CN112940030B - 一种微波辅助萃取偏光膜中环保型无卤阻燃剂的方法 - Google Patents
一种微波辅助萃取偏光膜中环保型无卤阻燃剂的方法 Download PDFInfo
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- CN112940030B CN112940030B CN202110207854.7A CN202110207854A CN112940030B CN 112940030 B CN112940030 B CN 112940030B CN 202110207854 A CN202110207854 A CN 202110207854A CN 112940030 B CN112940030 B CN 112940030B
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 title claims abstract description 19
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 title claims abstract description 13
- 238000000605 extraction Methods 0.000 claims abstract description 51
- 239000002904 solvent Substances 0.000 claims abstract description 22
- 239000000047 product Substances 0.000 claims abstract description 17
- 239000002699 waste material Substances 0.000 claims abstract description 17
- 239000000706 filtrate Substances 0.000 claims abstract description 16
- 238000000874 microwave-assisted extraction Methods 0.000 claims abstract description 13
- 238000001704 evaporation Methods 0.000 claims abstract description 12
- 238000007789 sealing Methods 0.000 claims abstract description 4
- 238000007873 sieving Methods 0.000 claims abstract description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 30
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- 239000004973 liquid crystal related substance Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 4
- 238000002390 rotary evaporation Methods 0.000 claims description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 12
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 11
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 11
- 239000011574 phosphorus Substances 0.000 abstract description 11
- 238000004064 recycling Methods 0.000 abstract description 4
- 238000000967 suction filtration Methods 0.000 abstract 1
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 24
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 13
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 11
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 238000007865 diluting Methods 0.000 description 7
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000012043 crude product Substances 0.000 description 6
- 238000000944 Soxhlet extraction Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 3
- 229920002284 Cellulose triacetate Polymers 0.000 description 2
- 238000004566 IR spectroscopy Methods 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
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- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
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- 229910019142 PO4 Inorganic materials 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
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- 230000000593 degrading effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- -1 electronics Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
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- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
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- 238000000194 supercritical-fluid extraction Methods 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/12—Esters of phosphoric acids with hydroxyaryl compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/02—Solvent extraction of solids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/02—Solvent extraction of solids
- B01D11/0207—Control systems
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
- B01J19/122—Incoherent waves
- B01J19/126—Microwaves
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
- C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Electromagnetism (AREA)
- Automation & Control Theory (AREA)
- Toxicology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Extraction Or Liquid Replacement (AREA)
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CN202110207854.7A CN112940030B (zh) | 2021-02-25 | 2021-02-25 | 一种微波辅助萃取偏光膜中环保型无卤阻燃剂的方法 |
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CN202110207854.7A CN112940030B (zh) | 2021-02-25 | 2021-02-25 | 一种微波辅助萃取偏光膜中环保型无卤阻燃剂的方法 |
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Citations (8)
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CN101407596A (zh) * | 2008-09-25 | 2009-04-15 | 上海第二工业大学 | 从废弃印刷线路板的非金属粉末中回收环氧树脂和玻璃纤维的方法 |
CN101982551A (zh) * | 2010-11-26 | 2011-03-02 | 上海第二工业大学 | 一种利用微生物资源化回收废弃pdp玻璃上有价金属的方法 |
US8192590B1 (en) * | 2008-04-14 | 2012-06-05 | University Of Central Florida Research Foundation, Inc. | Microwave-assisted formation of sulfonium photoacid generators |
CN102847503A (zh) * | 2011-06-30 | 2013-01-02 | Cem公司 | 用于执行自动微波辅助反应的设备及其方法 |
CN104272147A (zh) * | 2012-05-01 | 2015-01-07 | 柯尼卡美能达株式会社 | 相位差膜、偏振片的制造方法及液晶显示装置 |
CN108469482A (zh) * | 2018-03-22 | 2018-08-31 | 中华人民共和国汕头出入境检验检疫局检验检疫技术中心 | 一种gc-ms同时测定pvc中的磷系和溴系阻燃剂的方法 |
WO2020232970A1 (zh) * | 2019-05-17 | 2020-11-26 | 江南大学 | 一种测定肠道内容物或粪便中短链脂肪酸含量的方法 |
AU2020103864A4 (en) * | 2020-12-03 | 2021-02-11 | Xuzhou University Of Technology | A method for preparing Arctium lappa L Polyphenol by compound enzyme treatment combined with ultrasonic flash extraction |
Family Cites Families (1)
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CN100398584C (zh) * | 2002-10-18 | 2008-07-02 | 富士胶片株式会社 | 过滤和生产聚合物溶液的方法和制备溶剂的方法 |
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- 2021-02-25 CN CN202110207854.7A patent/CN112940030B/zh active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8192590B1 (en) * | 2008-04-14 | 2012-06-05 | University Of Central Florida Research Foundation, Inc. | Microwave-assisted formation of sulfonium photoacid generators |
CN101407596A (zh) * | 2008-09-25 | 2009-04-15 | 上海第二工业大学 | 从废弃印刷线路板的非金属粉末中回收环氧树脂和玻璃纤维的方法 |
CN101982551A (zh) * | 2010-11-26 | 2011-03-02 | 上海第二工业大学 | 一种利用微生物资源化回收废弃pdp玻璃上有价金属的方法 |
CN102847503A (zh) * | 2011-06-30 | 2013-01-02 | Cem公司 | 用于执行自动微波辅助反应的设备及其方法 |
CN104272147A (zh) * | 2012-05-01 | 2015-01-07 | 柯尼卡美能达株式会社 | 相位差膜、偏振片的制造方法及液晶显示装置 |
CN108469482A (zh) * | 2018-03-22 | 2018-08-31 | 中华人民共和国汕头出入境检验检疫局检验检疫技术中心 | 一种gc-ms同时测定pvc中的磷系和溴系阻燃剂的方法 |
WO2020232970A1 (zh) * | 2019-05-17 | 2020-11-26 | 江南大学 | 一种测定肠道内容物或粪便中短链脂肪酸含量的方法 |
AU2020103864A4 (en) * | 2020-12-03 | 2021-02-11 | Xuzhou University Of Technology | A method for preparing Arctium lappa L Polyphenol by compound enzyme treatment combined with ultrasonic flash extraction |
Non-Patent Citations (1)
Title |
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热解及超临界水处理废弃液晶面板偏光片的反应机理;王瑞雪等;环境化学;第39卷(第06期);1642-1649 * |
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