Method for treating and utilizing waste quartz stone solid waste in jewel processing
Technical Field
The invention relates to the technical field of waste treatment and recycling, in particular to a method for treating and utilizing waste quartz stone solid waste in gem processing.
Background
China is a large country for jewelry production and consumption, and currently, more than 30 different types of gem processing bases with world influence exist nationwide. For example, the Guangdong Polo quadrangle is a large domestic color gem processing trade gathering place, and more than 3000 small workshop type processing factories exist in the peak period. The raw materials processed and processed in the Guangdong Polo quadrangle building gem processing trade collecting and distributing place are all gem stones with pure texture and colorful colors. Gemstone stones come from all over the world, including many precious and rare gemstone sources.
A large amount of leftover materials are generated in the process of processing gemstones, and are not reasonably utilized at present. Taking quartz stone processing as an example, a large amount of quartz sand leftover solid waste is generated in the stone cutting, cutting and shaping processes. Quartz stone leftover materials produced in the processing process are mixed with other tailings, are disorderly poured everywhere, are not subjected to environmental protection treatment, are not reasonably utilized, cause resource waste, and seriously pollute the environment.
In order to effectively solve the problem of environmental pollution caused by the gem processing industry, a method for classifying and treating gem processing leftover materials is needed to be developed, so that solid wastes generated by gem processing can be recycled and reused with high value.
Disclosure of Invention
The invention mainly solves the technical problem of providing a method for treating and utilizing the solid waste of the waste quartz stone in gem processing, which can obtain various utilizable products by simple treatment, such as quartz sand and quartz powder for artificial quartz stone slabs, and changes waste into valuable.
In order to solve the technical problems, the invention adopts the technical scheme that: a method for treating and utilizing solid waste of waste quartz stone in gem processing comprises the following steps:
(1) directly scrubbing quartz stone leftover materials generated by processing gemstones, namely directly scrubbing the quartz stone leftover materials under the condition of original granularity to remove impurities to obtain scrubbed leftover materials; the scrubbing operation can be carried out by adopting a cylindrical scrubbing machine, soil or dirt on the surface of the leftover materials is scrubbed and removed, the leftover materials after scrubbing are screened out by a cylindrical screen to obtain oversize leftover materials and impurities, the impurities enter a mud material treatment system for treatment, and the oversize leftover materials are the scrubbed leftover materials;
(2) crushing the scrubbing leftover materials to a granularity of-4.75 mm, and then carrying out secondary scrubbing and impurity removal to obtain secondary scrubbing leftover materials; the secondary scrubbing treatment can be carried out by adopting a cylindrical scrubbing machine, and then fine-grained slurry with the thickness of-1 mm is screened out by a cylindrical screen to obtain secondary scrubbing leftover materials; the scrubbing leftover materials are crushed by a closed circuit, and preferably a closed circuit crushing device combining a double-roller crusher and a vibrating screen is adopted;
crushing to a granularity of-4.75 mm, and then scrubbing for the second time, wherein the specific surface area is increased after the granularity is thinned, so that the residual soil and dirt at the sunken position of the solid waste surface of the quartz stone after the first-stage scrubbing can be further removed; the crushing granularity of-4.75 mm is selected to be more suitable for the requirement of the granularity of the sand for the artificial quartz stone plate;
(3) screening the secondary scrubbing leftover materials to obtain coarse sand with the particle size of-4.75 mm and 0.71mm and fine sand with the particle size of-0.71 mm;
(4) drying the coarse-grained sand, screening and grading, and performing photoelectric color selection on each grade of graded products to obtain pure-color quartz stone sand grain products with different grain grades, wherein the pure-color quartz stone sand grain products with different grain grades are used as sand grain raw materials for the artificial quartz stone plate;
and grinding the fine sand to a granularity of-0.074 mm, and then performing iron removal and purification through strong magnetic separation to obtain a nonmagnetic product serving as a powdery raw material for the artificial quartz stone plate.
Preferably, in step (4), the screening and classification respectively obtain products with two size fractions of-4.75 +2.00mm and-2.00 +0.71 mm.
Preferably, in the step (4), the fine sand grinding is a closed circuit grinding system formed by connecting a ball mill and a cyclone; the ball mill adopts a ball mill with a ceramic lining, and preferably, the grinding medium of the ball mill is ceramic balls.
Preferably, in the step (4), impurities obtained by photoelectric color separation are used as a machine-made sand product.
Preferably, in the step (4), the magnetic impurities obtained by removing iron through strong magnetic separation are used as ceramsite products.
Preferably, the photoelectric color selection is performed by using a photoelectric color selector; further preferably, the photoelectric color selection conditions of the product with the particle size fraction of-4.75 +2.00mm are as follows: the background color is blue, the sensitivity is 30-60%, the number of lines is 3-5, the number of scabs is 1-8, and the mottled particles are removed in a heterochromous particle reverse selection mode;
photoelectric color selection conditions of a product with a particle size fraction of-2.00 +0.71mm are as follows: the background color is green, the sensitivity is 30-60%, the number of lines is 3-5, the number of scabs is 1-8, and the mottled particles are removed in a heterochromous particle reverse selection mode.
Preferably, the strong magnetic separator for removing iron by strong magnetic separation is a periodic high-gradient strong magnetic separator, the preferred magnetic separation strength is 0.8T-1.0T, and a steel mesh magnetic medium is preferably adopted.
The invention provides a method for treating and utilizing waste quartz stone solid waste in gem processing, which is characterized in that the quartz stone solid waste generated in the gem processing process, namely quartz stone leftover materials, is directly scrubbed by strong force, and the surface soil and dirt are removed by utilizing the collision among ores; then crushing and scrubbing again, further removing residual soil and dirt at the sunken part of the solid waste surface of the quartz stone after a section of scrubbing, and improving the purity of the raw material;
the crushing operation is set after the solid waste surface of the quartz stone is scrubbed and wetted, and the quartz stone does not need to be crushed before the first scrubbing, so that the generation of dust in the crushing process can be reduced, and the dust pollution is reduced;
the quartz stone solid waste is only treated by scrubbing, screening and color sorting processes, so that the original gem characteristics of a fragmentation interface can be kept, and the attractiveness of surface granules can be improved and the value of a quartz plate can be improved when the quartz stone solid waste is used for producing an artificial quartz stone plate;
the coarse sand is graded into products with two granularity ranges, then photoelectric color selection is carried out, and the products with narrow granularity ranges are adopted for optical head color selection, so that the photoelectric color selection effect can be improved, and the quality of the obtained pure quartz sand grain product is ensured.
The method for treating and utilizing the waste quartz stone solid waste in gem processing provided by the invention takes the quartz stone solid waste generated in gem processing industry as a raw material, and prepares the quartz stone solid waste which cannot be utilized at present into various products such as quartz sand, quartz powder and the like for the artificial quartz stone slab, thereby changing waste into valuable; compared with the existing production method of quartz sand and quartz powder for quartz stone slabs, the method provided by the invention has the advantages of simple preparation steps, low cost and high product cost performance.
The invention utilizes source classification treatment and mineral processing treatment technology, so that the solid waste of the quartz stone in gem processing is recycled and utilized with high value, the waste is changed into valuable, the process is simple, the invention has great significance for sustainable development of gem processing industry, and the popularization and the application are convenient.
Drawings
FIG. 1 is a process flow chart of a method for treating and utilizing waste quartz stone in gem processing provided by the invention.
Detailed Description
The technical solution of the present invention will be described in detail by specific examples.
The percentages in the following examples are given by mass.
Example 1
The object of this embodiment is that the quartz is useless admittedly, the leftover bits that produce in the quartz course of working, and the particle size range of former granularity is 10 ~ 205mm, and its multielement analysis is seen in table 1, and the particle size sieve analysis result is seen in table 2.
TABLE 1
Element(s)
|
Al2O3 |
SiO2 |
Fe2O3 |
CaO
|
MgO
|
K2O
|
Na2O
|
TiO2 |
Content (%)
|
0.45
|
99.34
|
0.11
|
0.05
|
0.02
|
0.036
|
0.048
|
0.01 |
TABLE 2
Size fraction (mm)
|
Yield (%)
|
+12
|
57.89
|
-12+8
|
34.78
|
-8+4
|
4.24
|
-4+2
|
1.74
|
-2
|
1.35
|
Total up to
|
100.00 |
The process flow shown in fig. 1 is adopted to treat the quartz stone leftover materials, and the treatment steps are as follows:
(1) scrubbing quartz stone leftover materials under the original granularity condition by a cylindrical scrubbing machine directly, removing surface soil or dirt by means of collision among the leftover material particles, screening-1 mm fine-grain slurry by a cylindrical screen after scrubbing to obtain oversize leftover materials 1 and impurities 1, enabling the impurities 1 to enter a slurry treatment system, and enabling the oversize leftover materials 1 to be the scrubbing leftover materials;
(2) feeding the oversize leftover materials 1 into a crusher for crushing, screening by a vibrating screen after crushing, returning oversize products to the crusher for crushing to form closed crushing, and crushing to-4.75 mm size fraction; then, a strong stirring scrubbing machine is adopted for secondary scrubbing and impurity removal, a cylindrical scrubbing machine can be adopted for secondary scrubbing, and then fine-grained mud with the thickness of-1 mm is screened out by a cylindrical screen, so that secondary scrubbing leftover materials are obtained;
(3) screening the secondary scrubbing leftover materials to obtain coarse sand with the particle size of-4.75 and 0.71mm and fine sand with the particle size of-0.71 mm;
(4) after coarse sand with the grain size of-4.75 mm to 0.71mm is dried, the coarse sand is classified into two grain sizes of-4.75 to +2.00mm and-2.00 to +0.71mm through screening; the two size fractions respectively enter a photoelectric color selector to adopt a heterochromous particle reverse sorting mode to sort, and the photoelectric color sorting parameters of the size fraction of-4.75 to +2.00mm are as follows: blue background color, sensitivity of 40%, line number of 5, lesion size of 6, -2.00- +0.71mm size fraction photoelectric color selection parameters: green background color, sensitivity of 60%, line number of 4 and lesion size of 4; obtaining a pure-color quartz stone sand grain product and impurities 2 in two size fraction intervals of-4.75- +2.00mm and-2.00- +0.71mm through color sorting; the pure-color quartz stone sand grain product is used as a sand grain raw material for the artificial quartz stone plate, and the impurity 2 product can be used as a machine-made sand product;
fine sand with the diameter of-0.71 mm enters a cyclone for classification, classified settled sand enters a ceramic ball mill for ore grinding, and a product after ore grinding returns to the cyclone for classification to form closed circuit ore grinding, and the ore grinding is carried out to the diameter of-0.074 mm; and (3) carrying out strong magnetic separation and iron removal purification on the ground ore pulp by a periodic high-gradient strong magnetic separator, wherein the magnetic field intensity is 0.8T, so as to obtain magnetic impurities as a product for ceramsite, and the obtained nonmagnetic product as a powdery raw material for artificial quartz stone slabs.
The multi-element analysis of the pure-colored quartzite sand grain product and the non-magnetic product are shown in tables 3 and 4, respectively.
TABLE 3
Element(s)
|
Al2O3 |
SiO2 |
Fe2O3 |
CaO
|
MgO
|
K2O
|
Na2O
|
TiO2 |
Content (%)
|
0.27
|
99.40
|
0.034
|
0.05
|
0.02
|
0.032
|
0.043
|
<0.01 |
TABLE 4
Element(s)
|
Al2O3 |
SiO2 |
Fe2O3 |
CaO
|
MgO
|
K2O
|
Na2O
|
TiO2 |
Content (%)
|
0.12
|
99.43
|
0.062
|
0.01
|
0.01
|
0.009
|
0.01
|
<0.01 |
Example 2
The object of this embodiment processing is quartz solid waste, namely, the leftover material that produces in the quartz processing, and the range of primary particle size granule size is 1 ~ 145mm, and its multielement analysis is seen in table 5, and the particle size sieve analysis result is seen in table 6.
TABLE 5
Element(s)
|
Al2O3 |
SiO2 |
Fe2O3 |
CaO
|
MgO
|
K2O
|
Na2O
|
TiO2 |
Content (%)
|
0.53
|
98.88
|
0.25
|
0.029
|
0.013
|
0.058
|
0.034
|
<0.01 |
TABLE 6
Size fraction (mm)
|
Yield (%)
|
+12
|
36.71
|
-12+8
|
41.53
|
-8+4
|
12.79
|
-4+2
|
5.03
|
-2
|
3.94
|
Total up to
|
100.00 |
The process flow shown in fig. 1 is adopted to treat the quartz stone leftover materials, and the treatment steps are as follows:
(1) scrubbing quartz stone leftover materials under the original granularity condition by a cylindrical scrubbing machine directly, removing surface soil or dirt by means of collision among the leftover material particles, screening-1 mm fine-grain slurry by a cylindrical screen after scrubbing to obtain oversize leftover materials 1 and impurities 1, enabling the impurities 1 to enter a slurry treatment system, and enabling the oversize leftover materials 1 to be the scrubbing leftover materials;
(2) feeding the oversize leftover materials 1 into a crusher for crushing, screening by a vibrating screen after crushing, returning oversize products to the crusher for crushing to form closed crushing, and crushing to-4.75 mm size fraction; then, a strong stirring scrubbing machine is adopted for secondary scrubbing and impurity removal, a cylindrical scrubbing machine can be adopted for secondary scrubbing, and then fine-grained mud with the thickness of-1 mm is screened out by a cylindrical screen, so that secondary scrubbing leftover materials are obtained;
(3) screening the secondary scrubbing leftover materials to obtain coarse sand with the particle size of-4.75 and 0.71mm and fine sand with the particle size of-0.71 mm;
(4) after coarse sand with the grain size of-4.75 mm to 0.71mm is dried, the coarse sand is classified into two grain sizes of-4.75 to +2.00mm and-2.00 to +0.71mm through screening; the two size fractions respectively enter a photoelectric color selector to adopt a heterochromous particle reverse sorting mode to sort, and the photoelectric color sorting parameters of the size fraction of-4.75 to +2.00mm are as follows: blue background color, sensitivity of 45%, line number of 4, disease spot of 1, -2.00- +0.71mm size fraction photoelectric color selection parameter: green background color, sensitivity of 50%, line number of 3 and lesion size of 2; obtaining a pure-color quartz stone sand grain product and impurities 2 in two size fraction intervals of-4.75- +2.00mm and-2.00- +0.71mm through color sorting; the pure-color quartz stone sand grain product is used as a sand grain raw material for the artificial quartz stone plate, and the impurity 2 product can be used as a machine-made sand product;
fine sand with the diameter of-0.71 mm enters a cyclone for classification, classified settled sand enters a ceramic ball mill for ore grinding, and a product after ore grinding returns to the cyclone for classification to form closed circuit ore grinding, and the ore grinding is carried out to the diameter of-0.074 mm; and (3) carrying out strong magnetic separation and iron removal purification on the ground ore pulp by a periodic high-gradient strong magnetic separator, wherein the magnetic field intensity is 1.0T, so as to obtain magnetic impurities as a product for ceramsite, and the obtained nonmagnetic product as a powdery raw material for artificial quartz stone slabs.
The multi-element analysis of the pure-colored quartzite grit product and the non-magnetic product are shown in tables 7 and 8.
TABLE 7
Element(s)
|
Al2O3 |
SiO2 |
Fe2O3 |
CaO
|
MgO
|
K2O
|
Na2O
|
TiO2 |
Content (%)
|
0.45
|
99.05
|
0.071
|
0.06
|
0.02
|
0.07
|
0.043
|
0.01 |
TABLE 8
Element(s)
|
Al2O3 |
SiO2 |
Fe2O3 |
CaO
|
MgO
|
K2O
|
Na2O
|
TiO2 |
Content (%)
|
0.21
|
99.25
|
0.10
|
0.019
|
0.01
|
0.01
|
0.01
|
0.03 |
Although the invention has been described in detail hereinabove by way of general description, specific embodiments and experiments, it will be apparent to those skilled in the art that many modifications and improvements can be made thereto based on the invention. Accordingly, such modifications and improvements are intended to be within the scope of the invention as claimed.