell stack, ammonia gas/hydrogen gas/nitrogen gas/water vapor mixed gas with a certain temperature is introduced at the gas inlet 2-1 of the connecting piece at a speed of not less than 1m/s, the ammonia gas in the mixed gas enters a catalyst Ni coating arranged at the position 3-6 of the heat absorption surface through diffusion, and is cracked and absorbed under the action of the catalyst Ni to absorb heat and absorb reaction heat from the cell, so that the cell stack is rapidly cooled; the cracked mixed gas flows to a flow area 3-3 through an air hole 3-2, and the mixed gas flows in the flow area 3-3 and diffuses into a PEN layer porous electrode to perform electrochemical reaction and generate electric energy; the reacted gas flows along the flow area 3-3 to the gas outlet 2-5 of the connecting piece and flows out of the connecting piece.
Due to the different heat generation and cell performance of the cells at different voltages, there will be different temperature distributions and current densities. In order for the improved coupling of the present invention to function adequately at different operating conditions, the optimum operating conditions of the inlet gas at different voltages are discussed herein. Taking the current density as a parameter for representing the performance of the battery; the maximum temperature difference is taken as a characteristic parameter of the battery temperature distribution. The gas introduced consists of 4 components: h2、 NH3、H2O、N2. So define H2And NH3In a total molar fraction of 0.95, N2And H2The total molar fraction of O was 0.05.
The temperature profile of the cell when using the improved connector of the invention is related to the inlet gas condition parameters (inlet velocity of the gas, ratio of components in the gas). The maximum value of the cell when the inlet velocity was varied from 1m/s to 3m/s and the total molar fraction of hydrogen was varied from 0.80 to 0.85 at voltages of 0.8V and 0.9VThe temperature differences are shown in fig. 4 and 5; the maximum current density is shown in fig. 6 and 7. The simulation was implemented using COMSOL commercial software. FIGS. 4 and 5 illustrate that the most uniform temperature distribution of the cell occurs at a gas velocity of 1m/s, but at a voltage of 0.8V, the most uniform temperature distribution was achieved at a hydrogen mole fraction of 0.83, and the maximum temperature difference was 6.23K; the working condition of the most uniform temperature distribution is obtained when the hydrogen mole fraction is 0.85 under the voltage of 0.9V, and the maximum temperature difference is 31.16K. FIGS. 6 and 7 show that the maximum current densities obtained at a velocity of 1m/s and a hydrogen mole fraction of 0.85 were 2619.4A/m, respectively2And 1368.7A/m2。
To illustrate the advantages of the improved connectors of the present invention, the performance and temperature profile of SOFC units thermally managed with excess air from the cell cathode using currently available connectors (configuration shown in fig. 1) were separately modeled and compared to the case of using the improved connectors of the present invention. By integrating the battery performance and the temperature distribution condition, the inlet working condition adopts the working condition when the current density is maximum: the gas velocity was 1m/s, and the hydrogen mole fraction was 0.85 (ammonia gas 0.1, remaining 0.5 from N)2And H2O composition). The other working condition parameters are the same as those of the traditional connecting piece (the working voltage of the two is 0.8V, and the inlet gas temperature is 923K).
The results are shown in FIGS. 8 and 9: when the current commonly used connecting piece is adopted and the excess air (5 times of air quantity, the speed is 5m/s) of the cathode of the battery is used for carrying out heat management, the maximum temperature difference of the battery along the length direction is 26.7K, and the output current density is 2310A/m2(ii) a When the improved connecting piece is adopted, the maximum temperature difference of the battery along the length direction is 15K, and the output current density is 2619.4A/m2Compared with an air cooling method, the maximum temperature difference in the battery is reduced by 3.98K, and the output current density is improved by 10.94%.
The results prove that the improved connecting piece not only can meet the three main functions of the conventional connecting piece (connecting the anode and the cathode of the adjacent single cell, conducting electrons, providing a flow channel for reactants and products), but also can carry out thermal management on the SOFC cell stack, effectively improve the nonuniformity of temperature distribution in the cell stack, reduce the maximum temperature difference in the cell stack and improve the output performance of the cell stack.
Claims (5)
1. An improved connector for a flat plate type solid oxide fuel cell stack, comprising a square base plate (2-4), characterized in that: the upper surface of the substrate (2-4) is uniformly provided with a plurality of protruding parallel ribs (2-3) at intervals along the length direction, the parallel ribs (2-3) and the substrate (2-4) are integrally formed, a groove is formed between every two adjacent parallel ribs (2-3), the tail of the groove is closed, a partition plate (2-6) parallel to the substrate (2-4) is arranged in the groove, the lower surface of the partition plate (2-6) is a heat absorption surface, catalyst Ni coatings are arranged on the lower surface of the partition plate (2-6) at intervals, and the tail of the partition plate (2-6) is provided with air holes (3-2) for air flow; the flow channel surrounded by the substrate (2-4), the partition plate (2-6) and the parallel ribs (2-3) is a heat management area (3-1), the flow channel surrounded by the partition plate (2-6), the parallel ribs (2-3) and the battery PEN layer (3-4) is a flow area (3-3), the left side of the heat management area (3-1) is a gas inlet (2-1), and the left side of the flow area (3-3) is a gas outlet (2-5).
2. An improved connector for a flat plate type solid oxide fuel cell stack according to claim 1, wherein: the improved connecting piece is made of high-temperature-resistant metal or alloy.
3. An improved connector for a flat plate type solid oxide fuel cell stack according to claim 1, wherein: the aperture of the air hole (3-2) is 0.8-1.2 mm.
4. A method for heat management of an improved connector of a flat plate type solid oxide fuel cell stack according to any of claims 1 to 3, characterized in that a mixture of ammonia, hydrogen, nitrogen and water vapor at a temperature of 923K is introduced at a connector gas inlet (2-1) at a rate of 1.0 to 1.2m/s, and the ratio of ammonia, hydrogen, nitrogen and water vapor in the mixture is 12 to 10%: 83% -85%: 5 percent, ammonia gas in the mixed gas enters a catalyst Ni coating arranged at the heat absorption surface (3-6) through diffusion, and is cracked and absorbed under the action of the catalyst Ni to absorb heat and absorb reaction heat from the battery, so that the battery stack is rapidly cooled; the cracked mixed gas flows to the flow area (3-3) through the air holes (3-2), and the mixed gas flows in the flow area (3-3) and diffuses into the PEN layer porous electrode to perform electrochemical reaction and generate electric energy; the reacted gas flows to the gas outlet (2-5) of the connecting piece along the flow area (3-3) and flows out of the connecting piece.
5. The method according to claim 4, wherein the mixed gas is introduced at a velocity of 1m/s, the molar fraction of ammonia gas in the mixed gas is 10%, and the molar fraction of hydrogen gas is 85%.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202110356055.6A CN113097530B (en) | 2021-04-01 | 2021-04-01 | Improved connecting piece for flat-plate solid oxide fuel cell stack and thermal management method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202110356055.6A CN113097530B (en) | 2021-04-01 | 2021-04-01 | Improved connecting piece for flat-plate solid oxide fuel cell stack and thermal management method |
Publications (2)
Publication Number | Publication Date |
---|---|
CN113097530A CN113097530A (en) | 2021-07-09 |
CN113097530B true CN113097530B (en) | 2022-04-19 |
Family
ID=76672747
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202110356055.6A Active CN113097530B (en) | 2021-04-01 | 2021-04-01 | Improved connecting piece for flat-plate solid oxide fuel cell stack and thermal management method |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN113097530B (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114725428B (en) * | 2022-04-19 | 2023-09-01 | 中国矿业大学 | Zero-carbon-emission solid oxide fuel cell and renewable energy combined power generation system taking ammonia gas as carrier |
CN114804149B (en) * | 2022-05-27 | 2023-10-31 | 中国能源建设集团广东省电力设计研究院有限公司 | Photocatalysis synthesis ammonia reactor and photocatalysis synthesis ammonia reaction system |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1677714A (en) * | 2004-03-30 | 2005-10-05 | 爱考斯研究株式会社 | Separator and fuel cell using that separator |
CN1870255A (en) * | 2005-05-24 | 2006-11-29 | 富准精密工业(深圳)有限公司 | Liquid-cooling heat sink |
CN101232100A (en) * | 2007-01-22 | 2008-07-30 | 英属盖曼群岛商胜光科技股份有限公司 | Cathode flow field structure used for fuel cell stack |
CN101496216A (en) * | 2006-07-28 | 2009-07-29 | 松下电器产业株式会社 | Fuel cell and fuel cell system |
CN106784937A (en) * | 2016-11-28 | 2017-05-31 | 苏州氢洁电源科技有限公司 | The vaporizer flow passage structure of methanol fuel cell |
CN110061178A (en) * | 2018-01-18 | 2019-07-26 | 比亚迪股份有限公司 | Battery, battery pack and automobile |
CN110581292A (en) * | 2019-08-13 | 2019-12-17 | 中国矿业大学 | Cooler for high-temperature fuel cell stack and thermal management method |
KR20200094876A (en) * | 2019-01-30 | 2020-08-10 | 한국전력공사 | Solid oxide fuel cells and solid oxide electrolysis cells |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8735012B2 (en) * | 2008-11-20 | 2014-05-27 | Mti Microfuel Cells Inc. | Direct oxidation fuel cell system with uniform vapor delivery of fuel |
CN104538651B (en) * | 2014-11-27 | 2017-02-22 | 同济大学 | Proton exchange membrane fuel cell for X-ray absorption fine structure spectrum test |
CN207818737U (en) * | 2018-01-18 | 2018-09-04 | 比亚迪股份有限公司 | Battery, battery pack and automobile |
-
2021
- 2021-04-01 CN CN202110356055.6A patent/CN113097530B/en active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1677714A (en) * | 2004-03-30 | 2005-10-05 | 爱考斯研究株式会社 | Separator and fuel cell using that separator |
CN1870255A (en) * | 2005-05-24 | 2006-11-29 | 富准精密工业(深圳)有限公司 | Liquid-cooling heat sink |
CN101496216A (en) * | 2006-07-28 | 2009-07-29 | 松下电器产业株式会社 | Fuel cell and fuel cell system |
CN101232100A (en) * | 2007-01-22 | 2008-07-30 | 英属盖曼群岛商胜光科技股份有限公司 | Cathode flow field structure used for fuel cell stack |
CN106784937A (en) * | 2016-11-28 | 2017-05-31 | 苏州氢洁电源科技有限公司 | The vaporizer flow passage structure of methanol fuel cell |
CN110061178A (en) * | 2018-01-18 | 2019-07-26 | 比亚迪股份有限公司 | Battery, battery pack and automobile |
KR20200094876A (en) * | 2019-01-30 | 2020-08-10 | 한국전력공사 | Solid oxide fuel cells and solid oxide electrolysis cells |
CN110581292A (en) * | 2019-08-13 | 2019-12-17 | 中国矿业大学 | Cooler for high-temperature fuel cell stack and thermal management method |
Also Published As
Publication number | Publication date |
---|---|
CN113097530A (en) | 2021-07-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN110380077B (en) | Combined flow passage fuel cell bipolar plate | |
CN109755622B (en) | Hollow symmetrical double-cathode high-temperature solid fuel cell stack | |
CN113097530B (en) | Improved connecting piece for flat-plate solid oxide fuel cell stack and thermal management method | |
US20070009781A1 (en) | Flow field plates for fuel cells | |
CN101009377A (en) | Bipolar plate for fuel cell | |
CN111092243B (en) | Runner of fish scale bionic structure for fuel cell | |
US20230025359A1 (en) | Single corrugated fuel cell and cell stack | |
CN101286568B (en) | Constant channel cross-section in a PEMFC outlet | |
CN114361505A (en) | Three-runner solid oxide fuel cell unit structure and cell stack | |
KR101092486B1 (en) | Flow channel plate for fuel cell | |
CN100550500C (en) | A kind of fuel battery | |
CN113013437B (en) | Fuel cell cathode runner with gradually-reduced slope structure | |
CN211125830U (en) | Hydrogen fuel cell bipolar plate with composite flow field | |
CN209947950U (en) | Bipolar plate with Taiji pattern flow field structure in liquid fuel cell, monocell and portable electronic product | |
CN218548496U (en) | Fuel cell stack | |
CN218385286U (en) | Bipolar plate for fuel cell | |
CN111864241A (en) | Small proton exchange film fuel cell | |
CN115084566A (en) | Fuel cell bipolar plate with bionic hexagonal flow channel | |
CN114361502A (en) | Bionic proton exchange membrane fuel cell based on vein derivation | |
CN112397743A (en) | Solid oxide fuel cell connector | |
CN113161568A (en) | Novel air inlet structure suitable for multi-channel flow field plate of fuel cell | |
CN116014168B (en) | Fuel cell flow field plate | |
CN109980241A (en) | There is Diagram of the Supreme Ultimate shape flow field structure bipolar plates and design method in fuel liquid battery | |
CN109980242A (en) | There is harp shape flow field structure bipolar plates and design method in fuel liquid battery | |
CN110034310A (en) | Proton exchange membrane fuel cell structure with wedge-shaped fin |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |