CN112955531A - 洗涤剂组合物 - Google Patents
洗涤剂组合物 Download PDFInfo
- Publication number
- CN112955531A CN112955531A CN201980061006.0A CN201980061006A CN112955531A CN 112955531 A CN112955531 A CN 112955531A CN 201980061006 A CN201980061006 A CN 201980061006A CN 112955531 A CN112955531 A CN 112955531A
- Authority
- CN
- China
- Prior art keywords
- acid
- diglycerides
- mono
- detergent composition
- laundry detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000003599 detergent Substances 0.000 title claims abstract description 34
- 239000004094 surface-active agent Substances 0.000 claims abstract description 46
- 239000004744 fabric Substances 0.000 claims abstract description 13
- 239000007864 aqueous solution Substances 0.000 claims abstract description 3
- 238000005008 domestic process Methods 0.000 claims abstract description 3
- 238000001035 drying Methods 0.000 claims abstract description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 35
- 125000000217 alkyl group Chemical group 0.000 claims description 24
- 229920006395 saturated elastomer Polymers 0.000 claims description 22
- 150000007524 organic acids Chemical class 0.000 claims description 21
- 239000002253 acid Substances 0.000 claims description 13
- DNISEZBAYYIQFB-PHDIDXHHSA-N (2r,3r)-2,3-diacetyloxybutanedioic acid Chemical compound CC(=O)O[C@@H](C(O)=O)[C@H](C(O)=O)OC(C)=O DNISEZBAYYIQFB-PHDIDXHHSA-N 0.000 claims description 9
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 9
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 9
- 235000015165 citric acid Nutrition 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 9
- 150000003899 tartaric acid esters Chemical class 0.000 claims description 9
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 8
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 8
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- 235000009421 Myristica fragrans Nutrition 0.000 description 3
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/08—Polycarboxylic acids containing no nitrogen or sulfur
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38636—Preparations containing enzymes, e.g. protease or amylase containing enzymes other than protease, amylase, lipase, cellulase, oxidase or reductase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
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Abstract
本发明涉及一种洗衣洗涤剂组合物，其包含：a)4‑50重量％的表面活性剂，其中50‑100重量％，优选60‑100重量％，更优选80‑100重量％，甚至更优选90‑100重量％，最优选100重量％的所述表面活性剂是可食用表面活性剂。一种处理织物的家用方法，其包括以下步骤：a)用0.5至20g/L的所述洗涤剂组合物的水溶液处理织物；b)任选地漂洗和干燥所述织物。
Description
技术领域
本发明涉及洗涤剂组合物。更特别地，包含可食用表面活性剂的洗涤剂组合物。
背景技术
单甘油酯和二甘油酯的有机酸酯衍生物是用于食品加工的表面活性剂，例如用于面包店中以改善面包质量或用于巧克力中以防止起霜。它们是从基于动物和植物的成分生产。
意外和有目的地摄入洗衣洗涤剂可导致健康问题。
期望减少与摄入洗衣洗涤剂有关的潜在风险，同时保持清洁性能。
发明内容
在第一方面，本发明涉及洗衣洗涤剂组合物，其包含：
a)4-50重量％，优选4-40重量％的表面活性剂；
其中50-100重量％，优选60-100重量％，更优选80-100重量％，甚至更优选90-100重量％，最优选100重量％的所述表面活性剂是可食用表面活性剂。
一种处理织物的家用方法，其包括以下步骤：
a)用0.5-20g/L，更优选1-10g/L的根据本发明的第一方面的洗涤剂组合物的水溶液处理织物；
b)任选地漂洗和干燥所述织物。
优选地，所述可食用表面活性剂是以下形式的单甘油酯和二甘油酯的有机酸衍生物：-
其中R1、R2和R3中的一个或两个，优选一个，独立地选自式R4CO-的酰基，其中R4是直链的或支链的、饱和的或单不饱和的C9至C21烷基链，优选C15至C21直链烷基链，最优选饱和的或单不饱和的C15至C17直链烷基链；
其中R1、R2和R3中的一个或两个，优选一个，选自通式(HOOC)nXCO-的有机酸，其中X是含有1至6个碳原子的饱和的或单不饱和的有机基团，并且n＝1-3；
其中R1、R2和R3中的一个或没有任何一个选自H，优选R1、R2和R3中的一个选自H。
优选地，R1、R2和R3中的一个独立地选自式R4CO-的酰基；其中R4是直链的或支链的、饱和的或单不饱和的C9至C21烷基链。
优选地，R4是直链的或支链的、饱和的或单不饱和的C15至C21直链烷基链，优选饱和的或单不饱和的C15至C17直链烷基链。
优选地，R1、R2和R3中的一个选自通式(HOOC)nXCO-的有机酸；其中X是含有1至6个碳原子的饱和的或单不饱和的有机基团，并且n＝1-3。
优选地，(HOOC)nXCO选自柠檬酸、苹果酸、酒石酸、单乙酰基和二乙酰基酒石酸、琥珀酸、草酸、马来酸、富马酸、丙二酸，更优选柠檬酸、乳酸、酒石酸、单乙酰基和二乙酰基酒石酸，其中酸基团失去OH以形成酯。
优选地，R1、R2和R3中的一个选自H。
优选地，单甘油酯和二甘油酯的有机酸衍生物选自：单甘油酯和二甘油酯的柠檬酸酯(citrem)；单甘油酯和二甘油酯的酒石酸酯(tatem)；单甘油酯和二甘油酯的二乙酰基酒石酸酯(datem)；及单甘油酯和二甘油酯的混合的乙酸、酒石酸和二乙酰基化酒石酸酯(MATEM)；优选地，单甘油酯和二甘油酯的有机酸衍生物选自：单甘油酯和二甘油酯的柠檬酸酯(citrem)；单甘油酯和二甘油酯的酒石酸酯(tatem)；及单甘油酯和二甘油酯的二乙酰基酒石酸酯(datem)；最优选地，单甘油酯和二甘油酯的有机酸衍生物选自：单甘油酯和二甘油酯的柠檬酸酯(citrem)。
羧酸甘油酯经常以未取代的单甘油酯和二甘油酯提供，优选地，(羧酸甘油酯)/(未取代的单甘油酯和二甘油酯)的重量比大于1，更优选大于2，最优选大于4。优选地，按重量计，未取代的单甘油酯和二甘油酯主要是单甘油酯。
洗涤剂组合物可包含阴离子、非离子、阳离子和/或两性表面活性剂。
优选地，组合物是液体或液体单位剂量组合物。
具体实施方式
制剂可以是任何形式，例如液体、固体、粉末、液体单位剂量。
优选地，组合物是液体或液体单位剂量组合物。
当溶于去矿物质水中时，制剂优选地具有4至8，更优选6.5至7.5，最优选7的pH。
表面活性剂
洗衣洗涤剂组合物包含4-50重量％，优选4-40重量％的表面活性剂；其中50-100重量％，优选60-100重量％，更优选80-100重量％，甚至更优选90-100重量％，最优选100重量％的所述表面活性剂是可食用表面活性剂。
可食用表面活性剂
可食用表面活性剂的存在量为总表面活性剂含量的50至100重量％，优选为60至100重量％，更优选为80至100重量％，甚至更优选为90至100重量％，最优选为100重量％。最优选地，100重量％的存在的表面活性剂是可食用表面活性剂。
可食用表面活性剂是指根据通过建立批准用于食品添加剂、食品酶、食品调味剂和营养物中的食品添加剂联合清单，修订关于食品添加剂的Annex III to Regulation(EC)No.1333/2008 of the European Parliament and of the Council的2011年11月11日的Commission Regulation(EU)No 1130/2011，该表面活性剂为食品级，具有EEA关联的文本参见https://eur-lex.europa.eu/legal-content/EN/TXT/？uri＝CELEX:32011R1130。
优选的可食用表面活性剂是甘油单酯和甘油二酯的有机酸衍生物。
单甘油酯和二甘油酯的有机酸衍生物
在本文中，单甘油酯和二甘油酯的有机酸衍生物被称为羧酸甘油酯。
单甘油酯和二甘油酯的有机酸衍生物具有以下形式：-
其中R1、R2和R3中的一个或两个，优选一个，独立地选自式R4CO-的酰基，其中R4是直链的或支链的、饱和的或单不饱和的C9至C21烷基链，优选C15至C21直链烷基链，最优选饱和的或单不饱和的C15至C17直链烷基链；
其中R1、R2和R3中的一个或两个，优选一个，选自通式(HOOC)nXCO-的有机酸，其中X是含有1至6个碳原子的饱和的或单不饱和的有机基团，并且n＝1-3；
其中R1、R2和R3中的一个或没有任何一个选自H，优选R1、R2和R3中的一个选自H。
优选地，(HOOC)nXCO选自柠檬酸、苹果酸、酒石酸、单乙酰基和二乙酰基酒石酸、琥珀酸、草酸、马来酸、富马酸、丙二酸，更优选柠檬酸、乳酸、酒石酸、单乙酰基和二乙酰基酒石酸，其中酸基团失去OH以形成酯。
单甘油酯和二甘油酯的有机酸衍生物的重量是以质子化形式计。
羧酸甘油酯可以通过用有机酸来酯化单甘油酯和二甘油酯而合成。单甘油酯和二甘油酯可以通过脂肪甘油解(fat glycerolysis)(200℃，碱性催化剂)而产生。单甘油酯可以通过在高真空下蒸馏来分离。单甘油酯和二甘油酯也可以通过脂肪的脂质酯酶催化水解来产生。该有机酸然后可以通过酯化反应或与有机酸的酸酐的反应(当结构允许时)来加成。
Hasenhuettl，G.L和Hartel，R.W.(编著)的Food Emulsifier and TheirApplication.2008(Springer)和Whitehurst，R.J(编著)的Emulsifiers in FoodTechnology 2008(Wiley-VCH)以及V.Norn编辑的这本书的第2版2015(Wiley-Blackwell)中讨论了羧酸甘油酯的性质和合成。
优选的单甘油酯和二甘油酯的有机酸衍生物选自：
E472c单甘油酯和二甘油酯的柠檬酸酯(citrem)；
E472d单甘油酯和二甘油酯的酒石酸酯(tatem)；
E472e单甘油酯和二甘油酯的二乙酰基酒石酸酯(datem)；和
E472f单甘油酯和二甘油酯的混合的乙酸、酒石酸和二乙酰基化酒石酸酯(MATEM)。
更优选的单甘油酯和二甘油酯的有机酸衍生物选自：
E472c单甘油酯和二甘油酯的柠檬酸酯(citrem)；
E472d单甘油酯和二甘油酯的酒石酸酯(tatem)；和,
E472e单甘油酯和二甘油酯的二乙酰基酒石酸酯(datem)。
其中E数字是在欧盟内允许用作食品添加剂使用的物质的编码。
E472c单甘油酯和甘油二酯的柠檬酸酯(citrem)是最优选的。
优选地，羧酸甘油酯是单甘油酯的酸酯。优选地，单甘油酯获自植物，优选地获自油菜籽、向日葵、玉米(maze)、大豆、花生、棉籽、橄榄油、妥尔油。
羧酸甘油酯可以是盐形式或酸形式，通常是水溶性钠、钾、铵、镁或单-、二-或三-C2-C3烷醇铵盐的形式，其中钠阳离子是常见的一个选择。
优选地，羧酸甘油酯主要具有饱和的和单不饱和的C18直链烷基链，最优选(C18羧酸甘油酯)/(C16羧酸甘油酯)的重量分数优选地为2至400，更优选8至200，其中羧酸甘油酯的重量是以质子化形式计。
优选结构的实例是
这些是饱和的C18羧酸甘油酯。
优选地，羧酸甘油酯包含小于1重量％的具有多不饱和烷基链的物质，更优选小于0.5重量％，最优选小于0.1重量％。这可以通过所述油的氢化来获得。
羧酸甘油酯可获自Danisco、Palsgaard和Acatris。
单甘油酯和二甘油酯的有机酸衍生物的存在水平为1至95重量％，优选1.5至50重量％，更优选2至40重量％。
另外的成分
制剂可以含有另外的成分。
如果组合物包含100重量％的可食用表面活性剂，则优选地，任何另外的成分是食品级成分。
制剂可以包含另外的食品级成分。
食品成分在Belitz、Grosch和Schieberle编辑的Food Chemistry(Springer2000)中讨论。
组合物可以包含10、15、20、25、30、35、40、45、50、55、60、65、80重量％的两种或更多种食品乳化剂。在本发明的又一个实施方式中，两种或更多种食品乳化剂包括两种，三种，四种，五种，六种，七种，八种，九种或十种乳化剂。
食品乳化剂包括单甘油酯和二甘油酯的有机酸衍生物，硬脂基-2-乳酸酯，脱水山梨糖醇脂肪酸酯，聚氧乙烯脱水山梨糖醇酯，聚甘油-聚蓖麻酸酯，卵磷脂，部分水解的卵磷脂，乳化蛋白，皂苷和糖脂，更优选单甘油酯和二甘油酯的有机酸衍生物，硬脂基-2-乳酸酯，脱水山梨糖醇脂肪酸酯和聚氧乙烯脱水山梨糖醇酯。
可溶性晶体食品材料，例如盐，蔗糖，葡萄糖可作为乳化剂的载体。
螯合剂选自柠檬酸，EDTA，葡糖酸，氧硬脂精，山梨糖醇，正磷酸，焦磷酸，三磷酸，具有10-15个残基的六偏磷酸和酒石酸，更优选柠檬酸，酒石酸和葡糖酸。优选地，螯合剂以0.5至5重量％存在。
可以存在选自苯甲酸，山梨酸，对羟基苯甲酸的烷基酯的抗微生物剂。
食用色素可以存在。
为了防止制剂的氧化，制剂中可以存在抗氧化剂。
可以存在选自生育酚，抗坏血酸酯，没食子酸酯，叔丁基羟基茴香醚和二叔丁基羟基甲苯的抗氧化剂。
另外的不可食用成分
可以存在另外的不可食用成分，例如洗衣洗涤剂组合物中通常存在的那些。
另外的表面活性剂
洗衣洗涤剂组合物包含4-50重量％，优选4-40重量％的表面活性剂；其中50-100重量％，优选60-100重量％，更优选80-100重量％，甚至更优选90-100重量％，最优选100重量％的所述表面活性剂是可食用表面活性剂。
洗衣组合物因此可以包含不可食用表面活性剂，但是优选100重量％的表面活性剂是可食用的。
常见的不可食用表面活性剂是用于洗衣洗涤剂组合物中的常规表面活性剂，例如阴离子，非离子，阳离子和两性表面活性剂。
优选的不可食用表面活性剂是阴离子，非离子和两性表面活性剂。
表面活性剂在CRC Press，Series Editor:Arthur T.Hubbard出版的SurfactantScience Series中讨论。
表面活性剂可包括非离子表面活性剂。优选地，非离子表面活性剂选自饱和的和单不饱和的脂肪醇乙氧基化物和饱和的和单不饱和的脂肪酸糖酯。更优选地，非离子表面活性剂是饱和的和单不饱和的脂肪醇乙氧基化物，优选选自具有平均5至30个乙氧基化物的C12至C20直链伯醇乙氧基化物，更优选具有平均10至25个乙氧基化物的C16至C18直链伯醇乙氧基化物。
表面活性剂可以包括阴离子表面活性剂，其优选为C12至C18烷基醚羧酸盐，和具有含约8至约22个碳原子的烷基的有机硫酸、醚硫酸和磺酸的水溶性碱金属盐，术语烷基用于包括高级烷基的烷基部分。
合适的合成阴离子洗涤剂化合物的实例是烷基硫酸钠和钾，特别是通过使高级C12至C18醇硫酸盐化而获得的那些、烷基C9至C20苯磺酸钠和钾，特别是直链仲烷基C10至C15苯磺酸钠，烷基(优选甲基)酯磺酸盐，及其混合物。
两性表面活性剂的实例包括椰油酰胺丙基甜菜碱。
优选地，所用的表面活性剂是饱和的或单不饱和的。
助洗剂或络合剂
组合物可包含助洗剂。
助洗剂材料可以选自1)钙螯合剂材料，2)沉淀材料，3)钙离子交换材料及4)其混合物。
钙螯合剂助洗剂材料的实例包括碱金属多磷酸盐，例如三聚磷酸钠，和有机螯合剂，例如乙二胺四乙酸。
沉淀助洗剂材料的实例包括正磷酸钠和碳酸钠。
钙离子交换助洗剂材料的实例包括各种类型的水不溶性晶体或无定形铝硅酸盐，其中沸石是其众所周知的代表，例如沸石A、沸石B(也称为沸石P)、沸石C、沸石X、沸石Y以及如EP-A-0,384,070中描述的P型沸石。
组合物还可以含有0-65重量％的助洗剂或络合剂，例如乙二胺四乙酸、二亚乙基三胺五乙酸、烷基或烯基琥珀酸、次氮基三乙酸或下文提及的其他助洗剂。许多助洗剂凭借其络合金属离子的能力也是漂白稳定剂。
沸石和碳酸盐(碳酸盐(包括碳酸氢盐和倍半碳酸盐))是优选的助洗剂，碳酸盐是特别优选的。
组合物可以含有作为助洗剂的晶体铝硅酸盐，优选碱金属铝硅酸盐，更优选铝硅酸钠。这通常是以小于15重量％、优选小于12.5重量％、更优选小于10重量％的含量存在。铝硅酸盐是具有以下通式的材料：
0.8-1.5M2O·Al2O3·0.8-6SiO2,
其中M为一价阳离子，优选钠。
这些材料含有一些结合水并且需要具有至少50mg CaO/g的钙离子交换能力。优选的铝硅酸钠在上式中含有1.5-3.5个SiO2单元。它们可以通过硅酸钠与铝酸钠之间的反应而容易地制备，如文献中充分描述的。表面活性剂与铝硅酸盐(当存在时)的比率优选大于5:2，更优选大于3:1。
替代地或在铝硅酸盐助洗剂之外，可以使用磷酸盐助洗剂。在本领域中，术语“磷酸盐”包括二磷酸盐、三磷酸盐和膦酸盐物质。其他形式的助洗剂包括硅酸盐，例如可溶性硅酸盐、偏硅酸盐、层状硅酸盐(例如来自Hoechst的SKS-6)。
更优选地，洗衣洗涤剂制剂是非磷酸盐助洗的洗衣洗涤剂制剂，即含有小于1重量％的磷酸盐。最优选地，洗衣洗涤剂制剂是非协助的，即，含有小于1重量％的助洗剂。
如果洗涤剂组合物是水性液体洗衣洗涤剂，则优选的是单丙二醇以1至30重量％，优选2至18重量％的含量存在，以向制剂提供适宜的、可倾倒的粘度。
荧光剂
组合物优选地包含荧光剂(光学增亮剂)。
荧光剂是众所周知的，并且许多这样的荧光剂是可商购的。通常，这些荧光剂以其碱金属盐，例如钠盐的形式提供和使用。
组合物中使用的一种或多种荧光剂的总量通常为0.0001至0.5重量％，优选0.005至2重量％，更优选0.01至0.1重量％。荧光剂的优选类别是：二苯乙烯基联苯化合物，例如Tinopal(商标)CBS-X，二胺二苯乙烯二磺酸化合物，例如Tinopal DMS pure Xtra和Blankophor(商标)HRH，以及吡唑啉化合物，例如Blankophor SN。
优选的荧光剂为具有CAS-No 3426-43-5、CAS-No 35632-99-6、CAS-No 24565-13-7、CAS-No 12224-16-7、CAS-No 13863-31-5、CAS-No4193-55-9、CAS-No 16090-02-1、CAS-No 133-66-4、CAS-No 68444-86-0、CAS-No 27344-41-8的荧光剂。
最优选的荧光剂是：2-(4-苯乙烯基-3-磺苯基)-2H-萘酚[1,2-d]三唑钠、4,4'-双{[(4-苯胺基-6-(N-甲基-N-2-羟乙基)氨基-1,3,5-三嗪-2-基)]氨基}二苯乙烯-2,2'二磺酸二钠、4,4'-双{[(4-苯胺基-6-吗啉代-1,3,5-三嗪-2-基)]氨基}二苯乙烯-2-2'二磺酸二钠，和4,4'-双(2-磺苯乙烯基)联苯二钠。
香料
组合物优选包含香料。在由CFTA Publications出版的CTFA(Cosmetic，Toiletryand Fragrance Association)1992International Buyers Guide和由SchnellPublishing Co.出版的OPD 1993Chemicals Buyers Directory 80th Annual Edition中提供了香料的许多合适实例。
优选地，香料包含以下的至少一种香型(note)(化合物)：α-异甲基紫罗酮，水杨酸苄酯；香茅醇；香豆素；己基肉桂醛；芳樟醇；2-甲基戊酸乙基酯；辛醛；乙酸苄酯；3,7-二甲基-1,6-辛二烯-3-醇3-乙酸酯；2-(1,1-二甲基乙基)-环己醇1-乙酸酯；δ-大马酮(damascone)；β-紫罗酮；乙酸三环癸烯酯(verdyl acetate)；十二醛；己基肉桂醛(hexylcinnamic aldehyde)；环十五内酯；苯乙酸2-苯基乙基酯；水杨酸戊酯；β-石竹烯；十一碳烯酸乙酯；邻氨基苯甲酸香叶酯；α-鸢尾酮；β-苯基乙基苯甲酸酯；α-檀香醇；雪松醇；乙酸柏木酯；甲酸柏木酯(cedry formate)；水杨酸环己酯；γ-十二内酯，和β-苯乙基苯基乙酸酯。
香料的有用组分包括天然和合成来源的材料两者。它们包括单一化合物和混合物。这样的组分的具体实例可见于现有文献中，例如，Fenaroli's Handbook of FlavorIngredients,1975,CRC Press；M.B.Jacobs,Synthetic Food Adjuncts,1947,VanNostrand编辑；或S.Arctander,Perfume and Flavor Chemicals,1969,Montclair,N.J.(USA)。
在制剂中存在多种香料组分是常见的。在本发明的组合物中，设想将存在四种或更多种、优选五种或更多种、更优选六种或更多种、或甚至七种或更多种不同的香料组分。
在香料混合物中，优选15至25重量％是头香。头香是由Poucher(Journal of theSociety of Cosmetic Chemists 6(2):80[1955])所定义的。优选的头香选自柑桔油、芳樟醇、乙酸芳樟酯、薰衣草、二氢月桂烯醇、玫瑰醚(rose oxide)和顺-3-己醇。
国际日用香精香料协会已在2011年发布了香氛成分(香料)的列表。(http://www.ifraorg.org/en-us/ingredients#.U7Z4hPldWzk)。
国际日用香料研究所提供了具有安全性信息的香料(香氛)数据库。
香料头香可用于提示本发明的白度和亮度益处。
一些或所有香料可以被包封，有利于包封的典型香料组分包括具有相对低的沸点的那些，优选沸点小于300℃，优选为100-250℃的那些。包封具有低Clog P(即，将具有更高的被分配到水中的倾向的那些)，优选具有小于3.0的CLog P的香料组分也是有利的。这些具有相对低沸点和相对低CLog P的材料已经被称为“延迟释香(delayed blooming)”的香料成分，并且包含以下材料中的一种或多种：己酸烯丙酯、乙酸戊酯、丙酸戊酯、茴香醛、苯甲醚、苯甲醛、乙酸苄酯、苄基丙酮、苯甲醇、甲酸苄酯、异戊酸苄酯、丙酸苄酯、β-γ己烯醇、樟脑胶、左旋-香芹酮、d-香芹酮、肉桂醇、甲酸肉桂酯(cinamyl formate)、顺-茉莉酮、顺-3-己烯基乙酸酯、枯茗醇、cyclal c、二甲基苄基甲醇、二甲基苄基甲醇乙酸酯、乙酸乙酯、乙酰乙酸乙酯、乙基戊基酮、苯甲酸乙酯、丁酸乙酯、乙基己基酮、乙基苯基乙酸酯、桉树脑、丁香酚、乙酸葑酯(fenchyl acetate)、flor acetate(三环癸烯基乙酸酯)、frutene(三环癸烯基丙酸酯)、香叶醇、己烯醇、乙酸己烯酯、乙酸己酯、甲酸己酯、龙葵醇(hydratropicalcohol)、羟基香茅醛、茚酮、异戊醇、异薄荷酮、乙酸异胡薄荷酯(isopulegyl acetate)、异喹啉酮、女贞醛、芳樟醇、芳樟醇氧化物、甲酸芳樟酯、薄荷酮、薄荷基苯乙酮(menthylacetphenone)、甲基戊基酮、邻氨基苯甲酸甲酯、苯甲酸甲酯、甲基苄基乙酸酯(methylbenyl acetate)、甲基丁香酚、甲基庚烯酮、甲基庚炔碳酸酯(methyl heptinecarbonate)、甲基庚基酮、甲基己基酮、甲基苯基甲基乙酸酯、水杨酸甲酯、甲基-n-甲基邻氨基苯甲酸酯、橙花醇、辛内酯、辛醇、对甲酚、对甲酚甲基醚、对甲氧基苯乙酮、对甲基苯乙酮、苯氧乙醇、苯基乙醛、苯基乙基乙酸酯、苯基乙基醇、苯基乙基二甲基甲醇、乙酸异戊二烯酯、propyl bornate、胡薄荷酮、玫瑰醚(rose oxide)、黄樟素、4-萜品烯醇(4-terpinenol)、α-萜品烯醇和/或苯乙醛二甲醇缩醛(viridine)。多种香料组分存在于制剂中是常见的。在本发明的组合物中，设想将有来自上文给出的延迟释香香料的给定列表的四种或更多种，优选五种或更多种，更优选六种或更多种，或甚至七种或更多种不同的香料组分存在于香料中。
可以与本发明一起应用的另一组香料是所谓的“芳香疗法”材料。这些包括也用于香水中的许多组分，包括精油的组分如鼠尾草、桉树、天竺葵、薰衣草、肉豆蔻干皮(Mace)提取物、橙花油、肉豆蔻、留兰香、甜紫罗兰叶和缬草。
优选的是洗衣处理组合物不含过氧漂白剂，例如过碳酸钠，过硼酸钠和过酸。
聚合物
组合物可以含有一种或多种另外的聚合物。实例是羧甲基纤维素、聚(乙二醇)、聚(乙烯醇)、聚羧酸盐如聚丙烯酸盐、马来酸/丙烯酸共聚物和甲基丙烯酸月桂酯/丙烯酸共聚物。
在烷基足够长以形成支链或环状链的情况下，烷基包括支链、环状和直链烷基链。烷基优选是直链的或支链的，最优选是直链的。
酶，例如脂肪酶、蛋白酶、淀粉酶和纤维素酶可存在于制剂中。
洗涤剂组合物任选地包含一种或多种洗衣辅助成分。
术语“辅助成分”包括：香料、分散剂、稳定剂、pH控制剂、金属离子控制剂、着色剂、增亮剂、染料、气味控制剂、前香料、环糊精、香料、溶剂、去污聚合物、防腐剂、抗微生物剂、氯清除剂、抗收缩剂、织物卷曲剂、去斑剂、抗氧化剂、抗腐蚀剂、增稠剂、悬垂和形态控制剂、光滑剂、静电控制剂、褶皱控制剂、卫生处理剂、消毒剂、细菌控制剂、霉菌控制剂、霉控制剂、抗病毒剂、抗微生物剂、干燥剂、耐污剂、污物释放剂、异味控制剂、织物清新剂、氯漂白控制剂、染料固定剂、染料转移抑制剂、调色染料、颜色保持剂、颜色恢复剂、复原剂(rejuvenation agent)、抗褪色剂、白度增强剂、抗磨剂、耐磨剂、织物完整剂、防磨剂和漂洗助剂、UV保护剂、日晒褪色抑制剂、驱虫剂、抗过敏剂、酶、阻燃剂、防水剂、织物舒适剂、水调理剂、抗皱剂、抗拉伸剂及其组合。
如果存在，这样的助剂可以按组合物的重量计0.1％至5％的含量使用。
除非另有规定，否则本文所用不定冠词“一个/种(‘a’或‘an’)”及其相应的定冠词“所述/该(the)”是指至少一个/种，或者一个/种或多个/种。
将参照下述非限制性实施例进一步阐述本发明。
实施例
将表面活性剂溶解在24法国硬水中以给出0.15g/L溶液。在设置为200rpm的tergotometer中，将800ml该溶液用于洗涤4个5×5cm EMPA117污渍监测物(聚棉上的血液/牛奶/墨水污渍)。洗涤等效于定量加料1.5g/L的含有10重量％的表面活性剂的洗衣处理组合物或15g/L的含有1重量％的表面活性剂的洗衣处理组合物。该洗涤在30℃的温度下花费60分钟。
一旦洗涤已经完成，将监测物在400ml清洁水中冲洗一次，取出干燥并在反射计上测量颜色，表示为CIE L*a*b*值。
污渍去除计算为ΔL*值：
ΔL*＝L*(洗涤后)-L*(洗涤前)
更高的ΔL*值等于更好的清洁。
C18 Datem是从可食用的、完全氢化的菜籽油制造的食品级的、单甘油酯的二乙酰基酒石酸酯。
C18 Citrem是从可食用的、完全氢化的菜籽油制造的食品级的、单甘油酯和二甘油酯的柠檬酸酯。
菜籽油含有大于90％的C18脂肪酸。
具有2摩尔乙氧基化的硬脂酰醚硫酸盐是Bistline R.G.等J.Am.Oil.Chem.Soc.43；157(1966)中描述的传统合成洗涤剂。其不是可食用的。
这三种表面活性剂体系具有同等的清洁性能。
Citrem和Datem是可食用表面活性剂，其提供与传统合成洗涤剂活性成分相配的清洁性能。
Claims (12)
1.一种洗衣洗涤剂组合物，其包含：
a)4-50重量％，优选4-40重量％的表面活性剂；
其中50-100重量％，优选60-100重量％，更优选80-100重量％，甚至更优选90-100重量％，最优选100重量％的所述表面活性剂是可食用表面活性剂。
2.根据权利要求1所述的洗衣洗涤剂组合物，其中所述可食用表面活性剂是以下形式的单甘油酯和二甘油酯的有机酸衍生物：-
其中R1、R2和R3中的一个或两个独立地选自式R4CO-的酰基；其中R4是直链的或支链的、饱和的或单不饱和的C9至C21烷基链；其中R1、R2和R3中的一个或两个选自通式(HOOC)nXCO-的有机酸；其中X是含有1至6个碳原子的饱和的或单不饱和的有机基团，并且n＝1-3；
其中R1、R2和R3中的一个或没有任何一个选自H。
3.根据权利要求2所述的洗衣洗涤剂组合物，其中R1、R2和R3中的一个独立地选自式R4CO-的酰基；其中R4是直链的或支链的、饱和的或单不饱和的C9至C21烷基链。
4.根据权利要求2或权利要求3所述的洗衣洗涤剂组合物，其中R4是直链的或支链的、饱和的或单不饱和的C15至C21直链烷基链，优选饱和的或单不饱和的C15至C17直链烷基链。
5.根据权利要求2至4中任一项所述的洗衣洗涤剂组合物，其中R1、R2和R3中的一个选自通式(HOOC)nXCO-的有机酸；其中X是含有1至6个碳原子的饱和的或单不饱和的有机基团，并且n＝1-3。
6.根据前述权利要求中任一项所述的洗衣洗涤剂组合物，其中(HOOC)nXCO选自柠檬酸、苹果酸、酒石酸、单乙酰基和二乙酰基酒石酸、琥珀酸、草酸、马来酸、富马酸、丙二酸，更优选柠檬酸、乳酸、酒石酸、单乙酰基和二乙酰基酒石酸，其中酸基团失去OH以形成酯。
7.根据前述权利要求中任一项所述的洗衣洗涤剂组合物，其中R1、R2和R3中的一个选自H。
8.根据前述权利要求中任一项所述的洗衣洗涤剂组合物，其中所述单甘油酯和二甘油酯的有机酸衍生物选自：单甘油酯和二甘油酯的柠檬酸酯(citrem)；单甘油酯和二甘油酯的酒石酸酯(tatem)；单甘油酯和二甘油酯的二乙酰基酒石酸酯(datem)；和单甘油酯和二甘油酯的混合的乙酸、酒石酸和二乙酰基化酒石酸酯(MATEM)；优选地，所述单甘油酯和二甘油酯的有机酸衍生物选自：单甘油酯和二甘油酯的柠檬酸酯(citrem)；单甘油酯和二甘油酯的酒石酸酯(tatem)；和单甘油酯和二甘油酯的二乙酰基酒石酸酯(datem)；最优选地，所述单甘油酯和二甘油酯的有机酸衍生物选自：单甘油酯和二甘油酯的柠檬酸酯(citrem)。
9.根据前述权利要求中任一项所述的洗衣洗涤剂组合物，其进一步包含阴离子、非离子、阳离子和/或两性表面活性剂。
10.根据前述权利要求中任一项所述的洗衣洗涤剂组合物，其包含选自脂肪酶、蛋白酶、淀粉酶和纤维素酶的一种或多种酶。
11.根据前述权利要求中任一项所述的洗衣洗涤剂组合物，其中所述组合物是液体或液体单位剂量组合物。
12.一种处理织物的家用方法，其包括以下步骤：
a)用0.5-20g/L，更优选1-10g/L的根据权利要求1-11中任一项所述的洗涤剂组合物的水溶液处理织物；
b)任选地漂洗和干燥所述织物。
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| US4816170A (en) * | 1986-08-14 | 1989-03-28 | Colgate-Palmolive Company | Stable aqueous fabric softening compositions based on lecithin, saponin and sorbic acid and methods for making and using same |
| EP0512328A1 (en) * | 1991-05-06 | 1992-11-11 | Miles Inc. | Food safe cleaning composition |
| US6048830A (en) * | 1996-03-22 | 2000-04-11 | The Procter & Gamble Company | Delivery system having release barrier loaded zeolite |
| KR20180041808A (ko) * | 2016-10-14 | 2018-04-25 | 오씨아이 주식회사 | 천연 세제 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3853336A1 (en) | 2021-07-28 |
| AR116407A1 (es) | 2021-05-05 |
| BR112021004666A2 (pt) | 2021-06-01 |
| ZA202100956B (en) | 2022-09-28 |
| US20220033732A1 (en) | 2022-02-03 |
| WO2020058088A1 (en) | 2020-03-26 |
| EP3853336B1 (en) | 2022-08-24 |
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