CN112730383B - A Fiber Array LIBS Detection System for Online Detection - Google Patents

A Fiber Array LIBS Detection System for Online Detection Download PDF

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CN112730383B
CN112730383B CN202011588099.3A CN202011588099A CN112730383B CN 112730383 B CN112730383 B CN 112730383B CN 202011588099 A CN202011588099 A CN 202011588099A CN 112730383 B CN112730383 B CN 112730383B
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张智
时铭鑫
王傲松
黄大鹏
邱岩
吴坚
李兴文
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China Nuclear Power Engineering Co Ltd
Xian Jiaotong University
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Abstract

本发明公开了一种用于在线检测的光纤阵列LIBS探测系统,包括激光光纤耦合模块、激光控制模块以及光谱采集模块;其中,激光光纤耦合模块包括纳秒激光器,二向色镜,平凸透镜一以及传输光纤;激光控制模块包括分光镜一,分光镜二,光电二极管,激光能量计以及可编程脉冲延迟发生器;光谱采集模块包括平凸透镜二,收集光纤,光谱仪以及ICCD;从纳秒激光器发出的激光光束最终通过传输光纤进入到光纤阵列LIBS探头中。光纤阵列模块安装于待测设备的正上方,其上的16根光纤套筒可以实现对整个设备表面的二维阵列同步检测。本发明可以实现对特殊设备运行状态的现场实时在线检测。

Figure 202011588099

The invention discloses a fiber array LIBS detection system for on-line detection, comprising a laser fiber coupling module, a laser control module and a spectrum acquisition module; wherein, the laser fiber coupling module includes a nanosecond laser, a dichroic mirror, a plano-convex lens and a and transmission fiber; laser control module includes beam splitter 1, beam splitter 2, photodiode, laser energy meter and programmable pulse delay generator; spectrum acquisition module includes plano-convex lens 2, collection fiber, spectrometer and ICCD; emitted from nanosecond laser The laser beam finally enters the fiber array LIBS probe through the transmission fiber. The optical fiber array module is installed directly above the equipment to be tested, and the 16 fiber optic sleeves on it can realize the synchronous detection of the two-dimensional array on the entire surface of the equipment. The invention can realize on-site real-time online detection of the running state of special equipment.

Figure 202011588099

Description

一种用于在线检测的光纤阵列LIBS探测系统A Fiber Array LIBS Detection System for Online Detection

技术领域technical field

本发明属于激光诊断技术领域,涉及一种用于在线检测的光纤阵列LIBS探测系统。The invention belongs to the technical field of laser diagnosis, and relates to an optical fiber array LIBS detection system for online detection.

背景技术Background technique

核电、化工、冶金行业关键设备的状态监测、维修及评价技术是评价安全性和经济性的重要支撑,为保障关键设备在制造后和运行中结构不存在危害性缺陷和损伤,相关法规要求对核电设备关键部件进行在役和役前无损检测。由于上述关键特殊设备往往具有高放射性、高温、高压等恶劣运行环境,常规的检测手段,如X射线照相技术、超声技术、涡流技术,难以实现远距离的在线测量。新近发展的远程在线检测技术如声发射技术和电化学技术也都有着各自的局限性:如声发射技术只能检测正在遭受破坏的材料所发出的压力波信号,不能对其寿命进行评估和预测;电化学技术则需要对核电系统加入小振幅的电信号扰动,可能会对系统造成不利影响。Condition monitoring, maintenance and evaluation technology of key equipment in the nuclear power, chemical and metallurgical industries is an important support for evaluating safety and economy. The key components of nuclear power equipment are subject to in-service and pre-service non-destructive testing. Since the above-mentioned key special equipment often has harsh operating environments such as high radioactivity, high temperature, and high pressure, conventional detection methods, such as X-ray photography technology, ultrasonic technology, and eddy current technology, are difficult to achieve long-distance online measurement. The newly developed remote online detection technologies such as acoustic emission technology and electrochemical technology also have their own limitations: for example, acoustic emission technology can only detect the pressure wave signal emitted by the material that is being damaged, but cannot evaluate and predict its life. ; Electrochemical technology needs to add small-amplitude electrical signal disturbances to the nuclear power system, which may adversely affect the system.

激光诱导击穿光谱技术(Laser Induced Breakdown Spectroscopy,以下简称LIBS技术)是利用激光诱导待测材料表面产生的等离子体的发射光谱定量测量样品元素组分、力学参数等的测量技术。与其他检测手段相比,LIBS技术具有明显的优势:远程在线原位检测,样本微损甚至无损,无须样本预处理,可实现多种元素同时分析等。Laser Induced Breakdown Spectroscopy (LIBS) is a measurement technology that quantitatively measures the elemental composition and mechanical parameters of a sample by using the emission spectrum of the plasma generated on the surface of the material to be measured by laser induction. Compared with other detection methods, LIBS technology has obvious advantages: remote on-line in-situ detection, samples are slightly damaged or even non-destructive, no sample preprocessing is required, and simultaneous analysis of multiple elements can be achieved.

光纤传输激光诱导击穿光谱技术(以下简称光纤LIBS技术)是对前有的传统诱导击穿光谱技术的改进与创新,更加适应极端场合的检测任务:利用光纤传输激光聚焦样品表面形成等离子体,同时对等离子体发射光谱进行收集,并采用光谱后处理算法分析以确定待测样品的物质成分及含量。该技术在核电厂、核电站检修维护企业、核燃料制造厂、乏燃料处理厂等场所具有巨大的潜在应用价值,可以通过光纤LIBS技术检测高温、高压、高辐射的生产线中设备管道或蒸汽过热弯管等人工难以到达的地方。Optical fiber transmission laser-induced breakdown spectroscopy (hereinafter referred to as fiber LIBS technology) is an improvement and innovation of the previous traditional induced breakdown spectroscopy technology, and is more suitable for detection tasks in extreme occasions: using optical fiber transmission laser to focus the sample surface to form plasma, At the same time, the plasma emission spectrum is collected and analyzed by spectral post-processing algorithm to determine the material composition and content of the sample to be tested. This technology has huge potential application value in nuclear power plants, nuclear power plant maintenance and maintenance enterprises, nuclear fuel manufacturing plants, spent fuel processing plants and other places. It can detect equipment pipes or steam superheated elbows in high temperature, high pressure and high radiation production lines through optical fiber LIBS technology. In places that are difficult to reach by humans.

然而,现在已开发的光纤LIBS装置也存在以下不足之处。一方面,传统的便携式光纤LIBS探测系统无法适应核电站主管道内等特殊的工作环境,也无法深入特殊设备内部指定区域进行远程控制检测(例如,华中科技大学,曾晓雁等,基于光纤激光器的便携式激光探针成分分析仪,[P],中国,2013107403189.20151104);另一方面,由于光纤LIBS技术传输激光轰击靶材料的能量密度一般低于传统LIBS,造成了较差元素灵敏度和元素检测限,导致某些关键元素的检测能力不够,甚至失效。为解决这一问题,需要针对特定元素的检测需求制造相应的特殊气体介质环境,改善光谱信号信背比,提高关键元素的检测灵敏度。此外,在检测仪器设备方面,针对复杂辐射场、高温高湿度等严苛的工作环境,可实现远程控制可靠运行的LIBS系统仍有待于进一步发展。However, the currently developed optical fiber LIBS devices also have the following disadvantages. On the one hand, traditional portable fiber-optic LIBS detection systems cannot adapt to special working environments such as the main pipeline of nuclear power plants, nor can they go deep into designated areas inside special equipment for remote control detection (for example, Huazhong University of Science and Technology, Zeng Xiaoyan, etc., Portable laser detectors based on fiber lasers). Needle Composition Analyzer, [P], China, 2013107403189.20151104); on the other hand, because the energy density of the optical fiber LIBS technology to transmit laser bombardment target materials is generally lower than that of traditional LIBS, resulting in poor element sensitivity and element detection limit, resulting in some The detection capability of key elements is insufficient or even invalid. In order to solve this problem, it is necessary to create a corresponding special gas medium environment according to the detection requirements of specific elements, improve the signal-to-background ratio of spectral signals, and improve the detection sensitivity of key elements. In addition, in terms of testing equipment, the LIBS system that can realize remote control and reliable operation for harsh working environments such as complex radiation fields, high temperature and high humidity still needs to be further developed.

发明内容SUMMARY OF THE INVENTION

本发明的目的在于解决现有技术中的问题,提供一种用于在线检测的光纤阵列LIBS探测系统,本发明利用成像方式聚焦激光诱导击穿光谱,主要用于特殊设备表面元素的在线定性与定量分析,以实现对设备的状态检测。The purpose of the present invention is to solve the problems in the prior art and provide an optical fiber array LIBS detection system for on-line detection. The present invention uses an imaging method to focus the laser-induced breakdown spectrum, and is mainly used for the on-line characterization and analysis of surface elements of special equipment. Quantitative analysis to realize the status detection of equipment.

为达到上述目的,本发明采用以下技术方案予以实现:To achieve the above object, the present invention adopts the following technical solutions to realize:

一种用于在线检测的光纤阵列LIBS探测系统,包括:An optical fiber array LIBS detection system for online detection, comprising:

激光光纤耦合模块,所述激光光纤耦合模块用于输出激光,通过光纤阵列LIBS探头入射到待测设备上;所述设置激光控制模块;a laser fiber coupling module, the laser fiber coupling module is used for outputting laser light, which is incident on the device to be tested through the fiber array LIBS probe; the laser control module is provided;

激光控制模块,所述激光控制模块设置于激光光纤耦合模块的输出光路上,用于监控输出激光的实际能量,并调整出光信号与门宽信号的延时;a laser control module, which is arranged on the output optical path of the laser fiber coupling module, and is used to monitor the actual energy of the output laser and adjust the delay between the output optical signal and the gate width signal;

光谱采集模块,所述光谱采集模块包括光谱仪和ICCD,光谱仪用于收集待测设备表面产生的等离子体光谱,并将光谱信息传输给计算机进行分析对比。The spectrum acquisition module includes a spectrometer and an ICCD, and the spectrometer is used to collect the plasma spectrum generated on the surface of the device to be tested, and transmit the spectrum information to a computer for analysis and comparison.

本发明进一步的改进在于:The further improvement of the present invention is:

所述激光光纤耦合模块包括纳秒激光器,所述纳秒激光器输出激光经二向色镜的反射进入第一平凸透镜,经第一平凸透镜聚焦后进由传输光纤传输至光纤阵列LIBS探头。The laser fiber coupling module includes a nanosecond laser, and the output laser light of the nanosecond laser enters the first plano-convex lens after being reflected by the dichroic mirror, and is focused by the first plano-convex lens and then transmitted from the transmission fiber to the fiber array LIBS probe.

所述传输光纤的光纤输入端面位于第一平凸透镜焦点后方3mm处;纳秒激光器1为Nd:YAG纳秒激光器,输出激光波长为1064nm,频率为1-10Hz,脉冲宽度FWHM为10ns,最大脉冲能量为150mJ,激光光束直径为6mm。The fiber input end face of the transmission fiber is located 3mm behind the focal point of the first plano-convex lens; the nanosecond laser 1 is an Nd:YAG nanosecond laser, the output laser wavelength is 1064nm, the frequency is 1-10Hz, the pulse width FWHM is 10ns, and the maximum pulse The energy is 150mJ and the laser beam diameter is 6mm.

所述光纤阵列LIBS探头包括光纤分束器和光纤阵列模块,光纤阵列模块上安装有若干光纤套筒;每根光纤套筒中装有聚焦透镜,聚焦透镜由2个卡环安装在光纤套筒上;传输光纤经过光纤分束器分束成若干根光纤,每根光纤进入到一根光纤套筒中。The optical fiber array LIBS probe includes an optical fiber beam splitter and an optical fiber array module, and several optical fiber sleeves are installed on the optical fiber array module; each optical fiber sleeve is equipped with a focusing lens, and the focusing lens is installed on the optical fiber sleeve by two snap rings. The transmission fiber is split into several fibers by the fiber splitter, and each fiber enters a fiber sleeve.

所述光纤阵列模块设置于待测设备的上方,直径为5m;光纤阵列模块与升降平台相连,通过升降平台控制其升降。The optical fiber array module is arranged above the equipment to be tested, and has a diameter of 5m; the optical fiber array module is connected to the lifting platform, and the lifting and lowering of the optical fiber array module is controlled by the lifting platform.

所述光纤套筒设置有16根;传输光纤经过光纤分束器分束成16根光纤;聚焦透镜18的直径为25.4mm,焦距为35mm。There are 16 optical fiber sleeves; the transmission optical fibers are split into 16 optical fibers by the optical fiber beam splitter; the diameter of the focusing lens 18 is 25.4 mm, and the focal length is 35 mm.

所述激光控制模块包括设置在纳秒激光器与二向色镜之间光路上的第一分光镜和第二分光镜;输出激光一部分投射第一分光镜至第二分光镜,另一部分被第一分光镜反射至光电二极管上,投射至第二分光镜的输出激光一部分投射至二向色镜,另一部分被第二分光镜反射至激光能量计。The laser control module includes a first beam splitter and a second beam splitter arranged on the optical path between the nanosecond laser and the dichroic mirror; a part of the output laser projects the first beam splitter to the second beam splitter, and the other part is captured by the first beam splitter. The beam splitter reflects on the photodiode, part of the output laser projected to the second beam splitter is projected to the dichroic mirror, and the other part is reflected by the second beam splitter to the laser energy meter.

所述纳秒激光器、第一分光镜、第二分光镜、二向色镜均位于同一光路,且纳秒激光器激光光轴中心、第一分光镜中心、第二分光镜中心、二向色镜中心均位于同一直线上;第一分光镜、第二分光镜、二向色镜均与纳秒激光器的输出激光光轴成°夹角。The nanosecond laser, the first beam splitter, the second beam splitter, and the dichroic mirror are all located on the same optical path, and the center of the laser optical axis of the nanosecond laser, the center of the first beam splitter, the center of the second beam splitter, and the dichroic mirror The centers are all located on the same straight line; the first beam splitter, the second beam splitter, and the dichroic mirror all form an angle with the output laser optical axis of the nanosecond laser.

所述光谱采集模块还包括第二平凸透镜,待测设备表面产生的等离子体沿原光路反向回传,经光纤阵列LIBS探头、传输光纤以及第一平凸透镜后变为平行光,平行光经过二向色镜以及第二平凸透镜聚焦到收集光纤中,所述收集光纤的另一端连接光谱仪。The spectrum acquisition module also includes a second plano-convex lens, and the plasma generated on the surface of the device to be tested is reversely transmitted along the original optical path, and becomes parallel light after passing through the fiber array LIBS probe, the transmission fiber and the first plano-convex lens, and the parallel light passes through. The dichroic mirror and the second plano-convex lens are focused into the collection fiber, and the other end of the collection fiber is connected to the spectrometer.

所述传输光纤为二氧化硅包层的多模光纤,长度为3m,光纤芯径为800μm,数值孔径为0.37,最大功率密度为1GW/cm2;光纤的两端使用SMA905不锈钢光纤连接器连接;二向色镜为短波通二向色镜,直径为50.8mm,截止波长为805nm;收集光纤的长度为1m,光纤芯径为400μm,数值孔径为0.22。The transmission fiber is a multimode fiber with silica cladding, the length is 3m, the fiber core diameter is 800μm, the numerical aperture is 0.37, and the maximum power density is 1GW/cm 2 ; both ends of the fiber are connected by SMA905 stainless steel fiber optic connectors The dichroic mirror is a short-wave pass dichroic mirror with a diameter of 50.8mm and a cut-off wavelength of 805nm; the length of the collecting fiber is 1m, the fiber core diameter is 400μm, and the numerical aperture is 0.22.

与现有技术相比,本发明具有以下有益效果:Compared with the prior art, the present invention has the following beneficial effects:

本发明实现了对待测在线表面的光纤阵列LIBS检测,相比传统的检测方法的优势在于:无须破坏待测在线,检测速度快,检测精度高;可同时得到整个在线表面上二维阵列的LIBS光谱信息,定量确定在线表面铬元素的含量,从而实现对管道腐蚀规律进行预测,并进而评估服役寿命。The invention realizes the detection of the optical fiber array LIBS on the surface of the line to be tested, and the advantages compared with the traditional detection method are: no need to destroy the line to be tested, the detection speed is fast, and the detection accuracy is high; the LIBS of the two-dimensional array on the entire line surface can be obtained at the same time. Spectral information, quantitatively determine the content of chromium element on the online surface, so as to predict the corrosion law of the pipeline, and then evaluate the service life.

附图说明Description of drawings

为了更清楚的说明本发明实施例的技术方案,下面将对实施例中所需要使用的附图作简单地介绍,应当理解,以下附图仅示出了本发明的某些实施例,因此不应被看作是对范围的限定,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他相关的附图。In order to describe the technical solutions of the embodiments of the present invention more clearly, the following briefly introduces the accompanying drawings that need to be used in the embodiments. It should be understood that the following drawings only show some embodiments of the present invention, and therefore do not It should be regarded as a limitation of the scope, and for those of ordinary skill in the art, other related drawings can also be obtained according to these drawings without any creative effort.

图1为用于在线检测的光纤阵列LIBS探测系统的总体结构图;Fig. 1 is the overall structure diagram of the optical fiber array LIBS detection system used for online detection;

图2为光纤阵列LIBS探头对设备进行检测的示意图。FIG. 2 is a schematic diagram of a fiber array LIBS probe for testing the device.

图中:1-纳秒激光器,2-第一分光镜,3-第二分光镜,4-第二平凸透镜,5-二向色镜,6-激光能量计,7-第一平凸透镜,8-传输光纤,9-光纤阵列LIBS探头,10-待测设备,11-收集光纤,12-光电二极管,13-可编程脉冲延迟发生器,14-光谱仪,15-ICCD,16-光纤分束器,17-光纤阵列模块,18-聚焦透镜,19-卡环,20-光纤连接器,21-光纤套筒,22-升降平台。In the picture: 1-nanosecond laser, 2-first beam splitter, 3-second beam splitter, 4-second plano-convex lens, 5-dichroic mirror, 6-laser energy meter, 7-first plano-convex lens, 8-Transmission fiber, 9-fiber array LIBS probe, 10-device under test, 11-collection fiber, 12-photodiode, 13-programmable pulse delay generator, 14-spectrometer, 15-ICCD, 16-fiber splitter 17-fiber array module, 18-focusing lens, 19-retaining ring, 20-fiber connector, 21-fiber sleeve, 22-lifting platform.

具体实施方式Detailed ways

为使本发明实施例的目的、技术方案和优点更加清楚,下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例是本发明一部分实施例,而不是全部的实施例。通常在此处附图中描述和示出的本发明实施例的组件可以以各种不同的配置来布置和设计。In order to make the purposes, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments These are some embodiments of the present invention, but not all embodiments. The components of the embodiments of the invention generally described and illustrated in the drawings herein may be arranged and designed in a variety of different configurations.

因此,以下对在附图中提供的本发明的实施例的详细描述并非旨在限制要求保护的本发明的范围,而是仅仅表示本发明的选定实施例。基于本发明中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。Thus, the following detailed description of the embodiments of the invention provided in the accompanying drawings is not intended to limit the scope of the invention as claimed, but is merely representative of selected embodiments of the invention. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.

应注意到:相似的标号和字母在下面的附图中表示类似项,因此,一旦某一项在一个附图中被定义,则在随后的附图中不需要对其进行进一步定义和解释。It should be noted that like numerals and letters refer to like items in the following figures, so once an item is defined in one figure, it does not require further definition and explanation in subsequent figures.

在本发明实施例的描述中,需要说明的是,若出现术语“上”、“下”、“水平”、“内”等指示的方位或位置关系为基于附图所示的方位或位置关系,或者是该发明产品使用时惯常摆放的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。此外,术语“第一”、“第二”等仅用于区分描述,而不能理解为指示或暗示相对重要性。In the description of the embodiments of the present invention, it should be noted that if the terms "upper", "lower", "horizontal", "inside", etc. appear, the orientation or positional relationship indicated is based on the orientation or positional relationship shown in the accompanying drawings , or the orientation or positional relationship that the product of the invention is usually placed in use, it is only for the convenience of describing the present invention and simplifying the description, rather than indicating or implying that the device or element referred to must have a specific orientation, be constructed in a specific orientation and operation, and therefore should not be construed as limiting the present invention. Furthermore, the terms "first", "second", etc. are only used to differentiate the description and should not be construed to indicate or imply relative importance.

此外,若出现术语“水平”,并不表示要求部件绝对水平,而是可以稍微倾斜。如“水平”仅仅是指其方向相对“竖直”而言更加水平,并不是表示该结构一定要完全水平,而是可以稍微倾斜。Furthermore, the presence of the term "horizontal" does not imply that the component is required to be absolutely horizontal, but rather may be tilted slightly. For example, "horizontal" only means that its direction is more horizontal than "vertical", it does not mean that the structure must be completely horizontal, but can be slightly inclined.

在本发明实施例的描述中,还需要说明的是,除非另有明确的规定和限定,若出现术语“设置”、“安装”、“相连”、“连接”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以根据具体情况理解上述术语在本发明中的具体含义。In the description of the embodiments of the present invention, it should also be noted that, unless otherwise expressly specified and limited, the terms "set", "installed", "connected" and "connected" should be understood in a broad sense. It can be a fixed connection, a detachable connection, or an integral connection; it can be a mechanical connection or an electrical connection; it can be a direct connection, or an indirect connection through an intermediate medium, and it can be internal communication between two components. For those of ordinary skill in the art, the specific meanings of the above terms in the present invention can be understood according to specific situations.

下面结合附图对本发明做进一步详细描述:Below in conjunction with accompanying drawing, the present invention is described in further detail:

参见图1,本发明实施例公开了一种用于在线检测的光纤阵列LIBS探测系统,包括激光光纤耦合模块、激光控制模块以及光谱采集模块。激光光纤耦合模块包括纳秒激光器1、二向色镜5、第一平凸透镜7以及传输光纤8;激光控制模块包括第一分光镜2、第二分光镜3、光电二极管12、激光能量计6以及可编程脉冲延迟发生器13;光谱采集模块包括第二平凸透镜4、收集光纤11、光谱仪14以及ICCD15;从纳秒激光器1发出的激光光束最终通过传输光纤8进入到光纤阵列LIBS探头9中。Referring to FIG. 1 , an embodiment of the present invention discloses a fiber array LIBS detection system for online detection, including a laser fiber coupling module, a laser control module, and a spectrum acquisition module. The laser fiber coupling module includes a nanosecond laser 1, a dichroic mirror 5, a first plano-convex lens 7 and a transmission fiber 8; the laser control module includes a first beam splitter 2, a second beam splitter 3, a photodiode 12, and a laser energy meter 6 and a programmable pulse delay generator 13; the spectrum acquisition module includes a second plano-convex lens 4, a collection fiber 11, a spectrometer 14 and an ICCD 15; the laser beam emitted from the nanosecond laser 1 finally enters the fiber array LIBS probe 9 through the transmission fiber 8 .

纳秒激光器1、第一分光镜2、第二分光镜3、二向色镜5均位于同一光路,且纳秒激光器1激光光轴中心、第一分光镜2中心、第二分光镜3中心、二向色镜5中心均位于同一直线上;第一分光镜2、第二分光镜3、二向色镜5均与纳秒激光器1的输出激光光轴成45°夹角。The nanosecond laser 1, the first beam splitter 2, the second beam splitter 3, and the dichroic mirror 5 are all located on the same optical path, and the center of the laser optical axis of the nanosecond laser 1, the center of the first beam splitter 2, and the center of the second beam splitter 3 The centers of the dichroic mirrors 5 and 5 are all located on the same straight line; the first beam splitter 2 , the second beam splitter 3 , and the dichroic mirror 5 all form an included angle of 45° with the output laser axis of the nanosecond laser 1 .

纳秒激光器1输出激光一路透过第一分光镜2,一路被其分光到光电探测器12中,光电探测器12对外连接到示波器上,用于监控主脉冲激光的输出信号;透过第一分光镜2的激光一路继续透过第二分光镜3,一路被其分光到激光能量计6中,激光能量计6对外连接到计算机上,通过实验提前测得进入激光能量计6的激光能量与纳秒激光器1输出的激光能量的比例,在计算机中设置相应的分光系数,从而可以监控纳秒激光器1输出激光的实际能量。The output laser of the nanosecond laser 1 passes through the first beam splitter 2, and is split into the photodetector 12. The photodetector 12 is externally connected to the oscilloscope for monitoring the output signal of the main pulse laser; The laser light of the beam splitter 2 continues to pass through the second beam splitter 3 all the way, and is split all the way to the laser energy meter 6. The laser energy meter 6 is externally connected to the computer, and the laser energy entering the laser energy meter 6 is measured in advance through experiments. The proportion of the laser energy output by the nanosecond laser 1, and the corresponding spectral coefficient is set in the computer, so that the actual energy of the laser output by the nanosecond laser 1 can be monitored.

二向色镜5为短波通二向色镜,直径为50.8mm,截止波长为805nm。对于830-1300nm波长的光,二向色镜5的反射率可以达到96%以上;对于波长为400-792nm波长的光,其通光率也能达到90%以上。The dichroic mirror 5 is a short-wave pass dichroic mirror with a diameter of 50.8 mm and a cut-off wavelength of 805 nm. For light with a wavelength of 830-1300 nm, the reflectivity of the dichroic mirror 5 can reach more than 96%; for light with a wavelength of 400-792 nm, the light transmittance can also reach more than 90%.

经过二向色镜5反射的平行激光束通过第一平凸透镜7聚焦进入传输光纤8中进行传输,传输光纤8的光纤输入端面放置在第一平凸透镜7的焦点后面约3mm处,以避免在光纤耦合时强大的聚焦能量损坏多模光纤芯部包层的边界。The parallel laser beam reflected by the dichroic mirror 5 is focused by the first plano-convex lens 7 into the transmission fiber 8 for transmission. The fiber input end face of the transmission fiber 8 is placed about 3 mm behind the focal point of the first plano-convex lens 7 to avoid The strong focused energy during fiber coupling damages the boundary of the core cladding of the multimode fiber.

图2为光纤阵列LIBS探头对在线进行检测的示意图。光纤阵列LIBS探头9由光纤分束器16和光纤阵列模块17组成;光纤阵列模块17安装固定有16根光纤套筒21;每根光纤套筒21中装有聚焦透镜18,聚焦透镜18由2个卡环19安装在光纤套筒21上的固定位置;传输光纤8经过光纤分束器16分束成16根光纤,每根光纤进入到一根光纤套筒21中;升降平台22与光纤阵列模块17相连并可控制其升降。FIG. 2 is a schematic diagram of the online detection of the fiber array LIBS probe. The fiber array LIBS probe 9 consists of a fiber beam splitter 16 and a fiber array module 17; the fiber array module 17 is installed and fixed with 16 fiber sleeves 21; each fiber sleeve 21 is equipped with a focusing lens 18, and the focusing lens 18 consists of 2 Each snap ring 19 is installed in a fixed position on the optical fiber sleeve 21; the transmission optical fiber 8 is split into 16 optical fibers by the optical fiber splitter 16, and each optical fiber enters an optical fiber sleeve 21; the lifting platform 22 and the optical fiber array The modules 17 are connected and can be controlled to rise and fall.

光纤阵列模块17安装于待测设备10的正上方,其直径为5m,与在线直径相当;通过升降平台22调节聚焦透镜18与待测设备10表面的距离以获得最佳的激光聚焦效果;光纤阵列模块17上的16根光纤套筒21可以实现对整个待测设备10表面的二维阵列同步检测。The fiber array module 17 is installed directly above the device under test 10, and its diameter is 5m, which is equivalent to the diameter of the line; the distance between the focusing lens 18 and the surface of the device under test 10 is adjusted by the lifting platform 22 to obtain the best laser focusing effect; The 16 optical fiber sleeves 21 on the array module 17 can realize the synchronous detection of the two-dimensional array on the entire surface of the device under test 10 .

优选的,本发明所使用的传输光纤8为二氧化硅包层的多模光纤。传输光纤8的长度为3m,光纤芯径为800μm,数值孔径为0.37,最大功率密度为1GW/cm2;光纤的两端使用SMA905不锈钢光纤连接器连接,大数值孔径有利于光纤输入端光线的耦合进入,而在输出端却由于多模光纤的发散性及离轴性使输出的激光难以聚焦打靶;低数值孔径提供了较低的光束发散度和均匀的光斑尺寸,这可以有助于光束传播后聚焦光束。可根据实际需要更换不同型号、不同长度、不同直径和不同数值孔径的多模光纤。Preferably, the transmission fiber 8 used in the present invention is a silica-clad multimode fiber. The length of the transmission fiber 8 is 3m, the fiber core diameter is 800μm, the numerical aperture is 0.37, and the maximum power density is 1GW/cm 2 ; the two ends of the fiber are connected by SMA905 stainless steel fiber connectors, and the large numerical aperture is conducive to the transmission of light at the input end of the fiber. Coupling in, but at the output end, due to the divergence and off-axis of multimode fiber, the output laser is difficult to focus and target; low numerical aperture provides lower beam divergence and uniform spot size, which can help the beam Focus the beam after propagation. Multimode fibers of different types, lengths, diameters and numerical apertures can be replaced according to actual needs.

从传输光纤8输出的激光能量经过光纤分束器16后,激光能量被均等分成16份,分别进入到16根光纤中;从16根光纤输出的16份激光能量同时经过16根光纤套筒21中;16根光纤套筒21中分别固定的16个聚焦透镜18同时将这16份激光能量聚焦击穿待测设备10表面从而形成等离子体。After the laser energy output from the transmission fiber 8 passes through the fiber beam splitter 16, the laser energy is equally divided into 16 parts and enters into the 16 fibers respectively; the 16 parts of the laser energy output from the 16 fibers pass through the 16 fiber sleeves 21 at the same time In the middle; the 16 focusing lenses 18 fixed in the 16 fiber sleeves 21 simultaneously focus the 16 pieces of laser energy to penetrate the surface of the device under test 10 to form plasma.

16根光纤的光纤输出端面放置在光纤套筒21中的聚焦透镜18的一倍焦距之外,根据凸透镜的成像规律,通过透镜的激光会在聚焦透镜18的另一侧形成倒立的实像,在此过程中激光在聚焦透镜18的另一侧存在聚焦;通过计算机控制升降平台22的升降高度,从而使得聚焦透镜18的聚焦焦点正好位于待测设备10表面处。The fiber output end faces of the 16 fibers are placed outside the focal length of the focusing lens 18 in the fiber sleeve 21. According to the imaging law of the convex lens, the laser light passing through the lens will form an inverted real image on the other side of the focusing lens 18. During this process, the laser is focused on the other side of the focusing lens 18 ; the lifting height of the lifting platform 22 is controlled by the computer, so that the focusing point of the focusing lens 18 is located at the surface of the device under test 10 .

激光经过聚焦透镜18聚焦击穿待测设备10表面从而产生等离子体,由于光路是可逆的,因此所产生的等离子体发光光束沿着原光路反向回传。等离子体羽发射的光子通过光纤套筒21内的聚焦透镜18聚焦到16根光纤之中,16根光纤输出的等离子体自发光光束经过光纤分束器16后,同时汇聚到传输光纤8中,然后等离子体自发光光束开始沿传输光纤8反向传输。此时,传输光纤8的激光输出端变为光子输入端,传输光纤8的激光输入端变为光子的输出端。The laser is focused and broken down on the surface of the device under test 10 through the focusing lens 18 to generate plasma. Since the optical path is reversible, the generated plasma luminous beam travels backward along the original optical path. The photons emitted by the plasma plume are focused into the 16 fibers through the focusing lens 18 in the fiber sleeve 21, and the plasma self-luminous beams output by the 16 fibers pass through the fiber beam splitter 16, and then converge into the transmission fiber 8 at the same time, Then the plasma self-luminous beam starts to propagate in the opposite direction along the transmission fiber 8 . At this time, the laser output end of the transmission fiber 8 becomes the photon input end, and the laser input end of the transmission fiber 8 becomes the photon output end.

本发明二向色镜5、第一平凸透镜7、第二平凸透镜4均位于同一光路,传输光纤8输入端面中心、第一平凸透镜7中心、二向色镜5中心、第二平凸透镜4中心、收集光纤11输入端面中心均位于同一直线上;二向色镜5与激光光路和等离子自发光光路成45°夹角。The dichroic mirror 5, the first plano-convex lens 7, and the second plano-convex lens 4 of the present invention are all located on the same optical path. The center of the input end face of the transmission fiber 8, the center of the first plano-convex lens 7, the center of the dichroic mirror 5, and the second plano-convex lens 4 The center and the center of the input end face of the collecting fiber 11 are all located on the same straight line; the dichroic mirror 5 forms an included angle of 45° with the laser light path and the plasma self-luminous light path.

从传输光纤8反向传播的等离子体自发光光束通过第一平凸透镜7变为平行光,平行光通过二向色镜5经过第二平凸透镜4聚焦到收集光纤11中,进而输入到光谱仪14中。The plasma self-luminous beam propagating backward from the transmission fiber 8 becomes parallel light through the first plano-convex lens 7 , and the parallel light is focused into the collection fiber 11 through the dichroic mirror 5 and the second plano-convex lens 4 , and then input to the spectrometer 14 middle.

优选的,收集光纤11的长度为1m,光纤芯径为400μm,数值孔径为0.22。Preferably, the length of the collecting fiber 11 is 1 m, the fiber core diameter is 400 μm, and the numerical aperture is 0.22.

优选的,聚焦透镜18的直径为25.4mm,焦距为35mm。Preferably, the diameter of the focusing lens 18 is 25.4mm, and the focal length is 35mm.

本发明所使用的纳秒激光器1为Nd:YAG纳秒激光器,输出激光波长为1064nm,频率为1-10Hz,脉冲宽度FWHM为10ns,最大脉冲能量为150mJ,激光光束直径为6mm。The nanosecond laser 1 used in the present invention is a Nd:YAG nanosecond laser, the output laser wavelength is 1064 nm, the frequency is 1-10 Hz, the pulse width FWHM is 10 ns, the maximum pulse energy is 150 mJ, and the laser beam diameter is 6 mm.

本发明在对待测设备10表面进行二维光纤阵列LIBS同步检测前的准备工作为:设置可编程脉冲延迟发生器13的参数,改变纳秒激光器1的出光信号与ICCD15门宽信号的延时,同时通过计算机进一步微调升降平台22的升降,使得在计算机的软件上观测到相关元素特征谱线的光谱强度的信背比和光谱图的纵坐标最大。The preparatory work of the present invention before the two-dimensional fiber array LIBS synchronous detection is performed on the surface of the device to be tested 10 is as follows: setting the parameters of the programmable pulse delay generator 13, changing the delay between the light output signal of the nanosecond laser 1 and the gate width signal of the ICCD 15, At the same time, the lifting and lowering of the lifting platform 22 is further fine-tuned by the computer, so that the signal-to-background ratio of the spectral intensity of the characteristic spectral lines of the relevant elements and the ordinate of the spectral graph are observed on the software of the computer to be the largest.

光谱仪14在每次进行待测设备10表面的测量之前,将进行环境背景光谱的采样。每次测量时,纳秒激光器将以1Hz频率间隔发射出20发次的脉冲激光,每次激光击穿待测设备10表面产生的等离子体光谱经过光路传输到光谱仪14中;光谱仪14将采集到的20发次脉冲产生的光谱累加传递到计算机中提供给用户,软件可以自动将得到的光谱数据与数据库中的LIBS元素光谱信息进行分析对比,提供给待测设备10表面中所含的元素种类及对应的谱线强度,并且可以进一步通过定标曲线确待测设备10中所含的铬元素含量。The spectrometer 14 will sample the ambient background spectrum before each measurement of the surface of the device to be tested 10 is performed. During each measurement, the nanosecond laser will emit 20 pulses of laser light at a frequency interval of 1 Hz, and the plasma spectrum generated by the laser breakdown on the surface of the device under test 10 is transmitted to the spectrometer 14 through the optical path; the spectrometer 14 will collect the The spectral accumulation generated by the 20 pulses is transmitted to the computer and provided to the user. The software can automatically analyze and compare the obtained spectral data with the LIBS element spectral information in the database, and provide the element species contained in the surface of the device under test 10. and the corresponding spectral line intensity, and the content of chromium element contained in the device to be tested 10 can be further determined through the calibration curve.

本发明的原理:Principle of the present invention:

本发明传输光纤为高功率传输光纤,具体是二氧化硅包层的多模光纤。传输光纤的长度为3m,光纤芯径为800μm,数值孔径为0.37,最大功率密度为1GW/cm2;光纤的两端使用SMA905不锈钢光纤连接器连接,大数值孔径有利于光纤输入端光线的耦合进入,而在输出端却由于多模光纤的发散性及离轴性使输出的激光难以聚焦打靶;低数值孔径提供了较低的光束发散度和均匀的光斑尺寸,这可以有助于光束传播后聚焦光束。可根据实际需要更换不同型号、不同长度、不同直径和不同数值孔径的多模光纤。The transmission optical fiber of the present invention is a high-power transmission optical fiber, specifically a multimode optical fiber with silica cladding. The length of the transmission fiber is 3m, the core diameter of the fiber is 800μm, the numerical aperture is 0.37, and the maximum power density is 1GW/cm 2 . At the output end, due to the divergence and off-axis of multimode fiber, the output laser is difficult to focus and target; low numerical aperture provides lower beam divergence and uniform spot size, which can help beam propagation rear focus beam. Multimode fibers of different types, lengths, diameters and numerical apertures can be replaced according to actual needs.

本发明光纤阵列模块安装于在线的正上方,其直径为5m与在线直径相当;通过升降平台调节聚焦透镜与在线表面的距离以获得最佳的激光聚焦效果;光纤阵列模块上的16根光纤套筒可以实现对整个在线表面的二维阵列同步检测。The optical fiber array module of the present invention is installed directly above the line, and its diameter is 5m, which is equivalent to the diameter of the line; the distance between the focusing lens and the surface of the line is adjusted by the lifting platform to obtain the best laser focusing effect; 16 fiber sleeves on the fiber array module The cartridge can realize the simultaneous detection of the two-dimensional array of the entire in-line surface.

以上仅为本发明的优选实施例而已,并不用于限制本发明,对于本领域的技术人员来说,本发明可以有各种更改和变化。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above are only preferred embodiments of the present invention, and are not intended to limit the present invention. For those skilled in the art, the present invention may have various modifications and changes. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention shall be included within the protection scope of the present invention.

Claims (4)

1. A fiber array LIBS detection system for on-line detection, comprising:
the laser fiber coupling module is used for outputting laser, and the laser is incident on equipment to be tested (10) through a fiber array LIBS probe (9); setting a laser control module; the laser fiber coupling module comprises a nanosecond laser (1), wherein laser output by the nanosecond laser (1) enters a first plano-convex lens (7) through reflection of a dichroic mirror (5), is focused by the first plano-convex lens (7), and is transmitted to an optical fiber array LIBS probe (9) through a transmission fiber (8); the fiber input end face of the transmission fiber (8) is positioned 3mm behind the focus of the first plano-convex lens (7); the nanosecond laser 1 is Nd: YAG nanosecond laser, output laser wavelength is 1064nm, frequency is 1-10Hz, pulse width FWHM is 10ns, maximum pulse energy is 150mJ, and laser beam diameter is 6mm; the optical fiber array LIBS probe (9) comprises an optical fiber beam splitter (16) and an optical fiber array module (17), wherein a plurality of optical fiber sleeves (21) are installed on the optical fiber array module (17); each optical fiber sleeve (21) is internally provided with a focusing lens (18), and the focusing lens (18) is arranged on the optical fiber sleeve (21) through 2 snap rings (19); the transmission optical fiber (8) is split into a plurality of optical fibers by an optical fiber splitter (16), and each optical fiber enters an optical fiber sleeve (21);
the laser control module is arranged on an output light path of the laser fiber coupling module and used for monitoring the actual energy of the output laser and adjusting the time delay of an outgoing light signal and a gate width signal; the laser control module comprises a first spectroscope (2) and a second spectroscope (3) which are arranged on a light path between a nanosecond laser (1) and a dichroic mirror (5); one part of the output laser is projected to the first spectroscope (2) to the second spectroscope (3), the other part of the output laser is reflected to the photodiode (12) by the first spectroscope (2), one part of the output laser projected to the second spectroscope (2) is projected to the dichroic mirror (5), and the other part of the output laser is reflected to the laser energy meter (6) by the second spectroscope (3);
the spectrum acquisition module comprises a spectrometer (14) and an ICCD (15), wherein the spectrometer (14) is used for collecting a plasma spectrum generated on the surface of the equipment to be tested (10) and transmitting spectrum information to the computer for analysis and comparison; the spectrum acquisition module further comprises a second plano-convex lens (4), plasma generated on the surface of the device to be measured (10) reversely passes back along an original light path, and is changed into parallel light after passing through an optical fiber array LIBS probe (9), a transmission optical fiber (8) and a first plano-convex lens (7), the parallel light is focused into a collection optical fiber (11) through a dichroic mirror (5) and the second plano-convex lens (4), and the other end of the collection optical fiber (11) is connected with a spectrometer (14);
the transmission optical fiber (8) is a silica-clad multimode optical fiber with the length of 3m, the core diameter of 800 μm, the numerical aperture of 0.37 and the maximum power density of 1GW/cm 2 (ii) a Two ends of the optical fiber are connected by an SMA905 stainless steel optical fiber connector; the dichroic mirror (5) is a short-wave-pass dichroic mirror, the diameter of the dichroic mirror is 50.8mm, and the cutoff wavelength is 805nm; the length of the collection fiber (11) was 1m, the fiber core diameter was 400 μm, and the numerical aperture was 0.22.
2. The fiber array LIBS detection system for on-line detection according to claim 1, wherein the fiber array module (17) is disposed above the device under test (10) and has a diameter of 5m; the optical fiber array module (17) is connected with the lifting platform (22) and is controlled to lift through the lifting platform (22).
3. The fiber optic array LIBS detection system for on-line detection as claimed in claim 1, wherein the fiber optic sleeve (21) is provided with 16; the transmission optical fiber (8) is split into 16 optical fibers by an optical fiber splitter (16); the focusing lens 18 has a diameter of 25.4mm and a focal length of 35mm.
4. The fiber array LIBS detection system for on-line detection according to claim 1, wherein the nanosecond laser (1), the first beam splitter (2), the second beam splitter (3) and the dichroic mirror (5) are all located on the same optical path, and the laser optical axis center of the nanosecond laser (1), the center of the first beam splitter (2), the center of the second beam splitter (3) and the center of the dichroic mirror (5) are all located on the same straight line; the first spectroscope (2), the second spectroscope (3) and the dichroic mirror (5) form (45) degrees included angles with an output laser optical axis of the nanosecond laser (1).
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