CN112973194A - Device and method for separating gas from liquid under pressure - Google Patents
Device and method for separating gas from liquid under pressure Download PDFInfo
- Publication number
- CN112973194A CN112973194A CN201911300513.3A CN201911300513A CN112973194A CN 112973194 A CN112973194 A CN 112973194A CN 201911300513 A CN201911300513 A CN 201911300513A CN 112973194 A CN112973194 A CN 112973194A
- Authority
- CN
- China
- Prior art keywords
- gas
- stripping
- tube
- liquid
- under pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 80
- 238000000034 method Methods 0.000 title claims abstract description 23
- 238000005070 sampling Methods 0.000 claims abstract description 37
- 238000004458 analytical method Methods 0.000 claims abstract description 3
- 239000007789 gas Substances 0.000 claims description 117
- 239000012159 carrier gas Substances 0.000 claims description 27
- 238000001704 evaporation Methods 0.000 claims description 20
- 230000008020 evaporation Effects 0.000 claims description 20
- 230000006837 decompression Effects 0.000 claims description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 6
- -1 meanwhile Substances 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 230000008569 process Effects 0.000 abstract description 9
- 238000000926 separation method Methods 0.000 abstract description 5
- 238000013461 design Methods 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 description 5
- 238000007789 sealing Methods 0.000 description 4
- 238000003795 desorption Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000011002 quantification Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
- B01D19/0005—Degasification of liquids with one or more auxiliary substances
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/06—Flash distillation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/10—Vacuum distillation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/34—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping with one or more auxiliary substances
- B01D3/38—Steam distillation
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/28—Preparing specimens for investigation including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q
- G01N1/34—Purifying; Cleaning
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/28—Preparing specimens for investigation including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q
- G01N1/40—Concentrating samples
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/28—Preparing specimens for investigation including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q
- G01N1/40—Concentrating samples
- G01N1/4022—Concentrating samples by thermal techniques; Phase changes
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/28—Preparing specimens for investigation including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q
- G01N1/40—Concentrating samples
- G01N1/4022—Concentrating samples by thermal techniques; Phase changes
- G01N2001/4033—Concentrating samples by thermal techniques; Phase changes sample concentrated on a cold spot, e.g. condensation or distillation
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Analytical Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Engineering & Computer Science (AREA)
- Biomedical Technology (AREA)
- Molecular Biology (AREA)
- Sampling And Sample Adjustment (AREA)
Abstract
The invention discloses a device and a method for separating gas from liquid under pressure, and belongs to the field of gas-liquid separation. The device includes: the injector, the sampler and the stripper are communicated in sequence through connecting pipelines; the sampler includes: the quantitative sampling tube, the inlet valve and the outlet valve are respectively arranged at two ends of the quantitative sampling tube; the stripper comprises: the steam stripping device comprises a steam stripping pipe communicated with a connecting pipeline, an air outlet pipe communicated with the upper part of the steam stripping pipe, an air inlet pipe communicated with the bottom of the steam stripping pipe, and a sieve plate arranged at the lower part of the inner cavity of the steam stripping pipe; wherein, the syringe is filled with the analysis liquid, and the quantitative sampling tube is filled with the liquid with pressure. The gas enriched by the device not only contains gas components flashed out by pressure reduction, but also comprises gas components remained in the liquid after pressure reduction, so that the content of the gas components in the liquid under pressure can be accurately quantified, and the process design and equipment model selection during the gas component treatment can meet the actual requirements.
Description
Technical Field
The invention relates to the field of gas-liquid separation, in particular to a device and a method for separating gas from liquid under pressure.
Background
Industrial processes often involve pressurized liquids, which typically have dissolved gaseous components such as carbon dioxide, hydrogen sulfide, oxygen, ammonia, and volatile organics. After gas-liquid separation of the pressurized liquid, a large amount of gas components are produced. There are currently two main ways of dealing with such gaseous components: the waste gas is directly discharged after being treated in modes of adsorption or catalytic degradation and the like, and the waste gas is recycled to avoid pollution. However, both of the above methods require accurate quantification of the content of the gas component in the pressurized liquid so that the process design and equipment selection for the treatment of the gas component can meet the actual requirements.
The dissolved gas components in the liquid under pressure generally comprise: however, conventionally, when gas-liquid separation is performed on a liquid under pressure, only the amount of gas remaining in the liquid under pressure can be obtained, for example, in a packed bed, a column, a degasser, or the like, and the gas flashed under pressure inevitably loses.
In the process of implementing the invention, the inventor finds that at least the following problems exist in the prior art:
the prior art can not quantify partial gas flashed out under reduced pressure, so that the content of dissolved gas components in the liquid under reduced pressure can not be accurately quantified, and effective support can not be provided for the subsequent treatment process of the gas components.
Disclosure of Invention
In view of the above, the present invention provides an apparatus and a method for separating gas from a pressurized liquid, which can solve the above technical problems.
Specifically, the method comprises the following technical scheme:
in one aspect, there is provided an apparatus for separating gas from a liquid under pressure, the apparatus comprising: the injector, the sampler and the stripper are communicated in sequence through connecting pipelines;
the sampler includes: the quantitative sampling tube, the inlet valve and the outlet valve are respectively arranged at two ends of the quantitative sampling tube;
the stripper includes: the steam stripping device comprises a steam stripping pipe communicated with the connecting pipeline, a gas outlet pipe communicated with the upper part of the steam stripping pipe, a gas inlet pipe communicated with the bottom of the steam stripping pipe, and a sieve plate arranged at the lower part of the inner cavity of the steam stripping pipe;
wherein, the syringe is filled with the analysis liquid, and the quantitative sampling tube is filled with the pressure liquid.
In one possible implementation, the apparatus further includes: a first support for supporting the sampler.
In a possible implementation manner, the first support is an iron stand with two clamping pieces, and the two clamping pieces are used for clamping two ends of the quantitative sampling tube.
In one possible implementation, the apparatus further includes: a second support for supporting the stripper.
In one possible implementation, the second support is a support platform having a storage slot for accommodating the stripping tube and the air inlet tube.
In one possible implementation, the sampler is passivated by the liquid under pressure before use.
In one possible implementation, the sampler passivated by the liquid under pressure is also passivated by the desorption liquid before use.
In a possible realization, the aperture of the sieve holes on the sieve plate is 0.5 mm-1 mm.
In one possible implementation, the distance between the gas outlet pipe and the bottom of the stripping pipe is 25-35 cm;
the distance between the sieve plate and the bottom of the stripping pipe is 3-5 cm.
In another aspect, there is provided a method of separating gas from a liquid under pressure, the method employing any one of the apparatus described above, comprising:
the inlet valve is kept in a closed state, the outlet valve is opened, so that part of pressurized liquid in the quantitative sampling tube enters the stripping tube through the connecting pipeline for decompression flash evaporation to obtain flash evaporation gas, meanwhile, carrier gas is introduced through the gas inlet tube, the flash evaporation gas is taken out of the stripping tube by the carrier gas, and the flash evaporation gas is discharged and enriched through the gas outlet tube;
keeping the carrier gas continuously introduced, opening an inlet valve, pushing an analytic solution into the quantitative sampling tube through an injector, allowing the analytic solution and the rest part of liquid in the quantitative sampling tube to enter the stripping tube through the connecting pipeline for stripping treatment to obtain a stripping gas, and allowing the stripping gas to be carried out of the stripping tube by the carrier gas, and discharging and enriching the stripping gas by the gas outlet tube.
The technical scheme provided by the embodiment of the invention has the beneficial effects that at least:
the device provided by the embodiment of the invention can be used for separating gas from pressurized liquid, when the device is applied, the inlet valve is kept in a closed state, the outlet valve is opened, part of pressurized liquid in the quantitative sampling tube enters the stripping tube through the connecting pipeline for decompression flash evaporation to obtain flash evaporation gas, meanwhile, carrier gas is introduced through the gas inlet tube, the flash evaporation gas is taken out of the stripping tube by the carrier gas, and the flash evaporation gas is discharged and enriched through the gas outlet tube. Keeping the carrier gas continuously introduced, opening the inlet valve, pushing the analytic solution into the quantitative sampling tube through the injector, allowing the analytic solution and the rest part of the liquid in the quantitative sampling tube to enter the stripping tube through the connecting pipeline for stripping treatment to obtain stripping gas, carrying the stripping gas out of the stripping tube through the carrier gas, and discharging and enriching the stripping gas through the gas outlet tube. It can be seen that, with the apparatus provided by the embodiment of the present invention, the enriched gas not only contains the gas component flashed off under reduced pressure, but also contains the gas component remaining in the liquid after reduced pressure. Since the composition of the carrier gas is determined, the content of the above gas components separated from the enriched gas can be easily determined, so that accurate quantification of the content of the gas components in the pressurized liquid can be realized, and the process design and equipment selection for processing the gas components can meet the actual requirements.
Drawings
In order to more clearly illustrate the technical solutions in the embodiments of the present invention, the drawings needed to be used in the description of the embodiments will be briefly introduced below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and it is obvious for those skilled in the art to obtain other drawings based on these drawings without creative efforts.
Fig. 1 is a schematic structural diagram of an apparatus for separating gas from a liquid under pressure according to an embodiment of the present invention.
The reference numerals denote:
1-injector, 2-sampler, 3-stripper, 4-first support, 5-second support,
201-a quantitative sampling tube, 202-an inlet valve, 203-an outlet valve,
301-stripping tube, 302-outlet tube, 303-inlet tube and 304-sieve plate.
Detailed Description
In order to make the technical solutions and advantages of the present invention clearer, the following will describe embodiments of the present invention in further detail with reference to the accompanying drawings.
In one aspect, an embodiment of the present invention provides an apparatus for separating gas from a liquid under pressure, as shown in fig. 1, the apparatus comprising: an injector 1, a sampler 2 and a stripper 3 which are communicated in sequence through connecting pipelines.
Wherein, sampler 2 includes: a quantitative sampling tube 201, an inlet valve 202 and an outlet valve 203 respectively arranged at two ends of the quantitative sampling tube 201.
The stripper 3 comprises: a stripping pipe 301 communicated with the connecting pipeline, an air outlet pipe 302 communicated with the upper part of the stripping pipe 301, an air inlet pipe 303 communicated with the bottom of the stripping pipe 301, and a sieve plate 304 arranged at the lower part of the inner cavity of the stripping pipe 301.
The syringe 1 contains a solution, and the quantitative sampling tube 201 contains a pressurized liquid.
The device provided by the embodiment of the invention can be used for separating gas from liquid under pressure, when the device is applied, the inlet valve 202 is kept in a closed state, the outlet valve 203 is opened, and part of liquid under pressure in the quantitative sampling tube 201 enters the stripping tube 301 through the connecting pipeline for decompression flash evaporation to obtain flash evaporation gas, meanwhile, carrier gas is introduced through the gas inlet tube 303, and the flash evaporation gas is taken out of the stripping tube 301 by the carrier gas and is discharged and enriched through the gas outlet tube 302. Keeping the carrier gas continuously introduced, opening the inlet valve 202, pushing the analytic solution into the quantitative sampling tube 201 through the injector 1, allowing the analytic solution and the rest part of the liquid in the quantitative sampling tube 201 to enter the stripping tube 301 through the connecting pipeline for stripping treatment to obtain a stripping gas, carrying the stripping gas out of the stripping tube 301 through the carrier gas, and discharging and enriching the stripping gas through the gas outlet pipe 302. It can be seen that the enriched gas contains not only the gas component flashed off under reduced pressure but also the gas component remaining in the liquid after reduced pressure. Since the composition of the carrier gas is determined, the content of the above gas components separated from the enriched gas can be easily determined, so that accurate quantification of the content of the gas components in the pressurized liquid can be realized, and the process design and equipment selection for processing the gas components can meet the actual requirements.
It can be understood that the stripping treatment of the flash evaporation gas and the gas remained in the decompressed liquid by the carrier gas not only improves the stripping efficiency, but also can fully enrich the dissolved gas components in the pressurized liquid and improve the measurement accuracy.
In the case of the sampler 2, the volume of the quantitative sampling tube 201 is determined, that is, the content of the pressurized liquid in the quantitative sampling tube 201 is determined, so that the content of the gas component in the pressurized liquid can be easily determined when the content of all the gas components contained therein is obtained.
In the embodiment of the present invention, the quantitative sampling tube 201 may be a metal hose, and an inlet valve 202 and an outlet valve 203 are respectively installed at two ends of the metal hose. In the non-operating state, both the inlet valve 202 and the outlet valve 203 are in a closed state, i.e., a normally closed state.
In order to avoid errors in the determination of the gas composition content by the material of the sampler 2, e.g. gas penetrating into the inner wall of the sampler 2, etc., the sampler 2 is passivated with an pressurised liquid before use, e.g. the sampler 2 may be allowed to store the pressurised liquid for several hours, e.g. 10-24 hours, e.g. 12 hours, etc., before use. Further, prior to use, the liquid-passivated probe 2 is also passivated with a resolving liquid, e.g. the resolving liquid is stored for several hours, e.g. 10-24 hours, e.g. 12 hours, etc. with the liquid-passivated probe 2.
After the passivation process, a quantitative sampling tube 201 is used to store a quantitative amount of pressurized liquid for separating gas therefrom.
In view of the convenience of operation, as shown in fig. 1, the apparatus provided by the embodiment of the present invention further includes: a first support 4, wherein the first support 4 is adapted to support the sampler 2.
Illustratively, the first holder 4 is an iron stand having two holding members for holding both ends of the quantitative sampling tube 201. It is understood that the hob head further comprises: the base to and the vertical stand that sets up on the base, wherein, two holders set up on the stand at a certain distance apart, the centre gripping ration sampling tube 201 respectively, makes it be in the position that is convenient for the separation operation.
Further, as shown in fig. 1, the apparatus provided in the embodiment of the present invention further includes: a second support 5, the second support 5 being for supporting the stripper 3 to further improve the convenience of operation.
As an example, the second support 5 is a support platform with a storage compartment for receiving the stripping tube 301 and the inlet tube 303.
It is understood that the structure of the storage tank is determined according to the structure and arrangement relationship of the stripping pipe 301 and the air inlet pipe 303, so as to ensure that the stripping pipe 301 is in a vertical state and the air inlet pipe 303 is kept stable.
The inlet pipe 303 may include an upper horizontal section, a main vertical section, a lower horizontal section, and a mouthpiece vertical section connected in series. Wherein the interface vertical section is in communication with the bottom of the stripping tube 301 to facilitate the carrier gas to smoothly enter the stripping tube 301 without backflow.
In an embodiment of the invention, the sieve plate 304 is used to generate bubbles of gas as the carrier gas passes through, which contact the liquid under pressure to carry the gas out of it. The sieve plate 304 has a plurality of sieve holes, for example, 20-40 sieve holes, for example, 30 sieve holes, wherein the pore diameter of the sieve holes is 0.5 mm-1 mm, so as to achieve a good gas carrying effect.
In order to provide sufficient space for the reduced pressure flash and stripping process, in the present example, outlet pipe 302 is spaced 30 cm from the bottom of stripping pipe 301. Meanwhile, in order to obtain a better gas carrying effect, the distance between the sieve plate 304 and the bottom of the stripping pipe 301 is 3.5 cm.
In the embodiment of the invention, the inlet valve 202, the quantitative sampling tube 201 and the outlet valve 203 all require the pressure-bearing capacity to be not less than 15 Mpa. The connection line may be a hose, for example of teflon, which is inert and of high strength, ensuring an accurate measurement of the gas content. The stripping tube 301, the inlet tube 303 and the sieve plate 304 may all be of quartz. The outlet pipe 302 may be vertically connected to and communicated with the upper side wall of the stripping pipe 301. Furthermore, the top opening of the stripping tube 301 is provided with a sealing cap through which the end of the connecting line is sealed into the stripping tube 301 to ensure that the gas is collected in its entirety. For example, the sealing cap may be screwed with the stripping tube 301, and a sealing member may be disposed therebetween, or the sealing cap may be a rubber plug inserted into the top opening of the stripping tube 301.
In another aspect, an embodiment of the present invention further provides a method for separating gas from a pressurized liquid, where the method employs any one of the apparatuses described above, including:
and (3) keeping the inlet valve in a closed state, opening the outlet valve, enabling part of pressurized liquid in the quantitative sampling tube to enter the stripping tube through the connecting pipeline for decompression flash evaporation to obtain flash evaporation gas, meanwhile, introducing carrier gas through the gas inlet tube, utilizing the carrier gas to bring the flash evaporation gas out of the stripping tube, and discharging and enriching the flash evaporation gas through the gas outlet tube.
Keeping the carrier gas continuously introduced, opening the inlet valve, pushing the analytic solution into the quantitative sampling tube through the injector, allowing the analytic solution and the rest part of the liquid in the quantitative sampling tube to enter the stripping tube through the connecting pipeline for stripping treatment to obtain stripping gas, carrying the stripping gas out of the stripping tube through the carrier gas, and discharging and enriching the stripping gas through the gas outlet tube.
Wherein, the enriched gas component and carrier gas mixture can determine the content of the target gas component by chemical absorption method or chromatography.
The desorption solution is used to completely strip out the gas components in the pressurized liquid, so that the composition of the desorption solution may be determined according to the kind of the gas components dissolved in the pressurized liquid, and the embodiment of the present invention is not particularly limited thereto. The carrier gas used in the embodiments of the present invention may be nitrogen.
In summary, the apparatus and method provided by the embodiments of the present invention have at least the following advantages:
(1) the gas component flashed out after the decompression of the pressurized liquid and the gas component in the residual liquid after the decompression are respectively enriched, so that the loss of part of gas flashed out after the decompression is avoided, and the accuracy of the subsequent gas component in the quantitative process is improved.
(2) The sampler is passivated in sequence before use, so that possible interaction between the sampler and gas components is avoided or reduced to the maximum extent, and the stripping efficiency is improved.
(3) The steam stripper has reasonable structural layout and simple and convenient operation, and is suitable for high-efficiency steam stripping of pressurized liquid.
(4) And after the pressure-bearing liquid is decompressed, part of gas flashed out is enriched after stripping, so that the stripping efficiency of the pressure-bearing liquid is improved, dissolved gas components in the pressure-bearing liquid can be completely enriched, and the measurement accuracy is improved.
The above description is only for facilitating the understanding of the technical solutions of the present invention by those skilled in the art, and is not intended to limit the present invention. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (10)
1. An apparatus for separating gas from a liquid under pressure, the apparatus comprising: the injector, the sampler and the stripper are communicated in sequence through connecting pipelines;
the sampler includes: the quantitative sampling tube, the inlet valve and the outlet valve are respectively arranged at two ends of the quantitative sampling tube;
the stripper includes: the steam stripping device comprises a steam stripping pipe communicated with the connecting pipeline, a gas outlet pipe communicated with the upper part of the steam stripping pipe, a gas inlet pipe communicated with the bottom of the steam stripping pipe, and a sieve plate arranged at the lower part of the inner cavity of the steam stripping pipe;
wherein, the syringe is filled with the analysis liquid, and the quantitative sampling tube is filled with the pressure liquid.
2. An apparatus for separating gas from a liquid under pressure according to claim 1, further comprising: a first support for supporting the sampler.
3. An apparatus for separating a gas from a liquid under pressure according to claim 2, wherein the first support is an iron stand having two clamping members for clamping both ends of the quantitative sampling tube.
4. An apparatus for separating gas from a liquid under pressure according to claim 1, further comprising: a second support for supporting the stripper.
5. An apparatus for separating gas from a liquid under pressure according to claim 5, wherein the second support is a support platform having a storage tank for receiving the stripping tube and the inlet tube.
6. An apparatus for separating a gas from a liquid under pressure according to claim 1, wherein the sampler is passivated by the liquid under pressure prior to use.
7. An apparatus for separating a gas from a liquid under pressure according to claim 6, wherein the sampler passivated by the liquid under pressure is also passivated by the stripping liquid prior to use.
8. An apparatus for separating gas from a liquid under pressure according to claim 1, wherein the openings in the screen deck have a diameter of 0.5 mm to 1 mm.
9. An apparatus for separating a gas from a liquid under pressure according to claim 1, wherein the outlet duct is spaced from the bottom of the stripping duct by a distance of 25 cm to 35 cm;
the distance between the sieve plate and the bottom of the stripping pipe is 3-5 cm.
10. A method for separating gas from a liquid under pressure, using an apparatus according to any one of claims 1 to 9, comprising:
the inlet valve is kept in a closed state, the outlet valve is opened, so that part of pressurized liquid in the quantitative sampling tube enters the stripping tube through the connecting pipeline for decompression flash evaporation to obtain flash evaporation gas, meanwhile, carrier gas is introduced through the gas inlet tube, the flash evaporation gas is taken out of the stripping tube by the carrier gas, and the flash evaporation gas is discharged and enriched through the gas outlet tube;
keeping the carrier gas continuously introduced, opening an inlet valve, pushing an analytic solution into the quantitative sampling tube through an injector, allowing the analytic solution and the rest part of liquid in the quantitative sampling tube to enter the stripping tube through the connecting pipeline for stripping treatment to obtain a stripping gas, and allowing the stripping gas to be carried out of the stripping tube by the carrier gas, and discharging and enriching the stripping gas by the gas outlet tube.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201911300513.3A CN112973194A (en) | 2019-12-17 | 2019-12-17 | Device and method for separating gas from liquid under pressure |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201911300513.3A CN112973194A (en) | 2019-12-17 | 2019-12-17 | Device and method for separating gas from liquid under pressure |
Publications (1)
Publication Number | Publication Date |
---|---|
CN112973194A true CN112973194A (en) | 2021-06-18 |
Family
ID=76342063
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201911300513.3A Pending CN112973194A (en) | 2019-12-17 | 2019-12-17 | Device and method for separating gas from liquid under pressure |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN112973194A (en) |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6193893B1 (en) * | 1998-03-20 | 2001-02-27 | Gdt Corporation | Stripping of contaminants from water |
CN102636368A (en) * | 2012-04-18 | 2012-08-15 | 华东理工大学 | Multiphase online sampling device and multiphase online sampling method suitable for high-temperature hydrocarbon gas (smoke) |
CN208990274U (en) * | 2018-08-22 | 2019-06-18 | 李明 | Sulfur-bearing TEG rich solution flash distillation stripping separator |
-
2019
- 2019-12-17 CN CN201911300513.3A patent/CN112973194A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6193893B1 (en) * | 1998-03-20 | 2001-02-27 | Gdt Corporation | Stripping of contaminants from water |
CN102636368A (en) * | 2012-04-18 | 2012-08-15 | 华东理工大学 | Multiphase online sampling device and multiphase online sampling method suitable for high-temperature hydrocarbon gas (smoke) |
CN208990274U (en) * | 2018-08-22 | 2019-06-18 | 李明 | Sulfur-bearing TEG rich solution flash distillation stripping separator |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6426188B2 (en) | Gas sampling device and filling station provided with such a device | |
US10705059B2 (en) | Gas sample injection device for gas chromatographic analysis, and method thereof | |
CN101893613B (en) | Purge and trap device | |
BE1026550B1 (en) | TEST DEVICE FOR TWO-PHASE GAS-LIQUID SATURATED CHARCOAL SAMPLES AND SATURATION TEST METHOD | |
CN105092350A (en) | Pretreatment apparatus and method for determination of dissolved helium and neon in water | |
RU2009141480A (en) | METHOD, DEVICE AND SYSTEM FOR REMOVING ACID GAS | |
CN112973194A (en) | Device and method for separating gas from liquid under pressure | |
CN109323909B (en) | Gas automatic separation system for inertness in small-gas-volume environment sample | |
CN110412160A (en) | The gas chromatography measuring method of ethyl alcohol in surrounding air | |
CN203598534U (en) | Solid-phase extraction device | |
CN102967678B (en) | Offline pretreatment device and method for simply measuring oxygen stable isotope ratio in water | |
CN108802225B (en) | Method for detecting benzene series in workplace | |
CN211987210U (en) | High-flux cross-contamination-prevention solid phase extraction device | |
CN205527751U (en) | High -purity nitrogen gas purification device | |
CN210751971U (en) | Device suitable for absorbing replacement gas of chloroethylene converter | |
CN207980505U (en) | A kind of solid-phase extraction device | |
JP3609550B2 (en) | Analysis method of disulfide | |
JPH107115A (en) | Analysis method for head space gas of negative pressure can | |
CN212722235U (en) | Sampling device | |
CN109276972A (en) | The method of separating-purifying hydrogen from refinery gas holder dry gas | |
CN211955530U (en) | Oil discharge and sample introduction device for insulating oil micro-water test | |
CN204330424U (en) | The sulfur hexafluoride sampler of low compatibility and low absorbability | |
CN201464438U (en) | Blowing trapping device | |
RU2400422C1 (en) | Method for separate determination of content of free hydrogen sulphide and hydropolysulphides in liquid sulphur | |
CN210935036U (en) | Distillation system |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20210618 |