CN112645515B - Tail end drainage integrated device for advanced treatment of tail water - Google Patents
Tail end drainage integrated device for advanced treatment of tail water Download PDFInfo
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- CN112645515B CN112645515B CN202011358471.1A CN202011358471A CN112645515B CN 112645515 B CN112645515 B CN 112645515B CN 202011358471 A CN202011358471 A CN 202011358471A CN 112645515 B CN112645515 B CN 112645515B
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
- C02F1/32—Treatment of water, waste water, or sewage by irradiation with ultraviolet light
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/725—Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/78—Treatment of water, waste water, or sewage by oxidation with ozone
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
Abstract
The invention discloses a tail end drainage integrated device for advanced treatment of tail water, which comprises a tail water regulating tank and an integrated sleeve type drainage pipe which are fixedly connected in a sealing way, wherein the tail water regulating tank is connected with an automatic acid-base adding device, a tail water inlet pipe and a regulating tank water outlet pipe are arranged on the side wall of a tank body, and an electric stirrer is arranged in the tank; the integrated sleeve type drain pipe is a transparent circular sleeve with a radial section of 3/4 sector and an upward opening direction, and the wall of the sleeve type drain pipe is axially provided with a plurality of circular trunking and micro-nano O distributed at intervals 3 The inside of the breather pipe is provided with a plurality of porous slots which are uniformly distributed along the radial direction, and the outside of the integrated sleeve type drain pipe is provided with a micro-nano O 3 Micro-nano O communicated with ventilation pipe 3 A generator. The invention realizes synchronous treatment of deep micro-nano aeration, ultraviolet irradiation and multi-layer adsorption while conveying tail water on the basis of not increasing a tail water discharge structure, has good effect of deep pollutant removal, flexible device arrangement and convenient installation and maintenance.
Description
Technical Field
The invention belongs to the technical field of sewage treatment engineering, and particularly relates to a tail end drainage integrated device for advanced treatment of tail water, which is used for advanced treatment of industrial wastewater or tail water discharged by a sewage treatment plant.
Background
Because the industrial sewage quality is complex, the difficulty of standard discharge or nano-tube is high, the cost is greatly increased by adopting the traditional sewage treatment method along with the continuous improvement of the standard discharge and nano-tube requirements of the sewage of enterprises, and the economic burden is increased. In addition, most urban domestic sewage plants adopt mature biological treatment processes, but the tail water discharged by the urban domestic sewage plants is seriously polluted by nitrogen and phosphorus. At present, sewage treatment at home and abroad mainly uses a mode of constructing various structures to form different treatment process facilities, and most pollutants are removed by an active carbon adsorption method, a membrane separation method, an advanced oxidation method, an ultrasonic radiation degradation method, an electrochemical oxidation method, an ozone oxidation method, a microorganism treatment method and the like, and then tail water is short-circuited to a pipe network for receiving sewage through a discharge pipeline or is directly discharged into a nearby receiving water body. Usually, the tail water discharge pipeline is a precast pipeline made of concrete pouring structures, PVC, concrete or glass fiber reinforced plastics and the like, and can only meet the discharge and diversion functions of wastewater.
In the prior art, there are many patents (or patent applications) related to improving the performance and function of tail water discharge pipelines, such as "CN 201210107988", a method for degrading grease in a restaurant sewage pipeline "," CN201310528568 ", a low pollution tail water advanced treatment device", "CN 201850198U", a high efficiency denitrification wetland system for advanced treatment of tail water in a sewage plant "," CN201210107988 ", a method for degrading grease in a restaurant sewage pipeline", "CN 201410433567.8", a permeable sewage dual-energy winding structure wall pipe "," CN 2015147678. X, an organic wastewater treatment pipeline and organic wastewater treatment system "," CN201620402571.2 ", a wastewater ultraviolet disinfection pipeline", "CN 201710252009.5", a wastewater evolution recycling device ", etc. In summary, the advanced treatment of the tail water at present needs new construction, increased land area, large investment and high energy consumption, and most pollutants (including emerging pollutants) cannot be removed simply by virtue of a total discharge pipeline, so that the requirements of directly discharging sewage to reach the standard cannot be met.
Disclosure of Invention
Aiming at the defects existing in the prior art, the invention aims to provide a tail end drainage integrated device for advanced treatment of tail water, which adopts ultraviolet light and O 3 The oxidation and catalytic adsorption combined integrated device is used for purifying tail water discharged by industrial enterprises or sewage treatment plants, and effectively degrading organic matters, heavy metals, nitrogen and phosphorus, bacterial pathogens and other emerging pollutants remained in the tail water.
In order to achieve the above purpose, the technical scheme adopted by the invention is as follows:
an end drainage integrated device for advanced treatment of tail water comprises a tail water adjusting tank and an integrated sleeve type drain pipe which are fixedly connected in a sealing manner;
the tail water adjusting tank is connected with an automatic acid-base adding device, a tail water inlet pipe and an adjusting tank water outlet pipe are arranged on the side wall of the tank body, and an electric stirrer is arranged in the tank;
the integrated sleeve type drain pipe is a transparent circular sleeve pipe with a radial section of 3/4 sector and an upward opening direction, and the pipe wall of the sleeve type drain pipe is axially provided with a plurality of circular wire grooves and micro-nano O which are distributed at intervals 3 A plurality of uniformly distributed porous slots are arranged in the breather pipe along the radial direction; wherein:
an ultraviolet lamp band is arranged in the circular wire slot, and the micro-nano O is arranged in the circular wire slot 3 A plurality of micro-nano O which are uniformly distributed are arranged on the pipe wall of the vent pipe 3 The cross section of the porous slot is in a round flask shape, the diameter of the round part of the porous slot is the same as the diameter of the inner wall of the integrated sleeve-type drain pipe, the width of the cross section of the bottleneck part is the same as the width of the opening of the integrated sleeve-type drain pipe, and a catalytic adsorption material bag is arranged in the porous slot;
the outside of the integrated sleeve-type drain pipe is provided with the micro-nano O 3 Micro-nano O communicated with ventilation pipe 3 A generator.
According to some embodiments of the invention, the tail water regulating tank is of a square concrete pouring structure, the height of the tank body is greater than 1 meter, the inner wall of the tank body is carved with a height scale, and the size of the tank body is 1-10m according to the flow velocity of tail water 3 Designing the daily average discharge amount; the water outlet pipe of the regulating tank is of an integral pouring structure with the tail water regulating tank, and is fixedly connected with the water inlet pipe orifice of the integral sleeve type water outlet pipe in a sealing way through a stainless steel outer sleeve.
According to some embodiments of the invention, the tail water inlet pipe is made of PVC, concrete or glass fiber reinforced plastic, is 10-15cm away from the bottom of the tail water regulating tank, and is connected with a flowmeter and a flow regulating valve.
According to some embodiments of the invention, the material of the water outlet pipe of the regulating tank is selected from PVC, concrete or glass fiber reinforced plastic, and the distance from the bottom of the tail water regulating tank is not less than 2/3 of the total height of the tank body.
According to some embodiments of the invention, the automatic acid-base adding device is communicated with the tail water regulating tank through an acid-base adding pipe 5, and the acid-base adding pipe is led into one side of the tail water regulating tank, which is close to the tail water inlet pipe; the acid-base adding pipe is made of polyethylene, and the capacity of the acid-base automatic adding device is not less than 40L.
In some embodiments of the present invention, the material of the integrated sleeve-type drain pipe is transparent PMMA or PVC, and the pipe wall is provided with a plurality of micro-nano O along the radial direction 3 And the fine holes are communicated with the vent holes, and an e-PTFE acid and alkali resistant patch type breathable waterproof film is fixed on one side of the inner wall of the fine holes.
According to some embodiments of the invention, the diameter of the circular wire grooves is 10-15mm, the number of the circular wire grooves is 6-8, and the ultraviolet lamp strip is formed by connecting UV LED lamp beads with the diameter of 8-12mm, the wavelength of 395nm and the power of 3W in series.
Some embodiments of the invention, the micro-nano O 3 The number of the ventilation pipes is 4-6, and the micro-nano O 3 The interval between the vent holes is 6-10cm.
According to some embodiments of the invention, the porous slots are made of ultra-fine polyethylene fibers and are uniformly distributed along the axial direction of the integrated sleeve type drain pipe at intervals of 10-15 cm.
According to some embodiments of the invention, the catalytic adsorption material bag is filled with a catalytic adsorption material packaged and shaped by a waterproof and anti-corrosion geotextile, and comprises the following components in parts by weight: 22-35 parts of polyacrylamide, 8-15 parts of graphene, 28-50 parts of ZnO, 45-60 parts of resin and CaCl 2 28-40 parts of MgCl 2 33-55 parts of magnesium ammonium phosphate, 25-37 parts of active alumina, 15-29 parts of micro-nano zero-valent iron and 10-20 parts of micro-nano zero-valent iron.
Compared with the prior art, the invention has the following beneficial effects:
(1) The invention adopts the ultraviolet light +O 3 The advanced treatment discharge pipeline for tail water with combination of oxidation and catalyst adsorption realizes synchronous treatment of nitrogen and phosphorus pollutants, organic matters, residual heavy metals, and the like by deep micro-nano aeration, ultraviolet irradiation and multi-layer adsorption while conveying the tail water on the basis of not increasing tail water discharge structures,The effective depth removing effect of the virus microorganism can be achieved.
(2) The tail end drainage integrated device can overcome the defect that the traditional advanced treatment is easy to block, has good purification treatment effect, can meet the standard discharge requirement of a sewage direct-discharge enterprise, and reduces the pollution of direct-discharge sewage discharge to surface water around a factory. In addition, the tail water emission of the nano-tube enterprises can reach the standard, and the sewage treatment cost of the enterprises is reduced.
(3) The terminal drainage integrated device is flexible in arrangement, convenient to install and maintain, low in cost, space-saving and particularly suitable for factories with shortage of land resources.
The conception, specific structure, and technical effects of the present invention will be further described with reference to the accompanying drawings to fully understand the objects, features, and effects of the present invention.
Drawings
FIG. 1 is a top view of an integrated end drain apparatus according to a preferred embodiment of the present invention.
Fig. 2 is a front view of a tail water adjusting tank in a preferred embodiment of the present invention.
Fig. 3 is an axial cut-away view of an integrated telescopic drain pipe in accordance with a preferred embodiment of the present invention.
Fig. 4 is a radial cross-sectional view of an integrated telescopic drain in accordance with a preferred embodiment of the present invention.
Fig. 5 is a partial view of an integrated telescopic drain pipe in a preferred embodiment of the present invention.
The reference numerals are as follows:
1-tail water inlet pipe, 2-flowmeter, 3-flow regulating valve, 4-acid and alkali automatic adding device, 5-acid and alkali adding pipe, 6-electric stirrer, 7-regulating tank water outlet pipe, 8-circular wire slot, 9-ultraviolet lamp belt and 10-micro-nano O 3 Generator, 11-micro-nano O 3 Ventilation tubule, 12-porous slot, 13-catalytic adsorption material bag, 14-micro-nano O 3 The air vent, a 15-drain pipe water outlet, a 16-tail water regulating tank, a 17-integrated sleeve-type drain pipe, an 18-pore and a 19-e-PTFE acid and alkali resistant patch type breathable waterproof membrane.
Detailed Description
The following description of the preferred embodiments of the present invention refers to the accompanying drawings, which make the technical contents thereof more clear and easy to understand. The present invention may be embodied in many different forms of embodiments and the scope of the present invention is not limited to only the embodiments described herein.
As shown in fig. 1 to 4, a tail end drainage integrated device for advanced treatment of tail water comprises a tail water regulating tank 16 and an integrated sleeve type drainage pipe 17 which are fixedly connected in a sealing manner; the tail water regulating tank 16 is connected with the automatic acid-base adding device 4, the side wall of the tank body is provided with a tail water inlet pipe 1 and a regulating tank water outlet pipe 7, and an electric stirrer 6 is arranged in the tank; the integrated sleeve type drain pipe 17 is a transparent circular sleeve with a radial section of 3/4 sector and an upward opening direction, and the wall of the sleeve type drain pipe is axially provided with a plurality of circular wire grooves 8 and micro-nano O which are distributed at intervals 3 A plurality of uniformly distributed porous slots 12 are arranged in the breather pipe 11 along the radial direction; an ultraviolet lamp strip 9 and micro-nano O are arranged in the circular wire groove 8 3 A plurality of micro-nano O which are uniformly distributed are arranged on the pipe wall of the vent pipe 11 3 The cross section of the vent hole 14 and the porous slot 12 is in a round flask shape, the diameter of the round part is the same as the diameter of the inner wall of the integrated sleeve-type drain pipe 17, the width of the cross section of the bottleneck part is the same as the width of the opening of the integrated sleeve-type drain pipe 17, and the catalytic adsorption material bag 13 is placed in the bottleneck part; the outside of the integrated sleeve type drain pipe 17 is also provided with micro-nano O 3 Micro-nano O communicated with breather pipe 11 3 A generator 10.
The tail water inlet pipe 1 is made of PVC, concrete or glass fiber reinforced plastic, is 10cm to 15cm away from the bottom of the tail water regulating tank 16, and is connected with a flowmeter 2 and a flow regulating valve 3. When the tail water is discharged into the tail water regulating tank 16, the water outlet flow rate can be regulated to be 0.02-0.05m 3 And/s, when the water level depth is higher than 0.8 times of the pool body depth, closing the valve of the flow regulating valve 3 to reduce the flow velocity to 0.01m 3 Below/s or closing the valve.
The automatic acid and alkali adding device 4 is communicated with the tail water regulating tank 16 through an acid and alkali adding pipe 5, the acid and alkali adding pipe 5 is led into one side of the tail water regulating tank 16, which is close to the tail water inlet pipe 1, the acid and alkali adding pipe 5 can be made of polyethylene, and the capacity of the automatic acid and alkali adding device 4 is not less than 40L. Wherein, the automatic acid-base adding device adjusts the pH value of sewage in the tail water adjusting tank 16 to be 6-9, when the pH value is lower than 6, the metering pump is automatically opened to add alkali, when the pH value reaches 7.5, the metering pump is closed, when the pH value is higher than 9, the metering pump is automatically opened to add acid, when the pH value reaches 7.5, the metering pump is closed, and one end of the acid-base adding pipe 5, which is led into the tank body, needs to be immersed below the normal water level.
As shown in fig. 5, the material of the integrated sleeve-type drain pipe 17 can be transparent PMMA or PVC, and the wall of the drain pipe is provided with a plurality of micro-nano O's along the radial direction 3 The vent hole 14 is communicated with the fine hole 18, and an e-PTFE acid and alkali resistant patch type breathable waterproof membrane 19 is fixed on one side of the inner wall of the fine hole 18. In a preferred embodiment, micro-nano O 3 The number of the ventilation pipes 11 is 4-6, and the number of the ventilation pipes is micro-nano O 3 The spacing between the ventilation holes 14 is 6-10cm. Wherein, the e-PTFE acid and alkali resistant patch type breathable waterproof membrane 19 can be used for preparing micro-nano O 3 O in the vent pipe 11 3 The gas diffuses into the integrated sleeve-type drain pipe 17 to oxidize organic matters discharged by tail water, and meanwhile, the waterproof performance of the membrane can also prevent sewage in the integrated sleeve-type drain pipe 17 from entering micro-nano O 3 In the vent pipe 11. Micro-nano O 3 Generator 10 regulates O per hour 3 The production amount is 10-30g, ozone concentration is 0.5-6mg/L, and the tail water is discharged until O is submerged 3 The fine hole tube is opened.
In one embodiment, the tail water adjusting tank 16 may be a square concrete casting structure for adjusting the water inflow and quality of the secondary treatment tail water, and satisfying the physical and chemical conditions for further removal of pollutants before the tail water enters the integrated sleeve type drain pipe 17; in order to reduce the energy consumption of drainage and form drop drainage, the height is set to be more than 1 meter, the inner wall of the tank body is carved with a height scale for regulating and controlling the inflow velocity and the sewage depth in the tank, and the size of the tank body is 1-10m according to the velocity of tail water 3 Designing the daily average discharge amount; the water outlet pipe 7 of the regulating tank is of an integral pouring structure with the tail water regulating tank 16, and is fixedly connected with the water inlet pipe orifice of the integral sleeve type water outlet pipe 17 in a sealing way through a stainless steel outer sleeve.
In one embodiment, the material of the outlet pipe 7 of the adjusting tank can be selected from PVC, concrete or glass fiber reinforced plastic, and is not lower than 2/3 of the total height of the tank body of the tail water adjusting tank 16 from the bottom of the tail water adjusting tank 16, so as to receive the secondary treated water, thereby being beneficial to fully stirring and uniformly mixing the tail water in the adjusting tank and simultaneously meeting the sewage diversion function.
In one embodiment, the diameter of the circular wire grooves 8 is 10-15mm, the number of the circular wire grooves is 6-8, the ultraviolet lamp strips 9 are formed by connecting ultraviolet LED lamp beads with the diameter of 8-12mm, the wavelength of 395nm and the power of 3W in series, and ultraviolet sterilization and disinfection are carried out when tail water flows through.
In one embodiment, the porous insert 12 may be made of ultra-fine polyethylene fibers uniformly distributed along the axial direction of the integrated sleeve drain pipe 17 at intervals of 10-15 cm. Wherein the porous slot 12 can ensure that the shape is still stable under the impact of pipeline water flow, when in use, the side surface of the catalytic adsorption material bag 13 is inserted into the porous slot 12 from the opening above the pipeline, the porous slot 12 is twisted until the porous slot 12 is clamped along the radial direction of the pipeline, and the slot material bag is replaced by reverse operation, and in addition, care needs to be taken to avoid shielding micro-nano O 3 A vent 14.
In one embodiment, the catalytic adsorption material bag 13 is filled with a catalytic adsorption material packaged and shaped by water-permeable anti-corrosion geotextile, and comprises the following components in parts by weight: 22-35 parts of polyacrylamide, 8-15 parts of graphene, 28-50 parts of ZnO, 45-60 parts of resin and CaCl 2 28-40 parts of MgCl 2 33-55 parts of magnesium ammonium phosphate, 25-37 parts of active alumina, 15-29 parts of micro-nano zero-valent iron and 10-20 parts of micro-nano zero-valent iron. The maximum packing size of the catalytic adsorbing material bags 13 cannot exceed the internal size of the porous slots 12, the catalytic adsorbing material is replaced every 3-6 months, and the catalytic adsorbing material bags 13 can be replaced together when worn and cannot be used continuously, and the catalytic adsorbing material bags are taken out from the slot openings.
The terminal drainage integrated device is subjected to field pilot-plant test operation, and the terminal drainage integrated device is concretely as follows: for a design scale of 2 ten thousand m respectively 3 /d and 5 km 3 Sewage treatment plant/d, secondary effluent CODcr30-80mg/L, SS-30 mg/L, NH 3 0.5-7.8mg/L, TP 0.9.9-2.5 mg/L of N, adding NaOH to adjust pH to 7.5-8.0, draining into an integrated sleeve type drain pipe 17 with diameter of 0.8m and length of 5m, and uniformly distributing10 slots of superfine polyethylene fiber containing catalytic adsorption material bag 13 are arranged, and the ultraviolet irradiation dose is 20-30mJ/cm 2 The ozone concentration is regulated to 2mg/L, and the components of the catalytic adsorption material are regulated within the following range (25-30 parts by weight of polyacrylamide, 8-10 parts by weight of graphene, 30-40 parts by weight of ZnO, 45-50 parts by weight of resin and CaCl) 2 30-35 parts by weight of MgCl 2 40-45 parts by weight of magnesium ammonium phosphate 25-30 parts by weight of active alumina 20-25 parts by weight of micro-nano zero-valent iron 10-15 parts by weight). In the ultraviolet irradiation, O 3 Under the combined action of oxidation and catalytic adsorption filtration, the secondary tail water is subjected to advanced treatment, the combined pollution load in the tail water of a sewage plant is greatly reduced, and the removal rates of nitrogen and phosphorus, heavy metals, resistance factors and escherichia coli respectively reach 78% -96.3%, 86.7% -98.8%, 65.2% -79.8% and 88.9% -97.7%. The device is easy to install and operate, is convenient for later maintenance, and the catalytic adsorption material bag after use can be recovered, so that the tail water treatment cost of enterprises is greatly reduced, and meanwhile, the tail end drainage water quality is remarkably improved.
The foregoing describes in detail preferred embodiments of the present invention. It should be understood that numerous modifications and variations can be made in accordance with the concepts of the invention without requiring creative effort by one of ordinary skill in the art. Therefore, all technical solutions which can be obtained by logic analysis, reasoning or limited experiments based on the prior art by the person skilled in the art according to the inventive concept shall be within the scope of protection defined by the claims.
Claims (8)
1. Tail end drainage integrated device of tail water advanced treatment, characterized by, include:
a tail water adjusting tank and an integrated sleeve type drain pipe which are fixedly connected in a sealing way;
the tail water adjusting tank is connected with an automatic acid-base adding device, a tail water inlet pipe and an adjusting tank water outlet pipe are arranged on the side wall of the tank body, and an electric stirrer is arranged in the tank;
the integrated sleeve type drain pipe is a transparent circular sleeve pipe with a radial section of 3/4 sector and an upward opening direction, and a plurality of alternately distributed pipe walls are axially arranged on the pipe wallsCircular wire groove and micro-nano O 3 A plurality of uniformly distributed porous slots are arranged in the breather pipe along the radial direction; wherein:
an ultraviolet lamp band is arranged in the circular wire slot, and the micro-nano O is arranged in the circular wire slot 3 A plurality of micro-nano O which are uniformly distributed are arranged on the pipe wall of the vent pipe 3 The cross section of the porous slot is in a round flask shape, the diameter of the round part of the porous slot is the same as the diameter of the inner wall of the integrated sleeve-type drain pipe, the width of the cross section of the bottleneck part is the same as the width of the opening of the integrated sleeve-type drain pipe, and a catalytic adsorption material bag is arranged in the porous slot;
the outside of the integrated sleeve-type drain pipe is provided with the micro-nano O 3 Micro-nano O communicated with ventilation pipe 3 A generator;
the tail water regulating tank is of a square concrete pouring structure, the height of the tank body is greater than 1 meter, a height scale is carved on the inner wall of the tank body, and the size of the tank body is 1-10m according to the flow velocity of tail water 3 Designing the daily average discharge amount;
the water outlet pipe of the regulating tank is of an integral pouring structure with the tail water regulating tank, and is fixedly connected with the water inlet pipe orifice of the integral sleeve type water outlet pipe in a sealing way through a stainless steel outer sleeve;
the catalytic adsorption material bag is internally provided with a catalytic adsorption material packaged and shaped by water-permeable anti-corrosion geotextile, and the catalytic adsorption material comprises the following components in parts by weight: 22-35 parts of polyacrylamide, 8-15 parts of graphene, 28-50 parts of ZnO, 45-60 parts of resin and CaCl 2 28-40 parts of MgCl 2 33-55 parts of magnesium ammonium phosphate, 25-37 parts of active alumina, 15-29 parts of micro-nano zero-valent iron and 10-20 parts of micro-nano zero-valent iron.
2. The integrated terminal drainage device according to claim 1, wherein the tail water inlet pipe is made of PVC, concrete or glass fiber reinforced plastic, and is 10-15cm away from the bottom of the tail water adjusting tank, and is connected with a flow meter and a flow adjusting valve.
3. The integrated terminal drainage device according to claim 1, wherein the material of the outlet pipe of the regulating tank is selected from PVC, concrete or glass fiber reinforced plastic, and the distance from the bottom of the tail water regulating tank is not less than 2/3 of the total height of the tank body.
4. The terminal drainage integrated device according to claim 1, wherein the acid-base automatic adding device is communicated with the tail water adjusting tank through an acid-base adding pipe, the acid-base adding pipe is led into one side, close to the tail water inlet pipe, of the tail water adjusting tank, the acid-base adding pipe is made of polyethylene, and the capacity of the acid-base automatic adding device is not less than 40L.
5. The integrated terminal drainage device according to claim 1, wherein the integrated sleeve-type drain pipe is made of transparent PMMA or PVC, and the wall of the integrated sleeve-type drain pipe is provided with a plurality of micro-nano O's along the radial direction 3 And the fine holes are communicated with the vent holes, and an e-PTFE acid and alkali resistant patch type breathable waterproof film is fixed on one side of the inner wall of the fine holes.
6. The integrated terminal drainage device according to claim 1, wherein the diameter of the circular wire grooves is 10-15mm, the number of the circular wire grooves is 6-8, and the ultraviolet lamp bands are formed by connecting ultraviolet LED lamp beads with the diameter of 8-12mm, the wavelength of 395nm and the power of 3W in series.
7. The terminal drainage integrated device of claim 1, wherein the micro-nano O 3 The number of the ventilation pipes is 4-6, and the micro-nano O 3 The interval between the vent holes is 6-10cm.
8. The integrated terminal drainage device according to claim 1, wherein the porous insert grooves are made of ultra-fine polyethylene fibers and are uniformly distributed along the axial direction of the integrated sleeve type drain pipe at intervals of 10-15 cm.
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| CN202011358471.1A CN112645515B (en) | 2020-11-27 | 2020-11-27 | Tail end drainage integrated device for advanced treatment of tail water |
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| US7335246B2 (en) * | 1998-05-14 | 2008-02-26 | United States Of America Enviromental Protection Agency | Contaminant adsorption and oxidation via the fenton reaction |
| WO2011105205A1 (en) * | 2010-02-24 | 2011-09-01 | 宇部興産株式会社 | Ultraviolet oxidation device, ultrapure water production device using same, ultraviolet oxidation method, and ultrapure water production method |
| CN205024045U (en) * | 2015-09-14 | 2016-02-10 | 王凯军 | Biological method processing apparatus of O3UV - of advanced wastewater treatment |
| CN105692861B (en) * | 2016-03-21 | 2018-07-27 | 南京大学 | The advanced oxidization method of artificial sweetener in a kind of removal sewage |
| CN106673278B (en) * | 2016-05-25 | 2019-07-19 | 中国科学院城市环境研究所 | A kind of petrochemical industry advance for the treatment of process of cyanide-bearing effluent and device |
| CN110013883B (en) * | 2019-05-27 | 2020-06-09 | 四川大学 | Composite material for treating heavy metal-organic matter pollution, preparation method and application thereof |
| CN210710853U (en) * | 2019-10-21 | 2020-06-09 | 南方科技大学 | Advanced treatment device for tail water of sewage treatment plant |
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