CN112878094B - Oil painting paper and preparation method thereof - Google Patents

Oil painting paper and preparation method thereof Download PDF

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Publication number
CN112878094B
CN112878094B CN202110028720.9A CN202110028720A CN112878094B CN 112878094 B CN112878094 B CN 112878094B CN 202110028720 A CN202110028720 A CN 202110028720A CN 112878094 B CN112878094 B CN 112878094B
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paper
oil painting
preparation
oil
sizing
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CN112878094A (en
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石立明
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BAODING HUARONG PAPER MILL
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BAODING HUARONG PAPER MILL
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F11/00Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
    • D21F11/06Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines of the cylinder type
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44DPAINTING OR ARTISTIC DRAWING, NOT OTHERWISE PROVIDED FOR; PRESERVING PAINTINGS; SURFACE TREATMENT TO OBTAIN SPECIAL ARTISTIC SURFACE EFFECTS OR FINISHES
    • B44D3/00Accessories or implements for use in connection with painting or artistic drawing, not otherwise provided for; Methods or devices for colour determination, selection, or synthesis, e.g. use of colour tables
    • B44D3/18Boards or sheets with surfaces prepared for painting or drawing pictures; Stretching frames for canvases
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21GCALENDERS; ACCESSORIES FOR PAPER-MAKING MACHINES
    • D21G9/00Other accessories for paper-making machines
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/02Chemical or chemomechanical or chemothermomechanical pulp
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/34Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/37Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/46Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/54Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
    • D21H17/55Polyamides; Polyaminoamides; Polyester-amides
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/12Coatings without pigments applied as a solution using water as the only solvent, e.g. in the presence of acid or alkaline compounds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/18Reinforcing agents
    • D21H21/20Wet strength agents
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/04Physical treatment, e.g. heating, irradiating
    • D21H25/06Physical treatment, e.g. heating, irradiating of impregnated or coated paper

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Paper (AREA)

Abstract

The invention provides oil painting paper and a preparation method thereof, and relates to the technical field of paper preparation. The preparation method provided by the invention comprises the following steps: sequentially pulping, mixing pulp, manufacturing paper and drying by a first drying cylinder to obtain raw paper; finishing the base paper to obtain texture paper; performing surface sizing and drying on the texture paper to obtain oil painting paper; the sizing liquid adopted by the surface sizing comprises polyvinyl alcohol, an organic fluorine compound and water. The oil-proof and strength of the oil painting paper prepared by the method provided by the invention can be effectively improved, and the paper has the surface texture of cloth marks. Compared with the traditional canvas, the oil painting paper prepared by the invention has the advantages of low price, convenient use and better pigment firmness, and can be used for oil painting practice and oil painting creation; compared with other oil painting paper, the method has better oil resistance and the surface has cloth texture.

Description

Oil painting paper and preparation method thereof
Technical Field
The invention relates to the technical field of paper preparation, in particular to oil painting paper and a preparation method thereof.
Background
Paper for painting is mainly classified into two categories: one is Chinese painting paper, and the other is Western painting paper. The Chinese painting paper includes Xuan paper, mulberry paper, paper for clamping river, etc., and the Western painting paper includes watercolor paper, oil painting paper, plate painting paper, etc. The oil painting paper is paper specially used for oil painting creation. Traditional oil painting creation is mainly performed on linen, but the oil painting canvas has the defects of high price, inconvenient use and the like, so that more and more people begin to use cheap and convenient oil painting paper to perform oil painting exercise and creation.
The oil painting creation has high requirements on paper, firstly, because the oil painting pigment contains vegetable oil, the oil painting paper is required to have oil resistance and water resistance, secondly, the oil painting creation needs to be repeatedly coated and scraped on the paper, so the paper is required to have high tensile strength and surface strength, and in addition, because painters are more used to the surface texture of oil painting canvas, the paper surface is also required to have natural cloth marks. In addition, the oil painting paper pigment is required to have good fastness, namely the oil painting pigment is not easy to fall off and dry and crack on the surface of paper after being dried.
At present, relatively few documents related to oil painting paper are published, and Chinese patent CN111197267A introduces a manufacturing process of easy-to-color oil painting paper, but the process is not suitable for industrial production on a paper machine, and oil repellency of the paper is not considered.
Disclosure of Invention
The invention aims to provide oil painting paper and a preparation method thereof, the preparation method provided by the invention is suitable for industrial production on a paper machine, and the produced oil painting paper has the advantages of good oil resistance and water resistance, high strength, high pigment firmness, and fabric texture on the surface, and meets the performance requirements of the oil painting paper.
In order to achieve the above object, the present invention provides the following technical solutions:
the invention provides a preparation method of oil painting paper, which comprises the following steps:
sequentially pulping, proportioning, papermaking and drying by a first drying cylinder to obtain raw paper;
finishing the base paper to obtain texture paper;
performing surface sizing and drying on the texture paper to obtain oil painting paper; the sizing liquid adopted by the surface sizing comprises polyvinyl alcohol, an organic fluorine compound and water.
Preferably, the finishing is performed by using a finishing roller with a cloth grain line.
Preferably, the sizing solution comprises, by weight, 100 parts of water, 0.1-1.2 parts of an organic fluorine compound and 0.5-3 parts of polyvinyl alcohol.
Preferably, the sizing amount of the sizing liquid is 4-15%.
Preferably, the temperature of the first drying cylinder drying is 60-105 ℃.
Preferably, the organic fluorine compound comprises one or more of a chromium complex of a perfluorocarboxylic acid, a fluorocarbon acrylate resin, and a fluorocarbon sulfonylaminoethyl acrylate.
Preferably, an auxiliary agent is added during slurry preparation; the auxiliary agent comprises polyamide epichlorohydrin resin and cationic polyacrylamide.
The invention provides the oil painting paper prepared by the preparation method of the technical scheme.
Preferably, the surface of the oil painting paper has a cloth texture.
Preferably, the quantitative weight of the oil painting paper is 280-300 g/m 2 (ii) a The tightness of the oil painting paper is 0.5-0.8 g/cm 3 (ii) a The Cobb water absorption capacity of the oil painting paper is 15-37 g/m 2 (ii) a The oil-proof kit value of the oil painting paper is 5-12; the transverse tensile strength of the oil painting paper is 13-20 kN/m.
The invention provides a preparation method of oil painting paper, which comprises the following steps: sequentially pulping, mixing pulp, manufacturing paper and drying by a first drying cylinder to obtain raw paper; finishing the base paper to obtain texture paper; performing surface sizing and drying on the texture paper to obtain oil painting paper; the sizing liquid adopted by the surface sizing comprises polyvinyl alcohol, an organic fluorine compound and water. In the invention, polyvinyl alcohol and organic fluoride are mixed to prepare the surface sizing solution, the strength of the oil painting paper is improved through the polyvinyl alcohol, the surface energy of the paper is reduced through the organic fluoride, and the oil resistance of the paper is increased; the invention arranges a finishing procedure after the first drying cylinder is dried, and the paper has moderate water content at the position, thereby providing clear and natural cloth texture on the surface. The oil-proof and strength of the oil painting paper prepared by the method provided by the invention can be effectively improved, and the paper has the surface texture of cloth grains. Compared with the traditional canvas, the oil painting paper prepared by the invention has the advantages of low price, convenient use and better pigment firmness, and can be used for oil painting practice and oil painting creation; compared with other oil painting paper, the method has better oil resistance and the surface has cloth texture.
Drawings
Fig. 1 is a pictorial view of an oil paper prepared in example.
Detailed Description
The invention provides a preparation method of oil painting paper, which comprises the following steps:
sequentially pulping, proportioning, papermaking and drying by a first drying cylinder to obtain raw paper;
finishing the base paper to obtain texture paper;
performing surface sizing and drying on the texture paper to obtain oil painting paper; the sizing liquid adopted by the surface sizing comprises polyvinyl alcohol, an organic fluorine compound and water.
The paper making material is sequentially subjected to pulping, pulp blending, papermaking and drying by a first drying cylinder to obtain the base paper. In the present invention, the papermaking material preferably includes one or more of bleached softwood pulp, bleached hardwood pulp, and bleached cotton pulp. In the present invention, when the papermaking material is a mixture of a plurality of materials, the present invention does not require any particular proportions of the components in the mixture, and may employ proportions well known to those skilled in the art. In a specific embodiment of the present invention, when the papermaking material is a mixture of bleached softwood pulp and bleached hardwood pulp, the mass ratio of the bleached softwood pulp to the bleached hardwood pulp is 1: 1.
In the invention, the beating concentration during beating is preferably 1.57%, and the beating degree to beating is preferably 20-35% ° SR, more preferably 30 to 35 ° SR。
In the invention, an auxiliary agent is added during slurry preparation; the adjuvants preferably include polyamide epichlorohydrin resins and cationic polyacrylamides. In the present invention, the amount of the polyamide epichlorohydrin resin (PAE) added to the oven-dried pulp is preferably 0.5 to 1.65 wt%, more preferably 0.55 to 0.88 wt%, and still more preferably 0.66 to 0.77 wt%. In a specific embodiment of the invention, the PAE used is a commercial product having an effective content of polyamide epichlorohydrin resin of 11%. In the present invention, the Cationic Polyacrylamide (CPAM) is preferably added in an amount of 0.05 to 0.6 wt%, more preferably 0.3 to 0.4 wt%, relative to the oven dried pulp.
In the present invention, the method for producing paper preferably includes: dewatering and forming the prepared pulp by a fourdrinier or cylinder paper machine, and squeezing wet paper.
In the invention, the drying temperature of the first drying cylinder is preferably 60-105 ℃, more preferably 65-100 ℃, and further preferably 70-80 ℃; the drying time of the first drying cylinder is preferably 10-30 s, and more preferably 15-20 s.
In the invention, the moisture content of the base paper is preferably 20-40%, and more preferably 25-35%.
After the base paper is obtained, the base paper is finished to obtain the texture paper. In the invention, the finishing is preferably finished by a finishing roller with cloth grain lines; the pressure of the finishing roller is preferably 2-4 kg, and more preferably 2.5-3.5 kg.
After obtaining texture paper, performing surface sizing on the texture paper to obtain oil painting paper; the sizing liquid adopted by the surface sizing comprises polyvinyl alcohol, an organic fluorine compound and water.
According to the invention, before the surface sizing is carried out, the texture paper is preferably dried; the drying temperature is preferably 80-105 ℃, and more preferably 95-105 ℃.
In the present invention, the method of surface sizing is preferably film transfer or impregnation. The present invention does not require a specific process for the film transfer or impregnation, and may employ processes well known to those skilled in the art.
In the invention, the sizing solution preferably comprises 100 parts by weight of water, 0.1-1.2 parts by weight of organic fluorine compound and 0.5-3 parts by weight of polyvinyl alcohol. In a specific embodiment of the invention, the sizing liquid comprises, by weight, 100 parts of water, 0.2-0.8 part of an organofluorine compound, and 1-2 parts of polyvinyl alcohol. In the invention, the sizing amount of the sizing liquid is preferably 4-15%, and more preferably 7-12%.
In the present invention, the organic fluorine compound preferably includes one or more of a chromium complex of perfluorocarboxylic acid, a fluorocarbon acrylate-based resin, and a fluorocarbon sulfonylaminoethyl acrylate, and more preferably a fluorocarbon acrylate-based resin. In the specific embodiment of the present invention, the organic fluorine compound is a commercially available product, and the effective content of the organic fluorine compound in the commercially available product is preferably 20%.
After surface sizing, the paper after sizing is dried to obtain the oil painting paper. In the invention, the drying is preferably carried out in a drying cylinder, and the drying temperature is preferably 95-110 ℃, and more preferably 100-105 ℃.
The invention provides the oil painting paper prepared by the preparation method of the technical scheme. In the present invention, the surface of the oil painting paper preferably has a cloth grain texture. In the invention, the quantitative ratio of the oil painting paper is preferably 280-300 g/m 2 More preferably 290g/m 2 (ii) a The tightness of the oil painting paper is preferably 0.5-0.8 g/cm 3 More preferably 0.7g/cm 3 (ii) a The Cobb water absorption capacity of the oil painting paper is preferably 15-37 g/m 2 More preferably 17 to 28g/m 2 (ii) a The oil-proof kit value of the oil painting paper is preferably 5-12, and more preferably 8-10; the transverse tensile strength of the oil painting paper is preferably 13-20 kN/m, and more preferably 17-18 kN/m.
The technical solution of the present invention will be clearly and completely described below with reference to the embodiments of the present invention. It should be apparent that the described embodiments are only some embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
(1) Pulping: adding 100% bleached softwood pulp into a tile power beating machine for beating, wherein the beating concentration is 1.57%, and the beating degree is 35% ° SR;
(2) Slurry preparation: sequentially adding 0.55 wt% of wet strength agent PAE (calculated by the effective components of the wet strength agent), 0.2% of CPAM (continuous extrusion) into the pulp, wherein the addition amounts are relative to the absolute dry pulp amount;
(3) manufacturing paper: dehydrating and molding the prepared pulp by a cylinder paper machine, and squeezing wet paper;
(4) drying by a first drying cylinder: the temperature is 80 ℃ and the time is 20 s;
(5) finishing: finishing by adopting a finishing roller with cloth grain lines to obtain texture paper; drying before sizing;
(6) surface sizing: carrying out surface sizing on the dried texture paper by a dipping mode; the sizing liquid comprises the following specific components in parts by weight: 100 parts of water, 0.4 part of acrylic fluorocarbon resin (calculated by the active ingredients of the organic fluoride), 2 parts of PVA and 9 percent of sizing amount;
(7) and (3) drying: and drying the paper after glue application through a drying cylinder at the drying temperature of 105 ℃ to obtain the oil painting paper.
The oil painting paper produced in the embodiment has the following technical indexes: quantitative determination of 290g/m 2 Tightness 0.7g/cm 3 Cobb Water absorption 17g/m 2 The oil repellency kit value is 10, the transverse tensile strength is 18kN/m, and the surface texture of the paper is shown in FIG. 1.
Example 2
(1) Pulping: adding 100% bleached hardwood pulp into a tile power beating machine for beating, wherein the beating concentration is 1.57%, and the beating degree is 30 ° SR;
(2) Slurry preparation: sequentially adding 0.66 wt% of wet strength agent PAE (calculated by the effective components of the wet strength agent), 0.3% of CPAM (continuous extrusion) into the pulp, wherein the addition amounts are relative to the absolute dry pulp amount;
(3) manufacturing paper: dehydrating and molding the prepared pulp by a cylinder paper machine, and squeezing wet paper;
(4) drying by a first drying cylinder: the temperature is 70 ℃ and the time is 25 s;
(5) finishing: finishing by adopting a finishing roller with cloth grain lines to obtain texture paper; drying before sizing;
(6) surface sizing: carrying out surface sizing on the dried texture paper in a dipping mode; the sizing liquid comprises the following specific components in parts by weight: 100 parts of water, 0.8 part of acrylic fluorocarbon resin (calculated by the active ingredient of the organic fluoride), 1 part of PVA and 4 percent of sizing amount;
(7) and (3) drying: drying the paper after sizing by a drying cylinder at the drying temperature of 105 ℃ to obtain the oil painting paper.
The oil painting paper produced in the embodiment has the following technical indexes: quantitative determination of 290g/m 2 Tightness 0.7g/cm 3 Cobb Water absorption 15g/m 2 The oil repellency kit value was 12, the transverse tensile strength was 13kN/m, and the surface texture of the paper sheet was as shown in FIG. 1.
Example 3
(1) Pulping: the bleached softwood pulp and bleached hardwood pulp are mixed according to the weight ratio of 1:1 is added into a tile power beater to be beaten, the beating concentration is 1.57 percent, and the beating degree is 20 ° SR;
(2) Slurry preparation: sequentially adding 0.88 wt% of wet strength agent PAE (calculated by the effective component of the wet strength agent), 0.3% of CPAM (continuous extrusion) into the pulp, wherein the addition amounts are relative to the absolute dry pulp amount;
(3) manufacturing paper: dehydrating and molding the prepared pulp by a cylinder paper machine, and squeezing wet paper;
(4) drying by a first drying cylinder: the temperature is 75 ℃, and the time is 15 s;
(5) finishing: finishing by adopting a finishing roller with cloth grain lines to obtain texture paper; drying before sizing;
(6) surface sizing: surface sizing is carried out on the dried texture paper in a membrane transfer mode; the sizing liquid comprises the following specific components in parts by weight: 100 parts of water, 0.1 part of acrylic fluorocarbon resin (calculated by the active ingredient of the organic fluoride), 1.5 parts of PVA and 7 percent of sizing amount;
(7) and (3) drying: and drying the paper after glue application through a drying cylinder at the drying temperature of 105 ℃ to obtain the oil painting paper.
The oil painting paper produced in the embodiment has the following technical indexes: quantitative determination of 290g/m 2 Tightness 0.7g/cm 3 Cobb Water absorption 37g/m 2 The oil repellency kit value was 5, the transverse tensile strength was 17kN/m, and the surface texture of the paper sheet was as shown in FIG. 1.
Example 4
(1) Pulping: adding 100% bleached cotton pulp into a tile power beating machine for beating, wherein the beating concentration is 1.57%, and the beating degree is 35% ° SR;
(2) Slurry preparation: sequentially adding 0.77 wt% of wet strength agent PAE (calculated by the effective component of the wet strength agent), 0.4% of CPAM (continuous extrusion) into the pulp, wherein the addition amounts are relative to the absolute dry pulp amount;
(3) manufacturing paper: dehydrating and molding the prepared pulp by a cylinder paper machine, and squeezing wet paper;
(4) drying by a first drying cylinder: the temperature is 65 ℃ and the time is 20 s;
(5) finishing: finishing by adopting a finishing roller with cloth grain lines to obtain texture paper; drying before sizing;
(6) surface sizing: surface sizing is carried out on the dried texture paper in a membrane transfer mode; the sizing liquid comprises the following specific components in parts by weight: 100 parts of water, 0.2 part of acrylic fluorocarbon resin (calculated by the active ingredients of the organic fluoride), 3 parts of PVA and 12 percent of sizing amount;
(7) and (3) drying: and drying the paper after glue application through a drying cylinder at the drying temperature of 105 ℃ to obtain the oil painting paper.
The oil painting paper produced in the embodiment has the following technical indexes: quantitative determination of 290g/m 2 Tightness 0.7g/cm 3 Cobb Water absorption 28g/m 2 The oil repellency kit value was 8, the transverse tensile strength was 20kN/m, and the surface texture of the paper sheet was as shown in FIG. 1.
The oil painting paper prepared by the preparation method disclosed by the embodiment of the invention has the advantages of good oil resistance and water resistance, high strength, high pigment firmness and fabric texture on the surface, and meets the performance requirements of the oil painting paper.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various modifications and amendments can be made without departing from the principle of the present invention, and these modifications and amendments should also be considered as the protection scope of the present invention.

Claims (9)

1. The preparation method of the oil painting paper is characterized by comprising the following steps:
sequentially pulping, proportioning, papermaking and drying by a first drying cylinder to obtain raw paper;
finishing the base paper to obtain texture paper;
performing surface sizing and drying on the texture paper to obtain oil painting paper; the sizing liquid adopted by the surface sizing comprises polyvinyl alcohol, an organic fluorine compound and water;
the finishing adopts a finishing roller with cloth grain lines for finishing.
2. The preparation method of claim 1, wherein the sizing solution comprises 100 parts by weight of water, 0.1-1.2 parts by weight of organofluorine compound and 0.5-3 parts by weight of polyvinyl alcohol.
3. The preparation method according to claim 1 or 2, wherein the sizing amount of the sizing solution is 4-15%.
4. The preparation method according to claim 1, wherein the temperature of the first drying cylinder is 60-105 ℃.
5. The method of claim 1, wherein the organic fluorine compound comprises one or more of a chromium complex of perfluorocarboxylic acid, a fluorocarbon resin of the acrylic ester type, and a fluorocarbon sulfonylaminoethyl acrylate.
6. The preparation method according to claim 1, characterized in that an auxiliary agent is added during the slurry preparation; the auxiliary agent comprises polyamide epichlorohydrin resin and cationic polyacrylamide.
7. The oil painting paper prepared by the preparation method of any one of claims 1 to 6.
8. The oil painting paper as claimed in claim 7, wherein the surface of the oil painting paper has a cloth texture.
9. According to claim7 the oil painting paper is characterized in that the ration of the oil painting paper is 280-300 g/m 2 (ii) a The tightness of the oil painting paper is 0.5-0.8 g/cm 3 (ii) a The Cobb water absorption capacity of the oil painting paper is 15-37 g/m 2 (ii) a The oil-proof kit value of the oil painting paper is 5-12; the transverse tensile strength of the oil painting paper is 13-20 kN/m.
CN202110028720.9A 2021-01-11 2021-01-11 Oil painting paper and preparation method thereof Active CN112878094B (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105970716A (en) * 2016-05-20 2016-09-28 浙江省普瑞科技有限公司 Method for making manual watercolour paper
CN107059483A (en) * 2017-04-27 2017-08-18 浙江省普瑞科技有限公司 A kind of manufacture method of manual copperplate etching art paper
CN111197267A (en) * 2020-03-05 2020-05-26 安徽雪山纸业有限公司 Manufacturing process of easy-to-color oil painting paper

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105970716A (en) * 2016-05-20 2016-09-28 浙江省普瑞科技有限公司 Method for making manual watercolour paper
CN107059483A (en) * 2017-04-27 2017-08-18 浙江省普瑞科技有限公司 A kind of manufacture method of manual copperplate etching art paper
CN111197267A (en) * 2020-03-05 2020-05-26 安徽雪山纸业有限公司 Manufacturing process of easy-to-color oil painting paper

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