CN113089116A - Copper-silver series sterilization and deodorization artificial silk thread and manufacturing method and application thereof - Google Patents
Copper-silver series sterilization and deodorization artificial silk thread and manufacturing method and application thereof Download PDFInfo
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- CN113089116A CN113089116A CN202110370619.1A CN202110370619A CN113089116A CN 113089116 A CN113089116 A CN 113089116A CN 202110370619 A CN202110370619 A CN 202110370619A CN 113089116 A CN113089116 A CN 113089116A
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- copper
- sterilized
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- silver
- silver series
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- NEIHULKJZQTQKJ-UHFFFAOYSA-N [Cu].[Ag] Chemical class [Cu].[Ag] NEIHULKJZQTQKJ-UHFFFAOYSA-N 0.000 title claims abstract description 225
- 230000001954 sterilising effect Effects 0.000 title claims abstract description 161
- 238000004659 sterilization and disinfection Methods 0.000 title claims abstract description 91
- 238000004332 deodorization Methods 0.000 title claims abstract description 30
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 21
- 229920002955 Art silk Polymers 0.000 title claims abstract description 16
- 150000001879 copper Chemical class 0.000 claims abstract description 60
- -1 polypropylene Polymers 0.000 claims abstract description 58
- 239000000835 fiber Substances 0.000 claims abstract description 56
- 239000004743 Polypropylene Substances 0.000 claims abstract description 50
- 229920001155 polypropylene Polymers 0.000 claims abstract description 50
- 229920001778 nylon Polymers 0.000 claims abstract description 46
- 229920002334 Spandex Polymers 0.000 claims abstract description 43
- 239000004759 spandex Substances 0.000 claims abstract description 43
- 239000004677 Nylon Substances 0.000 claims abstract description 34
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 33
- 238000009987 spinning Methods 0.000 claims abstract description 29
- 229920000642 polymer Polymers 0.000 claims abstract description 23
- 239000000126 substance Substances 0.000 claims abstract description 18
- 229920004933 Terylene® Polymers 0.000 claims abstract description 16
- 239000005020 polyethylene terephthalate Substances 0.000 claims abstract description 16
- 239000011858 nanopowder Substances 0.000 claims abstract description 15
- 238000009941 weaving Methods 0.000 claims abstract description 14
- 238000002844 melting Methods 0.000 claims abstract description 6
- 230000008018 melting Effects 0.000 claims abstract description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 5
- 230000032050 esterification Effects 0.000 claims abstract description 5
- 238000005886 esterification reaction Methods 0.000 claims abstract description 5
- 238000006068 polycondensation reaction Methods 0.000 claims abstract description 5
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 5
- 230000004048 modification Effects 0.000 claims abstract 2
- 238000012986 modification Methods 0.000 claims abstract 2
- 239000004744 fabric Substances 0.000 claims description 45
- 229920002972 Acrylic fiber Polymers 0.000 claims description 33
- 229920000742 Cotton Polymers 0.000 claims description 22
- 239000003963 antioxidant agent Substances 0.000 claims description 21
- 230000003078 antioxidant effect Effects 0.000 claims description 21
- 210000002268 wool Anatomy 0.000 claims description 20
- 239000003206 sterilizing agent Substances 0.000 claims description 18
- 239000004952 Polyamide Substances 0.000 claims description 12
- 229920002647 polyamide Polymers 0.000 claims description 12
- 239000000155 melt Substances 0.000 claims description 10
- 238000004804 winding Methods 0.000 claims description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 9
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 9
- 229910052802 copper Inorganic materials 0.000 claims description 9
- 239000010949 copper Substances 0.000 claims description 9
- YCKOAAUKSGOOJH-UHFFFAOYSA-N copper silver Chemical compound [Cu].[Ag].[Ag] YCKOAAUKSGOOJH-UHFFFAOYSA-N 0.000 claims description 9
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 8
- 239000005751 Copper oxide Substances 0.000 claims description 8
- 229910000431 copper oxide Inorganic materials 0.000 claims description 8
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 claims description 8
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 claims description 8
- 229940112669 cuprous oxide Drugs 0.000 claims description 8
- 239000002105 nanoparticle Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 claims description 7
- 229920000728 polyester Polymers 0.000 claims description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 230000001877 deodorizing effect Effects 0.000 claims description 6
- 239000002270 dispersing agent Substances 0.000 claims description 6
- 239000004698 Polyethylene Substances 0.000 claims description 5
- 238000007664 blowing Methods 0.000 claims description 5
- 239000011521 glass Substances 0.000 claims description 5
- 229920000573 polyethylene Polymers 0.000 claims description 5
- 229910052709 silver Inorganic materials 0.000 claims description 5
- 239000004332 silver Substances 0.000 claims description 5
- 238000009940 knitting Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- QIRJMTNEXDJJHV-UHFFFAOYSA-J [Na+].P(=O)([O-])([O-])[O-].O[Zr+3] Chemical compound [Na+].P(=O)([O-])([O-])[O-].O[Zr+3] QIRJMTNEXDJJHV-UHFFFAOYSA-J 0.000 claims description 3
- 229910021529 ammonia Inorganic materials 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 3
- 150000002825 nitriles Chemical class 0.000 claims description 3
- 238000007493 shaping process Methods 0.000 claims description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 2
- 238000005096 rolling process Methods 0.000 claims description 2
- 230000000249 desinfective effect Effects 0.000 claims 1
- 238000000034 method Methods 0.000 abstract 3
- 230000007547 defect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 2
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 2
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 2
- 150000008301 phosphite esters Chemical class 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229940037312 stearamide Drugs 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/36—Cored or coated yarns or threads
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
- D10B2201/02—Cotton
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2211/00—Protein-based fibres, e.g. animal fibres
- D10B2211/01—Natural animal fibres, e.g. keratin fibres
- D10B2211/02—Wool
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2211/00—Protein-based fibres, e.g. animal fibres
- D10B2211/01—Natural animal fibres, e.g. keratin fibres
- D10B2211/04—Silk
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/02—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
- D10B2321/022—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polypropylene
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/10—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/10—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyurethanes
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Artificial Filaments (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Abstract
A copper-silver series sterilization and deodorization artificial silk thread and a manufacturing method and application thereof are characterized in that a copper-silver series with the weight percentage of 2% -60% is correspondingly doped into a polymer or terylene or polypropylene or acrylic or nylon or spandex nano powder with the weight percentage of 98% -40%, a copper series polymer master batch, a copper series terylene master batch or a copper series polypropylene master batch or a copper series acrylic master batch or a copper series nylon master batch or a copper series spandex master batch obtained through grafting modification such as multiple polymerization reactions and/or multiple esterifications and/or polycondensations are prepared into a copper series chemical fiber silk roll (barrel) through processes such as melting high-pressure spinning or spinning at the temperature of 260-350 ℃, and various sterilization and deodorization mildew-proof clothes, trousers and various sterilization and deodorization socks are prepared through a clothes making process and a sock weaving process.
Description
Technical Field
The invention belongs to the technical field of textile technology, and particularly relates to a copper-silver series sterilization and deodorization artificial silk thread, and a manufacturing method and application and manufacturing technical field thereof.
Background
Various natural silk threads or artificial silk threads in the prior art rarely contain disinfection and sterilization components and do not have strong disinfection and sterilization functions, various fabrics in the prior art also have the same problems, and the fabric is easy to sweat after being worn for a long time, is easy to breed various bacteria to generate odor, is not only smelly, and has no good solution to the defect.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides a copper-silver series sterilization and deodorization artificial silk thread and a manufacturing method and application thereof, wherein the manufacturing method comprises the following steps: one or more of simple substance copper, copper oxide, cuprous oxide and copper salt nano powder or particles are combined to form a copper series sterilizing agent, 1.8 to 40 weight percent of copper series sterilizing agent is correspondingly doped into 93 to 40 weight percent of polymer, terylene, polypropylene, acrylic fiber, nylon, spandex nano powder or master batch, 5 to 10 weight percent of compatilizer, 0.1 to 6 percent of dispersing agent and 0.1 to 4 percent of antioxidant are added, the sum of the raw materials is 100 percent, the mixture is put into a high-speed mixer to be mixed for 2 to 10 minutes, the mixture is put into a melting screw extruder, the processing temperature is 160 to 320 ℃, the rotating speed of the screw is 180 to 800 revolutions per minute, and the mixture is melted to respectively form the copper series sterilizing polymer, the terylene, the copper series sterilizing polymer, the copper series sterilizing polypropylene, the copper series sterilizing acrylic fiber or the copper series sterilizing polypropylene or the copper series sterilizing acrylic fiber or the copper series sterilizing polymer, the copper The melt of the sterilized nylon or the sterilized spandex of the copper series has a melt index of 0.8-40g/10min, and is prepared into a sterilized polymer yarn coil (barrel) of the copper series, a sterilized polyester yarn coil (barrel) of the copper series, a sterilized polypropylene yarn coil (barrel) of the copper series, a sterilized acrylic yarn coil (barrel) of the copper series, a sterilized nylon yarn coil (barrel) of the copper series, a sterilized spandex yarn coil (barrel) of the copper series, a sterilized nylon yarn coil (barrel) of the copper series and a sterilized spandex yarn coil (barrel) of the copper series by extrusion and high-pressure spinning or spinning, cooling and blowing for spinning, oiling for spinning, winding, traction and winding, wherein the sterilized: polyethylene, polypropylene, polyvinyl chloride, polystyrene, styrene-butadiene-acrylonitrile.
Preferably, the copper-silver series sterilizing agent formed by one or more of simple substance copper, copper oxide, cuprous oxide, copper salt and silver ion glass nano powder or particles is prepared by correspondingly doping the copper-silver series sterilizing agent with the weight percentage of 2% -60% into 98% -40% of polymer, terylene, polypropylene fiber, acrylic fiber, nylon or spandex nano powder or master batch, performing multiple polymerization reaction and/or multiple esterification and/or polycondensation and the like to obtain copper-silver series sterilizing polymer master batch, copper-silver series sterilizing terylene master batch, copper-silver series sterilizing polypropylene fiber master batch, copper-silver series sterilizing acrylic fiber master batch, copper-silver series sterilizing nylon master batch or copper-silver series sterilizing spandex master batch, performing melt high-pressure spinning or spinning at 260-350 ℃, and performing high-pressure spinning or spinning, Spinning cooling is blown, the spinning is oiled, the coiling, draw, the coiling is made into copper silver series sterilization polymer silk book (bucket), copper silver series sterilization polyester silk book (bucket), copper silver series sterilization polypropylene fiber silk book (bucket), copper silver series sterilization acrylic fiber silk book (bucket), copper silver series sterilization polyamide fiber silk book (bucket), copper silver series sterilization nylon silk book (bucket), copper silver series sterilization spandex silk book (bucket), the polymer includes: polyethylene, polypropylene, polyvinyl chloride, polystyrene, styrene-butadiene-acrylonitrile.
Preferably, the compatilizer is polypropylene grafted maleic anhydride (PP-g-MAH), the melt index of the compatilizer is 1-150g/10min, the grafting rate is 0.5-1%, the dispersant is organic wax or stearamide, which can be any single component or a mixed component, the organic wax and the stearamide, the organic wax comprises polyethylene wax, the proportion of the mixed component is 0.1-99.9%, the antioxidant is hindered phenol antioxidant or is compounded with phosphite antioxidant, the hindered phenol antioxidant is 1010, and the compounding ratio of the hindered phenol antioxidant to the phosphite antioxidant is 1010/168 of 1: 1; the copper-silver series sterilizing agent also comprises: one or more of glass silver-loaded hydroxyl zirconium sodium phosphate containing silver ions, elementary copper, copper oxide, cuprous oxide and copper salt nano powder or particles are combined to form the copper-silver series sterilizing agent.
Preferably, the copper-silver series sterilized polypropylene fiber coil (barrel) or the copper-silver series sterilized acrylic fiber coil (barrel) or the copper-silver series sterilized nylon fiber coil (barrel) or the copper-silver series sterilized spandex fiber coil (barrel) are woven into the copper-silver series sterilized chemical fiber cloth through an air-jet loom or a shuttle loom respectively: the polyamide fabric is made of copper-silver series sterilized polypropylene fabric, copper-silver series sterilized nitrile fabric, copper-silver series sterilized polyamide fabric, copper-silver series sterilized nylon fabric and copper-silver series sterilized ammonia fabric.
Preferably, the copper-silver series sterilized polypropylene fiber roll (barrel) or the copper-silver series sterilized acrylic fiber roll (barrel) or the copper-silver series sterilized nylon fiber roll (barrel) or the copper-silver series sterilized spandex roll (barrel) are respectively blended with cotton threads, wool threads or real threads through weaving by an air-jet loom or a shuttle loom to prepare the copper-silver series sterilized blended fabric: copper-silver series sterilized cotton-acrylic cloth or copper-silver series sterilized cotton-polyester cloth or copper-silver series sterilized cotton-acrylic cloth or copper-silver series sterilized cotton-polyamide cloth; two or three of copper-silver series sterilized polypropylene fiber roll (barrel) or copper-silver series sterilized acrylic fiber roll (barrel) or copper-silver series sterilized nylon fiber roll (barrel) or copper-silver series sterilized spandex fiber roll (barrel) are mixed and woven by an air flow weaving machine or a shuttle weaving machine to obtain the copper-silver series sterilized chemical fiber blended fabric.
Preferably, the copper-silver series sterilized polypropylene fiber coil (barrel) or the copper-silver series sterilized acrylic fiber coil (barrel) or the copper-silver series sterilized nylon fiber coil (barrel) or the copper-silver series sterilized spandex fiber coil (barrel) are respectively intertwined with cotton threads, wool threads or silk threads to form the copper-silver series sterilized core wrapping wire: the copper-silver series sterilized polypropylene fiber covered cotton thread or the copper-silver series sterilized acrylic fiber covered cotton thread or the copper-silver series sterilized nylon covered cotton thread or the copper-silver series sterilized spandex covered cotton thread or the copper-silver series sterilized polypropylene fiber covered wool thread or the copper-silver series sterilized acrylic fiber covered wool thread or the copper-silver series sterilized nylon covered wool thread or the copper-silver series sterilized spandex covered wool thread or the copper-silver series sterilized polypropylene fiber covered silk thread or the copper-silver series sterilized nylon covered silk thread or the copper-silver series sterilized spandex covered silk thread.
Preferably, the sterilization and deodorization underwear, the sterilization and deodorization underpants, the sterilization and mildew-proof warm underwear and the sterilization and mildew-proof underwear of the copper-silver series, the sterilization and mildew-proof thermal underwear of the copper-silver series, the sterilization and mildew-proof outerwear of the copper-silver series, the sterilization and mildew-proof down coat of the copper-silver series, the sterilization and mildew-proof down wadded trousers of the copper-silver series, the sterilization and mildew-proof T shirt of the copper-silver series, the sterilization and mildew-proof jacket of the copper-silver series, the sterilization and mildew-proof tights of the copper-silver series, the sterilization and mildew-proof suit of the copper-silver series, the sterilization and mildew-proof midlength coat of the copper-silver series, the sterilization and mildew-proof midheight suit of the copper-silver series, the sterilization and mildew-proof autumn suit of the copper-silver series, the sterilization and mildew-proof woollen suit of the sterilization and mildew-proof autumn suit of the copper-silver series, the sterilization, A copper-silver series sterilization bra, a copper-silver series sterilization sanitary towel, a copper-silver series sterilization sanitary cotton strip and the like.
Preferably, the various copper-silver series sterilization deodorization socks are manufactured by knitting various socks by a sock knitting machine by using the copper-silver series sterilization chemical fiber or the copper-silver series sterilization cored wire.
Advantageous effects
The invention relates to a copper-silver series sterilization and deodorization artificial silk thread and a manufacturing method and application thereof, which solve the defect that the traditional chemical fiber silk thread and cotton thread do not have sterilization and deodorization functions, and can realize the blending or core-covering manufacture of the chemical fiber raw material effectively carrying the copper-silver silk thread and the cotton thread, real silk and wool by adopting the mixed dispersion compatibility technology and/or the polymerization, esterification and polycondensation technology of the invention to manufacture sterilization and deodorization chemical fiber cloth and sterilization and deodorization blended cotton cloth, the sterilization and deodorization blended real silk cloth and the sterilization and deodorization blended wool cloth, and manufacture sterilization and deodorization clothes such as copper-silver series sterilization and deodorization underwear, copper-silver series sterilization and deodorization short-sleeved underwear, copper-silver series sterilization and mildew-proof outerwear, copper-silver series sterilization and mildew-proof down underwear, copper-silver series sterilization and mildew-proof T-shaped sterilization and mildew-proof underwear, long-sleeved, The sterilization and mildew-proof jacket of the copper-silver series, the sterilization and mildew-proof bra of the copper-silver series, the sterilization and mildew-proof body-beautifying close-fitting coat of the copper-silver series, the sterilization and mildew-proof woolen overcoat of the copper-silver series, the sterilization and mildew-proof suit of the copper-silver series, the sterilization and mildew-proof coat of the copper-silver series, the sterilization and mildew-proof middle-length coat of the copper-silver series, the sterilization and mildew-proof middle-mountain coat of the copper-silver series, the sterilization and mildew-proof spring coat of the copper-silver series, the sterilization and mildew-proof autumn coat of the copper-silver series, the sterilization and mildew-proof bra of the copper-silver series, the sterilization and deodorization sanitary towel of the copper-silver series, and the sterilization and deodorization socks of.
Detailed Description
The technical solution of the present invention will be clearly and completely described below. In the description of the present invention, it should be noted that the terms "center", "upper", "lower", "left", "right", "vertical", "horizontal", "inner", "outer", etc. indicate orientations or positional relationships based on the orientations or positional relationships for convenience in describing the present invention and simplifying the description, but do not indicate or imply that the device or element referred to must have a specific orientation, be constructed in a specific orientation, and be operated, and thus, should not be construed as limiting the present invention. Furthermore, the terms "first," "second," and "third" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance.
In the description of the present invention, it should be noted that, unless otherwise explicitly specified or limited, the terms "mounted," "connected," and "connected" are to be construed broadly, e.g., as meaning either a fixed connection, a removable connection, or an integral connection; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meanings of the above terms in the present invention can be understood in specific cases to those skilled in the art.
The invention relates to a copper-silver series sterilization and deodorization artificial silk thread and a manufacturing method and application thereof, wherein the manufacturing method comprises the following steps: one or more of simple substance copper, copper oxide, cuprous oxide and copper salt nano powder or particles are combined to form a copper series sterilizing agent, 1.8 to 40 weight percent of copper series sterilizing agent is correspondingly doped into 93 to 40 weight percent of polymer, terylene, polypropylene, acrylic fiber, nylon or spandex nano powder or master batch, 5 to 10 weight percent of compatilizer, 0.1 to 6 percent of dispersing agent and 0.1 to 4 percent of antioxidant are added, the sum of the raw materials is 100 percent, the mixture is put into a high-speed mixer to be mixed for 2 to 10 minutes, the mixture is put into a melting screw extruder, the processing temperature is 160 to 320 ℃, the rotating speed of the screw is 180 to 800 revolutions per minute, and the copper series sterilizing polymer which is uniformly dispersed, highly compatible and mutually adhered is respectively formed by melting, The melt of the copper series sterilized terylene or copper series sterilized polypropylene fiber or copper series sterilized acrylic fiber or copper series sterilized nylon or copper series sterilized spandex has a melt index of 0.8-40g/10min, and is prepared into a copper series sterilized polymer yarn roll (barrel), a copper series sterilized terylene yarn roll (barrel), a copper series sterilized polypropylene fiber roll (barrel), a copper series sterilized acrylic fiber roll (barrel), a copper series sterilized nylon yarn roll (barrel), a copper series sterilized spandex yarn roll (barrel) through extrusion, high-pressure spinning or spinning, spinning cooling and blowing, spinning oiling, winding, traction and winding.
Preferably, the copper-silver series sterilizing agent formed by one or more of simple substance copper, copper oxide, cuprous oxide, copper salt and silver ion glass nano powder or particles is prepared by correspondingly doping the copper-silver series sterilizing agent with the weight percentage of 2% -60% into 98% -40% of polymer, terylene, polypropylene fiber, acrylic fiber, nylon or spandex nano powder or master batch, performing multiple polymerization reaction and/or multiple esterification and/or polycondensation and the like to obtain copper-silver series sterilizing polymer master batch, copper-silver series sterilizing terylene master batch, copper-silver series sterilizing polypropylene fiber master batch, copper-silver series sterilizing acrylic fiber master batch, copper-silver series sterilizing nylon master batch or copper-silver series sterilizing spandex master batch, performing melt high-pressure spinning or spinning at 260-350 ℃, and performing high-pressure spinning or spinning, Cooling and blowing spinning, oiling spinning, winding, drawing and rolling to prepare a copper-silver series sterilization polymer master batch, a copper-silver series sterilization terylene yarn coil (barrel), a copper-silver series sterilization polypropylene yarn coil (barrel), a copper-silver series sterilization acrylic yarn coil (barrel), a copper-silver series sterilization polyamide yarn coil (barrel), a copper-silver series sterilization nylon yarn coil (barrel) and a copper-silver series sterilization spandex yarn coil (barrel).
Example one
The compatilizer is polypropylene grafted maleic anhydride (PP-g-MAH) with the melt index of 1-150g/10min and the grafting rate of 0.5-1%, the dispersant is organic wax or stearic acid amide, which can be any single component or a mixed component, the organic wax comprises polyethylene wax, and the proportion of the mixed component is 0.1% -99.9%; the antioxidant is hindered phenol antioxidant or is compounded with phosphite ester antioxidant, the hindered phenol antioxidant is 1010, the hindered phenol antioxidant and the phosphite ester antioxidant are compounded into 1010/168 with the ratio of 1:1, and the copper-silver series sterilizing agent also comprises: the glass containing silver ions, such as one or more of silver-carrying sodium zirconium phosphate hydroxide, elementary copper, copper oxide, cuprous oxide and copper salt nano powder or particles, form a copper-silver series sterilizing agent.
Example two
Weaving and weaving a copper-silver series sterilized polypropylene fiber coil (barrel) or a copper-silver series sterilized acrylic fiber coil (barrel) or a copper-silver series sterilized nylon fiber coil (barrel) or a copper-silver series sterilized spandex fiber coil (barrel) through an air-jet loom or a shuttle loom respectively to prepare the copper-silver series sterilized chemical fiber cloth: the polyamide fabric is made of copper-silver series sterilized polypropylene fabric, copper-silver series sterilized nitrile fabric, copper-silver series sterilized polyamide fabric, copper-silver series sterilized nylon fabric and copper-silver series sterilized ammonia fabric.
EXAMPLE III
Respectively weaving and blending a copper-silver series sterilized polypropylene fiber coil (barrel) or a copper-silver series sterilized acrylic fiber coil (barrel) or a copper-silver series sterilized nylon fiber coil (barrel) or a copper-silver series sterilized spandex fiber coil (barrel) with cotton threads or wool threads or real silk by an air-jet loom or a shuttle loom to prepare copper-silver series sterilized blended fabric: copper-silver series sterilized cotton-acrylic cloth or copper-silver series sterilized cotton-polyester cloth or copper-silver series sterilized cotton-acrylic cloth or copper-silver series sterilized cotton-polyamide cloth; two or three of copper-silver series sterilized polypropylene fiber roll (barrel) or copper-silver series sterilized acrylic fiber roll (barrel) or copper-silver series sterilized nylon fiber roll (barrel) or copper-silver series sterilized spandex fiber roll (barrel) are mixed and woven by an air flow weaving machine or a shuttle weaving machine to obtain the copper-silver series sterilized chemical fiber blended fabric.
Example four
Respectively winding a copper-silver series sterilized polypropylene fiber coil (barrel) or a copper-silver series sterilized acrylic fiber coil (barrel) or a copper-silver series sterilized nylon fiber coil (barrel) or a copper-silver series sterilized spandex fiber coil (barrel) with cotton threads or wool threads or silk threads to form a copper-silver series sterilized core covering wire: the copper-silver series sterilized polypropylene fiber covered cotton thread or the copper-silver series sterilized acrylic fiber covered cotton thread or the copper-silver series sterilized nylon covered cotton thread or the copper-silver series sterilized spandex covered cotton thread or the copper-silver series sterilized polypropylene fiber covered wool thread or the copper-silver series sterilized acrylic fiber covered wool thread or the copper-silver series sterilized nylon covered wool thread or the copper-silver series sterilized spandex covered wool thread or the copper-silver series sterilized polypropylene fiber covered silk thread or the copper-silver series sterilized nylon covered silk thread or the copper-silver series sterilized spandex covered silk thread.
EXAMPLE five
The sterilizing and deodorizing underwear, sterilizing and deodorizing underpants, sterilizing and mildew-proof warm-keeping underwear, sterilizing and mildew-proof outerwear, sterilizing and mildew-proof down jackets, sterilizing and mildew-proof down coats, sterilizing and mildew-proof down wadded trousers, sterilizing and mildew-proof T shirts, sterilizing and mildew-proof jackets, sterilizing and mildew-proof tights, sterilizing and shaping conjoined underwear, sterilizing and mildew-proof woolen overcoat, sterilizing and mildew-proof suit, sterilizing and mildew-proof bra, sterilizing and mildew-proof middle-length gown, sterilizing and mildew-proof Zhongshan gown, sterilizing and mildew-proof spring suit, sterilizing and mildew-proof autumn suit, sterilizing and mildew-proof underwear, sterilizing and shaping underwear, and sterilizing and mildew-proof underwear, and sterilizing, Copper-silver series sterilized sanitary napkins, copper-silver series sterilized tampons, and the like.
EXAMPLE six
Various socks are knitted by adopting copper-silver series sterilized chemical fiber or copper-silver series sterilized core-spun yarns through a sock knitting machine to prepare various copper-silver series sterilized deodorizing socks.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to cover the technical scope of the present invention, the equivalent substitution or change according to the technical solution and the concept of the present invention within the technical scope of the present invention.
Claims (8)
1. A copper-silver series sterilization and deodorization artificial silk thread and a manufacturing method and application thereof are characterized by comprising the following steps: one or more of simple substance copper, copper oxide, cuprous oxide and copper salt nano powder or particles are combined to form a copper series sterilizing agent, 1.8 to 40 weight percent of copper series sterilizing agent is correspondingly doped into 93 to 40 weight percent of polymer, terylene, polypropylene, acrylic fiber, nylon or spandex nano powder or master batch, 5 to 10 weight percent of compatilizer, 0.1 to 6 percent of dispersing agent and 0.1 to 4 percent of antioxidant are added, the sum of the raw materials is 100 percent, the mixture is put into a high-speed mixer to be mixed for 2 to 10 minutes, the mixture is put into a melting screw extruder, the processing temperature is 160 to 320 ℃, the rotating speed of the screw is 180 to 800 revolutions per minute, and the copper series sterilizing polymer which is uniformly dispersed, highly compatible and mutually adhered is respectively formed by melting, The melt of the copper series sterilized terylene or copper series sterilized polypropylene fiber or copper series sterilized acrylic fiber or copper series sterilized nylon or copper series sterilized spandex has a melt index of 0.8-40g/10min, and is prepared into a copper series sterilized polymer yarn roll (barrel), a copper series sterilized terylene yarn roll (barrel), a copper series sterilized polypropylene fiber roll (barrel), a copper series sterilized acrylic fiber roll (barrel), a copper series sterilized nylon yarn roll (barrel), a copper series sterilized spandex yarn roll (barrel) through extrusion, high-pressure spinning or spinning, spinning cooling and blowing, spinning oiling, winding, traction and winding.
2. A copper-silver series sterilization and deodorization artificial silk thread and a manufacturing method and application thereof are characterized by comprising the following steps: the sterilizing agent is prepared by mixing 2-60 wt% of the sterilizing agent into 98-40 wt% of polymer, terylene, polypropylene fiber, acrylic fiber, nylon or spandex nano powder or master batch, performing multiple polymerization reactions and/or multiple esterification and/or polycondensation and other grafting modification to obtain a copper-silver sterilizing polymer master batch, a copper-silver sterilizing polyester master batch, a copper-silver sterilizing polypropylene master batch, a copper-silver sterilizing acrylic master batch, a copper-silver sterilizing nylon master batch, a copper-silver sterilizing spandex master batch, a copper-silver sterilizing nylon master batch, a copper-silver sterilizing spandex master batch, a melt high-pressure spinning or spinning at 260-350 ℃, cooling and blowing, Spinning, oiling, winding, traction and rolling to prepare a copper-silver series sterilization polymer yarn roll (barrel), a copper-silver series sterilization polyester yarn roll (barrel), a copper-silver series sterilization polypropylene yarn roll (barrel), a copper-silver series sterilization acrylic yarn roll (barrel), a copper-silver series sterilization polyamide yarn roll (barrel), a copper-silver series sterilization nylon yarn roll (barrel) and a copper-silver series sterilization spandex yarn roll (barrel).
3. The copper-silver series sterilization and deodorization artificial silk thread as well as the manufacturing method and the application thereof according to claim 1 are characterized in that: the compatilizer is polypropylene grafted maleic anhydride (PP-g-MAH) with the melt index of 1-150g/10min and the grafting rate of 0.5-1%, the dispersant is organic wax or stearic acid amide which can be any single component or a mixed component, the organic wax and the stearic acid amide, the organic wax comprises polyethylene wax, the proportion of the mixed component is 0.1-99.9%, the antioxidant is hindered phenol antioxidant or is compounded with phosphite antioxidant, the hindered phenol antioxidant is 1010, and the hindered phenol antioxidant and the phosphite antioxidant are compounded into 1010/168 of 1: 1; the copper-silver series sterilizing agent also comprises: one or more of glass silver-loaded hydroxyl zirconium sodium phosphate containing silver ions, elementary copper, copper oxide, cuprous oxide and copper salt nano powder or particles are combined to form the copper-silver series sterilizing agent.
4. The copper-silver series sterilization and deodorization artificial silk thread as claimed in claim 1, 2 or 3, and the manufacturing method and application thereof, characterized in that: weaving and weaving a copper-silver series sterilized polypropylene fiber coil (barrel) or a copper-silver series sterilized acrylic fiber coil (barrel) or a copper-silver series sterilized nylon fiber coil (barrel) or a copper-silver series sterilized spandex fiber coil (barrel) through an air-jet loom or a shuttle loom respectively to prepare the copper-silver series sterilized chemical fiber cloth: the polyamide fabric is made of copper-silver series sterilized polypropylene fabric, copper-silver series sterilized nitrile fabric, copper-silver series sterilized polyamide fabric, copper-silver series sterilized nylon fabric and copper-silver series sterilized ammonia fabric.
5. The copper-silver series sterilization and deodorization artificial silk thread as claimed in claim 1, 2 or 3, and the manufacturing method and application thereof, characterized in that: respectively weaving and blending a copper-silver series sterilized polypropylene fiber coil (barrel) or a copper-silver series sterilized acrylic fiber coil (barrel) or a copper-silver series sterilized nylon fiber coil (barrel) or a copper-silver series sterilized spandex fiber coil (barrel) with cotton threads or wool threads or real silk by an air-jet loom or a shuttle loom to prepare copper-silver series sterilized blended fabric: copper-silver series sterilized cotton-acrylic cloth or copper-silver series sterilized cotton-polyester cloth or copper-silver series sterilized cotton-acrylic cloth or copper-silver series sterilized cotton-polyamide cloth; two or three of copper-silver series sterilized polypropylene fiber roll (barrel) or copper-silver series sterilized acrylic fiber roll (barrel) or copper-silver series sterilized nylon fiber roll (barrel) or copper-silver series sterilized spandex fiber roll (barrel) are mixed and woven by an air flow weaving machine or a shuttle weaving machine to obtain the copper-silver series sterilized chemical fiber blended fabric.
6. The copper-silver series sterilization and deodorization artificial silk thread as claimed in claim 1, 2 or 3, and the manufacturing method and application thereof, characterized in that: respectively winding a copper-silver series sterilized polypropylene fiber coil (barrel) or a copper-silver series sterilized acrylic fiber coil (barrel) or a copper-silver series sterilized nylon fiber coil (barrel) or a copper-silver series sterilized spandex fiber coil (barrel) with cotton threads or wool threads or silk threads to form a copper-silver series sterilized core covering wire: the copper-silver series sterilized polypropylene fiber covered cotton thread or the copper-silver series sterilized acrylic fiber covered cotton thread or the copper-silver series sterilized nylon covered cotton thread or the copper-silver series sterilized spandex covered cotton thread or the copper-silver series sterilized polypropylene fiber covered wool thread or the copper-silver series sterilized acrylic fiber covered wool thread or the copper-silver series sterilized nylon covered wool thread or the copper-silver series sterilized spandex covered wool thread or the copper-silver series sterilized polypropylene fiber covered silk thread or the copper-silver series sterilized nylon covered silk thread or the copper-silver series sterilized spandex covered silk thread.
7. The copper-silver series sterilization and deodorization artificial silk thread as claimed in claim 1, 2 or 3, and the manufacturing method and application thereof, characterized in that: the sterilizing and deodorizing underwear, sterilizing and deodorizing underpants, sterilizing and mildew-proof warm underwear, sterilizing and mildew-proof coat, sterilizing and mildew-proof trousers, sterilizing and mildew-proof down coat, sterilizing and mildew-proof down pants, sterilizing and mildew-proof T, sterilizing and mildew-proof jacket, sterilizing and mildew-proof bra, sterilizing and beautifying body close-fitting underwear, sterilizing and beautifying body-shaping one-piece underwear, sterilizing and mildew-proof woolen overcoat, sterilizing and mildew-proof suit, sterilizing and mildew-proof wind coat, sterilizing and mildew-proof midlength coat, sterilizing and mildew-proof Zhongshan coat, sterilizing and mildew-proof spring coat, sterilizing and mildew-proof autumn coat, sterilizing and mildew-proof underwear, and disinfecting and mildew-proof underwear, and sterilizing, Copper-silver series sterilized sanitary napkins and copper-silver series sterilized tampons.
8. The copper-silver series sterilization and deodorization artificial silk thread as claimed in claim 1, 2 or 3, and the manufacturing method and application thereof, characterized in that: various socks are knitted by adopting copper-silver series sterilized chemical fiber or copper-silver series sterilized core-spun yarns through a sock knitting machine to prepare various copper-silver series sterilized deodorizing socks.
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