CN112961705A - Gasification furnace for directly preparing methane/methanol by coal gasification - Google Patents

Gasification furnace for directly preparing methane/methanol by coal gasification Download PDF

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Publication number
CN112961705A
CN112961705A CN202110156370.4A CN202110156370A CN112961705A CN 112961705 A CN112961705 A CN 112961705A CN 202110156370 A CN202110156370 A CN 202110156370A CN 112961705 A CN112961705 A CN 112961705A
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CN
China
Prior art keywords
gasification
methanol
gasification furnace
chilling
water tank
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Pending
Application number
CN202110156370.4A
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Chinese (zh)
Inventor
王鹏杰
罗丽珍
许世森
任永强
李小宇
陶继业
刘刚
刘沅
陈智
樊强
张欢
王瑞超
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Huaneng Clean Energy Research Institute
Huaneng Group Technology Innovation Center Co Ltd
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Huaneng Clean Energy Research Institute
Huaneng Group Technology Innovation Center Co Ltd
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Priority to CN202110156370.4A priority Critical patent/CN112961705A/en
Publication of CN112961705A publication Critical patent/CN112961705A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/48Apparatus; Plants
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/152Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the reactor used
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/74Construction of shells or jackets
    • C10J3/76Water jackets; Steam boiler-jackets
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/82Gas withdrawal means
    • C10J3/84Gas withdrawal means with means for removing dust or tar from the gas
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/02Dust removal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/08Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • C10K1/101Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids with water only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/08Production of synthetic natural gas
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/093Coal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0959Oxygen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1603Integration of gasification processes with another plant or parts within the plant with gas treatment
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1603Integration of gasification processes with another plant or parts within the plant with gas treatment
    • C10J2300/1615Stripping
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656Conversion of synthesis gas to chemicals
    • C10J2300/1662Conversion of synthesis gas to chemicals to methane (SNG)
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656Conversion of synthesis gas to chemicals
    • C10J2300/1665Conversion of synthesis gas to chemicals to alcohols, e.g. methanol or ethanol
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency

Abstract

The invention discloses a gasification furnace for directly preparing methane/methanol by coal gasification, which comprises a gasification reaction chamber burner, a synthesis gas conduit, a gasification furnace shell, a catalyst layer, a chilling water tank, a gasification reaction chamber and a slag bath, wherein the catalyst layer, the chilling water tank, the gasification reaction chamber and the slag bath are arranged in the gasification furnace shell and are sequentially distributed from top to bottom, one end of the synthesis gas conduit is communicated with an outlet at the top of the gasification reaction chamber, the other end of the synthesis gas conduit is inserted into the chilling water tank, a product gas outlet is formed in the top of the gasification furnace shell, the gasification reaction chamber burner is inserted into the gasification reaction chamber, the inner wall of the gasification reaction chamber is a water-cooled wall, the gasification furnace can prepare methane/methanol, an external heat source is.

Description

Gasification furnace for directly preparing methane/methanol by coal gasification
Technical Field
The invention belongs to the field of coal gasification, and relates to a gasification furnace for directly preparing methane/methanol by coal gasification.
Background
The coal gasification technology is a tap core technology in the field of coal chemical industry. In the coal chemical industry, synthesis gas generated by a gasification furnace needs to be cooled and ash-removed and then output to a subsequent synthesis unit for producing methane or methanol generally, in the traditional production process, the synthesis gas is cooled to a lower temperature (about 200 ℃), the synthesis gas needs to be reheated, and a catalyst is reused for synthesizing methane or methanol, so that other energy sources are consumed, and the energy utilization efficiency is low.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide a gasification furnace for directly preparing methane/methanol by coal gasification, which can prepare methane/methanol, does not need an external heat source for heating and has high energy utilization efficiency.
In order to achieve the purpose, the gasification furnace for directly preparing methane/methanol by coal gasification comprises a gasification reaction chamber burner, a synthesis gas conduit, a gasification furnace shell, a catalyst layer, a chilling water tank, a gasification reaction chamber and a slag pool, wherein the catalyst layer, the chilling water tank, the gasification reaction chamber and the slag pool are arranged in the gasification furnace shell and are sequentially distributed from top to bottom, one end of the synthesis gas conduit is communicated with an outlet at the top of the gasification reaction chamber, the other end of the synthesis gas conduit is inserted into the chilling water tank, a product gas outlet is formed in the top of the gasification furnace shell, the gasification reaction chamber burner is inserted into the gasification reaction chamber, and the inner wall of the gasification reaction chamber.
A demister is arranged above the catalyst layer.
The water-cooled wall is provided with a water-cooled wall circulating water inlet and a water-cooled wall circulating water outlet.
The chilling water tank is provided with a chilling water tank water inlet and a chilling water tank water outlet.
The slag bath is provided with a slag bath circulating water inlet and a slag bath circulating water outlet.
The bottom of the slag pool is provided with a slag discharge port.
A slag discharging valve is arranged at the slag discharging opening.
The upper end of the synthetic gas conduit passes through the chilling water tank and then is bent and inserted into the chilling water tank.
The upper end of the synthesis gas conduit is of an inverted U-shaped structure.
And adjusting the type of the catalyst layer according to the type of the required product gas so as to output the required product gas.
The invention has the following beneficial effects:
when the gasification furnace for directly preparing methane/methanol by coal gasification is specifically operated, the product gas is generated by the heat of the synthesis gas through the catalyst layer, so that the synthesis gas is prevented from being heated by an external heat source.
Drawings
The accompanying drawings, which are incorporated in and constitute a part of this specification, are included to provide a further understanding of the invention, and are incorporated in and constitute a part of this specification, illustrate exemplary embodiments of the invention and together with the description serve to explain the invention and not to limit the invention. In the drawings:
FIG. 1 is a schematic structural view of the present invention;
wherein, 1 is a gasification furnace shell, 2 is a gasification reaction chamber, 2.1 is a gasification reaction chamber burner, 3 is a water-cooled wall, 3.1 is a water-cooled wall circulating water inlet, 3.2 is a water-cooled wall circulating water outlet, 4 is a synthesis gas conduit, 5 is a chilling water tank, 5.1 is a chilling water tank water inlet, 5.2 is a chilling water tank water outlet, 6 is a catalyst layer, 7 is a demister, 8 is a product gas outlet, 9 is a slag pool, 9.1 is a slag pool circulating water inlet, and 9.2 is a slag pool circulating water outlet.
Detailed Description
The present invention will be described in detail below with reference to the embodiments with reference to the attached drawings. It should be noted that the embodiments and features of the embodiments in the present application may be combined with each other without conflict.
The following detailed description is exemplary in nature and is intended to provide further details of the invention. Unless otherwise defined, all technical terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this application belongs. The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of exemplary embodiments according to the invention.
Referring to fig. 1, the gasification furnace for directly producing methane/methanol by coal gasification according to the present invention includes a gasification reaction chamber burner 2.1, a syngas conduit 4, a gasification furnace housing 1, and a catalyst layer 6, a quench water tank 5, a gasification reaction chamber 2, and a slag bath 9, which are disposed in the gasification furnace housing 1 and sequentially distributed from top to bottom, wherein one end of the syngas conduit 4 is communicated with a top outlet of the gasification reaction chamber 2, the other end of the syngas conduit 4 is inserted into the quench water tank 5, a product gas outlet 8 is disposed at the top of the gasification furnace housing 1, the gasification reaction chamber burner 2.1 is inserted into the gasification reaction chamber 2, and the inner wall of the gasification reaction chamber 2 is a water-cooled wall 3.
A demister 7 is provided above the catalyst layer 6.
The water-cooled wall 3 is provided with a water-cooled wall circulating water inlet 3.1 and a water-cooled wall circulating water outlet 3.2.
The chilling water tank 5 is provided with a chilling water tank water inlet 5.1 and a chilling water tank water outlet 5.2.
The slag pool 9 is provided with a slag pool circulating water inlet 9.1 and a slag pool circulating water outlet 9.2.
The bottom of the slag pool 9 is provided with a slag discharge port, and the slag discharge port is provided with a slag discharge valve.
The upper end of the synthetic gas conduit 4 penetrates through the chilling water tank 5 and then is bent and inserted into the chilling water tank 5, and the upper end of the synthetic gas conduit 4 is of an inverted U-shaped structure.
The kind of the catalyst layer 6 is adjusted according to the kind of the desired product gas to output the desired product gas.
The specific working process of the invention is as follows:
coal and oxygen enter a gasification reaction chamber 2 to be gasified, synthesis gas output by the gasification reaction chamber 2 is introduced into a chilling water tank 5 through a synthesis gas guide pipe 4, ash removal treatment is carried out through chilling water, then the synthesis gas rises and enters a catalyst layer 6, corresponding product gas is generated by catalysis of the catalyst layer 6, wherein the product gas continuously rises and is discharged through a product gas outlet 8, and the catalyst layer 6 is a methane catalyst layer 6 or a methanol catalyst layer 6.
The slag discharged from the bottom of the gasification reaction chamber 2 falls into the slag pool 9 and is finally discharged from the slag discharge port periodically.
The invention utilizes the waste heat generated during the generation of the synthesis gas to directly lift the synthesis gas to the catalyst layer 6, utilizes the heat of the synthesis gas to generate the product gas, avoids heating the synthesis gas by an external heat source, simultaneously avoids excessively cooling the synthesis gas in the gasification furnace, and reduces the consumption of chilling water.
Finally, it should be noted that: the above embodiments are only for illustrating the technical solutions of the present invention and not for limiting the same, and although the present invention is described in detail with reference to the above embodiments, those of ordinary skill in the art should understand that: modifications and equivalents may be made to the embodiments of the invention without departing from the spirit and scope of the invention, which is to be covered by the claims.

Claims (10)

1. The utility model provides a gasifier of direct system methane/methyl alcohol of coal gasification, a serial communication port, including gasification reacting chamber nozzle (2.1), synthetic gas pipe (4), gasifier casing (1) and set up in gasifier casing (1) and catalyst layer (6) that distribute in proper order from the top down, chilling basin (5), gasification reacting chamber (2) and slag bath (9), the one end of synthetic gas pipe (4) is linked together with the top export of gasification reacting chamber (2), the other end of synthetic gas pipe (4) inserts in chilling basin (5), the top of gasification furnace casing (1) is provided with product gas export (8), gasification reacting chamber nozzle (2.1) inserts in gasification reacting chamber (2), the inner wall of gasification reacting chamber (2) is water-cooling wall (3).
2. The gasification furnace for directly producing methane/methanol by coal gasification according to claim 1, wherein a demister (7) is disposed above the catalyst layer (6).
3. The gasification furnace for directly producing methane/methanol by coal gasification according to claim 1, wherein the water-cooled wall (3) is provided with a water-cooled wall circulating water inlet (3.1) and a water-cooled wall circulating water outlet (3.2).
4. The gasification furnace for directly preparing methane/methanol by coal gasification according to claim 1, wherein the chilling water tank (5) is provided with a chilling water tank water inlet (5.1) and a chilling water tank water outlet (5.2).
5. The gasification furnace for directly producing methane/methanol by coal gasification according to claim 1, wherein the slag bath (9) is provided with a slag bath circulating water inlet (9.1) and a slag bath circulating water outlet (9.2).
6. The gasification furnace for directly producing methane/methanol by coal gasification according to claim 1, wherein a slag discharge port is arranged at the bottom of the slag pool (9).
7. The gasification furnace for directly producing methane/methanol by coal gasification according to claim 7, wherein a slag discharge valve is disposed at the slag discharge port.
8. The gasification furnace for directly producing methane/methanol by coal gasification according to claim 1, wherein the upper end of the syngas conduit (4) passes through the chilling water tank (5) and is then bent and inserted into the chilling water tank (5).
9. The gasification furnace for directly producing methane/methanol by coal gasification according to claim 8, wherein the upper end of the syngas conduit (4) has an inverted U-shaped structure.
10. The gasification furnace for directly producing methane/methanol by coal gasification according to claim 1, wherein the type of the catalyst layer (6) is adjusted according to the type of the desired product gas to output the desired product gas.
CN202110156370.4A 2021-02-04 2021-02-04 Gasification furnace for directly preparing methane/methanol by coal gasification Pending CN112961705A (en)

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CN202110156370.4A CN112961705A (en) 2021-02-04 2021-02-04 Gasification furnace for directly preparing methane/methanol by coal gasification

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CN202110156370.4A CN112961705A (en) 2021-02-04 2021-02-04 Gasification furnace for directly preparing methane/methanol by coal gasification

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2251399A2 (en) * 2009-03-19 2010-11-17 Energie Oberwart Errichtungs GmbH Device and method for creating a gas
CN102021037A (en) * 2009-09-14 2011-04-20 新奥科技发展有限公司 Method and apparatus for preparing methane by catalytic gasification of coal
US20160083319A1 (en) * 2011-04-15 2016-03-24 Air Liquide Global E&C Solutions Germany Gmbh Plant for the production of methanol from synthesis gas rich in inerts
CN109652145A (en) * 2017-10-12 2019-04-19 中国石油化工股份有限公司 The device and method of fluidized bed coal catalytic gasification methane with nozzle
CN212204595U (en) * 2020-05-09 2020-12-22 中国华能集团有限公司 Pulverized coal partial gasification and denitration system

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2251399A2 (en) * 2009-03-19 2010-11-17 Energie Oberwart Errichtungs GmbH Device and method for creating a gas
CN102021037A (en) * 2009-09-14 2011-04-20 新奥科技发展有限公司 Method and apparatus for preparing methane by catalytic gasification of coal
US20160083319A1 (en) * 2011-04-15 2016-03-24 Air Liquide Global E&C Solutions Germany Gmbh Plant for the production of methanol from synthesis gas rich in inerts
CN109652145A (en) * 2017-10-12 2019-04-19 中国石油化工股份有限公司 The device and method of fluidized bed coal catalytic gasification methane with nozzle
CN212204595U (en) * 2020-05-09 2020-12-22 中国华能集团有限公司 Pulverized coal partial gasification and denitration system

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
张明: "《煤制合成天然气技术与应用》", 30 September 2017 *

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