CN113036240A - Method for monitoring oxidation condition of battery pole of distribution network automation equipment - Google Patents

Method for monitoring oxidation condition of battery pole of distribution network automation equipment Download PDF

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Publication number
CN113036240A
CN113036240A CN202110221147.3A CN202110221147A CN113036240A CN 113036240 A CN113036240 A CN 113036240A CN 202110221147 A CN202110221147 A CN 202110221147A CN 113036240 A CN113036240 A CN 113036240A
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automation equipment
color
pole
distribution network
battery
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Inventor
吴宏辉
吴海星
莫捷晖
苏映彰
魏翩翩
梁俊杰
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Shaoguan Power Supply Bureau Guangdong Power Grid Co Ltd
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Shaoguan Power Supply Bureau Guangdong Power Grid Co Ltd
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Priority to CN202110221147.3A priority Critical patent/CN113036240A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/425Structural combination with electronic components, e.g. electronic circuits integrated to the outside of the casing
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4285Testing apparatus
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/48Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/48Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte
    • H01M10/482Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte for several batteries or cells simultaneously or sequentially
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/425Structural combination with electronic components, e.g. electronic circuits integrated to the outside of the casing
    • H01M2010/4271Battery management systems including electronic circuits, e.g. control of current or voltage to keep battery in healthy state, cell balancing
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/425Structural combination with electronic components, e.g. electronic circuits integrated to the outside of the casing
    • H01M2010/4278Systems for data transfer from batteries, e.g. transfer of battery parameters to a controller, data transferred between battery controller and main controller
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Secondary Cells (AREA)

Abstract

The invention provides a method for monitoring the oxidation condition of a battery pole of distribution network automation equipment, which comprises the following steps: (1) detecting the content of chemical substances generated in the oxidation process of the battery pole of the distribution automation equipment; (2) and (3) judging whether the content detected in the step (1) exceeds a set value or not, and if so, automatically giving an alarm by the communication module. The method can realize real-time monitoring of the oxidation condition of the battery pole of the distribution network automation equipment, effectively control the oxidation condition of the battery pole of the storage battery, and prevent the automation equipment from working abnormally when the storage battery operates abnormally due to the oxidation of the battery pole of the storage battery so as to cause line tripping faults and power failure or maintenance power failure.

Description

Method for monitoring oxidation condition of battery pole of distribution network automation equipment
Technical Field
The invention belongs to the technical field of power grids, and relates to a method for monitoring the oxidation condition of a battery pole of distribution automation equipment.
Background
At present, along with the gradual development of distribution network construction, some automation equipment are already applied to distribution network lines, and the power consumption sources of the automation equipment are two generally, firstly, the high voltage is obtained and converted into low-voltage power supply power consumption, and secondly, the storage battery pack is arranged for power supply power consumption. Under the normal operating mode of circuit, the automation equipment adopts usually to change high pressure to low pressure power supply power consumption and use, and the relevant power module of the storage battery cooperation of configuration lasts to charge, and until circuit tripping operation trouble has a power failure or when overhauing and having a power failure, automation equipment loses high-pressure side end power, and storage battery becomes by the charged state become the discharge state this moment, provides the electric energy for the normal operating of automation equipment in short-term. Presently, a lead-acid battery is one of the battery systems that is typically representative of the battery systems. The lead-acid accumulator has the advantages of stable electromotive force during discharging, stable working voltage, wide range of using temperature and using current, capability of charging and discharging for hundreds of cycles, good storage performance (especially suitable for dry charge storage) and low cost, thus having wide application. Lead-acid storage batteries are used in most of the conventional distribution network automation equipment (FTU, DTU and the like), so that the method is mainly used for monitoring the oxidation condition of the lead-acid storage battery pole of the distribution network automation equipment in real time and application.
The normal operation of the storage battery pack is related to the battery health degree and the pole oxidation degree of the storage battery pack. When the pole is oxidized, the original good metal connection can be damaged, virtual connection occurs, the conductive capacity is reduced, and the conductive connection can be blocked in severe cases. In addition, because the storage battery pack is arranged in the power distribution cabinet and the power distribution box, the information of the oxidation degree of the pole of the storage battery pack cannot be obtained in time through approaches such as background detection and the like unless the cabinet door is opened in inspection.
In addition, distribution network automation equipment has the function of detecting "backup power supply is abnormal" (whether the voltage of a lead-acid storage battery pack with a backup power supply is normal or not, whether the lead-acid storage battery pack with the backup power supply is connected or not and the like) but cannot judge the oxidation condition of the pole of the storage battery pack, the pole can be detected when the oxidation is very serious and the storage battery pack is connected into a power supply loop and fails due to oxidative fracture, the pole is late, the detection level is low, the efficiency is not high, and therefore the function cannot realize the monitoring function on the problem of monitoring the oxidation of the pole of.
The existing maintenance method only finds problems through manual daily periodic field maintenance and inspection, and changes in batches in three years (or a certain year).
Therefore, when a line tripping fault has power failure or maintenance power failure, the automatic equipment loses a high-voltage side power supply, but the automatic equipment cannot normally work due to the fact that electric energy cannot be obtained from the storage battery pack due to the fact that the storage battery pack is subjected to post oxidation, and therefore the accuracy of fault isolation of the automatic equipment during fault operation, equipment operation and distribution network normal operation is greatly affected.
At present, in distribution network automation equipment, the existing maintenance method for the lead-acid storage battery pack only finds problems through daily periodic field maintenance inspection and inspection, and changes are carried out in batches for three years (or a certain year).
The oxidation of the lead-acid storage battery pole is mainly influenced by the following factors and has the disadvantages under the existing maintenance method:
1. influence of climatic environment factors. First, moisture: the south weather is rich in rainwater, including the special weather influences such as the return south weather and the spring water weather, and provides an environment with high air humidity for the storage battery in an outdoor switch cabinet and a switch box, so that the oxidation of the storage battery pole is aggravated; second, temperature difference: in the automation equipment, a part of equipment is in rural areas, fields and mountains, the temperature difference between day and night is large, and condensed water, moisture and the like can be caused in a distribution box and a distribution cabinet due to the temperature difference, so that the long-term weather influence is realized, and the oxidation of the storage battery can be aggravated. Meanwhile, the storage battery pack can also be affected by temperature to generate expansion and contraction effects, so that internal chemical substances are volatilized and overflowed, and the process of pole oxidation of the storage battery pack is aggravated. Because the daily periodic inspection cycle is too long, the number of automatic equipment is not small, inspection cannot meet the requirement, if the manual inspection is concentrated, a large number of personnel and vehicles need to be called, and the labor cost is increased rapidly. The existing periodic inspection cannot solve the problem, the rotation can be performed only by estimating the service life of the storage battery pack and setting the age, and the short age setting may replace some storage battery packs with good operation conditions, so that economic resource waste is caused.
2. Individual difference effects. The quality of part of lead-acid storage batteries is poor, the sealing performance of the batteries can be damaged when the batteries are frequently bumped before transportation and installation, so that internal acid liquid overflows when the batteries are used, and the subsequent acid liquid corrodes the poles to generate oxidation. Or when the charging current of some storage batteries is relatively overlarge, the relative volatilization of acid liquid in the batteries is relatively large, and then the acid liquid reacts with the poles to generate oxidation. And the service time of some storage batteries is too long, so that the acid liquid in the batteries is slowly volatilized to react with the battery poles to generate oxidation. The current maintenance method cannot meet the requirements under the relative individual conditions, and also shows that the oxidation state of each automatic equipment lead-acid storage battery pole cannot be monitored in real time by means of the prior art, and the monitoring is only carried out by daily work inspection (the monitoring quantity is small) and periodic inspection (the period is long), and the efficiency is low.
CN104466275A discloses an electric power system battery intelligence online maintenance system. The electric power system storage battery intelligent online maintenance system disclosed by the scheme comprises: the online storage battery maintenance system comprises a storage battery intelligent online charging and discharging system, a storage battery intelligent online maintenance instrument and a storage battery online maintenance system network management platform, wherein the storage battery intelligent online maintenance instrument is controlled by the storage battery online maintenance system network management platform, and the storage battery intelligent online charging and discharging system is inquired and managed by the storage battery online maintenance system network management platform; the intelligent online charging and discharging system of the storage battery is used for performing a remote discharging test function on the storage battery; the intelligent online maintenance instrument for the storage battery comprises a sulfur removal device, is connected with an intelligent online charging and discharging system for the storage battery and is used for performing online maintenance on the storage battery and collecting key parameters of the storage battery, and the collected data mainly comprises the terminal voltage of the storage battery, the voltage of each single battery, the ambient temperature and the power supply state of a station; the collected data are uploaded to a server side of a network management platform of the storage battery online maintenance system in a wired mode or a wireless mode; the storage battery online maintenance system network management platform is connected with the storage battery intelligent online charging and discharging system and the storage battery intelligent online maintenance instrument, and comprises a sulfur removal device for receiving data sent by a server side, real-time data of storage batteries of all stations can be checked in a web browsing mode, and once power failure alarm occurs, a short message issuing platform sends an alarm short message to maintenance personnel. But this scheme has the problem that can't carry out effective monitoring to the oxidation condition of distribution network automation equipment lead acid battery utmost point post.
Disclosure of Invention
Aiming at the defects in the prior art, the invention aims to provide a method for monitoring the oxidation condition of a battery pole of distribution network automation equipment. The method provided by the invention can realize real-time monitoring of the oxidation condition of the battery pole of the distribution network automation equipment, powerfully control the oxidation condition of the battery pole of the storage battery, prevent the oxidation condition from happening, and prevent the automation equipment from not working normally when the storage battery abnormally runs to cause line tripping fault power failure or maintenance power failure due to the oxidation of the battery pole.
In order to achieve the purpose, the invention adopts the following technical scheme:
the invention provides a method for monitoring the oxidation condition of a battery pole of distribution network automation equipment, which comprises the following steps:
(1) detecting the content of chemical substances generated in the oxidation process of the battery pole of the distribution automation equipment;
(2) and (3) judging whether the content detected in the step (1) exceeds a set value or not, and if so, automatically giving an alarm by the communication module.
The method provided by the invention realizes real-time monitoring of the oxidation condition of the battery pole of the distribution network automation equipment and powerfully controls the oxidation condition of the battery pole of the storage battery. Meanwhile, by the method and the application, if automatic monitoring equipment is adopted, the oxidation of the pole of the storage battery pack can be found in time, and automatic alarm and signaling can be realized, so that defects can be found in advance, the defect can be eliminated in time, and the lead-acid storage battery pack with the oxidation condition or the heavier oxidation condition can be replaced, the problems of long time period, poor timeliness, high labor cost and the like caused by manual maintenance inspection are solved, the productivity is liberated, the production operation efficiency is improved, the safe operation capability of a power distribution network line is powerfully consolidated, unnecessary replacement expenditure of the storage battery pack by turns is reduced, and the economic benefit is improved.
In the invention, the types of chemical substances generated in the oxidation process of the battery pole of the automatic equipment can be analyzed and selected by related auxiliary materials (wiring terminals, screws, gaskets and the like) according to different battery and lead materials (aluminum, iron and the like).
The following is a preferred technical solution of the present invention, but not a limitation to the technical solution provided by the present invention, and the technical objects and advantageous effects of the present invention can be better achieved and achieved by the following preferred technical solution.
As a preferable technical scheme of the invention, the battery in the step (1) comprises a lead-acid storage battery.
The basic structure of a lead-acid battery is to insert electrodes made of lead dioxide and metallic lead into a dilute sulfuric acid solution. The method takes spongy lead as a negative electrode, lead dioxide as a positive electrode and sulfuric acid aqueous solution as electrolyte, and the spongy lead and the lead dioxide participate in electrochemical reaction of the battery. When the circuit is completed, the lead dioxide of the positive electrode gets electrons to become lead sulfate, and the lead of the negative electrode loses electrons to become lead sulfate.
When both the lead and lead dioxide solids become lead sulfate, the battery is discharged. If the lead sulfate on both sides is respectively connected with an external power supply at the moment, the lead sulfate connected with the positive electrode of the power supply loses electrons and becomes lead dioxide, and the lead sulfate connected with the negative electrode of the power supply obtains electrons and becomes lead under the action of current. That is, the battery is again fully charged.
Understanding the electrode reaction equation for lead acid batteries: compound state of lead PbO2And PbSO4Therefore, the following steps are carried out: in dilute H2SO4Lead of +4 and +2 valence in environment is respectively reacted with O2-And SO4 2-Has strong binding capacity.
During discharging:
(cathode) Pb lost 2 electrons and changed to + 2-valent lead immediately before it reacts with SO around the electrode4 2-Combined into PbSO4Is attached to the electrode, and is provided with a plurality of electrodes,
electrode formula is Pb-2e-+SO4 2-==PbSO4
(positive electrode): PbO2The + 4-valent lead in the electrolyte is converted into + 2-valent lead by 2 electrons and SO around the electrode4 2-Combined into PbSO4Attached to an electrode to release O2-Combine with hydrogen ions in solution to form H2O,
The electrode is PbO2+2e-+4H++SO4 2-==PbSO4+2H2O;
The total reaction formula during discharge is Pb + PbO2+2H2SO4==2PbSO4+2H2O。
(II) during charging:
PbSO on (cathode) electrodes4The lead with the middle +2 valence is converted into Pb by 2 electrons sent by a power supply and then releases SO4 2-
The electrode is PbSO4+2e-==Pb+SO4 2-
PbSO on (anodic) electrodes4The lead with the middle +2 valence is deprived of 2 electrons by the power supply to become the lead with the +4 valence, and the lead with the +4 valence is forcibly deprived of H2O of O2-To make itself become PbO2While at the same time making H2H in O+The release of the active ingredients is realized,
the electrode is PbSO4+2e-+2H2O==PbO2+4H+
So that the total reaction formula during charging is 2PbSO4+2H2O==PbO2+Pb+2H2SO4
Preferably, the battery in the step (1) is a storage battery pack.
The problem of oxidation of the battery is an inherent phenomenon of lead acid batteries, also known as creep acid corrosion. The lead-acid storage battery pole is generally made of lead and lead alloy, the storage battery shell is generally made of ABS or PP, the connection and the sealing of the storage battery pole and the shell are very important, but the problem of sulfuric acid leakage caused by poor connection and sealing of two materials by a sealant always exists.
Preferably, in the step (1), the lead wire connected to the battery is a copper wire, and the connection terminal on the battery post is made of copper (copper nose).
Preferably, the chemical of step (1) comprises copper sulfate.
In actual production, in view of the advantages of both the conductive capability and the price cost of copper, the storage battery generally adopts copper as the material of the lead, and the material of the connecting terminal on the battery post is copper (copper nose). On the basis, most of the oxidation products generated when the lead-acid storage battery pole is oxidized are mainly copper sulfate CuSO4(1, copper is oxidized into copper oxide in the air, the copper oxide reacts with acid liquor overflowing from the pole to generate copper sulfate and water, 2, the acid liquor overflowing from the copper and the pole reacts under the heating condition to generate copper sulfate, sulfur dioxide and water) and is in a white powder shape, and the copper sulfate and the water are crystallized into copper sulfate crystals CuSO under the environment with large moisture content4·5H2O, blue, light green.
As a preferred technical solution of the present invention, the distribution network automation device in step (1) includes an automation switch. The distribution automation equipment mainly refers to an automation switch, a control box of the distribution automation equipment enables the switch to realize automation functions such as remote measurement, remote signaling and remote control through electric quantity extraction, meanwhile, the equipment has a communication module, and can realize information interaction functions with three operators such as a network system and a communication system in a southern power grid, and typically, a pole switch FTU of a distribution network line, a cable distribution box or a DTU of a switch station belong to the distribution automation equipment.
Preferably, the distribution automation equipment in step (1) includes the communication module.
As a preferred technical solution of the present invention, the detecting in step (1) includes detecting any one of mass percentage, concentration percentage or mole percentage of the chemical substance, or a combination of at least two of the above. The specific chemical substance detection method can be carried out according to the method in the prior art. This is a direct measure of the chemical content.
As a preferred embodiment of the present invention, the method for detecting in step (1) comprises: and spraying pigment with the color different from that of the chemical substance on the pole to serve as a safety color, taking the color of the chemical substance as an alarm color, periodically collecting the color of the pole by using an optical system, and determining the oxidation condition of the battery pole of the distribution automation equipment according to the area ratio of the alarm color to the safety color. Wherein the area of the warning color is based on the total area of all kinds of warning colors. This is an indirect detection of the content of a chemical by the proportion of the area occupied by the particular colour of the chemical.
The optical system can adopt a color sensor to collect information, and calculate and judge the percentages of the safety color and the warning color through a built-in or external color identification and calculation system.
Besides the method for detecting according to the color, the method can also be used for discriminating other characteristics of the oxide generated in the oxidation process as a monitoring basis.
Preferably, the alert colors include white, blue and green.
Preferably, the security color comprises red. Red is the inverse of white, blue and green.
As a preferable technical scheme of the invention, the detection period of the detection in the step (1) is 1-4 times, such as 1 time, 2 times, 3 times or 4 times, in a day.
As a preferable technical solution of the present invention, the set value in the step (2) is a critical value at which the oxidation degree affects normal operation of the battery of the distribution network automation equipment. The critical value is an oxidation degree value which can affect the normal operation of the distribution network automation equipment battery and cause the distribution network automation equipment battery to be incapable of operating normally or needs to be eliminated.
As a preferable technical solution of the present invention, in the step (2), if the preset value is exceeded, the detection device converts the information exceeding the preset value into an electronic signal pulse and transmits the electronic signal pulse to the distribution network automation equipment, and a system of the distribution network automation equipment automatically sends an alarm through the communication module.
As a preferred technical scheme of the invention, the alarm in the step (2) comprises a background on-line system alarm and/or a short message alarm.
In the invention, a background on-line system can display the excessive oxidation degree of the pole of the storage battery of the automatic equipment to which the storage battery belongs, and a short message sending alarm function can be put into use if necessary. At the moment, the operation and maintenance personnel of the power supply department can see that the battery post of certain automatic equipment, which is prompted by the system, is seriously oxidized and needs to replace the storage battery pack on a platform on the network line, and can receive a short message prompt sent by the automatic equipment under the condition that no computer is available (or busy with other work such as going out), so as to arrange and process the hidden danger of the oxidization of the battery post in time.
As a further preferred technical solution of the method of the present invention, the method comprises the steps of:
(1) detecting the content of copper sulfate generated in the oxidation process of the terminal of the lead-acid storage battery pack of the distribution network automation equipment; the lead wire connected with the lead-acid storage battery pack is a copper wire, and the connecting terminal on the pole of the lead-acid storage battery pack is made of copper;
the detection method comprises the following steps: spraying pigment with the color different from that of the copper sulfate on the pole to serve as a safety color, taking the color of the chemical substance as an alarm color, periodically collecting the color of the pole by using an optical system, and determining the oxidation condition of the battery pole of the distribution network automation equipment according to the area proportion of the alarm color and the safety color; the detection period of the detection is 1-4 times a day;
(2) and (2) judging whether the content detected in the step (1) exceeds a set value or not, if so, converting the information exceeding the set value into an electronic signal pulse by a detection device and transmitting the electronic signal pulse to the distribution network automation equipment, and automatically sending a background online system alarm and/or a short message alarm by a system of the distribution network automation equipment through a communication module in the distribution network automation equipment.
Compared with the prior art, the invention has the following beneficial effects:
the method for monitoring the oxidation condition of the battery pole of the distribution network automation equipment can realize real-time monitoring of the oxidation condition of the battery pole of the distribution network automation equipment, powerfully control the oxidation condition of the pole of the storage battery pack, and prevent the automation equipment from working normally when the line has a trip fault or is in maintenance power failure due to abnormal operation of the storage battery pack caused by the oxidation of the pole of the storage battery pack. Meanwhile, through the method and the application, the oxidation of the pole of the storage battery pack can be found in time, and automatic alarm and signal sending can be realized, so that the defects can be found in advance, the defects can be eliminated in time, and the lead-acid storage battery pack with the oxidation condition or the heavier oxidation condition can be replaced, the problems of long time period, poor timeliness, high labor cost and the like caused by manual inspection are solved, the productivity is liberated, the production operation efficiency is improved, the safe operation capacity of the power distribution network line is powerfully consolidated, the unnecessary replacement expenditure of the storage battery pack by turns is reduced, and the economic benefit is improved.
Detailed Description
The technical solution of the present invention is further illustrated by the following specific examples. It should be understood by those skilled in the art that the examples are only for the understanding of the present invention and should not be construed as the specific limitations of the present invention.
Example 1
(1) Detecting the content of copper sulfate generated in the oxidation process of a lead-acid storage battery pack pole of the distribution network automatic switch; the lead of the lead-acid storage battery is a copper wire, and the material of a connecting terminal on a pole of the battery is copper (copper nose);
the detection method comprises the following steps: spraying red pigment as a safety color on the pole, taking the color of copper sulfate (white, blue and green) as an alarm color, periodically and automatically acquiring the color of the pole by using an optical system, and determining the oxidation condition of the battery pole of the distribution automation equipment according to the area ratio of the alarm color (the sum of the white, the blue and the green) to the safety color; the detection period of the detection is 1 time per day;
(2) and (2) judging whether a set value is exceeded or not according to the content detected in the step (1) (the ratio of the area of the alarm color to the area of the safety color is 50 percent) if the content exceeds the set value, converting the information exceeding the set value into electronic signal pulses by a detection device and transmitting the electronic signal pulses to the distribution network automatic switch, and automatically transmitting signals by a system of the distribution network automatic switch through a communication module in the distribution network automatic switch to enable a background on-line system to display the excessive oxidation degree of the storage battery post of the automatic switch belonging to the storage battery.
Example 2
(1) Detecting the content of copper sulfate generated in the oxidation process of a lead-acid storage battery pack pole of the distribution network automatic switch; the lead of the lead-acid storage battery is a copper wire, and the material of a connecting terminal on a pole of the battery is copper (copper nose);
the detection method comprises the following steps: spraying red pigment as a safety color on the pole, taking the color of copper sulfate (white, blue and green) as an alarm color, periodically and automatically acquiring the color of the pole by using an optical system, and determining the oxidation condition of the battery pole of the distribution automation equipment according to the area ratio of the alarm color (the sum of the white, the blue and the green) to the safety color; the detection period of the detection is 4 times a day (namely, the detection is performed every 6 hours);
(2) and (2) judging whether a set value is exceeded or not according to the content detected in the step (1) (the ratio of the area of the alarm color to the area of the safety color is 50 percent) if the content exceeds the set value, converting the information exceeding the set value into electronic signal pulses by a detection device and transmitting the electronic signal pulses to the distribution network automatic switch, and automatically transmitting signals by a system of the distribution network automatic switch through a communication module in the distribution network automatic switch to enable a background on-line system to display the excessive oxidation degree of the storage battery post of the automatic switch storage battery and give an alarm by short messages at the same time.
The method provided in the embodiment can realize real-time monitoring of the oxidation condition of the battery pole of the distribution network automation equipment, effectively control the oxidation condition of the battery pole of the storage battery, and prevent the automation equipment from working normally when the line is in a trip fault or is in maintenance power failure due to abnormal operation of the storage battery caused by the oxidation of the battery pole. Meanwhile, through the method and the application, the oxidation of the pole of the storage battery pack can be found in time, and automatic alarm and signal sending can be realized, so that the defects can be found in advance, the defects can be eliminated in time, and the lead-acid storage battery pack with the oxidation condition or the heavier oxidation condition can be replaced, the problems of long time period, poor timeliness, high labor cost and the like caused by manual inspection are solved, the productivity is liberated, the production operation efficiency is improved, the safe operation capacity of the power distribution network line is powerfully consolidated, the unnecessary replacement expenditure of the storage battery pack by turns is reduced, and the economic benefit is improved.
The applicant states that the present invention is illustrated by the above examples to show the detailed process equipment and process flow of the present invention, but the present invention is not limited to the above detailed process equipment and process flow, i.e. it does not mean that the present invention must rely on the above detailed process equipment and process flow to be implemented. It should be understood by those skilled in the art that any modification of the present invention, equivalent substitutions of the raw materials of the product of the present invention, addition of auxiliary components, selection of specific modes, etc., are within the scope and disclosure of the present invention.

Claims (10)

1. The method for monitoring the oxidation condition of the battery pole of the distribution network automation equipment is characterized by comprising the following steps of:
(1) detecting the content of chemical substances generated in the oxidation process of the battery pole of the distribution automation equipment;
(2) and (3) judging whether the content detected in the step (1) exceeds a set value or not, and if so, automatically giving an alarm by the communication module.
2. The method of claim 1, wherein the battery of step (1) comprises a lead-acid battery;
preferably, the battery of step (1) is a battery pack;
preferably, in the step (1), the lead wire connected with the battery is a copper wire, and the connecting terminal on the battery post is made of copper;
preferably, the chemical of step (1) comprises copper sulfate.
3. The method of claim 1 or 2, wherein step (1) the distribution network automation device comprises an automation switch;
preferably, the distribution automation equipment in step (1) includes the communication module.
4. The method of any one of claims 1-3, wherein the detecting of step (1) comprises detecting any one of mass percent, concentration percent, or mole percent of the chemical species, or a combination of at least two thereof.
5. The method according to any one of claims 1-4, wherein the method of detecting of step (1) comprises: spraying pigment with the color different from that of the chemical substance on the pole to serve as a safety color, taking the color of the chemical substance as an alarm color, periodically collecting the color of the pole by using an optical system, and determining the oxidation condition of the battery pole of the distribution automation equipment according to the area ratio of the alarm color to the safety color;
preferably, the alert colors include white, blue and green;
preferably, the security color comprises red.
6. The method according to any one of claims 1-5, wherein the detection period of the detection in step (1) is 1-4 times a day.
7. The method of any one of claims 1-6, wherein the set point of step (2) is a threshold at which a degree of oxidation affects normal operation of the network automation device battery.
8. The method according to any one of claims 1 to 7, wherein in step (2), if a set value is exceeded, a detection device converts the information exceeding the set value into an electronic signal pulse to be transmitted to the distribution network automation equipment, and a system of the distribution network automation equipment automatically sends an alarm through a communication module.
9. The method of any one of claims 1-8, wherein the alert of step (2) comprises a background online system alert and/or a short message alert.
10. Method according to any of claims 1-9, characterized in that the method comprises the steps of:
(1) detecting the content of copper sulfate generated in the oxidation process of the terminal of the lead-acid storage battery pack of the distribution network automation equipment; the lead wire connected with the lead-acid storage battery pack is a copper wire, and the connecting terminal on the pole of the lead-acid storage battery pack is made of copper;
the detection method comprises the following steps: spraying pigment with the color different from that of the copper sulfate on the pole to serve as a safety color, taking the color of the chemical substance as an alarm color, periodically collecting the color of the pole by using an optical system, and determining the oxidation condition of the battery pole of the distribution network automation equipment according to the area proportion of the alarm color and the safety color; the detection period of the detection is 1-4 times a day;
(2) and (2) judging whether the content detected in the step (1) exceeds a set value or not, if so, converting the information exceeding the set value into an electronic signal pulse by a detection device and transmitting the electronic signal pulse to the distribution network automation equipment, and automatically sending a background online system alarm and/or a short message alarm by a system of the distribution network automation equipment through a communication module in the distribution network automation equipment.
CN202110221147.3A 2021-02-26 2021-02-26 Method for monitoring oxidation condition of battery pole of distribution network automation equipment Pending CN113036240A (en)

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JPH09229869A (en) * 1996-02-28 1997-09-05 Tomoe Corp Method and system apparatus for detecting internal corrosion inside tubes
JP2010019807A (en) * 2008-07-14 2010-01-28 Nippon Telegr & Teleph Corp <Ntt> Image analysis method for conduit inspection using luminance and color difference, image analysis apparatus, conduit inspection system, and program
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