CN112830574A - Method for using wine-making wastewater for carbon source supplement of sewage treatment plant - Google Patents

Method for using wine-making wastewater for carbon source supplement of sewage treatment plant Download PDF

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Publication number
CN112830574A
CN112830574A CN202011620288.4A CN202011620288A CN112830574A CN 112830574 A CN112830574 A CN 112830574A CN 202011620288 A CN202011620288 A CN 202011620288A CN 112830574 A CN112830574 A CN 112830574A
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China
Prior art keywords
carbon source
wastewater
sewage treatment
treatment plant
alkalization
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Pending
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CN202011620288.4A
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Inventor
刘宫介
孙刚
钱辰
汪玉莲
王文华
盛佳杰
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Shanghai Tongren Environmental Protection Technology Development Co ltd
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Shanghai Tongren Environmental Protection Technology Development Co ltd
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Priority to CN202011620288.4A priority Critical patent/CN112830574A/en
Publication of CN112830574A publication Critical patent/CN112830574A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/302Nitrification and denitrification treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/302Nitrification and denitrification treatment
    • C02F3/305Nitrification and denitrification treatment characterised by the denitrification
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/32Nature of the water, waste water, sewage or sludge to be treated from the food or foodstuff industry, e.g. brewery waste waters

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  • Life Sciences & Earth Sciences (AREA)
  • Microbiology (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

The invention discloses a method for using wine-making wastewater for carbon source supplement of a sewage treatment plant, which comprises the following steps: s1, performing primary alkalization on the brewing wastewater, adding alkali into the wastewater, and adjusting the pH value to 6-8; s2, adding a coagulant into the wastewater subjected to primary alkalization and stirring to precipitate a coagulant; s3, performing filter pressing on the aggregate by adopting at least one of a plate-and-frame filter press and a screw filter press; s4, adding alkali into the supernatant and the filtrate, adjusting the pH value to 9-11, and carrying out secondary alkalization; s5, preparing and subpackaging the carbon source supplement. The invention has the advantages that: the water treatment cost and pressure are low, and the carbon source adding cost is reduced.

Description

Method for using wine-making wastewater for carbon source supplement of sewage treatment plant
Technical Field
The invention relates to the technical field of sewage treatment, in particular to a method for using wine-making wastewater for carbon source supplement of a sewage treatment plant.
Background
At present, the requirement on the effluent quality index of a sewage treatment plant is increasingly strict, but in most cases, the composition of substances including but not limited to town sewage relatively lacks a carbon source and is not beneficial to nitrogen and phosphorus removal of a general sewage treatment system, so a carbon source substance supplementing and adding mode is often adopted to increase the nitrogen and phosphorus removal effect of the sewage treatment system, and the existing carbon source substances generally comprise micromolecular organic matters such as methanol, ethanol, sodium acetate, glucose and the like. The addition of these carbon source substances often increases the operating cost of sewage treatment plants and strives for industrial raw material resources. The brewing wastewater is generally a residue leachate, a pit mud leachate, a distillation waste liquid generated by brewing fermentation, wastewater generated by container cleaning and the like, has high concentration and high treatment cost, but also contains a large amount of small molecular organic matters such as alcohols, volatile fatty acids, saccharides and the like, and is a substance suitable for carbon source supplement in a municipal sewage treatment plant. If the brewing wastewater can be partially used for supplementing the carbon source for the urban sewage treatment plant, the operation cost of the sewage treatment plant can be reduced, the sewage treatment pressure and cost of brewing enterprises can be reduced, and the competition of industrial raw material resources in the sewage treatment industry can be avoided. However, the brewing wastewater contains a large amount of macromolecular organic matters and gas-producing microorganisms in addition to the small molecular organic matters, and if the brewing wastewater is directly used for carbon source supplement of urban sewage treatment plants, the organic load of the wastewater is obviously increased, so that the debugging difficulty and the operation cost are increased, and the wastewater is inconvenient to transport due to gas production of microorganisms.
Disclosure of Invention
The invention aims to solve the technical problem of providing a method for supplementing a carbon source in a sewage treatment plant by using brewing wastewater, which has low wastewater treatment cost and pressure and reduces carbon source adding cost.
In order to solve the technical problems, the technical scheme provided by the invention is as follows: a method for using wine-making wastewater for carbon source supplement of a sewage treatment plant comprises the following steps:
s1, performing primary alkalization on the brewing wastewater, adding alkali into the wastewater, and adjusting the pH value to 6-8;
s2, adding a coagulant into the wastewater subjected to primary alkalization and stirring to precipitate a coagulant;
s3, performing filter pressing on the aggregate by adopting at least one of a plate-and-frame filter press and a screw filter press;
s4, adding alkali into the supernatant and the filtrate, adjusting the pH value to 9-11, and carrying out secondary alkalization;
s5, preparing and subpackaging the carbon source supplement.
Compared with the prior art, the invention has the advantages that: the method for supplementing the carbon source of the sewage treatment plant by using the brewing wastewater comprises the steps of carrying out primary alkalization on the brewing wastewater, and neutralizing the pH value of the brewing wastewater to a range suitable for a coagulant to play a role; adding a coagulant for coagulation to change most macromolecular organic matters in the wastewater into flocculent precipitate aggregates and obtain a supernatant at the same time; carrying out filter pressing on the coagulated substance obtained by coagulation, and separating water in the coagulated substance to obtain filtrate and filter residue; carrying out secondary alkalization on the obtained supernatant and the filtrate, and raising the pH value to a range which is not beneficial to microbial gas production; the carbon source supplement prepared by the process contains a large amount of small molecular organic matters such as alcohols, volatile fatty acids, saccharides and the like, and is an ideal carbon source substance for urban sewage treatment plants.
Further, the alkali used in S1 is at least one of sodium hydroxide, potassium hydroxide, and calcium hydroxide.
Further, the coagulant in S2 is at least one of cationic polyacrylamide, anionic polyacrylamide, nonionic polyacrylamide, polyaluminium chloride, and polyferric sulfate.
Furthermore, the dosage of the coagulant in the S2 is 3-30 g/t.
Further, the alkali in S4 is at least one of sodium hydroxide and potassium hydroxide.
Further, in the step S3, filter pressing is carried out on the aggregate, and then filter residue is treated, wherein the treatment mode is at least one of composting, burning and brick making.
Drawings
FIG. 1 is a process flow diagram of a method for using brewery wastewater for carbon source supplement in a sewage treatment plant according to the present invention.
Detailed Description
Example one
A method for using wine-making wastewater for carbon source supplement of a sewage treatment plant comprises the following steps:
s1, performing primary alkalization on the wine brewing wastewater, adding sodium hydroxide and potassium hydroxide into the wastewater, and adjusting the pH value to 8;
s2, adding cationic polyacrylamide and anionic polyacrylamide into the wastewater subjected to primary alkalization, and stirring to precipitate an aggregate;
s3, performing filter pressing on the aggregate by adopting a screw filter press, and treating filter residues in a compost treatment mode;
s4, adding sodium hydroxide into the supernatant and the filtrate, adjusting the pH value to 10, and carrying out secondary alkalization;
s5, preparing and subpackaging the carbon source supplement.
Example two
A method for using wine-making wastewater for carbon source supplement of a sewage treatment plant comprises the following steps:
s1, performing primary alkalization on the wine brewing wastewater, adding potassium hydroxide into the wastewater, and adjusting the pH value to 7.5;
s2, adding cationic polyacrylamide into the wastewater subjected to primary alkalization and stirring to precipitate an aggregate;
s3, performing filter pressing on the aggregate by adopting a screw filter press, and treating filter residues in a compost treatment mode;
s4, adding sodium hydroxide into the supernatant and the filtrate, adjusting the pH value to 9.5, and carrying out secondary alkalization;
s5, preparing and subpackaging the carbon source supplement.
EXAMPLE III
A method for using wine-making wastewater for carbon source supplement of a sewage treatment plant comprises the following steps:
s1, performing primary alkalization on the wine brewing wastewater, adding calcium hydroxide into the wastewater, and adjusting the pH value to 7;
s2, adding polyaluminium chloride into the wastewater subjected to primary alkalization, and stirring to precipitate an aggregate;
s3, performing filter pressing on the aggregate by using a screw filter press, and treating filter residues in a brick making way;
s4, adding sodium hydroxide into the supernatant and the filtrate, adjusting the pH value to 10.5, and carrying out secondary alkalization;
s5, preparing and subpackaging the carbon source supplement.
Although the present invention has been described in detail with reference to the above embodiments, it should be understood by those skilled in the art that: modifications and equivalents may be made thereto without departing from the spirit and scope of the invention and it is intended to cover in the claims the invention as defined in the appended claims.

Claims (6)

1. A method for using wine-making wastewater for carbon source supplement of a sewage treatment plant is characterized by comprising the following steps:
s1, performing primary alkalization on the brewing wastewater, adding alkali into the wastewater, and adjusting the pH value to 6-8;
s2, adding a coagulant into the wastewater subjected to primary alkalization and stirring to precipitate a coagulant;
s3, performing filter pressing on the aggregate by adopting at least one of a plate-and-frame filter press and a screw filter press;
s4, adding alkali into the supernatant and the filtrate, adjusting the pH value to 9-11, and carrying out secondary alkalization;
s5, preparing and subpackaging the carbon source supplement.
2. The method for supplementing the carbon source of the sewage treatment plant by the brewing wastewater according to claim 1, which is characterized in that: the alkali used in S1 is at least one of sodium hydroxide, potassium hydroxide and calcium hydroxide.
3. The method for supplementing the carbon source of the sewage treatment plant by the brewing wastewater according to claim 1, which is characterized in that: and the coagulant in S2 is at least one of cationic polyacrylamide, anionic polyacrylamide, nonionic polyacrylamide, polyaluminium chloride and polyferric sulfate.
4. The method for supplementing the carbon source of the sewage treatment plant by the brewing wastewater according to claim 1, which is characterized in that: the dosage of the coagulant in the S2 is 3-30 g/t.
5. The method for supplementing the carbon source of the sewage treatment plant by the brewing wastewater according to claim 1, which is characterized in that: the alkali in the S4 is at least one of sodium hydroxide and potassium hydroxide.
6. The method for supplementing the carbon source of the sewage treatment plant by the brewing wastewater according to claim 1, which is characterized in that: and S3, performing filter pressing on the aggregate, and then treating the filter residue, wherein the treatment mode is at least one of composting, burning and brick making.
CN202011620288.4A 2020-12-31 2020-12-31 Method for using wine-making wastewater for carbon source supplement of sewage treatment plant Pending CN112830574A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002301498A (en) * 2001-04-04 2002-10-15 Kubota Corp Water treatment method and apparatus using acid fermentation
CN101538101A (en) * 2009-04-23 2009-09-23 同济大学 Home position strengthening fermentation regenerated carbon source sewage disposal system for sewage plant
CN102776239A (en) * 2012-07-25 2012-11-14 华南理工大学 Microbial flocculant produced by yeast wastewater and beer wastewater and method
CN106977053A (en) * 2017-04-25 2017-07-25 南昌大学 A kind of brewed spirit Waste Water Treatment
CN108947118A (en) * 2018-07-16 2018-12-07 江南大学 A kind of method of citric acid fermentation utilization of wastewater resource
CN112047473A (en) * 2020-09-11 2020-12-08 重庆蓝洁广顺净水材料有限公司 Novel composite carbon source supplement and preparation method and application thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002301498A (en) * 2001-04-04 2002-10-15 Kubota Corp Water treatment method and apparatus using acid fermentation
CN101538101A (en) * 2009-04-23 2009-09-23 同济大学 Home position strengthening fermentation regenerated carbon source sewage disposal system for sewage plant
CN102776239A (en) * 2012-07-25 2012-11-14 华南理工大学 Microbial flocculant produced by yeast wastewater and beer wastewater and method
CN106977053A (en) * 2017-04-25 2017-07-25 南昌大学 A kind of brewed spirit Waste Water Treatment
CN108947118A (en) * 2018-07-16 2018-12-07 江南大学 A kind of method of citric acid fermentation utilization of wastewater resource
CN112047473A (en) * 2020-09-11 2020-12-08 重庆蓝洁广顺净水材料有限公司 Novel composite carbon source supplement and preparation method and application thereof

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