CN112619566A - Multistage jet loop reactor for preparing ethylene by oxidative coupling of methane - Google Patents

Multistage jet loop reactor for preparing ethylene by oxidative coupling of methane Download PDF

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CN112619566A
CN112619566A CN202110068239.2A CN202110068239A CN112619566A CN 112619566 A CN112619566 A CN 112619566A CN 202110068239 A CN202110068239 A CN 202110068239A CN 112619566 A CN112619566 A CN 112619566A
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shell
multistage
methane
gas distributor
guide cylinder
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CN112619566B (en
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李德宝
高用祥
刘俊义
林明桂
马军祥
张力
贾丽涛
崔艳斌
余海兵
夏铭
牛鹏宇
荆明杰
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Shanxi Lu'an Chemical Co ltd
Shanxi Institute of Coal Chemistry of CAS
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Shanxi Institute of Coal Chemistry of CAS
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B01J8/224Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
    • B01J8/226Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement internally, i.e. the particles rotate within the vessel
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C07C2/82Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling
    • C07C2/84Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling catalytic
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

The invention relates to the technical field of methane conversion, in particular to a multistage jet circulation reactor for preparing ethylene by oxidative coupling of methane, which comprises a nozzle, a conical bottom, multistage guide cylinders, a gas distributor, a shell, a cyclone separator, a heat exchanger and a material returning device, wherein the nozzle is positioned at the bottom of the conical bottom, the conical bottom is positioned at the bottom end of the shell, the multistage guide cylinders are positioned at the middle lower part of the shell, the multistage guide cylinders are cylinders which are vertically arranged in equal diameter and have the quantity of more than or equal to 2, and the gas distributor is positioned at the middle lower part of the shell and has the quantity of 1 or more. The invention utilizes the nozzle, the conical bottom, the multi-stage guide cylinders and the gas distributor to form the forced internal circulation of materials, can promote the regular movement of the materials, reduce back mixing, strengthen mass transfer and heat transfer, is beneficial to the uniform distribution of the temperature in the reactor, and improves the utilization rate of the catalyst and the yield of the product.

Description

Multistage jet loop reactor for preparing ethylene by oxidative coupling of methane
Technical Field
The invention relates to the technical field of methane conversion, in particular to a multistage jet loop reactor for preparing ethylene by oxidative coupling of methane.
Background
Ethylene is an important basic organic chemical product and raw material, and the production level is an important index for measuring the national chemical strength. At present, naphtha cracking is mainly used for ethylene production, and the problems of high cost and energy consumption, greenhouse gas emission and the like exist. With the development of international economy, ethylene production raw materials tend to be light and diversified. The technology for directly preparing ethylene by the one-step method of Oxidative Coupling of Methane (OCM) has the advantages of simple route, good economy and the like, is an ethylene production technology with wide development prospect, and has great significance for the optimization of energy structure in China.
The OCM reaction is a strong exothermic reaction at high temperature (750-950 ℃), and the ethylene yield has high sensitivity to temperature. How to remove the severe exotherm during the reaction is the key to engineering the technology. At present, OCM reactors mainly comprise fixed beds, fluidized beds, membrane reactors and the like.
The traditional fixed bed reactor has mature technology, measures such as multi-section cold shock, raw material quantity control and dilution gas addition are often used as an auxiliary measure in the implementation process to control the bed temperature, but the problem of difficult temperature control still exists in the actual production process aiming at the reaction characteristic of rapid strong heat release of OCM. Publication No. CN 106732201B discloses an OCM thin-layer fixed bed reactor, which comprises at least two sections of reaction section beds, wherein each section bed is composed of 1-2 layers of catalyst, the height is 20-40 mm, and each section of reaction section is connected through a quenching heat exchanger. Although the reactor overcomes the problem of axial temperature gradient, the radial direction still has the problems of uneven temperature distribution and the like, the temperature control among beds is more complicated, and the equipment and the operation cost are higher.
The fluidized bed can effectively strengthen the mass transfer and heat transfer process by utilizing the violent movement between gas and solid, and eliminate hot spots in the reactor. Publication No. CN 108530248A discloses an OCM fluidized bed device, which comprises a fluidizing zone and a settling zone, wherein the fluidizing zone comprises a heat exchanger and a gas distributor, and a plurality of cyclone separators are arranged in the settling zone. Although the reactor can effectively eliminate hot spots, gas in the reactor is seriously mixed back, which aggravates the secondary reaction process and influences the selectivity of ethylene.
Jaso (2011, 2011.03.23) proposed an auxiliary fluidized bed membrane reactor with oxygen feed rate controlled by the membrane to control reactor temperature and reaction degree. Although the membrane reactor can realize uniform distribution of temperature and high ethylene yield, the problems of membrane regeneration and pollution in industrialization are inevitable.
Disclosure of Invention
In order to overcome the defects of the prior art, the invention provides a multistage jet loop reactor for preparing ethylene by oxidative coupling of methane, which aims to solve the problems of nonuniform temperature distribution, serious back mixing and low ethylene yield in the reactor.
The technical scheme adopted by the invention is as follows: a multi-stage jet circulation reactor for preparing ethylene by methane oxidative coupling comprises a nozzle (1), a conical bottom (2), a multi-stage guide cylinder, a gas distributor (5), a shell (3), a cyclone separator (9), a heat exchanger (11) and a material returning device, wherein the nozzle (1) is positioned at the bottom of the conical bottom (2), the conical bottom (2) is positioned at the bottom end of the shell (3), the multi-stage guide cylinder is positioned at the middle lower part of the shell (3) in number, the multi-stage guide cylinder is a cylinder which is vertically arranged in equal diameter and has the quantity more than or equal to 2, the gas distributor (5) is positioned at the middle lower part of the shell (3) and has the quantity of 1 or more, a gas outlet (7) at the top end of the shell (3) is connected with the upper part of the cyclone separator (9), a product gas outlet (8) is arranged at the top end of the cyclone separator (9), and the bottom of the, the middle of the dipleg (10) is provided with a heat exchanger (11), the dipleg (10) is communicated with a material returning device, and the material returning device comprises a material returning valve (12), a secondary air inlet (13), a discharge valve (14) and a material returning pipe (15).
One or more nozzles (1) are arranged, the jet air speed is 10-80 m/s, when one nozzle (1) is arranged, the nozzle (1) and the shell (3) are coaxial, when a plurality of nozzles (1) are arranged, the nozzles (1) are positioned on a circle on the axis of the central shell (3), and the maximum diameter of a circumscribed circle formed by each nozzle (1) is smaller than the diameter of the multistage guide cylinder.
The center lines of a plurality of cylinders contained in the multistage draft tube are overlapped, and the height of the cylinder positioned below is larger than or equal to that of the cylinder positioned above.
The ratio of the diameter of the multistage guide cylinder to the diameter of the shell (3) is 0.5-0.8; the ratio of the total height of the multi-stage guide cylinder to the height of the shell (3) is 0.4-0.7; the ratio of the distance from the bottom of the multistage draft tube to the bottom of the shell (3) to the diameter of the shell (3) is-0.3, and a negative value represents that the bottom of the lowest cylinder of the multistage draft tube is below the bottom of the shell (3).
The gas distributor is an annular gas distributor, and is one of a double annular gas distributor and a single annular gas distributor or a mixed combination of the double annular gas distributor and the single annular gas distributor.
The double-ring-shaped gas distributor is positioned at the interstage center of the multistage guide cylinder or the middle height of each cylinder of the multistage guide cylinder, the double-ring-shaped gas distributor consists of an inner ring-shaped distributor (17) and an outer ring-shaped distributor (20), the inner ring-shaped distributor (17) and the outer ring-shaped distributor (20) are connected through 4 guide pipes (19) which sequentially form 90 degrees, the inner ring-shaped distributor (17) is positioned in the multistage guide cylinder and vertically and upwardly uniformly distributed with upward spray holes (16), the outer ring-shaped distributor (20) is positioned between the multistage guide cylinder and the shell (3) and vertically and downwardly uniformly distributed with downward spray holes (21), the number of the upward spray holes (16) is more than or equal to 4 and less than or equal to that of the downward spray holes (21), and the number of the downward spray holes (21) is less than.
The single-ring-shaped gas distributor is positioned at the interstage center of the multi-stage guide cylinder and the middle height of each cylinder of the multi-stage guide cylinder, the diameter of the single-ring-shaped gas distributor positioned at the interstage center is smaller than that of the multi-stage guide cylinder, upward spray holes (16) are vertically and upwardly and uniformly distributed, the diameter of the single-ring-shaped gas distributor positioned at the middle height of each cylinder is between the diameters of the multi-stage guide cylinder and the shell (3), the downward spray holes (21) are vertically and downwardly and uniformly distributed, the number of the upward spray holes (16) is more than or equal to 4 and less than or equal to that of the downward spray holes (21), and the number of.
The secondary air inlet has two functional modes, namely an air inlet mode and a catalyst inlet mode.
The gas composition of the nozzle (1), the gas distributor (5) and the secondary air inlet (13) is a mixture of methane, oxygen and nitrogen.
The gas composition of the nozzle (1) is that the methane content is more than 90%, and the gas composition of the gas distributor and the secondary air inlet is that the oxygen content and the nitrogen content are more than 90%.
The cooling medium of the heat exchanger is saturated water or a mixture of water and steam, and high-quality steam can be produced as a byproduct.
The working principle of the multistage jet circulation reactor for preparing ethylene by oxidative coupling of methane comprises the following steps: according to the structure of the reactor, the reactor is divided into a conical bottom area, a circulating flow area, a gas-solid separation area, a cyclone separation area and a material returning area. The reaction raw material gas is sprayed into the conical bottom through the nozzle, the kinetic energy generated by the nozzle pushes catalyst particles to move upwards to enter the first-stage guide cylinder of the circulation zone, after the material leaves the first-stage guide cylinder, a part of the material continues to move upwards to enter the second-stage guide cylinder, a part of the material enters the first-stage guide cylinder and the shell annular space and moves downwards, a part of the material leaving the second-stage guide cylinder enters the gas-solid separation zone, and a part of the material returns to the second-stage guide cylinder and the shell annular space to participate in circulation. The concentration difference between the guide cylinder and the mixture of gas and particles in the annular space forms a circulating driving force, in addition, the circulation is strengthened by utilizing the different gas inlet directions of the inner ring and the outer ring of the gas distributor, and the oxygen concentration in the reactor is adjusted by adjusting the composition of the gas fed into the gas distributor. The orderly internal circulation of gas and solid can be forced through the action of injection and internal circulation flow, and the back mixing is reduced. The material entering the gas-solid separation zone is reduced in speed due to the widening of the flow channel, so that gas and solid catalyst are separated, the large-particle-size solid returns to the circulation zone, and the gas and the small-particle-size solid which is difficult to separate enter the cyclone separation zone for further separation. The product gas is discharged from the top of the cyclone separator, and the small-particle-size solid catalyst discharged from the bottom of the cyclone separator is cooled by a heat exchanger and then returns to the bottom of the reactor through a material returning area. The material returning area is provided with a secondary air inlet, and the product yield is assisted to be regulated and controlled by controlling the air inflow of the secondary air.
Compared with the prior art, the invention has the beneficial effects that:
1. the forced internal circulation of the materials is formed by the nozzle, the conical bottom, the multi-stage guide cylinders and the gas distributor, so that the regular movement of the materials can be promoted, the back mixing is reduced, the mass transfer and the heat transfer are enhanced, the uniform distribution of the temperature in the reactor is facilitated, and the utilization rate of the catalyst and the yield of the product are improved;
2. a three-stage gas regulation mechanism is formed by the nozzle, the gas distributor and the secondary air inlet, so that the oxygen concentration in the reactor is controlled, the deep reaction is effectively reduced, and the ethylene yield is improved;
3. the jet circulation reactor for preparing ethylene by oxidative coupling of methane has the advantages of simple structure, high operation flexibility and easy engineering amplification.
Drawings
FIG. 1 is a schematic diagram of the structure of an OCM multi-stage jet loop reactor;
FIG. 2 is a top view of a dual annular gas distributor;
FIG. 3 illustrates three possible annular gas distributor placements;
FIG. 4 is a top view of a single ring gas distributor (FIG. 3 (b));
wherein: 1-nozzle, 2-conical bottom, 3-shell, 4-first stage draft tube, 5-gas distributor, 6-second stage draft tube, 7-shell top gas outlet, 8-product gas outlet, 9-cyclone separator, 10-dipleg, 11-heat exchanger, 12-return valve, 13-secondary air inlet, 14-discharge valve, 15-return pipe, 16-upward spray hole, 17-inner ring distributor, 18-air inlet, 19-conduit, 20-outer ring distributor, and 21-downward spray hole.
Detailed Description
The invention is further described below with reference to the accompanying drawings.
Example 1
A multi-stage jet circulation reactor for preparing ethylene by oxidative coupling of methane is composed of conic bottom region, circulation region, gas-solid separation region, cyclone separation region and material returning region. The conical bottom zone comprises a nozzle 1 and a conical bottom 2; the circulation zone comprises a space at the middle lower part of the shell 3, a gas distributor 5, a first-stage guide cylinder 4 and a second-stage guide cylinder 6; the gas-solid separation zone comprises the upper space of the shell 3; the cyclonic separation zone comprises a cyclone 9; the material returning area comprises a dipleg 10, a heat exchanger 11, a material returning valve 12, a secondary air inlet 13, a discharge valve 14 and a material returning pipe 15.
As shown in fig. 1, the nozzle 1 is located at the bottom of the conical bottom 2, the conical bottom 2 is connected with the bottom of the shell 3, the first-stage guide cylinder 4 and the second-stage guide cylinder 6 are located at the middle lower part of the shell 3 and are vertically placed in sequence, the lower part of the shell 3 is provided with 1 or more gas distributors 5, the top of the shell 3 is provided with a gas outlet 7 and is connected with an inlet of a cyclone separator 9, the top of the cyclone separator 9 is provided with a product gas outlet 8, the bottom of the cyclone separator 9 is connected with a dipleg 10, the middle part of the dipleg 10 is provided with a heat exchanger 11 and is connected with a material returning valve 12 of a material returning device, the bottom of the dipleg 10 is provided with a discharge valve 14, a secondary air inlet 13 and a material returning pipe.
By adopting the placement of the annular gas distributor as shown in fig. 3 (a), in the specific implementation process, the reactor is heated to the reaction temperature before the start-up, the reaction raw material gas is sprayed into the conical bottom 2 through the nozzle 1, the catalyst is added to the target value through the secondary air inlet 13, and then the secondary air inlet 13 is switched to the air inlet mode. The kinetic energy generated by the nozzle 1 pushes catalyst particles to move upwards to enter the first-stage guide cylinder 4 of the circulation zone, after the materials leave the first-stage guide cylinder 4, a part of the materials continue to move upwards to enter the second-stage guide cylinder 6, a part of the materials enter annular gaps of the first-stage guide cylinder 4 and the shell 3 and move downwards, a part of the materials leaving the second-stage guide cylinder 6 enter a gas-solid separation zone, and a part of the materials return to the annular gaps of the second-stage guide cylinder 6 and the shell 3 to participate in circulation. The secondary raw material gas enters the double-ring-shaped gas distributor 5 through the gas inlet 18 and is redistributed through the inner ring-shaped distributor 17, the outer ring-shaped distributor 20 and the guide pipe 19 between the inner ring-shaped distributor and the outer ring-shaped distributor, one part of the redistributed secondary raw material gas is sprayed upwards from the upward spray holes 16 of the inner ring-shaped distributor 17 to enter the guide cylinder area, and the other part of the redistributed secondary raw material gas is sprayed downwards from the downward spray holes 21 of the outer ring-shaped distributor 20 to enter the annular space area. The concentration difference between the inside of the multistage draft tube and the mixture of gas and particles in the annular space forms a circulating driving force to promote the ordered internal circulation of the gas and the solids and reduce back mixing. The material entering the gas-solid separation zone is widened due to the flow channel and reduced in speed, so that gas and solid catalyst are separated, the large-particle-size solid returns to the circulation zone, the gas and the small-particle-size solid which is difficult to separate enter the cyclone separator 9 through the gas outlet 7 at the top end of the shell for further separation, the product gas is discharged from the product gas outlet 8 at the top end of the cyclone separator 9, and the small-particle-size solid catalyst is settled from the bottom of the cyclone separator 9, enters the dipleg 10, is cooled by the heat exchanger 11 and returns to the conical bottom 2 through the return pipe 15. The cooling medium in the heat exchanger 11 is saturated water or a mixture of water and steam to produce high-quality steam as a byproduct. In the operation process, the gas content of the nozzle 1, the gas distributor 5 and the secondary air inlet 13 is adjusted to regulate the product yield. When the catalyst needs to be replaced or supplemented, the secondary air inlet 13 can be switched into a catalyst inlet mode so as to realize the online non-stop operation.
The OCM jet loop reactor shown in figure 1 and figure 3 (a) is adopted, the average particle size of the catalyst is 100 μm, the reaction temperature is 800 ℃, the operation is carried out under normal pressure, the gas component passing through the nozzle is methane, the gas component passing through the gas distributor and the secondary air inlet is oxygen and nitrogen, the volume space velocity is 6000 h-1Methane: oxygen: nitrogen is present inThe methane conversion was 45% and the ethylene yield was 29% at a gas molar ratio of 3:1: 1.
Example 2
The same reactor configuration as in example 1 was used, except that: the annular gas distributor placement shown in fig. 3 (B) is adopted, and is particularly characterized in that the adopted annular gas distributor is a single annular gas distributor, wherein a single annular gas distributor with an upward opening (shown in fig. 4 (B-B)) is placed between stages of guide cylinders, and a single annular gas distributor with a downward opening (shown in fig. 4 (A-A)) is placed at the middle height of each guide cylinder. The average particle diameter of the catalyst is 100 μm, the reaction temperature is 800 ℃, the operation is carried out under normal pressure, the gas component passing through the nozzle is methane, the gas component passing through the gas distributor and the secondary air inlet is oxygen and nitrogen, and the volume space velocity is 6000 h-1Methane: oxygen: the methane conversion was 46% and the ethylene yield was 30% at a nitrogen molar ratio of 3:1: 1.
Example 3
The same reactor configuration as in example 1 was used, except that: the annular gas distributor placement mode shown in fig. 3 (c) is adopted, and specifically, the adopted double annular gas distribution mode is placed at the middle height of each guide shell. The average particle diameter of the catalyst is 150 μm, the reaction temperature is 800 ℃, the operation pressure is 5 bar, the gas components passing through the nozzle are methane and oxygen, the gas components passing through the gas distributor and the secondary air inlet are oxygen and nitrogen, and the volume space velocity is 8000 h-1Methane: oxygen: the methane conversion was 47% and the ethylene yield was 28% at a nitrogen molar ratio of 3:1: 1.

Claims (10)

1. A multi-stage jet circulation reactor for preparing ethylene by methane oxidative coupling is characterized in that: comprises a nozzle (1), a conical bottom (2), a multi-stage guide cylinder, a gas distributor (5), a shell (3), a cyclone separator (9), a heat exchanger (11) and a material returning device, wherein the nozzle (1) is positioned at the bottom of the conical bottom (2), the conical bottom (2) is positioned at the bottom of the shell (3), the multi-stage guide cylinder is positioned at the middle lower part of the shell (3) and is a cylinder with the same diameter and more than or equal to 2, the gas distributor (5) is positioned at the middle lower part of the shell (3) and is 1 or more, a shell top gas outlet (7) of the shell (3) is connected with the upper part of the cyclone separator (9), a product gas outlet (8) is arranged at the top of the cyclone separator (9), the bottom of the cyclone separator (9) is communicated with a material leg (10), the heat exchanger (11) is arranged in the middle of the material leg (10), and the material returning device is communicated with the material leg (10), the material returning device comprises a material returning valve (12), a secondary air inlet (13), a discharge valve (14) and a material returning pipe (15).
2. The multistage jet loop reactor for the oxidative coupling of methane to ethylene according to claim 1, wherein: one or more nozzles (1) are arranged, the jet air speed is 10-80 m/s, when one nozzle (1) is arranged, the nozzle (1) and the shell (3) are coaxial, when a plurality of nozzles (1) are arranged, the nozzles (1) are positioned on a circle on the axis of the central shell (3), and the maximum diameter of a circumscribed circle formed by each nozzle (1) is smaller than the diameter of the multistage guide cylinder.
3. The multistage jet loop reactor for the oxidative coupling of methane to ethylene according to claim 1, wherein: the center lines of a plurality of cylinders contained in the multistage draft tube are overlapped, and the height of the cylinder positioned below is larger than or equal to that of the cylinder positioned above.
4. The multistage jet loop reactor for the oxidative coupling of methane to ethylene according to claim 1, wherein: the ratio of the diameter of the multistage guide cylinder to the diameter of the shell (3) is 0.5-0.8; the ratio of the total height of the multi-stage guide cylinder to the height of the shell (3) is 0.4-0.7; the ratio of the distance from the bottom of the multistage draft tube to the bottom of the shell (3) to the diameter of the shell (3) is-0.3, and a negative value represents that the bottom of the lowest cylinder of the multistage draft tube is below the bottom of the shell (3).
5. The multistage jet loop reactor for the oxidative coupling of methane to ethylene according to claim 1, wherein: the gas distributor is an annular gas distributor, and is one of a double annular gas distributor and a single annular gas distributor or a mixed combination of the double annular gas distributor and the single annular gas distributor.
6. The multistage jet loop reactor for the oxidative coupling of methane to ethylene according to claim 5, wherein: the double-ring-shaped gas distributor is positioned at the interstage center of the multistage guide cylinder or the middle height of each cylinder of the multistage guide cylinder, the double-ring-shaped gas distributor consists of an inner ring-shaped distributor (17) and an outer ring-shaped distributor (20), the inner ring-shaped distributor (17) and the outer ring-shaped distributor (20) are connected through 4 guide pipes (19) which sequentially form 90 degrees, the inner ring-shaped distributor (17) is positioned in the multistage guide cylinder and vertically and upwardly uniformly distributed with upward spray holes (16), the outer ring-shaped distributor (20) is positioned between the multistage guide cylinder and the shell (3) and vertically and downwardly uniformly distributed with downward spray holes (21), the number of the upward spray holes (16) is more than or equal to 4 and less than or equal to that of the downward spray holes (21), and the number of the downward spray holes (21) is less than.
7. The multistage jet loop reactor for the oxidative coupling of methane to ethylene according to claim 5, wherein: the single-ring-shaped gas distributor is positioned at the interstage center of the multi-stage guide cylinder and the middle height of each cylinder of the multi-stage guide cylinder, the diameter of the single-ring-shaped gas distributor positioned at the interstage center is smaller than that of the multi-stage guide cylinder, upward spray holes (16) are vertically and upwardly and uniformly distributed, the diameter of the single-ring-shaped gas distributor positioned at the middle height of each cylinder is between the diameters of the multi-stage guide cylinder and the shell (3), the downward spray holes (21) are vertically and downwardly and uniformly distributed, the number of the upward spray holes (16) is more than or equal to 4 and less than or equal to that of the downward spray holes (21), and the number of.
8. The multistage jet loop reactor for the oxidative coupling of methane to ethylene according to claim 1, wherein: the secondary air inlet has two functional modes, namely an air inlet mode and a catalyst inlet mode.
9. The multistage jet loop reactor for the oxidative coupling of methane to ethylene according to claim 1, wherein: the gas composition of the nozzle (1), the gas distributor (5) and the secondary air inlet (13) is a mixture of methane, oxygen and nitrogen.
10. The multistage jet loop reactor for the oxidative coupling of methane to ethylene according to claim 1, wherein: the gas composition of the nozzle (1) is that the methane content is more than 90%, and the gas composition of the gas distributor and the secondary air inlet is that the oxygen content and the nitrogen content are more than 90%.
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