CN112808245B - Low-wind-resistance adsorption material structure and manufacturing method thereof - Google Patents

Low-wind-resistance adsorption material structure and manufacturing method thereof Download PDF

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CN112808245B
CN112808245B CN202110104028.XA CN202110104028A CN112808245B CN 112808245 B CN112808245 B CN 112808245B CN 202110104028 A CN202110104028 A CN 202110104028A CN 112808245 B CN112808245 B CN 112808245B
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shell
adhesive
zeolite particles
zeolite
roller
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CN112808245A (en
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林建东
徐健元
陈永基
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/24Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16Alumino-silicates
    • B01J20/165Natural alumino-silicates, e.g. zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/2803Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/288Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00Aspects relating to sorbent materials
    • B01J2220/40Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/48Sorbents characterised by the starting material used for their preparation
    • B01J2220/4875Sorbents characterised by the starting material used for their preparation the starting material being a waste, residue or of undefined composition
    • B01J2220/4881Residues from shells, e.g. eggshells, mollusk shells

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  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Inorganic Chemistry (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Separation Of Gases By Adsorption (AREA)

Abstract

The invention discloses a high-efficiency low-wind resistance adsorption material structure, which comprises shells, an adhesive and zeolite particles; the zeolite particles are adhered to and covered on all surfaces inside and outside the shell through an adhesive, and compact zeolite particle thin layers are formed on the surfaces inside and outside the shell; the zeolite particles of the zeolite particle thin layer have exposed parts, and the exposed parts of the zeolite particles are not covered by the adhesive. The adsorption material has good adsorption performance and good air permeability and water permeability, and can greatly reduce high wind resistance formed after the adsorption material is stacked and reduce the energy consumption of the air blower especially when the adsorption material is applied to the field of waste gas purification. The shells belong to low-value wastes, and the adsorption material with high value is prepared to realize waste utilization, so that the environment protection is facilitated. The invention also discloses a manufacturing method of the high-efficiency low-wind-resistance adsorption material structure.

Description

Low-wind-resistance adsorption material structure and manufacturing method thereof
Technical Field
The invention relates to an adsorption material structure and a manufacturing method thereof, in particular to a structure of an adsorption material suitable for fluid purification and a manufacturing method thereof, belonging to the technical fields of environmental protection and new materials.
Background
Under the increasingly serious conditions of air, water source and soil pollution, innocent treatment on pollutants is not delayed, various technical means are applied to environmental treatment at present, wherein the adsorption technology comprises activated carbon and zeolite molecular sieves, particularly the activated carbon adsorption technology is widely adopted in the fields of air purification and water purification, the activated carbon has good adsorption performance, but has obvious defects, and the main problem is that the activated carbon cannot bear too high desorption temperature, or the risk of combustion and even fire easily occurs, and low-temperature desorption is difficult to completely desorb certain adsorbates, the activated carbon gradually becomes blocked and the adsorption function gradually loses over time. Most active carbon has service life not longer than one year, and frequent replacement of active carbon causes high cost of environmental protection treatment, and the scrapped active carbon produced in large quantity causes secondary pollution of the environment. In the process of preparing the honeycomb or granular form from the zeolite powder or the activated carbon powder, the binder is added to prepare the honeycomb or granular form, and the added binder can block micropores in the zeolite or the activated carbon, so that the adsorption capacity is greatly reduced. In addition, most of the particle filling forms great wind resistance, and a high-pressure fan is needed in air purification, so that the energy consumption of the fan is increased.
Disclosure of Invention
The invention aims to solve the technical problem of providing an adsorption material structure which has high adsorption capacity, and has the characteristics of high temperature resistance, low wind resistance, long service life, low cost, wide application range and strong adaptability.
The invention also provides a manufacturing method of the adsorption material structure.
The adsorption material structure of the invention can adopt the following technical scheme:
a high-efficiency low-wind resistance adsorption material structure comprises shells, a binder and zeolite particles; the zeolite particles are adhered to and covered on all surfaces inside and outside the shell through an adhesive, and compact zeolite particle thin layers are formed on the surfaces inside and outside the shell; the zeolite particles of the zeolite particle thin layer have exposed parts, and the exposed parts of the zeolite particles are not covered by the adhesive.
The invention can further take the following improvement measures:
the improvement is that the shell is a shell piece of double-shell type shell with two shell pieces separated.
Further improvement is that the projected area of the shell is between 0.6 and 16 square centimeters.
Further improvements are that the zeolite particles may be natural zeolite particles or artificial zeolite particles.
In a further improvement, the adhesive is a refractory inorganic adhesive.
In a further improvement, the adhesive is a sodium silicate adhesive.
The zeolite particles are single zeolite components or combined zeolite particles with loose and transparent three-dimensional structures formed by combining zeolite powder and inorganic frameworks.
The improvement is that the organic matter on the surface of the shell is removed by chemical treatment or high-temperature treatment.
In a further improvement, the shell is a curved fragment of the broken shell.
The technical scheme of the manufacturing method of the high-efficiency low-wind resistance adsorption material structure comprises the following steps,
step one: selecting shell pieces which are separated, putting the shells cleaned by organic matters into a sealed roller container, adding adhesive, and rotating the container to ensure that the adhesive is completely adhered to the inner and outer surfaces of all shells;
step two: transferring the shell with the adhesive adhered to the step one to a roller with meshes for rotation, and flowing out excessive adhesive through the meshes of the roller to adhere a layer of adhesive to the inner surface and the outer surface of the shell;
step three: placing enough zeolite particles into another sealing roller, adding the shell with the adhesive thin layer into the sealing roller, and allowing the zeolite particles to adhere to the surface of the shell through the adhesive by rotating the roller;
step four: then the shell fully stuck with zeolite particles after the step three is sent into a drying tunnel, and the curing of the adhesive is accelerated by baking at about 200 ℃ so that the zeolite particles are firmly adhered to the surface of the shell;
step five: and then feeding the shell baked and solidified in the fourth step into another roller with meshes, flowing out the unnecessary zeolite particles which are not adhered with the shell from the meshes of the roller by rotating the roller, and finally obtaining a finished product of the adsorbing material, wherein the unnecessary zeolite particles flowing out of the meshes of the roller can be reused.
The technical scheme has the following technical effects:
1. the adsorption material prepared by the invention utilizes the appearance characteristics of large specific surface area and irregular curved surface of the shells, so that after the adsorption material is packed and stacked, the larger contact area between the fluid and the zeolite layer is ensured, but the stacking density is reduced, a large number of gaps are kept in the adsorption material, the good adsorption performance of the adsorption material is achieved, the adsorption material has good air permeability and water permeability, and particularly, the high wind resistance formed after the adsorption material is stacked can be greatly reduced, and the energy consumption of a fan is reduced when the adsorption material is applied to the field of waste gas purification.
2. The zeolite particles are suitable for organic waste gas treatment and sewage purification by virtue of adsorption and desorption properties, and the main components of the product are composed of inorganic matters, so that the product has higher desorption temperature adaptability than that of the traditional activated carbon, and can be used repeatedly for a long time through desorption and regeneration after the adsorption saturation of the zeolite particles.
3. The shells belong to low-value wastes, and the adsorption material with high value is prepared to realize waste utilization, so that the environment protection is facilitated.
Drawings
Fig. 1 is a schematic structural view of embodiment 1 of the present invention.
FIG. 2 is a schematic structural diagram of zeolite particles of example 2 of the present invention.
Detailed Description
The present invention will be specifically described with reference to the following examples.
Example 1: as shown in fig. 1, an efficient low-wind-resistance adsorption material comprises a shell 1, a binder 2 and zeolite particles 3; the zeolite particles 3 are bonded through the adhesive 2 and cover all the surfaces inside and outside the shell 1, and a compact zeolite particle 3 thin layer is formed on the inner and outer surfaces of the shell 1; one surface of the zeolite particles 3 is adhered to the surface of the shell 1 through the adhesive 2, the zeolite particles 3 on the other surface are exposed, and the zeolite particles 3 exposed outside are not covered by the adhesive 2.
The shells adopt Bai Xianzi and Sha Xian shells, the two shells are separated, and the projected area of the shells is between 0.6 and 16 square centimeters. Of course, other double shell type shell pieces can be used as the shell.
The shell 1 is subjected to high-temperature treatment, and organic matters on the surface of the shell are removed through high temperature of 350 ℃.
The zeolite particles 3 are artificial zeolite particles;
the adhesive 2 is a sodium silicate fireproof inorganic adhesive;
the adhesive 2 is not dissolved by water after curing.
Principle of operation
Because the finished product contains a large amount of zeolite (also called molecular sieve), the invention has good adsorption performance and permeability, can enable gas or liquid to pass through and contact the surfaces of zeolite particles in a low resistance state, can adsorb VOCs components flowing through air and harmful substances such as ammonia nitrogen components, heavy metals and the like in sewage, effectively absorb the VOCs components in the air and reduce the BOD value of the sewage, effectively filter and purify the fluid, can bear high temperature of 300 ℃ or more at most to keep structural integrity because the structure in the finished product is inorganic mineral, is suitable for high-temperature desorption after adsorption saturation, has more thorough desorption effect on adsorbates with high boiling point and pyrolysis gasification temperature, has higher flame retardant safety, has high rigidity as a framework and is not easy to break, can be repeatedly used for a long time, and can replace the existing adsorption materials such as active carbon. The skeleton formed by the shell sheets is selected, the effect is that the shells have irregular curved surface appearance, have lower stacking density, form larger gaps between the shells inside after stacking, have good permeability, are especially used for air purification, have the characteristic of low wind resistance, and can be energy-saving by using a fan with low wind pressure. The main component of the shell is calcium carbonate, has stable chemical property, has considerable rigidity and temperature resistance, is suitable for being used as a skeleton of an adsorption material, and is common waste with low cost.
The zeolite particles for purifying sewage have a particle size of 50-200 μm, and the zeolite particles used for the adsorption material for purifying air have a particle size of less than 50 μm.
Example 2: an efficient low-wind-resistance adsorption material comprises a shell 1, a binder 2 and zeolite particles 3; the zeolite particles 3 are bonded through the adhesive 2 and cover all the surfaces inside and outside the shell 1, and a compact zeolite particle 3 thin layer is formed on the inner and outer surfaces of the shell 1; one surface of the zeolite particles 3 is adhered to the surface of the shell 1 through the adhesive 2, the zeolite particles 3 on the other surface are exposed, and the zeolite particles 3 exposed outside are not covered by the adhesive 2.
The shell adopts abalone shell, and two shell pieces are separated.
The shell 1 is subjected to high-temperature treatment to remove organic matters on the surface, or the organic matters on the surface of the shell 1 are removed through chemical treatment.
The zeolite particles are combined with inorganic frameworks 4 by zeolite powder to form porous three-dimensional structure combined zeolite particles (shown in figure 2).
The zeolite powder is artificial zeolite powder;
the adhesive 2 is a sodium silicate fireproof inorganic adhesive;
the adhesive 2 is not dissolved by water after curing.
The particle size of the combined zeolite particles is 0.5-2mm;
the projected area of the adopted shells is between 0.6 and 16 square centimeters. Of course, other area sizes may be used as desired by the design.
Example 2 zeolite particles were combined with zeolite powder and inorganic framework 4 to form a porous three-dimensional structure (see fig. 2), which can hold more zeolite particles with a larger adsorption capacity than example 1, while the material supporting the fixed zeolite particles is a porous framework, which can ensure that most zeolite particles can contact gas or liquid flowing through, and the porous framework supporting the fixed zeolite particles can filter dust or suspended matters in the fluid, thereby reducing the problem of clogging of micropores of the zeolite particles. The embodiment can be applied to sewage filtration and purification and adsorption of VOCs gas in air.
Examples 1 and 2 can be obtained by the following production methods.
The manufacturing method of the high-efficiency low-wind-resistance adsorption material structure comprises the following steps:
step one: selecting shell pieces which are separated, putting the shells cleaned by organic matters into a sealed roller container, adding adhesive, and rotating the container to ensure that the adhesive is completely adhered to the inner and outer surfaces of all shells;
step two: transferring the shell with the adhesive adhered to the step one to a roller with meshes for rotation, and flowing out excessive adhesive through the meshes of the roller to adhere a layer of adhesive to the inner surface and the outer surface of the shell;
step three: placing enough zeolite particles into another sealing roller, adding the shell with the adhesive thin layer into the sealing roller, and allowing the zeolite particles to adhere to the surface of the shell through the adhesive by rotating the roller.
If a portion of the zeolite particles has glue on the outer surface, there will be one or more layers of zeolite particles adhered to the other zeolite particles, until finally no more zeolite particles can be adhered, and the outermost layer of zeolite particles is partially uncovered by glue.
Step four: then the shell fully stuck with zeolite particles after the step three is sent into a drying tunnel, and the curing of the adhesive is accelerated by baking at about 200 ℃ so that the zeolite particles are firmly adhered to the surface of the shell;
step five: and then feeding the shell baked and solidified in the fourth step into another roller with meshes, flowing out the unnecessary zeolite particles which are not adhered with the shell from the meshes of the roller by rotating the roller, and finally obtaining a finished product of the adsorbing material, wherein the unnecessary zeolite particles flowing out of the meshes of the roller can be reused.
The manufacturing method has the advantages of simple equipment and few process steps, and can make the product easy and simple to manufacture.
The invention can also replace double shell shells with curved fragments after the spiral shell is broken.
The foregoing description of the preferred embodiments of the invention is not intended to be limiting, but rather is intended to cover all modifications, equivalents, and alternatives falling within the spirit and principles of the invention.

Claims (1)

1. The manufacturing approach of a kind of high-efficient low wind resistance adsorption material structure, the said adsorption material includes shell, adhesive, zeolite particle, the projected area of said shell is between 0.6-16 square centimeters, the said adhesive is sodium silicate adhesive, the said zeolite particle is single zeolite composition or zeolite powder and inorganic matter skeleton are combined zeolite particle forming the porous penetrating three-dimensional structure of form, characterized by that: comprises the steps of,
step one: selecting shell pieces which are separated, putting the shells cleaned by organic matters into a sealed roller container, adding adhesive, and rotating the container to ensure that the adhesive is completely adhered to the inner and outer surfaces of all shells;
step two: transferring the shell with the adhesive adhered to the step one to a roller with meshes for rotation, and flowing out excessive adhesive through the meshes of the roller to adhere a layer of adhesive to the inner surface and the outer surface of the shell;
step three: placing enough zeolite particles into another sealing roller, adding the shell with the adhesive thin layer into the sealing roller, and allowing the zeolite particles to adhere to the surface of the shell through the adhesive by rotating the roller;
step four: then the shell fully stuck with zeolite particles after the step three is sent into a drying tunnel, and the curing of the adhesive is accelerated by baking at 200 ℃ so that the zeolite particles are firmly adhered to the surface of the shell;
step five: and then feeding the shell baked and solidified in the fourth step into another roller with meshes, flowing out the unnecessary zeolite particles which are not adhered with the shell from the meshes of the roller by rotating the roller, and finally obtaining a finished product of the adsorbing material, wherein the unnecessary zeolite particles flowing out of the meshes of the roller can be reused.
CN202110104028.XA 2021-01-26 2021-01-26 Low-wind-resistance adsorption material structure and manufacturing method thereof Active CN112808245B (en)

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CN112808245B true CN112808245B (en) 2024-03-08

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1119436A (en) * 1997-05-08 1999-01-26 Takasago Thermal Eng Co Ltd Filter and its production, and purifier

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8647997B2 (en) * 2010-11-30 2014-02-11 General Electric Company Zeolite membrane and methods of making the same

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1119436A (en) * 1997-05-08 1999-01-26 Takasago Thermal Eng Co Ltd Filter and its production, and purifier

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