CN112979164B - Volcanic flow rock effect digital glaze ink and preparation method and application thereof - Google Patents
Volcanic flow rock effect digital glaze ink and preparation method and application thereof Download PDFInfo
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- CN112979164B CN112979164B CN202110315708.6A CN202110315708A CN112979164B CN 112979164 B CN112979164 B CN 112979164B CN 202110315708 A CN202110315708 A CN 202110315708A CN 112979164 B CN112979164 B CN 112979164B
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Abstract
The invention provides a volcanic flow rock effect digital glaze ink and a preparation method and application thereof, wherein the volcanic flow rock effect digital glaze ink comprises the following raw materials of flow rock glaze powder, a binder, a dispersing agent, a surfactant, a defoaming agent, a suspending agent and an organic solvent; the powder of the flowing rock glaze comprises Al 2 O 3 、Fe 2 O 3 、ZnO、CaO、MgO、K 2 O、Na 2 O、BaO、Ti 2 O and SiO 2 . By adjusting the composition of the digital glaze ink and the fluent rock glaze material powder, the invention ensures that the glaze layer formed by the digital glaze ink when used for ink-jet printing is thinner, and has excellent wear resistance, high temperature resistance and transparency, high-brightness volcanic fluent rock effect and higher visual impact.
Description
Technical Field
The invention belongs to the technical field of materials, relates to a glaze material, and particularly relates to volcanic fluid rock effect digital glaze ink as well as a preparation method and application thereof.
Background
The ceramic has different artistic styles and different technical characteristics, colorful and various colored glazes appear during the development period of the ceramic technology, and cyan comprises bean green, shadow green, pink green or Longquan sky green and the like; the purple color comprises worship red, Langdian red, rose violet, drunk beauty or enamel red, etc.; yellow including radix Et rhizoma Rhei, rhizoma picrorhizae, Monopteri albi yellow or pollen yellow etc.; green including emerald green, malachite green, staphylinium green or malachite green; black including black gold, rust or dull black; others include crystalline glaze, crack glaze or gold sand glaze, etc.
Among the colored glazes, the ceramic product obtained by adopting the glaze with the lighter color has the advantages of good brightness and luster, but the ceramic product obtained by adopting the glaze with the darker color is generally darker and has insufficient visual impact.
The ceramic ink-jet technology is a non-contact digital printing technology, and is characterized by that the ceramic pigment can be made into multi-colour ink, and said ink can be directly printed on the surface of ceramic by means of computer-controlled printer, so that it can utilize rich resource of computer, and can utilize software signal to change decorative design in real time, and can raise development and production efficiency of new product and can raise decorative effect.
CN 106542812A discloses a magic glazed tile and a production method thereof, the method comprises the steps of sequentially applying base glaze and overglaze on a ceramic blank after biscuit firing through a glaze pouring device, carrying out ink-jet printing on the overglaze through an ink-jet printer to form a pattern, sequentially carrying out fixed-point printing on the pattern through continuously arranged first and second screen printing devices to form matte convex glaze and bright convex glaze, carrying out fixed-point printing on the pattern through a third screen printing device when the ink-jet printing ink does not contain bright red ink, and finally applying candy glaze on the tile surface. However, the above production method is complicated in operation, and when it is necessary to print red, the problem of color development of scarlet ink cannot be solved.
CN 105219159a discloses a ceramic flash glaze ink and a preparation method thereof, wherein the ceramic flash glaze ink comprises the following raw material components: 2-10 parts of resin; 30-60 parts of organic solvent; 30-55 parts of flash glaze; 5-10 parts of hyperdispersant; 0.1-35 parts of assistant. Through the adjustment of the formula of the flash glaze, the ceramic flash glaze printing ink is durable, environment-friendly and non-toxic, the ink-jet printing technology is combined with the traditional technology, the functional ink is directly sprayed to the surface of the ceramic, the fired glaze surface has good brightness, and the ink-jet printing has the characteristics of high efficiency, low pollution, small glaze amount, safety and high efficiency. CN 105131716a discloses a ceramic bright glaze ink and a preparation method thereof, the ceramic bright glaze ink comprises the following raw material components: 2-10 parts of resin; 30-60 parts of organic solvent; 30-55 parts of flash glaze; 5-10 parts of hyperdispersant; 0.1 to 35 portions of auxiliary agent. Through the adjustment of the formula of the flash glaze, the ceramic flash glaze printing ink is durable, environment-friendly and non-toxic, the ink-jet printing technology is combined with the traditional technology and the technology, the functional ink is directly sprayed to the surface of the ceramic, the fired glaze surface is good in brightness, and the ink-jet printing has the characteristics of high efficiency, low pollution, small glaze amount, safety and high efficiency.
According to the preparation method, the glaze with the glittering effect is obtained through the adjustment of the glaze components and the synergistic use of ink-jet printing, but the preparation method cannot be used for preparing the glaze with deeper color and higher brightness.
In contrast, a brand new digital glaze ink is needed, and after the ink is printed on a substrate in an inkjet manner, a glaze with a volcanic rock effect and a deep color and high brightness can be obtained.
Disclosure of Invention
Aiming at the defects in the prior art, the invention aims to provide the volcanic flow rock effect digital glaze ink and the preparation method and the application thereof.
In order to achieve the purpose, the invention adopts the following technical scheme:
in a first aspect, the invention provides a volcanic fluid rock effect digital glaze ink, which comprises the following raw materials in parts by weight:
according to the invention, by adjusting the proportion of the flowing rock glaze powder, the binder, the dispersing agent, the surfactant, the defoaming agent, the suspending agent and the organic solvent, the volcanic-flowing rock effect digital glaze ink has a thinner glaze layer formed when being used for ink-jet printing, and has excellent wear resistance, high temperature resistance and transparency, a high-brightness volcanic-flowing rock effect and a high visual impact force.
The parts by weight of the flow rock glaze powder in the volcanic flow rock effect digital glaze ink of the invention are 30-45 parts, such as 30 parts, 31 parts, 32 parts, 33 parts, 34 parts, 35 parts, 36 parts, 37 parts, 38 parts, 39 parts, 40 parts, 41 parts, 42 parts, 43 parts, 44 parts or 45 parts, but not limited to the enumerated values, and other unrecited values in the numerical range are also applicable, preferably 35-40 parts.
The binder in the volcanic flow rock effect digital glaze ink is 4-8 parts by weight, such as 4 parts, 5 parts, 6 parts, 7 parts or 8 parts, but not limited to the enumerated values, and other unrecited values in the numerical range are also applicable, and 5-7 parts are preferred.
The weight portion of the dispersant in the volcanic fluid rock effect digital glaze ink is 25 to 45 portions, such as 25 portions, 27 portions, 28 portions, 30 portions, 32 portions, 35 portions, 36 portions, 38 portions, 40 portions, 42 portions or 45 portions, but not limited to the recited values, and other values in the numerical range are also applicable, and 30 to 40 portions are preferred.
The parts by weight of the surfactant in the volcanic fluid rock effect digital glaze ink of the invention are 2-4 parts, for example, 2 parts, 2.5 parts, 3 parts, 3.5 parts or 4 parts, but not limited to the values listed, and other values not listed in the range of the values are also applicable, and 3-4 parts is preferred.
The foam suppressor is used in the volcanic rock effect digital glaze ink in an amount of 0.2-0.5 parts by weight, such as 0.2 parts, 0.3 parts, 0.4 parts or 0.5 parts by weight, but not limited to the above-mentioned values, and other values within the range of values are also applicable, preferably 0.2-0.4 parts by weight.
The weight portion of the suspending agent in the volcanic flow rock effect digital glaze ink is 0.05-0.12, such as 0.05, 0.06, 0.07, 0.08, 0.09, 0.1, 0.11 or 0.12, but not limited to the recited values, and other values in the range of the values are also applicable, and preferably 0.05-0.08.
The parts by weight of the organic solvent in the volcanic fluid rock effect digital glaze ink of the invention are 30-40 parts, such as 30 parts, 31 parts, 32 parts, 33 parts, 34 parts, 35 parts, 36 parts, 37 parts, 38 parts, 39 parts or 40 parts, but not limited to the cited values, and other values in the numerical range are also applicable, preferably 32-36 parts.
Preferably, the composition of the flowing rock glaze material powder comprises the following components in percentage by mass:
the balance being SiO 2 。
Al in the powder of the fluent rock glaze material 2 O 3 Is 13.5 to 16 wt.%, for exampleIn an amount of 13.5 wt.%, 14 wt.%, 14.5 wt.%, 15 wt.%, 15.5 wt.% or 16 wt.%, but not limited to the recited values, and other values not recited in the numerical ranges are equally applicable, preferably 14 to 15.5 wt.%.
Fe in the powder of the fluid rock glaze of the invention 2 O 3 The percentage by mass of (B) is 0.01 to 0.1% by weight, and may be, for example, 0.01%, 0.02%, 0.03%, 0.04%, 0.05%, 0.06%, 0.07%, 0.08%, 0.09% or 0.1% by weight, but is not limited to the values recited, and other values not recited within the numerical range are also applicable.
The powder of the slip rock glaze according to the invention contains 1.5 to 4 wt% of ZnO, and may be, for example, 1.5 wt%, 2 wt%, 2.5 wt%, 3 wt%, 3.5 wt% or 4 wt%, but is not limited to the recited values, and other values not recited in the range of values are also applicable, and preferably 2 to 3 wt%.
The mass percent of CaO in the powder of the quickrock glaze of the present invention is 8 to 12 wt%, for example, 8 wt%, 9 wt%, 10wt%, 11 wt% or 12 wt%, but not limited to the recited values, and other values not recited in the range of values are also applicable, preferably 9 to 11 wt%.
The powder of the slip rock glaze according to the invention may contain MgO in an amount of 2 to 6 wt%, for example 2 wt%, 3 wt%, 4 wt%, 5 wt% or 6 wt%, but is not limited to the values recited, and other values not recited in the numerical range are equally applicable, preferably 3 to 6 wt%.
K in the powder of the fluent rock glaze material 2 The percentage by mass of O is from 0.5 to 2% by weight, and may be, for example, 0.5%, 0.8%, 1%, 1.2%, 1.5%, 1.6%, 1.8% or 2% by weight, but is not limited to the values cited, and other values not listed in the numerical range are equally applicable, preferably from 1 to 2% by weight.
Na in the flowing rock glaze powder 2 The percentage by mass of O is, for example, from 2 to 4% by weight, and may be, for example, 2%, 2.5%, 3%, 3.5% or 4% by weight, but is not limited to the values cited, and other values not listed in the numerical range are equally applicable, preferably from 2.5 to 4% by weight.
The powder of the slip rock glaze of the present invention may contain BaO in an amount of 1 to 4 wt%, for example, 1 wt%, 1.5 wt%, 2 wt%, 2.5 wt%, 3 wt%, 3.5 wt% or 4 wt%, but is not limited to the recited values, and other values not recited in the range of values are also applicable, preferably 2 to 3 wt%.
Ti in the fluid rock glaze powder 2 The percentage by mass of O is 0.01 to 0.1% by weight, and may be, for example, 0.01%, 0.02%, 0.03%, 0.04%, 0.05%, 0.06%, 0.07%, 0.08%, 0.09% or 0.1% by weight, but is not limited to the values cited, and other values not listed within the range of values are equally suitable.
The invention can be used for ink-jet printing by adjusting the composition of the volcanic flow rock effect digital glaze ink and the flow rock glaze powder. The formed glaze layer can protect the pattern layer from being damaged and has better transparency; the glaze layer has a certain wear-resistant effect, delicate hand feeling and wide firing range; the embossing effect in the firing process is not easy to level, and the glossiness is more than 80 degrees after firing.
Furthermore, the invention adjusts Al in the flowing rock glaze powder 2 O 3 CaO and Na 2 The mass percentage of the O component enables a large amount of anorthite crystals to be separated out in the process of firing the glaze layer, the diffuse reflection effect of light is improved, and the visual effect of light fall is formed.
Preferably, the powder of quickrock glaze has a loss on ignition of 1 to 10wt%, for example 1 wt%, 2 wt%, 3 wt%, 4 wt%, 5 wt%, 6 wt%, 7 wt%, 8 wt%, 9 wt% or 10wt%, but not limited to the recited values, and other values not recited within the range of values are equally applicable, preferably 5 to 10 wt%.
Preferably, the binder comprises carboxymethyl cellulose and/or acrylic resin.
Preferably, the dispersant comprises any one of or a combination of at least two of a polyacrylate dispersant, a polyurethane dispersant or an aromatic hydrocarbon dispersant.
Preferably, the surfactant comprises any one of or a combination of at least two of octadecyl dihydroxyethyl amine oxide, tetradecyl dihydroxyethyl amine oxide, or octadecyl amidopropyl amine oxide.
Preferably, the defoamer comprises polydimethylsiloxane.
Preferably, the suspending agent comprises bentonite and/or attapulgite.
Preferably, the organic solvent includes any one of hydrocarbon organic solvents, alcohol organic solvents or ester organic solvents or a combination of at least two thereof.
Illustratively, the hydrocarbon organic solvent includes n-decane and/or n-hexane.
Illustratively, the alcoholic organic solvent includes any one of isopropyl alcohol, butyl alcohol, or ethylene glycol or a combination of at least two thereof.
Illustratively, the ester organic solvent includes any one of ethyl acetate, butyl acetate, diethylene glycol butyl ether acetate, or propylene glycol methyl ether propionate, or a combination of at least two thereof.
In a second aspect, the invention provides a preparation method of the volcanic flow rock effect digital glaze ink as described in the first aspect, and the preparation method comprises the following steps:
(1) mixing the fluid rock glaze powder with 30-50wt% of binder according to the formula amount, and continuously mixing the dispersant to obtain a mixture;
(2) grinding the mixture obtained in the step (1) to a specific particle size;
(3) and continuously adding a surfactant, a defoaming agent, a suspending agent, an organic solvent and the balance of a binder according to the formula amount, and continuously grinding until the mixture is uniformly dispersed to obtain the volcanic flow rock effect digital glaze ink.
The binder is added in batches, so that the uniform dispersion effect of the flowing rock glaze powder in the volcanic flowing rock effect digital glaze ink is ensured. The amount of binder added for the first time is 30 to 50% by weight of the total amount of binder, and may be, for example, 30%, 35%, 40%, 45% or 50% by weight, but is not limited to the recited values, and other values not recited within the numerical range are also applicable.
Preferably, the specific particle size in step (2) is an average particle size of 10 to 30 μm, and may be, for example, 10 μm, 15 μm, 20 μm, 25 μm or 30 μm, but is not limited to the values recited, and other values not recited in the range of values are also applicable.
In a third aspect, the present invention provides a use of a volcanic flow rock effect glaze as defined in the first aspect, said use comprising the steps of: and ink-jet printing is carried out on the surface of the substrate to obtain the volcanic rock effect digital glaze ink, and a finished product of the glaze surface with the volcanic rock effect is obtained after sintering.
Preferably, the substrate comprises a rock plate.
Preferably, the sintering comprises the steps of:
(i) raising the temperature to 400-500 ℃ at the temperature rise rate of 8-10 ℃/min, and preserving the heat for 20-40 min;
(ii) raising the temperature to 800-900 ℃ at the temperature rise rate of 6-8 ℃/min, and preserving the heat for 60-80 min;
(iii) raising the temperature to 1150-1250 ℃ at the temperature rise rate of 4-6 ℃/min, and preserving the heat for 60-120 min;
(iv) naturally cooling to room temperature to finish sintering.
The temperature rise rate in step (i) during sintering is 8-10 deg.C/min, and may be, for example, 8 deg.C/min, 8.5 deg.C/min, 9 deg.C/min, 9.5 deg.C/min or 10 deg.C/min, but is not limited to the values recited, and other values not recited in the range of values are also applicable.
In the sintering process, the temperature raising temperature in step (i) is 400-.
During the sintering, the holding time in step (i) is 20-40min, for example, 20min, 25min, 30min, 35min or 40min, but is not limited to the values listed, and other values not listed in the range of values are also applicable.
The temperature rise rate in step (ii) during sintering is 6-8 deg.C/min, and may be, for example, 6 deg.C/min, 6.5 deg.C/min, 7 deg.C/min, 7.5 deg.C/min or 8 deg.C/min, but is not limited to the values recited, and other values not recited in the range of values are also applicable.
The temperature rise in step (ii) during sintering is 800-900 deg.C, which may be, for example, 800 deg.C, 810 deg.C, 820 deg.C, 830 deg.C, 840 deg.C, 850 deg.C, 860 deg.C, 870 deg.C, 880 deg.C, 890 deg.C or 900 deg.C, but is not limited to the values listed, and other values not listed in the range of values are equally applicable.
The holding time in step (ii) during sintering is 60-80min, for example 60min, 65min, 70min, 75min or 80min, but not limited to the values listed, and other values not listed in the range of values are equally applicable.
The temperature increase rate in step (iii) during sintering is 4-6 deg.C/min, and may be, for example, 4 deg.C/min, 4.5 deg.C/min, 5 deg.C/min, 5.5 deg.C/min or 6 deg.C/min, but is not limited to the values recited, and other values not recited in the range of values are also applicable.
In the sintering process, the temperature raising temperature in step (iii) is 1150-.
The holding time in step (iii) during sintering is 60-120min, such as 60min, 70min, 80min, 90min, 100min, 110min or 120min, but not limited to the values listed, and other values not listed in the range of values are also applicable.
As a preferable technical solution of the application of the third aspect of the present invention, the application includes the steps of:
ink-jet printing is carried out on the surface of the rock plate to obtain the volcanic flow rock effect digital glaze ink, and a finished product of a glaze surface with the volcanic flow rock effect is obtained after sintering;
the sintering comprises the following steps:
(i) raising the temperature to 400-500 ℃ at the temperature rise rate of 8-10 ℃/min, and preserving the heat for 20-40 min;
(ii) raising the temperature to 800-900 ℃ at the temperature rise rate of 6-8 ℃/min, and preserving the heat for 60-80 min;
(iii) raising the temperature to 1150-1250 ℃ at the temperature raising rate of 4-6 ℃/min, and preserving the temperature for 60-120 min;
(iv) and naturally cooling to room temperature to finish sintering.
The numerical ranges set forth herein include not only the recited values but also any values between the recited numerical ranges not enumerated herein, and are not intended to be exhaustive or otherwise clear from the intended disclosure of the invention in view of brevity and clarity.
Compared with the prior art, the invention has the beneficial effects that:
(1) according to the invention, by adjusting the proportion of the free rock glaze powder, the binder, the dispersant, the surfactant, the defoaming agent, the suspending agent and the organic solvent, the volcanic free rock effect digital glaze ink has a thinner glaze layer when being used for ink-jet printing, has excellent wear resistance, high temperature resistance and transparency, has a high-brightness volcanic free rock effect and has high visual impact;
(2) the volcanic flow rock effect digital glaze ink and the flow rock glaze powder are adjusted to be used for ink-jet printing; the formed glaze layer can not only protect the pattern layer from being damaged, but also has better transparency; the glaze layer has a certain wear-resistant effect, delicate hand feeling and wide firing range; the embossing effect in the firing process is not easy to level, and the glossiness is more than 80 degrees after firing.
Detailed Description
The technical solution of the present invention is further explained by the following embodiments.
Example 1
The embodiment provides a preparation method of volcanic fluid rock effect digital glaze ink, which comprises the following steps:
(1) mixing the flowing rock glaze powder with 40 wt% of binder according to the formula amount, and continuously mixing the dispersing agent to obtain a mixture;
(2) grinding the mixture obtained in the step (1) to an average particle size of 20 mu m;
(3) and continuously adding a surfactant, a defoaming agent, a suspending agent, an organic solvent and the balance of a binder according to the formula amount, and continuously grinding to obtain the volcanic fluid rock effect digital glaze ink.
The flowing rock glaze material powder is calculated by mass percentComprises 15 wt% of Al 2 O 3 0.05 wt% of Fe 2 O 3 2.5 wt% of ZnO, 10wt% of CaO, 4 wt% of MgO, and 1.5 wt% of K 2 O, 3 wt% of Na 2 O, 2.5 wt% BaO and 0.05 wt% Ti 2 O, the balance being SiO 2 。
The loss on ignition of the flowing rock glaze material powder is 6 wt%.
The binder is carboxymethyl cellulose; the dispersant is polyurethane dispersant DY-9006; the surfactant is octadecyl dihydroxyethyl amine oxide; the antifoaming agent is corning DC 184; the suspending agent is bentonite; the organic solvent is ethylene glycol.
Example 2
The embodiment provides a preparation method of volcanic flow rock effect digital glaze ink, which comprises the following steps:
(1) mixing the fluid rock glaze powder with 35 wt% of binder according to the formula amount, and continuously mixing the dispersant to obtain a mixture;
(2) grinding the mixture obtained in the step (1) to an average particle size of 15 mu m;
(3) and continuously adding a surfactant, a defoaming agent, a suspending agent, an organic solvent and the balance of a binder according to the formula amount, and continuously grinding to obtain the volcanic flow rock effect digital glaze ink.
The composition of the flowing rock glaze material powder comprises 15 wt% of Al in percentage by mass 2 O 3 0.05 wt% Fe 2 O 3 2.5 wt% ZnO, 10wt% CaO, 4 wt% MgO, 1.5 wt% K 2 O, 3 wt% of Na 2 O, 2.5 wt% BaO and 0.05 wt% Ti 2 O, the balance being SiO 2 。
The loss on ignition of the flowing rock glaze material powder is 6 wt%.
The binder is carboxymethyl cellulose; the dispersant is polyurethane dispersant DY-9006; the surfactant is octadecyl amide propyl amine oxide; the antifoaming agent is corning DC 184; the suspending agent is bentonite; the organic solvent is n-hexane.
Example 3
The embodiment provides a preparation method of volcanic flow rock effect digital glaze ink, which comprises the following steps:
(1) mixing the fluid rock glaze powder with 45 wt% of binder according to the formula amount, and continuously mixing the dispersant to obtain a mixture;
(2) grinding the mixture obtained in the step (1) to an average particle size of 25 μm;
(3) and continuously adding a surfactant, a defoaming agent, a suspending agent, an organic solvent and the balance of a binder according to the formula amount, and continuously grinding to obtain the volcanic flow rock effect digital glaze ink.
The composition of the fluid rock glaze powder comprises 15 wt% of Al in percentage by mass 2 O 3 0.05 wt% of Fe 2 O 3 2.5 wt% of ZnO, 10wt% of CaO, 4 wt% of MgO, and 1.5 wt% of K 2 O, 3 wt% of Na 2 O, 2.5 wt% BaO and 0.05 wt% Ti 2 O, the balance being SiO 2 。
The loss on ignition of the fluid rock glaze powder is 6 wt%.
The binder is carboxymethyl cellulose; the dispersant is polyacrylate dispersant PROX A987; the surfactant is tetradecyl dihydroxyethyl amine oxide; the antifoaming agent is corning DC 184; the suspending agent is attapulgite; the organic solvent is ethyl acetate.
Example 4
The embodiment provides a preparation method of volcanic flow rock effect digital glaze ink, which comprises the following steps:
(1) mixing the flowing rock glaze powder with 30 wt% of binder according to the formula amount, and continuously mixing the dispersant to obtain a mixture;
(2) grinding the mixture obtained in the step (1) to an average particle size of 10 mu m;
(3) and continuously adding a surfactant, a defoaming agent, a suspending agent, an organic solvent and the balance of a binder according to the formula amount, and continuously grinding to obtain the volcanic flow rock effect digital glaze ink.
The composition of the fluid rock glaze powder comprises 15w by mass percentt% of Al 2 O 3 0.05 wt% of Fe 2 O 3 2.5 wt% ZnO, 10wt% CaO, 4 wt% MgO, 1.5 wt% K 2 O, 3 wt% of Na 2 O, 2.5 wt% BaO and 0.05 wt% Ti 2 O, the balance being SiO 2 。
The loss on ignition of the fluid rock glaze powder is 6 wt%.
The binder is carboxymethyl cellulose; the dispersant is polyurethane dispersant DY-9006; the surfactant is octadecyl dihydroxyethyl amine oxide; the antifoaming agent is corning DC 184; the suspending agent is bentonite; the organic solvent is ethylene glycol.
Example 5
The embodiment provides a preparation method of volcanic flow rock effect digital glaze ink, which comprises the following steps:
(1) mixing the fluid rock glaze powder with 50wt% of binder according to the formula amount, and continuously mixing the dispersant to obtain a mixture;
(2) grinding the mixture obtained in the step (1) to an average particle size of 30 mu m;
(3) and continuously adding a surfactant, a defoaming agent, a suspending agent, an organic solvent and the balance of a binder according to the formula amount, and continuously grinding to obtain the volcanic flow rock effect digital glaze ink.
The composition of the flowing rock glaze material powder comprises 15 wt% of Al in percentage by mass 2 O 3 0.05 wt% of Fe 2 O 3 2.5 wt% ZnO, 10wt% CaO, 4 wt% MgO, 1.5 wt% K 2 O, 3 wt% of Na 2 O, 2.5 wt% BaO and 0.05 wt% Ti 2 O, the balance being SiO 2 。
The loss on ignition of the fluid rock glaze powder is 6 wt%.
The binder is carboxymethyl cellulose; the dispersant is polyurethane dispersant DY-9006; the surfactant is octadecyl dihydroxyethyl amine oxide; the antifoaming agent is corning DC 184; the suspending agent is bentonite; the organic solvent is ethylene glycol.
The formulation compositions of the volcanic effect digital glaze inks described in examples 1-5 are shown in table 1, and the data in table 1 represents the parts by weight of each composition.
TABLE 1
| Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | |
| Powder of slip rock glaze | 36 | 35 | 40 | 30 | 45 |
| Binder | 6 | 5 | 7 | 4 | 8 |
| Dispersing agent | 35 | 30 | 40 | 25 | 45 |
| Surface active agent | 3.5 | 4 | 3 | 4 | 2 |
| Defoaming agent | 0.3 | 0.2 | 0.4 | 0.2 | 0.5 |
| Suspending agent | 0.06 | 0.08 | 0.05 | 0.12 | 0.05 |
| Organic solvent | 35 | 36 | 32 | 40 | 30 |
Example 6
This example provides a method for preparing volcanic flow rock effect digital glaze ink, except that the composition of the flow rock glaze powder includes 14 wt% of Al 2 O 3 0.03 wt% of Fe 2 O 3 2 wt% of ZnO, 9 wt% of CaO, 3 wt% ofMgO, 1 wt% K 2 O, 2.5 wt% of Na 2 O, 2 wt% BaO and 0.03 wt% Ti 2 O, the balance being SiO 2 The same as in example 1, except that the loss on ignition of the powder of the quickrock glaze was 5 wt%.
Example 7
This example provides a method for preparing volcanic flow rock effect digital glaze ink, except that the composition of the flow rock glaze powder includes 15.5 wt% of Al 2 O 3 0.08 wt% Fe 2 O 3 3 wt% of ZnO, 11 wt% of CaO, 5 wt% of MgO, and 2 wt% of K 2 O, 3.5 wt% of Na 2 O, 3 wt% BaO and 0.08 wt% Ti 2 O, the balance being SiO 2 The same as example 1, except that the loss on ignition of the powder of the quickrock glaze was 8 wt%.
Example 8
This example provides a method for preparing volcanic flow rock effect digital glaze ink, except that the composition of the flow rock glaze powder includes 13.5 wt% of Al 2 O 3 0.01 wt% of Fe 2 O 3 1.5 wt% ZnO, 8 wt% CaO, 2 wt% MgO, 0.5 wt% K 2 O, 2 wt% of Na 2 O, 1 wt% BaO and 0.01 wt% Ti 2 O, the balance being SiO 2 The same procedure as in example 1 was repeated except that the loss on ignition of the powder of the quickrock glaze was 1 wt%.
Example 9
This example provides a method for preparing a volcanic fluid rock effect digital glaze ink, except that the fluid rock glaze powder comprises 16 wt% of Al 2 O 3 0.1 wt% of Fe 2 O 3 4 wt% of ZnO, 12 wt% of CaO, 6 wt% of MgO, 2 wt% of K 2 O, 4 wt% of Na 2 O, 4 wt% BaO and 0.1 wt% Ti 2 O, the balance being SiO 2 The same as in example 1, except that the loss on ignition of the powder of the quickrock glaze was 10 wt%.
Example 10
The embodiment provides a preparation method of volcanic flow rock effect digital glaze ink, which is used for removing Al in flow rock glaze powder 2 O 3 The mass percent of the components is 12 wt%Otherwise, the same procedure as in example 1 was repeated.
Example 11
The embodiment provides a preparation method of volcanic flow rock effect digital glaze ink, which is used for removing Al in flow rock glaze powder 2 O 3 The same as in example 1 except that the mass percentage of (B) was 18 wt%.
Example 12
The embodiment provides a preparation method of volcanic flow rock effect digital glaze ink, and the method is the same as the embodiment 1 except that the mass percent of CaO in flow rock glaze powder is 6 wt%.
Example 13
The embodiment provides a preparation method of volcanic flow rock effect digital glaze ink, and the method is the same as the embodiment 1 except that the mass percent of CaO in flow rock glaze powder is 14 wt%.
Example 14
The embodiment provides a preparation method of volcanic flow rock effect digital glaze ink, which is used for removing Na in flow rock glaze powder 2 The procedure of example 1 was repeated except that the mass percentage of O was 1 wt%.
Example 15
This example provides a method for preparing volcanic fluid rock effect digital glaze ink, which removes Na in fluid rock glaze powder 2 The procedure of example 1 was repeated except that the mass percentage of O was 5 wt%.
Example 16
The embodiment provides a preparation method of volcanic flow rock effect digital glaze ink, and the method is the same as the embodiment 1 except that the mass percent of ZnO in the flow rock glaze powder is 1 wt%.
Example 17
The embodiment provides a preparation method of volcanic flow rock effect digital glaze ink, and the method is the same as the embodiment 1 except that the mass percent of ZnO in the flow rock glaze powder is 5 wt%.
Comparative example 1
The comparative example provides a preparation method of the digital glaze ink, and the preparation method is the same as the preparation method of the example 1 except that no binder is added in the formula of the volcanic fluid rock effect digital glaze ink.
The application of the digital glaze ink cannot be realized because no binder is added.
Comparative example 2
The comparative example provides a preparation method of a digital glaze ink, and the preparation method is the same as that of the example 1 except that a surfactant is not added in the formula of the volcanic fluid rock effect digital glaze ink.
Comparative example 3
The comparative example provides a preparation method of the digital glaze ink, and the preparation method is the same as the preparation method of the example 1 except that no defoaming agent is added in the formula of the volcanic flow rock effect digital glaze ink.
Comparative example 4
The comparative example provides a preparation method of the digital glaze ink, and the preparation method is the same as that of the example 1 except that no suspending agent is added in the formula of the volcanic fluid rock effect digital glaze ink.
Application example 1
The application example provides an application of the volcanic flow rock effect digital glaze ink provided in example 1, and the application includes the following steps:
ink-jet printing is carried out on the surface of the rock plate to obtain the volcanic flow rock effect digital glaze ink, and a finished product of a glaze surface with the volcanic flow rock effect is obtained after sintering;
the sintering comprises the following steps:
(i) raising the temperature to 450 ℃ at the heating rate of 9 ℃/min, and keeping the temperature for 30 min;
(ii) raising the temperature to 850 ℃ at the heating rate of 7 ℃/min, and keeping the temperature for 70 min;
(iii) raising the temperature to 1200 ℃ at the heating rate of 5 ℃/min, and preserving the heat for 90 min;
(iv) and naturally cooling to room temperature to finish sintering.
The glaze layer obtained by the application example can not only protect the pattern layer from being damaged, but also has better transparency; the glaze layer has a certain wear-resistant effect, delicate hand feeling and wide firing range; the embossing effect in the firing process is not easy to level; and has good diffuse reflection effect and visual effect of light fall.
Application example 2
The application example provides an application of the volcanic flow rock effect digital glaze ink provided in example 1, and the application includes the following steps:
ink-jet printing is carried out on the surface of the rock plate to obtain the volcanic flow rock effect digital glaze ink, and a finished product of a glaze surface with the volcanic flow rock effect is obtained after sintering;
the sintering comprises the following steps:
(i) raising the temperature to 400 ℃ at the heating rate of 8 ℃/min, and keeping the temperature for 40 min;
(ii) raising the temperature to 800 ℃ at the heating rate of 6 ℃/min, and keeping the temperature for 80 min;
(iii) raising the temperature to 1150 ℃ at the heating rate of 4 ℃/min, and keeping the temperature for 120 min;
(iv) naturally cooling to room temperature to finish sintering.
The glaze layer obtained by the application example can protect the pattern layer from being damaged and has better transparency; the glaze layer has a certain wear-resistant effect, delicate hand feeling and wide sintering range; the embossing effect in the firing process is not easy to level; and has good diffuse reflection effect and visual effect of light fall.
Application example 3
The application example provides an application of the volcanic flow rock effect digital glaze ink provided in example 1, and the application includes the following steps:
ink-jet printing is carried out on the surface of the rock plate to obtain the volcanic flow rock effect digital glaze ink, and a finished product of a glaze surface with the volcanic flow rock effect is obtained after sintering;
the sintering comprises the following steps:
(i) raising the temperature to 500 ℃ at a heating rate of 10 ℃/min, and keeping the temperature for 20 min;
(ii) raising the temperature to 900 ℃ at the heating rate of 8 ℃/min, and keeping the temperature for 60 min;
(iii) raising the temperature to 1250 ℃ at the heating rate of 6 ℃/min, and preserving the heat for 60 min;
(iv) and naturally cooling to room temperature to finish sintering.
The glaze layer obtained by the application example can protect the pattern layer from being damaged and has better transparency; the glaze layer has a certain wear-resistant effect, delicate hand feeling and wide firing range; the embossing effect in the firing process is not easy to level; and has good diffuse reflection effect and visual effect of light fall.
Application example 4
The application example provides application of the volcanic fluid rock effect digital glaze ink provided in example 2, and the application conditions are the same as those in application example 1.
The glaze layer obtained by the application example can protect the pattern layer from being damaged and has better transparency; the glaze layer has a certain wear-resistant effect, delicate hand feeling and wide sintering range; the embossing effect in the firing process is not easy to level; and has good diffuse reflection effect and visual effect of light fall.
Application example 5
The application example provides application of the volcanic flow rock effect digital glaze ink provided in example 3, and the application conditions are the same as those of application example 1.
The glaze layer obtained by the application example can protect the pattern layer from being damaged and has better transparency; the glaze layer has a certain wear-resistant effect, delicate hand feeling and wide firing range; the embossing effect in the firing process is not easy to level; and has good diffuse reflection effect and visual effect of light fall.
Application example 6
The application example provides an application of the volcanic flow rock effect digital glaze ink provided in example 4, and the application conditions are the same as those of application example 1.
The glaze layer obtained by the application example can protect the pattern layer from being damaged and has better transparency; the glaze layer has a certain wear-resistant effect, delicate hand feeling and wide firing range; the embossing effect in the firing process is not easy to level; and has good diffuse reflection effect and visual effect of light fall.
Application example 7
The application example provides application of the volcanic flow rock effect digital glaze ink provided in example 5, and the application conditions are the same as those of application example 1.
The glaze layer obtained by the application example can protect the pattern layer from being damaged and has better transparency; the glaze layer has a certain wear-resistant effect, delicate hand feeling and wide sintering range; the embossing effect in the firing process is not easy to level; and has good diffuse reflection effect and visual effect of light fall.
Application example 8
The application example provides application of the volcanic flow rock effect digital glaze ink provided in example 6, and the application conditions are the same as those of application example 1.
The glaze layer obtained by the application example can protect the pattern layer from being damaged and has better transparency; the glaze layer has a certain wear-resistant effect, delicate hand feeling and wide firing range; the embossing effect in the firing process is not easy to level; and has good diffuse reflection effect and visual effect of light fall.
Application example 9
The application example provides application of the volcanic fluid rock effect digital glaze ink provided in example 7, and the application conditions are the same as those in application example 1.
The glaze layer obtained by the application example can protect the pattern layer from being damaged and has better transparency; the glaze layer has a certain wear-resistant effect, delicate hand feeling and wide firing range; the embossing effect in the firing process is not easy to level; and has good diffuse reflection effect and visual effect of light fall.
Application example 10
The application example provides an application of the volcanic flow rock effect digital glaze ink provided in example 8, and the application conditions are the same as those of application example 1.
The glaze layer obtained by the application example can protect the pattern layer from being damaged and has better transparency; the glaze layer has a certain wear-resistant effect, delicate hand feeling and wide sintering range; the embossing effect in the firing process is not easy to level; and has good diffuse reflection effect and visual effect of light fall.
Application example 11
The application example provides application of the volcanic flow rock effect digital glaze ink provided in example 9, and the application conditions are the same as those of application example 1.
The glaze layer obtained by the application example can protect the pattern layer from being damaged and has better transparency; the glaze layer has a certain wear-resistant effect, delicate hand feeling and wide firing range; the embossing effect in the firing process is not easy to level; and has good diffuse reflection effect and visual effect of light fall.
Application example 12
The application example provides application of the volcanic fluid rock effect digital glaze ink provided in example 10, and the application conditions are the same as those in application example 1.
Application example 13
The application example provides application of the volcanic fluid rock effect digital glaze ink provided in example 11, and the application conditions are the same as those in application example 1.
Application example 14
The present application example provides an application of the volcanic flow rock effect digital glaze ink provided in example 12, and the conditions of the application are the same as those in application example 1.
Application example 15
The present application example provides an application of the volcanic flow rock effect digital glaze ink provided in example 13, and the conditions of the application are the same as those in application example 1.
Application example 16
The present application example provides an application of the volcanic flow rock effect digital glaze ink provided in example 14, and the conditions of the application are the same as those of application example 1.
Application example 17
The present application example provides an application of the volcanic flow rock effect digital glaze ink provided in example 15, and the conditions of the application are the same as those of application example 1.
Application example 18
The present application example provides an application of the volcanic flow rock effect digital glaze ink provided in example 16, and the conditions of the application are the same as those of application example 1.
Application example 19
The application example provides application of the volcanic fluid rock effect digital glaze ink provided in example 17, and the application conditions are the same as those in application example 1.
Comparative application example 1
The comparative application example provides application of the volcanic fluid rock effect digital glaze ink provided in example 1, and the application examples are the same as the application example 1 except that sintering is carried out at a heating rate of 9 ℃/min to 1200 ℃, heat preservation is carried out for 190min, and then natural cooling is carried out to room temperature.
Comparative application example 2
The present comparative application example provides an application of the digital glaze ink provided in comparative example 1, under the same conditions as in application example 1.
Comparative application example 3
The present comparative application example provides an application of the digital glaze ink provided in comparative example 2, under the same conditions as in application example 1.
Comparative application example 4
The present comparative application example provides an application of the digital glaze ink provided in comparative example 3, under the same conditions as in application example 1.
Comparative application example 5
The present comparative application example provides an application of the digital glaze ink provided in comparative example 4, under the same conditions as in application example 1.
The glaze layers obtained by the application examples 1 to 19 and the comparative application examples 1 to 5 were tested for wear resistance, transparency and glossiness. The glossiness is tested by using a glossiness meter, and the transmittance is tested by using a light transmittance meter; the abrasion resistance is measured according to the method specified in GB 11950-89. The results obtained are shown in table 1.
TABLE 1
In conclusion, the ratio of the free flowing rock glaze powder, the binder, the dispersant, the surfactant, the defoaming agent, the suspending agent and the organic solvent is adjusted, so that the volcanic free flowing rock effect digital glaze ink has a thinner glaze layer when being used for ink-jet printing, and has excellent wear resistance, high temperature resistance and transparency, a high-brightness volcanic free flowing rock effect and high visual impact force; the volcanic flow rock effect digital glaze ink and the flow rock glaze powder are adjusted to be used for ink-jet printing; the formed glaze layer can protect the pattern layer from being damaged and has better transparency; the glaze layer has a certain wear-resistant effect, delicate hand feeling and wide sintering range; the embossing effect in the firing process is not easy to level, and the glossiness is more than 80 degrees after firing.
The above-mentioned embodiments are intended to illustrate the objects, technical solutions and advantages of the present invention in further detail, and it should be understood that the above-mentioned embodiments are only exemplary embodiments of the present invention, and are not intended to limit the present invention, and any modifications, equivalents, improvements and the like made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (13)
1. The volcanic flow rock effect digital glaze ink is characterized by comprising the following raw materials in parts by weight:
30-45 parts of fluid rock glaze powder
4-8 parts of binder
25-45 parts of dispersant
2-4 parts of surfactant
0.2 to 0.5 portion of antifoaming agent
0.05 to 0.12 portion of suspending agent
30-40 parts of an organic solvent;
the composition of the flowing rock glaze powder comprises the following components in percentage by mass:
Al 2 O 3 13.5-16wt%
Fe 2 O 3 0.01-0.1wt%
ZnO 1.5-4wt%
CaO 8-12wt%
MgO 2-6wt%
K 2 O 0.5-2wt%
Na 2 O 2-4wt%
BaO 1-4wt%
TiO 2 0.01-0.1wt%
the balance being SiO 2 ；
The surfactant comprises any one or the combination of at least two of octadecyl dihydroxyethyl amine oxide, tetradecyl dihydroxyethyl amine oxide or octadecyl amidopropyl amine oxide;
the defoamer comprises polydimethylsiloxane;
the suspending agent comprises bentonite and/or attapulgite.
2. The volcanic fluid rock effect digital glaze ink as claimed in claim 1, wherein the volcanic fluid rock effect digital glaze ink comprises the following raw materials in parts by weight:
35-40 parts of flow rock glaze powder
5-7 parts of binder
30-40 parts of dispersant
3-4 parts of surfactant
0.2 to 0.4 portion of defoaming agent
0.05 to 0.08 portion of suspending agent
32-36 parts of an organic solvent.
3. The volcanic flow rock effect digital glaze ink as claimed in claim 1, wherein the composition of the flow rock glaze powder comprises, in mass percent:
Al 2 O 3 14-15.5wt%
Fe 2 O 3 0.01-0.1wt%
ZnO 2-3wt%
CaO 9-11wt%
MgO 3-6wt%
K 2 O 1-2wt%
Na 2 O 2.5-4wt%
BaO 2-3wt%
TiO 2 0.01-0.1wt%
the balance being SiO 2 。
4. The volcanic flow rock effect digital glaze ink as claimed in claim 1, wherein the loss on ignition of the flow rock glaze powder is 1-10 wt%.
5. The volcanic flow rock effect digital glaze ink as claimed in claim 4, wherein the loss on ignition of the flow rock glaze powder is 5-10 wt%.
6. The volcanic flow rock effect digital glaze ink as claimed in claim 1, wherein the binder comprises carboxymethyl cellulose and/or acrylic resin.
7. The volcanic flow rock effect digital glaze ink as claimed in claim 1, wherein the dispersant comprises any one of polyacrylate dispersant, polyurethane dispersant or aromatic hydrocarbon dispersant or a combination of at least two thereof.
8. The volcanic flow rock effect digital glaze ink as claimed in claim 1, wherein the organic solvent comprises any one of hydrocarbon organic solvent, alcohol organic solvent or ester organic solvent or a combination of at least two of the hydrocarbon organic solvent, the alcohol organic solvent or the ester organic solvent.
9. A method for preparing the volcanic flow rock effect digital glaze ink as set forth in any one of claims 1 to 8, wherein the method comprises the following steps:
(1) mixing the fluid rock glaze powder with a binder accounting for 30-50wt% of the total weight of the binder according to the formula amount, and continuously mixing a dispersant to obtain a mixture;
(2) grinding the mixture obtained in the step (1) to an average particle size of 10-30 μm;
(3) and continuously adding a surfactant, a defoaming agent, a suspending agent, an organic solvent and the balance of a binder according to the formula amount, and continuously grinding until the mixture is uniformly dispersed to obtain the volcanic fluid rock effect digital glaze ink.
10. Use of a volcanic flow rock effect digital glaze ink as set forth in any of claims 1 to 8, wherein the use comprises the steps of: and ink-jet printing the volcanic flow rock effect digital glaze ink on the surface of the substrate, and sintering to obtain a finished product of the glaze surface with the volcanic flow rock effect.
11. The use according to claim 10, wherein the substrate comprises a rock plate.
12. Use according to claim 10, wherein the sintering comprises the steps of:
(i) raising the temperature to 400-500 ℃ at the temperature raising rate of 8-10 ℃/min, and preserving the temperature for 20-40 min;
(ii) raising the temperature to 800-900 ℃ at the temperature rise rate of 6-8 ℃/min, and preserving the heat for 60-80 min;
(iii) raising the temperature to 1150-1250 ℃ at the temperature raising rate of 4-6 ℃/min, and preserving the temperature for 60-120 min;
(iv) and naturally cooling to room temperature to finish sintering.
13. The application according to claim 10, characterized in that it comprises the following steps:
ink-jet printing is carried out on the surface of the rock plate to obtain the volcanic rock effect digital glaze ink, and a finished product with a volcanic rock effect glaze surface is obtained after sintering;
the sintering comprises the following steps:
(i) raising the temperature to 400-500 ℃ at the temperature raising rate of 8-10 ℃/min, and preserving the temperature for 20-40 min;
(ii) raising the temperature to 800-900 ℃ at the temperature rise rate of 6-8 ℃/min, and preserving the heat for 60-80 min;
(iii) raising the temperature to 1150-1250 ℃ at the temperature raising rate of 4-6 ℃/min, and preserving the temperature for 60-120 min;
(iv) naturally cooling to room temperature to finish sintering.
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| CN113735441A (en) * | 2021-08-24 | 2021-12-03 | 广州铁路职业技术学院（广州铁路机械学校） | Digital glaze for ceramic large plate or rock plate and preparation method thereof |
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