CN112784367A - Method for calculating thickness of blank shell at position of continuous casting roller row and solidification tail end of casting machine - Google Patents

Method for calculating thickness of blank shell at position of continuous casting roller row and solidification tail end of casting machine Download PDF

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CN112784367A
CN112784367A CN202011451609.2A CN202011451609A CN112784367A CN 112784367 A CN112784367 A CN 112784367A CN 202011451609 A CN202011451609 A CN 202011451609A CN 112784367 A CN112784367 A CN 112784367A
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thickness
solidification
billet
shell
continuous casting
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任一峰
饶立华
许晓红
葛洪硕
白云
柳琴
马晓东
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Jiangyin Xingcheng Special Steel Works Co Ltd
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    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
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Abstract

本发明涉及一种连铸辊列位置坯壳厚度和铸机凝固末端推算方法,其特征在于:利用零塑性温度与固相线温度近似相等的规律,通过寻找连铸坯低倍上的点状裂纹,测量裂纹距铸坯边部的距离,求得拉矫辊处的坯壳厚度,根据测得的距弯月面最远辊子处的坯壳厚度和相应辊列位置和拉速,通过二次运用凝固定律平方根公式,进一步推算铸机综合凝固系数和液相穴长度,从而实现射钉或者凝固模型计算的效果。本发明公布一种不需模型、无须射钉,通过研究连铸坯低倍,推断坯壳厚度和凝固末端的方法,进而可以优化末端电磁搅拌、轻压下工装布置和生产工艺,从而改善连铸坯、轧材的偏析问题。The invention relates to a method for estimating the thickness of the shell at the row position of the continuous casting roll and the solidification end of the casting machine. Crack, measure the distance between the crack and the edge of the billet, and obtain the thickness of the billet at the pull-leveling roll. Next, the square root formula of the solidification law is used to further calculate the comprehensive solidification coefficient of the casting machine and the length of the liquid phase cavity, so as to achieve the effect of nail shooting or solidification model calculation. The invention discloses a method for inferring the thickness of the billet shell and the solidification end by studying the low magnification of the continuous casting billet without the need for models and nails, so as to optimize the electromagnetic stirring at the end, the arrangement of the light pressing tooling and the production process, thereby improving the continuous casting. The problem of segregation of cast billets and rolled products.

Description

Method for calculating thickness of blank shell at position of continuous casting roller row and solidification tail end of casting machine
Technical Field
The invention belongs to the technical field of metal smelting, and particularly relates to a method for calculating the shell thickness of a blank at a position of a continuous casting roller row and the solidification tail end of a casting machine.
Background
Segregation, particularly center segregation, is an important index for evaluating the quality of steel materials, particularly special steel, and poor segregation control brings serious harm to the service performance of steel processing products. In order to improve the center segregation, an electromagnetic stirring and light pressing device is usually arranged at the tail end of a continuous casting machine, but a plurality of steel enterprises generally need to debug the equipment for a long time, and a proper process is not found for some years or even many years, so that the segregation improvement cannot achieve the expected effect. The reason for this is that the thickness of the shell at the solidification end or at the fixed point is not accurate. Generally, a method of shooting a nail or a mathematical model is adopted to find the measured or calculated blank thickness and the solidification end. Both of these approaches have some limitations and difficulties in application. The nail shooting method is to shoot a steel nail containing a sulfide tracer material into a casting blank which is solidifying, and sampling and analyzing corresponding positions of the casting blank. In the technology for judging the thickness of the blank shell, due to the fact that the two-phase region is partially melted and dissolved to foreign steel and sulfide, the problem of fuzzy identification of the two-phase region boundary exists no matter from the shape of a nail or in a sulfur print tracing mode, and different people of the same sample judge that measurement results may have differences. The following difficulties exist in terms of operation: the novel nail shooting device has the advantages that the existing factory building and equipment arrangement is avoided, and the position of shooting nails can be limited; the preparation process is complicated, the thickness of the blank shell at 1 position is usually detected at one time, and if a plurality of positions are required to be carried out together, the preparation workload is multiplied; the firearms are easy to break down, and the bullet deviation condition can occur due to the installation precision or operation reason; sample preparation process is complicated, and processing of samples is more difficult when the samples meet nail deflection. In the aspect of safety, the nail shooting work is dangerous, the operation area is high in temperature, and the fire risk of firearms exists. In addition, the entrusting of nail shooting business of institutions also requires expense. In short, it is not easy to obtain effective data by the nail shooting method.
The utilization of mathematical models is difficult, and the modeling process from now on needs a talent team with expert programming ability and well-known continuous casting solidification professional knowledge, and the programming process usually takes years; the existing model is utilized, and the problems that whether the model is suitable for the current casting machine (difference of square, round, plate type, specification and the like) and whether the physical property parameters are suitable exist; whether grid division representing calculation accuracy is enough or not is judged, if the grid division representing calculation accuracy is too dense, the calculation speed is too slow, and if the grid division representing calculation accuracy is too sparse, the calculation is not accurate enough; whether the boundary conditions are set properly or not, environmental factors may influence the values of certain physical property parameters, which may influence the accuracy of the calculation result and the adaptability of the calculation process to the field.
Disclosure of Invention
The invention aims to solve the technical problem of providing a method for calculating the thickness of the shell of the continuous casting roller row position and the solidification tail end of a casting machine without a model and a nail, which aims at the prior art, and can optimize the electromagnetic stirring of the tail end, the arrangement of a tool under light pressure and the production process by researching the low power of the continuous casting billet to deduce the thickness of the shell of the continuous casting roller and the solidification tail end of the continuous casting machine, thereby improving the segregation problem of the continuous casting billet and a rolled material.
The technical scheme adopted by the invention for solving the problems is as follows: a method for calculating the shell thickness of a continuous casting roller row position and the solidification tail end of a casting machine is characterized in that a continuous casting billet has zero plasticity temperature and zero strength temperature in a temperature gradient from the surface to the center of the casting blank in a two-phase region in the solidification process, and cracks are generated at the position when the casting blank is deformed due to mechanical pressure during the period; according to a plurality of production practices and certain observation and analysis experiences of the casting blank, the crack points are in an intermittent linear distribution, and cracks generated at the zero plasticity temperature are relatively heavy. The zero plasticity temperature measured by the high temperature tensile test is approximately equal to the solidus temperature.
By utilizing the rule, the thickness of the billet shell at the position of a pulling and straightening roller (a light press roller) can be obtained by measuring the position of a crack point on the continuous casting billet in a macroscopic manner, and the thickness of the hot billet shell during production can be obtained through certain correction; under the condition of knowing roller row position and pulling speed, the square root formula of solidification law is applied
Figure BDA0002827187850000021
The position of the coagulation tip can be further solved; thus, the effect of nail shooting or solidification model calculation can be realized.
Compared with the prior art, the invention has the advantages that:
the method has no safety risk; the high-temperature working environment of the shooting nail is severe, and the risk of accidental fire escape or people injury caused by rebound and refraction of firearms also exists;
the method is convenient and quick, and analysis can be completed within half an hour generally (the preparation time of the nail shooting platform support in the early stage of nail shooting is long, more time is needed for later sample preparation, and the model calculation usually needs a computer to run for a plurality of hours);
according to the method, extra cost is not required to be added (the cost is high when a commercial continuous casting solidification mathematical model is purchased, and a certain cost is required when a scientific research institution is entrusted with a nail shooting test), and the sample is not required to be prepared additionally, so that the analysis can be completely carried out on the ready-made conventional production low-power sample;
the method can analyze the influence of the thickness of the billet shell and the change of the solidification tail end caused by the tooling, the environmental conditions and the like in the same metallurgical process (the difference can not be calculated by a mathematical model), so that the continuous casting process is properly adjusted, and the expected metallurgical effect is realized.
Drawings
FIG. 1 is a schematic drawing showing the sampling and processing of a steel ingot of 200X 200 square in the example of the present invention.
FIG. 2 is a schematic view showing the observation and analysis of a cast slab of 200X 200 square in the example of the present invention.
Detailed Description
The invention is described in further detail below with reference to the accompanying examples.
Examples are: measuring the distance H between an inner arc and an outer arc of a certain steel casting blank of 200 multiplied by 200 square to be 195mm in low power, wherein the positions of the roller rows are 13.5 meters for a 1# roller, 15 meters for a 2# roller and 16.5 meters for a 3# roller respectively; the continuous casting speed is 1.2 m/min; the casting blank is known to be longitudinally low. And solving the shell thickness of the steel at each roller and the solidification end position of the steel during full solidification in the continuous casting machine process.
According to the known conditions, namely the nominal thickness M of the casting blank is 200mm, and the thickness H of the casting blank in low magnification is 195 mm;
cutting a continuous casting billet low-power sample with the length equivalent to the section size of the casting billet, sawing along the central line of the inner cambered surface and the outer cambered surface to obtain a longitudinal low-power piece with the thickness of 20mm, corroding the continuous casting billet low-power piece with 10-40% of nitric acid aqueous solution in volume percentage for 3-10 minutes after milling, observing the low-power sample by naked eyes or a magnifying glass, finding out point-like cracks layer by layer, and measuring the distance between each layer of crack point and the edge of the casting billet. The distance is the thickness of the blank shell at the position of the pulling and straightening roller (the light pressing roller).
According to the longitudinal low power of the casting blank, the thickness of the blank shell corresponding to each roller on the low power (cold state) is sequentially judged to be 60mm, 75mm and 93mm, and because the casting blank generally exists in a hot state on a continuous casting machine, the thickness of the blank shell needs to be corrected in the hot state, and the specific correction mode is according to the following formula:
Figure BDA0002827187850000031
in the formula: a is the thickness of the shell at a certain roller measured on the low power (cold state), B is a corrected value, C is the thickness of the shell passing through the certain roller at the moment of production (hot state), M is the nominal thickness of the casting blank, H is the thickness of the casting blank on the low power (inner and outer arc spacing), n is the serial number of the roller row, and the thickness unit is mm.
I.e. a1 ═ 60 mm; b1 ═ 200 + 195 × 60 ÷ 195 ÷ 1.5mm, C1 ═ 60+1.5 ÷ 61.5 mm;
a2 ═ 75 mm; b2 ═ 200 + 195 × 75 ÷ 195 ÷ 1.9mm, C2 ═ 75+1.9 ═ 76.9 mm;
a3 ═ 93 mm; b3 ═ 200-;
namely, the thickness of the shell of the hot casting blank passing through the three rollers is 61.5mm, 76.9mm and 95.4mm in sequence. The results of the calculations are given in the following table
Figure BDA0002827187850000032
From the above conditions, the comprehensive solidification coefficient can be calculated according to the shell thickness and the pulling rate of the last roll
Figure BDA0002827187850000033
Figure BDA0002827187850000034
I.e. the solidification end position of the steel when the process is used on this continuous casting machine is 18.1 meters.
In addition to the above embodiments, the present invention also includes other embodiments, and any technical solutions formed by equivalent transformation or equivalent replacement should fall within the scope of the claims of the present invention.

Claims (4)

1.一种连铸辊列位置坯壳厚度和铸机凝固末端推算方法,其特征在于:利用零塑性温度与固相线温度近似相等的规律,通过寻找连铸坯低倍上的点状裂纹,测量裂纹距铸坯边部的距离,求得拉矫辊处的坯壳厚度,根据测得的距弯月面最远辊子处的坯壳厚度和相应辊列位置和拉速,通过二次运用凝固定律平方根公式,进一步推算铸机综合凝固系数和液相穴长度,从而实现射钉或者凝固模型计算的效果。1. A method for calculating the thickness of the shell at the row position of the continuous casting roll and the solidification end of the casting machine, characterized in that: using the law that the zero plasticity temperature and the solidus temperature are approximately equal, by looking for the point cracks on the continuous casting billet at a low magnification , measure the distance from the crack to the edge of the billet, and obtain the thickness of the billet at the pull-leveling roll. Using the square root formula of the solidification law, the comprehensive solidification coefficient of the casting machine and the length of the liquid phase cavity are further calculated, so as to achieve the effect of nail shooting or solidification model calculation. 2.根据权利要求1所述的一种连铸辊列位置坯壳厚度和铸机凝固末端推算方法,其特征在于:切取与铸坯断面尺寸相当长度的连铸坯低倍样,沿内外弧面的中心线锯切得到一定厚度的纵向低倍片,磨铣后用10%~40%体积百分比的硝酸水溶液腐蚀3~10分钟,肉眼或配合放大镜观察低倍样,逐层找出点状裂纹,量出每层裂纹点距离铸坯边部的距离,此距离即为拉矫辊处的坯壳厚度。2. A method for calculating the thickness of the shell at the row position of the continuous casting rolls and the solidification end of the casting machine according to claim 1, characterized in that: cut a low-magnification sample of the continuous casting billet with a length equivalent to the cross-sectional size of the billet, along the inner and outer arcs. The center line of the surface is sawed to obtain a longitudinal low-magnification piece of a certain thickness. After milling, it is corroded with a 10% to 40% volume percent of nitric acid aqueous solution for 3 to 10 minutes. Crack, measure the distance between the crack point of each layer and the edge of the billet, this distance is the thickness of the billet shell at the tension leveling roller. 3.根据权利要求2所述的一种连铸辊列位置坯壳厚度和铸机凝固末端推算方法,其特征在于:考虑热胀冷缩的原因,为得到精确的热态坯壳厚度,采用以下公式进行修正:3. The method for calculating the thickness of the shell at the row position of the continuous casting rolls and the solidification end of the casting machine according to claim 2, characterized in that: considering the reasons for thermal expansion and contraction, in order to obtain the accurate thickness of the shell in the hot state, the method is: The following formula is corrected:
Figure FDA0002827187840000011
Cn=An+Bn.
Figure FDA0002827187840000011
Cn=An+Bn.
公式中:An为低倍上测量的某辊处冷态坯壳厚度,Bn为修正值,Cn为生产时通过某辊时刻的热态坯壳厚度,M为铸坯的名义厚度,H为铸坯低倍上的厚度,n为辊列序号,上述厚度的单位为mm。In the formula: An is the thickness of the cold billet shell at a certain roll measured at a low magnification, Bn is the correction value, Cn is the thickness of the hot billet shell at the moment of passing a certain roll during production, M is the nominal thickness of the casting billet, and H is the casting billet thickness. The thickness of the blank at a low magnification, n is the serial number of the roll, and the unit of the above thickness is mm.
4.根据权利要求3所述的一种连铸辊列位置坯壳厚度和铸机凝固末端推算方法,其特征在于:根据距离弯月面最远辊子位置处或者最接近铸坯中心的坯壳厚度数据,通过凝固定律平方根公式可以求得综合凝固系数,再次利用凝固定律平方根公式可以得到凝固末端距离弯月面的位置,4. The method for calculating the thickness of the shell at the row position of the continuous casting rolls and the solidification end of the casting machine according to claim 3, characterized in that: according to the position of the roll farthest from the meniscus or the shell closest to the center of the casting billet For the thickness data, the comprehensive solidification coefficient can be obtained by the square root formula of the solidification law, and the position of the solidification end from the meniscus can be obtained by using the square root formula of the solidification law again. 附凝固定律平方根公式:
Figure FDA0002827187840000012
The square root formula of the law of solidification is attached:
Figure FDA0002827187840000012
公式中:C为坯壳厚度,单位mm,L为坯壳距弯月面位置,单位m,V为拉速,单位m/分钟,K为综合凝固系数。In the formula: C is the thickness of the shell, in mm, L is the position of the shell from the meniscus, in m, V is the pulling speed, in m/min, and K is the comprehensive solidification coefficient.
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113804482A (en) * 2021-09-15 2021-12-17 芜湖新兴铸管有限责任公司 Method for rapidly detecting solidification tail end position of continuous casting billet
CN114858851A (en) * 2022-03-21 2022-08-05 江阴兴澄特种钢铁有限公司 Method for measuring zero strength temperature of steel
CN115041649A (en) * 2022-05-14 2022-09-13 江阴兴澄特种钢铁有限公司 Method for slightly pressing solidified tail end of super-large-specification round billet

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000015412A (en) * 1998-06-30 2000-01-18 Nkk Corp Steel continuous casting method
CN101367115A (en) * 2008-08-22 2009-02-18 武汉钢铁(集团)公司 Casting blank liquid core length measuring method
CN102029368A (en) * 2010-12-25 2011-04-27 大连理工大学 A method for on-line detection of solid-liquid phase fraction and solidification end in the secondary cooling zone of continuous casting slab
JP2015062918A (en) * 2013-09-25 2015-04-09 Jfeスチール株式会社 Steel continuous casting method
CN106556363A (en) * 2015-09-28 2017-04-05 宝山钢铁股份有限公司 Thickness of continuous casting shell online test method and device
CN110181004A (en) * 2018-04-26 2019-08-30 江阴兴澄特种钢铁有限公司 A kind of detection method judging continuous casting and solidifying green shell according to dotted crack position

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000015412A (en) * 1998-06-30 2000-01-18 Nkk Corp Steel continuous casting method
CN101367115A (en) * 2008-08-22 2009-02-18 武汉钢铁(集团)公司 Casting blank liquid core length measuring method
CN102029368A (en) * 2010-12-25 2011-04-27 大连理工大学 A method for on-line detection of solid-liquid phase fraction and solidification end in the secondary cooling zone of continuous casting slab
JP2015062918A (en) * 2013-09-25 2015-04-09 Jfeスチール株式会社 Steel continuous casting method
CN106556363A (en) * 2015-09-28 2017-04-05 宝山钢铁股份有限公司 Thickness of continuous casting shell online test method and device
CN110181004A (en) * 2018-04-26 2019-08-30 江阴兴澄特种钢铁有限公司 A kind of detection method judging continuous casting and solidifying green shell according to dotted crack position

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
庞洪亮: ""连铸坯液相穴长度的测定"", 《黑龙江冶金》, no. 2006, pages 18 - 20 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113804482A (en) * 2021-09-15 2021-12-17 芜湖新兴铸管有限责任公司 Method for rapidly detecting solidification tail end position of continuous casting billet
CN113804482B (en) * 2021-09-15 2023-07-25 芜湖新兴铸管有限责任公司 Method for rapidly detecting solidification end position of continuous casting billet
CN114858851A (en) * 2022-03-21 2022-08-05 江阴兴澄特种钢铁有限公司 Method for measuring zero strength temperature of steel
CN115041649A (en) * 2022-05-14 2022-09-13 江阴兴澄特种钢铁有限公司 Method for slightly pressing solidified tail end of super-large-specification round billet
CN115041649B (en) * 2022-05-14 2023-10-24 江阴兴澄特种钢铁有限公司 Method for slightly pressing solidification tail end of oversized round billet

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Application publication date: 20210511