CN112679868A - Rubber material for automobile pipeline and preparation method thereof - Google Patents
Rubber material for automobile pipeline and preparation method thereof Download PDFInfo
- Publication number
- CN112679868A CN112679868A CN202011593120.9A CN202011593120A CN112679868A CN 112679868 A CN112679868 A CN 112679868A CN 202011593120 A CN202011593120 A CN 202011593120A CN 112679868 A CN112679868 A CN 112679868A
- Authority
- CN
- China
- Prior art keywords
- parts
- mixing
- rubber
- rubber material
- automobile
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 47
- 239000005060 rubber Substances 0.000 title claims abstract description 47
- 239000000463 material Substances 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 238000002156 mixing Methods 0.000 claims abstract description 40
- 229920002943 EPDM rubber Polymers 0.000 claims abstract description 25
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 21
- 239000004014 plasticizer Substances 0.000 claims abstract description 21
- 239000012763 reinforcing filler Substances 0.000 claims abstract description 21
- 239000002994 raw material Substances 0.000 claims abstract description 19
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 17
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000012190 activator Substances 0.000 claims abstract description 13
- 239000011593 sulfur Substances 0.000 claims abstract description 13
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 13
- IPJGAEWUPXWFPL-UHFFFAOYSA-N 1-[3-(2,5-dioxopyrrol-1-yl)phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC(N2C(C=CC2=O)=O)=C1 IPJGAEWUPXWFPL-UHFFFAOYSA-N 0.000 claims abstract description 11
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 10
- 238000007599 discharging Methods 0.000 claims description 16
- ZNRLMGFXSPUZNR-UHFFFAOYSA-N 2,2,4-trimethyl-1h-quinoline Chemical compound C1=CC=C2C(C)=CC(C)(C)NC2=C1 ZNRLMGFXSPUZNR-UHFFFAOYSA-N 0.000 claims description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 14
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 14
- 238000001816 cooling Methods 0.000 claims description 12
- 238000004898 kneading Methods 0.000 claims description 10
- 239000006232 furnace black Substances 0.000 claims description 9
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 claims description 8
- 238000004140 cleaning Methods 0.000 claims description 8
- 238000001125 extrusion Methods 0.000 claims description 8
- 239000010445 mica Substances 0.000 claims description 8
- 229910052618 mica group Inorganic materials 0.000 claims description 8
- 229920000642 polymer Polymers 0.000 claims description 8
- 238000010074 rubber mixing Methods 0.000 claims description 8
- 239000002202 Polyethylene glycol Substances 0.000 claims description 7
- 235000021355 Stearic acid Nutrition 0.000 claims description 7
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 7
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 7
- 229920001223 polyethylene glycol Polymers 0.000 claims description 7
- 239000008117 stearic acid Substances 0.000 claims description 7
- 239000011787 zinc oxide Substances 0.000 claims description 7
- 239000006242 Semi-Reinforcing Furnace Substances 0.000 claims description 5
- 239000012169 petroleum derived wax Substances 0.000 claims description 5
- 235000019381 petroleum wax Nutrition 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims 1
- 239000000498 cooling water Substances 0.000 abstract description 5
- 230000006835 compression Effects 0.000 description 8
- 238000007906 compression Methods 0.000 description 8
- 239000003292 glue Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 239000013543 active substance Substances 0.000 description 4
- 229920002725 thermoplastic elastomer Polymers 0.000 description 4
- 239000004636 vulcanized rubber Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000005662 Paraffin oil Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000003878 thermal aging Methods 0.000 description 3
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920001875 Ebonite Polymers 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000007541 indentation hardness test Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to the field of rubber, and discloses a rubber material for an automobile pipeline and a preparation method thereof, wherein the rubber material comprises the following raw materials in parts by weight: 36.29-38.06 parts of ethylene propylene diene monomer, 41.94-42.69 parts of reinforcing filler, 12.82-13.16 parts of plasticizer, 2.45-3.09 parts of activator, 0.04-0.11 part of sulfur, 2.10-2.21 parts of 1,31, 4-bis (tert-butylperoxyisopropyl) benzene, 1.03-1.05 parts of trimethylolpropane trimethacrylate, 0.54-0.57 part of N, N' -m-phenylene bismaleimide and 0.89-0.96 part of anti-aging agent; the preparation method of the rubber material comprises the following steps: (1) mixing ethylene propylene diene monomer with a reinforcing filler, a plasticizer, an activator and an anti-aging agent according to a specific sequence and a specific adding amount to obtain a master batch; (2) and (3) mixing the master batch with the rest raw materials to obtain the product. The rubber material prepared by taking the ethylene propylene diene monomer as the raw material can meet the requirement of the DBL6254 standard, can be used for preparing a cooling water pipe of an automobile, and widens the application range of the ethylene propylene diene monomer.
Description
Technical Field
The invention relates to the field of rubber, in particular to a rubber material for an automobile pipeline and a preparation method thereof.
Background
The rubber product for the automobile cooling water pipe is required to have high temperature resistance, low compression permanent deformation resistance and insulation resistance, and meet the DBL6254 standard requirement and the ELV instruction requirement. At present, ethylene propylene diene monomer has heat aging resistance, electrical insulation and ozone resistance, so that ethylene propylene diene monomer becomes one of the preferred materials for rubber products. However, in the prior art, when the ethylene propylene diene monomer is used for manufacturing rubber products for automobile cooling water pipe pipelines, the ethylene propylene diene monomer is difficult to meet the requirements of the DBL6254 standard on compression permanent deformation resistance and elongation at break change after thermal aging resistance, so that the ethylene propylene diene monomer material cannot be applied to the manufacturing of the automobile cooling water pipe pipelines. Therefore, a rubber material which meets the DBL6254 standard requirement and is prepared by taking ethylene propylene diene monomer as a raw material is needed.
Disclosure of Invention
The invention aims to provide a rubber material for automobile pipelines and a preparation method thereof, and aims to solve the problem that a rubber product prepared from ethylene propylene diene monomer serving as a raw material in the prior art is difficult to meet the DBL6254 standard.
In order to achieve the purpose, the invention adopts the following technical scheme: a rubber material for an automobile pipeline comprises the following raw materials in parts by weight: 36.29-38.06 parts of ethylene propylene diene monomer, 41.94-42.69 parts of reinforcing filler, 12.82-13.16 parts of plasticizer, 2.45-3.09 parts of activator, 0.04-0.11 part of sulfur, 2.10-2.21 parts of 1,31, 4-bis (tert-butylperoxyisopropyl) benzene, 1.03-1.05 parts of trimethylolpropane trimethacrylate, 0.54-0.57 part of N, N' -m-phenylene bismaleimide and 0.89-0.96 part of anti-aging agent.
The invention also provides a preparation method of the rubber material for the automobile pipeline, which comprises the following steps:
step one, controlling the working temperature of an internal mixer to be below 100 ℃, putting ethylene propylene diene monomer into the internal mixer, mixing for 8-12 s, sequentially putting 2/3 reinforcing filler, 2/3 plasticizer, activator and anti-aging agent, mixing for 35-45 s, sequentially putting the rest reinforcing filler and plasticizer, mixing for 55-65 s, cleaning, continuously mixing for 200-250 s, discharging rubber when the mixing temperature reaches 155-165 ℃, moving the rubber to an open rubber mixing machine, discharging the rubber, and cooling to room temperature to obtain master batch;
and step two, controlling the working temperature of the kneading machine to be below 70 ℃, putting the master batch, sulfur, 1,31, 4-bis (tert-butyl peroxy isopropyl) benzene, trimethylolpropane trimethacrylate and N, N' -m-phenylene bismaleimide into the kneading machine together for mixing for 55-65 s, continuously mixing for 200-240 s after turning over and cleaning, discharging the rubber and transferring to an open type rubber mixing machine for sheet discharging, cooling and standing to obtain the product.
Preferably, as an improvement, the reinforcing filler is 19.21-19.42 parts of fast extrusion furnace black, 11.65-12.10 parts of semi-reinforcing furnace black and 10.87-11.38 parts of mica.
Preferably, as an improvement, the plasticizer is petroleum wax.
Preferably, as an improvement, the activator is 1.55-2.13 parts of zinc oxide, 0.16-0.21 part of stearic acid and 0.74-0.75 part of polyethylene glycol.
Preferably, as an improvement, the anti-aging agent is 0.54-0.57 part of 2,2, 4-trimethyl-1, 2-dihydroquinoline polymer and 0.35-0.39 part of 2-mercaptobenzimidazole.
Preferably, as an improvement, in the step one, the rotation speed of mixing is 35-38 rpm; in the second step, the rotation speed of the mixing is 25-28 rpm.
The principle and the advantages of the scheme are as follows: in the scheme, the ethylene propylene diene monomer with medium ethylene content (the ethylene mass content is 55-65%) is adopted as the formula of the main raw material, so that the prepared product has both high and low temperature resistance and insulation performance, in addition, sulfur, 1,31, 4-bis (tert-butyl peroxy isopropyl) benzene, trimethylolpropane trimethacrylate and N, N' -m-phenylene bismaleimide are used as vulcanizing agents to improve the heat resistance and the compression permanent deformation resistance of the vulcanized rubber, fast extrusion furnace black, semi-reinforced furnace black and mica are used as reinforcing fillers to improve the hardness and the insulating property of the vulcanized rubber, 2, 4-trimethyl-1, 2-dihydroquinoline polymer and 2-mercaptobenzimidazole are used as anti-aging agents to improve the heat resistance of the vulcanized rubber, and paraffin oil with a high flash point is used as a plasticizer to improve the heat resistance of the vulcanized rubber; and a unique preparation method is matched, and the specific adding sequence, adding amount, mixing time, mixing temperature and mixing rotating speed are adopted, so that the compression permanent deformation resistance and the elongation at break change after thermal aging resistance of the prepared product meet the requirements of the DBL6254 standard.
Detailed Description
The following is further detailed by way of specific embodiments:
example 1
A rubber material for an automobile pipeline comprises the following raw materials in parts by weight: 37.13 parts of ethylene propylene diene monomer, 42.33 parts of reinforcing filler, 13.00 parts of plasticizer, 2.79 parts of activator, 0.07 part of sulfur, 2.15 parts of 1,31, 4-bis (tert-butyl peroxy isopropyl) benzene, 1.04 parts of trimethylolpropane trimethacrylate, 0.56 part of N, N' -m-phenylene bismaleimide and 0.93 part of anti-aging agent. Wherein the reinforcing filler comprises 19.31 parts of fast extrusion furnace black, 11.88 parts of semi-reinforcing furnace black and 11.14 parts of mica; the plasticizer is petroleum wax; the active agent is zinc oxide 1.86 parts, stearic acid 0.19 parts and polyethylene glycol 0.74 parts; the anti-aging agent comprises 0.56 part of 2,2, 4-trimethyl-1, 2-dihydroquinoline polymer and 0.37 part of 2-mercaptobenzimidazole.
A preparation method of a rubber material for an automobile pipeline comprises the following steps;
step one, introducing water into an internal mixer for cooling, controlling the temperature of a working chamber of the internal mixer to be below 100 ℃, adjusting the rotating speed to be 35rpm, adjusting the top plug pressure to be 0.45MPa, putting a rubber raw material, namely ethylene propylene diene monomer rubber, in the formula into the internal mixer, and mixing for 10 s; adjusting the rotation speed to 38rpm, sequentially adding 2/3 reinforcing filler, 2/3 plasticizer, activator and antioxidant into an internal mixer, mixing for 40s, then adding the rest reinforcing filler and plasticizer, and mixing for 60 s; cleaning, continuously mixing for 200s until the glue temperature reaches 160 ℃, then discharging the glue, moving to an open rubber mixing machine for sheet discharging, and cooling to room temperature to obtain master batch;
and step two, cooling the kneading machine by introducing water, controlling the temperature of a working chamber of the kneading machine to be below 70 ℃, adjusting the rotating speed to be 25rpm, adjusting the top plug pressure to be 0.70MPa, putting the master batch prepared in the step one, sulfur, 1,31, 4-bis (tert-butyl peroxy isopropyl) benzene, trimethylolpropane trimethacrylate and N, N' -m-phenylene bismaleimide in the formula into the kneading machine together, mixing for 60s, then turning over and cleaning, continuously mixing until the glue temperature reaches 90 ℃, discharging the glue after the mixing time reaches 200s, then moving the glue to an open type rubber mixing machine, discharging the sheets, cooling, and standing for 8-24 h to obtain the product.
Example 2
This embodiment is different from embodiment 1 in that: the weight parts of the raw materials in this embodiment are different from those in embodiment 1, and specifically, in this embodiment, a rubber material for an automobile pipeline includes the following raw materials in parts by weight: 36.29 parts of ethylene propylene diene monomer, 42.69 parts of reinforcing filler, 13.16 parts of plasticizer, 3.09 parts of activator, 0.11 part of sulfur, 2.10 parts of 1,31, 4-bis (tert-butyl peroxy isopropyl) benzene, 1.03 parts of trimethylolpropane trimethacrylate, 0.57 part of N, N' -m-phenylene bismaleimide and 0.96 part of anti-aging agent. Wherein the reinforcing filler comprises 19.21 parts of fast extrusion furnace black, 12.10 parts of semi-reinforcing furnace black and 11.38 parts of mica; the plasticizer is petroleum wax; the active agent is 2.13 parts of zinc oxide, 0.21 part of stearic acid and 0.75 part of polyethylene glycol; the anti-aging agent comprises 0.57 part of 2,2, 4-trimethyl-1, 2-dihydroquinoline polymer and 0.39 part of 2-mercaptobenzimidazole.
Example 3
This embodiment is different from embodiment 1 in that: the weight parts of the raw materials in this embodiment are different from those in embodiment 1, and specifically, in this embodiment, a rubber material for an automobile pipeline includes the following raw materials in parts by weight: 38.06 parts of ethylene propylene diene monomer, 41.94 parts of reinforcing filler, 12.82 parts of plasticizer, 2.45 parts of activator, 0.04 part of sulfur, 2.21 parts of 1,31, 4-bis (tert-butylperoxyisopropyl) benzene, 1.05 parts of trimethylolpropane trimethacrylate, 0.54 part of N, N' -m-phenylene bismaleimide and 0.89 part of anti-aging agent. Wherein the reinforcing filler comprises 19.42 parts of fast extrusion furnace black, 11.65 parts of semi-reinforcing furnace black and 10.87 parts of mica; the plasticizer is petroleum wax; the active agent is 1.55 parts of zinc oxide, 0.16 part of stearic acid and 0.74 part of polyethylene glycol; the anti-aging agent comprises 0.54 part of 2,2, 4-trimethyl-1, 2-dihydroquinoline polymer and 0.35 part of 2-mercaptobenzimidazole.
Comparative example
The comparative example provides a rubber product taking ethylene propylene diene monomer as a raw material in the prior art, which comprises the following raw materials in parts by weight: 35.41 parts of ethylene propylene diene monomer, 23.73 parts of fast extrusion furnace black, 23.02 parts of mica, 12.75 parts of paraffin oil, 1.77 parts of zinc oxide, 0.18 part of stearic acid, 0.71 part of polyethylene glycol, 0.07 part of sulfur, 1.06 parts of dicumyl peroxide, 0.42 part of triallyl isocyanurate, 0.53 part of 2,2, 4-trimethyl-1, 2-dihydroquinoline polymer and 0.35 part of 2-mercaptobenzimidazole. Wherein, the fast extrusion furnace black and mica are used as reinforcing fillers, paraffin oil is used as a plasticizer, zinc oxide, stearic acid and polyethylene glycol are used as active agents, sulfur, dicumyl peroxide and triallyl isocyanurate are used as vulcanizing agents, and 2,2, 4-trimethyl-1, 2-dihydroquinoline polymer and 2-mercaptobenzimidazole are used as anti-aging agents.
The method for preparing the rubber product in the comparative example comprises the following steps:
step one, introducing water into an internal mixer for cooling, controlling the temperature of a working chamber of the internal mixer to be below 100 ℃, adjusting the rotating speed to be 35rpm, adjusting the top plug pressure to be 0.45MPa, putting a rubber raw material, namely ethylene propylene diene monomer rubber, in the formula into the internal mixer, and mixing for 10 s; adjusting the rotation speed to 40rpm, sequentially adding the reinforcing filler, the plasticizer, the activator and the anti-aging agent into an internal mixer, and mixing for 100 s; cleaning, continuously mixing until the glue temperature reaches 150 ℃, mixing for 200s, then discharging the glue, moving to an open rubber mixing machine, discharging the sheet, and cooling to room temperature to obtain master batch;
and step two, introducing water into the kneading machine for cooling, controlling the temperature of a working chamber of the kneading machine to be below 70 ℃, adjusting the rotating speed to be 25rpm, adjusting the top plug pressure to be 0.70MPa, putting the master batch prepared in the step one and a vulcanizing agent in the formula into the kneading machine, mixing for 60s, then turning over and cleaning the rubber, continuously mixing until the rubber temperature reaches 100 ℃, discharging the rubber after the mixing time reaches 200s, moving the rubber to an open type rubber mixing machine for discharging, cooling and standing for 8-24 h to obtain the product.
The products prepared in examples 1 to 3 and the product prepared in the comparative example were subjected to an index test against the DBL6254 standard, and the test results are shown in table 1.
TABLE 1
In Table 1, test method ISO 868 refers to a test conducted in accordance with the indentation hardness test using a durometer for plastics and hard rubbers, ISO 37 refers to a test conducted in accordance with the measurement Standard for vulcanized or thermoplastic rubbers and tensile stress-Strain characteristics, ISO 34-1 refers to a test conducted in accordance with the measurement of the tear Strength of vulcanized or thermoplastic rubbers, ISO 188 refers to a test conducted in accordance with the accelerated aging and Heat resistance test for vulcanized or thermoplastic rubbers, and ISO 815-1B refers to a test conducted in accordance with the measurement of the compression set of vulcanized or thermoplastic rubbers.
As can be seen from Table 1, the products prepared in examples 1 to 3 had elongation at break changes of-46.1%, -48.0%, -47.1%, respectively, and met the DBL6254 standard, and had compression set resistances of 36.6, 37.5, and 36.4, respectively, and also met the DBL6254 standard, and the other indices (in Table 1) were all acceptable. However, the product prepared in the comparative example, although the other indexes (in table 1) of the product prepared in the comparative example were acceptable, had a change in elongation at break of-56.1% and a compression set resistance of 71.0, both of which did not meet the DBL6254 standard.
Therefore, in the invention, because the sulfur, the 1,31, 4-bis (tert-butylperoxyisopropyl) benzene, the trimethylolpropane trimethacrylate and the N, N' -m-phenylene bismaleimide are adopted as vulcanizing agents, and a unique preparation method is matched to limit the adding sequence and adding amount of raw materials and limit the mixing rotating speed, mixing time and mixing temperature in different stages, the compression permanent deformation resistance of the rubber material produced and prepared by the invention is improved, the rubber material meets the DBL6254 standard, meanwhile, the elongation at break change after thermal aging resistance meets the DBL6254 standard, and other indexes meet the DBL6254 standard, so that the rubber material prepared by taking the ethylene propylene diene monomer as the raw material can be used for preparing an automobile cooling water pipe, and the application range of the ethylene propylene diene monomer is widened.
The foregoing is merely an example of the present invention and common general knowledge in the art of designing and/or characterizing particular aspects and/or features is not described in any greater detail herein. It should be noted that, for those skilled in the art, without departing from the technical solution of the present invention, several variations and modifications can be made, which should also be regarded as the protection scope of the present invention, and these will not affect the effect of the implementation of the present invention and the practicability of the patent. The scope of the claims of the present application shall be determined by the contents of the claims, and the description of the embodiments and the like in the specification shall be used to explain the contents of the claims.
Claims (7)
1. A rubber material for automobile pipelines is characterized in that: the composite material comprises the following raw materials in parts by weight: 36.29-38.06 parts of ethylene propylene diene monomer, 41.94-42.69 parts of reinforcing filler, 12.82-13.16 parts of plasticizer, 2.45-3.09 parts of activator, 0.04-0.11 part of sulfur, 2.10-2.21 parts of 1,31, 4-bis (tert-butylperoxyisopropyl) benzene, 1.03-1.05 parts of trimethylolpropane trimethacrylate, 0.54-0.57 part of N, N' -m-phenylene bismaleimide and 0.89-0.96 part of anti-aging agent.
2. The rubber material for automobile pipes according to claim 1, wherein: the reinforcing filler is 19.21-19.42 parts of fast extrusion furnace black, 11.65-12.10 parts of semi-reinforcing furnace black and 10.87-11.38 parts of mica.
3. The rubber material for automobile pipes according to claim 2, wherein: the plasticizer is petroleum wax.
4. The rubber material for automobile pipes according to claim 3, wherein: the activator is 1.55-2.13 parts of zinc oxide, 0.16-0.21 part of stearic acid and 0.74-0.75 part of polyethylene glycol.
5. The rubber material for automobile pipes according to claim 4, wherein: the anti-aging agent comprises 0.54-0.57 part of 2,2, 4-trimethyl-1, 2-dihydroquinoline polymer and 0.35-0.39 part of 2-mercaptobenzimidazole.
6. A preparation method of a rubber material for an automobile pipeline is characterized by comprising the following steps: the method comprises the following steps:
step one, controlling the working temperature of an internal mixer to be below 100 ℃, putting ethylene propylene diene monomer into the internal mixer, mixing for 8-12 s, sequentially putting 2/3 reinforcing filler, 2/3 plasticizer, activator and anti-aging agent, mixing for 35-45 s, sequentially putting the rest reinforcing filler and plasticizer, mixing for 55-65 s, cleaning, continuously mixing for 200-250 s, discharging rubber when the mixing temperature reaches 155-165 ℃, moving the rubber to an open rubber mixing machine, discharging the rubber, and cooling to room temperature to obtain master batch;
and step two, controlling the working temperature of the kneading machine to be below 70 ℃, putting the master batch, sulfur, 1,31, 4-bis (tert-butyl peroxy isopropyl) benzene, trimethylolpropane trimethacrylate and N, N' -m-phenylene bismaleimide into the kneading machine together for mixing for 55-65 s, continuously mixing for 200-240 s after turning over and cleaning, discharging the rubber and transferring to an open type rubber mixing machine for sheet discharging, cooling and standing to obtain the product.
7. The method for preparing a rubber material for automobile pipes according to claim 6, wherein: in the first step, the mixing speed is 35-38 rpm; in the second step, the rotation speed of the mixing is 25-28 rpm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011593120.9A CN112679868A (en) | 2020-12-29 | 2020-12-29 | Rubber material for automobile pipeline and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011593120.9A CN112679868A (en) | 2020-12-29 | 2020-12-29 | Rubber material for automobile pipeline and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112679868A true CN112679868A (en) | 2021-04-20 |
Family
ID=75454976
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202011593120.9A Pending CN112679868A (en) | 2020-12-29 | 2020-12-29 | Rubber material for automobile pipeline and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112679868A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107857944A (en) * | 2017-11-03 | 2018-03-30 | 上海天普汽车零部件有限公司 | A kind of automobile using urea conducting tube elastomeric material and preparation method thereof |
-
2020
- 2020-12-29 CN CN202011593120.9A patent/CN112679868A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107857944A (en) * | 2017-11-03 | 2018-03-30 | 上海天普汽车零部件有限公司 | A kind of automobile using urea conducting tube elastomeric material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107189236B (en) | Sulfur-vulcanized ethylene propylene diene monomer composition with heat aging resistance and low pressure change, preparation method, application and application product thereof | |
| CN106317901B (en) | A kind of modified Nano compound silica gel sealing ring and its preparation | |
| JP7316484B2 (en) | Rubber composition and processing method, and rubber product using the same and manufacturing method | |
| CN106543505B (en) | A kind of high-performance acrylonitrile butadiene packing material and preparation method thereof | |
| CS196337B2 (en) | Elastomere thermoplastic composition | |
| CN100429274C (en) | Sulfurizing system and chlorinated isobutylene rubber/polyolefine thermoplastic elastomer | |
| CN112321952B (en) | Ethylene propylene diene monomer composite rubber material and preparation method thereof | |
| CN107446358A (en) | A kind of low temperature resistant electrically insulating silicone rubber and preparation method thereof | |
| BR112014017195B1 (en) | PEROXIDE-FREE RETICULABLE THERMOPLASTIC COMPOSITION, PROCESS TO PREPARE A RETICULATED SEMICONDUCTOR THERMOPLASTIC ARTICLE, IN-LINE PROCESS TO PREPARE A RETICULABLE COMPOSITION AND GRAIN | |
| CN111234388A (en) | High-temperature-resistant low-pressure-change radiator water pipe material vulcanized by sulfur system and preparation method thereof | |
| JP7152033B2 (en) | Rubber composition and processing method, and high-strength product and manufacturing method using the same | |
| CN108299743A (en) | Rubber composition and processing method and application, and production fire-retardant product method | |
| CN111253687A (en) | Blended rubber of silicon rubber and ethylene propylene diene monomer and preparation method thereof | |
| CN112375306B (en) | Rubber material for sealing rubber strip | |
| CN110591175B (en) | Non-filled rubber composition with high mechanical property and low hysteresis loss and preparation method thereof | |
| CN111548570A (en) | High-performance ethylene propylene rubber sealing gasket, and preparation method and application thereof | |
| WO2021256296A1 (en) | Silane coupling agent composition, and rubber composition comprising same | |
| CN112679868A (en) | Rubber material for automobile pipeline and preparation method thereof | |
| CN113354949A (en) | High-temperature-resistant and illumination-resistant silicon rubber material for sealing household appliance | |
| CN107828121A (en) | A kind of dynamic vulcanization thermoplastic elastomer material and preparation method thereof | |
| CN104861313B (en) | A kind of preparation method of resistant to urea solution thermal-ageing-resistant rubber material | |
| CN115028927B (en) | Ultralow-hardness high-resilience low-pressure-change ethylene propylene diene monomer rubber material and preparation method thereof | |
| KR101922525B1 (en) | Foam compounds having excellent processibility, high mechanical properties, low compression set and adhesion strength in primerless state and method producing thereof | |
| WO2023112393A1 (en) | Tire rubber composition, and tire | |
| KR20160119547A (en) | Foam compounds having high mechanical properties and low compression set and adhesion strength in primerless state and method producing thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20210420 |