CN113062006B - Environment-friendly composite textile material and preparation method thereof - Google Patents
Environment-friendly composite textile material and preparation method thereof Download PDFInfo
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- CN113062006B CN113062006B CN202110359982.3A CN202110359982A CN113062006B CN 113062006 B CN113062006 B CN 113062006B CN 202110359982 A CN202110359982 A CN 202110359982A CN 113062006 B CN113062006 B CN 113062006B
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- 239000004753 textile Substances 0.000 title claims abstract description 70
- 239000000463 material Substances 0.000 title claims abstract description 68
- 239000002131 composite material Substances 0.000 title claims abstract description 65
- 238000002360 preparation method Methods 0.000 title claims abstract description 27
- 239000000835 fiber Substances 0.000 claims abstract description 177
- 238000009987 spinning Methods 0.000 claims abstract description 31
- 238000001035 drying Methods 0.000 claims abstract description 17
- 238000002156 mixing Methods 0.000 claims abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 16
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 15
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 15
- 241001330002 Bambuseae Species 0.000 claims abstract description 15
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 15
- 239000011425 bamboo Substances 0.000 claims abstract description 15
- 229920000747 poly(lactic acid) Polymers 0.000 claims abstract description 14
- 239000004626 polylactic acid Substances 0.000 claims abstract description 14
- 238000004140 cleaning Methods 0.000 claims abstract description 10
- 238000002074 melt spinning Methods 0.000 claims abstract description 9
- 210000002268 wool Anatomy 0.000 claims abstract description 3
- 239000011435 rock Substances 0.000 claims description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 30
- 239000002245 particle Substances 0.000 claims description 27
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 26
- 239000000243 solution Substances 0.000 claims description 24
- 238000007664 blowing Methods 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 17
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 13
- 239000008367 deionised water Substances 0.000 claims description 10
- 229910021641 deionized water Inorganic materials 0.000 claims description 10
- 239000012670 alkaline solution Substances 0.000 claims description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 8
- 239000002202 Polyethylene glycol Substances 0.000 claims description 8
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 8
- VCNTUJWBXWAWEJ-UHFFFAOYSA-J aluminum;sodium;dicarbonate Chemical compound [Na+].[Al+3].[O-]C([O-])=O.[O-]C([O-])=O VCNTUJWBXWAWEJ-UHFFFAOYSA-J 0.000 claims description 8
- 150000001408 amides Chemical class 0.000 claims description 8
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 8
- 229910000388 diammonium phosphate Inorganic materials 0.000 claims description 8
- 235000019838 diammonium phosphate Nutrition 0.000 claims description 8
- 239000000839 emulsion Substances 0.000 claims description 8
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 8
- 229920001223 polyethylene glycol Polymers 0.000 claims description 8
- -1 polyoxyethylene Polymers 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 238000004804 winding Methods 0.000 claims description 6
- NMDQPQZRIKCRDU-UHFFFAOYSA-N 3-chloro-2-dodecylpyridine Chemical compound CCCCCCCCCCCCC1=NC=CC=C1Cl NMDQPQZRIKCRDU-UHFFFAOYSA-N 0.000 claims description 4
- 238000007654 immersion Methods 0.000 claims description 4
- 238000005470 impregnation Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 229910017604 nitric acid Inorganic materials 0.000 claims description 3
- 238000010298 pulverizing process Methods 0.000 claims description 3
- 238000007873 sieving Methods 0.000 claims description 3
- 238000009826 distribution Methods 0.000 claims description 2
- 238000001125 extrusion Methods 0.000 claims description 2
- 230000035699 permeability Effects 0.000 abstract description 16
- 238000010521 absorption reaction Methods 0.000 abstract description 12
- 230000000694 effects Effects 0.000 abstract description 8
- 239000002699 waste material Substances 0.000 abstract description 8
- 239000000203 mixture Substances 0.000 abstract description 7
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 238000004040 coloring Methods 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 3
- 230000009467 reduction Effects 0.000 abstract description 2
- 239000011363 dried mixture Substances 0.000 abstract 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 71
- 229920000139 polyethylene terephthalate Polymers 0.000 description 70
- 229920000728 polyester Polymers 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 9
- 239000004744 fabric Substances 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 238000011161 development Methods 0.000 description 7
- 230000018109 developmental process Effects 0.000 description 7
- 230000008859 change Effects 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000007788 roughening Methods 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 238000007598 dipping method Methods 0.000 description 3
- 238000004043 dyeing Methods 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 230000009471 action Effects 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000009940 knitting Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 206010004542 Bezoar Diseases 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 230000008642 heat stress Effects 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- FJQXCDYVZAHXNS-UHFFFAOYSA-N methadone hydrochloride Chemical compound Cl.C=1C=CC=CC=1C(CC(C)N(C)C)(C(=O)CC)C1=CC=CC=C1 FJQXCDYVZAHXNS-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
- D06M11/71—Salts of phosphoric acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
- D10B2201/10—Bamboo
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
- Y02P70/62—Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses an environment-friendly composite textile material and a preparation method thereof, and relates to the technical field of textile materials. The invention discloses an environment-friendly composite textile material which is prepared from the following raw materials in parts by weight: 60-80 parts of regenerated PET modified fiber, 10-20 parts of bamboo fiber, 10-20 parts of polylactic acid fiber and a proper amount of fiber impregnating solution; the preparation method comprises the steps of mixing the regenerated PET modified fiber and the bamboo fiber in a wool mixing machine, then placing the mixture in a fiber impregnating solution, taking out the mixture after impregnating for a period of time, airing the mixture, cleaning the mixture, drying the dried mixture, adding the mixture and polylactic acid fiber into a high-speed mixer, and carrying out melt spinning to obtain the fiber. The environment-friendly composite textile material has high strength, excellent toughness, hydrophilicity, air permeability and coloring effect, and good moisture absorption quick-drying property and elasticity; the textile material is made of the regenerated PET fiber and the environment-friendly material, has wide sources and low cost, has good spinning effect, reasonably utilizes the recycled waste resources, reduces environmental pollution, and achieves the purposes of environmental protection and resource consumption reduction.
Description
Technical Field
The invention belongs to the technical field of textile materials, and particularly relates to an environment-friendly composite textile material and a preparation method thereof.
Background
With the rapid development of textile industry in China, the problem of textile materials becomes a bottleneck for preventing the development of the textile materials. With the concept of recycling economy, energy conservation and environmental protection going deep into people's daily life, natural fibers have become a development trend, but the growth rate of natural fibers is far from keeping up with the development rate of textile industry, but textile materials on the market at present are mainly chemical fibers, but the production of chemical fibers presents staged and structural surplus productivity, and a large amount of production can bring about huge environmental pollution, which does not accord with the national conditions of sustainable development of China. In recent years, the development of the polyester industry in China is rapid, the productivity is more than 40% of the world proportion, but the high-efficiency utilization and recovery of polyester are far from those in foreign countries, and particularly the PET recovery and utilization ratio in China is low, and the environment-friendly concept is not compounded, so that the recovery of PET fibers changes waste into valuables, not only accords with the environment-friendly concept, but also plays a very important role in solving the problem of social resource shortage in China.
The source of the regenerated PET fiber raw material mainly comprises waste drinking water and beverage packaging bottles, films, clothes and non-woven fabrics, waste silk, waste blocks and the like generated in the production process of polyester and fiber, wherein the polyester bottle flakes are used as the main source. The regenerated PET fiber has special high molecular structure, low production cost, light weight, high strength, high modulus, no toxicity, high impact strength, acid resistance, oxidation resistance and other advantages, and has wide application range. The regenerated polyester industry in China starts to develop before 40 years, but the industry gradually matures and develops in recent years, the level of development and utilization of the recycled polyester by domestic enterprises is insufficient, scientific research investment liquid for bottle-grade polyester re-spinning technology is insufficient, the quality of the recycled polyester is difficult to meet the requirements of textile fibers, and the recycled polyester is mostly used as a general filling material. The intrinsic viscosity of the existing PET product is generally not more than 0.7dL/g, and then the intrinsic viscosity of the PET product is reduced under the action of heat stress in the preparation process of the PET product, and in the recycling process, slow thermal degradation and hydrolysis can occur when the PET product is contacted with water, acid, alkali, alcohol and the like, so that the molecular weight and the intrinsic viscosity of the polyester are further reduced. Therefore, the regenerated PET fiber must be pretreated to meet the requirements of intrinsic viscosity, molecular weight, crystallinity and the like before spinning. The existing regenerated PET fiber has very low moisture regain, poor moisture absorption and quick drying properties, high fiber strength, small elongation at break, namely high rigidity and small elasticity, and has the defects of similar terylene, namely low moisture content, poor air permeability, poor dyeing property, easy pilling and fuzzing, easy contamination and the like. Therefore, the regenerated PET fiber needs to be modified at present, and an environment-friendly composite textile material which has good spinning property and excellent comprehensive performance and can utilize the regenerated PET fiber is developed.
Disclosure of Invention
The invention aims to provide an environment-friendly composite textile material which has high strength, excellent toughness, hydrophilicity, air permeability and coloring effect, and good moisture absorption quick-drying property and elasticity; the textile material is made of the regenerated PET fiber and the environment-friendly material, has wide sources and low cost, has good spinning effect, reasonably utilizes the recycled waste resources, reduces environmental pollution, and achieves the purposes of environmental protection and resource consumption reduction.
In order to achieve the aim of the invention, the invention provides an environment-friendly composite textile material, which is prepared from the following raw materials in parts by weight: 60-80 parts of regenerated PET modified fiber, 10-20 parts of bamboo fiber, 10-20 parts of polylactic acid fiber and fiber impregnating solution, wherein the solid-liquid ratio is 1: (10-50).
The preparation method of the composite textile material specifically comprises the following steps:
(1) And (3) placing the regenerated PET modified fiber and the bamboo fiber in a wool blending machine, and mixing for 0.5h at normal temperature to obtain the mixed fiber.
The specific preparation method of the regenerated PET modified fiber comprises the following steps:
p1 adding 0.5g/L dodecylpyridine chloride solution into 0.4mol/L NaOH solution, stirring at 120-150r/min for 5-10min to obtain alkaline solution; immersing the regenerated PET fiber in the alkaline solution for 30min at 70-80 ℃, taking out and drying to obtain the regenerated PET fiber with the surface modified;
p2, selecting appropriate amount of volcanic rock, pulverizing, sieving with 100 mesh sieve to obtain volcanic rock particles, placing volcanic rock particles in 2mol/L dilute nitric acid solution, stirring for 10-20min, filtering, cleaning with deionized water, and drying at 100deg.C for 2 hr to obtain pretreated volcanic rock particles;
and P3, firstly stirring the pretreated volcanic rock particles, nano calcium carbonate and polyoxyethylene amide in a mixer for 30min, then adding the surface-modified regenerated PET fibers and vinyl trimethoxy silane, stirring at 50-60 ℃ for 30min, introducing into a double-screw extruder, and treating by a melt distributing pipe, a spinning box, a metering pump, a composite spinning assembly, a side blowing, bundling and oiling, winding and chemical fiber to obtain the regenerated PET modified fibers.
(2) And (3) placing the mixed fiber in a fiber dipping solution, dipping for 10-18 hours at 40-50 ℃, taking out and airing after dipping, cleaning for three times by deionized water, and drying to obtain the treated mixed fiber.
(3) Adding the treated mixed fiber and polylactic acid fiber into a high-speed mixer, mixing for 1h at 50 ℃, and carrying out melt spinning to obtain the composite textile material.
Further, the fiber impregnating solution comprises the following raw materials in percentage by mass: 0.8 to 1.6 percent of sulfosuccinate, 4 to 8 percent of EVA emulsion, 1.6 to 2.5 percent of diammonium hydrogen phosphate, 0.5 to 1.2 percent of basic aluminum sodium carbonate, 5 to 10 percent of polyethylene glycol, 20 to 30 percent of ethanol and the balance of water.
Further, the fiber impregnating solution comprises the following raw materials in percentage by mass: 1.2% of sulfosuccinate, 5.6% of EVA emulsion, 2.1% of diammonium hydrogen phosphate, 0.6% of basic aluminum sodium carbonate, 8.3% of polyethylene glycol, 22% of ethanol and the balance of water.
Further, in the preparation method of the regenerated PET modified fiber, the mass of the nano calcium carbonate is 10-15% of the mass of the pretreated volcanic rock particles, the mass of the polyoxyethylene amide is 5-8% of the mass of the pretreated volcanic rock particles, the mass of the pretreated volcanic rock particles is 8-12% of the mass of the surface modified regenerated PET fiber, and the mass of the vinyl trimethoxy silane is 0.5-0.8% of the mass of the surface modified regenerated PET fiber.
Further, in the preparation method of the regenerated PET modified fiber, the extrusion temperature of the twin-screw extruder in the P3 is 260-280 ℃.
Further, in the step (3), the process parameters of the melt spinning are as follows: the spinning temperature is 250-275 ℃, the side blowing cooling air temperature is 25 ℃, the side blowing air speed is 1m/s, the spinning speed is 2500-3800m/min, and the draft ratio is 2.0-5.0.
The invention has the following beneficial effects:
1. the composite textile material is prepared from the regenerated PET modified fiber, the bamboo fiber and the polylactic acid fiber, wherein the regenerated PET modified fiber is prepared by modifying the regenerated PET fiber, and the regenerated PET fiber is a resource recovered and reused by waste polyester, so that waste is changed into valuable, the cost is saved, the environment is protected, the resource is saved, and the composite textile material has excellent performances of better strength, acid and alkali resistance, oxidation resistance and the like; the bamboo fiber is a natural material, is biodegradable, and has good air permeability, water absorbability, wear resistance and coloring effect, so that the air permeability, water absorbability and dyeing property of the composite textile material are improved by the proportion of the bamboo fiber; the polylactic acid fiber is a biodegradable synthetic fiber, has good biocompatibility, strength and heat resistance, improves the compatibility among all components in the composite textile material, further improves the strength and heat resistance of the composite textile material, and increases the environmental degradation performance of the composite textile material.
2. According to the invention, the regenerated PET fiber is modified by the alkaline solution, and under the action of the alkaline solution and the cationic surfactant (dodecylpyridine chloride), the internal gaps and pits of the regenerated PET fiber are increased, the specific surface area of the regenerated PET fiber is increased, and the compatibility and adsorptivity between the regenerated PET fiber and other components are improved, so that the moisture absorption and quick drying performance of the composite textile fiber is improved; the concentration of the alkaline solution can also ensure that the strength of the regenerated PET fiber is reduced to the minimum, and the regenerated PET fiber still has good strength.
3. The pretreated volcanic rock is added into the regenerated PET modified fiber, so that the heat preservation and insulation performance, fire resistance and corrosion resistance of the composite textile material are improved, the strength of the regenerated PET modified fiber is further improved, the volcanic rock has a plurality of holes and light weight, the regenerated PET modified fiber has a very high specific surface area, and the air permeability of the composite textile material is increased; the nano calcium carbonate is added into the regenerated PET modified fiber, the surface of the nano calcium carbonate is oleophylic and hydrophobic, the compatibility among the components is improved, the toughness, the dimensional stability and the heat resistance of the composite textile fiber are improved, the spinning effect is improved, the reinforcing and toughening effects are achieved, the porosity of the regenerated PET modified fiber is reduced, and the composite PET modified fiber has excellent air permeability and excellent heat insulation effect.
4. The mixed fiber is immersed in the fiber impregnating solution, so that the mixed fiber is adhered with flame retardant, hydrophilic and other components, the compatibility between the mixed fiber and the polylactic acid fiber is increased, the spinning property of the regenerated PET fiber is improved, the fiber has excellent flame retardance, aging resistance, light resistance and hydrophilicity, and the toughness and strength of the fiber are improved.
5. The raw materials used in the invention are wide in sources, environment-friendly and easy to degrade, and the composite textile material has excellent flame retardance, strength, toughness, hygroscopicity, air permeability, soft hand feeling, good dyeing property and excellent ageing resistance, and can be used in the fields of medical treatment, clothing, daily necessities and the like.
Detailed Description
The following description of the embodiments of the present invention will be made clearly and completely, and it is apparent that the described embodiments are only some embodiments of the present invention, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
The solid-liquid ratio in the invention refers to the ratio between the mass sum of the regenerated PET modified fiber and the bamboo fiber and the mass of the fiber impregnating solution.
The following describes an environment-friendly composite textile material and a preparation method thereof in connection with specific examples.
Example 1 an environmentally friendly composite textile Material
The preparation method of the environment-friendly composite textile material comprises the following steps: placing 600g of regenerated PET modified fiber and 200g of bamboo fiber in a roughening machine, and mixing for 30min to obtain mixed fiber; immersing the mixed fiber in 40kg of fiber immersion liquid for 10 hours at 50 ℃, taking out and airing after immersion, cleaning for three times by deionized water, and drying to obtain treated mixed fiber; adding the treated mixed fiber and 200g polylactic acid fiber into a high-speed mixer, mixing for 1h at 50 ℃, carrying out melt spinning, wherein the spinning temperature is 250 ℃, the side blowing cooling air temperature is 25 ℃, the side blowing air speed is 1m/s, the spinning speed is 2800m/min, and the draft ratio is 4, so as to prepare the composite textile material.
The specific preparation method of the regenerated PET modified fiber comprises the following steps:
p1. adding 0.5g/L of 1L dodecylpyridine chloride solution into 0.4mol/L of 1LNaOH solution, and stirring at a speed of 120-150r/min for 5-10min to obtain alkaline solution. Immersing the regenerated PET fiber (commercially available) in the alkaline solution for 30min at 70-80 ℃, taking out and drying to obtain the regenerated PET fiber with modified surface.
P2 selecting appropriate amount of volcanic rock, pulverizing, sieving with 100 mesh sieve to obtain volcanic rock particles, placing volcanic rock particles in 2mol/L dilute nitric acid solution, stirring for 10-20min, filtering, cleaning with deionized water, and drying at 100deg.C for 2 hr to obtain pretreated volcanic rock particles.
And P3, firstly stirring 120g of pretreated volcanic rock particles, 18g of nano calcium carbonate and 9.6g of polyoxyethylene amide in a mixer for 30min, then adding 1kg of surface modified regenerated PET fibers and 5g of vinyl trimethoxy silane, stirring for 30min at 50-60 ℃, introducing into a double screw extruder, extruding at 260-280 ℃, and preparing the regenerated PET modified fibers through melt distribution pipes, spinning beams, metering pumps, composite spinning components, cross-blowing, bundling and oiling, winding and chemical fiber treatment.
The fiber impregnating solution comprises the following raw materials in percentage by mass: 1.6% of sulfosuccinate, 4% of EVA emulsion, 2.5% of diammonium hydrogen phosphate, 0.8% of basic aluminum sodium carbonate, 10% of polyethylene glycol, 20% of ethanol and the balance of water.
Example 2 an environmentally friendly composite textile Material
The preparation method of the environment-friendly composite textile material comprises the following steps: placing 800g of regenerated PET modified fiber and 100g of bamboo fiber in a roughening machine, and mixing for 30min to obtain mixed fiber; placing the mixed fiber in 9kg of fiber impregnating solution, impregnating for 18 hours at 40 ℃, taking out and airing after impregnation, cleaning for three times by deionized water, and drying to obtain treated mixed fiber; adding the treated mixed fiber and 100g polylactic acid fiber into a high-speed mixer, mixing for 1h at 50 ℃, carrying out melt spinning, wherein the spinning temperature is 275 ℃, the side blowing cooling air temperature is 25 ℃, the side blowing air speed is 1m/s, the spinning speed is 2500m/min, and the draft ratio is 5, so as to obtain the composite textile material.
The specific preparation method of the regenerated PET modified fiber comprises the following steps:
p1. a surface-modified recycled PET fiber was prepared in the same manner as in example 1, with specific reference to example 1.
P2. pretreated volcanic rock particles were prepared in the same manner as in example 1, with specific reference to example 1.
And P3, firstly stirring 80g of pretreated volcanic rock particles, 8g of nano calcium carbonate and 4g of polyoxyethylene amide in a mixer for 30min, then adding 1kg of surface modified regenerated PET fibers and 8g of vinyl trimethoxy silane, stirring for 30min at 50-60 ℃, introducing into a double screw extruder, extruding at 260-280 ℃, and treating by using a melt distributing pipe, a spinning box, a metering pump, a composite spinning component, a side blowing, bundling and oiling, winding and chemical fiber to obtain the regenerated PET modified fibers.
The fiber impregnating solution comprises the following raw materials in percentage by mass: 0.8% of sulfosuccinate, 8% of EVA emulsion, 1.6% of diammonium hydrogen phosphate, 1.2% of basic aluminum sodium carbonate, 5% of polyethylene glycol, 30% of ethanol and the balance of water.
Example 3 an environmentally friendly composite textile Material
The preparation method of the environment-friendly composite textile material comprises the following steps: placing 700g of regenerated PET modified fiber and 100g of bamboo fiber in a roughening machine, and mixing for 30min to obtain mixed fiber; placing the mixed fiber in 24kg fiber impregnating solution, impregnating for 15 hours at 50 ℃, taking out and airing after impregnation, cleaning for three times by deionized water, and drying to obtain treated mixed fiber; adding the treated mixed fiber and 200g polylactic acid fiber into a high-speed mixer, mixing for 1h at 50 ℃, carrying out melt spinning, wherein the spinning temperature is 260 ℃, the side blowing cooling air temperature is 25 ℃, the side blowing air speed is 1m/s, the spinning speed is 3800m/min, and the draft ratio is 2, so as to prepare the composite textile material.
The specific preparation method of the regenerated PET modified fiber comprises the following steps:
p1. a surface-modified recycled PET fiber was prepared in the same manner as in example 1, with specific reference to example 1.
P2. pretreated volcanic rock particles were prepared in the same manner as in example 1, with specific reference to example 1.
And P3, firstly stirring 100g of pretreated volcanic rock particles, 12g of nano calcium carbonate and 6g of polyoxyethylene amide in a mixer for 30min, then adding 1kg of surface modified regenerated PET fibers and 6.4g of vinyl trimethoxy silane, stirring for 30min at 50-60 ℃, introducing into a double screw extruder, extruding at 260-280 ℃, and preparing the regenerated PET modified fibers after melt distributing pipes, spinning beams, metering pumps, composite spinning components, cross blowing, bundling and oiling, winding and chemical fiber treatment.
The fiber impregnating solution comprises the following raw materials in percentage by mass: 1.0% of sulfosuccinate, 6.3% of EVA emulsion, 2.2% of diammonium hydrogen phosphate, 0.5% of basic aluminum sodium carbonate, 8.6% of polyethylene glycol, 23% of ethanol and the balance of water.
Example 4 an environmentally friendly composite textile Material
The preparation method of the environment-friendly composite textile material comprises the following steps: placing 700g of regenerated PET modified fiber and 150g of bamboo fiber in a roughening machine, and mixing for 30min to obtain mixed fiber; placing the mixed fiber in 30kg of fiber impregnating solution, impregnating for 15 hours at 50 ℃, taking out and airing after impregnation, cleaning for three times by deionized water, and drying to obtain treated mixed fiber; adding the treated mixed fiber and 150g polylactic acid fiber into a high-speed mixer, mixing for 1h at 50 ℃, carrying out melt spinning, wherein the spinning temperature is 265 ℃, the side blowing cooling air temperature is 25 ℃, the side blowing air speed is 1m/s, the spinning speed is 3200m/min, and the draft ratio is 3.6, so as to prepare the composite textile material.
The specific preparation method of the regenerated PET modified fiber comprises the following steps:
p1. a surface-modified recycled PET fiber was prepared in the same manner as in example 1, with specific reference to example 1.
P2. pretreated volcanic rock particles were prepared in the same manner as in example 1, with specific reference to example 1.
And P3, firstly stirring 110g of pretreated volcanic rock particles, 14.3g of nano calcium carbonate and 7.7g of polyoxyethylene amide in a mixer for 30min, then adding 1kg of surface modified regenerated PET fibers and 5.8g of vinyl trimethoxy silane, stirring for 30min at 50-60 ℃, introducing into a double screw extruder, extruding at 260-280 ℃, and processing by using a melt distributing pipe, a spinning box, a metering pump, a composite spinning assembly, a side blowing, bundling, oiling, winding and chemical fiber to obtain the regenerated PET modified fibers.
The fiber impregnating solution comprises the following raw materials in percentage by mass: 1.2% of sulfosuccinate, 5.6% of EVA emulsion, 2.1% of diammonium hydrogen phosphate, 0.6% of basic aluminum sodium carbonate, 8.3% of polyethylene glycol, 22% of ethanol and the balance of water.
Example 5 an environmentally friendly composite textile Material
The preparation method of the environment-friendly composite textile material is the same as that of example 4, except that the regenerated PET modified fiber is 700g, the bamboo fiber is 200g, and the polylactic acid fiber is 100g.
Comparative example 1 an environmentally friendly composite textile material
The raw material composition and preparation method of the environment-friendly composite textile material were the same as in example 4, except that not the recycled PET modified fiber but the unmodified commercial recycled PET fiber was used.
Comparative example 2 an environmentally friendly composite textile material
The raw material composition and the preparation method of the environment-friendly composite textile material are the same as those of the example 4, except that the pretreated volcanic rock particles are not added into the regenerated PET modified fiber, and other components and operation steps are unchanged.
Comparative example 3 an environmentally friendly composite textile material
The raw material components and the preparation method of the environment-friendly composite textile material are the same as those of the example 4, except that nano calcium carbonate is not added into the regenerated PET modified fiber, and other components and operation steps are unchanged.
The mechanical properties of the environment-friendly composite textile materials prepared according to the above examples 1 to 5 and comparative examples 1 to 3 were tested, and the test results are shown in table 1 below.
Table 1 results of mechanical property test of environment-friendly composite textile materials
As can be seen from the mechanical property detection results in Table 1, the environment-friendly composite textile material has better breaking strength and elongation at break, and has higher initial modulus, namely, the textile material prepared from the textile material has soft hand feeling and is not easy to deform. According to the invention, the regenerated PET fiber is modified, so that the breaking strength and the elongation of the composite textile material are improved, and the composite textile material has good hand feeling and elasticity and good strength. The invention adds pretreated volcanic rock particles or nano calcium carbonate to improve the strength of the composite textile material.
The environment-friendly composite textile materials prepared in the examples 1-5 and the comparative examples 1-3 are woven into fiber fabrics on a weft knitting circular knitting machine, the weave structure of the fiber fabrics is weft flat weave, namely the fiber fabrics are manufactured by adopting the same weaving process, weave structure and post-finishing technology, and the density of the fiber fabrics is as follows: the transverse density/5 cm was 55, and the longitudinal density/5 cm was 65. The fabrics manufactured in examples 1 to 5 and comparative examples 1 to 3 were subjected to water absorption, air permeability, anti-pilling property test, and the test results are shown in Table 2.
Water absorption: and placing the sample in deionized water for soaking for 5min, taking out and suspending until the time interval between two drops is not less than 30s, and calculating the water absorption.
Wherein A is water absorption,%; m is the mass of the sample after no water drops,g;M 0 g is the initial mass of the sample.
Air permeability test: the detection was carried out using the provisions of GB/T5435-1997 test for air permeability of fabrics.
Fuzzing and pilling resistance test: the experiment was carried out by using YG401G Martindale fuzzing and pilling instrument, placing the round sample in standard atmosphere to be subjected to humidity control for 24 hours, then clamping the sample in a clamp holder, setting the friction times to be 50 times, setting the friction pressure to be 160G, and taking the average value of 5 friction tests.
Table 2 results of performance testing of fibrous webs
Air permeability (mm/s) | Water absorption (%) | Anti-pilling property | |
Example 1 | 3690 | 279.5 | No change |
Example 2 | 3740 | 268.4 | No change |
Example 3 | 3570 | 289.6 | No change |
Example 4 | 3910 | 310.5 | No change |
Example 5 | 3860 | 297.6 | No change |
Comparative example 1 | 2250 | 220.3 | With hair ball |
Comparative example 2 | 3220 | 256.4 | Individual hair bulb |
Comparative example 3 | 3030 | 325.1 | No change |
From the performance test results in table 2, it can be seen that the environment-friendly composite textile material of the present invention has excellent air permeability, water absorption and fuzzing and pilling resistance. According to the invention, the regenerated PET fiber is modified, so that the air permeability, the water absorption rate and the fuzzing and pilling resistance of the fabric are greatly improved; according to the invention, through adding the pretreated volcanic rock particles, the air permeability and the water absorption rate of the fabric are improved; according to the invention, the nano calcium carbonate is added, so that the air permeability of the fabric is improved.
The technical features of the above-described embodiments may be arbitrarily combined, and all possible combinations of the technical features in the above-described embodiments are not described for brevity of description, however, as long as there is no contradiction between the combinations of the technical features, they should be considered as the scope of the description.
The foregoing examples illustrate only a few embodiments of the invention and are described in detail herein without thereby limiting the scope of the invention. It should be noted that it will be apparent to those skilled in the art that several variations and modifications can be made without departing from the spirit of the invention, which are all within the scope of the invention.
Claims (5)
1. The environment-friendly composite textile material is characterized by being prepared from the following raw materials in parts by weight: 60-80 parts of regenerated PET modified fiber, 10-20 parts of bamboo fiber, 10-20 parts of polylactic acid fiber and fiber impregnating solution, wherein the solid-liquid ratio is 1: (10-50);
the preparation method of the composite textile material specifically comprises the following steps:
(1) Placing the regenerated PET modified fiber and the bamboo fiber in a wool blending machine, and mixing for 0.5h at normal temperature to obtain mixed fiber;
the specific preparation method of the regenerated PET modified fiber comprises the following steps:
p1 adding 0.5g/L dodecylpyridine chloride solution into 0.4mol/L NaOH solution, stirring at 120-150r/min for 5-10min to obtain alkaline solution; immersing the regenerated PET fiber in the alkaline solution for 30min at 70-80 ℃, taking out and drying to obtain the regenerated PET fiber with the surface modified;
p2, selecting appropriate amount of volcanic rock, pulverizing, sieving with 100 mesh sieve to obtain volcanic rock particles, placing volcanic rock particles in 2mol/L dilute nitric acid solution, stirring for 10-20min, filtering, cleaning with deionized water, and drying at 100deg.C for 2 hr to obtain pretreated volcanic rock particles;
p3, firstly stirring the pretreated volcanic rock particles, nano calcium carbonate and polyoxyethylene amide in a mixer for 30min, then adding the surface-modified regenerated PET fibers and vinyl trimethoxy silane, stirring at 50-60 ℃ for 30min, introducing into a double-screw extruder, and preparing the regenerated PET modified fibers after melt distribution pipes, spinning boxes, metering pumps, composite spinning components, side blowing, bundling and oiling, winding and chemical fiber treatment;
(2) Immersing the mixed fiber in fiber immersion liquid at 40-50 ℃ for 10-18h, taking out and airing after immersion, cleaning for three times by deionized water, and drying to obtain treated mixed fiber;
the fiber impregnating solution consists of the following raw materials in percentage by mass: 0.8 to 1.6 percent of sulfosuccinate, 4 to 8 percent of EVA emulsion, 1.6 to 2.5 percent of diammonium hydrogen phosphate, 0.5 to 1.2 percent of basic aluminum sodium carbonate, 5 to 10 percent of polyethylene glycol, 20 to 30 percent of ethanol and the balance of water;
(3) Adding the treated mixed fiber and polylactic acid fiber into a high-speed mixer, mixing for 1h at 50 ℃, and carrying out melt spinning to obtain the composite textile material.
2. The environment-friendly composite textile material according to claim 1, wherein the fiber impregnation liquid is composed of the following raw materials in percentage by mass: 1.2% of sulfosuccinate, 5.6% of EVA emulsion, 2.1% of diammonium hydrogen phosphate, 0.6% of basic aluminum sodium carbonate, 8.3% of polyethylene glycol, 22% of ethanol and the balance of water.
3. The environment-friendly composite textile material according to claim 1, wherein in the preparation method of the regenerated PET modified fiber, the mass of the nano calcium carbonate is 10-15% of the mass of the pretreated volcanic rock particles, the mass of the polyoxyethylene amide is 5-8% of the mass of the pretreated volcanic rock particles, the mass of the pretreated volcanic rock particles is 8-12% of the mass of the surface modified regenerated PET fiber, and the mass of the vinyl trimethoxysilane is 0.5-0.8% of the mass of the surface modified regenerated PET fiber.
4. The environment-friendly composite textile material according to claim 1, wherein in the preparation method of the regenerated PET modified fiber, the extrusion temperature of the twin-screw extruder in the P3 is 260-280 ℃.
5. The environment-friendly composite textile material according to claim 1, wherein in the step (3), the process parameters of the melt spinning are as follows: the spinning temperature is 250-275 ℃, the side blowing cooling air temperature is 25 ℃, the side blowing air speed is 1m/s, the spinning speed is 2500-3800m/min, and the draft ratio is 2.0-5.0.
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