CN113046158A - High-adhesion overweight load water-resistant open gear grease and preparation method thereof - Google Patents
High-adhesion overweight load water-resistant open gear grease and preparation method thereof Download PDFInfo
- Publication number
- CN113046158A CN113046158A CN202110312597.3A CN202110312597A CN113046158A CN 113046158 A CN113046158 A CN 113046158A CN 202110312597 A CN202110312597 A CN 202110312597A CN 113046158 A CN113046158 A CN 113046158A
- Authority
- CN
- China
- Prior art keywords
- parts
- agent
- grease
- adhesion
- open gear
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004519 grease Substances 0.000 title claims abstract description 114
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 56
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 66
- 239000002131 composite material Substances 0.000 claims abstract description 35
- 239000000654 additive Substances 0.000 claims abstract description 29
- 230000000996 additive effect Effects 0.000 claims abstract description 29
- 230000001050 lubricating effect Effects 0.000 claims abstract description 24
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 16
- 230000007797 corrosion Effects 0.000 claims abstract description 16
- 238000005260 corrosion Methods 0.000 claims abstract description 16
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000000853 adhesive Substances 0.000 claims abstract description 15
- 230000001070 adhesive effect Effects 0.000 claims abstract description 15
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 15
- 229910052802 copper Inorganic materials 0.000 claims abstract description 15
- 239000010949 copper Substances 0.000 claims abstract description 15
- 239000010722 industrial gear oil Substances 0.000 claims abstract description 15
- 239000012744 reinforcing agent Substances 0.000 claims abstract description 15
- 238000005491 wire drawing Methods 0.000 claims abstract description 15
- 239000003112 inhibitor Substances 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 14
- 239000002199 base oil Substances 0.000 claims abstract description 13
- 230000002940 repellent Effects 0.000 claims abstract description 13
- 239000005871 repellent Substances 0.000 claims abstract description 13
- 239000013538 functional additive Substances 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims description 39
- 239000003921 oil Substances 0.000 claims description 15
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 14
- 229910052744 lithium Inorganic materials 0.000 claims description 14
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 13
- 229920002396 Polyurea Polymers 0.000 claims description 13
- 229910052791 calcium Inorganic materials 0.000 claims description 13
- 239000011575 calcium Substances 0.000 claims description 13
- 239000003607 modifier Substances 0.000 claims description 11
- 239000012964 benzotriazole Substances 0.000 claims description 9
- -1 polypropylene Polymers 0.000 claims description 8
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 7
- 238000005282 brightening Methods 0.000 claims description 7
- 229920000570 polyether Polymers 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 150000003863 ammonium salts Chemical class 0.000 claims description 5
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 5
- 239000003822 epoxy resin Substances 0.000 claims description 5
- 125000004494 ethyl ester group Chemical group 0.000 claims description 5
- 239000003292 glue Substances 0.000 claims description 5
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical group NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims description 5
- 150000004702 methyl esters Chemical class 0.000 claims description 5
- 229940049964 oleate Drugs 0.000 claims description 5
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 5
- 125000002811 oleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 229920000647 polyepoxide Polymers 0.000 claims description 5
- 238000005086 pumping Methods 0.000 claims description 5
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 4
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 4
- TXQVDVNAKHFQPP-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] octadecanoate Chemical group CCCCCCCCCCCCCCCCCC(=O)OCC(CO)(CO)CO TXQVDVNAKHFQPP-UHFFFAOYSA-N 0.000 claims description 4
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 claims 5
- 239000013053 water resistant agent Substances 0.000 claims 2
- 150000002642 lithium compounds Chemical class 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 8
- 239000010426 asphalt Substances 0.000 abstract description 8
- 239000010439 graphite Substances 0.000 abstract description 8
- 229910002804 graphite Inorganic materials 0.000 abstract description 8
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 abstract description 8
- 229910052982 molybdenum disulfide Inorganic materials 0.000 abstract description 8
- 239000000126 substance Substances 0.000 abstract description 6
- 230000006378 damage Effects 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 238000005245 sintering Methods 0.000 description 5
- 239000002585 base Substances 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- WJUMWVJBOZKPPU-UHFFFAOYSA-N 2,3-bis(6-methylheptyl)-N-phenylaniline Chemical compound C(CCCCC(C)C)C=1C(=C(C=CC1)NC1=CC=CC=C1)CCCCCC(C)C WJUMWVJBOZKPPU-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 241000878128 Malleus Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000013556 antirust agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000003339 best practice Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 231100000086 high toxicity Toxicity 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 210000002331 malleus Anatomy 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/1033—Polyethers, i.e. containing di- or higher polyoxyalkylene groups used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/08—Amides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/221—Six-membered rings containing nitrogen and carbon only
- C10M2215/222—Triazines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/045—Polyureas; Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
Abstract
The invention relates to a high-adhesion overweight load water-resistant open gear grease and a preparation method thereof, belonging to the technical field of chemical material combination, wherein the open gear grease comprises 100 parts of base oil, 15-35 parts of lubricating grease and 15.77-49.83 parts of functional additives; the functional additives comprise a water repellent agent, a wire drawing agent, a high-temperature antioxidant, a strong adhesive, a DE film forming agent, a cohesion reinforcing agent, an industrial gear oil composite additive, an oiliness agent, an antirust additive, a copper corrosion inhibitor, a friction improver and a brightener. The open gear has the advantages of super-strong grease bearing capacity, excellent water resistance, excellent adhesion and high cost performance, does not contain asphalt, graphite or molybdenum disulfide, is energy-saving and environment-friendly, and is suitable for lubricating the open gear working in various working environments, particularly high-load, ultrahigh-load and water vapor environments.
Description
Technical Field
The invention relates to a high-adhesion overweight load water-resistant open gear grease and a preparation method thereof, belonging to the technical field of chemical material combination.
Background
In the industries of mines, metallurgy, steel, thermal power generation, cement and the like, a plurality of heavy-load and overweight load devices such as ball mills, sintering machine cylinder machines, punching mills, forging presses and the like are provided, and the devices all use large open gears as power transmission and speed reduction devices. The open gears have heavy load, large tangential stress, serious sliding friction and serious dust pollution, are partially in open-air operation and contacted with water vapor, have extremely poor working environment and conditions and have extremely high lubricating difficulty.
Currently, there are three cases of grease used for open gears or bearings in these working environments:
(1) lithium-based resins containing molybdenum disulfide or graphite, composite lithium-based resins, and the like are used with difficulty. The lubricating greases have the disadvantages of insufficient comprehensive performance, insufficient bearing capacity and lubricating capacity, small sintering load (PD value) which is only five to six hundred kilograms, and incapability of meeting the lubricating requirement of large-scale overweight load open gears; the water resistance is weak, so that grease is thinned or lost, the lubrication is insufficient, the working performance is reduced or lost, equipment is corroded, and the service life of lubricating grease and equipment is shortened; the gear is poor in adhesion and cannot be adhered to the surface of the gear for a long time, and when the gear is occluded, the gear is extremely easy to extrude or throw out, so that a series of problems of serious equipment damage, short service life of the equipment, low production efficiency and the like are caused; molybdenum disulfide can also cause metal corrosion, resulting in damage to the friction pair interface; molybdenum disulfide and graphite can also cause environmental damage.
(2) Conventional and conventional special domestic open gear grease is used. However, the special grease has small sintering load (PD value) which is only five-six-hundred kilograms generally, has insufficient extreme pressure performance and cannot meet the lubrication of a large overweight load open gear; the gear is poor in adhesion and cannot be adhered to the surface of the gear for a long time, and when the gear is occluded, the gear is extremely easy to extrude or throw out, so that a series of problems of serious equipment damage, short service life of the equipment, low production efficiency and the like are caused; in addition, the current domestic special open gear grease contains molybdenum disulfide or graphite, which can damage the environment.
(3) Imported products of International brands such as MOBIL, SHELL, KLUBER, BRUGAROLAS and the like were used. At present, domestic high-end open gear grease is basically monopolized by foreign brands, the price is high, and the supply is not timely. In addition, the imported high-end open gear grease is added with substances such as asphalt and the like in order to solve the adhesion and cohesion of the grease. Asphalt has high toxicity and serious damage to the environment, and is banned from being used in lubricating grease in China for a long time; technically, the cohesion of asphalt is not strong enough, and effective and durable adhesion can not be carried out on some open gears with overweight loads; in order to increase the sintering load of grease, graphite or molybdenum disulfide and other solid lubricants are added, so that great pressure is brought to environmental protection. The open gear grease of the Shell Maries series (MALLEUS GL) which is the most widely and mostly used in China contains asphalt and graphite.
The application aims to develop the high-adhesion overweight load water-resistant open gear lubricating grease which has super-strong bearing capacity, excellent water resistance, excellent adhesion and high cost performance, the product quality of the high-adhesion overweight load water-resistant open gear lubricating grease is superior to that of similar products of foreign companies such as Mobil and Shell, does not contain asphalt, graphite or molybdenum disulfide, is energy-saving and environment-friendly, is suitable for lubricating open gears working in various working environments, particularly high load, ultrahigh load and water vapor environments, can replace similar imported products, and has important value for the market of domestic high-end open gear grease.
Disclosure of Invention
Aiming at the defects in the prior art, the invention provides a high-adhesion overweight load water-resistant open gear grease and a preparation method thereof, so as to achieve the aims of better extreme pressure performance, stronger adhesion and more environmental protection.
The technical scheme for solving the technical problems is as follows: the high-adhesion overweight load water-resistant open gear grease is characterized in that the open gear grease comprises, by weight, 100 parts of base oil, 15-35 parts of lubricating grease and 15.77-49.83 parts of functional additives;
the functional additives comprise a water repellent agent, a wire drawing agent, a high-temperature antioxidant, a strong adhesive, a DE film forming agent, a cohesion reinforcing agent, an industrial gear oil composite additive, an oiliness agent, an antirust additive, a copper corrosion inhibitor, a friction improver and a brightener.
Preferably, the base oil comprises 50 parts by weight of 150BS, 30 parts by weight of PAO40 and 20 parts by weight of oil-soluble polyether, wherein the oil-soluble polyether is OSP220 of Dow chemical USA.
150BS and PAO40 are both high-viscosity base oil and can provide higher oil film strength; the low pour points of the PAO40 and the oil soluble polyether OSP220 improve the low temperature performance and pumpability of the grease.
Preferably, the lubricating grease is any one of a calcium sulfonate-polyurea composite grease or a lithium composite grease, the calcium sulfonate-polyurea composite grease is an NLGI 2 calcium sulfonate-polyurea composite grease or an NLGI 3 calcium sulfonate-polyurea composite grease, and the lithium composite grease is an NLGI 2 lithium composite grease or an NLGI 3 lithium composite grease.
The calcium sulfonate-polyurea composite grease is high-quality multi-effect lubricating grease which integrates heavy load resistance, high temperature resistance, water resistance, acid and alkali resistance and rust prevention, and also has better pumping performance; the composite lithium grease is high-temperature grease with excellent performance, high dropping point and good pumping performance.
Preferably, the functional additive comprises the following components in parts by weight:
0.2-1.0 part of water repellent agent;
2.0-7.0 parts of a wire drawing agent;
0.5-3.0 parts of a high-temperature antioxidant;
3.0-10.0 parts of a strong adhesive;
1.0-5.0 parts of DE film-forming agent;
1.0-5.0 parts of cohesive force reinforcing agent;
1.8-5.0 parts of industrial gear oil composite additive;
2.5-5.0 parts of an oiliness agent;
0.56-1.80 parts of an antirust additive;
0.01-0.03 part of copper corrosion inhibitor;
3.0-6.0 parts of a friction modifier;
0.2-1.0 part of brightener.
Preferably, the water repellent agent is hydrogenated styrene diene copolymer, the water repellent agent hydrogenated styrene diene copolymer can greatly improve the water resistance of the grease, and the water resistance can be improved by 4-5 times;
the wire drawing agent is random polypropylene APP, and can greatly improve the wire drawing property and the adhesion of grease;
the high-temperature antioxidant is at least one of IRGANOX L115 and T516Z of BASF company, and IRGANOX L115 and T516Z are high-temperature antioxidants with excellent performance, so that the antioxidant capacity of the grease can be obviously improved, and the service life of the grease is prolonged;
the strong adhesive is strong mouse-sticking glue which can greatly improve the adhesion of grease and improve the metal adhesion capability of the grease;
the DE film forming agent is epoxy resin oleate, and the epoxy resin oleate is an excellent DE film forming agent, so that the thickness and strength of an oil film of the oil can be remarkably improved, and the anti-sliding friction and abrasion resistance of the oil can be improved;
the cohesion reinforcing agent is rosin pentaerythritol ester which is excellent in performance, the cohesion reinforcing agent can obviously improve the cohesion of the grease, improve the anti-bleeding capacity of the grease, improve the metal adhesion capacity of the grease, and make up for the problem of insufficient cohesion of the grease caused by the elimination of asphalt;
the industrial gear oil composite additive is any one of the LZ5060 of Luborun in America and the German Ryzine chemical RC9410, and the LZ5060 and the RC9410 are industrial gear oil composite agents with excellent performance, are reasonably used, have very high sintering load values and are particularly outstanding in extreme pressure abrasion resistance;
the oiliness agent is any one of sulfurized lard methyl ester and sulfurized lard ethyl ester, the sulfurized lard methyl ester or the sulfurized lard ethyl ester is an oiliness agent with excellent performance, and the oiliness agent is matched with LZ5060 and RC9410 for use, so that the oil film thickness and strength of the grease can be obviously improved, and the bearing capacity and the shock resistance of the grease are improved;
the antirust additive is at least one of benzotriazole fatty ammonium salt T406 and oleoyl sarcosine-octadecylammonium salt, and the benzotriazole fatty ammonium salt T406 is a multi-effect lubricating oil additive and can improve the antifriction and antirust properties of oil products; oleoyl sarcosine-octadecylammonium salt is an excellent environment-friendly ferrous metal antirust agent;
the copper corrosion inhibitor is benzotriazole T706, and has good copper corrosion resistance;
the friction modifier is melamine cyanurate, and the melamine cyanurate can improve the interface characteristic of the grease and improve the anti-friction capability of the grease;
the brightening agent is pentaerythritol stearate, can improve the appearance of the grease, and also has the functions of improving the cohesion of the grease and improving the anti-flowing and anti-scattering capacity of the grease.
The invention also discloses a preparation method of the high-adhesion overweight load water-resistant open gear grease, which comprises the following steps:
(1) pumping the base oil raw material into a stirring kettle which can be vacuumized through metering, uniformly mixing to obtain base oil, and then metering and adding a high-temperature antioxidant;
(2) stirring and heating the stirred tank to 150 +/-5 ℃, and stopping heating;
(3) adding a water repellent agent and a wire drawing agent in a metering manner, starting vacuum in a stirring kettle, stirring at a constant temperature for 60-90 minutes, and then releasing the vacuum;
(4) starting cold oil circulation, cooling the materials in the stirring kettle to 115 +/-5 ℃, and stopping cooling;
(5) sequentially adding the measured DE film forming agent, the measured cohesion reinforcing agent, the measured antirust additive, the measured copper corrosion inhibitor and the measured brightening agent into a stirring kettle, and stirring until all materials are uniformly dissolved;
(6) adding lubricating grease and an oiliness agent into a kettle in a metering manner, and stirring for 60-120 minutes until the materials in the stirring kettle are uniform semifluid grease;
(7) and starting cold oil circulation, metering the industrial gear oil composite additive, the strong adhesive and the friction modifier into the stirring kettle when the temperature of the materials in the stirring kettle is reduced to below 50 ℃, continuously stirring for 30-60 minutes, and uniformly stirring to obtain the high-adhesion overweight load water-resistant open gear grease.
Further, in step (1), the base oil comprises 50 parts of 150BS, 30 parts of PAO40 and 20 parts of American Dow chemical oil soluble polyether OSP 220.
Further, in the step (6), the lubricating grease is 15-35 parts by weight, and the lubricating grease is any one of NLGI 2 calcium sulfonate-polyurea composite grease, NLGI 3 calcium sulfonate-polyurea composite grease, NLGI 2 composite lithium base grease or NLGI 3 composite lithium base grease.
Further, 0.2-1.0 part of a water repellent agent; 2.0-7.0 parts of a wire drawing agent; 0.5-3.0 parts of a high-temperature antioxidant; 3.0-10.0 parts of a strong adhesive; 1.0-5.0 parts of DE film-forming agent; 1.0-5.0 parts of cohesive force reinforcing agent; 1.8-5.0 parts of industrial gear oil composite additive; 2.5-5.0 parts of an oiliness agent; 0.56-1.80 parts of an antirust additive; 0.01-0.03 part of copper corrosion inhibitor; 3.0-6.0 parts of a friction modifier; 0.2-1.0 part of brightener.
Further, the water repellent agent is hydrogenated styrene diene copolymer; the wire drawing agent is random polypropylene; the high-temperature antioxidant is at least one of IRGANOX L115 and diisooctyl diphenylamine T516Z of BASF corporation; the strong adhesive is strong rat glue; the DE film-forming agent is epoxy resin oleate; the cohesive force reinforcing agent is rosin pentaerythritol ester; the industrial gear oil composite additive is any one of LZ5060 of Luborun USA and RC9410 of Laine Germany; the oiliness agent is any one of sulfurized lard methyl ester and sulfurized lard ethyl ester; the antirust additive is at least one of benzotriazole fatty ammonium salt T406 and oleoyl sarcosine-octadecylammonium salt; the copper corrosion inhibitor is benzotriazole T706; the friction modifier is melamine cyanurate; the brightening agent is pentaerythritol stearate. .
The invention has the beneficial effects that: the high-adhesion overweight load water-resistant open gear disclosed by the invention is strong in cohesion and adhesion, excellent in metal adhesion performance and anti-flowing performance, excellent in extreme pressure resistance and impact resistance, excellent in water resistance, excellent in oxidation stability and thermal stability, free of asphalt, graphite and molybdenum disulfide, energy-saving and environment-friendly, and especially suitable for lubricating various heavy-load and overweight-load open gears working in a high-temperature and high-humidity environment; the open gear grease can be used as high-end open gear grease to replace imported like products of the international brands such as MOBIL, SHELL, KLUBER, BRUGAROLAS and the like.
Detailed Description
The present invention will be described in detail with reference to the following embodiments in order to make the aforementioned objects, features and advantages of the invention more comprehensible. In the following description, numerous specific details are set forth in order to provide a thorough understanding of the present invention. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used herein in the description of the invention is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention.
Example 1
This example provides a high-adhesion overweight load water-resistant open gear grease with NLGI 0 consistency grade prepared from calcium sulfonate-polyurea composite grease, and the raw material ratio is shown in table 1.
TABLE 1 formulation of raw materials and compounding ratio of calcium sulfonate-polyurea composite grease to NLGI 0 consistency class open gear grease of working examples 11-17
Example 2
This example provides a high-adhesion overweight load water-resistant open gear grease with NLGI 0 consistency grade prepared from lithium complex grease, and the raw material ratio is shown in table 2.
TABLE 2 composition and compounding ratio of raw materials of working examples 21 to 27 made of lithium complex base grease having consistency grade NLGI 0 grease
The preparation method of the high-adhesion overweight load water-resistant open gear grease in the embodiment 1-2 comprises the following steps:
(1) pumping 50% of 150BS, 30% of PAO40 and 20% of oil-soluble polyether OSP220 into a stirring kettle capable of being vacuumized, and uniformly mixing to obtain base oil; metering and adding a high-temperature antioxidant;
(2) stirring and heating to 150 +/-5 ℃, and stopping heating;
(3) metering a water repellent agent and a wire drawing agent; starting vacuum, and stirring at constant temperature for 60-90 minutes; releasing the vacuum;
(4) starting cold oil circulation, cooling the materials in the stirring kettle to 115 +/-5 ℃, and stopping cooling;
(5) sequentially adding the measured DE film forming agent, the measured cohesion reinforcing agent, the measured antirust additive, the measured copper corrosion inhibitor and the measured brightening agent into a stirring kettle, and stirring until all materials are uniformly dissolved;
(6) adding the lubricating grease and the oiliness agent into a stirring kettle in a metering manner, and stirring for 60-120 minutes until the materials in the stirring kettle are uniform semifluid grease;
(7) starting cold oil circulation, metering the industrial gear oil composite additive, the strong mouse glue and the friction modifier into the stirring kettle when the temperature of the materials in the stirring kettle is reduced to below 50 ℃, and continuously stirring for 30-60 minutes; stirring evenly to obtain the high-adhesion overweight load water-resistant open gear grease.
The performance data of the highly adhesive overweight loaded water-resistant open gear grease of NLGI 0 consistency grade prepared with the calcium sulfonate-polyurea compound grease of example 1 in optimal working example 14 are shown in table 3.
TABLE 3 Performance data of the highly adherent overweight loaded water-resistant open gear grease of consistency class NLGI 0 made from calcium sulfonate-polyurea compound grease optimum operating example 14
The performance data of the highly adhesive overweight loaded water-resistant open gear grease of NLGI 0 consistency grade prepared with the lithium complex base grease of example 2 in best practice 24 is shown in table 4.
Table 4 performance data for high adhesion overweight loaded water-resistant open gear grease with consistency grade NLGI 0 made from lithium composite
TABLE 5 Performance index of high-adhesion overweight load water-resistant open gear grease
The content in table 5 is the enterprise standard of the high-adhesion overweight load water-resistant open gear grease, and the comparison of the data in table 3 and table 4 in table 5 shows that the open gear grease obtained by the technical scheme completely meets the performance index of the high-adhesion overweight load water-resistant open gear grease.
The technical features of the embodiments described above may be arbitrarily combined, and for the sake of brevity, all possible combinations of the technical features in the embodiments described above are not described, but should be considered as being within the scope of the present specification as long as there is no contradiction between the combinations of the technical features.
The above-mentioned embodiments only express several embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.
Claims (10)
1. The high-adhesion overweight load water-resistant open gear grease is characterized in that the open gear grease comprises, by weight, 100 parts of base oil, 15-35 parts of lubricating grease and 15.77-49.83 parts of functional additives;
the functional additives comprise a water repellent agent, a wire drawing agent, a high-temperature antioxidant, a strong adhesive, a DE film forming agent, a cohesion reinforcing agent, an industrial gear oil composite additive, an oiliness agent, an antirust additive, a copper corrosion inhibitor, a friction improver and a brightener.
2. The high adhesion overweight load water-resistant open gear grease according to claim 1, wherein the base oil comprises 50 parts by weight of 150BS, 30 parts by weight of PAO40 and 20 parts by weight of oil soluble polyether OSP 220.
3. A high-adhesion overweight load water-resistant open gear grease according to claim 1, wherein the lubricating grease is calcium sulfonate-polyurea composite grease or composite lithium-based grease.
4. The high-adhesion overweight load water-resistant open gear grease as claimed in claim 1, wherein the functional additive comprises the following components in parts by weight:
0.2-1.0 part of water repellent agent;
2.0-7.0 parts of a wire drawing agent;
0.5-3.0 parts of a high-temperature antioxidant;
3.0-10.0 parts of a strong adhesive;
1.0-5.0 parts of DE film-forming agent;
1.0-5.0 parts of cohesive force reinforcing agent;
1.8-5.0 parts of industrial gear oil composite additive;
2.5-5.0 parts of an oiliness agent;
0.56-1.80 parts of an antirust additive;
0.01-0.03 part of copper corrosion inhibitor;
3.0-6.0 parts of a friction modifier;
0.2-1.0 part of brightener.
5. A high-adhesion overweight load water-resistant open gear grease according to claim 4,
the water repellent agent is hydrogenated styrene diene copolymer;
the wire drawing agent is random polypropylene;
the high-temperature antioxidant is at least one of IRGANOX L115 and T516Z;
the strong adhesive is strong rat glue;
the DE film-forming agent is epoxy resin oleate;
the cohesive force reinforcing agent is rosin pentaerythritol ester;
the industrial gear oil composite additive is any one of LZ5060 and RC 9410;
the oiliness agent is any one of sulfurized lard methyl ester and sulfurized lard ethyl ester;
the antirust additive is at least one of benzotriazole fatty ammonium salt T406 and oleoyl sarcosine-octadecylammonium salt;
the copper corrosion inhibitor is benzotriazole T706;
the friction modifier is melamine cyanurate;
the brightening agent is pentaerythritol stearate.
6. A method for preparing a high-adhesion overweight load water-resistant open gear grease according to any one of claims 1-5, characterized in that the preparation method comprises the following steps:
(1) pumping the base oil raw material into a stirring kettle which can be vacuumized through metering, uniformly mixing to obtain base oil, and then metering and adding a high-temperature antioxidant;
(2) stirring and heating the stirred tank to 150 +/-5 ℃, and stopping heating;
(3) adding a water repellent agent and a wire drawing agent in a metering manner, starting vacuum in a stirring kettle, stirring at a constant temperature for 60-90 minutes, and then releasing the vacuum;
(4) starting cold oil circulation, cooling the materials in the stirring kettle to 115 +/-5 ℃, and stopping cooling;
(5) sequentially adding the measured DE film forming agent, the measured cohesion reinforcing agent, the measured antirust additive, the measured copper corrosion inhibitor and the measured brightening agent into a stirring kettle, and stirring until all materials are uniformly dissolved;
(6) adding lubricating grease and an oiliness agent into a kettle in a metering manner, and stirring for 60-120 minutes until the materials in the stirring kettle are uniform semifluid grease;
(7) and starting cold oil circulation, metering the industrial gear oil composite additive, the strong adhesive and the friction modifier into the stirring kettle when the temperature of the materials in the stirring kettle is reduced to below 50 ℃, continuously stirring for 30-60 minutes, and uniformly stirring to obtain the high-adhesion overweight load water-resistant open gear grease.
7. The method for preparing a high-adhesion overweight load water-resistant open gear grease according to claim 6, wherein in step (1), the base oil comprises 50 parts of 150BS, 30 parts of PAO40 and 20 parts of oil-soluble polyether OSP 220.
8. The method for preparing a high-adhesion overweight loading water-resistant open gear grease according to claim 6, wherein in the step (6), the lubricating grease is 15-35 parts by weight, and the lubricating grease is calcium sulfonate-polyurea compound grease or lithium compound grease.
9. The method for preparing the high-adhesion overweight load water-resistant open gear grease according to claim 6, characterized in that the water-resistant agent accounts for 0.2-1.0 part by weight; 2.0-7.0 parts of a wire drawing agent; 0.5-3.0 parts of a high-temperature antioxidant; 3.0-10.0 parts of a strong adhesive; 1.0-5.0 parts of DE film-forming agent; 1.0-5.0 parts of cohesive force reinforcing agent; 1.8-5.0 parts of industrial gear oil composite additive; 2.5-5.0 parts of an oiliness agent; 0.56-1.80 parts of an antirust additive; 0.01-0.03 part of copper corrosion inhibitor; 3.0-6.0 parts of a friction modifier; 0.2-1.0 part of brightener.
10. The method for preparing a high-adhesion overweight load water-resistant open gear grease according to claim 9, characterized in that the water-resistant agent is hydrogenated styrene diene copolymer; the wire drawing agent is random polypropylene; the high-temperature antioxidant is at least one of IRGANOX L115 and T516Z; the strong adhesive is strong rat glue; the DE film-forming agent is epoxy resin oleate; the cohesive force reinforcing agent is rosin pentaerythritol ester; the industrial gear oil composite additive is any one of LZ5060 and RC 9410; the oiliness agent is any one of sulfurized lard methyl ester and sulfurized lard ethyl ester; the antirust additive is at least one of benzotriazole fatty ammonium salt T406 and oleoyl sarcosine-octadecylammonium salt; the copper corrosion inhibitor is benzotriazole T706; the friction modifier is melamine cyanurate; the brightening agent is pentaerythritol stearate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110312597.3A CN113046158A (en) | 2021-03-24 | 2021-03-24 | High-adhesion overweight load water-resistant open gear grease and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110312597.3A CN113046158A (en) | 2021-03-24 | 2021-03-24 | High-adhesion overweight load water-resistant open gear grease and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113046158A true CN113046158A (en) | 2021-06-29 |
Family
ID=76514755
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110312597.3A Pending CN113046158A (en) | 2021-03-24 | 2021-03-24 | High-adhesion overweight load water-resistant open gear grease and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113046158A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004091711A (en) * | 2002-09-03 | 2004-03-25 | Nippon Koyu:Kk | Grease composition |
| CN106635325A (en) * | 2016-11-17 | 2017-05-10 | 纳拓润滑技术（上海）有限公司 | Open gear oil and preparation method thereof |
| CN109810767A (en) * | 2019-03-22 | 2019-05-28 | 山东奇士登润滑科技有限公司 | A kind of high-performance heavy load high temperature waterproof grease and preparation method |
| US20200109345A1 (en) * | 2017-04-19 | 2020-04-09 | Chemtura Chemicals (Nanjing) Company Limited | Lubricating grease of polyurea/high base number calcium sulfonate composite |
-
2021
- 2021-03-24 CN CN202110312597.3A patent/CN113046158A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004091711A (en) * | 2002-09-03 | 2004-03-25 | Nippon Koyu:Kk | Grease composition |
| CN106635325A (en) * | 2016-11-17 | 2017-05-10 | 纳拓润滑技术（上海）有限公司 | Open gear oil and preparation method thereof |
| US20200109345A1 (en) * | 2017-04-19 | 2020-04-09 | Chemtura Chemicals (Nanjing) Company Limited | Lubricating grease of polyurea/high base number calcium sulfonate composite |
| CN109810767A (en) * | 2019-03-22 | 2019-05-28 | 山东奇士登润滑科技有限公司 | A kind of high-performance heavy load high temperature waterproof grease and preparation method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101624549B (en) | Extreme-pressure lubricating grease and preparation method thereof | |
| CN103981004B (en) | Extreme pressure Al Matrix Grease composition and preparation method | |
| CN101696366B (en) | Method for preparing lubricating grease with excellent anti-wear and wear-resistant performance | |
| CN104164280A (en) | Antirust high-temperature lubricating grease composition | |
| CN104450117A (en) | Lubricating grease composition for water pump bearing of automobile and preparation method thereof | |
| CN110616103B (en) | Commercial vehicle wheel hub bearing lubricating grease and preparation method thereof | |
| CN104130832A (en) | Antifriction synergist of rotary-kiln support-wheel shaft bushing lubricating oil and preparation method thereof | |
| CN105273815A (en) | Vegetable-oil lubricating oil | |
| CN102766500B (en) | High-base-number compound-sulfonic lithium/calcium composite lubricating grease and preparation method thereof | |
| CN112940836B (en) | High-dispersity nano molybdenum disulfide water-based rolling liquid and preparation method thereof | |
| CN103484202A (en) | Wear-resistant lithium-based lubricating grease composition | |
| CN102703177B (en) | Lubricating grease special for outer ball cage of automotive universal joint and preparation method for lubricating grease | |
| CN111171927B (en) | Aluminum product rolling oil containing coumarin and preparation method thereof | |
| CN113046158A (en) | High-adhesion overweight load water-resistant open gear grease and preparation method thereof | |
| CN103805323A (en) | High-temperature grease and preparation method thereof | |
| CN102952616A (en) | High temperature high speed oil film bearing oil | |
| CN104893807A (en) | Lubricating grease for guide rail lead screw mechanism of dust-free room | |
| CN114231338A (en) | Ultrahigh-temperature anti-stress paste and preparation method thereof | |
| CN109913296B (en) | Low-friction-coefficient assembly lubricating paste and preparation method thereof | |
| CN104031717B (en) | A kind of aluminium nitride and copper mixing nanometer lubricating grease additive and application thereof | |
| CN114196461A (en) | Cleaning oil composition for heavy-duty axle and preparation method and application thereof | |
| CN111334363A (en) | Energy-saving antifriction lithium-based lubricating grease and preparation method thereof | |
| CN110951521A (en) | Lubricating grease special for corrugating machine bearing and preparation method thereof | |
| CN111961518B (en) | Composite calcium sulfonate-based lubricating grease for open gears and preparation method and application thereof | |
| CN115772435B (en) | Composite calcium type automobile hub bearing lubricating grease composition and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20210629 |