CN112875740B - System and method for preparing high-purity gypsum from semi-dry desulfurized fly ash - Google Patents
System and method for preparing high-purity gypsum from semi-dry desulfurized fly ash Download PDFInfo
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- CN112875740B CN112875740B CN202011518288.3A CN202011518288A CN112875740B CN 112875740 B CN112875740 B CN 112875740B CN 202011518288 A CN202011518288 A CN 202011518288A CN 112875740 B CN112875740 B CN 112875740B
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- washing
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- gypsum
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- 229910052602 gypsum Inorganic materials 0.000 title claims abstract description 70
- 239000010440 gypsum Substances 0.000 title claims abstract description 70
- 239000010881 fly ash Substances 0.000 title claims abstract description 29
- 238000000034 method Methods 0.000 title claims abstract description 22
- 238000005406 washing Methods 0.000 claims abstract description 115
- 239000002002 slurry Substances 0.000 claims abstract description 110
- 239000007788 liquid Substances 0.000 claims abstract description 83
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 54
- 239000003546 flue gas Substances 0.000 claims abstract description 54
- 238000006477 desulfuration reaction Methods 0.000 claims abstract description 47
- 230000023556 desulfurization Effects 0.000 claims abstract description 47
- 239000007789 gas Substances 0.000 claims abstract description 47
- 239000002956 ash Substances 0.000 claims abstract description 38
- 239000000706 filtrate Substances 0.000 claims abstract description 35
- GBAOBIBJACZTNA-UHFFFAOYSA-L calcium sulfite Chemical compound [Ca+2].[O-]S([O-])=O GBAOBIBJACZTNA-UHFFFAOYSA-L 0.000 claims abstract description 25
- 235000010261 calcium sulphite Nutrition 0.000 claims abstract description 25
- 238000004537 pulping Methods 0.000 claims abstract description 25
- 239000000292 calcium oxide Substances 0.000 claims abstract description 24
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 24
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000007921 spray Substances 0.000 claims abstract description 20
- 230000003647 oxidation Effects 0.000 claims abstract description 18
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 238000004140 cleaning Methods 0.000 claims abstract description 7
- 239000003570 air Substances 0.000 claims description 56
- 239000002245 particle Substances 0.000 claims description 27
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 24
- 238000005507 spraying Methods 0.000 claims description 22
- 239000000725 suspension Substances 0.000 claims description 20
- 239000000428 dust Substances 0.000 claims description 16
- 230000009471 action Effects 0.000 claims description 12
- 238000004090 dissolution Methods 0.000 claims description 10
- 239000012535 impurity Substances 0.000 claims description 8
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 7
- 239000000920 calcium hydroxide Substances 0.000 claims description 7
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- 230000008569 process Effects 0.000 claims description 7
- 239000000779 smoke Substances 0.000 claims description 7
- 239000012080 ambient air Substances 0.000 claims description 6
- 230000005484 gravity Effects 0.000 claims description 6
- 239000011148 porous material Substances 0.000 claims description 6
- 238000000889 atomisation Methods 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 4
- 238000007599 discharging Methods 0.000 claims description 3
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 claims 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 230000003009 desulfurizing effect Effects 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
- 229910001634 calcium fluoride Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/46—Sulfates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
- B01D53/502—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound characterised by a specific solution or suspension
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
- B01D53/504—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound characterised by a specific device
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/46—Sulfates
- C01F11/468—Purification of calcium sulfates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/40—Alkaline earth metal or magnesium compounds
- B01D2251/404—Alkaline earth metal or magnesium compounds of calcium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/60—Inorganic bases or salts
- B01D2251/604—Hydroxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Geology (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
Abstract
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CN202011518288.3A CN112875740B (en) | 2020-12-21 | 2020-12-21 | System and method for preparing high-purity gypsum from semi-dry desulfurized fly ash |
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CN202011518288.3A CN112875740B (en) | 2020-12-21 | 2020-12-21 | System and method for preparing high-purity gypsum from semi-dry desulfurized fly ash |
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CN112875740A CN112875740A (en) | 2021-06-01 |
CN112875740B true CN112875740B (en) | 2023-04-14 |
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CN202011518288.3A Active CN112875740B (en) | 2020-12-21 | 2020-12-21 | System and method for preparing high-purity gypsum from semi-dry desulfurized fly ash |
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Families Citing this family (1)
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CN114618278B (en) * | 2022-04-06 | 2023-08-15 | 承德建龙特殊钢有限公司 | Device system and method for cooperatively utilizing lime-based desulfurized ash by lime-gypsum method |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103599690B (en) * | 2013-11-12 | 2015-04-22 | 山东中实易通集团有限公司 | Composite limestone/calcium hydroxide gypsum wet desulfurization device and technique |
CN109364730A (en) * | 2018-12-17 | 2019-02-22 | 新疆天富集团有限责任公司 | A kind of full working scope wet desulphurization tail gas receipts water eliminating white smoke system and method |
CN110201524A (en) * | 2019-05-23 | 2019-09-06 | 新疆天富环保科技有限公司 | A kind of wet desulphurization device and method of semi-dry desulphurization ash resource utilization |
CN111054197B (en) * | 2019-12-30 | 2022-04-22 | 江苏垦乐节能环保科技有限公司 | Semi-dry deep desulfurization method for sulfur-containing flue gas |
CN111637481A (en) * | 2020-05-27 | 2020-09-08 | 杭州蕴泽环境科技有限公司 | Tail gas purification system and method for recovering flue gas waste heat |
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Date | Code | Title | Description |
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PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A system and method for preparing high-purity gypsum from semi dry desulfurization ash Effective date of registration: 20230718 Granted publication date: 20230414 Pledgee: Hangzhou Gaoxin Financing Guarantee Co.,Ltd. Pledgor: HANGZHOU YUNZE ENVIRONMENTAL TECHNOLOGY Co.,Ltd. Registration number: Y2023330001516 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20240108 Address after: 311215 No. 419, Shengxing Road, ningwei street, Xiaoshan District, Hangzhou City, Zhejiang Province Patentee after: Zhejiang Zeyu Technology Development Co.,Ltd. Address before: Room 605, Minghao building, 1688 Binsheng Road, Binjiang District, Hangzhou City, Zhejiang Province 310051 Patentee before: HANGZHOU YUNZE ENVIRONMENTAL TECHNOLOGY Co.,Ltd. |
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TR01 | Transfer of patent right | ||
CI03 | Correction of invention patent |
Correction item: Patentee|Address Correct: Hangzhou Yunze Environmental Technology Co., Ltd.|Room 605, Minghao building, 1688 Binsheng Road, Binjiang District, Hangzhou City, Zhejiang Province 310051 False: Zhejiang Zeyu Technology Development Co., Ltd.|311215 No. 419, Shengxing Road, ningwei street, Xiaoshan District, Hangzhou City, Zhejiang Province Number: 04-01 Volume: 40 |
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CI03 | Correction of invention patent |