CN112845413A - Steel pipe cleaning method - Google Patents

Steel pipe cleaning method Download PDF

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Publication number
CN112845413A
CN112845413A CN201911172532.2A CN201911172532A CN112845413A CN 112845413 A CN112845413 A CN 112845413A CN 201911172532 A CN201911172532 A CN 201911172532A CN 112845413 A CN112845413 A CN 112845413A
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CN
China
Prior art keywords
steel pipe
cleaning
pipeline
cleaning method
water
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Pending
Application number
CN201911172532.2A
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Chinese (zh)
Inventor
李荣军
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SAE Technologies Development Dongguan Co Ltd
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SAE Technologies Development Dongguan Co Ltd
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Publication date
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Priority to CN201911172532.2A priority Critical patent/CN112845413A/en
Publication of CN112845413A publication Critical patent/CN112845413A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B9/00Cleaning hollow articles by methods or apparatus specially adapted thereto 
    • B08B9/02Cleaning pipes or tubes or systems of pipes or tubes
    • B08B9/027Cleaning the internal surfaces; Removal of blockages
    • B08B9/032Cleaning the internal surfaces; Removal of blockages by the mechanical action of a moving fluid, e.g. by flushing
    • B08B9/0321Cleaning the internal surfaces; Removal of blockages by the mechanical action of a moving fluid, e.g. by flushing using pressurised, pulsating or purging fluid
    • B08B9/0328Cleaning the internal surfaces; Removal of blockages by the mechanical action of a moving fluid, e.g. by flushing using pressurised, pulsating or purging fluid by purging the pipe with a gas or a mixture of gas and liquid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/10Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
    • B08B3/12Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration by sonic or ultrasonic vibrations
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/06Hydroxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/08Acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/10Salts
    • C11D7/12Carbonates bicarbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/263Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/265Carboxylic acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/32Organic compounds containing nitrogen
    • C11D7/3245Aminoacids

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Mechanical Engineering (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Abstract

The invention discloses a steel pipe cleaning method, which comprises the following steps: (1) flushing cleaning liquid into the pipeline to be cleaned by using high-pressure gas pulses, and introducing ultrasonic waves; (2) injecting rinsing liquid or a gas-liquid mixture of the rinsing liquid and compressed gas into the pipeline; (3) introducing hot gas into the pipeline, and heating the temperature inside the pipeline to 90-160 ℃; (4) and introducing compressed gas with the temperature of 80-120 ℃ into the pipeline to obtain the cleaned steel pipe. The cleaning method comprises the steps of firstly cleaning grease on the inner surface of the steel pipe through cleaning liquid combined with high-pressure gas pulse and ultrasonic wave, and then further removing metal oxide and grease on the inner surface of the steel pipe under the action of rinsing liquid or rinsing liquid and compressed gas.

Description

Steel pipe cleaning method
Technical Field
The invention relates to a metal cleaning method, in particular to a steel pipe cleaning method.
Background
Steel pipes are manufactured using grease or metal oxides and further processed to remove these contaminants. Degreasing or pickling processes are generally used for the dirt, and means such as high-pressure washing, ultrasonic waves, brushes, cleaning balls and the like are used for improving the cleaning efficiency. The processes are effective in cleaning large-caliber pipes and the outer walls of the pipes, but the cleaning effect of the inner walls of the small-caliber pipes is not obvious. Therefore, it is necessary to develop a method for cleaning the inner wall of the small-diameter pipe.
Disclosure of Invention
The invention aims to overcome the defects in the prior art and provide a steel pipe cleaning method.
In order to achieve the purpose, the invention adopts the technical scheme that: a steel pipe cleaning method comprises the following steps:
(1) flushing cleaning liquid into the pipeline to be cleaned by using high-pressure gas pulses, and introducing ultrasonic waves; the pressure of the cleaning liquid is 1.0-3.5 MPa, the temperature is 30-50 ℃, and the flow speed is 3-15 m/s;
(2) injecting rinsing liquid or a gas-liquid mixture of the rinsing liquid and compressed gas into the pipeline;
(3) introducing hot gas into the pipeline, and heating the temperature inside the pipeline to 90-160 ℃;
(4) and introducing compressed gas with the temperature of 80-120 ℃ into the pipeline to obtain the cleaned steel pipe.
The cleaning method comprises the steps of firstly cleaning the grease on the inner surface of the steel pipe by using a cleaning solution in combination with high-pressure gas pulse and ultrasonic wave, wherein when the cleaning solution adopts the pressure, the temperature and the flow rate, the damage degree to the pipeline is small, and the cleaning effect on the attached grease is good; and then under the action of rinsing liquid or rinsing liquid and compressed gas, further removing metal oxides and grease on the inner surface of the steel pipe, and finally, raising the temperature in the pipeline to release active ingredients, namely the rinsing liquid and cleaning liquid, remained on the pipe wall to form an anti-rust layer. The method has the advantages of good cleaning effect, less cleaning times and low cleaning cost, and can solve the problem of cleaning metal oxides and grease on the inner wall of the small-caliber steel pipe.
As a preferred embodiment of the steel pipe cleaning method, the cleaning solution comprises the following components in percentage by weight: 25-35% of phosphoric acid, 5-10% of oxalic acid, 1-3% of triethanolamine oleate, 1-4% of an alcohol ether solvent and the balance of water. The cleaning liquid, the high-pressure gas pulse and the ultrasonic wave are combined to achieve a good grease removing effect. As a more preferable embodiment of the steel pipe cleaning method, the cleaning solution comprises the following components in percentage by weight: 30% of phosphoric acid, 8% of oxalic acid, 1.5% of triethanolamine oleate, 2.5% of alcohol ether solvent and the balance of water.
As a preferred embodiment of the steel pipe cleaning method, the rinsing liquid comprises the following components in percentage by weight: 13-17% of graphene dispersion, 18-22% of alkaline cleaning agent, 8-12% of dispersing agent and the balance of water. The graphene dispersion is insoluble in water, and can be left on the inner wall of the steel pipe after being cleaned to form a rust-proof layer by heating, and the dispersant is preferably propylene glycol methyl ether.
As a more preferable embodiment of the steel pipe cleaning method, the rinsing liquid comprises the following components in percentage by weight: 15% of graphene dispersion, 20% of alkaline cleaning agent, 10% of dispersing agent and the balance of water.
In a preferred embodiment of the method for cleaning a steel pipe according to the present invention, in the step (2), the pressure of the compressed gas is 0.4 to 0.8 MPa.
As a preferred embodiment of the steel pipe cleaning method, the alkaline cleaning agent comprises the following components in percentage by weight: 13-16% of sodium carbonate, 4-6% of sodium hydroxide, 12-17% of EDTA-2Na and the balance of water.
As a more preferable embodiment of the steel pipe cleaning method, the alkaline cleaning agent comprises the following components in percentage by weight: 15% of sodium carbonate, 5% of sodium hydroxide, 15% of EDTA-2Na and the balance of water.
As a preferable embodiment of the steel pipe cleaning method of the present invention, the hardness of the water is 0 to 20 degrees dGH, the chloride ion content is less than 100PPM, and the sulfur ion content is less than 100 PPM.
The invention has the beneficial effects that: the invention provides a steel pipe cleaning method. The cleaning method comprises the steps of firstly cleaning grease on the inner surface of the steel pipe through cleaning liquid combined with high-pressure gas pulse and ultrasonic wave, and then further removing metal oxide and grease on the inner surface of the steel pipe under the action of rinsing liquid or rinsing liquid and compressed gas.
Detailed Description
To better illustrate the objects, aspects and advantages of the present invention, the present invention will be further described with reference to specific examples.
Example 1
In an embodiment of the steel pipe cleaning method of the present invention, the steel pipe cleaning method includes the following steps:
(1) flushing cleaning liquid into a pipeline to be cleaned by using high-pressure gas pulses, and introducing ultrasonic waves, wherein the pressure of the cleaning liquid is 2MPa, the temperature of the cleaning liquid is 44 ℃, and the flow speed of the cleaning liquid is 10 m/s; the cleaning solution comprises the following components in percentage by weight: 30% of phosphoric acid, 8% of oxalic acid, 1.5% of triethanolamine oleate, 2.5% of an alcohol ether solvent and the balance of water;
(2) injecting rinsing liquid or a gas-liquid mixture of the rinsing liquid and compressed gas into the pipeline, wherein the rinsing liquid comprises the following components in percentage by weight: 15% of graphene dispersion, 20% of an alkaline cleaning agent, 10% of propylene glycol methyl ether and the balance of water, wherein the alkaline cleaning agent comprises the following components in percentage by weight: 15% of sodium carbonate, 5% of sodium hydroxide, 15% of EDTA-2Na and the balance of water; the pressure of the compressed gas is 0.5 MPa;
(3) introducing hot gas into the pipeline, and heating the temperature inside the pipeline to 100 ℃;
(4) and introducing compressed gas with the temperature of 110 ℃ and the pressure of 0.5MPa into the pipeline to obtain the cleaned steel pipe.
By adopting the method of the embodiment, more than 99% of grease and metal oxide attached to the inner wall of the steel pipe can be removed.
Example 2
In an embodiment of the steel pipe cleaning method of the present invention, the steel pipe cleaning method includes the following steps:
(1) flushing cleaning liquid into a pipeline to be cleaned by using high-pressure gas pulses, and introducing ultrasonic waves, wherein the pressure of the cleaning liquid is 3MPa, the temperature of the cleaning liquid is 30 ℃, and the flow speed of the cleaning liquid is 15 m/s; the cleaning solution comprises the following components in percentage by weight: 25% of phosphoric acid, 10% of oxalic acid, 1% of triethanolamine oleate, 4% of an alcohol ether solvent and the balance of water;
(2) injecting rinsing liquid or a gas-liquid mixture of the rinsing liquid and compressed gas into the pipeline, wherein the rinsing liquid comprises the following components in percentage by weight: 13% of graphene dispersion, 18% of an alkaline cleaning agent, 12% of propylene glycol methyl ether and the balance of water, wherein the alkaline cleaning agent comprises the following components in percentage by weight: 13% of sodium carbonate, 4% of sodium hydroxide, 17% of EDTA-2Na and the balance of water; the pressure of the compressed gas is 0.8 MPa;
(3) introducing hot gas into the pipeline, and heating the temperature inside the pipeline to 90 ℃;
(4) and introducing compressed gas with the temperature of 80 ℃ and the pressure of 0.8MPa into the pipeline to obtain the cleaned steel pipe.
By adopting the method of the embodiment, more than 98% of grease and metal oxide attached to the inner wall of the steel pipe can be removed.
Example 3
In an embodiment of the steel pipe cleaning method of the present invention, the steel pipe cleaning method includes the following steps:
(1) flushing cleaning liquid into a pipeline to be cleaned by using high-pressure gas pulses, and introducing ultrasonic waves, wherein the pressure of the cleaning liquid is 1MPa, the temperature is 50 ℃, and the flow speed is 10 m/s; the cleaning solution comprises the following components in percentage by weight: 25% of phosphoric acid, 5% of oxalic acid, 3% of triethanolamine oleate, 3% of an alcohol ether solvent and the balance of water;
(2) injecting rinsing liquid or a gas-liquid mixture of the rinsing liquid and compressed gas into the pipeline, wherein the rinsing liquid comprises the following components in percentage by weight: 15% of graphene dispersion, 22% of an alkaline cleaning agent, 8% of propylene glycol methyl ether and the balance of water, wherein the alkaline cleaning agent comprises the following components in percentage by weight: 16% of sodium carbonate, 4% of sodium hydroxide, 15% of EDTA-2Na and the balance of water; the pressure of the compressed gas is 0.5 MPa;
(3) introducing hot gas into the pipeline, and heating the temperature inside the pipeline to 120 ℃;
(4) and introducing compressed gas with the temperature of 100 ℃ and the pressure of 0.5MPa into the pipeline to obtain the cleaned steel pipe.
By adopting the method of the embodiment, more than 98% of grease and metal oxide attached to the inner wall of the steel pipe can be removed.
Example 4
In an embodiment of the steel pipe cleaning method of the present invention, the steel pipe cleaning method includes the following steps:
(1) flushing cleaning liquid into a pipeline to be cleaned by using high-pressure gas pulses, and introducing ultrasonic waves, wherein the pressure of the cleaning liquid is 3.5MPa, the temperature is 35 ℃, and the flow speed is 3 m/s; the cleaning solution comprises the following components in percentage by weight: 20% of phosphoric acid, 10% of oxalic acid, 3% of triethanolamine oleate, 1% of an alcohol ether solvent and the balance of water;
(2) injecting rinsing liquid or a gas-liquid mixture of the rinsing liquid and compressed gas into the pipeline, wherein the rinsing liquid comprises the following components in percentage by weight: 17% of graphene dispersion, 18% of an alkaline cleaning agent, 10% of propylene glycol methyl ether and the balance of water, wherein the alkaline cleaning agent comprises the following components in percentage by weight: 15% of sodium carbonate, 6% of sodium hydroxide, 12% of EDTA-2Na and the balance of water; the pressure of the compressed gas is 0.4 MPa;
(3) introducing hot gas into the pipeline, and heating the temperature inside the pipeline to 160 ℃;
(4) and introducing compressed gas with the temperature of 120 ℃ and the pressure of 0.4MPa into the pipeline to obtain the cleaned steel pipe.
By adopting the method of the embodiment, more than 98% of grease and metal oxide attached to the inner wall of the steel pipe can be removed.
Finally, it should be noted that the above embodiments are only used for illustrating the technical solutions of the present invention and not for limiting the protection scope of the present invention, and although the present invention is described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications or equivalent substitutions can be made on the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention.

Claims (9)

1. A steel pipe cleaning method is characterized by comprising the following steps:
(1) flushing cleaning liquid into the pipeline to be cleaned by using high-pressure gas pulses, and introducing ultrasonic waves; the pressure of the cleaning liquid is 1.0-3.5 MPa, the temperature is 30-50 ℃, and the flow speed is 3-15 m/s;
(2) injecting rinsing liquid or a gas-liquid mixture of the rinsing liquid and compressed gas into the pipeline;
(3) introducing hot gas into the pipeline, and heating the temperature inside the pipeline to 90-160 ℃;
(4) and introducing compressed gas with the temperature of 80-120 ℃ into the pipeline to obtain the cleaned steel pipe.
2. The steel pipe cleaning method according to claim 1, wherein the cleaning solution comprises the following components in percentage by weight: 25-35% of phosphoric acid, 5-10% of oxalic acid, 1-3% of triethanolamine oleate, 1-4% of an alcohol ether solvent and the balance of water.
3. The steel pipe cleaning method according to claim 2, wherein the cleaning solution comprises the following components in percentage by weight: 30% of phosphoric acid, 8% of oxalic acid, 1.5% of triethanolamine oleate, 2.5% of alcohol ether solvent and the balance of water.
4. The steel pipe cleaning method according to claim 1, wherein the rinsing liquid comprises the following components in percentage by weight: 13-17% of graphene dispersion, 18-22% of alkaline cleaning agent, 8-12% of dispersing agent and the balance of water.
5. The steel pipe cleaning method according to claim 4, wherein the rinsing liquid comprises the following components in percentage by weight: 15% of graphene dispersion, 20% of alkaline cleaning agent, 10% of dispersing agent and the balance of water.
6. The steel pipe cleaning method according to claim 1, wherein in the step (2), the pressure of the compressed gas is 0.4 to 0.8 MPa.
7. The steel pipe cleaning method according to claim 4, wherein the alkaline cleaning agent comprises the following components in percentage by weight: 13-16% of sodium carbonate, 4-6% of sodium hydroxide, 12-17% of EDTA-2Na and the balance of water.
8. The steel pipe cleaning method according to claim 7, wherein the alkaline cleaning agent comprises the following components in percentage by weight: 15% of sodium carbonate, 5% of sodium hydroxide, 15% of EDTA-2Na and the balance of water.
9. The method for cleaning a steel pipe as claimed in any one of claims 1 to 8, wherein the hardness of the water is 0 to 20 ° dGH, the chloride ion content is less than 100PPM, and the sulfur ion content is less than 100 PPM.
CN201911172532.2A 2019-11-26 2019-11-26 Steel pipe cleaning method Pending CN112845413A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201911172532.2A CN112845413A (en) 2019-11-26 2019-11-26 Steel pipe cleaning method

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101768746A (en) * 2008-12-31 2010-07-07 中国蓝星(集团)股份有限公司 Cleaning agent special for stainless steel and preparation method and application thereof
CN203091341U (en) * 2013-01-10 2013-07-31 薛兆旺 Water body pipeline cleaning device
CN104674251A (en) * 2015-03-12 2015-06-03 武汉钢铁(集团)公司 Degreasing agent for cold-rolled continuous annealing unit
CA2984779A1 (en) * 2017-11-06 2018-01-10 Danny D. L. Livshitz Method for preventing deposits in pipes
CN107828550A (en) * 2017-11-22 2018-03-23 广东桑海环保有限公司 A kind of efficient alkaline cleaning agent and preparation method thereof
CN108188116A (en) * 2017-12-29 2018-06-22 厦门日村环保科技有限公司 A kind of pipeline pulse cleaning technique
US20190017362A1 (en) * 2016-09-27 2019-01-17 Huazhong University Of Science And Technology Pipeline descaling and rock stratum fracturing device based on electro-hydraulic pulse shock waves

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101768746A (en) * 2008-12-31 2010-07-07 中国蓝星(集团)股份有限公司 Cleaning agent special for stainless steel and preparation method and application thereof
CN203091341U (en) * 2013-01-10 2013-07-31 薛兆旺 Water body pipeline cleaning device
CN104674251A (en) * 2015-03-12 2015-06-03 武汉钢铁(集团)公司 Degreasing agent for cold-rolled continuous annealing unit
US20190017362A1 (en) * 2016-09-27 2019-01-17 Huazhong University Of Science And Technology Pipeline descaling and rock stratum fracturing device based on electro-hydraulic pulse shock waves
CA2984779A1 (en) * 2017-11-06 2018-01-10 Danny D. L. Livshitz Method for preventing deposits in pipes
CN107828550A (en) * 2017-11-22 2018-03-23 广东桑海环保有限公司 A kind of efficient alkaline cleaning agent and preparation method thereof
CN108188116A (en) * 2017-12-29 2018-06-22 厦门日村环保科技有限公司 A kind of pipeline pulse cleaning technique

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
姜山: "纳米", 科学普及出版社, pages: 179 *

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