CN112919406B - Solid-state hydrogen source reactor - Google Patents
Solid-state hydrogen source reactor Download PDFInfo
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- CN112919406B CN112919406B CN202110226989.8A CN202110226989A CN112919406B CN 112919406 B CN112919406 B CN 112919406B CN 202110226989 A CN202110226989 A CN 202110226989A CN 112919406 B CN112919406 B CN 112919406B
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0078—Composite solid storage mediums, i.e. coherent or loose mixtures of different solid constituents, chemically or structurally heterogeneous solid masses, coated solids or solids having a chemically modified surface region
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0031—Intermetallic compounds; Metal alloys; Treatment thereof
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0031—Intermetallic compounds; Metal alloys; Treatment thereof
- C01B3/0036—Intermetallic compounds; Metal alloys; Treatment thereof only containing iron and titanium; Treatment thereof
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0031—Intermetallic compounds; Metal alloys; Treatment thereof
- C01B3/0047—Intermetallic compounds; Metal alloys; Treatment thereof containing a rare earth metal; Treatment thereof
- C01B3/0057—Intermetallic compounds; Metal alloys; Treatment thereof containing a rare earth metal; Treatment thereof also containing nickel
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
Abstract
The invention relates to a solid hydrogen source reactor, which adopts a phase-change material to recycle heat in a solid hydrogen storage chemical reaction, can fill heat-conducting particles among metal hydrogen storage material particles after mixing the heat-conducting particles with the metal hydrogen storage material, does not reduce the mass of the metal hydrogen storage material in unit volume, realizes the quick heat conduction of gaps of the metal hydrogen storage material due to the high heat-conducting property of the heat-conducting particles, reduces the temperature gradient of the metal hydrogen storage material, arranges a heat-conducting medium storage tank, utilizes a temperature detection device to detect the temperature to open and close a valve, realizes that high-temperature medium does not enter the solid hydrogen storage tank during hydrogen absorption, and low-temperature medium does not enter the phase-change material heat storage tank during dehydrogenation, further improves the heat exchange efficiency and the stability of hydrogenation and hydrogen discharge.
Description
Technical Field
The invention relates to the field of hydrogen power, in particular to a solid-state hydrogen source reactor.
Background
The use of fossil fuels in large quantities not only aggravates the consumption of traditional energy sources, but also causes severe environmental pollution. The hydrogen energy storage is rich, the combustion heat value is high, and the pollution of the combustion product to the environment is very weak. However, the current restriction factor for realizing large-scale application of hydrogen is mainly that the hydrogen storage technology is immature and hydrogen storage and transportation are difficult to carry out quickly, safely and efficiently. The existing hydrogen storage modes mainly comprise high-pressure gas hydrogen storage, low-temperature liquid hydrogen storage and solid hydrogen storage. Solid hydrogen storage, especially metal hydrogen storage materials, is considered to be one of the most promising hydrogen storage materials due to the characteristics of large energy storage density, small volume, portability and safe and stable generated compounds. The metal hydrogen storage material needs to absorb heat during hydrogen absorption and release heat during hydrogen release, and the heat management of the hydrogen storage reactor is an important factor for improving the hydrogen storage efficiency of the metal hydrogen storage material.
CN108426169B discloses a hydrogen power system based on a heat self-balancing solid hydrogen source reactor, in which the phase change material can store the heat released by the hydrogen absorption reaction in the form of latent heat and release the heat in the hydrogen desorption reaction, so that the heat in the hydrogen absorption process is used in the hydrogen desorption process, thereby saving the heating and cooling device, reducing the cost, improving the utilization rate of energy, and simultaneously improving the speed of the hydrogen absorption and desorption reaction. Although the technology recovers the heat generated in the hydrogen absorption reaction process and stores the heat in a latent heat form, the heat exchange efficiency is low in the mode, and the utilization rate of the heat released by the hydrogen absorption reaction is low. Meanwhile, because the heat utilization rate is low, the heat self-balance is difficult to maintain for a long time. Meanwhile, the solid-state hydrogen source reactor has large particle size of hydrogen storage materials, and is difficult to avoid gaps, so that the temperature in the reactor has local difference, and high-efficiency hydrogen absorption and desorption reactions are difficult to occur.
US20120201719a1 discloses a tank for storing hydrogen and/or heat, wherein a heat storage element is provided, which comprises a spacer embedded in a phase change material. Can play the heat-retaining, exothermic effect in the jar. However, the process is difficult to be automatically controlled, and is a naturally changing process, such as in the hydrogenation heat release process, when the temperature of the phase change material becomes high, the hydrogenation effect is affected, and after the enhancement is finished, if the temperature of the phase change material is still in a high temperature state, the hydrogen release is accelerated, which is not desirable.
Therefore, the solid-state hydrogen storage reactor generally has the problems of low heat exchange efficiency and difficult automation control, and has limitations in practical industrial application.
Disclosure of Invention
In order to overcome the shortcomings of the prior art, the invention provides a solid state hydrogen source reactor.
The technical scheme adopted by the invention is as follows: the solid state hydrogen source reactor comprises: solid-state hydrogen storage tank 1, heat storage tank 2, bidirectional pump 4, heat conduction communicating pipe 5, set up hydrogen storage tank heat pipe 12 in the solid-state hydrogen storage tank 1, set up heat storage tank heat pipe 22 in the heat storage tank 2, hydrogen storage tank heat pipe 12 one end with heat storage tank heat pipe 22 one end is through heat conduction communicating pipe 5 intercommunication, hydrogen storage tank transmission pipe 11 is connected to the hydrogen storage tank heat pipe 12 other end, hydrogen storage tank transmission pipe 11 intercommunication bidirectional pump 4, the heat storage tank heat pipe 22 other end sets up heat storage tank transmission pipe 21, heat storage tank transmission pipe 21 connects bidirectional pump 4, set up metal hydrogen storage material 15 and heat conduction particle 16 in the solid-state hydrogen storage tank 1, set up phase change material 25 in the heat storage tank 2.
Further, the heat conducting particles 16 are one or more of expanded graphite, carbon nanotubes, graphene, and graphene oxide;
Further, the outside of the solid hydrogen storage tank 1 and the heat storage tank 2 are both provided with the heat insulation layer 3;
further, a three-way valve 13 is arranged on the hydrogen storage tank heat conduction pipe 12, and the three-way valve 13 is connected with a hydrogen storage tank heat conduction medium storage tank 14;
further, a heat storage tank three-way valve 23 is arranged on the heat storage tank heat pipe 22, and the heat storage tank three-way valve 23 is connected with a heat storage tank heat-conducting medium storage tank 24;
further, a two-way valve 51 is arranged on the heat conducting communicating pipe;
further, a hydrogenation port and a hydrogen outlet are arranged on the solid hydrogen storage tank 1;
further, in the hydrogenation process, the bidirectional pump 4 drives the heat-conducting medium in the hydrogen storage tank heat-conducting pipe 12 to be conveyed to the heat storage tank transmission pipe 21;
further, a hydrogen storage temperature detection device 52 is disposed on the solid hydrogen storage tank 1 side of the heat conduction pipe communication pipe 5, and a heat storage temperature detection device 53 is disposed on the heat storage tank 2 side of the heat conduction pipe communication pipe 5;
further, in the hydrogen discharging process, the bidirectional pump 4 drives the heat-conducting medium in the heat storage tank heat-conducting pipe 22 to be conveyed into the hydrogen storage tank heat-conducting pipe 12;
further, the hydrogen storage tank heat-conducting pipe 12 and the heat storage tank heat-conducting pipe 22 are one or more of a coil pipe, a coiled pipe and an irregularly-shaped folded pipe;
Further, fins are provided on the hydrogen storage tank heat transfer pipe 12 and the heat storage tank heat transfer pipe 22;
further, the solid-state hydrogen source reactor is also provided with a heating device;
further, the heating device is used for heating the phase change material and/or the heat conducting medium;
further, the metal hydrogen storage material is AB5Type La Ni series, AB type Ti-Fe series2Zirconium-based hydrogen storage hydride, A2B type magnesium-based hydride, A2One or more of type B calcium based hydrides;
further, in the hydrogen discharging process, the bidirectional pump 4 drives the heat-conducting medium in the heat-conducting pipeline to be conveyed into the heat-conducting pipeline in the hydrogen storage tank, and the bidirectional valve (51) is closed; when the temperature A of the heat storage tank temperature detection device 53 and the temperature F of the hydrogen storage temperature detection device 52 meet A > (F + 5), the two-way valve 51 is opened;
further, in the hydrogenation process, the bidirectional pump 4 drives the heat-conducting medium in the heat-conducting pipeline to be conveyed to the heat-conducting pipeline in the heat storage tank, and the bidirectional valve (51) is closed; when the temperature C of the hydrogen storage tank temperature detection means 52 is higher than the temperature D of the heat storage tank temperature detection means 53, the two-way valve 51 is opened.
Compared with the prior art, the invention has the beneficial effects that:
(1) The heat-conducting particles can be filled among the metal hydrogen storage material particles after being mixed with the metal hydrogen storage material, the mass of the metal hydrogen storage material in unit volume is not reduced, and meanwhile, because the heat-conducting particles have high heat-conducting property, the quick heat conduction of the gaps of the metal hydrogen storage material is realized, the temperature gradient of the metal hydrogen storage material is reduced, and the hydrogen discharge reaction is more stable;
(2) the heat-conducting medium storage tank is arranged, the temperature detection device is used for detecting the temperature to open and close the valve, so that the high-temperature medium does not enter the solid hydrogen storage tank during hydrogen absorption, the low-temperature medium does not enter the heat storage tank during dehydrogenation, the heat exchange efficiency is further improved, and the stability of hydrogenation and hydrogen discharge is further improved.
(3) Set up heat conduction particle, heat pipe etc. and carry out temperature monitoring through temperature-detecting device, realized the miniaturization of solid-state hydrogen source reactor, can use this solid-state hydrogen source reactor setting on unmanned aerial vehicle, plant protection machine and portable car-mounted.
Drawings
FIG. 1 is a schematic diagram of a solid state hydrogen source reactor;
FIG. 2 is a schematic diagram of a solid state hydrogen source reactor.
Detailed Description
The present invention is further described in detail below with reference to examples so that those skilled in the art can practice the invention with reference to the description.
It will be understood that terms such as "having," "including," and "comprising," as used herein, do not preclude the presence or addition of one or more other elements or groups thereof.
Example 1
The invention is further described below with reference to the accompanying drawings:
referring to fig. 1-2, a solid state hydrogen source reactor includes: the solid hydrogen storage tank 1, the heat storage tank 2, the heat preservation layer 3, the bidirectional pump 4 and the heat conduction communication pipe 5 are arranged, the heat preservation layer 3 is arranged on the outer sides of the solid hydrogen storage tank 1 and the heat storage tank 2, the hydrogen storage tank heat conduction pipe 12 is arranged in the solid hydrogen storage tank 1, the heat storage tank heat conduction pipe 22 is arranged in the heat storage tank 2, one end of the hydrogen storage tank heat conduction pipe 12 is communicated with one end of the heat storage tank heat conduction pipe 22 through the heat conduction communication pipe 5, the other end of the hydrogen storage tank heat conduction pipe 12 is connected with the hydrogen storage tank transmission pipe 11, the hydrogen storage tank transmission pipe 11 is communicated with the bidirectional pump 4, the other end of the heat storage tank heat conduction pipe 22 is provided with the heat storage tank transmission pipe 21, the heat storage tank transmission pipe 21 is connected with the bidirectional pump 4, the solid hydrogen storage tank 1 is internally provided with the metal hydrogen storage material 15 and the heat conduction particles 16, and the heat storage tank 2 is internally provided with the phase change material 25; the heat conducting particles 16 are one or more of expanded graphite, carbon nanotubes, graphene and graphene oxide; the hydrogen storage tank heat conduction pipe 12 is provided with a three-way valve 13, and the three-way valve 13 is connected with a hydrogen storage tank heat conduction medium storage tank 14; a heat storage tank three-way valve 23 is arranged on the heat storage tank heat conduction pipe 22, and the heat storage tank three-way valve 23 is connected with a heat storage tank heat conduction medium storage tank 24; a two-way valve 51 is arranged on the heat conducting communicating pipe; the solid hydrogen storage tank 1 is provided with a hydrogen inlet and a hydrogen outlet; in the hydrogenation process, the bidirectional pump 4 drives the heat-conducting medium in the heat-conducting pipe 12 of the hydrogen storage tank to be conveyed to the heat storage tank transmission pipe 21; the solid hydrogen storage tank 1 side of the heat conducting pipe communicating pipe 5 is provided with a hydrogen storage temperature detection device 52, and the heat conducting pipe communicating pipe 5 side of the heat storage tank 2 is provided with a heat storage temperature detection device 53.
Example 2
On the basis of the embodiment 1, the metal hydrogen storage material is lanthanum nickel hydride, which is subjected to hydrogenation reaction with hydrogen at 35 ℃, and the phase change material is paraffin (with the phase change temperature of about 30 ℃); the two-way valve 51 is in a closed state;
the heat control method comprises a hydrogen discharge process and/or a hydrogenation process:
in the hydrogen releasing process, the bidirectional pump 4 drives the heat-conducting medium in the heat-conducting pipeline to be conveyed into the heat-conducting pipeline in the hydrogen storage tank, and the bidirectional valve (51) is closed; when the temperature A of the heat storage tank temperature detection device 53 and the temperature F of the hydrogen storage temperature detection device 52 meet A > (F + 5), the two-way valve 51 is opened;
in the hydrogenation process, the bidirectional pump 4 drives the heat-conducting medium in the heat-conducting pipeline to be conveyed to the heat-conducting pipeline in the heat storage tank, and the bidirectional valve (51) is closed; when the temperature C of the hydrogen storage tank temperature detection means 52 is higher than the temperature D of the heat storage tank temperature detection means 53, the two-way valve 51 is opened.
Example 3
On the basis of embodiment 2, the metal hydrogen storage material is set as magnesium-based complex hydride and the like, which need to be subjected to hydrogenation/dehydrogenation reaction with hydrogen at a high temperature of more than 150 ℃, the phase change material is selected from inorganic hydrated salt, and when the temperature a of the heat storage tank temperature detection device 53 and the temperature F of the hydrogen storage temperature detection device 52 meet a > (F + 10), the two-way valve 51 is opened; otherwise the two-way valve 51 is closed.
Example 4
On the basis of embodiment 2, the metal hydrogen storage material is set to be pure magnesium-based or calcium-based hydride to perform hydrogenation/dehydrogenation reaction with hydrogen at the high temperature of 350-500 ℃, the phase change material can be selected from salt and composite salt, metal and alloy and other types of phase change materials with the phase change temperature of more than 350 ℃ and the phase change latent heat of more than 300 kJ/kg, and when the temperature a of the heat storage tank temperature detection device 53 and the temperature F of the hydrogen storage temperature detection device 52 meet a > (F + 30), the two-way valve 51 is opened; otherwise the two-way valve 51 is closed.
Although the embodiments of the invention have been described above, they are not limited to the applications listed in the description and the embodiments, which are fully applicable to the analysis of test data in various fields of research and further modifications will be readily apparent to those skilled in the art, and the invention is therefore not limited to the specific details and embodiments shown and described herein without departing from the general concept defined by the claims and their equivalents.
Claims (10)
1. A solid state hydrogen source reactor, comprising: solid-state hydrogen storage tank (1), heat storage tank (2), bidirectional pump (4), heat conduction communicating pipe (5), set up hydrogen storage tank heat pipe (12) in solid-state hydrogen storage tank (1), set up heat storage tank heat pipe (22) in heat storage tank (2), hydrogen storage tank heat pipe (12) one end with heat storage tank heat pipe (22) one end is through heat conduction communicating pipe (5) intercommunication, hydrogen storage tank transmission pipe (11) is connected to the hydrogen storage tank heat pipe (12) other end, hydrogen storage tank transmission pipe (11) intercommunication bidirectional pump (4), heat storage tank heat pipe (22) other end sets up heat storage tank transmission pipe (21), heat storage tank transmission pipe (21) are connected bidirectional pump (4), set up metal hydrogen storage material (15) and heat conduction particle (16) in solid-state hydrogen storage tank (1), set up phase change material (25) in heat storage tank (2), the solid-state hydrogen source reactor comprises a hydrogenation process and/or a hydrogen discharge process.
2. A solid state hydrogen source reactor according to claim 1, wherein the thermally conductive particles (16) are one or more of expanded graphite, carbon nanotubes, graphene oxide.
3. A solid state hydrogen source reactor according to claim 1, wherein a three-way valve (13) is provided on the hydrogen storage tank heat transfer tube (12), the three-way valve (13) being connected to the hydrogen storage tank heat transfer medium reservoir (14).
4. A solid state hydrogen source reactor according to claim 1, wherein a heat storage tank three-way valve (23) is arranged on the heat storage tank heat pipe (22), and the heat storage tank three-way valve (23) is connected with the heat storage tank heat transfer medium storage tank (24).
5. A solid state hydrogen source reactor according to claim 1, 3 or 4, characterized in that said conductive feed-through tubes are provided with two-way valves (51).
6. The solid state hydrogen reactor according to claim 5, wherein during the hydrogen discharge, the bidirectional pump (4) drives the heat transfer medium in the heat transfer pipeline to transfer to the heat transfer pipeline in the hydrogen storage tank, and the bidirectional valve (51) is closed; when the temperature A of the heat storage tank temperature detection device (53) and the temperature F of the hydrogen storage temperature detection device 52 meet A > (F + 5), the two-way valve (51) is opened.
7. The solid-state hydrogen source reactor according to claim 5, wherein during hydrogenation, the bidirectional pump (4) drives the heat-conducting medium in the heat-conducting pipeline to convey to the heat-conducting pipeline in the heat storage tank, and the bidirectional valve (51) is closed; and when the temperature C of the hydrogen storage tank temperature detection device (52) is higher than the temperature D of the heat storage tank temperature detection device (53), the two-way valve (51) is opened.
8. The solid-state hydrogen source reactor according to claim 1, wherein the solid-state hydrogen source reactor is further provided with a heating device, the heating device is arranged in the solid-state hydrogen storage tank (1) and/or the heat storage tank (2), further, the solid-state hydrogen source reactor further comprises a heat insulation layer (3), and the heat insulation layer (3) is arranged outside the solid-state hydrogen storage tank (1) and/or the heat storage tank (2).
9. The solid state hydrogen source reactor of claim 1 wherein said metallic hydrogen storage material is AB5Type La-Ni, type AB TiFe, type AB2Zirconium-based hydrogen storage hydride, A2B type magnesium-based hydride, A2One or more calcium based hydrides of type B.
10. A solid state hydrogen source reactor according to claim 6 or 7, wherein during hydrogen discharge, when the two-way valve (51) is closed, the three-way valve (13) is opened to communicate with the heat transfer medium storage tank (14) of the hydrogen storage tank; further, in the hydrogenation process, when the two-way valve (51) is in a closed state, the three-way valve (23) of the heat storage tank is communicated with the heat-conducting medium storage tank (24) of the heat storage tank in an opening mode.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US8418841B2 (en) * | 2010-05-14 | 2013-04-16 | Ford Global Technologies, Llc | Method of enhancing thermal conductivity in hydrogen storage systems |
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|---|---|---|---|---|
| CN101647145A (en) * | 2007-02-02 | 2010-02-10 | 法商Bic公司 | Hydrogen generator |
| CN104528648A (en) * | 2008-12-16 | 2015-04-22 | 国家科学研究中心 | Adiabatic tank for metal hydride |
| CN105060244A (en) * | 2015-08-31 | 2015-11-18 | 江苏氢阳能源有限公司 | Continuous hydrogenation reaction system for liquid organic hydrogen storage carrier and hydrogenation reaction method |
| CN106895253A (en) * | 2017-01-11 | 2017-06-27 | 浙江大学 | A kind of fibre reinforced composites gas cylinder with superconducting radiator |
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