CN112919424B - O (O) 3 High-energy active oxygen preparing device - Google Patents

O (O) 3 High-energy active oxygen preparing device Download PDF

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Publication number
CN112919424B
CN112919424B CN202110336315.3A CN202110336315A CN112919424B CN 112919424 B CN112919424 B CN 112919424B CN 202110336315 A CN202110336315 A CN 202110336315A CN 112919424 B CN112919424 B CN 112919424B
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CN
China
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net
ring group
magnetic ring
rare earth
titanium alloy
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CN202110336315.3A
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CN112919424A (en
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崔金福
罗月月
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Zhejiang Free Trade Zone Chentongtai Energy Conservation And Environmental Protection Technology Co ltd
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Zhejiang Free Trade Zone Chentongtai Energy Conservation And Environmental Protection Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/10Preparation of ozone
    • C01B13/11Preparation of ozone by electric discharge
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2201/00Preparation of ozone by electrical discharge
    • C01B2201/10Dischargers used for production of ozone
    • C01B2201/14Concentric/tubular dischargers
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2201/00Preparation of ozone by electrical discharge
    • C01B2201/20Electrodes used for obtaining electrical discharge
    • C01B2201/22Constructional details of the electrodes
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2201/00Preparation of ozone by electrical discharge
    • C01B2201/60Feed streams for electrical dischargers
    • C01B2201/62Air
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2201/00Preparation of ozone by electrical discharge
    • C01B2201/80Additional processes occurring alongside the electrical discharges, e.g. catalytic processes
    • C01B2201/84Treatment with magnetic fields

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Catalysts (AREA)

Abstract

O (O) 3 The high-energy active oxygen preparation device comprises a cylindrical main body, wherein an air inlet is formed in the top of the main body, a bypass type negative electrode net barrel is arranged in the main body, an active catalytic net is arranged in the bypass type negative electrode net barrel, a rare earth magnetic ring group is arranged in the active catalytic net, a high-voltage positive electrode discharge needle is arranged above the active catalytic net, a quartz glass tube is arranged in the rare earth magnetic ring group, a titanium alloy inner discharge net is arranged on the inner side of the quartz glass tube, and a titanium alloy outer discharge net is arranged on the outer side of the quartz glass tube. The invention can treat the air under the double functions of the magnetic field and the electric field to ensure that the air contains 3 to 5 percent of O 3 Equivalent O of 3 The cost of the invention is far lower than that of the electrolytic oxygen on the premise of the production, and the air contains 3-5% of O on the basis of 20-25% of oxygen of oil 3 The combustion-supporting agent has the functions of supporting combustion, sterilizing, catalyzing and the like, reduces the maintenance cost and the operation cost, and is convenient for O 3 Is widely popularized and applied.

Description

O (O) 3 High-energy active oxygen preparing device
Technical Field
The invention belongs to O 3 The field of high-energy active oxygen production, in particular to an O 3 High-energy active oxygen preparing device.
Background
Ozone, i.e. O 3 With the discovery of ozone, the application of ozone has been widely studied, due to O 3 Has strong oxidability and is widely applied to the fields of catalysts, combustion air, disinfectants and the like, but the current ozone production method is to ionize oxygen to generate O 3 The production cost is higher, thus affecting O 3 Is widely used.
Disclosure of Invention
The invention provides an O 3 The high-energy active oxygen preparing device is used for solving the defects in the prior art.
The invention is realized by the following technical scheme:
o (O) 3 The high-energy active oxygen preparation device comprises a cylindrical main body, wherein the main body is fixed with clamping and fixing insulating plates at two sides through fixing bolts, an air inlet is formed in the top of the main body, a duct type negative electrode net barrel is arranged in the main body, an active catalytic net is arranged in the duct type negative electrode net barrel, a rare earth magnetic ring group is arranged in the active catalytic net, and the active catalytic net is arranged in the active catalytic netThe upper side set up high-voltage positive electrode discharge needle, high-voltage positive electrode discharge needle be connected with first positive electrode connecting wire, the first negative electrode connecting wire of a duct formula negative electrode net section of thick bamboo connection connect, the rare earth magnetic ring group in set up quartz glass tube, quartz glass tube inboard set up the interior discharge network of titanium alloy, quartz glass tube outside set up the outer discharge network of titanium alloy, the outer discharge network of titanium alloy with the second positive electrode connecting wire, the interior discharge network of titanium alloy with the second negative electrode connecting wire, the lower part of main part set up O 3 High energy fluid outlet.
One of the above O 3 The high-energy active oxygen preparing device is characterized in that the rare earth magnetic ring group is connected with the main body through a permanent magnetic ring group fixing and adjusting bolt.
One of the above O 3 The high-energy active oxygen preparation device is characterized in that an insulation shunt plug is arranged at the top of the rare earth magnetic ring group, the insulation shunt plug is fixedly connected with the rare earth magnetic ring group through a permanent magnetic ring group fixing and adjusting bolt, and the insulation shunt plug is connected with a high-voltage positive electrode discharge needle through a high-voltage positive electrode discharge needle fixing bolt.
One of the above O 3 The high-energy active oxygen preparing device is characterized in that the active catalytic net is coated with Ce and Pt on the surface.
One of the above O 3 The high-energy active oxygen preparing device is characterized in that the active catalytic net is coated with Ce and Pt on the surface.
One of the above O 3 The high-energy active oxygen preparing device is characterized in that the active catalytic net is coated with Ce and Pt on the surface.
The invention has the advantages that: the invention can treat the air under the double functions of the magnetic field and the electric field to ensure that the air contains 3 to 5 percent of O 3 Although not prepared as pure O 3 But the raw material is air, which is equal to O 3 The cost of the invention is far lower than that of the electrolytic oxygen on the premise of the production, and the air contains 3-5% of O on the basis of 20-25% of oxygen of oil 3 The combustion-supporting agent has the functions of supporting combustion, sterilizing, catalyzing and the like, reduces the maintenance cost and the operation cost, and is convenient for O 3 Is widely popularized and applied.When the invention is used, air is introduced into the main body from the air inlet and reaches a high-frequency pulse discharge area formed by a high-voltage positive electrode discharge needle and a duct type negative electrode net barrel, a first positive electrode connecting wire and a first negative electrode connecting wire are connected with a high-frequency pulse discharger to supply power, the air inlet is subjected to electron bombardment to form an unbalanced plasma state (a fourth state of a substance), and the duct type negative electrode net barrel is connected with a negative electrode to form a barrel-shaped negative electrode net around a rare earth magnetic ring group which is smelted and synthesized by rare earth permanent magnet neodymium iron boron, and has a strong magnetic field which is opposite to O 2 The O, e _spin and other paramagnetic gas substances have affinity for aggregation, and the bypass type negative electrode net barrel has affinity for positive electrons in ionized gas, so that positive and negative ions and paramagnetic substances in ionized plasma gas are affinity-attracted and separated in a magnetic and electric double-field effect environment of a bypass type negative electrode net barrel electric field and a rare earth magnetic ring group magnetic field. The rare earth magnetic ring group adopts N groups of homopolar opposite arrangement, and because homopolar repulsive magnetic rings and magnetic rings form external thrust in the screw positioning of the permanent magnet ring group fixed adjusting screw, self-forming elastic gaps are formed, and the size gap adjusting effect of the magnetic group is completed through adjusting the screw cap. Meanwhile, an insulating shunt plug is arranged at the end, facing the air inlet, of the rare earth magnetic ring group, and is used for sealing and shunting the middle channel of the rare earth magnetic ring group, and pole separation and retention are carried out between the rare earth magnetic ring group and the duct type negative electrode net barrel by evenly shunting the inlet gas. The periphery of the rare earth magnetic ring group is wound with active catalytic nets plated with Ce and Pt, and because of being plated with active noble metal catalyst, the Ce element has the oxygen storage and release capacity, and at the same time, the inner channel of the rare earth magnetic ring group is equipped with dielectric barrier discharge effect formed from quartz glass tube, titanium alloy inner discharge net and titanium alloy outer discharge net, so that the rare earth magnetic ring group is attracted and gathered to be O, O 2 The gas is converted into O through the dielectric barrier effect 3 And oxygen+ (13, 16, 18) and other strong oxidation active substances, so that the substances lose paramagnetism, and are separated from the magnetic curtain field region of the rare earth magnetic ring group to complete deactivation, and meanwhile, because of O 3 And substances such as oxygen and the like are strong oxidation active gases, so that the combustion-supporting agent can effectively improve the efficiency and optimize the combustion.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions of the prior art, the drawings that are needed in the embodiments or the description of the prior art will be briefly described below, it will be obvious that the drawings in the following description are some embodiments of the present invention, and that other drawings can be obtained according to these drawings without inventive effort to a person skilled in the art.
Fig. 1 is a schematic diagram of the structure of the present invention.
Reference numerals: 1. a main body; 2. a fixing bolt; 3. clamping and fixing an insulating plate; 4. an air inlet; 5. a bypass type negative electrode net barrel; 6. an active catalytic web; 7. a rare earth magnetic ring group; 8. a high voltage positive electrode discharge needle; 9. a first positive electrode connection line; 10. a first negative electrode connection line; 11. a quartz glass tube; 12. discharging a power grid in the titanium alloy; 13. a titanium alloy external discharge grid; 14. a second positive electrode connection line; 15. a second negative electrode connection line; 16. o (O) 3 A high energy fluid outlet; 17. fixing an adjusting bolt by the permanent magnet ring set; 18. an insulation shunt plug; 19. high-voltage positive electrode discharge needle fixing bolts.
Detailed Description
For the purpose of making the objects, technical solutions and advantages of the embodiments of the present invention more apparent, the technical solutions of the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention, and it is apparent that the described embodiments are some embodiments of the present invention, but not all embodiments of the present invention. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
O (O) 3 The high-energy active oxygen preparation device comprises a cylindrical main body 1, wherein the main body 1 is fixed with clamping fixed insulating plates 3 on two sides through fixing bolts 2, an air inlet 4 is formed in the top of the main body 1, a bypass type negative electrode net barrel 5 is arranged in the main body 1, an active catalytic net 6 is arranged in the bypass type negative electrode net barrel 5, a rare earth magnetic ring group 7 is arranged in the active catalytic net 6, a high-voltage positive electrode discharge needle 8 is arranged above the active catalytic net 6, and the high-voltage positive electrode is arranged on the high-voltage positive electrode discharge needle 8The electrode discharge needle 8 is connected with a first positive electrode connecting wire 9, the bypass type negative electrode net barrel 5 is connected with a first negative electrode connecting wire 10, a quartz glass tube 11 is arranged in the rare earth magnetic ring group 7, a titanium alloy inner discharge net 12 is arranged on the inner side of the quartz glass tube 11, a titanium alloy outer discharge net 13 is arranged on the outer side of the quartz glass tube 11, the titanium alloy outer discharge net 13 is connected with a second positive electrode connecting wire 14, the titanium alloy inner discharge net 12 is connected with a second negative electrode connecting wire 15, and O is arranged on the lower portion of the main body 1 3 A high energy fluid outlet 16.
Preferably, the rare earth magnetic ring group 7 is connected with the main body through a permanent magnetic ring group fixing and adjusting bolt 17.
Preferably, an insulation shunt plug 18 is arranged at the top of the rare earth magnetic ring group 7, the insulation shunt plug 18 is fixedly connected with the rare earth magnetic ring group 7 through a permanent magnetic ring group fixing and adjusting bolt 17, and the insulation shunt plug 18 is connected with the high-voltage positive electrode discharge needle 8 through a high-voltage positive electrode discharge needle fixing bolt 19.
Preferably, the active catalytic net 6 is coated with Ce and Pt on the surface.
Preferably, the main body is O 3 The high-energy active oxygen flow is used for combustion supporting or sewage aeration, so that the efficiency can be improved, and the fuel or the running electricity consumption can be saved.
Preferably, the air inlet is provided with a common air pressure feeding device through a fan, so that the main body has continuous raw material air feeding and is processed and manufactured.
Preferably, the high-voltage positive electrode discharge needle is combined with the bypass type negative electrode net barrel to form a high-voltage tip discharge area, pulse tip discharge is continuously formed, and the air inlet is used for air bombardment ionization to form an unbalanced plasma state.
Preferably, the bypass type negative electrode net barrel is a honeycomb hole type bypass round barrel made of 304 stainless steel, and is connected with a first negative electrode connecting wire to form a negative electrode induced aggregation net, and the negative electrode induced aggregation net is used as a main body total support frame and has a negative electrode electric field effect, so that positive electrons in ionized air are affine induced aggregation and separated from honeycomb holes in a shunting way, and pole separation is completed.
Preferably, the first positive electrode connecting wire is used for connecting and conveying pulse current released by the high-voltage discharger to the high-voltage positive electrode discharging needle to enable the high-voltage positive electrode discharging needle to work, generating pulse electric waves and forming a pulse discharging area in cooperation with the bypass type negative electrode net barrel.
Preferably, the first negative electrode connecting wire is connected with a bypass type negative electrode net barrel to lead the pulse current released by the high-voltage positive electrode discharge needle to form a loop.
Preferably, the insulating shunt plug is mainly used for sealing and blocking the air inlet of the rare earth magnetic ring group channel, and simultaneously, the air inlet is supplied into the ionized air flow for uniform separation, so that the ionized air flow is uniformly distributed in the gap between the bypass type negative electrode net barrel and the rare earth magnetic ring group in the magnetoelectric field region.
Preferably, the active catalytic nets plated with Ce and Pt have the functions of oxygen storage and oxygen release, the Pt has excellent conductivity and thermal activity, and two noble metals are plated on a stainless steel net body to form the catalytic net, so that a large amount of negative electrons can be attracted in the process of being activated by a magnetic field and an electric field, the magnetic field induced gathering force is increased, and meanwhile, the active catalytic net is activated by the electric field to generate an activation effect to attract electrons to be activated and released.
Preferably, the rare earth magnetic ring group is formed into multi-dimensional magnetic curtain fields with different sizes by arranging a plurality of magnetic rings homopolar in a relative way, fixing and fixing the permanent magnetic ring group by fixing and adjusting screws, adjusting gaps by adjusting the screws on the permanent magnetic ring group fixing and adjusting screws, and adsorbing and gathering paramagnetic molecules and atoms in the ionized gas.
Preferably, the quartz glass tube is blocked, namely, a titanium alloy inner discharge net and a titanium alloy outer discharge net are blocked, so that two discharge electrodes form a dielectric blocking effect and are inserted into a middle channel of a rare earth magnetic ring group, and paramagnetic gas adsorbed and induced by the rare earth magnetic ring group is discharged and ionized to form O 3 The high energy state is used for losing paramagnetic effect, stimulating activity, smoothly removing magnetic field and sending into O 3 High energy active gas flow outlet completion O 3 And (3) preparing high-energy active oxygen.
Preferably, the titanium alloy inner discharge net is mainly used for high-frequency discharge, is blocked by a blocking quartz glass tube in combination with the titanium alloy outer discharge net to form a dielectric barrier discharge effect, and oxygen in the gas flow is ionized to form O 3 High energy state active gas flow.
Preferably, the titanium alloy outer discharge grid is combined with the titanium alloy inner discharge grid, is blocked by a blocking quartz glass tube, and ionizes the inner channel by airflow to form O 3 High energy active airflow and output application.
Preferably, the insulating board is clamped and fixed, namely the main body device is clamped before the insulating board, so that an early electric and magnetic double-field main body is formed, the insulating effect is achieved, magnetic flux is not generated, the rare earth magnetic ring group of the permanent magnet group does not have magnetic loss, and meanwhile, N groups of units can be integrated to assemble infinite amplifying equipment.
Preferably, the permanent magnet ring group is fixed with an adjusting screw, and the rare earth magnet ring group is penetrated to play a role in fixing and adjusting.
Preferably, the main body is provided with a fixing screw, the main body 1 is fixed on the clamped fixed insulating plate, and N groups of integrated combination can be realized, so that large-scale equipment is formed.
Preferably, O 3 The high-energy active air flow outlet is O made by applying work to rare earth magnetic ring group, quartz glass tube, titanium alloy inner discharge net and titanium alloy outer discharge net 3 High energy activity oxygen flow output and application.
Finally, it should be noted that: the above embodiments are only for illustrating the technical solution of the present invention, and are not limiting; although the invention has been described in detail with reference to the foregoing embodiments, it will be understood by those of ordinary skill in the art that: the technical scheme described in the foregoing embodiments can be modified or some technical features thereof can be replaced by equivalents; such modifications and substitutions do not depart from the spirit and scope of the technical solutions of the embodiments of the present invention.

Claims (3)

1. O (O) 3 High energy active oxygen prepares device, its characterized in that: including tubular main part (1), main part (1) fix with clamping fixed insulation board (3) of both sides through fixing bolt (2), main part (1) top set up air intake (4), main part (1) in set up a duct formula negative pole net section of thick bamboo (5), duct formula negative pole net section of thick bamboo (5) in set up active catalytic net(6) The novel high-voltage anode discharge wire comprises an active catalytic net (6), wherein a rare earth magnetic ring group (7) is arranged in the active catalytic net (6), a high-voltage anode discharge wire (8) is arranged above the active catalytic net (6), the high-voltage anode discharge wire (8) is connected with a first anode connecting wire (9), a functional anode net barrel (5) is connected with a first anode connecting wire (10), a quartz glass tube (11) is arranged in the rare earth magnetic ring group (7), a titanium alloy inner discharge wire (12) is arranged on the inner side of the quartz glass tube (11), a titanium alloy outer discharge wire (13) is arranged on the outer side of the quartz glass tube (11), the titanium alloy outer discharge wire (13) is connected with a second anode connecting wire (14), the titanium alloy inner discharge wire (12) is connected with a second anode connecting wire (15), and O is arranged on the lower portion of a main body (1) 3 A high energy fluid outlet (16);
the rare earth magnetic ring group (7) top set up insulating reposition of redundant personnel end cap (18), insulating reposition of redundant personnel end cap (18) pass through permanent magnetic ring group fixed adjustment bolt (17) and rare earth magnetic ring group (7) fixed connection, insulating reposition of redundant personnel end cap (18) pass through high-voltage positive electrode discharge needle fixing bolt (19) and high-voltage positive electrode discharge needle (8).
2. An O according to claim 1 3 High energy active oxygen prepares device, its characterized in that: the rare earth magnetic ring group (7) is connected with the main body through a permanent magnetic ring group fixing and adjusting bolt (17).
3. An O according to claim 1 3 High energy active oxygen prepares device, its characterized in that: the active catalytic net (6) is coated with Ce and Pt on the surface.
CN202110336315.3A 2021-03-29 2021-03-29 O (O) 3 High-energy active oxygen preparing device Active CN112919424B (en)

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Publication number Priority date Publication date Assignee Title
CN115159762B (en) * 2022-07-15 2023-10-27 北京纳米能源与系统研究所 Electroporation sterilizing water purifying equipment
CN116078127B (en) * 2023-03-03 2023-11-17 浙大城市学院 Dielectric barrier discharge tube with needle electrode cooperated with cylinder multi-channel adsorption catalyst

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