CN112777937A - 一种以废玻璃为主要原料制备的微孔发泡玻璃 - Google Patents
一种以废玻璃为主要原料制备的微孔发泡玻璃 Download PDFInfo
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- CN112777937A CN112777937A CN202110110074.0A CN202110110074A CN112777937A CN 112777937 A CN112777937 A CN 112777937A CN 202110110074 A CN202110110074 A CN 202110110074A CN 112777937 A CN112777937 A CN 112777937A
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- China
- Prior art keywords
- glass
- raw material
- prepared
- waste glass
- foamed glass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011521 glass Substances 0.000 title claims abstract description 115
- 239000002994 raw material Substances 0.000 title claims abstract description 41
- 239000002699 waste material Substances 0.000 title claims abstract description 36
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims abstract description 34
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 32
- 239000011324 bead Substances 0.000 claims abstract description 31
- 239000000463 material Substances 0.000 claims abstract description 18
- 239000004317 sodium nitrate Substances 0.000 claims abstract description 17
- 235000010344 sodium nitrate Nutrition 0.000 claims abstract description 17
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 16
- 238000005187 foaming Methods 0.000 claims abstract description 16
- 229910052656 albite Inorganic materials 0.000 claims abstract description 14
- 229910021538 borax Inorganic materials 0.000 claims abstract description 13
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004327 boric acid Substances 0.000 claims abstract description 13
- 235000010338 boric acid Nutrition 0.000 claims abstract description 13
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims abstract description 13
- 239000010436 fluorite Substances 0.000 claims abstract description 13
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 13
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 13
- 238000010438 heat treatment Methods 0.000 claims abstract description 11
- 238000001816 cooling Methods 0.000 claims abstract description 7
- 239000002245 particle Substances 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- 229910001868 water Inorganic materials 0.000 claims description 22
- 238000000227 grinding Methods 0.000 claims description 16
- 239000011148 porous material Substances 0.000 claims description 16
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 11
- 239000011230 binding agent Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 238000010521 absorption reaction Methods 0.000 claims description 8
- 238000000498 ball milling Methods 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 7
- 239000000919 ceramic Substances 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 6
- 229920000858 Cyclodextrin Polymers 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000001116 FEMA 4028 Substances 0.000 claims description 3
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 claims description 3
- 235000011175 beta-cyclodextrine Nutrition 0.000 claims description 3
- 229960004853 betadex Drugs 0.000 claims description 3
- 239000006184 cosolvent Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000000748 compression moulding Methods 0.000 claims description 2
- 238000011049 filling Methods 0.000 claims description 2
- 239000011268 mixed slurry Substances 0.000 claims description 2
- 239000004088 foaming agent Substances 0.000 abstract description 8
- 238000000034 method Methods 0.000 abstract description 6
- 230000002159 abnormal effect Effects 0.000 abstract description 3
- 239000011494 foam glass Substances 0.000 description 9
- 239000002002 slurry Substances 0.000 description 8
- 238000009413 insulation Methods 0.000 description 6
- 210000004027 cell Anatomy 0.000 description 5
- 230000007547 defect Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000005303 weighing Methods 0.000 description 5
- 238000007605 air drying Methods 0.000 description 4
- 238000005520 cutting process Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 4
- 238000003825 pressing Methods 0.000 description 4
- 239000011819 refractory material Substances 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- 229910001928 zirconium oxide Inorganic materials 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 238000004134 energy conservation Methods 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000004321 preservation Methods 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000004566 building material Substances 0.000 description 2
- 235000010216 calcium carbonate Nutrition 0.000 description 2
- 238000003889 chemical engineering Methods 0.000 description 2
- 230000007123 defense Effects 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 239000004604 Blowing Agent Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000011325 microbead Substances 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C11/00—Multi-cellular glass ; Porous or hollow glass or glass particles
- C03C11/007—Foam glass, e.g. obtained by incorporating a blowing agent and heating
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/08—Other methods of shaping glass by foaming
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
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CN202110110074.0A CN112777937B (zh) | 2021-01-27 | 2021-01-27 | 一种以废玻璃为主要原料制备的微孔发泡玻璃 |
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CN202110110074.0A CN112777937B (zh) | 2021-01-27 | 2021-01-27 | 一种以废玻璃为主要原料制备的微孔发泡玻璃 |
Publications (2)
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CN112777937A true CN112777937A (zh) | 2021-05-11 |
CN112777937B CN112777937B (zh) | 2023-09-15 |
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CN202110110074.0A Active CN112777937B (zh) | 2021-01-27 | 2021-01-27 | 一种以废玻璃为主要原料制备的微孔发泡玻璃 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113603426A (zh) * | 2021-08-27 | 2021-11-05 | 东台市艺和园装饰品有限公司 | 一种人造无机仿石材纹理装饰板制作方法 |
Citations (10)
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---|---|---|---|---|
DD220018A1 (de) * | 1983-10-19 | 1985-03-20 | Trisola Steinach Veb | Verfahren zur herstellung hohler mikrokugeln aus glas |
JP2011016278A (ja) * | 2009-07-08 | 2011-01-27 | Mitsubishi Rayon Co Ltd | 繊維強化複合材料成形品の製造方法 |
CN103011882A (zh) * | 2012-12-29 | 2013-04-03 | 清华大学 | 一种具有三级孔结构的无机保温材料及其制备方法 |
CN103553343A (zh) * | 2013-10-31 | 2014-02-05 | 河北勇龙邦大新材料有限公司 | 一种利用废玻璃制备微孔泡沫玻璃的方法 |
CN104193178A (zh) * | 2014-03-19 | 2014-12-10 | 广西科学院 | 一种废玻璃发泡生产的高强轻质建筑材料及制备方法 |
CN107512873A (zh) * | 2017-09-21 | 2017-12-26 | 成都新柯力化工科技有限公司 | 一种低密度建筑泡沫玻璃及其制备方法 |
CN109053210A (zh) * | 2018-08-29 | 2018-12-21 | 广西科学院 | 一种利用废玻璃为原料微波高温加热制备轻质材料的方法 |
CN109704805A (zh) * | 2019-02-19 | 2019-05-03 | 河北恒钏建筑材料股份有限公司 | 一种铁尾矿制备微晶发泡材料及其制造方法 |
US20190135676A1 (en) * | 2017-11-06 | 2019-05-09 | Dennert Poraver Gmbh | Hollow glass microspheres and method for producing same |
CN112876072A (zh) * | 2021-01-27 | 2021-06-01 | 中钢集团马鞍山矿山研究总院股份有限公司 | 一种微孔发泡玻璃的制备方法 |
-
2021
- 2021-01-27 CN CN202110110074.0A patent/CN112777937B/zh active Active
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DD220018A1 (de) * | 1983-10-19 | 1985-03-20 | Trisola Steinach Veb | Verfahren zur herstellung hohler mikrokugeln aus glas |
JP2011016278A (ja) * | 2009-07-08 | 2011-01-27 | Mitsubishi Rayon Co Ltd | 繊維強化複合材料成形品の製造方法 |
CN103011882A (zh) * | 2012-12-29 | 2013-04-03 | 清华大学 | 一种具有三级孔结构的无机保温材料及其制备方法 |
CN103553343A (zh) * | 2013-10-31 | 2014-02-05 | 河北勇龙邦大新材料有限公司 | 一种利用废玻璃制备微孔泡沫玻璃的方法 |
CN104193178A (zh) * | 2014-03-19 | 2014-12-10 | 广西科学院 | 一种废玻璃发泡生产的高强轻质建筑材料及制备方法 |
CN107512873A (zh) * | 2017-09-21 | 2017-12-26 | 成都新柯力化工科技有限公司 | 一种低密度建筑泡沫玻璃及其制备方法 |
US20190135676A1 (en) * | 2017-11-06 | 2019-05-09 | Dennert Poraver Gmbh | Hollow glass microspheres and method for producing same |
CN109053210A (zh) * | 2018-08-29 | 2018-12-21 | 广西科学院 | 一种利用废玻璃为原料微波高温加热制备轻质材料的方法 |
CN109704805A (zh) * | 2019-02-19 | 2019-05-03 | 河北恒钏建筑材料股份有限公司 | 一种铁尾矿制备微晶发泡材料及其制造方法 |
CN112876072A (zh) * | 2021-01-27 | 2021-06-01 | 中钢集团马鞍山矿山研究总院股份有限公司 | 一种微孔发泡玻璃的制备方法 |
Non-Patent Citations (1)
Title |
---|
张永福: "利用废玻璃制备泡沫玻璃的试验研究" * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113603426A (zh) * | 2021-08-27 | 2021-11-05 | 东台市艺和园装饰品有限公司 | 一种人造无机仿石材纹理装饰板制作方法 |
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CN112777937B (zh) | 2023-09-15 |
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Effective date of registration: 20231011 Address after: 243000 No. 666 Xitang Road, Ma'anshan Economic Development Zone, Anhui Province Patentee after: MAANSHAN Mine Research Institute Co.,Ltd. Patentee after: SINOSTEEL MIMR NEW MATERIAL TECHNOLOGY Co.,Ltd. Address before: 243000 No. 666 Xitang Road, Ma'anshan Economic Development Zone, Anhui Province Patentee before: MAANSHAN Mine Research Institute Co.,Ltd. Patentee before: SINOSTEEL MIMR NEW MATERIAL TECHNOLOGY Co.,Ltd. Patentee before: Sinosteel Nanjing Huaxin Technology Co.,Ltd. |