CN112940634A - TPU (thermoplastic polyurethane) effect color-changed car cover and preparation process thereof - Google Patents
TPU (thermoplastic polyurethane) effect color-changed car cover and preparation process thereof Download PDFInfo
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/29—Laminated material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60J—WINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
- B60J11/00—Removable external protective coverings specially adapted for vehicles or parts of vehicles, e.g. parking covers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
- C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/385—Acrylic polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2433/00—Presence of (meth)acrylic polymer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2467/00—Presence of polyester
- C09J2467/006—Presence of polyester in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2471/00—Presence of polyether
- C09J2471/006—Presence of polyether in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2475/00—Presence of polyurethane
- C09J2475/006—Presence of polyurethane in the substrate
Abstract
The invention belongs to the technical field of automobile coatings, and particularly relates to a TPU (thermoplastic polyurethane) effect color-changed automobile coating and a preparation process thereof. It changes the chromatograph including inoxidizing coating, multilayer effect, TPU transparent basic unit, bond line, inoxidizing coating, multilayer effect change chromatograph, TPU transparent basic unit, bond line from the top down set gradually, the inoxidizing coating includes from type inoxidizing coating and multi-functional inoxidizing coating, and TPU transparent basic unit is equipped with one deck multilayer effect and changes the chromatograph in one side wherein at least. The invention has the following technical advantages: the invention combines with the surface of the vehicle paint, provides proper initial adhesion and holding adhesion, and has the advantage of no residual glue on the paint surface. The vehicle cover is ensured to have higher modulus and strength, excellent ageing resistance, scratch resistance, impact resistance, wear resistance and other physical properties by adopting the thermosetting resin/UV coating.
Description
Technical Field
The invention belongs to the technical field of automobile coatings, and particularly relates to a TPU (thermoplastic polyurethane) effect color-changed automobile coating and a preparation process thereof.
Background
At present, high-end equipment such as automobiles and furniture enters thousands of households, and various industries are filled, and especially, the automobiles become basic equipment of most common families, namely: the automobile paint is beautiful and everyone knows, and no matter how long the automobile is used, consumers want to look clean, so the consumers generally maintain the automobile regularly, but the traditional waxing, glazing and even high-end coating and plating are not careful when the automobile is scratched, the automobile paint is dropped and the automobile paint is dropped, which is unacceptable for the consumers, and therefore, the automobile clothes begin to appear.
The car clothing on the market at present is PVC and TPU material, and PVC is the biggest advantage be very high hardness, pastes on the car surface can rely on the protection lacquer painting of hard physical property, but the drawback of this kind of product is also obvious. The service life of the automobile clothes is short, the service life is usually only about 1 year, and the automobile clothes exposed outside for a long time can be gradually decomposed along with long-time solarization, and then the automobile clothes are yellow and cracked, and sometimes peculiar smell can be generated, so that the automobile clothes are unacceptable for many people, and high-end automobile clothes are mainly made of TPU materials, and the situation is avoided.
However, the modern TPU car cover is a transparent protective film, the brightness of the car body can be only improved by 30% when the TPU car cover is pasted on the automobile paint surface, the brightness of the car body can only be improved when the TPU car cover is pasted on the automobile paint surface, and personalized customization and color changing effects cannot be achieved.
For automobile clothes, a protective film is generally covered, and the main protective film is a TPU transparent base material protective film, so that the popularization and the application are limited due to the defects, and the defects are summarized as the following points:
the currently produced automobile clothes are invisible, cannot provide color changing effect, cannot better meet the personalized and personalized customization of customers, and have no obvious color enhancement on the appearance of the automobile;
the currently used TPU has poor yellowing resistance, low hardness and strength and poor ageing resistance;
at present, most of TPU substrate protective films are acrylic adhesives, the adhesion effect is poor, and residues are easily left on the surface of automobile paint.
Therefore, the technical development work in the field focuses on a TPU car cover which has a better protection effect on the automobile base paint, meets the personalized customization of customers and has various color changing effects and a preparation process thereof.
Disclosure of Invention
In view of the defects of the prior art, the technical problems to be solved by the invention are that the automobile surface paint protective film has poor durability, meets the personalized and personalized customization of customers and has residual glue in use.
In order to achieve the purpose, the invention provides a TPU effect color-changing car cover which comprises a protective layer, a multilayer effect color-changing layer, a TPU transparent base layer and a bonding layer, wherein the protective layer, the multilayer effect color-changing layer, the TPU transparent base layer and the bonding layer are sequentially arranged from top to bottom, the protective layer comprises a release protective layer and a multifunctional protective layer, at least one surface of the TPU transparent base layer is provided with the multilayer effect color-changing layer, and the bonding layer comprises a glue layer and an anti-sticking layer.
Further, the release protective layer and the anti-sticking layer are made of random copolymer PET, the multifunctional protective layer is made of a polyacrylate system, the multi-layer effect color-modifying layer is made of a PU ink system, the base material layer is made of a polyether-polyester copolymer or a thermoplastic aliphatic polyurethane elastomer system, and the glue layer is made of a pressure-sensitive adhesive made of a polyacrylate system.
Further, the multifunctional protective layer is made of a polypropylene resin system and comprises the following components: 30-50 parts of dimethyl octyl acrylic acid, 40-60 parts of difunctional poly urethane acrylic acid copolymer film-forming aid, 20-30 parts of methyl isobutyl ketone, 20-30 parts of butyl acetate and 0.4-0.6 part of adhesion promoter.
Further, the multilayer effect color-changing layer is made of a PU ink system, and comprises the following components: 50-60 parts of solid resin, 30-60 parts of dimethylformamide, 5-40 parts of methyl ethyl ketone, 1-40 parts of solid pigment, 0.5-10 parts of functional material powder and 0.5-5 parts of wetting accelerator.
Further, the solid resin is one or more of 60-90A polyether-polyester copolymer, polyester type aliphatic TPU and polyether type aliphatic TPU.
Further, the functional material powder can be one or a mixture of more of pearl powder, fluorescent powder, noctilucent powder, temperature-change powder, light-change powder, reflective powder, extinction powder, flash silver powder, silver paste, color-change powder, laser powder and the like.
Further, the TPU substrate layer is made of a polyether-polyester copolymer or a thermoplastic aliphatic polyurethane elastomer system, and comprises the following components: 80-90 parts of polyether-polyester copolymer with the hardness of 80-95A or thermoplastic aliphatic polyurethane elastomer with the hardness of 85-95A, 1-7 parts of slipping agent and 0.5-2 parts of transparent master batch.
Further, the glue layer is made of a polyacrylate system into a pressure-sensitive adhesive, and the pressure-sensitive adhesive comprises the following components: 30-40 parts of polyacrylate, 25 parts of toluene, 30-40 parts of ethyl acetate and 0.5 part of an appropriate amount of oligomeric silane coupling agent.
Furthermore, the thickness of the release protective layer is 0.025-0.08mm, the thickness of the multifunctional protective layer is 0.01-0.05mm, the thickness of the multilayer effect color changing layer is 0.015-0.08mm, the thickness of the TPU transparent base layer is 0.05-0.3mm, the thickness of the glue layer is 0.01-0.05mm, and the thickness of the anti-sticking layer is 0.05-0.3 mm.
Preferably, the thickness of the release protective layer is 0.05mm, the thickness of the multifunctional protective layer is 0.01mm, the thickness of the multilayer effect color changing layer is 0.025mm, the thickness of the TPU transparent base layer is 0.12mm, the thickness of the glue layer is 0.02mm, and the thickness of the anti-sticking layer is 0.1 mm.
According to the TPU effect color-changing car cover, the invention provides a related preparation process, which comprises the following steps:
step 1: forming a TPU substrate layer: the materials are configured according to the formula, and then all the materials are melted, extruded and calendered at the temperature of 160-200 ℃ to form the TPU substrate layer with the thickness of 0.12 mm.
Step 2: forming an upper or lower multi-layer effect color-changing layer: the raw materials are prepared according to the formula, and the reaction kettle is uniformly mixed to prepare a multilayer effect color changing layer which is coated with a PET film and PP paper for transfer.
And step 3: film transfer: and laminating the PET film or PP paper bearing the multilayer effect color modifying layer on the TPU substrate layer at a high temperature of 150-200 ℃ in a full-dry manner.
And 4, step 4: a lower glue layer was formed: the materials are prepared according to the formula, and the materials are uniformly mixed to prepare the self-crosslinking pressure-sensitive adhesive which is coated on the PET film for transfer.
And 5: forming an adhesive layer: and bonding the lower glue layer to the surface of the lower surface of the TPU substrate layer or the multi-layer effect color-changing layer in a semi-dry normal-temperature laminating mode.
Step 6: forming an upper multifunctional protective layer: preparing materials according to a formula, and blending AB dual components according to a proportion, wherein the component A is mainly polyacrylate copolymer, the component B contains urethane curing component, and then coating the urethane curing component on a filter screen for filtering, and then directly coating the urethane curing component on a PET release film through roll coating construction, and then directly attaching to the upper surface of a TPU layer or a multi-layer effect layer.
And 7: forming a protective layer: drying at 50-100 deg.C, curing in a constant temperature room at 60 deg.C for at least 48 hr, and curing to obtain the final product.
Compared with the similar products in the market, the invention has the following technical advantages:
(1) can produce various types of color-changed car clothes with different effects, meets the personalized and personalized customization of customers, and has obvious color-adding effect on the appearance of the car.
(2) The original film of the base material layer of the TPU effect color-changed car cover of the product is flat, has no water marks and crystal points, has high light transmittance, better modulus and strength and low yellowing index, and ensures the requirements of weather resistance, glossiness, transparency and the like;
(3) the self-crosslinking pressure-sensitive adhesive is combined with the surface of the vehicle paint, provides proper initial adhesion and holding adhesion, and has the advantage of no residual glue on the paint surface.
(4) The vehicle cover is ensured to have higher modulus and strength, excellent ageing resistance, scratch resistance, impact resistance, wear resistance and other physical properties by adopting the thermosetting resin/UV coating.
(5) The preparation method of the TPU effect color-changed car cover is simple, the reaction conditions are mild, the technological parameters are easy to control, and the data-based large-scale production can be realized.
(6) The TPU effect color-changed car cover not only has the appearance effect, but also has the flatness, the glossiness and the corresponding physical and chemical properties superior to those of the existing car cover products in the market, and the service life can reach more than ten years.
Drawings
FIG. 1 is a schematic structural diagram of the present invention.
Fig. 2 is a schematic structural diagram of the present invention.
FIG. 3 is a flow chart of the inventive manufacturing process of the present invention.
Fig. 4 is a schematic view of embodiment 1 of the present invention.
Fig. 5 is a schematic view of embodiment 2 of the present invention.
Fig. 6 is a schematic view of embodiment 3 of the present invention.
FIG. 7 is a schematic view of embodiment 4 of the present invention.
FIG. 8 is a schematic view of embodiment 5 of the present invention.
Fig. 9 is a schematic view of embodiment 6 of the present invention.
Detailed Description
The conception, the specific structure and the technical effects of the present invention will be further described with reference to the accompanying drawings.
The coating distribution of the automobile clothes products on the market at present: the adhesive is a thermosetting/UV layer-TPU substrate layer-acrylic non-drying adhesive layer; the coating distribution of the product of the invention mainly has two modes as shown in figure 1 and figure 2: wherein, the color changing layer is mixed in the following mode: pigments are singly discolored and/or effect-composed.
The invention relates to a light and thin TPU multilayer effect color-changing car cover which is characterized by comprising a protective layer with the thickness of 50-100 um, a multilayer effect color-changing layer with the thickness of 15-80um, a TPU transparent base layer with the thickness of 120um and a bonding layer with the thickness of 50-150 um, wherein the protective layer, the multilayer effect color-changing layer, the TPU transparent base layer and the bonding layer are sequentially arranged from top to bottom, the protective layer comprises a release protective layer and a multifunctional protective layer, at least one surface of the TPU transparent base layer is provided with one or more than one multilayer effect color-changing layer, and the bonding layer comprises a glue layer and an anti-sticking layer.
A preparation process of a light and thin TPU multi-layer effect color-changing car cover is characterized by comprising the following steps:
(1) forming a TPU substrate layer: preparing raw materials, wherein the raw material components comprise 80-90 parts of polyether-polyester copolymer with the hardness of 80-95A or 80-90 parts of thermoplastic aliphatic polyurethane elastomer with the hardness of 85-95A, 1-7 parts of slipping agent and 0.5-2 parts of transparent master batch, and all the raw materials are subjected to melt extrusion film forming processing to prepare a TPU substrate layer with the thickness of 120 mu m;
(2) forming an upper or lower multi-layer effect color-changing layer: preparing raw materials, wherein the raw material components comprise 50-60 parts of solid resin, 30-60 parts of dimethylformamide, 5-40 parts of methyl ethyl ketone, 1-40 parts of solid pigment, 0.5-10 parts of functional material powder and 0.5-5 parts of wetting accelerator to form a composite layer, and after the raw materials are mixed and cured, coating a multi-layer effect color-changing layer on the surface of a PET film or PP paper with the thickness of 25-80 microns by taking the PET film or PP paper as a release film;
(3) film transfer: bonding the multilayer effect color changing layer to the surface of the TPU substrate layer in a full-dry high-temperature lamination mode at 150-200 ℃ so that the color changing layer is transferred to the surface of the substrate layer;
(4) a lower glue layer was formed: preparing raw materials, wherein the raw material components comprise 30-40 parts of polyacrylate, 25 parts of toluene, 30-40 parts of ethyl acetate and 0.5 part of a proper amount of oligomeric silane coupling agent, uniformly mixing to prepare self-crosslinking pressure-sensitive adhesive, taking PET as a release film after curing of solid resin and the coupling agent is completed, and coating the self-crosslinking pressure-sensitive adhesive on the surface of the release film with the thickness of 50-150 microns;
(5) forming an adhesive layer: bonding the lower glue layer to the lower surface of the TPU substrate layer or the multilayer effect color-changing layer in a semi-dry normal-temperature laminating mode;
(6) forming an upper multifunctional protective layer: preparing raw materials, wherein the raw materials are prepared from A, B double components, the raw material components comprise 30-50 parts of dimethyl octyl acrylic acid, 40-60 parts of difunctional poly urethane acrylic acid copolymer film-forming aid, 20-30 parts of methyl isobutyl ketone, 20-30 parts of butyl acetate and 0.4-0.6 part of adhesion promoter, the raw materials are uniformly mixed, coated on a filter screen for filtration, directly coated on a PET release film through roller coating construction, and then directly attached to the upper surface of a TPU layer or a multilayer effect layer, and the thickness of the TPU layer or the multilayer effect layer is 10-100 mu m;
(7) forming a protective layer: drying and curing the raw materials in a drying tunnel at 50-100 ℃, then curing the raw materials in a constant temperature room at 60 ℃ for at least 48 hours, and finishing the protective layer after the raw materials are cured.
Preferably, in the step (1), the raw materials of the TPU substrate layer are uniformly mixed and then dried for 2 hours at 80 ℃ of a blast dryer, when the temperature of each zone of a cylinder of the composite extruder rises to 160 ℃ in the first zone of the cylinder, 160 ℃ in the second zone of the cylinder, 170 ℃ in the third zone of the cylinder, 160 ℃ in the first zone of the screen changing zone, 175 ℃ in the 2 zone of the screen changing zone, 180 ℃ in the first zone of a die head, 180 ℃ in the second zone of the die head, 180 ℃ in the third zone of the die head, 180 ℃ in the connection zone of the die head and 200 ℃ in a die head, raw material particles are added for melt plasticization, the mixture is extruded and cast through a casting die with a gap of 120.
Preferably, the solid resin in step (2) is one or more of polyether-polyester copolymer, polyester type aliphatic TPU, and polyether type aliphatic TPU.
Preferably, the functional material powder in the step (2) is one or a mixture of more of pearl powder, fluorescent powder, noctilucent powder, temperature-change powder, light-change powder, reflecting powder, extinction powder, flash silver powder, silver paste, color-change powder and laser powder.
Preferably, in the step (6), the raw material is A, B bi-component prepared, and the A component: 30-50 parts of dimethyl octyl acrylate, 10 parts of isobutyl ketone and 20 parts of butyl acetate, wherein the component B comprises the following components: 40-60 parts of difunctional block urethane acrylic copolymer film-forming aid, 30 parts of methyl isobutyl ketone, 30 parts of butyl acetate and 0.4-0.6 part of adhesion promoter, wherein the two components can be directly and uniformly mixed, and then the raw material is coated on the surface of the upper TPU layer or the upper multi-layer effect layer through roller coating construction, and then the mixture passes through a normal-temperature drying tunnel.
Preferably, in the step (6), the ratio of the A, B components is 1-4: 1.
Preferably, in the step (5), the adhesive layer provides a peel strength of 5-25N/25.4 mm.
Preferably, in the step (6), the UV coating can be selected from 40-60 parts of dimethyl octyl acrylate, 30-60 parts of functional polyurethane acrylic copolymer film-forming aid, 30-40 parts of methyl isobutyl ketone, 20-40 parts of butyl acetate and 0.5-1 part of light-induced reaction promoter.
The specific implementation mode is as follows:
fig. 1 is a schematic structural diagram of one of the TPU effect color-changing car cover protective films provided by the present invention, which includes a TPU substrate layer, wherein a release protective layer, a multifunctional protective layer, and a multilayer effect color-changing layer are sequentially disposed on an upper surface of the TPU substrate layer from top to bottom, and a glue layer and an anti-sticking layer are sequentially disposed on a lower surface of the TPU substrate layer from top to bottom.
In a preferred embodiment of the invention, the release protective layer is a random copolymerization PET film with the thickness of 50um, has the functions of isolation, dirt resistance and dust resistance, has the function of stretching and extending coverage, and plays a role in protecting the multifunctional protective layer before use. The multifunctional protective layer is a polyacrylate system coating with the thickness of 10 mu m, has the characteristics of increasing the hardness, scratch resistance and scratch resistance of the car cover, has high light transmittance and high gloss, enables the car cover to have bright and attractive appearance and mellow texture, and has the functions of super-strong impact resistance, stain resistance, scratch resistance and automatic repair. The core of the invention is a PU printing ink system with the thickness of 25um and the multi-layer effect color changing layer can provide a multi-effect color changing coating film for automobile clothes, meet the personalized selection of customers and play a role in coloring the appearance of automobiles. The TPU substrate layer is 120 mu m in thickness, is a basic framework of the automobile protective film, and has the advantages of high toughness, durability, weather resistance, flexure resistance, high light transmittance, high gloss, low yellowing and the like. The glue layer is self-crosslinking pressure sensitive adhesive for thickness 20um, and its effect bonds TPU substrate layer and car lacquer for car clothing can be better bonds on car lacquer surface, provides suitable just adhesion and holds the adhesion, is convenient for construct with the repeated construction and does not appear the remaining problem of glue. The anti-sticking layer is a random copolymerization PET film with the same thickness of 50um, and is used for protecting the adhesive layer when not in use, and then bears the adhesive layer and is stuck on the TPU substrate layer together in the sticking process.
The invention provides a preparation process of the TPU effect color-changed car cover, which comprises the following steps:
forming a TPU substrate layer
The raw material formula is as follows: 80-90 parts of polyether-polyester copolymer with the hardness of 80-95A or thermoplastic aliphatic polyurethane elastomer with the hardness of 85-95A, 1-7 parts of slipping agent and 0.5-2 parts of transparent master batch.
Uniformly mixing the raw materials of the TPU substrate layer, drying the mixture for 2 hours at 80 ℃ of a blast drier, raising the temperature of each zone of a machine barrel of the composite extruder to 160 ℃ of a first zone of the machine barrel, 160 ℃ of a second zone of the machine barrel, 170 ℃ of a third zone of the machine barrel, 160 ℃ of a screen changing zone 1, 175 ℃ of a screen changing zone 2, 180 ℃ of a first zone of a die head, 180 ℃ of a second zone of the die head, 180 ℃ of a third zone of the die head, 180 ℃ of a die head connecting zone and 200 ℃ of a die head mold, adding raw material particles for fusion and plasticization, extruding and casting through a casting mold with a gap of 120 mu m, continuously calendering through.
Forming an upper or lower multi-layer effect color-changing layer
The raw material formula is as follows: 50-60 parts of solid resin, 30-60 parts of dimethylformamide, 5-40 parts of methyl ethyl ketone, 1-40 parts of solid pigment, 0.5-10 parts of functional material powder and 0.5-5 parts of wetting accelerator.
Wherein, the wetting accelerant is X-6797, and the solid content can be adjusted according to the surface effect of the PU printing ink system. The solid resin is a thermoplastic elastomer with the hardness of 60-90A, such as one or more of polyether-polyester copolymer, polyester aliphatic TPU, polyether aliphatic TPU, film-grade styrene elastomer and nylon 12 elastomer.
The PU printing ink which is well mixed in the reaction kettle is coated on a PET film or PP paper by a scraper type coating machine to form a film with the thickness of 25um by using a multifunctional coating machine head, and then the film is dried in a drying tunnel at the temperature of 50-100 ℃.
Film transfer
And the multilayer effect color changing layer is bonded to the surface of the TPU substrate layer in a high-temperature laminating mode at 150-200 ℃ after being dried completely in the drying tunnel, so that the color changing layer is transferred to the surface of the substrate layer.
Forming a lower glue layer
The raw material formula is as follows: 30-40 parts of polyacrylate, 25 parts of toluene, 30-40 parts of ethyl acetate and 0.5 part of an appropriate amount of oligomeric silane coupling agent are uniformly mixed to prepare the self-crosslinking pressure-sensitive adhesive.
Preparing raw materials, uniformly mixing for 0.5-2 hours, taking PET as a release film after curing of the solid resin and the coupling agent is completed, and coating the self-crosslinking pressure-sensitive adhesive on the surface of the release film.
Forming an adhesion layer
And bonding the lower glue layer to the lower surface of the TPU substrate layer or the multi-layer effect color-changing layer in a semi-dry normal-temperature laminating mode.
The finished automobile clothes are manufactured through the steps, and the automobile clothes enter a drying oven at the temperature of 80 ℃ for at least 48 hours, so that the TPU effect color-changed automobile clothes are finally obtained.
Forming a multifunctional protective layer
The raw material formula is as follows: 30-50 parts of dimethyl octyl acrylic acid, 40-60 parts of difunctional poly urethane acrylic acid copolymer film-forming aid, 20-30 parts of methyl isobutyl ketone, 20-30 parts of butyl acetate and 0.4-0.6 part of adhesion promoter.
The adhesive force promoter is prepared from methacrylate, carboxylate and phosphate ester according to proportion, wherein the component A is mainly polyacrylate copolymer, and the component B contains urethane curing component in a ratio of 1-4: 1.
The prepared raw materials are filtered by a filter screen, then directly coated on a PET release film through roller coating construction, and then directly attached to the upper surface of a TPU layer or a multilayer effect layer.
Forming a protective layer
And (3) drying and curing the protective layer for 10 minutes through a drying tunnel at 50-100 ℃, then curing the protective layer in a constant temperature room at 60 ℃ for at least 48 hours, and finishing the lamination of the multifunctional protective layer after the raw materials are cured.
Example 1
This scheme provides a manufacturing technology that coral blue singly changes look TPU effect and changes look car clothing, specifically as follows:
firstly forming a TPU substrate layer, wherein the raw material formula comprises the following components: 89 parts of thermoplastic aliphatic polyurethane elastomer system, 3 parts of slipping agent and 2 parts of transparent master batch. Uniformly mixing the raw materials of the TPU substrate layer, drying the mixture for 2 hours at 80 ℃ of a blast drier, raising the temperature of each zone of a machine barrel of the composite extruder to 165 ℃ in a first zone of the machine barrel, 170 ℃ in a second zone of the machine barrel, 180 ℃ in a third zone of the machine barrel, 160 ℃ in a screen changing zone 1, 180 ℃ in a screen changing zone 2, 180 ℃ in a first zone of a die head, 180 ℃ in a second zone of the die head, 180 ℃ in a third zone of the die head, 180 ℃ in a connection zone of the die head and 210 ℃ in a die head mould, adding raw material particles for fusion and plasticization, extruding and casting through a casting mould with a gap of 120 mu m, continuously.
Then, a PET film is used as a carrier in a scraper type coating machine, 60 parts of solid resin, 60 parts of dimethyl formamide, 5 parts of methyl ethyl ketone, 6 parts of white paste, 5.2 parts of blue paste, 2.5 parts of mauve paste, 2.2 parts of medium yellow paste, 0.5 part of purple paste and 2 parts of a wetting agent are promoted, PU printing ink with the thickness of 30 mu m is coated on the PU printing ink, the PU printing ink enters a drying tunnel at the temperature of 50-100 ℃ for drying, and then the multilayer effect color changing layer is transferred to the upper surface of the TPU substrate layer from the PET film in a high-temperature laminating and fitting mode at the temperature of 190 ℃.
The TPU substrate layer is attached with the anti-sticking layer and the protective layer according to the mode, and the automobile clothing product is completed.
The produced car cover has the advantages of high glossiness, high weather resistance, high wear resistance, flat film surface and no yellowing, and the key point is to provide a novel car cover with the color changing effect.
Example 2
This scheme provides a manufacturing technology who electroplates grey TPU effect and change look car clothing, specifically as follows:
firstly forming a TPU substrate layer, wherein the raw material formula comprises the following components: 85 parts of thermoplastic aliphatic polyurethane elastomer system, 1 part of slipping agent and 0.5 part of transparent master batch. Uniformly mixing the raw materials of the TPU substrate layer, drying the mixture for 2 hours at 80 ℃ of a blast drier, raising the temperature of each zone of a machine barrel of the composite extruder to 158 ℃ of a first zone of the machine barrel, 168 ℃ of a second zone of the machine barrel, 170 ℃ of a third zone of the machine barrel, 150 ℃ of a screen changing zone 1, 170 ℃ of a screen changing zone 2, 180 ℃ of a first zone of a die head, 180 ℃ of a second zone of the die head, 180 ℃ of a third zone of the die head, 190 ℃ of a die head connecting zone and 220 ℃ of a die head mold, adding raw material particles for fusion and plasticization, extruding and casting through a casting mold with a gap of 120 mu m, continuously calendering through.
Then, a PET film is used as a carrier in a scraper type coating machine, a PU printing ink with the thickness of 25um is coated on the PET film according to the formula of raw materials of 58 parts of solid resin, 40 parts of dimethyl formamide, 20 parts of methyl ethyl ketone, 3 parts of aluminum silver paste, 0.1 part of black paste, 0.5 part of ultramarine blue paste and 0.5 part of wetting promoter, and the PU printing ink enters a drying tunnel at the temperature of 50-100 ℃ for drying and then transfers the multilayer effect color-changing layer to the upper surface of the TPU substrate layer from the PET film in a high-temperature laminating and attaching mode at the temperature of 150-200 ℃.
The TPU substrate layer is attached with the anti-sticking layer and the protective layer according to the mode, and the automobile clothing product is completed.
The produced car cover not only has a special electroplating gray effect in the market, but also has excellent mechanical properties, no yellowing and better construction performance.
Example 3
The scheme provides a manufacturing process for a car cover with a rose gold electroplated TPU effect and a color changed effect, which comprises the following steps:
forming a TPU substrate layer, wherein the raw material formula is as follows: 90 parts of thermoplastic aliphatic polyurethane elastomer system, 2 parts of slipping agent and 1 part of transparent master batch. Uniformly mixing the raw materials of the TPU substrate layer, drying the mixture for 2 hours at 80 ℃ of a blast drier, raising the temperature of each zone of a machine barrel of the composite extruder to 158 ℃ of a first zone of the machine barrel, 168 ℃ of a second zone of the machine barrel, 170 ℃ of a third zone of the machine barrel, 150 ℃ of a screen changing zone 1, 170 ℃ of a screen changing zone 2, 180 ℃ of a first zone of a die head, 180 ℃ of a second zone of the die head, 180 ℃ of a third zone of the die head, 190 ℃ of a die head connecting zone and 220 ℃ of a die head mold, adding raw material particles for fusion and plasticization, extruding and casting through a casting mold with a gap of 120 mu m, continuously calendering through.
Then, a PET film is used as a carrier in a scraper type coating machine, a 25-micron PU printing ink layer is coated on 55 parts of solid resin, 20 parts of dimethyl formamide, 10 parts of methyl ethyl ketone, 10 parts of ethyl acetate, 1.5 parts of fluorescent red pigment, 1.5 parts of gold powder, 2 parts of aluminum silver paste and 0.5 part of clear red paste according to the formula of raw materials, the PU printing ink layer enters a drying tunnel at the temperature of 50-100 ℃ for drying, then a 30-micron PU printing ink layer is coated on the PU printing ink layer and comprises 60 parts of solid resin, 50 parts of dimethyl formamide, 30 parts of white paste, 1 part of cyan-red paste, 0.6 part of medium yellow paste and 2 parts of wetting promoting agent, and the PU printing ink layer is also subjected to high-temperature laminating and attaching mode after drying in the drying tunnel at the temperature of 150-200 ℃ at the temperature of 50-100 ℃ so as to transfer the multi-.
The TPU substrate layer is attached with the anti-sticking layer and the protective layer according to the mode, and the automobile clothing product is completed.
The produced car cover provides a color-changing layer with multiple effects of fluorescence, electroplating, extinction and the like, and the appearance of the car cover has no phenomena of pits, pocks, orange peel lines, bubbling and the like, and has obvious color-increasing effect on the appearance of a car.
Example 4
This scheme provides a radium-shine gold TPU effect changes preparation technology of look car clothing, specifically as follows:
forming a TPU substrate layer, wherein the raw material formula is as follows: 90 parts of thermoplastic aliphatic polyurethane elastomer system, 3 parts of slipping agent and 1 part of transparent master batch. Uniformly mixing the raw materials of the TPU substrate layer, drying the mixture for 2 hours at 80 ℃ of a blast drier, raising the temperature of each zone of a machine barrel of the composite extruder to 160 ℃ of a first zone of the machine barrel, 170 ℃ of a second zone of the machine barrel, 170 ℃ of a third zone of the machine barrel, 170 ℃ of a screen changing zone 1, 160 ℃ of a screen changing zone 2, 180 ℃ of a first zone of a die head, 180 ℃ of a second zone of the die head, 180 ℃ of a third zone of the die head, 200 ℃ of a die head connecting zone and 210 ℃ of a die head mold, adding raw material particles for fusion and plasticization, extruding and casting through a casting mold with a gap of 120 mu m, continuously calendering through.
Then, a PET film is used as a carrier in a scraper type coating machine, a PU printing ink with the thickness of 25 microns is coated on 0.5 part of laser powder according to the formula of raw materials of 60 parts of solid resin, 40 parts of dimethyl formamide, and after the PU printing ink enters a drying tunnel at the temperature of 50-100 ℃ and is dried, a PU printing ink system with the thickness of 40 microns is coated on the PU printing ink and comprises 60 parts of solid resin, 40 parts of dimethyl formamide, 20 parts of methyl ethyl ketone, 3 parts of aluminum silver paste, 5 parts of medium yellow color paste, 0.7 part of clear red, 0.5 part of flatting agent and 1 part of wetting agent, and the PU printing ink system is also introduced into the drying tunnel at the temperature of 150-200 ℃ and is dried at the temperature of 50-100 ℃ and then is laminated and attached at the high temperature, so.
After the TPU substrate layer is attached with the anti-sticking layer in the mode, as an optional scheme, a formula of raw materials of an upper multifunctional protective layer is formed: 40 parts of dimethyl octyl acrylate, 60 parts of functional group urethane acrylic copolymer film-forming aid, 30 parts of methyl isobutyl ketone, 30 parts of butyl acetate and 0.5 part of light-induced reaction accelerator.
Wherein the photoinitiator is one or more of 184, 659, 1173, 754, 379, MBF and TPO which are not yellowed.
And coating the prepared raw materials on the other surface of the TPU substrate directly through roller coating construction, drying the TPU substrate through a drying tunnel at 50-100 ℃, attaching PET release paper, curing the PET release paper under the irradiation of a UV lamp, and then delivering the cured TPU release paper into a constant-temperature room at 60 ℃ for curing for at least 72 hours to finish the automobile clothing product.
Wherein, the UV curing uses an ultraviolet curing machine, the curing time is 8-16 seconds, and the ultraviolet intensity is 800-1000W.
The multifunctional coating is a UV curing coating, an acrylic acid system is taken as a main body to perform chemical crosslinking reaction under the irradiation of ultraviolet light, the shrinkage rate is relatively mild, the surface of the coating has no shrinkage cavity phenomenon, and meanwhile, the introduction of a photoinitiator leads to the improvement of reaction efficiency and production efficiency.
Example 5
This scheme provides a chameleon TPU effect changes preparation technology of look car clothing, specifically as follows:
forming a TPU substrate layer, wherein the raw material formula is as follows: 80 parts of thermoplastic aliphatic polyurethane elastomer system, 1 part of slipping agent and 0.5 part of transparent master batch. Uniformly mixing the raw materials of the TPU substrate layer, drying the mixture for 2 hours at 80 ℃ of a blast drier, raising the temperature of each zone of a machine barrel of the composite extruder to 158 ℃ of a first zone of the machine barrel, 168 ℃ of a second zone of the machine barrel, 170 ℃ of a third zone of the machine barrel, 150 ℃ of a screen changing zone 1, 170 ℃ of a screen changing zone 2, 180 ℃ of a first zone of a die head, 180 ℃ of a second zone of the die head, 180 ℃ of a third zone of the die head, 190 ℃ of a die head connecting zone and 220 ℃ of a die head mold, adding raw material particles for fusion and plasticization, extruding and casting through a casting mold with a gap of 120 mu m, continuously calendering through.
The anti-sticking layer is attached to the TPU substrate layer in the mode, then a PET film is used as a carrier in a scraper type coating machine, 60 parts of solid resin, 40 parts of dimethyl formamide, 5 parts of methyl ethyl ketone and 3 parts of color-changing pearlescent pigment are coated with 25-micron PU printing ink according to a raw material formula, the PU printing ink enters a drying channel with the temperature of 50-100 ℃ for drying, then a PU printing ink system with the thickness of 25-micron and comprising 50 parts of solid resin, 50 parts of dimethyl formamide, 10 parts of black paste, 2 parts of flatting agent and 3 parts of wetting agent is coated, and the PU printing ink system is also subjected to high-temperature laminating attachment after drying in the drying channel with the temperature of 150-200 ℃ at 50-100 ℃ so as to transfer the multi-layer effect color-changing layer to the upper surface of.
The TPU substrate layer is attached with the anti-sticking layer and the protective layer according to the mode, and the automobile clothing product is completed.
Example 6
The scheme provides a manufacturing process of a pearlescent TPU (thermoplastic polyurethane) effect color-changed car cover, which specifically comprises the following steps:
forming a TPU substrate layer, wherein the raw material formula is as follows: 86 parts of thermoplastic aliphatic polyurethane elastomer system, 1 part of slipping agent and 2 parts of transparent master batch. Uniformly mixing the raw materials of the TPU substrate layer, drying the mixture for 2 hours at 80 ℃ of a blast drier, raising the temperature of each zone of a machine barrel of the composite extruder to 158 ℃ of a first zone of the machine barrel, 168 ℃ of a second zone of the machine barrel, 170 ℃ of a third zone of the machine barrel, 150 ℃ of a screen changing zone 1, 170 ℃ of a screen changing zone 2, 180 ℃ of a first zone of a die head, 180 ℃ of a second zone of the die head, 180 ℃ of a third zone of the die head, 190 ℃ of a die head connecting zone and 220 ℃ of a die head mold, adding raw material particles for fusion and plasticization, extruding and casting through a casting mold with a gap of 120 mu m, continuously calendering through.
Then, taking PP fog face paper as a carrier in a scraper type coating machine, coating a layer of PU ink with the thickness of 25um on the PP fog face paper according to the raw material formula of 60 parts of solid resin, 40 parts of dimethyl formamide, 10 parts of methyl ethyl ketone, 35 parts of white slurry, 0.7 part of clear red slurry and 0.5 part of medium yellow, drying the PU ink in a drying tunnel at the temperature of 50-100 ℃, coating a PU ink system with the thickness of 25um on the PU ink system with the thickness of 60 parts of solid resin, 40 parts of dimethyl formamide, 1 part of white pearlescent effect pigment and 3 parts of wetting agent promoting agent, and transferring the multilayer effect color-changing layer from the PET film to the lower surface of the TPU substrate layer in a high-temperature laminating and attaching mode after drying the PU ink in the drying tunnel at the temperature of 50-100 ℃.
The TPU substrate layer is attached with the anti-sticking layer and the protective layer according to the mode, and the automobile clothing product is completed.
The invention uses mechanical equipment with high precision and simple operation, and can better ensure the thickness uniformity and good appearance of coating.
By detecting and analyzing the car cover of the embodiment, the car cover can be obtained
TABLE 1 TPU automotive vehicle cover product properties produced by the present invention
TABLE 2 appearance Properties of TPU automotive coatings produced according to the invention
The performance contrast in the surface can be obtained, and the protective film produced by using the protective film provided by the invention has the outstanding advantages in performance indexes such as construction performance and weather resistance, and also has the special car cover coloring effect in the market in surface smoothness and surface effect.
It should be understood that the above-described embodiments of the present invention are merely examples for clearly illustrating the present invention, and are not intended to limit the embodiments of the present invention. Other variations and modifications will be apparent to persons skilled in the art in light of the above description. And are neither required nor exhaustive of all embodiments. Any modification, equivalent replacement, and improvement made within the spirit and principle of the present invention should be included in the protection scope of the claims of the present invention.
Claims (10)
1. The utility model provides a TPU effect changes look car clothing, a serial communication port, the TPU effect changes look car clothing and includes inoxidizing coating, multilayer effect change colour layer, TPU transparent base layer, bond line, inoxidizing coating, multilayer effect change colour layer, TPU transparent base layer, bond line from the top down set gradually, the inoxidizing coating includes from type inoxidizing coating and multi-functional inoxidizing coating, TPU transparent base layer wherein the one side is equipped with one deck multilayer effect at least and changes the colour layer, and the bond line includes glue layer and antiseized layer.
2. The TPU effect color changing car cover of claim 1, wherein the release protective layer and the release layer are made of random copolymerized PET, the multifunctional protective layer is made of a polyacrylate system, the multi-layer effect color changing layer is made of a PU ink system, the substrate layer is made of a polyether-polyester copolymer or a thermoplastic aliphatic polyurethane elastomer system, and the glue layer is made of a pressure sensitive adhesive of a polyacrylate system.
3. The TPU effect color changing car cover according to claim 2, wherein the multifunctional protective layer is made of a polyacrylate system and comprises the following components: 30-50 parts of dimethyl octyl acrylic acid, 40-60 parts of difunctional poly urethane acrylic acid copolymer film-forming aid, 20-30 parts of methyl isobutyl ketone, 20-30 parts of butyl acetate and 0.4-0.6 part of adhesion promoter.
4. The TPU effect color change car cover of claim 2 wherein the multi-layer effect color change layer is made from a PU ink system having the components: 50-60 parts of solid resin, 30-60 parts of dimethylformamide, 5-40 parts of methyl ethyl ketone, 1-40 parts of solid pigment, 0.5-10 parts of functional material powder and 0.5-5 parts of wetting accelerator.
5. The TPU effect color changing car cover according to claim 4, wherein the solid resin is one or more of 60-90A polyether-polyester copolymer, polyester aliphatic TPU, and polyether aliphatic TPU.
6. The TPU effect color changing car cover according to claim 4, wherein the functional material powder can be one or more of pearl powder, fluorescent powder, noctilucent powder, temperature change powder, light change powder, reflective powder, extinction powder, silver paste, color change powder, laser powder and the like.
7. The TPU effect color modified car cover of claim 2 wherein the TPU substrate layer is made from a polyether-polyester copolymer or thermoplastic aliphatic polyurethane elastomer system having the composition: 80-90 parts of polyether-polyester copolymer with the hardness of 80-95A or thermoplastic aliphatic polyurethane elastomer with the hardness of 85-95A, 1-7 parts of slipping agent and 0.5-2 parts of transparent master batch.
8. The TPU effect color changing car cover according to claim 2, wherein the glue layer is made from a polyacrylate system to a pressure sensitive adhesive having the composition: 30-40 parts of polyacrylate, 25 parts of toluene, 30-40 parts of ethyl acetate and 0.5 part of an appropriate amount of oligomeric silane coupling agent.
9. The TPU effect color changing car cover according to claim 1, wherein the thickness of the release protective layer is 0.025-0.08mm, the thickness of the multifunctional protective layer is 0.01-0.05mm, the thickness of the multilayer effect color changing layer is 0.015-0.08mm, the thickness of the TPU transparent base layer is 0.05-0.3mm, the thickness of the glue layer is 0.01-0.05mm, and the thickness of the anti-sticking layer is 0.05-0.3 mm.
10. A preparation process of a TPU effect color-changed car cover is characterized by comprising the following steps:
step 1: forming a TPU transparent base layer: preparing materials according to a formula, and then melting, extruding, calendering and molding all the materials at the temperature of 160-200 ℃ to form a TPU substrate layer with the thickness of 0.12 mm;
step 2: forming an upper or lower multi-layer effect color-changing layer: preparing raw materials according to a formula, uniformly mixing the raw materials through a reaction kettle to prepare a multi-layer effect color changing layer, and coating a PET film and PP paper as transfer;
and step 3: film transfer: laminating and adhering a PET film or PP paper bearing the multilayer effect color modifying layer to the TPU transparent base layer at a high temperature of 150-200 ℃ in a full-dry mode;
and 4, step 4: a lower glue layer was formed: preparing materials according to a formula, uniformly mixing to prepare a self-crosslinking pressure-sensitive adhesive, and coating the self-crosslinking pressure-sensitive adhesive on a PET film for transfer;
and 5: forming an adhesive layer: bonding the lower glue layer to the lower surface of the TPU transparent base layer or the multi-layer effect color-changing layer in a semi-dry normal-temperature laminating mode;
step 6: forming an upper multifunctional protective layer: preparing materials according to a formula, and blending AB dual components according to a proportion, wherein the component A is mainly polyacrylate copolymer, the component B contains a urethane curing component, the urethane curing component is coated on a filter screen for filtering, and then is directly coated on a PET release film through roll coating construction, and then is directly attached to the upper surface of a TPU layer or a multi-layer effect layer;
and 7: forming a protective layer: drying at 50-100 ℃, then delivering the obtained product into a constant temperature room at 60 ℃ for curing for at least 48 hours, and finishing the protective layer after the raw materials are cured to finish the preparation of the TPU effect color-changed car cover.
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Cited By (3)
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| CN115806778A (en) * | 2022-12-07 | 2023-03-17 | 辽宁弗佰克高新材料有限公司 | Automobile color film capable of replacing automobile paint and preparation method and application thereof |
| CN115820147A (en) * | 2022-07-18 | 2023-03-21 | 常州山由帝杉防护材料制造有限公司 | Paint surface protective film with color changing effect, preparation method and application thereof |
| CN116333618A (en) * | 2022-11-28 | 2023-06-27 | 云南三恩新能源材料有限公司 | Color-changing car cover and preparation method thereof |
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| CN110218525A (en) * | 2019-06-18 | 2019-09-10 | 宁波市嘉化新材料科技有限公司 | A kind of the invisible vehicle cover protective film and its manufacture craft of TPU substrate |
| CN212051205U (en) * | 2019-12-26 | 2020-12-01 | 浦诺菲新材料有限公司 | Paint surface protective film |
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| CN110218525A (en) * | 2019-06-18 | 2019-09-10 | 宁波市嘉化新材料科技有限公司 | A kind of the invisible vehicle cover protective film and its manufacture craft of TPU substrate |
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Cited By (3)
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| CN115820147A (en) * | 2022-07-18 | 2023-03-21 | 常州山由帝杉防护材料制造有限公司 | Paint surface protective film with color changing effect, preparation method and application thereof |
| CN116333618A (en) * | 2022-11-28 | 2023-06-27 | 云南三恩新能源材料有限公司 | Color-changing car cover and preparation method thereof |
| CN115806778A (en) * | 2022-12-07 | 2023-03-17 | 辽宁弗佰克高新材料有限公司 | Automobile color film capable of replacing automobile paint and preparation method and application thereof |
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