CN112830684A - High-strength low-radiation coated hollow glass for energy-saving building and preparation method thereof - Google Patents

High-strength low-radiation coated hollow glass for energy-saving building and preparation method thereof Download PDF

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Publication number
CN112830684A
CN112830684A CN202110396205.6A CN202110396205A CN112830684A CN 112830684 A CN112830684 A CN 112830684A CN 202110396205 A CN202110396205 A CN 202110396205A CN 112830684 A CN112830684 A CN 112830684A
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hollow glass
glass
layer
strength
splicing
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顾军
许乃伟
耿云飞
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Nantong Datong Decoration Engineering Co ltd
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Nantong Datong Decoration Engineering Co ltd
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Priority to CN202110396205.6A priority Critical patent/CN112830684A/en
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/42Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating of an organic material and at least one non-metal coating
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C27/00Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
    • C03C27/06Joining glass to glass by processes other than fusing
    • C03C27/10Joining glass to glass by processes other than fusing with the aid of adhesive specially adapted for that purpose
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00Methods for coating glass
    • C03C2218/10Deposition methods
    • C03C2218/15Deposition methods from the vapour phase
    • C03C2218/154Deposition methods from the vapour phase by sputtering
    • C03C2218/156Deposition methods from the vapour phase by sputtering by magnetron sputtering

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Joining Of Glass To Other Materials (AREA)

Abstract

The invention discloses high-strength low-radiation coated hollow glass for an energy-saving building and a preparation method thereof. According to the invention, the stability of the hollow glass main body can be effectively maintained through the spacing soft strips and the stable extrusion of the wafer, the shaking of the hollow glass main body in the stable groove is reduced, the hollow glass main body is convenient to use in various environments, the strength and stability of the hollow glass main body are further improved, the ultraviolet absorption efficiency of the hollow glass main body can be improved through the radiation layer, the stimulation of ultraviolet to personnel is effectively blocked, the safety of the personnel is further protected, the falling caused by unstable splicing is reduced, and the use efficiency is improved.

Description

High-strength low-radiation coated hollow glass for energy-saving building and preparation method thereof
The invention relates to the field of hollow glass, in particular to high-strength low-radiation coated hollow glass for an energy-saving building and a preparation method thereof.
Background
The hollow glass invented by Americans in 1865 is a new type building material with good heat-insulating, sound-insulating, beautiful and applicable properties and capable of reducing self-weight of building, and is made up by using two (or three) sheets of glass and using high-strength high-air-tightness composite adhesive to make the glass sheet and aluminium alloy frame containing drying agent be adhered together so as to obtain the invented high-effective sound-insulating and heat-insulating glass. The hollow glass has various properties superior to those of common double-layer glass, so that the hollow glass is accepted by all countries in the world, and two or more pieces of glass are effectively supported and uniformly separated and are bonded and sealed at the periphery, so that a dry gas space is formed between glass layers. The main materials are glass, warm edge spacing strips, corner bolts, butyl rubber, polysulfide glue and drying agents.
The prior hollow glass is generally used in buildings, and the following three problems exist today:
1. in the using process, the hollow glass is generally directly installed by using a glass material, but in the using process, the strength of the hollow glass is relatively low, and the application range of the hollow glass is relatively low.
2. The hollow glass has relative length, needs relative splicing in the installation process, is generally directly fixed by a fixing bolt, and is easy to damage the hollow glass.
3. The hollow glass is relatively fragile in the installation process, and if the hollow glass is knocked against corners carelessly, the whole glass can be broken.
Aiming at the defects, certain adverse effects are brought to the using process of people, and a filtering device for a tap water sand filter is provided.
Disclosure of Invention
Based on the technical problems in the background art, the invention provides high-strength low-radiation coated hollow glass for an energy-saving building and a preparation method thereof, and the high-strength low-radiation coated hollow glass has the advantages of high strength and convenience in splicing and protecting the hollow glass.
In order to achieve the purpose, the invention provides the following technical scheme: the utility model provides an energy-conserving for building high strength low radiation coating film cavity glass, includes the cavity glass main part, the upper and lower both ends surface of cavity glass main part is provided with inhales the magnetic sheet, the left and right sides of cavity glass main part is provided with splicing mechanism, both ends are provided with high strength mechanism around the cavity glass main part, the inside of cavity glass main part is provided with protection machanism, high strength mechanism includes high strength layer, coating film layer, radiation layer and inoxidizing coating.
Preferably, be integrated into one piece between cavity glass main part and the high strength mechanism in advance, inhale and be provided with fixing bolt No. one between magnetic sheet and the cavity glass main part, and the upper and lower both ends surface of cavity glass main part through a fixing bolt and inhale the outer wall fixed connection of magnetic sheet, be provided with the recess No. one between cavity glass main part and the concatenation mechanism, and the outer wall fixed connection of recess and concatenation mechanism is passed through to the left and right sides surface of cavity glass main part, be provided with the recess No. two between cavity glass main part and the protection mechanism, and the inside of cavity glass main part is through the outer wall fixed connection of recess No. two and protection mechanism.
Preferably, the high strength layer is located the lower extreme surface on coating film layer, the radiation layer is located the lower extreme surface on high strength layer, the inoxidizing coating is located the lower extreme surface on radiation layer, be provided with the fixed glue No. one between high strength layer and the coating film layer, and the outer surface of the upper end on high strength layer is connected through the lower extreme surface fixed of a fixed glue and coating film layer, be provided with the fixed glue No. two between high strength layer and the radiation layer, and the lower extreme surface on high strength layer is connected through the upper end surface fixed of No. two fixed glues and radiation layer, be provided with the fixed glue No. three between radiation layer and the inoxidizing coating, and the lower extreme surface on radiation layer is connected through the upper end surface fixed of No. three fixed glues and inoxidizing coating.
The utility model provides an energy-conserving for building high strength low radiation coating film cavity glass's mosaic structure, includes splicing mechanism, splicing mechanism includes buckle subassembly, concatenation recess, buffering soft piece, concatenation frame and extrusion spring, the concatenation recess has been seted up to the front end surface of concatenation frame, buckle subassembly is located the inside of concatenation recess, buffering soft piece is located the front end surface of concatenation frame and is located the upper end of concatenation recess, the extrusion spring is located the inside of concatenation recess and is located the rear end surface of buckle subassembly.
Preferably, be provided with the powerful glue No. one between buffering soft piece and the concatenation frame, and the rear end surface of buffering soft piece is connected through the front end surface fixed connection of a powerful glue and concatenation frame, be provided with four good fixed glues between extrusion spring and the concatenation frame, and the front end of concatenation frame is inside to be connected through the rear end surface fixed connection of No. four fixed glues and concatenation recess and extrusion spring, be provided with No. five fixed glues between buckle subassembly and the extrusion spring, and the front end surface of extrusion spring is connected through the rear end surface fixed connection of No. five fixed glues and buckle subassembly, buckle subassembly's outer wall is through the front end surface swing joint of extrusion spring and concatenation recess and concatenation frame.
A protective structure of high-strength low-radiation coated hollow glass for energy-saving buildings comprises a protective mechanism, the protection mechanism comprises a protection shell, a hollow glass barrier plate, a spacing soft strip, a sealing gasket, a protection soft cushion, a stable groove, a stable extrusion wafer and an extrusion circular groove, the sealing gasket is positioned on the outer surface of the front end of the protective shell, the spacing soft strip is positioned on the outer surface of the front end of the sealing gasket, the hollow glass baffle plate is positioned on the outer surface of the front end of the protective shell and penetrates through the wall body of the sealing gasket, the hollow glass baffle plates are positioned at the upper end and the lower end of the spacing soft strip, the inner surfaces of the upper end and the lower end of the protective shell are provided with extrusion circular grooves, the firm extrusion disk is located the inside of extrusion circular slot and extends to the protective housing outside, stable recess has been seted up between protective housing and the hollow glass barrier plate, the protection cushion is located one side internal surface of stable recess.
Preferably, through welded connection between cavity glass barrier plate and the protective housing, be provided with No. two super glue between protective cushion and the stable recess, and the outer wall of protective cushion through No. two fixed glue and the inner wall fixed connection who stabilizes the recess, be provided with No. three super glue between sealed pad and the protective housing, and the sealed rear end surface of filling up is through No. three super glue and protective housing's front end fixed surface connection, be provided with No. four super glue between the soft strip of interval and the sealed pad, and the rear end surface of the soft strip of interval is through No. four super glue and sealed front end fixed surface connection who fills up, be provided with No. five super glue between firm extrusion disk and the protective housing, and the outer wall of firm extrusion disk is through No. five super glue and the upper and lower both ends fixed surface connection of extrusion circular slot and protective housing.
Preferably, the method comprises the following steps:
s1, selecting materials: selecting materials such as 30-50 parts of organic glass, 2-5 parts of light stabilizer, 1-2 parts of photocatalyst, 1-2 parts of stearic acid, 2-3 parts of composite ultraviolet absorbent, 1-2 parts of silicon nitride, 1-2 parts of fluorine-doped zirconia, 1-2 parts of nano liquid glass and the like;
s2, mixing: the selected materials are poured into a mixer to be mixed, so that the materials are convenient to mix, the mixed materials are pushed out of the mixer through a double screw, and then granulation is carried out through a granulator;
s3, plating: directly sputtering silicon nitride substances and fluorine-doped zirconium oxide substances on silicon nitride by a vacuum magnetron sputtering method, wherein the sputtering thickness of the silicon nitride is controlled to be between 10 and 30 nanometers, the fluorine content in the fluorine-doped zirconium oxide is 1 to 2 weight percent, and the sputtering thickness is between 25 and 30 nanometers;
s4, glass substance: sputtering the nano liquid glass into a nano liquid glass substance by a vacuum sputtering method, wherein the sputtering thickness is between 150 and 220 nanometers, and sputtering the composite ultraviolet absorbent substance by the vacuum sputtering method to obtain an organic layer, wherein the thickness is between 35 and 50 nanometers;
s5, tidiness: the glass substrate is placed into an ultrasonic cleaning machine for cleaning, so that dust and impurities on the glass substrate are cleaned;
s6, vacuum standby: the cleaned glass substrate is placed in a vacuum cavity, air is pumped by a vacuum air pump, so that the interior of the vacuum cavity is kept vacuum, and then high-purity neon of 1000-2000sccm is filled into a sputtering silicon target, so that the target is convenient to clean;
s7, catalysis: the light stabilizer is a mixture of UV-531, UV-234, UV-326 and UV-328, and the photocatalyst is titanium dioxide powder with particles positioned at 20-90 nanometers;
s8, preparation: and after the required thickness is reached, closing the target, sequentially preparing the fluorine-doped zirconium oxide substance, the silicon nitride substance and the nano liquid glass substance by using high-purity neon, performing framing and laminating procedures after the preparation is finished, preparing the hollow glass, and finally performing gluing and sealing by using a glass sealant.
Advantageous effects
The method can increase the strength of the hollow glass main body through the high-strength layer, reduce the damage of the hollow glass main body caused by careless collision in the use process of the hollow glass main body, the coating layer can correspondingly coat the hollow glass main body, the effect of the hollow glass main body can be increased, the radiation layer can increase the ultraviolet absorption efficiency of the hollow glass main body, effectively block the stimulation of ultraviolet rays to personnel, and further protect the safety of the personnel, wherein the radiation layer is made of a composite ultraviolet absorbent, the protective layer is made of glass fiber, the high-strength layer is made of plastic fiber, when the hollow glass main body needs to be used, a worker can conveniently fit two opposite parts through a clamping groove, the buffer soft block can play the roles of buffering and protection, and the stability of the hollow glass main body in the splicing process can be further improved, then the buckle component can conveniently enter the hollow glass main body under the action of the extrusion spring, thereby keeping the stability of the two hollow glass main bodies, reducing the falling caused by unstable splicing, improving the use efficiency, being convenient for the hollow glass main bodies to be arranged in the protective shell through the stable groove, wherein the protective soft cushion can effectively protect the safety of the hollow glass main body, reduce the damage of the hollow glass main body caused by the extrusion of the protective shell and the hollow glass baffle plate, the sealing gasket can facilitate the contact between the hollow glass main body and the protective shell, further protect the safety of the hollow glass main body, wherein the soft strip of interval and firm extrusion disk can effectually keep the stability of cavity glass main part, reduce cavity glass main part and rock in stabilizing the recess inside, make things convenient for cavity glass main part to use in various environment, further increase cavity glass main part's intensity and stability.
Drawings
FIG. 1 is a schematic view of the overall structure of a high-strength low-emissivity coated hollow glass for energy-saving buildings according to the invention.
Fig. 2 is a structural analysis diagram of a high-strength mechanism of the high-strength low-emissivity coated hollow glass for the energy-saving building.
Fig. 3 is a schematic diagram of a splicing mechanism of the high-strength low-emissivity coated hollow glass for the energy-saving building.
Fig. 4 is a side sectional view of a splicing mechanism of the high-strength low-emissivity coated hollow glass for the energy-saving building.
Fig. 5 is a schematic diagram of a protection mechanism of the high-strength low-emissivity coated hollow glass for the energy-saving building.
In the figure: 1. a hollow glass body; 2. a high-strength mechanism; 3. a splicing mechanism; 4. a protection mechanism; 5. a magnetic attraction plate; 201. a high-strength layer; 202. coating a film layer; 203. a radiation layer; 204. a protective layer; 301. a buckle assembly; 302. splicing the grooves; 303. buffering the soft block; 304. splicing the frames; 305. a compression spring; 401. a protective housing; 402. a hollow glass barrier plate; 403. spacing soft strips; 404. a gasket; 405. a protective cushion; 406. a stabilizing recess; 407. firmly extruding the wafer; 408. and extruding the circular groove.
Detailed Description
In order to make the technical means, the creation characteristics, the achievement purposes and the effects of the invention easy to understand, the invention is further described with the specific embodiments.
In the description of the present invention, it should be noted that the terms "upper", "lower", "inner", "outer", "front", "rear", "both ends", "one end", "the other end", and the like indicate orientations or positional relationships based on those shown in the drawings, and are only for convenience of description and simplicity of description, but do not indicate or imply that the referred device or element must have a specific orientation, be constructed in a specific orientation, and be operated, and thus, should not be construed as limiting the present invention. Furthermore, the terms "first" and "second" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance.
In the description of the present invention, it is to be noted that, unless otherwise explicitly specified or limited, the terms "mounted," "disposed," "connected," and the like are to be construed broadly, such as "connected," which may be fixedly connected, detachably connected, or integrally connected; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meanings of the above terms in the present invention can be understood in specific cases to those skilled in the art.
Detailed description of the preferred embodiment
The embodiment is an embodiment of high-strength low-radiation coated hollow glass for an energy-saving building.
As shown in fig. 1-2, the hollow glass comprises a hollow glass body 1, magnetic absorption plates 5 are arranged on the outer surfaces of the upper end and the lower end of the hollow glass body 1, splicing mechanisms 3 are arranged on the left side and the right side of the hollow glass body 1, high-strength mechanisms 2 are arranged on the front end and the rear end of the hollow glass body 1, a protection mechanism 4 is arranged inside the hollow glass body 1, and each high-strength mechanism 2 comprises a high-strength layer 201, a coating layer 202, a radiation layer 203 and a protection layer 204.
The hollow glass main body 1 and the high-strength mechanism 2 are integrally formed, a first fixing bolt is arranged between the magnetic absorption plate 5 and the hollow glass main body 1, the outer surfaces of the upper end and the lower end of the hollow glass main body 1 are fixedly connected with the outer wall of the magnetic absorption plate 5 through the first fixing bolt, a first groove is arranged between the hollow glass main body 1 and the splicing mechanism 3, the outer surfaces of the left side and the right side of the hollow glass main body 1 are fixedly connected with the outer wall of the splicing mechanism 3 through the first groove, a second groove is arranged between the hollow glass main body 1 and the protection mechanism 4, and the interior of the hollow glass main body 1 is fixedly connected with the outer wall of the protection mechanism 4 through the second groove; high strength layer 201 is located the lower extreme surface of coating film layer 202, radiation layer 203 is located the lower extreme surface of high strength layer 201, inoxidizing coating 204 is located the lower extreme surface of radiation layer 203, be provided with the fixed glue No. one between high strength layer 201 and the coating film layer 202, and the outer surface of the upper end of high strength layer 201 is connected with the lower extreme surface fixed connection of coating film layer 202 through the fixed glue No. one, be provided with the fixed glue No. two between high strength layer 201 and the radiation layer 203, and the lower extreme surface of high strength layer 201 is connected with the upper end surface fixed connection of radiation layer 203 through the fixed glue No. two, be provided with the fixed glue No. three between radiation layer 203 and the inoxidizing coating 204, and the lower extreme surface of radiation layer 203 is connected with the upper end surface fixed connection of inoxidi.
It should be noted that, the invention is a high-strength low-radiation coated hollow glass for energy-saving buildings, the strength of the hollow glass main body 1 can be increased through the high-strength layer 201, the damage to the hollow glass main body 1 caused by careless collision in the use process of the hollow glass main body 1 is reduced, the coating layer 202 can correspondingly coat the hollow glass main body 1, the effect of the hollow glass main body 1 can be increased, the radiation layer 203 can increase the ultraviolet absorption efficiency of the hollow glass main body 1, the stimulation of ultraviolet to personnel is effectively blocked, and the safety of personnel is further protected, wherein the radiation layer 203 is made of a composite ultraviolet absorbent, the protective layer 204 is made of glass fiber, and the high-strength layer 201 is made of plastic fiber.
Detailed description of the invention
The embodiment is an embodiment of a splicing structure in high-strength low-radiation coated hollow glass for an energy-saving building.
As shown in fig. 1, 3 and 4, the splicing mechanism 3 includes a buckle assembly 301, a splicing groove 302, a soft buffer block 303, a splicing frame 304 and an extrusion spring 305, the splicing groove 302 is provided on the front end outer surface of the splicing frame 304, the buckle assembly 301 is located inside the splicing groove 302, the soft buffer block 303 is located on the front end outer surface of the splicing frame 304 and located at the upper end of the splicing groove 302, and the extrusion spring 305 is located inside the splicing groove 302 and located on the rear end outer surface of the buckle assembly 301.
Be provided with the super glue between buffering soft mass 303 and the concatenation frame 304, and the rear end surface of buffering soft mass 303 is through the front end surface fixed connection of super glue and concatenation frame 304, be provided with four good fixed glues between extrusion spring 305 and the concatenation frame 304, and the front end of concatenation frame 304 is inside through four fixed glues and the rear end surface fixed connection of concatenation recess 302 and extrusion spring 305, be provided with No. five fixed glues between buckle subassembly 301 and the extrusion spring 305, and the front end surface of extrusion spring 305 is through the rear end surface fixed connection of No. five fixed glues and buckle subassembly 301, the outer wall of buckle subassembly 301 passes through the front end surface swing joint of extrusion spring 305 and concatenation recess 302 and concatenation frame 304.
It should be noted that, the invention is a high-strength low-radiation coated hollow glass for energy-saving buildings, when the hollow glass main body 1 needs to be used, a worker can conveniently fit the two opposite hollow glass main bodies through the clamping groove, wherein the buffering soft block 303 can play a role in buffering and protecting, the stability of the splicing process of the hollow glass main bodies 1 can be further improved, and then the buckle assembly 301 can conveniently enter the hollow glass main bodies 1 under the action of the extrusion spring 305, so that the stability of the two hollow glass main bodies 1 is maintained, the falling caused by unstable splicing is reduced, and the use efficiency is improved.
Detailed description of the preferred embodiment
The embodiment is an embodiment of a protective structure in high-strength low-radiation coated hollow glass for an energy-saving building.
As shown in fig. 1 and 5, the protection mechanism 4 includes a protection housing 401, a hollow glass barrier plate 402, a spacer soft strip 403, a sealing gasket 404, a protection cushion 405, a stabilizing groove 406, a stable extrusion disc 407 and an extrusion circular groove 408, where the sealing gasket 404 is located on the front end outer surface of the protection housing 401, the spacer soft strip 403 is located on the front end outer surface of the sealing gasket 404, the hollow glass barrier plate 402 is located on the front end outer surface of the protection housing 401 and penetrates through the wall body of the sealing gasket 404, the hollow glass barrier plate 402 is located on the upper and lower ends of the spacer soft strip 403, the extrusion circular groove 408 is opened on the inner surface of the upper and lower ends of the protection housing 401, the stable extrusion disc 407 is located inside the extrusion circular groove 408 and extends to the outside of the protection housing 401, the stabilizing groove 406 is opened between the protection housing 401 and the hollow glass barrier plate 402.
The hollow glass stop plate 402 is connected with the protective shell 401 through welding, a second super glue is arranged between the protective cushion 405 and the stabilizing groove 406, the outer wall of the protective cushion 405 is fixedly connected with the inner wall of the stabilizing groove 406 through a second fixing glue, a third super glue is arranged between the sealing gasket 404 and the protective shell 401, the outer surface of the rear end of the sealing gasket 404 is fixedly connected with the outer surface of the front end of the protective shell 401 through the third super glue, a fourth super glue is arranged between the spacing soft strip 403 and the sealing gasket 404, the outer surface of the rear end of the spacing soft strip 403 is fixedly connected with the outer surface of the front end of the sealing gasket 404 through the fourth super glue, a fifth super glue is arranged between the stable extrusion wafer 407 and the protective shell 401, and the outer wall of the stable extrusion wafer 407 is fixedly connected with the inner surfaces of the upper end and the lower end of the protective shell 401 through the fifth super.
It should be noted that the invention is a high-strength low-emissivity coated hollow glass for energy-saving buildings, the hollow glass main body 1 can be conveniently installed inside the protective housing 401 through the stabilizing groove 406, wherein the protective cushion 405 can effectively protect the safety of the hollow glass main body 1, damage to the hollow glass main body 1 caused by extrusion of the protective housing 401 and the hollow glass barrier plate 402 is reduced, the sealing gasket 404 can facilitate contact between the hollow glass main body 1 and the protective housing 401, and further protect the safety of the hollow glass main body 1, wherein the spacing soft strips 403 and the stabilizing extrusion wafers 407 can effectively maintain the stability of the hollow glass main body 1, reduce shaking of the hollow glass main body 1 inside the stabilizing groove 406, facilitate use of the hollow glass main body 1 in various environments, and further increase the strength and stability of the hollow glass main body 1.
Detailed description of the invention
A preparation method of high-strength low-radiation coated hollow glass for energy-saving buildings comprises the following steps:
s1, selecting materials: selecting materials such as 30-50 parts of organic glass, 2-5 parts of light stabilizer, 1-2 parts of photocatalyst, 1-2 parts of stearic acid, 2-3 parts of composite ultraviolet absorbent, 1-2 parts of silicon nitride, 1-2 parts of fluorine-doped zirconia, 1-2 parts of nano liquid glass and the like;
s2, mixing: pouring the selected materials into a mixer for mixing, so as to facilitate the mixing of the materials, pushing the mixed materials out of the mixer through a double screw, and then granulating through a granulator;
s3, plating: directly sputtering silicon nitride substances and fluorine-doped zirconium oxide substances on silicon nitride by a vacuum magnetron sputtering method, wherein the sputtering thickness of the silicon nitride is controlled to be between 10 and 30 nanometers, the fluorine content in the fluorine-doped zirconium oxide is 1 to 2 weight percent, and the sputtering thickness is between 25 and 30 nanometers;
s4, glass substance: sputtering the nano liquid glass into a nano liquid glass substance by a vacuum sputtering method, wherein the sputtering thickness is between 150 and 220 nanometers, and sputtering the composite ultraviolet absorbent substance by the vacuum sputtering method to obtain an organic layer, wherein the thickness is between 35 and 50 nanometers;
s5, tidiness: putting the glass substrate into an ultrasonic cleaning machine for cleaning, thereby cleaning dust and impurities on the glass substrate;
s6, vacuum standby: placing the cleaned glass substrate into a vacuum cavity, exhausting by a vacuum air pump so as to keep the interior of the vacuum cavity vacuum, and then filling high-purity neon of 1000-plus-2000 sccm into the sputtering silicon target so as to conveniently clean the target;
s7, catalysis: the light stabilizer is a mixture of UV-531, UV-234, UV-326 and UV-328, and the photocatalyst is titanium dioxide powder with particles positioned at 20-90 nanometers;
s8, preparation: and closing the target after the required thickness is reached, then preparing the fluorine-doped zirconium oxide substance, the silicon nitride substance and the nano liquid glass substance by using high-purity neon in sequence, performing framing and laminating procedures after the preparation is finished to prepare hollow glass, and finally performing gluing and sealing by using glass sealant.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.

Claims (8)

1. The utility model provides an energy-conserving for building high strength low radiation coating film cavity glass, includes cavity glass main part (1), its characterized in that: the outer surface of the upper end and the lower end of the hollow glass main body (1) are provided with magnetic absorption plates (5), the left side and the right side of the hollow glass main body (1) are provided with splicing mechanisms (3), high-strength mechanisms (2) are arranged at the front end and the rear end of the hollow glass main body (1), a protection mechanism (4) is arranged inside the hollow glass main body (1), and each high-strength mechanism (2) comprises a high-strength layer (201), a coating layer (202), a radiation layer (203) and a protection layer (204).
2. The high-strength low-emissivity coated hollow glass for the energy-saving building according to claim 1, wherein the coating layer comprises: be integrated into one piece between cavity glass main part (1) and high strength mechanism (2) in advance, inhale and be provided with fixing bolt between magnetic sheet (5) and cavity glass main part (1), and the upper and lower both ends surface of cavity glass main part (1) through fixing bolt and the outer wall fixed connection who inhales magnetic sheet (5), be provided with the recess between cavity glass main part (1) and splicing mechanism (3) No. one, and the outer wall fixed connection of the left and right sides surface of cavity glass main part (1) through recess and splicing mechanism (3), be provided with the recess No. two between cavity glass main part (1) and protection machanism (4), and the inside of cavity glass main part (1) is through the outer wall fixed connection of recess No. two and protection machanism (4).
3. The high-strength low-emissivity coated hollow glass for the energy-saving building according to claim 1, wherein the coating layer comprises: the high-strength layer (201) is positioned on the outer surface of the lower end of the coating layer (202), the radiation layer (203) is positioned on the outer surface of the lower end of the high-strength layer (201), the protective layer (204) is positioned on the outer surface of the lower end of the radiation layer (203), a first fixing adhesive is arranged between the high-strength layer (201) and the coating layer (202), the outer surface of the upper end of the high-strength layer (201) is fixedly connected with the outer surface of the lower end of the coating layer (202) through a first fixing adhesive, a second fixing glue is arranged between the high-strength layer (201) and the radiation layer (203), the outer surface of the lower end of the high-strength layer (201) is fixedly connected with the outer surface of the upper end of the radiation layer (203) through a second fixing glue, a third fixing glue is arranged between the radiation layer (203) and the protective layer (204), and the outer surface of the lower end of the radiation layer (203) is fixedly connected with the outer surface of the upper end of the protective layer (204) through a third fixing glue.
4. The utility model provides an energy-conserving for building high strength low radiation coated hollow glass's mosaic structure, includes splicing mechanism (3), its characterized in that: splicing mechanism (3) are including buckle subassembly (301), concatenation recess (302), buffering soft block (303), concatenation frame (304) and extrusion spring (305), concatenation recess (302) have been seted up to the front end surface of concatenation frame (304), buckle subassembly (301) are located the inside of concatenation recess (302), buffering soft block (303) are located the front end surface of concatenation frame (304) and are located the upper end of concatenation recess (302), extrusion spring (305) are located the inside of concatenation recess (302) and are located the rear end surface of buckle subassembly (301).
5. The high-strength low-emissivity coated hollow glass for energy-saving buildings according to claim 4, wherein the coating glass comprises: a first super glue is arranged between the buffering soft block (303) and the splicing frame (304), the outer surface of the rear end of the buffering soft block (303) is fixedly connected with the outer surface of the front end of the splicing frame (304) through a first super glue, four fixing glue is arranged between the extrusion spring (305) and the splicing frame (304), the inner part of the front end of the splicing frame (304) is fixedly connected with the outer surface of the rear end of the extrusion spring (305) through a fourth fixing adhesive and a splicing groove (302), a fifth fixing glue is arranged between the buckle component (301) and the extrusion spring (305), and the outer surface of the front end of the extrusion spring (305) is fixedly connected with the outer surface of the rear end of the buckle component (301) through a fifth fixing glue, the outer wall of the buckle assembly (301) is movably connected with the outer surface of the front end of the splicing frame (304) through an extrusion spring (305) and a splicing groove (302).
6. The utility model provides an energy-conserving for building high strength low radiation coated hollow glass's protective structure, includes protection machanism (4), its characterized in that: the protection mechanism (4) comprises a protection shell (401), a hollow glass blocking plate (402), a spacing soft strip (403), a sealing gasket (404), a protection cushion (405), a stable groove (406), a stable extrusion circular sheet (407) and an extrusion circular groove (408), wherein the sealing gasket (404) is positioned on the outer surface of the front end of the protection shell (401), the spacing soft strip (403) is positioned on the outer surface of the front end of the sealing gasket (404), the hollow glass blocking plate (402) is positioned on the outer surface of the front end of the protection shell (401) and penetrates through the wall body of the sealing gasket (404), the hollow glass blocking plate (402) is positioned at the upper end and the lower end of the spacing soft strip (403), the extrusion circular groove (408) is arranged on the inner surface of the upper end and the lower end of the protection shell (401), the stable extrusion circular sheet (407) is positioned in the extrusion circular groove (408) and extends to the outside of, a stabilizing groove (406) is formed between the protective shell (401) and the hollow glass barrier plate (402), and the protective soft cushion (405) is located on the inner surface of one side of the stabilizing groove (406).
7. The high-strength low-emissivity coated hollow glass for energy-saving buildings according to claim 6, wherein the coating glass comprises: through welded connection between cavity glass stop plate (402) and protective housing (401), be provided with No. two super glue between protective cushion (405) and the stable recess (406), and the outer wall of protective cushion (405) through No. two fixed glue and the inner wall fixed connection who stabilizes recess (406), be provided with No. three super glue between sealed pad (404) and protective housing (401), and the rear end surface of sealed pad (404) passes through the front end surface fixed connection of No. three super glue and protective housing (401), be provided with No. four super glue between interval soft strip (403) and sealed pad (404), and the rear end surface of interval soft strip (403) passes through No. four super glue and the front end surface fixed connection who seals up pad (404), be provided with No. five super glue between firm extrusion wafer (407) and protective housing (401), and the outer wall of firm extrusion wafer (407) passes through No. five super glue and extrusion circular slot (408) and protective housing (401) The inner surfaces of the upper end and the lower end of the connecting rod are fixedly connected.
8. A preparation method of high-strength low-radiation coated hollow glass for energy-saving buildings is characterized by comprising the following steps: the method comprises the following steps:
s1, selecting materials: selecting materials such as 30-50 parts of organic glass, 2-5 parts of light stabilizer, 1-2 parts of photocatalyst, 1-2 parts of stearic acid, 2-3 parts of composite ultraviolet absorbent, 1-2 parts of silicon nitride, 1-2 parts of fluorine-doped zirconia, 1-2 parts of nano liquid glass and the like;
s2, mixing: the selected materials are poured into a mixer to be mixed, so that the materials are convenient to mix, the mixed materials are pushed out of the mixer through a double screw, and then granulation is carried out through a granulator;
s3, plating: directly sputtering silicon nitride substances and fluorine-doped zirconium oxide substances on silicon nitride by a vacuum magnetron sputtering method, wherein the sputtering thickness of the silicon nitride is controlled to be between 10 and 30 nanometers, the fluorine content in the fluorine-doped zirconium oxide is 1 to 2 weight percent, and the sputtering thickness is between 25 and 30 nanometers;
s4, glass substance: sputtering the nano liquid glass into a nano liquid glass substance by a vacuum sputtering method, wherein the sputtering thickness is between 150 and 220 nanometers, and sputtering the composite ultraviolet absorbent substance by the vacuum sputtering method to obtain an organic layer, wherein the thickness is between 35 and 50 nanometers;
s5, tidiness: the glass substrate is placed into an ultrasonic cleaning machine for cleaning, so that dust and impurities on the glass substrate are cleaned;
s6, vacuum standby: the cleaned glass substrate is placed in a vacuum cavity, air is pumped by a vacuum air pump, so that the interior of the vacuum cavity is kept vacuum, and then high-purity neon of 1000-2000sccm is filled into a sputtering silicon target, so that the target is convenient to clean;
s7, catalysis: the light stabilizer is a mixture of UV-531, UV-234, UV-326 and UV-328, and the photocatalyst is titanium dioxide powder with particles positioned at 20-90 nanometers;
s8, preparation: and after the required thickness is reached, closing the target, sequentially preparing the fluorine-doped zirconium oxide substance, the silicon nitride substance and the nano liquid glass substance by using high-purity neon, performing framing and laminating procedures after the preparation is finished, preparing the hollow glass, and finally performing gluing and sealing by using a glass sealant.
CN202110396205.6A 2021-04-13 2021-04-13 High-strength low-radiation coated hollow glass for energy-saving building and preparation method thereof Pending CN112830684A (en)

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CN115257086B (en) * 2022-07-25 2024-01-23 尹梅 Glass with built-in aerogel composite board and preparation method thereof

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Application publication date: 20210525