CN112794546B - Method for treating ammonium-containing wastewater generated in taurine production - Google Patents
Method for treating ammonium-containing wastewater generated in taurine production Download PDFInfo
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- CN112794546B CN112794546B CN202011562074.6A CN202011562074A CN112794546B CN 112794546 B CN112794546 B CN 112794546B CN 202011562074 A CN202011562074 A CN 202011562074A CN 112794546 B CN112794546 B CN 112794546B
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/02—Treatment of water, waste water, or sewage by heating
- C02F1/04—Treatment of water, waste water, or sewage by heating by distillation or evaporation
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/469—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
- C02F1/4693—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis electrodialysis
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
- C02F2103/36—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/05—Conductivity or salinity
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/08—Multistage treatments, e.g. repetition of the same process step under different conditions
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/124—Water desalination
Abstract
The invention discloses a method for treating ammonium-containing wastewater generated in taurine production, which comprises the following steps: firstly, sending collected ammonium-containing wastewater into a negative pressure evaporator for rapid negative pressure evaporation to obtain ammonia-containing steam and a highly saturated concentrated solution, then carrying out solid-liquid separation on the highly saturated concentrated solution, and mixing unsaturated liquid formed after separation into the ammonium-containing wastewater for re-evaporation; step two, introducing the ammonium-containing steam generated in the step one into a condenser, and condensing and recovering the ammonia-containing steam; step three, introducing the condensed water obtained in the step two into an electrodialysis device for electrodialysis separation; and step four, feeding the concentrated water separated in the step three into a negative pressure evaporator to be mixed with the ammonium-containing wastewater for re-steaming, and step five, detecting the conductivity of the fresh water obtained in the step three, wherein the fresh water is qualified and is used as workshop production water, and the fresh water is mixed into condensed water if the conductivity of the fresh water is not qualified. By the mode, the invention can shorten the processing flow, improve the processing speed and reduce the processing cost.
Description
Technical Field
The invention relates to the field of wastewater treatment, in particular to a method for treating ammonium-containing wastewater generated in taurine production.
Background
Taurine can produce a certain amount of ammonium salt-containing wastewater in the production process, the conventional treatment mode of the ammonium salt-containing wastewater is to remove ammonium ions by using a biochemical method, a stripping method or a steam stripping method, remove the ions in the solution of the saline wastewater by using an ion exchange device, further concentrate the saline wastewater by using a reverse osmosis membrane, crystallize and evaporate the concentrated solution to obtain mixed salts, and condense and recover the evaporated steam.
Disclosure of Invention
The invention mainly solves the technical problem of providing a method for treating ammonium-containing wastewater generated in taurine production, which can improve the treatment speed and reduce the treatment cost.
In order to solve the technical problems, the invention adopts a technical scheme that: the method for treating the ammonium-containing wastewater generated in the production of taurine comprises the following steps:
firstly, negative pressure evaporation, namely sending the collected ammonium-containing wastewater into a negative pressure evaporator for rapid negative pressure evaporation to obtain ammonia-containing steam and a highly saturated concentrated solution, carrying out solid-liquid separation on the highly saturated concentrated solution to obtain crystalline salt and unsaturated liquid, and then mixing the unsaturated liquid into the ammonium-containing wastewater for re-evaporation;
step two, condensing and collecting, wherein the ammonium-containing steam generated in the step one is introduced into a condenser, and the ammonia-containing steam is condensed and recovered;
step three, dialysis separation, namely introducing the collected condensed water into an electrodialysis device for electrodialysis separation after the collected condensed water is concentrated to a certain amount, and separating the condensed water into concentrated water and fresh water after the electrodialysis separation treatment;
feeding the concentrated water separated in the third step into a negative pressure evaporator to be mixed with the ammonium-containing wastewater for re-steaming;
and step five, detecting that the conductivity of the fresh water meets the standard of the process requirement, using the fresh water as workshop production water, and mixing the fresh water into condensed water for repeating electrodialysis treatment if the detected conductivity is unqualified.
In a preferred embodiment of the present invention, dilute sulfuric acid is used to adjust the PH of the ammonium-containing wastewater before the negative pressure evaporation in the step (a), so that the PH of the ammonium-containing wastewater is less than 7.
In a preferred embodiment of the present invention, the vacuum degree of the negative pressure evaporation is 0.1-0.2 atm, and the evaporation temperature is 40-60 ℃.
In a preferred embodiment of the present invention, the negative pressure evaporation in the first step is performed twice, wherein the first negative pressure evaporation generates a primary ammonia-containing vapor and a primary highly saturated concentrated solution, the primary highly saturated concentrated solution is subjected to solid-liquid separation to obtain a primary crystallized salt and a primary unsaturated liquid, the primary unsaturated liquid is subjected to secondary negative pressure evaporation to generate a secondary ammonia-containing vapor and a secondary highly saturated concentrated solution, the secondary ammonia-containing vapor and the primary ammonia-containing vapor are mixed and simultaneously enter a condenser for condensation, the secondary highly saturated concentrated solution is subjected to solid-liquid separation to obtain a secondary crystallized salt and a secondary unsaturated liquid, and the secondary unsaturated liquid is mixed into the ammonium-containing wastewater for re-evaporation.
In a preferred embodiment of the present invention, the electrodialysis separation in the third step is performed twice, the concentrated water produced after the first electrodialysis separation is separated and concentrated again through the second electrodialysis, and then sent into the negative pressure evaporator for re-evaporation, the fresh water produced in the second electrodialysis is mixed with the fresh water produced in the first electrodialysis for use after passing the conductivity detection, and if the conductivity detection is not passing the conductivity detection, the fresh water is mixed with the condensed water and then subjected to the electrodialysis treatment again.
In a preferred embodiment of the present invention, the conductivity in the fifth step is detected as a conductivity less than 5 us/cm.
The invention has the beneficial effects that: the treatment scheme of the invention combines negative pressure evaporation and electrodialysis treatment, carries out circulating evaporation treatment on the ammonium-containing wastewater, continuously crystallizes and separates out salts in the wastewater, and the whole treatment process is mainly based on physical means, so that new impurities cannot be introduced into the system.
Detailed Description
The following detailed description of the preferred embodiments of the present invention is provided to enable those skilled in the art to more readily understand the advantages and features of the present invention and to clearly and clearly define the scope of the present invention.
The embodiment of the invention comprises the following steps:
a method for treating ammonium-containing wastewater generated in taurine production comprises the following steps:
firstly, negative pressure evaporation, namely sending the collected ammonium-containing wastewater into a negative pressure evaporator for rapid negative pressure evaporation to obtain ammonia-containing steam and a highly saturated concentrated solution, carrying out solid-liquid separation on the highly saturated concentrated solution to obtain crystalline salt and unsaturated liquid, and then mixing the unsaturated liquid into the ammonium-containing wastewater for re-evaporation;
step two, condensing and collecting, namely introducing the ammonium-containing steam generated in the step one into a condenser, and condensing and recovering the ammonia-containing steam;
step three, dialysis separation, namely introducing the collected condensed water into an electrodialysis device for electrodialysis separation after the collected condensed water is concentrated to a certain amount, and separating the condensed water into concentrated water and fresh water after the electrodialysis separation treatment;
step four, feeding the concentrated water separated in the step three into a negative pressure evaporator to be mixed with the ammonium-containing wastewater for re-steaming,
and step five, detecting that the conductivity of the fresh water meets the standard of the process requirement, using the fresh water as workshop production water, and mixing the fresh water into condensed water for repeating electrodialysis treatment if the detected conductivity is unqualified.
And adjusting the pH value of the ammonium-containing wastewater by using dilute sulfuric acid before negative pressure evaporation in the first step to enable the pH value of the ammonium-containing wastewater to be less than 7, wherein the purpose of adjusting the pH value by using dilute acid is to convert free ammonia molecules in the waste liquid into ion forms, so that the free ammonia molecules can be crystallized into salt in the concentration process, and the escape amount of the ammonia molecules in the subsequent evaporation process is reduced.
In the first step, the vacuum degree of negative pressure evaporation is 0.1-0.2 atmospheric pressure, the evaporation temperature is 40-60 ℃, the evaporation heat is less, the heat required by water molecule evaporation can be reduced, and the evaporation separation speed is increased.
The method comprises the following steps of performing negative pressure evaporation in the first step twice, wherein the first negative pressure evaporation generates primary ammonia-containing steam and primary high-saturation concentrated solution, the primary high-saturation concentrated solution is subjected to solid-liquid separation to obtain primary crystallized salts and primary unsaturated liquid, the primary unsaturated liquid is subjected to secondary negative pressure evaporation to generate secondary ammonia-containing steam and secondary high-saturation concentrated solution, the secondary ammonia-containing steam is mixed with the primary ammonia-containing steam and then simultaneously enters a condenser to be condensed, the secondary high-saturation concentrated solution is subjected to solid-liquid separation to obtain secondary crystallized salts and secondary unsaturated liquid, and the secondary unsaturated liquid is mixed into ammonium-containing wastewater to be re-evaporated. The water in the wastewater can be evaporated as much as possible by a secondary evaporation mode, and the total amount of unsaturated liquid mixed into the wastewater for re-evaporation subsequently is reduced.
And the electrodialysis separation in the third step is performed twice, and the concentrated water generated after the first electrodialysis separation is separated and concentrated again through the second electrodialysis and then is sent into a negative pressure evaporator for re-evaporation. The fresh water produced in the second electrodialysis is qualified after conductivity detection and then is mixed with the fresh water produced in the first electrodialysis for use, if the conductivity detection is unqualified, the fresh water is mixed with condensed water and then is subjected to electrodialysis treatment again, and after the condensed fluid is subjected to electrodialysis treatment and concentration twice, on one hand, low-salt fresh water can be separated as much as possible, on the other hand, the ion concentration in the concentrated water finally obtained can be improved, and the waste caused by adding the concentrated water into the initial wastewater for re-steaming is reduced.
And the detection standard of the conductivity in the step five is that the conductivity is less than 5 us/cm. The reason for adopting the standard is that when the conductivity is lower than 5us/cm, the content of impurities in ionic form in water is not more than 0.5mmg/L, the impurities in the solution are less, no peculiar smell exists, and the water can be directly used as production water or workshop cleaning water, so that the waste of water resources in production is reduced.
By the mode, the treatment scheme disclosed by the invention realizes closed loop of ammonium-containing wastewater treatment, and is short in treatment flow and low in cost.
The above description is only an embodiment of the present invention, and is not intended to limit the scope of the present invention, and all equivalent structures or equivalent processes performed by the present invention or directly or indirectly applied to other related technical fields are also included in the scope of the present invention.
Claims (2)
1. A method for treating ammonium-containing wastewater generated in taurine production is characterized by comprising the following steps:
firstly, negative pressure evaporation, namely feeding the collected ammonium-containing wastewater into a negative pressure evaporator for rapid negative pressure evaporation to obtain ammonia-containing steam and highly saturated concentrated solution, carrying out solid-liquid separation on the highly saturated concentrated solution to obtain crystalline salt and unsaturated liquid, and then mixing the unsaturated liquid into the ammonium-containing wastewater for re-evaporation;
step two, condensing and collecting, wherein the ammonium-containing steam generated in the step one is introduced into a condenser, and the ammonia-containing steam is condensed and recovered;
step three, dialysis separation, namely introducing the collected condensed water into an electrodialysis device for electrodialysis separation after the collected condensed water is concentrated to a certain amount, and separating the condensed water into concentrated water and fresh water after the electrodialysis separation treatment;
step four, feeding the concentrated water separated in the step three into a negative pressure evaporator to be mixed with the ammonium-containing wastewater for re-steaming,
step five, detecting that the conductivity of the fresh water meets the standard of the process requirement, using the fresh water as workshop production water, and mixing the fresh water into condensed water for repeated electrodialysis treatment if the detected conductivity is unqualified;
before negative pressure evaporation, using dilute sulfuric acid to adjust the pH value of the ammonium-containing wastewater, so that the pH value of the ammonium-containing wastewater is less than 7; the vacuum degree of negative pressure evaporation is 0.1-0.2 atmospheric pressure, and the evaporation temperature is 40-60 ℃ at the moment; the negative pressure evaporation in the first step is carried out twice, wherein the first negative pressure evaporation generates primary ammonia-containing steam and primary high-saturation concentrated solution, the primary high-saturation concentrated solution is subjected to solid-liquid separation to obtain primary crystallized salts and primary unsaturated liquid, the primary unsaturated liquid is subjected to secondary negative pressure evaporation to generate secondary ammonia-containing steam and secondary high-saturation concentrated solution, the secondary ammonia-containing steam is mixed with the primary ammonia-containing steam and then simultaneously enters a condenser for condensation, the secondary high-saturation concentrated solution is subjected to solid-liquid separation to obtain secondary crystallized salts and secondary unsaturated liquid, and the secondary unsaturated liquid is mixed with ammonium-containing wastewater for re-evaporation; and the electrodialysis separation in the third step is performed twice, concentrated water generated after the first electrodialysis separation is separated and concentrated again through the second electrodialysis and then is sent into the negative pressure evaporator for re-evaporation, fresh water generated in the second electrodialysis is mixed with fresh water generated by the first electrodialysis for use after the conductivity detection is qualified, and the fresh water is mixed with condensed water and then subjected to electrodialysis treatment again after the conductivity detection is unqualified.
2. The method for treating ammonium-containing wastewater produced in the production of taurine according to claim 1, wherein the detection standard for conductivity in the fifth step is a conductivity of less than 5 us/cm.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106349123A (en) * | 2016-08-25 | 2017-01-25 | 江苏德玛膜科技有限公司 | Method for separating taurine in taurine crude product mother solution |
| CN108314112A (en) * | 2017-01-17 | 2018-07-24 | 中国石油化工股份有限公司 | A kind of method of ammonium salt-containing wastewater treatment |
| CN108358258A (en) * | 2018-02-26 | 2018-08-03 | 天华化工机械及自动化研究设计院有限公司 | A kind of MVR deaminations divide salt integrated technique |
| CN109704508A (en) * | 2017-10-25 | 2019-05-03 | 于德志 | A kind of processing method of the liquid containing ammonium sulfate high-salt wastewater generated in taurine production technology |
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- 2020-12-25 CN CN202011562074.6A patent/CN112794546B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106349123A (en) * | 2016-08-25 | 2017-01-25 | 江苏德玛膜科技有限公司 | Method for separating taurine in taurine crude product mother solution |
| CN108314112A (en) * | 2017-01-17 | 2018-07-24 | 中国石油化工股份有限公司 | A kind of method of ammonium salt-containing wastewater treatment |
| CN109704508A (en) * | 2017-10-25 | 2019-05-03 | 于德志 | A kind of processing method of the liquid containing ammonium sulfate high-salt wastewater generated in taurine production technology |
| CN108358258A (en) * | 2018-02-26 | 2018-08-03 | 天华化工机械及自动化研究设计院有限公司 | A kind of MVR deaminations divide salt integrated technique |
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