CN112725100A - Pigment-free environment-friendly degradable laundry slice and manufacturing method thereof - Google Patents
Pigment-free environment-friendly degradable laundry slice and manufacturing method thereof Download PDFInfo
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- CN112725100A CN112725100A CN202011610204.9A CN202011610204A CN112725100A CN 112725100 A CN112725100 A CN 112725100A CN 202011610204 A CN202011610204 A CN 202011610204A CN 112725100 A CN112725100 A CN 112725100A
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- sulfonic acid
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0086—Laundry tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0047—Other compounding ingredients characterised by their effect pH regulated compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/384—Animal products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Zoology (AREA)
- Detergent Compositions (AREA)
Abstract
The invention provides a pigment-free environment-friendly degradable laundry tablet, which comprises the following components in percentage by weight: 50% of soda powder, 12% of dodecylbenzene sulfonic acid, 10% of sodium metasilicate, 10% of alkylbenzene sulfonic acid, 5% of distilled beef tallow, 8% of sodium silicate, 1% of carboxy methyl cellulose, 0.1% of fluorescent whitening agent, 0.5% of thickening agent and the balance of water. The invention provides a method for manufacturing a pigment-free environment-friendly degradable laundry piece, which comprises the following steps: a. adding water into the reactor, and heating to 60 ℃; b. sequentially adding soda powder, dodecyl benzene sulfonic acid, sodium metasilicate and alkyl benzene sulfonic acid into the heated water and continuously stirring; c. after standing for 2 hours, heating the reactor to 75 ℃, and adding distilled beef tallow and sodium silicate; d. after the temperature of the solution is reduced to 30 ℃; e. and finally pouring the solution into a mould, and airing to obtain the laundry tablets.
Description
Technical Field
The invention relates to the technical field of daily washing products, in particular to a pigment-free environment-friendly degradable laundry piece and a manufacturing method thereof.
Background
The laundry pieces are popular with consumers due to the advantages of convenient carrying, convenient packaging and transportation, small occupied space, water conservation, accurate control of usage amount and the like. However, the dirt-removing power of the existing clothes washing pieces on the market at present is difficult to reach the national standard; talcum powder is added as a filler to cause secondary pollution to the environment; the main reasons that the content of active matters of effective decontamination ingredients is not high, the addition mode of enzyme is not scientific and the like exist; according to measures that necessary measures must be taken to prevent, reduce and control marine environmental pollution in various countries of 'United nations ocean Law convention', domestic sewage discharge in ocean operation and ship trip accounts for 50%, so that an environment-friendly degradable washing product is important.
Disclosure of Invention
In view of the above, the application provides a pigment-free environment-friendly degradable laundry tablet and a manufacturing method thereof, and solves the problems that the existing laundry tablet cannot degrade the components and is easy to pollute the environment.
The technical scheme of the invention is as follows:
a non-pigment environment-friendly degradable laundry tablet comprises the following components in percentage by weight: 50% of soda powder, 12% of dodecylbenzene sulfonic acid, 10% of sodium metasilicate, 10% of alkylbenzene sulfonic acid, 5% of distilled beef tallow, 8% of sodium silicate, 1% of carboxy methyl cellulose, 0.1% of fluorescent whitening agent, 0.5% of thickening agent and the balance of water.
The thickening agent is 25% of starch and 75% of pectin.
The thickening agent is 15% of dextrin and 85% of seaweed gel.
The invention also provides a manufacturing method of the pigment-free environment-friendly degradable laundry slice, which comprises the following steps:
a. adding water into the reactor, and heating to 60 ℃;
b. sequentially adding soda powder, dodecylbenzene sulfonic acid, sodium metasilicate and alkylbenzene sulfonic acid into the heated water, continuously stirring, standing for 2 hours after stirring for 30 minutes, and keeping the water temperature at 60 ℃ in the period;
c. standing for 2 hours, heating the reactor to 75 ℃, adding distilled beef tallow and sodium silicate, continuously stirring for 20 minutes, and then stopping heating to ensure that the temperature of the reactor is reduced to 30 ℃;
d. after the temperature of the solution is reduced to 30 ℃, adding carboxymethyl cellulose, fluorescent whitening agent and thickening agent into the reactor in sequence, and continuously stirring for 1 hour;
e. and finally pouring the solution into a mould, and airing to obtain the laundry tablets.
Compared with the prior art, the detailed description of the application is as follows:
the laundry tablets are scientific, environment-friendly, green and pollution-free, can be degraded in natural environment, are safe and stable, have high cleaning degree on products such as clothes and the like when being used, have no chemical corrosivity or irritation, and are low in production cost and good in performance because dodecyl benzene sulfonic acid is an anionic surfactant. The sodium metasilicate has a very high active alkalinity and pH buffering index, has a strong wetting, emulsifying and saponifying effect on grease, has excellent performance in removing, dispersing and suspending dirt, and can prevent redeposition of dirt. The sodium silicate can increase pH and balance. The carboxyl methyl cellulose can prevent the soil from being redeposited on the washed fabrics in water, and can ensure that the detergent can exert larger detergency. The fluorescent whitening agent can make the dyed material obtain the glittering effect similar to fluorite, so that the material seen by naked eyes is very white, thereby achieving the whitening effect.
Detailed Description
In order to make those skilled in the art better understand the technical solution of the present invention, the following detailed description of the present invention is provided with reference to specific embodiments.
Example 1
A non-pigment environment-friendly degradable laundry tablet comprises the following components in percentage by weight: 50% of soda powder, 12% of dodecylbenzene sulfonic acid, 10% of sodium metasilicate, 10% of alkylbenzene sulfonic acid, 5% of distilled beef tallow, 8% of sodium silicate, 1% of carboxy methyl cellulose, 0.1% of fluorescent whitening agent, 0.5% of thickening agent and the balance of water. Wherein the thickener is starch 25% and pectin 75%.
The invention also provides a manufacturing method of the pigment-free environment-friendly degradable laundry slice, which comprises the following steps:
a. adding water into the reactor, and heating to 60 ℃;
b. sequentially adding soda powder, dodecylbenzene sulfonic acid, sodium metasilicate and alkylbenzene sulfonic acid into the heated water, continuously stirring, standing for 2 hours after stirring for 30 minutes, and keeping the water temperature at 60 ℃ in the period;
c. standing for 2 hours, heating the reactor to 75 ℃, adding distilled beef tallow and sodium silicate, continuously stirring for 20 minutes, and then stopping heating to ensure that the temperature of the reactor is reduced to 30 ℃;
d. after the temperature of the solution is reduced to 30 ℃, adding carboxymethyl cellulose, fluorescent whitening agent and thickening agent into the reactor in sequence, and continuously stirring for 1 hour;
e. and finally pouring the solution into a mould, and airing to obtain the laundry tablets.
Example 2
A non-pigment environment-friendly degradable laundry tablet comprises the following components in percentage by weight: 50% of soda powder, 12% of dodecylbenzene sulfonic acid, 10% of sodium metasilicate, 10% of alkylbenzene sulfonic acid, 5% of distilled beef tallow, 8% of sodium silicate, 1% of carboxy methyl cellulose, 0.1% of fluorescent whitening agent, 0.5% of thickening agent and the balance of water.
Wherein the thickener is dextrin 15% and seaweed gel 85%.
The invention also provides a manufacturing method of the pigment-free environment-friendly degradable laundry slice, which comprises the following steps:
a. adding water into the reactor, and heating to 60 ℃;
b. sequentially adding soda powder, dodecylbenzene sulfonic acid, sodium metasilicate and alkylbenzene sulfonic acid into the heated water, continuously stirring, standing for 2 hours after stirring for 30 minutes, and keeping the water temperature at 60 ℃ in the period;
c. standing for 2 hours, heating the reactor to 75 ℃, adding distilled beef tallow and sodium silicate, continuously stirring for 20 minutes, and then stopping heating to ensure that the temperature of the reactor is reduced to 30 ℃;
d. after the temperature of the solution is reduced to 30 ℃, adding carboxymethyl cellulose, fluorescent whitening agent and thickening agent into the reactor in sequence, and continuously stirring for 1 hour;
e. and finally pouring the solution into a mould, and airing to obtain the laundry tablets.
The above is only a preferred embodiment of the present invention, and it should be noted that the above preferred embodiment should not be considered as limiting the present invention, and the protection scope of the present invention should be subject to the scope defined by the claims.
Claims (4)
1. A non-pigment environment-friendly degradable laundry tablet is characterized by comprising the following components in percentage by weight: 50% of soda powder, 12% of dodecylbenzene sulfonic acid, 10% of sodium metasilicate, 10% of alkylbenzene sulfonic acid, 5% of distilled beef tallow, 8% of sodium silicate, 1% of carboxy methyl cellulose, 0.1% of fluorescent whitening agent, 0.5% of thickening agent and the balance of water.
2. The non-pigmented, environmentally friendly, degradable laundry tablet of claim 1, wherein: the thickening agent is 25% of starch and 75% of pectin.
3. The non-pigmented, environmentally friendly, degradable laundry tablet of claim 1, wherein: the thickening agent is 15% of dextrin and 85% of seaweed gel.
4. The method for making the non-pigmented environment-friendly degradable laundry tablet according to claim 1, characterized by comprising the steps of:
a. adding water into the reactor, and heating to 60 ℃;
b. sequentially adding soda powder, dodecylbenzene sulfonic acid, sodium metasilicate and alkylbenzene sulfonic acid into the heated water, continuously stirring, standing for 2 hours after stirring for 30 minutes, and keeping the water temperature at 60 ℃ in the period;
c. standing for 2 hours, heating the reactor to 75 ℃, adding distilled beef tallow and sodium silicate, continuously stirring for 20 minutes, and then stopping heating to ensure that the temperature of the reactor is reduced to 30 ℃;
d. after the temperature of the solution is reduced to 30 ℃, adding carboxymethyl cellulose, fluorescent whitening agent and thickening agent into the reactor in sequence, and continuously stirring for 1 hour;
e. and finally pouring the solution into a mould, and airing to obtain the laundry tablets.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011610204.9A CN112725100A (en) | 2020-12-30 | 2020-12-30 | Pigment-free environment-friendly degradable laundry slice and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011610204.9A CN112725100A (en) | 2020-12-30 | 2020-12-30 | Pigment-free environment-friendly degradable laundry slice and manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112725100A true CN112725100A (en) | 2021-04-30 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202011610204.9A Pending CN112725100A (en) | 2020-12-30 | 2020-12-30 | Pigment-free environment-friendly degradable laundry slice and manufacturing method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1428410A (en) * | 2001-12-25 | 2003-07-09 | 上海白猫有限公司 | Sheet detergent for washing clothes and its preparation method |
| CN106609192A (en) * | 2015-10-22 | 2017-05-03 | 鄢晋 | Industrial washing powder and preparation method thereof |
| CN106854513A (en) * | 2015-12-09 | 2017-06-16 | 西安网清生物科技有限公司 | A kind of green non-phosphide detergent and preparation method thereof |
| CN111117805A (en) * | 2019-12-10 | 2020-05-08 | 中山榄菊日化实业有限公司 | Floor cleaner composition and preparation method thereof |
-
2020
- 2020-12-30 CN CN202011610204.9A patent/CN112725100A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1428410A (en) * | 2001-12-25 | 2003-07-09 | 上海白猫有限公司 | Sheet detergent for washing clothes and its preparation method |
| CN106609192A (en) * | 2015-10-22 | 2017-05-03 | 鄢晋 | Industrial washing powder and preparation method thereof |
| CN106854513A (en) * | 2015-12-09 | 2017-06-16 | 西安网清生物科技有限公司 | A kind of green non-phosphide detergent and preparation method thereof |
| CN111117805A (en) * | 2019-12-10 | 2020-05-08 | 中山榄菊日化实业有限公司 | Floor cleaner composition and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 张华涛: "国内外洗涤用品发展趋势", 《中国洗涤用品工业》 * |
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| PB01 | Publication | ||
| PB01 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20210430 |