CN112900123A - Real silk fabric printing method - Google Patents
Real silk fabric printing method Download PDFInfo
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- CN112900123A CN112900123A CN201911221694.0A CN201911221694A CN112900123A CN 112900123 A CN112900123 A CN 112900123A CN 201911221694 A CN201911221694 A CN 201911221694A CN 112900123 A CN112900123 A CN 112900123A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
- D06L1/16—Multi-step processes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
- D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic System
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/11—Starch or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
- D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Coloring (AREA)
Abstract
The invention discloses a real silk fabric printing method, which comprises the following steps: 1) preparing slurry; 2) cleaning; 3) padding; 4) sizing; 5) drying; 6) printing; 7) steaming; 8) washing with water; 9) soaping; 10) washing with water; 11) and drying to obtain a finished product, wherein the real silk fabric has good K/S value, color fixing rate and wet treatment fastness, the urea consumption in the real silk reactive printing process is reduced, and the sewage treatment burden is relieved.
Description
Technical Field
The invention belongs to the technical field of printing and dyeing, and particularly relates to a real silk fabric printing method.
Background
The silk fabric is relative to the silk-like fabric, and generally refers to silk, including mulberry silk, tussah silk, castor-oil plant silk, cassava silk, and the like. The fabric is a quite expensive fabric, is widely applied to clothes and furniture, is famous for uneasy care and comfortable ventilation, and has incomparable skin affinity with all other fabrics.
The digital ink-jet printing technology is a printing technology developed rapidly in recent years, and is characterized by that under the drive of compressed air the ink containing pigment is jetted onto the fabric by means of nozzle, and the computer is used to control and form pattern on the fabric according to the design requirements, and according to the performance of ink system, the proper after-treatment can be implemented so as to make the fabric possess a certain colour fastness and vividness. The real silk fabric has higher requirement on printing fineness, the pretreatment of the fabric is very important for reducing the infiltration degree of ink on the fabric, and the infiltration process of the ink on the fabric can be divided into two parts, namely the infiltration during the ink-jet printing and the infiltration generated in the steaming process. Therefore, before ink-jet printing, sizing pretreatment needs to be carried out on the fabric, sodium alginate is generally selected as a thickening agent, urea is added as a moisture absorbent, the ink is reduced from permeating to the periphery on the fabric, a good printing effect is achieved, and the color of the fabric after ink-jet printing is light. And a large amount of urea is required to be added in the printing process of the reactive dye, so that the dissolving assisting effect is achieved, the moisture absorbing and expanding effect is achieved, locked moisture can be released during steaming, favorable conditions are provided for fixing the dye and the fiber, and the fiber is fully swelled to accelerate the dye fixing. However, the urea is discharged into water and naturally decomposed into carbon dioxide and nitrogen-containing compounds, the latter can accelerate the growth of algae substances and finally cause the phenomenon of water quality eutrophication, and the urea is one of the main sources of chemical oxygen demand and ammonia nitrogen pollutants.
Disclosure of Invention
The invention aims to provide a real silk fabric printing method which has good K/S value, color fixing rate and wet treatment fastness, reduces the urea consumption in the real silk active printing process and lightens the sewage treatment burden.
The technical scheme adopted by the invention is as follows: a real silk fabric printing method comprises the steps of slurry preparation, washing, padding, sizing, drying, printing, steaming, washing, soaping, washing and drying, and comprises the following specific steps:
preparing slurry;
cleaning: putting the real silk fabric into cleaning water for cleaning, and naturally airing;
padding: then padding the mixture in a biological enzyme solution, inactivating enzyme, washing with water, and naturally drying;
sizing: sizing the padded real silk fabric by a sizing machine;
drying: drying the sized real silk fabric through an oven at the drying temperature of 40-50 ℃;
printing: printing the dried real silk fabric by a printing system;
steaming: reacting and fixing the printed real silk fabric for 10-50min under the saturated steam condition at the temperature of 100-110 ℃ through a steaming box;
washing with water: washing the fixed silk fabric with cold water by a washing machine, and then washing with hot water at 50-60 ℃;
soaping: soaping the real silk fabric washed by hot water, wherein the soaping time is 8-12min, and the soaping temperature is 95-98 ℃;
washing with water: washing the real silk fabric washed by the soap with hot water at 50-60 ℃, and then washing with cold water;
drying: and drying the washed real silk fabric to obtain a finished product.
Preferably, the slurry comprises the following components in percentage by weight: 1.2-2.8% of sodium alginate, 2-6% of sodium bicarbonate, 6-10% of a diluting and swelling agent, 2-6% of sodium sulfate, 1-3% of modified starch, 0.5-1.2% of glycerol, 78-6% of a stain-resistant salt S2 and the balance of water.
Preferably, the diluted swelling agent comprises the following components in percentage by weight: 6-10% of urea, 6-10% of triethylene glycol and 6-10% of glycerol.
Preferably, the biological enzyme solution comprises the following components in percentage by weight: 2-5% of chelating dispersant, 1-2% of high-temperature amylase and 2-3% of refining penetrant.
Preferably, the padding time is 20-40min, and the padding temperature is 35-40 ℃.
Preferably, the bath ratio in soaping is 1:40, the soap flakes are 2-4g/L, and the sodium carbonate is 3-5 g/L.
Compared with the prior art, the invention has the beneficial effects that: 1) the real silk fabric has good K/S value, color fixing rate and wet processing fastness; 2) the urea consumption in the silk active printing process is reduced, and the sewage treatment burden is reduced.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments.
In the description of the present invention, it is to be understood that the terms "upper", "lower", "front", "rear", "left", "right", "top", "bottom", "inner", "outer", and the like, indicate orientations or positional relationships based on the orientations or positional relationships shown in the drawings, are merely for convenience in describing the present invention and simplifying the description, and do not indicate or imply that the device or element being referred to must have a particular orientation, be constructed and operated in a particular orientation, and thus, should not be construed as limiting the present invention.
Example 1
A real silk fabric printing method comprises the steps of slurry preparation, washing, padding, sizing, drying, printing, steaming, washing, soaping, washing and drying, and comprises the following specific steps:
preparing slurry; the slurry comprises the following components in percentage by weight: 1.8% of sodium alginate, 4% of sodium bicarbonate, 8% of a diluted swelling agent, 4% of sodium sulfate, 2% of modified starch, 0.8% of glycerol, dye-resistant salt S3% and the balance of water;
the diluting and swelling agent comprises the following components in percentage by weight: 10% of urea, 6% of triethylene glycol and 8% of glycerol;
cleaning: putting the real silk fabric into cleaning water for cleaning, and naturally airing;
padding: then placing the mixture into a biological enzyme solution for padding for 30min at the padding temperature of 40 ℃; inactivating enzyme, washing with water, and naturally drying;
the biological enzyme solution comprises the following components in percentage by weight: 3% of chelating dispersant, 1.5% of high-temperature amylase and 3% of refining penetrant;
sizing: sizing the padded real silk fabric by a sizing machine;
drying: drying the sized real silk fabric through an oven at the drying temperature of 50 ℃;
printing: printing the dried real silk fabric by a printing system;
steaming: reacting and fixing the printed real silk fabric for 30min under the saturated steam condition at the temperature of 105 ℃ by a steaming box;
washing with water: washing the fixed silk fabric with cold water by a washing machine, and then washing with hot water at 60 ℃;
soaping: soaping the real silk fabric washed by hot water, wherein the soaping time is 10min, and the soaping temperature is 96 ℃; the bath ratio during soaping is 1:40, the soap flakes are 3g/L, and the sodium carbonate is 4 g/L;
washing with water: washing the real silk fabric washed by the soap with hot water at 55 ℃, and then washing with cold water;
drying: and drying the washed real silk fabric to obtain a finished product.
Example 2
A real silk fabric printing method comprises the steps of slurry preparation, washing, padding, sizing, drying, printing, steaming, washing, soaping, washing and drying, and comprises the following specific steps:
preparing slurry;
cleaning: putting the real silk fabric into cleaning water for cleaning, and naturally airing;
padding: then placing the seeds into a biological enzyme solution for padding for 20-40min at 35-40 ℃, inactivating enzyme, washing with water, and naturally drying;
sizing: sizing the padded real silk fabric by a sizing machine;
drying: drying the sized real silk fabric through an oven at the drying temperature of 45 ℃;
printing: printing the dried real silk fabric by a printing system;
steaming: reacting and fixing the printed real silk fabric for 40min under the saturated steam condition at the temperature of 108 ℃ by a steaming box;
washing with water: washing the color-fixed real silk fabric with cold water by a washing machine, and then washing with hot water at 52 ℃;
soaping: soaping the real silk fabric washed by hot water, wherein the soaping time is 8min, the soaping temperature is 98 ℃, the bath ratio during soaping is 1:40, the soap flake is 3/L, and the sodium carbonate is 5 g/L;
washing with water: washing the soaped real silk fabric with hot water at 52 ℃, and then washing with cold water;
drying: and drying the washed real silk fabric to obtain a finished product.
The slurry comprises the following components in percentage by weight: 1.2% of sodium alginate, 2% of sodium bicarbonate, 6% of a diluted swelling agent, 3% of sodium sulfate, 2% of modified starch, 0.8% of glycerol, dye-resistant salt S6% and the balance of water.
The diluting and swelling agent comprises the following components in percentage by weight: 10% of urea, 6% of triethylene glycol and 6% of glycerol.
The biological enzyme solution comprises the following components in percentage by weight: 2% of chelating dispersant, 1% of high-temperature amylase and 2% of refining penetrant.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.
Claims (6)
1. A real silk fabric printing method is characterized by comprising the following steps:
1) preparing slurry;
2) cleaning: putting the real silk fabric into cleaning water for cleaning, and naturally airing;
3) padding: then padding the mixture in a biological enzyme solution, inactivating enzyme, washing with water, and naturally drying;
4) sizing: sizing the padded real silk fabric by a sizing machine;
5) drying: drying the sized real silk fabric through an oven at the drying temperature of 40-50 ℃;
6) printing: printing the dried real silk fabric by a printing system;
7) steaming: reacting and fixing the printed real silk fabric for 10-50min under the saturated steam condition at the temperature of 100-110 ℃ through a steaming box;
8) washing with water: washing the fixed silk fabric with cold water by a washing machine, and then washing with hot water at 50-60 ℃;
9) soaping: soaping the real silk fabric washed by hot water, wherein the soaping time is 8-12min, and the soaping temperature is 95-98 ℃;
10) washing with water: washing the real silk fabric washed by the soap with hot water at 50-60 ℃, and then washing with cold water;
11) drying: and drying the washed real silk fabric to obtain a finished product.
2. The method for printing silk fabrics according to claim 1, wherein the size in step 1 comprises the following components in percentage by weight: 1.2-2.8% of sodium alginate, 2-6% of sodium bicarbonate, 6-10% of a diluting and swelling agent, 2-6% of sodium sulfate, 1-3% of modified starch, 0.5-1.2% of glycerol, 78-6% of a stain-resistant salt S2 and the balance of water.
3. The real silk fabric printing method according to claim 2, wherein the diluted swelling agent comprises the following components in percentage by weight: 6-10% of urea, 6-10% of triethylene glycol and 6-10% of glycerol.
4. The real silk fabric printing method according to claim 1, wherein the biological enzyme solution in the step 2 comprises the following components in percentage by weight: 2-5% of chelating dispersant, 1-2% of high-temperature amylase and 2-3% of refining penetrant.
5. A real silk fabric printing method according to claim 1, wherein the padding time in the step 3 is 20-40min, and the padding temperature is 35-40 ℃.
6. The real silk fabric printing method according to claim 1, wherein the bath ratio in the step 9 of soaping is 1:40, the soap flakes are 2-4g/L, and the sodium carbonate is 3-5 g/L.
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CN201911221694.0A CN112900123A (en) | 2019-12-03 | 2019-12-03 | Real silk fabric printing method |
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CN201911221694.0A CN112900123A (en) | 2019-12-03 | 2019-12-03 | Real silk fabric printing method |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103451970A (en) * | 2013-09-10 | 2013-12-18 | 石家庄市荷西服饰贸易有限公司 | Digital reactive dye printing process for mulberry silk fabric |
CN104233825A (en) * | 2014-09-03 | 2014-12-24 | 长兴国圆印染有限公司 | Environment-friendly silk printing method |
CN104278588A (en) * | 2013-07-09 | 2015-01-14 | 无锡市兴麟染整环保有限公司 | Digital ink jet printing process of mulberry silk fabric |
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2019
- 2019-12-03 CN CN201911221694.0A patent/CN112900123A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104278588A (en) * | 2013-07-09 | 2015-01-14 | 无锡市兴麟染整环保有限公司 | Digital ink jet printing process of mulberry silk fabric |
CN103451970A (en) * | 2013-09-10 | 2013-12-18 | 石家庄市荷西服饰贸易有限公司 | Digital reactive dye printing process for mulberry silk fabric |
CN104233825A (en) * | 2014-09-03 | 2014-12-24 | 长兴国圆印染有限公司 | Environment-friendly silk printing method |
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