CN112616845A - Pesticide composition containing pyrazole formamide insecticide and application thereof - Google Patents

Pesticide composition containing pyrazole formamide insecticide and application thereof Download PDF

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Publication number
CN112616845A
CN112616845A CN202011515865.3A CN202011515865A CN112616845A CN 112616845 A CN112616845 A CN 112616845A CN 202011515865 A CN202011515865 A CN 202011515865A CN 112616845 A CN112616845 A CN 112616845A
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mass ratio
active component
component
cyhalothrin
pesticide
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Inventor
葛家成
张永芳
巨翠红
张凯莉
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Qingdao Tengrunxiang Testing And Evaluation Co ltd
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Qingdao Tengrunxiang Testing And Evaluation Co ltd
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Publication of CN112616845A publication Critical patent/CN112616845A/en
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/58—1,2-Diazines; Hydrogenated 1,2-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/28—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
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    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • A01N37/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
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    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing within the same carbon skeleton a carboxylic group or a thio analogue, or a derivative thereof, and a carbon atom having only two bonds to hetero atoms with at the most one bond to halogen, e.g. keto-carboxylic acids
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    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
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    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/707—1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
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    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
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    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
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    • A01N47/18—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring
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Abstract

The invention discloses a pesticide composition containing a pyrazole formamide pesticide and application thereof, wherein an active component A is the pyrazole formamide pesticide, and a component B is at least one other pesticide defined in the specification, and particularly relates to the pesticide composition for preventing and treating common lepidoptera, coleoptera, diptera, thysanoptera and homoptera pests of plants.

Description

Pesticide composition containing pyrazole formamide insecticide and application thereof
Technical Field
The present invention relates to pesticidal compositions containing a pyrazole carboxamide insecticide and methods of applying the compositions.
Background
Dimipryridaz is a pyrazole carboxamide insecticide developed by basf under the chemical name: 1- (1,2 dimethylpropyl) -N-ethyl-5-methyl-N-pyridazin-4-yl-pyrazole-4-carboxamide, CAS number 1403615-77-9, structural formula as follows:
Figure BDA0002847393590000011
the Dimppyridaz is a medicament which has better control effect on aphids of homoptera, coleoptera, diptera, thysanoptera and lepidoptera, whitefly, thrips, leafhopper and diamond back moth.
International patent application WO2012143317 discloses pyrazole carboxamide derivatives and their use as pesticides, and there is no specific mention in this document of possible pesticidal compositions, nor of the weight ratio of pyrazole carboxamide insecticides to other pesticide components present in the composition.
International patent application WO2013189801 discloses pyrazole compounds and pesticidal mixtures comprising pyrazole compounds, which simply discloses methods and uses of the pyrazole compounds in admixture with a part of pesticides for controlling invertebrate pests, and does not mention the type of combined action of a specific composition for the control of a certain pest.
In the field of pesticides, novel pesticide compositions with insecticidal synergistic effects are frequently used to delay the drug resistance of pests and simultaneously reduce the influence of pesticides on the environment to the maximum extent.
Disclosure of Invention
The invention provides a pesticide composition containing a pyrazole formamide insecticide, which contains the pyrazole formamide insecticide and another known insecticide. The insecticidal composition can be used for preventing and controlling aphids, whiteflies, leafhoppers, thrips, diamond back moths and the like which are common pests of homoptera, coleoptera, diptera, thysanoptera and lepidoptera, such as fruit trees, vegetables, grain crops, tea leaves and the like.
The invention relates to an insecticidal composition, which comprises an active component A and an active component B.
Further, the active component A is Dimppyridazz, and the active component B is at least one insecticidal compound selected from B1-B17.
B1 carbamates: benfuracarb, propoxur, carbosulfan, benfuracarb, methiocarb, carbaryl, pirimicarb, carbofuran, benfuracarb, bendiocarb, pirimicarb, bendiocarb, methomyl, oxamyl, aldicarb, ethiocarb, isoprocarb, fenobucarb, triazamate, metam, metolcarb, propoxur, monocarb, propoxur;
b2 organophosphates: sulfosulphos, butylphosphate, fenthion, fenamiphos, pyrazofos, prothioconazole, ethoprophos, pyridaphenthion, phenthoate, trichlorfon, dichlorvos, chlorfenphos, chlorpyrifos, parathion, diazinon, naled, famciclovir, methamidophos, phorate, picolinafen, methylcrotophos, methylparathion, methylglutamyl, pirimiphos, demeton-methyl, foscarnet, monocrotophos, quinalphos, dimethoate, cadusafos, chlorothiophos, phosphorus oxychloride, malathion, fenamiphos, triazophos, cyanophos, fenide, fenitrothion, methidathion, phos, isocrotophos, phoxim, phos, omethion, dimethoate, fosetyl, ethoprophos, ethiophos, methamidophos, pyrazofos, triazophos, terbufos, phoxim, dimethos, dimethomophos, ethion, methamidophos, fosinate, pyrazofos, iso, Coumaphos, fenitrothion, baoban, leopard, ethyl bromophos, bromophenyl phosphine, Temiathion, triphosphas, ethoprophos, pyraflufen, iprobenfos and methidathion;
b3 pyrethroids: s-fenvalerate, theta-cypermethrin, beta-cypermethrin, abamectin, cyphenothrin, tefluthrin, DDT, resmethrin, prallethrin, allethrin, pyrethrin, cyfluthrin, fluthrin, silafluofen, penfluthrin, imiprothrin, thianthrin, flumethrin, cyfluthrin, flucythrinate, lambda-cyhalothrin, trifluorethrin, fluvalinate, cyhalothrin, permethrin, phenothrin, metofluthrin, profluthrin, lambda-cyhalothrin, methomethrin, fenpropathrin, permethrin, tefluthrin, fenpropathrin, prallethrin, imiphostin, cyhalothrin, bifenthrin, cyhalothrin, permethrin, cyhalothrin, cy, Bioresmethrin, bioallethrin, beta-cypermethrin, cyclopentene-propathrin, cypermethrin, transfluthrin, tetramethrin, tetrabromthrin, empenthrin, profenothrin, deltamethrin, cycloprothrin, cyhalothrin, profenothrin, resmethrin, deltamethrin, pyrethrin;
b4 neonicotinoids: imidacloprid, acetamiprid, dinotefuran, sulfoxaflor, clothianidin, thiacloprid, thiamethoxam, nitenpyram, nicotine, trifluoro-benzene pyrimidine, nithiazine, imidaclothiz, imidacloprid,
B5 benzoylureas: diflubenzuron, noviflumuron, teflubenzuron, flufenoxuron, chlorfluazuron, hexaflumuron, noviflumuron, triflumuron, lufenuron, difiulururon, chlorfluazuron, fluazuron, chlorfluazuron, florourea;
b6 juvenile hormone mimics including fenoxycarb, pyriproxyfen, methoprene, hydroprene, methoprene, benfenoxaprop, juvenile ether and methoprene;
b7 nereistoxin analogue: thiocyclam, monosulfuron, dimehypo, cartap hydrochloride;
b8 avermectin: abamectin, emamectin benzoate, lepimectin, emamectin benzoate;
b9 biological substances, hormones or pheromones selected from azadirachtin, Bacillus species, Beauveria species, Metarhizium species, Paecilomyces species, Bacillus thuringiensis, Verticillium species;
b10 pyrazoles: buthrozoon, fipronil, ethiprole, acetoprole, ethiprole and fluorine pyrazole insect;
b11 oxadiazines: indoxacarb;
b12 organochlorine compound: lindane, chlordane, endosulfan;
b13 bisamides: flubendiamide, chlorantraniliprole, cyantraniliprole, flubendiamide, chlorofluorobisphenol and fluorochlorfonamide;
b14 bishydrazides: tebufenozide, chromafenozide, methoxyfenozide, chlorfenozide;
b15 other heterocycles: pyridalyl, fluazifop-butyl, pymetrozine, butryprole, pyripyraclostrobin, fipronil, ethiprole, flonicamid, tolfenpyrad, indoxacarb, chlorfenapyr, dicyclanil, pyrimethanil and pyridalyl;
b16 biological insecticide: spinosyns, spinetorams;
b17 acaricide: fenaminoquinone, fenpyroximate, pyridaben, sulfadiazine, bifenazate, milbemectin, propargite, buprofezin, dicofol, tetradifon, fenpyroximate, bromopropylate, fenamiprin, spirotetramat, spiromesifen, spirodiclofen, fenazaquin, pyridaben, tebufenpyrad, flufenzine, pyriminostrobin, hexythiazox, clofentezine, ivermectin, etoxazole, cyflumetofen, cyenopyrafen, fenbutatin oxide, cyhexatin oxide and azocyclotin.
When the active components exist in a specific mass ratio, the synergistic effect is very remarkable, and the mass ratio of the active component A to the active component B is 0.1: 100-100: 0.1, preferably 1: 12-100: 0.1, and more preferably 1: 4-100: 1.
Further, the mass ratio of the active component A to the avermectin is 25: 1-100: 1, the mass ratio of the active component A to the pyriproxyfen is 1: 2-2: 1, the mass ratio of the active component A to the imidacloprid is 2: 5-50: 1, the mass ratio of the active component A to the pymetrozine is 5: 2-10: 1, the mass ratio of the active component A to the profenofos is 1: 1-50: 1, the mass ratio of the active component A to the tebufenozide is 1: 4-1: 1, the mass ratio of the active component A to the diflubenzuron is 1: 8-1: 2, the mass ratio of the active component A to the butirofipronil is 5: 2-10: 1, the mass ratio of the active component A to the tebufenpyrad is 5: 1-20: 1, the mass ratio of the active component A to the acetamiprid is 25: 3-100: 3, the mass ratio of the active component A to the dinotefuran is 1: 5-20: 1, the mass ratio of the active component A to the flufenoxuron is 1: 1-12, the mass ratio of the active component A to the sulfoxaflor is 1: 5-50: 1, the mass ratio of the active component A to the flonicamid is 2: 5-2: 1, the mass ratio of the active component A to the chlorfluazuron is 10: 1-50: 1, the mass ratio of the active component A to the hexaflumuron is 10: 1-40: 1, the mass ratio of the active component A to the flubendiamide is 100: 0.5-100: 0.1, the mass ratio of the active component A to the lambda-cyhalothrin is 25: 4-25: 1, the mass ratio of the active component A to the emamectin benzoate is 50: 1-100: 0.5, the mass ratio of the active component A to the methoxyfenozide is 1: 2-2: 1, the mass ratio of the active component A to the cyenopyrafen is 25: 0.2-50: 0.1, the mass ratio of the active component A to the pirimicarb is 5: 2-10: 1, and the mass ratio of the active component A to the pyroximate is 5: 2: 1-10: 1, the mass ratio of the active component A to the bifenthrin is 2: 1-100: 0.1, the mass ratio of the active component A to the spirotetramat is 25: 2-50: 1, the mass ratio of the active component A to the chlorantraniliprole is 25: 1-100: 1, the mass ratio of the active component A to the propargite is 5: 2-10: 1, the mass ratio of the active component A to the clothianidin is 1: 2-20: 1, the mass ratio of the active component A to the thiamethoxam is 5: 1-20: 1, the mass ratio of the active component A to the trifluorinated pyrimidine is 4: 1-50: 1, the mass ratio of the active component A to the triflumizole ether is 5: 1-20: 1, the mass ratio of the active component A to the triazophos is 1: 1-4: 1, the mass ratio of the active component A to the dimehypothiobac-sodium is 1: 1-4: 1, the mass ratio of the active component A to the triflumilast-rate is 5: 1-20: 1, and the mass ratio of the active component A to the lufenuron is 5: 1-10: 1, the mass ratio of the active component A to the bistrifluron is 1: 4-10: 1, the mass ratio of the active component A to the nitenpyram is 2: 1-20: 1, the mass ratio of the active component A to the ethiprole is 2: 1-10: 1, the mass ratio of the active component A to the spinetoram is 25: 2-50: 1, the mass ratio of the active component A to the etoxazole is 25: 1-100: 1, the mass ratio of the active component A to the isoprocarb is 2: 5-5: 2, the mass ratio of the active component A to the indoxacarb is 5: 2-50: 1, the mass ratio of the active component A to the tolfenpyrad is 1: 2-2: 1, and the mass ratio of the active component A to the fenpyroximate is 25: 1-100: 1;
further, the mass ratio of the active component A to the avermectin is 25: 1-50: 1, the mass ratio of the active component A to the pyriproxyfen is 1: 1-2: 1, the mass ratio of the active component A to the imidacloprid is 10: 1-50: 1, the mass ratio of the active component A to the pymetrozine is 5: 1-10: 1, the mass ratio of the active component A to the profenofos is 4: 1-50: 1, the mass ratio of the active component A to the tebufenozide is 1: 2-1: 1, the mass ratio of the active component A to the diflubenzuron is 1: 8-1: 2, the mass ratio of the active component A to the butafenapyr is 5: 1-10: 1, the mass ratio of the active component A to the cyflumetofen is 10: 1-20: 1, the mass ratio of the active component A to the acetamiprid is 50: 3-100: 3, the mass ratio of the active component A to the dinotefuran is 2: 5-20: 1, and the mass ratio of the active component A to the flufenoxuron is 1: 12: 1, the mass ratio of the active component A to the sulfoxaflor is 1: 5-25: 3, the mass ratio of the active component A to the flonicamid is 2: 5-4: 5, the mass ratio of the active component A to the chlorfluazuron is 20: 1-50: 1, the mass ratio of the active component A to the hexaflumuron is 20: 1-40: 1, the mass ratio of the active component A to the flubendiamide is 100: 0.5-100: 0.1, the mass ratio of the active component A to the lambda-cyhalothrin is 25: 2-25: 1, the mass ratio of the active component A to the emamectin benzoate is 100: 1-100: 0.5, the mass ratio of the active component A to the methoxyfenozide is 1: 1-2: 1, the mass ratio of the active component A to the cyenopyrafen is 50: 0.2-50: 0.1, the mass ratio of the active component A to the pirimicarb is 5: 2-5: 1, the mass ratio of the active component A to the bifenazate is 1: 10-10, the mass ratio of the active component A to the bifenthrin is 4: 1-10: 1, the mass ratio of the active component A to the spirotetramat is 25: 1-50: 1, the mass ratio of the active component A to the chlorantraniliprole is 50: 1-100: 1, the mass ratio of the active component A to the propargite is 5: 1-10: 1, the mass ratio of the active component A to the clothianidin is 1: 2-1: 1, the mass ratio of the active component A to the thiamethoxam is 5: 1-20: 1, the mass ratio of the active component A to the trifluoropyrimidine is 4: 1-50: 1, the mass ratio of the active component A to the trifluorpirifen is 10: 1-20: 1, the mass ratio of the active component A to the triazophos is 1: 1-4: 1, the mass ratio of the active component A to the dimehypothiobac-sodium is 2: 1-4: 1, the mass ratio of the active component A to the triflumuron is 5: 1-10: 1, and the mass ratio of the active component A to the lufenuron is 5: 1-10: 1, the mass ratio of the active component A to the bistrifluron is 1: 2-10: 1, the mass ratio of the active component A to the nitenpyram is 2: 1-10: 1, the mass ratio of the active component A to the ethiprole is 2: 1-5: 1, the mass ratio of the active component A to the spinetoram is 25: 2-50: 1, the mass ratio of the active component A to the etoxazole is 25: 1-100: 1, the mass ratio of the active component A to the isoprocarb is 2: 5-5: 2, the mass ratio of the active component A to the indoxacarb is 5: 2-20: 1, the mass ratio of the active component A to the tolfenpyrad is 1: 2-2: 1, and the mass ratio of the active component A to the fenpyroximate is 25: 1-100: 1.
Still further, the mass ratio of the active component A to the avermectin is 50:1, 25:1, 100:1 and 50:1, the mass ratio of the active component A to the pyriproxyfen is 1:2 and 2:1, the mass ratio of the active component A to the imidacloprid is 10:1, 5:1, 20:1, 1:1, 2:5, 5:2, 25:1, 25:3, 50:1 and 50:3, the mass ratio of the active component A to the pymetrozine is 4:1, 2:1, 10:1, 5:1 and 5:2, the mass ratio of the active component A to the profenofos is 5:1, 5:2, 25:4, 2:1, 1:1, 4:1, 2:1, 25:2, 50:1 and 25:1, the mass ratio of the active component A to the tebufenozide is 1:2, 1:4, 1:1, 50:1, the mass ratio of the active component A to the tebufenozide is 1:8, the mass ratio of the active component A to the avermectin benzoate is 1:2, and the mass ratio of the avermectin, 10:1, 5:1, 25:3, 100:1.5, 50:3, 10:1, 25:3, 100:1, 1:2, 5:2, 1:8, 1:12, 1:4, 1:6, 1:1, 1:2, 2:1, 2:5, 1:5, 25:1, 25:2, 50:1, 25:3, 25:6, 50:3, 4:5, 25:1, 10:1, 50:1, 40:1, 20:1, 0:1, 100: 100, 100:1, 1:2, 2:1, 2:5, 1:5, 25:1, 25:3, 25:6, 50:3, 4:5, 25: 5, 0:1, 100:1, 2: 2, 5, 2, 5, the pesticide composition comprises the following components, by mass, 100:0.1, 100:0.5, 25:4, 25:1 and 25:2 of an active component A and efficient cyhalothrin, 50:1, 100:0.5 and 100:1 of the active component A and emamectin benzoate, 1:2, 2:1 and 1:1 of the active component A and methoxyfenozide, 25:0.1, 125:1 and 50:0.1 of the active component A and cyenopyrafen, 5:1, 5:2 and 10:1 of the active component A and bifenazate, 5:1, 10:1 of the active component A and bifenthrin, 2:1, 10:1, 4:1, 50:0.1, 25:0.1 and 100:0.1 of the active component A and spirotetramat a, 25:1, 25: 2:1 of the active component A and 50:1 of the spirotetramat, 25:1 of the active component A and 50:1, and 50:1 of the spirotetramat least one of the active component A, and the flufenoxanil, 25:1, 100:1 and 50:1, the mass ratio of the active component A to the propargite is 5:1, 5:2 and 10:1, the mass ratio of the active component A to the clothianidin is 1:1, 1:2, 5:4, 20:1 and 10:1, the mass ratio of the active component A to the thiamethoxam is 5:1, 20:1 and 10:1, the mass ratio of the active component A to the trifluoropyrimidine is 20:1, 4:1, 50:1 and 10:1, the mass ratio of the active component A to the trifluoromethoxyfen is 5:1, 20:1 and 10:1, the mass ratio of the active component A to the triazophos is 1:1, 4:1 and 2:1, the mass ratio of the active component A to the dimehypothion is 1:1, 4:1 and 2:1, the mass ratio of the active component A to the triflumuron is 10:1, 5:1 and 20:1, and the mass ratio of the active component A to the lufenuron is 1, 5:2 and 10:1, the mass ratio of the active component A to the bistrifluron is 1:2, 1:4, 1:1, 5:2, 10:1 and 5:1, the mass ratio of the active component A to the nitenpyram is 4:1, 2:1, 8:1, 2:1, 5:1, 20:1 and 10:1, the mass ratio of the active component A to the ethiprole is 4:1, 2:1, 10:1 and 5:1, the mass ratio of the active component A to the spinetoram is 25:2, 50:1 and 25:1, the mass ratio of the active component A to the etoxazole is 25:1, 100:1 and 50:1, the mass ratio of the active component A to the isoprocarb is 2:5, 5:2 and 1:1, the mass ratio of the active component A to the indoxacarb is 10:1, 5:1, 20:1 and 5:2, the mass ratio of the active component A to the tolfenpyrad is 1:2, 1:1, the mass ratio of the active component A to the fenpyroximate is 25:1, 100:1 and 50: 1.
When the composition is used for preventing and treating myzus persicae, the mass ratio of the active component A to the pirimicarb is 5:1, 5:2 and 10:1, the mass ratio of the active component A to the lambda-cyhalothrin is 25:4, 25:1 and 25:2, the mass ratio of the active component A to the bifenthrin is 25:0.1, 100:0.1 and 50:0.1, the mass ratio of the active component A to the imidacloprid is 25:1, 25:3, 50:1 and 50:3, the mass ratio of the active component A to the acetamiprid is 50:3, 25:3 and 100:3, the mass ratio of the active component A to the dinotefuran is 5:1, 20:1 and 10:1, the mass ratio of the active component A to the sulfoxaflor is 50:1, 25:1, the mass ratio of the active component A to the thiamethoxam is 5:1, 20:1 and 10:1, the mass ratio of the active component A to the thiamethoxam is 5:1, 10:1, the mass ratio of the active component A to the nitenpyram is 5:1, 20:1 and 10:1, the mass ratio of the active component A to the pymetrozine is 5:2, 10:1 and 5:1, the mass ratio of the active component A to the sulfoxaflor is 25:6, 50:3 and 25:3, preferably the mass ratio of the active component A to the lambda-cyhalothrin is 25:4, 25:1 and 25:2, the mass ratio of the active component A to the bifenthrin is 25:0.1, 100:0.1, 50:0.1 and 50:3, the mass ratio of the active component A to the acetamiprid is 50:3 and 25:3, the mass ratio of the active component A to the dinotefuran is 5:1, 20:1 and 10:1, the mass ratio of the active component A to the sulfoxaflor the active component A to the nitenpyram is 25:1, the mass ratio of the active component A to the thiamethoxam is 10:1, and the mass ratio of the active component A to the nitenpyram is 10:1, The mass ratio of the active component A to the pymetrozine is 5:1, and the mass ratio of the active component A to the sulfoxaflor is 50:3 and 25: 3;
when the composition is used for preventing and treating rice planthoppers, the mass ratio of the active component A to the isoprocarb is 1:1, 2:5 and 5:2, the mass ratio of the active component A to the profenofos is 5:1, 5:2, 25:2 and 25:4, the mass ratio of the active component A to the imidacloprid is 2:5, 5:2 and 1:1, the mass ratio of the active component A to the dinotefuran is 2:5, 1:1 and 1:2, the mass ratio of the active component A to the sulfoxaflor is 2:5, 1:1 and 1:2, the mass ratio of the active component A to the clothianidin is 1:1, 1:2, 5:2 and 5:4, the mass ratio of the active component A to the nitenpyram is 4:1, 2:1, 10:1 and 5:1, and the mass ratio of the active component A to the trifluralin is 20:1, 4:1, 10:1 and 4:1, 4: 1: 4:1, 2:1, 10:1 and 5:1, wherein the mass ratio of the active component A to the pymetrozine is 4:1, 2:1, 10:1 and 5:1, and the mass ratio of the active component A to the flonicamid is 4:5, 2:1 and 1: 1; preferably, the mass ratio of the active component A to isoprocarb is 1:1 and 2:5, the mass ratio of the active component A to profenofos is 5:1 and 25:2, the mass ratio of the active component A to clothianidin is 1:1, the mass ratio of the active component A to pymetrozine is 4:1 and 2:1, and the mass ratio of the active component A to flonicamid is 4:5, 2:1 and 1: 1;
when the composition is used for controlling trialeurodes vaporariorum, the mass ratio of the active component A to the sulfoxaflor is 1:2, 2:1 and 1:1, the mass ratio of the active component A to the bistrifluron is 1:4, 1:1 and 1:2, and the mass ratio of the active component A to the pyriproxyfen is 1:2, 2:1 and 1: 1; preferably, the mass ratio of the active component A to the sulfoxaflor is 2:1 and 1:1, the mass ratio of the active component A to the bistrifluron is 1:4 and 1:2, and the mass ratio of the active component A to the pyriproxyfen is 2:1 and 1: 1.
When the composition is used for preventing and treating plutella xylostella, the mass ratio of the active component A to profenofos is 25:2, 50:1 and 25:1, the mass ratio of the active component A to diflubenzuron is 1:8, 1:2 and 1:4, the mass ratio of the active component A to chlorfluazuron is 10:1, 50:1 and 20:1, the mass ratio of the active component A to hexaflumuron is 10:1, 40:1 and 20:1, the mass ratio of the active component A to triflumuron is 5:1, 20:1 and 10:1, the mass ratio of the active component A to lufenuron is 5:2, 10:1 and 5:1, the mass ratio of the active component A to bistrifluron is 5:2, 10:1 and 5:1, the mass ratio of the active component A to avermectin is 25:1, 100:1 and 50:1, and the mass ratio of the active component A to emamectin is 10:1, 50:1 and 0.1, the mass ratio of the active component A to the indoxacarb is 5:2, 10:1 and 5:1, the mass ratio of the active component A to the chlorantraniliprole is 25:1, 100:1 and 50:1, the mass ratio of the active component A to the fluorochlordiamide is 100:1, 100:0.1 and 20:0.1, the mass ratio of the active component A to the tebufenozide is 1:20, 1:4, 1:1 and 1:2, the mass ratio of the active component A to the methoxyfenozide is 1:2, 2:1 and 1:1, the mass ratio of the active component A to the tolfenpyrad is 1:2, 2:1 and 1:1, the mass ratio of the active component A to the ethyl spinosad is 25:2, 50:1 and 25:1, the mass ratio of the active component A to the butafenacet is 5:2, 10:1 and 5:1, and the mass ratio of the active component A to the triflumezopyr is 5:1, 20:1 and 20: 1; preferably, the mass ratio of the active component A to the profenofos is 50:1 and 25:1, the mass ratio of the active component A to the diflubenzuron is 1:2 and 1:4, the mass ratio of the active component A to the chlorfluazuron is 50:1 and 20:1, the mass ratio of the active component A to the hexaflumuron is 40:1 and 20:1, the mass ratio of the active component A to the triflumuron is 20:1 and 10:1, the mass ratio of the active component A to the lufenuron is 5:2, 10:1 and 5:1, the mass ratio of the active component A to the bistrifluron is 10:1 and 5:1, the mass ratio of the active component A to the abamectin is 25:1 and 100:1 and 50:1, the mass ratio of the active component A to the emamectin benzoate is 50:1, 50:0.1 and 100:1, the mass ratio of the active component A to the indoxacarb is 10:1 and 5:1, and the mass ratio of the active component A to the chlorantraniliprole is 100:1, 50:1, the mass ratio of the active component A to the fluorochlorobinamide is 100:0.1 and 20:0.1, the mass ratio of the active component A to the tebufenozide is 1:1 and 1:2, the mass ratio of the active component A to the methoxyfenozide is 2:1 and 1:1, the mass ratio of the active component A to the tolfenpyrad is 1:2, 2:1 and 1:1, the mass ratio of the active component A to the spinetoram is 50:1 and 25:1, the mass ratio of the active component A to the butirotetramat is 10:1 and 5:1, and the mass ratio of the active component A to the trifluralin is 5:1, 20:1 and 10: 1.
When the composition is used for preventing and treating chilo suppressalis, the mass ratio of the active component A to profenofos is 2:1, 1:1 and 4:1, the mass ratio of the active component A to triazophos is 2:1, 1:1 and 4:1, the mass ratio of the active component A to dinotefuran is 5:2, 10:1 and 5:1, the mass ratio of the active component A to dimehypo is 1:1, 4:1 and 2:1, the mass ratio of the active component A to butafenapyr is 5:2, 10:1 and 5:1, the mass ratio of the active component A to chlorantraniliprole is 50:1, 25:1, 100:1 and 50:1, and the mass ratio of the active component A to fluorochlordiamide is 50:0.1, 100:1, 100:0.1 and 20: 0.1; preferably, the mass ratio of the active component A to the profenofos is 2:1 and 4:1, the mass ratio of the active component A to the triazophos is 2:1 and 4:1, the mass ratio of the active component A to the dinotefuran is 5:2, 10:1 and 5:1, the mass ratio of the active component A to the dimehypo is 4:1 and 2:1, the mass ratio of the active component A to the butirotetramine is 10:1 and 5:1, the mass ratio of the active component A to the chlorantraniliprole is 50:1, 25:1, 100:1 and 50:1, and the mass ratio of the active component A to the fluorochlordiamide is 50:0.1, 100:1, 100:0.1 and 20: 0.1.
When the composition is used for preventing and treating tea lesser leafhoppers, the mass ratio of the active component A to bifenthrin is 5:1, 2:1, 10:1 and 4:1, the mass ratio of the active component A to imidacloprid is 10:1, 5:1 and 20:1, the mass ratio of the active component A to dinotefuran is 5:1, 20:1 and 10:1, the mass ratio of the active component A to nitenpyram is 2:1, 8:1 and 4:1, and the mass ratio of the active component A to indoxacarb is 5:1, 20:1 and 10: 1; preferably, the mass ratio of the active component A to the imidacloprid is 10:1 and 20:1, the mass ratio of the active component A to the dinotefuran is 5:1, 20:1 and 10:1, the mass ratio of the active component A to the nitenpyram is 4:1, and the mass ratio of the active component A to the indoxacarb is 20: 1.
When the composition is used for preventing and treating tetranychus cinnabarinus, the mass ratio of an active component A to flufenoxuron is 1:8, 1:12, 1:4 and 1:6, the mass ratio of the active component A to fenpyroximate is 50:1, 25:1 and 100:1, the mass ratio of the active component A to bifenazate is 5:1, 5:2, 10:1 and 5:1, the mass ratio of the active component A to propargite is 5:2, 10:1 and 5:1, the mass ratio of the active component A to etoxazole is 50:1, 25:1 and 100:1, the mass ratio of the active component A to cyflumetofen is 5:1, 20:1 and 10:1, the mass ratio of the active component A to cyenopyrafen is 25:0.2, 50:0.1 and 25:0.1, and the mass ratio of the active component A to spirotetramat is 25:2, 50:1 and 25: 1; preferably, the mass ratio of the active component A to the fenpyroximate is 50:1 and 100:1, the mass ratio of the active component A to the bifenazate is 10:1 and 5:1, the mass ratio of the active component A to the propargite is 5:1, the mass ratio of the active component A to the cyflumetofen is 20:1 and 10:1, the mass ratio of the active component A to the cyenopyrafen is 25:0.2, 50:0.1 and 25:0.1, and the mass ratio of the active component A to the spirotetramat is 25:2, 50:1 and 25: 1.
In the insecticidal composition, the total amount of the active component A and the active component B accounts for 1-90 percent, preferably 10-70 percent by mass percent.
The insecticidal composition also contains an auxiliary agent and a carrier of a pesticide preparation.
The insecticidal composition can be used for controlling lepidoptera, coleopteran, diptera, thysanoptera and homoptera pests.
The insecticidal composition provided by the invention can be particularly used for controlling thysanoptera and homoptera pests, especially homoptera pests.
Compared with the prior art, the insecticidal composition has the following remarkable advantages:
1. the insecticidal composition has obvious synergistic effect, can reduce the use times and reduce the application amount of a single agent;
2. the insecticidal composition disclosed by the invention has activity on various generations of pests;
3. the insecticidal composition disclosed by the invention consists of active components with different action mechanisms, can effectively slow down the generation of drug resistance of pests, and greatly reduces the resistance risk caused by single application of the same component;
4. the insecticidal composition provided by the invention can obviously improve the tolerance of crops, so that the safety of the pesticide to the crops is higher.
Detailed Description
The examples of biological activity are classified into indoor examples of biological activity and field examples of biological activity.
Indoor biological activity, the inventor adopts a Bliss method to determine the synergistic effect of the composition of the active component A and the active component B on pests.
Mt＝1-(1-PA)(1-PB)
Me-Mt＝Me-(PA+PB-PA×PB)
In the formula:
Me: the composition actually measures the control effect
Mt: theoretical control effect of composition
PA、PB: the actually measured control effect of the component A and the component B under the corresponding concentration is respectively.
Me-MtWhen the ratio is more than 0, the synergistic effect is synergistic, Me-MtWhen < 0 the synergistic effect is antagonistic, Me-MtThe addition is between 0.
The following tests can demonstrate the control effect of the pesticidal composition of the present invention on specific pests, but are not limited to the pest control methods provided.
Example 1 indoor Activity of insecticidal compositions on Myzus persicae
Selecting peach aphids with consistent ages, soaking the peach aphids in the liquid medicine for 10s, sucking redundant liquid medicine by using filter paper, transferring the test insects to a normal condition for feeding, repeating the test insects for 10 times every 4 times, and evaluating the death rate of the peach aphids after culturing for 24 hours, wherein the results are shown in table 1.
TABLE 1 indoor Activity results of insecticidal compositions against Myzus persicae
Figure BDA0002847393590000091
Figure BDA0002847393590000101
Example 2 indoor Activity of insecticidal compositions against Rice planthopper and Trialeurodes vaporariorum
Selecting larvae with the age of 2-3, soaking rice planthoppers in the liquid medicine for about 10s by adopting a pest soaking method, sucking redundant liquid medicine by using filter paper, transferring the test insects to normal conditions for feeding, repeating the treatment for 4 times, soaking 10 heads for each time, and calculating the death rate after feeding for 24 hours, wherein the results are shown in tables 2-3.
TABLE 2 indoor test results of insecticidal compositions on rice planthopper
Figure BDA0002847393590000102
Figure BDA0002847393590000111
TABLE 3 indoor test results of insecticidal compositions against Bemisia alba
Figure BDA0002847393590000112
Example 3: laboratory test of insecticidal compositions against diamondback moth
And (3) punching a leaf disc by using a puncher with the diameter of 1cm, putting the leaf disc into a culture dish, adding the test medicament into the culture dish for culturing for 4 hours, and putting the leaf disc into a tissue culture plate for later use. Selecting diamondback moths with the insect age of 2-3, starving for 4h, selecting 60 test insects, respectively putting the test insects into a culture plate for feeding, selecting 20 test insects which completely eat the leaf disks 4h after inoculation, culturing for 24 h at normal temperature, investigating the death condition of the test insects, and calculating the death rate (prevention effect). Each treatment was repeated 4 times and the results are shown in Table 4.
TABLE 4 indoor test results of insecticidal compositions against plutella xylostella
Figure BDA0002847393590000121
Figure BDA0002847393590000131
Example 4: indoor activity of insecticidal composition on chilo suppressalis
And (3) punching a leaf disc by using a puncher with the diameter of 1cm, putting the leaf disc into a culture dish, adding the test medicament into the culture dish for culturing for 4 hours, and putting the leaf disc into a tissue culture plate for later use. Selecting chilo suppressalis of which the insect age is 2-3 years, starving for 4 hours, selecting 50 test insects, respectively putting the test insects into a culture plate for feeding, selecting 15 test insects which completely eat the leaf disc 4 hours after inoculation, culturing for 24 hours at normal temperature, investigating the death condition of the test insects, and calculating the death rate (prevention effect). Each treatment was repeated 4 times and the results are shown in Table 5.
TABLE 5 indoor test results of insecticidal compositions against Chilo suppressalis
Figure BDA0002847393590000132
Figure BDA0002847393590000141
Example 5: indoor activity test of insecticidal composition on tea lesser leafhoppers
Selecting larvae with the ages of 2-3, soaking the tea lesser leafhopper into the medicinal liquid for about 10s by adopting an insect soaking method, sucking redundant medicinal liquid by using filter paper, transferring the test insects to normal conditions for feeding, repeating the treatment for 4 times, soaking 15 insects for each time, and calculating the death rate after feeding for 24 hours, wherein the results are shown in Table 6.
TABLE 6 indoor Activity results of insecticidal compositions against tea Empoasca vitis
Figure BDA0002847393590000142
Figure BDA0002847393590000151
Example 6: indoor activity of insecticidal composition on tetranychus cinnabarinus
Selecting citrus leaves with growth inhibition, making into leaf discs by using a puncher, inoculating nymphs of tetranychus cinnabarinus cultured indoors onto the leaf discs, inoculating 20 heads to each leaf disc, spraying by using a Potter spray tower, setting the spraying liquid amount to be 1mL, taking out after the liquid medicine is settled for 1min, transferring to a room temperature for feeding, checking the death number of test insects after 48 hours, and calculating the death rate, wherein the test is shown in Table 7.
TABLE 7 indoor Activity results of insecticidal compositions against Tetranychus cinnabarinus
Figure BDA0002847393590000152
Figure BDA0002847393590000161
The results of indoor tests show that the compounds listed in tables 1-7 have good indoor activity on green peach aphids, rice planthoppers, whiteflies, diamond back moths, chilo suppressalis, tea lesser leafhoppers and carmine spider mites.
Example 7: field control effect of insecticidal composition on myzus persicae
The test is completed in the Qingdao, i.e. the Tachy test base, and the crop is selected to be cabbage. The test adopts a complete random block design, the water consumption per mu is 15L, 4 times of treatment are repeated, the base number is investigated before the pesticide is applied, the number of live insects is investigated after the pesticide is applied, and the decline rate and the prevention and treatment effect are calculated respectively. The investigation method uses 5-point sampling, 5 plants are investigated at each point, each plant is marked with one leaf with enough aphid number, the aphids of the whole leaf are counted, and the base number of each cell is not lower than 500 aphids.
Oral cavity decline rate (%) (oral cavity base-number of insect after application)/base before test × 100
Control effect (%) - (reduction rate of population of insects in medicament treatment-reduction rate of population of insects in blank control area)/(reduction rate of population of insects in 100-blank control area) × 100
TABLE 8 field control of green peach aphids on cabbage with insecticidal compositions
Figure BDA0002847393590000171
Test results show that the insecticidal compositions listed in Table 8 achieve expected control effects on green peach aphids on brassicaceae cabbages, and the control effects are 82.06% -93.27%.
Example 8: field control effect of insecticidal composition on rice planthopper
The test is completed in a test base of the Hunan Changsha rice, 5 treatments are set in the test, clear water is set for comparison, each treatment area is 20 square meters, the repeated treatment is carried out for 3 times, and the water consumption per mu is 15L. The number of live insects was investigated 14 days after application. The investigation method comprises the steps of investigating 25 clusters of rice in each treatment, shaking the clusters, counting the number of rice planthoppers floating on the water surface among the clusters, and calculating the control effect.
Control effect (%) [ (number of live insects after control in control area-number of live insects after control in treatment area)/number of live insects after control in control area ]. times 100
TABLE 9 control Effect of insecticidal compositions on Rice planthoppers
Figure BDA0002847393590000172
Figure BDA0002847393590000181
The test results show that the insecticidal compositions listed in Table 9 have good control effect on rice planthoppers, and the control effect is 66.76-84.62%.
Example 9: field control effect of insecticidal composition on trialeurodes vaporariorum
The test is carried out on greenhouse cultivated cucumbers, each cell is 20 square meters, protective plants are arranged around the cells, the treatment is repeated for 4 times, and 20L of water is used for each mu of land. And 6 compound leaves of the same growth part of 10 cucumbers are repeatedly investigated, the leaves are slightly turned when adults in the early morning are inactive, and the number of the adults on each leaf is counted. The population base number is investigated before the application of the pesticide, the number of live insects is investigated 7 days after the pesticide application, and the population decline rate and the prevention and treatment effect are calculated.
Oral cavity decline rate (%) (oral cavity base-number of insect after application)/base before test × 100
Control effect (%) - (reduction rate of population of insects in medicament treatment-reduction rate of population of insects in blank control area)/(reduction rate of population of insects in 100-blank control area) × 100
TABLE 10 controlling Effect of insecticidal compositions on Bemisia alba in greenhouse
Figure BDA0002847393590000182
Test results show that the insecticidal compositions listed in the table 10 have the control effect on cucumber whitefly in greenhouses higher than 70%, and do not cause chemical injury to cucumbers.
Example 10: field control effect of insecticidal composition on diamondback moth
The test is completed in a test base of Qingdao, i.e. Mo city, and the crop is selected to be Chinese cabbage. The test adopts a complete random block design, the base number is investigated before the pesticide application and the number of live insects is investigated 7 days after the pesticide application after 4 treatments are repeated, 15L of water is used for each mu of land, and the decline rate and the prevention and treatment effect are respectively calculated. The investigation method uses 5-point sampling, 5 plants are investigated at each point, and the total number of larvae of each insect age of the whole plutella xylostella is investigated.
Oral cavity decline rate (%) (oral cavity base-number of insect after application)/base before test × 100
Control effect (%) - (reduction rate of population of insects in medicament treatment-reduction rate of population of insects in blank control area)/(reduction rate of population of insects in 100-blank control area) × 100
TABLE 11 field control Effect of insecticidal compositions on Plutella xylostella
Figure BDA0002847393590000191
The test results show that the insecticidal compositions listed in Table 11 have good control effects on the cabbage moth, the control effects are 64.34-92.36%, and no phytotoxicity is generated on the cabbage in the test process.
Example 11: field control effect of insecticidal composition on chilo suppressalis
The pesticide is applied when the sheath withering rate of the first-generation chilo suppressalis in the tillering stage of the rice is about 2% -3%, the water consumption per mu is 15L, and the application is repeated for 3 times, and each repetition is 40 square meters. The population base number of the insects is not checked before the pesticide is applied, the leaf rolling condition is checked 7 days after the pesticide is applied, 25 clusters of rice plants are checked 20 days after the pesticide is applied in each cell, and the prevention and treatment effect is calculated.
Leaf rolling rate (%) — investigated leaf rolling number/investigated total leaf number × 100
Control effect (%) - (after-blank area drug leaf rolling rate-after-drug leaf rolling rate in drug-treated area)/blank area leaf rolling rate × 100
TABLE 12 field control effect of insecticidal compositions on rice stem borer
Figure BDA0002847393590000201
The test results show that the insecticidal compositions listed in Table 12 have good control effect on rice stem borers, the leaf rolling rate of each treatment is lower than 11%, and the control effect is 69.71% -78.91%. No adverse effect is caused to the rice in the test process.
Example 12: field control effect of insecticidal composition on tea lesser leafhoppers
The test is carried out in a Shandong Qingdao tea garden, the area of a test plot is 40 square meters, the test plot is repeated for 4 times, the water consumption per mu is 15L, points are fixedly arranged in the plot, the quantity of nymphs on 50 young leaves is investigated as the population base number, the population number after the pesticide application is investigated 7 days later, and the population decline rate and the control effect are calculated.
Oral cavity decline rate (%) (oral cavity base-number of insect after application)/base before test × 100
Control effect (%) - (reduction rate of population of insects in medicament treatment-reduction rate of population of insects in blank control area)/(reduction rate of population of insects in 100-blank control area) × 100
TABLE 13 field control effect of insecticidal compositions on tea lesser leafhoppers
Figure BDA0002847393590000202
Figure BDA0002847393590000211
Test results show that the different insecticidal compositions listed in Table 13 have good control effect on tea lesser leafhoppers, the decline rate in 7 days after the insecticide is higher than 70%, the control effect is 79.95% -84.19%, and in the test process, the compositions do not cause phytotoxicity on tea leaves and do not cause adverse effects on beneficial organisms.
Example 13 field control of insecticidal compositions against Tetranychus cinnabarinus
The test is carried out in a Shandong Qingdao, namely a black eggplant plantation, the fertilizer and water conditions are good, the eggplants are cultivated in the open air, the cells are randomly arranged, the area is 20 square meters, the treatment is repeated for 3 times, and the pesticide application is carried out for 1 time. And (4) fixedly taking 20 leaves per cell to count the number of mites (containing adult mites and nymphs). Investigation was conducted 7 days after application of the drug, and the control effect was calculated.
Mite reduction rate (%) (population basis-number of applied worms)/population basis before test 100
Control effect (%) (agent treatment mite reduction rate-blank control area mite reduction rate)/(100-blank control area mite reduction rate) × 100
TABLE 14 field control Effect of insecticidal compositions on Tetranychus cinnabarinus
Figure BDA0002847393590000212
Test results show that the different insecticidal compositions listed in the table 14 have good control effect on tetranychus cinnabarinus, and the control effect is 65.53-70.19% 7 days after the insecticide is applied. And the insecticidal composition has no influence on the growth of eggplants and has no harm to beneficial organisms.
Preparation examples of formulations
The pesticidal composition of the present invention may be prepared by a method known to those skilled in the art at the time of formulation.
When the insecticidal composition is prepared into a suspending agent, the suspending agent comprises active components, and also comprises an auxiliary agent such as 1-8% (preferably 2-7%), a wetting agent 2-7% (preferably 2-4%), a thickening agent 0-10% (preferably 1-5%), a preservative 0-10% (preferably 1-2%), a defoaming agent 1-10% (0.5-1%), an antifreezing agent 1-10% (2-5%) and carrier deionized water for balancing.
Example 14: the 51% A-avermectin (50:1) suspending agent comprises 50% A, 1% avermectin, 2.5% alkyl naphthalene sulfonic acid polycondensate anion sulfonate, 1.5% white carbon black, 0.5% xanthan gum, 5% ethylene glycol, 0.2% sodium benzoate, 0.5% organic silicon and deionized water for balancing;
example 15: the 15% A-pyriproxyfen (2:1) suspending agent comprises 10% A, 5% pyriproxyfen, 5% alkyl naphthalene sulfonic acid polycondensate anion sulfonate, 0.5% organosilicon, 1.5% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% white carbon black, 9% ethylene glycol, 0.2% sodium benzoate and deionized water for balancing;
example 16: the 10% A tebufenozide (1:1) suspending agent comprises 5% of A, 5% of tebufenozide, 0.6% of xanthan gum, 4% of alkyl naphthalene sulfonic acid polycondensate anion sulfonate, 0.5% of organic silicon, 1.5% of alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% of white carbon black, 8% of ethylene glycol, 0.2% of sodium benzoate and deionized water for balancing;
example 17: the 15% A-diflubenzuron (1:2) suspending agent comprises 5% A, 10% diflubenzuron, 5% FS3000, 1% TXC, 0.2% xanthan gum, 1% magnesium aluminum silicate, 4% ethylene glycol, 0.2% BIT, 0.3% organosilicon and deionized water for balancing;
example 18: the 21% A-cyflumetofen (20:1) suspending agent comprises 20% A, 1% cyflumetofen, 2% FS3000, 5% TXC, 0.2% xanthan gum, 1% magnesium aluminum silicate, 5% glycol, 0.2% BIT, 0.4% organosilicon and deionized water for balancing;
example 19: the suspension comprises 50% of A, 3% of acetamiprid, 4% of FS3000, 1% of TXC, 0.5% of xanthan gum, 1% of magnesium aluminum silicate, 5% of glycol, 0.2% of 1, 2-benzisothiazolin-3-one, 0.3% of Silwet806 and deionized water for balancing;
example 20: the 15% A.sulfoxaflor (2:1) suspending agent comprises 10% A, 5% sulfoxaflor, 4% sodium salt of alkyl naphthalene sulfonic acid polycondensate, 2% Morwet EFW, 0.5% xanthan gum, 1% magnesium aluminum silicate, 5% ethylene glycol, 0.2% 1, 2-benzisothiazolin-3-one, 0.3% organosilicon and deionized water to make up the balance;
example 21: 26% of A.sulfoxaflor (25:1) suspending agent comprises 25% of A, 1% of sulfoxaflor, 0.6% of xanthan gum, 4% of alkyl naphthalene sulfonic acid polycondensate anionic sulfonate, 0.5% of organic silicon, 2% of alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% of white carbon black, 9% of ethylene glycol, 0.2% of sodium benzoate and deionized water for balancing;
example 22: the 53% A.sulfoxaflor (50:3) suspending agent comprises 50% A, 3% sulfoxaflor, 2% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% xanthan gum, 6% glycol, 3% alkyl naphthalene sulfonic acid polycondensate anionic sulfonate, 1% organosilicon, 2% white carbon black, 0.2% sodium benzoate and deionized water for balancing;
example 23: the 10% A.flonicamid (1:1) suspending agent comprises 5% A, 5% flonicamid, 3% alkyl naphthalene sulfonic acid polycondensate anion sulfonate, 1.5% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% white carbon black, 0.2% xanthan gum, 5% ethylene glycol, 0.2% sodium benzoate, 0.5% organic silicon and deionized water for balancing;
example 24: the 21% A-chlorfluazuron (20:1) suspending agent comprises 20% A, 1% chlorfluazuron, 4% alkyl naphthalene sulfonic acid polycondensate anion sulfonate, 0.3% xanthan gum, 2% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 0.5% organosilicon, 1.5% white carbon black, 6% ethylene glycol, 0.2% sodium benzoate and deionized water for balancing;
example 25: the 15% A methoxyfenozide (2:1) suspending agent comprises 10% A, 5% methoxyfenozide, 4% alkyl naphthalene sulfonic acid polycondensate anion sulfonate, 1% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% white carbon black, 0.2% xanthan gum, 6% ethylene glycol, 0.2% sodium benzoate, 0.5% organosilicon and deionized water for balancing;
example 26: 50.2% of A-cyenopyrafen (250:1) suspending agent comprises 50% of A, 0.2% of cyenopyrafen, 4% of alkyl naphthalene sulfonic acid polycondensate anionic sulfonate, 0.5% of organic silicon, 1.5% of alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% of white carbon black, 9% of ethylene glycol, 0.2% of sodium benzoate and 0.5% of deionized water, wherein the balance is made up;
example 27: the 22% A-bifenazate (10:1) suspending agent comprises 20% of A, 2% of bifenazate, 5.5% of alkyl naphthalene sulfonic acid polycondensate anion sulfonate, 0.5% of xanthan gum, 0.5% of organosilicon, 4% of glycol, 2% of alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1.5% of white carbon black, 0.2% of sodium benzoate and deionized water for balancing;
example 28.04% A bifenthrin (500:1) suspending agent with 20% A, 0.04% bifenthrin, 4% FS3000, 1% TXC, 0.18% xanthan gum, 1% magnesium aluminum silicate, 5% ethylene glycol, 0.2% BIT, 0.3% Silwet806 synergist, deionized water to make up the balance;
example 29: the 51% A-spirotetramat (50:1) suspending agent comprises 50% A, 1% spirotetramat, 0.6% gelatin, 4% alkyl naphthalene sulfonic acid polycondensate anion sulfonate, 0.5% organosilicon, 1.5% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% white carbon black, 12% ethylene glycol, 0.2% sodium benzoate and deionized water for balancing;
example 30: the 21% A-trifluoro methyl pyridine ether (20:1) suspending agent comprises 20% A, 1% trifluoro methyl pyridine ether, 4% alkyl naphthalene sulfonic acid polycondensate anion sulfonate, 0.5% organic silicon, 2% alkyl phenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% white carbon black, 12% ethylene glycol, 0.2% potassium sorbate and 1.5% deionized water for balancing;
example 31: the 20% A-bisultap (4:1) suspending agent comprises 16% of A, 4% of bisultap, 4% of alkyl naphthalene sulfonic acid polycondensate anion sulfonate, 0.3% of xanthan gum, 1.5% of alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 0.5% of organosilicon, 1.5% of white carbon black, 6% of ethylene glycol, 0.2% of potassium sorbate and deionized water for balancing;
example 32: the 21% A-triflumuron (20:1) suspending agent comprises 20% of A, 1% of triflumuron, 2% of alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% of xanthan gum, 6% of ethylene glycol, 3% of alkyl naphthalene sulfonic acid polycondensate anionic sulfonate, 1% of organic silicon, 2% of white carbon black, 0.2% of sodium benzoate and deionized water for balancing;
example 33: the 15% A.bistrifluron (1:2) suspending agent comprises 5% A, 10% bistrifluron, 4% alkyl naphthalene sulfonic acid polycondensate anion sulfonate, 0.3% xanthan gum, 1.5% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 0.5% organosilicon, 1.5% white carbon black, 6% ethylene glycol, 0.2% potassium sorbate and deionized water for balancing;
example 34: the 22% A.bistrifluron (10:1) suspending agent comprises 20% A, 2% bistrifluron, 4% alkyl naphthalene sulfonic acid polycondensate anion sulfonate, 0.3% xanthan gum, 1.5% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1.5% white carbon black, 6% N, 0.2% potassium sorbate and 1% deionized water for balancing;
example 35: the 18% A-etoxazole (5:1) suspending agent comprises 15% A, 3% etoxazole, 4% alkyl naphthalene sulfonic acid polycondensate anion sulfonate, 0.3% xanthan gum, 1.5% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 0.5% organosilicon, 1.5% white carbon black, 6% N-methyl pyrrolidone, 0.2% sodium benzoate and deionized water for balancing;
example 36: the 14% A-isoprocarb (2:5) suspending agent comprises 4% A, 10% isoprocarb, 4% FS3000, 1% TXC, 0.18% xanthan gum, 1% magnesium aluminum silicate, 5% ethylene glycol, 0.2% BIT, 0.3% Silwet806 synergist and deionized water to make up the balance;
example 37: the 22% A-indoxacarb (10:1) suspending agent comprises 20% A, 2% indoxacarb,% urea-formaldehyde resin, 4% 0201B emulsifier, 15% S200# solvent, 15% SP682, 12% SP3262, 5% gelatin, 0.2% ethylene glycol and deionized water, and the balance is made up;
example 38: the 21% A-indoxacarb (20:1) suspending agent comprises 20% A, 1% indoxacarb, 2% agricultural emulsion 600, 8% xylene, 2% SP-682, 6% SP-326, 4% magnesium aluminum silicate and deionized water for the balance;
example 39: the 10% A-tolfenpyrad (1:1) suspending agent comprises 5% A, 5% tolfenpyrad, 3% urea-formaldehyde resin, 4% 0201B emulsifier, 5% S200# solvent, 7% SP3262, 5% xanthan gum, 0.2% ethylene glycol and deionized water for the balance;
example 40: 20.2 percent of A-fenpyroximate (100:1) suspending agent comprises 20 percent of A, 0.2 percent of fenpyroximate, 2 percent of urea-formaldehyde resin, 5 percent of 0201B emulsifier, 4 percent of agricultural emulsion 600, 4 percent of xylene, 10 percent of SPSC29, 3 percent of gelatin, 0.5 percent of glycol and deionized water, and the balance is made up.
When the insecticidal composition is prepared into water dispersible granules, besides active components, the insecticidal composition also comprises 1-10% (preferably 3-7%) of an auxiliary dispersing agent, 1-10% (preferably 3-7%) of a wetting agent, 0.5-10% (preferably 1-5%) of a disintegrating agent, 0.5-10% (preferably 1-5%) of an adhesive and the balance of a filler.
Example 41: the formula of 22% A imidacloprid (10:1) water dispersible granule comprises 20% A, 2% imidacloprid, 3% lignosulfonate, 4% ammonium sulfate and corn starch for balancing;
example 42: the formula of the 53% A imidacloprid (50:3) water dispersible granule comprises 50% A, 3% imidacloprid, 5% lignosulfonate, 5% sodium benzoate, 1% ammonium sulfate and corn starch for balancing;
example 43: the formula of the 15% A-pymetrozine (2:1) water dispersible granule comprises 10% A, 5% pymetrozine, 1% alkyl naphthalene sulfonic acid sodium salt, 3% ammonium sulfate and corn starch for balancing;
example 44: the formula of the 18% A-pymetrozine (5:1) water dispersible granule comprises 15% A, 3% pymetrozine, 3% naphthalenesulfonate, 3.5% sodium benzoate and corn starch for the balance;
example 45: the formula of 22% A-dinotefuran (10:1) water dispersible granule comprises 20% A, 2% dinotefuran, 4% lignosulfonate, 4% sodium benzoate and corn starch for the balance;
example 46: the formula of the 21% A dinotefuran (20:1) water dispersible granule comprises 20% A, 1% dinotefuran, 2% alkyl naphthalene sulfonic acid sodium salt, 4% sodium benzoate, 1% ammonium sulfate and corn starch for the balance;
example 47: 10.01 percent of A-chlorofluorobisphenol (1000:1) water dispersible granule, wherein the formula comprises 10 percent of A, 0.01 percent of chlorofluorobisphenol, 1.5 percent of sodium naphthalene sulfonate, 2 percent of sodium benzoate, 1 percent of ammonium sulfate and corn starch for balancing;
example 48: 40.2 percent of A-emamectin benzoate (200:1) water dispersible granule, wherein the formula comprises 40 percent of A, 0.2 percent of emamectin benzoate, 5 percent of alkyl naphthalene sulfonic acid sodium salt, 5 percent of sodium benzoate, 1 percent of ammonium sulfate and corn starch for balancing;
example 49: the formula of the 20.2% A-chlorantraniliprole (100:1) water dispersible granule comprises 20% A, 0.2% chlorantraniliprole, 2% lignosulfonate, 4% ammonium sulfate and corn starch, and the balance is added;
example 50: the formulation of 51% A-chlorantraniliprole (50:1) water dispersible granule comprises 50% A, 1% chlorantraniliprole, 5% sodium alkyl naphthalene sulfonate, 6% ammonium sulfate and corn starch;
example 51: the formula of the 10% A clothianidin (1:1) water dispersible granule comprises 5% A, 5% clothianidin, 2% lignosulfonate, 2% ammonium sulfate and corn starch, and the balance is complemented;
example 52: the formula of the 22% A lufenuron (10:1) water dispersible granule comprises 20% A, 2% lufenuron, 4% lignosulfonate, 4% ammonium sulfate and corn starch for balancing;
example 53: the formula of 51% A spinetoram (50:1) water dispersible granules comprises 50% A, 1% spinetoram, 6% sodium alkyl naphthalene sulfonate, 7% sodium benzoate and corn starch, and the balance is the balance.
When the insecticidal composition is prepared into missible oil, the insecticidal composition comprises 1-20 percent (2-10 percent) of auxiliary emulsifier and the balance of solvent besides active components.
Example 52: the formula of 21% A-profenofos (2:1) emulsifiable concentrate is 20% of A, 1% of profenofos, 10% of alkyl phenyl polyethylene ether and rapeseed oil, and the balance is made up;
example 53: the formula of 21% A-profenofos (2:5) emulsifiable concentrate is 20% A, 1% profenofos, 10% Nongru 0204 and rapeseed oil, and the rest is added;
example 54: the formula of 51% A-profenofos (50:1) emulsifiable concentrate is prepared from 50% A, 1% profenofos, 20% alkyl phenyl polyethylene ether and rapeseed oil, and the balance is made up;
example 55: the formula of 22% A-butryonitrile (10:1) missible oil comprises 20% A, 2% butryonitrile, 10% Nongru 0204 and rapeseed oil;
example 56: the formula of 18% A-buthronitrile (5:1) emulsifiable concentrate is prepared from 15% A, 3% buthronitrile, 6% Nongru 0204 and rapeseed oil in balance;
example 57: the formula of 41% A.hexaflumuron (40:1) emulsifiable concentrate is that 40% A, 1% hexaflumuron, 15% Nongru 0204 and colza oil are added to make up the rest;
example 58: the formula of 20% A-triazophos (4:1) emulsifiable concentrate is 16% of A, 4% of triazophos, 7% of alkyl phenyl polyethylene ether and rapeseed oil, and the balance is made up.
When the insecticidal composition is prepared into wettable powder, the insecticidal composition comprises 1-10 percent (3-7 percent) of auxiliary dispersing agent, 1-10 percent (preferably 3-7 percent) of wetting agent and filler for complementing the balance besides active components.
Example 59: the formula of 52 percent A.high-efficiency cyhalothrin (50:2) wettable powder comprises 50 percent A, 2 percent high-efficiency cypermethrin, 2 percent sodium dodecyl benzene sulfonate, 10 percent white carbon black, 7 percent sodium lignin sulfonate and light calcium carbonate for supplementing the balance;
example 60: the formula of 20% A-nitenpyram (4:1) wettable powder comprises 16% A, 4% nitenpyram, 3% sodium dodecyl benzene sulfonate, 15% white carbon black, 6% sodium lignin sulfonate and light calcium carbonate for balancing.

Claims (9)

1. A pesticide composition containing a pyrazolyl amide pesticide comprises a component A and a component B, wherein the component A is Dimppyridazz, the chemical formula is 1- (1, 2-dimethylpropyl) -N-ethyl-5-methyl-N-pyridazin-4-yl-pyrazole-4-formamide, and the structural formula is as follows:
Figure FDA0002847393580000011
component B is an active compound selected from at least groups B1-B17;
b1 carbamates: benfuracarb, propoxur, carbosulfan, benfuracarb, methiocarb, carbaryl, pirimicarb, carbofuran, benfuracarb, bendiocarb, pirimicarb, bendiocarb, methomyl, oxamyl, aldicarb, ethiocarb, isoprocarb, fenobucarb, triazamate, metam, metolcarb, propoxur, monocarb, propoxur;
b2 organophosphates: sulfosulphos, butylphosphate, fenthion, fenamiphos, pyrazofos, prothioconazole, ethoprophos, pyridaphenthion, phenthoate, trichlorfon, dichlorvos, chlorfenphos, chlorpyrifos, parathion, diazinon, naled, famciclovir, methamidophos, phorate, picolinafen, methylcrotophos, methylparathion, methylglutamyl, pirimiphos, demeton-methyl, foscarnet, monocrotophos, quinalphos, dimethoate, cadusafos, chlorothiophos, phosphorus oxychloride, malathion, fenamiphos, triazophos, cyanophos, fenide, fenitrothion, methidathion, phos, isocrotophos, phoxim, phos, omethion, dimethoate, fosetyl, ethoprophos, ethiophos, methamidophos, pyrazofos, triazophos, terbufos, phoxim, dimethos, dimethomophos, ethion, methamidophos, fosinate, pyrazofos, iso, Coumaphos, fenitrothion, baoban, leopard, ethyl bromophos, bromophenyl phosphine, Temiathion, triphosphas, ethoprophos, pyraflufen, iprobenfos and methidathion;
b3 pyrethroids: s-fenvalerate, theta-cypermethrin, beta-cypermethrin, cyphenothrin, tefluthrin, DDT, resmethrin, prallethrin, allethrin, pyrethrin, cyfluthrin, flupropathrin, silafluofen, pentafluorophenthrin, imiprothrin, thianthrin, flumethrin, cyfluthrin, flucythrinate, lambda-cyhalothrin, trifluorethrin, lambda-cyhalothrin, cyfluthrin, metofluthrin, fenpropathrin, methofluthrin, tetramethrin, lambda-cyhalothrin, fenpropathrin, permethrin, cypermethrin, etofenprox, tefluthrin, fenvalerate, prallethrin, thifluthrin, cyfluthrin, cyhalothrin, bifenthrin, cyhalothrin, permethrin, cyhalothrin, prallethrin, fluthrin, cyhalo, Bioresmethrin, bioallethrin, beta-cypermethrin, cyclopentene-propathrin, cypermethrin, transfluthrin, tetramethrin, tetrabromthrin, empenthrin, profenothrin, deltamethrin, cycloprothrin, cyhalothrin, profenothrin, resmethrin, deltamethrin, pyrethrin;
b4 neonicotinoids: imidacloprid, acetamiprid, dinotefuran, sulfoxaflor, clothianidin, thiacloprid, thiamethoxam, nitenpyram, nicotine, trifluoropyrimidine, nithiazide and imidaclothiz;
b5 benzoylureas: diflubenzuron, noviflumuron, teflubenzuron, flufenoxuron, chlorfluazuron, hexaflumuron, noviflumuron, triflumuron, lufenuron, difiulfuron, chlorfluazuron, fluazuron, chlorfluazuron, floruron;
b6 juvenile hormone mimics: fenoxycarb, pyriproxyfen, methoprene, hydroprene, methoprene, benfenoether, jubafen and methoprene;
b7 nereistoxin analogue: thiocyclam, monosulfuron, dimehypo, cartap hydrochloride;
b8 avermectin: abamectin, emamectin benzoate, lepimectin, emamectin benzoate;
b9 biological substances, hormones or pheromones: nimbin, bacillus strains, beauveria strains, metarhizium strains, paecilomyces strains, bacillus thuringiensis and verticillium strains;
b10 pyrazoles: buthrozoon, fipronil, ethiprole, acetoprole, ethiprole and fluorine pyrazole insect;
b11 oxadiazines: indoxacarb;
b12 organochlorine compound: lindane, chlordane, endosulfan;
b13 bisamides: flubendiamide, chlorantraniliprole, cyantraniliprole, flubendiamide, chlorofluorobisphenol and fluorochlorfonamide;
b14 bishydrazides: tebufenozide, chromafenozide, methoxyfenozide, chlorfenozide;
b15 other heterocycles: pyridine dinotefuran, diflufenican, pymetrozine, pyriminostrobin, flonicamid, tolfenpyrad, chlorfenapyr, dicyclanil, pyrimethanil and pyridalyl;
b16 biological insecticide: spinosyns, spinetorams;
b17 acaricide: fenaminoquinone, fenpyroximate, pyridaben, sulfadiazine, bifenazate, milbemectin, propargite, buprofezin, dicofol, tetradifon, fenpyroximate, bromopropylate, fenamiprin, spirotetramat, spiromesifen, spirodiclofen, fenazaquin, pyridaben, tebufenpyrad, flufenzine, pyriminostrobin, hexythiazox, clofentezine, ivermectin, etoxazole, cyflumetofen, cyenopyrafen, fenbutatin oxide, cyhexatin oxide and azocyclotin.
2. Pesticidal compositions according to claim 1, characterized in that at least one component B of the composition is selected from
B1 carbamates: benfuracarb, carbosulfan, pirimicarb, carbofuran, gossypol, isoprocarb, fenobucarb, triazamate;
b2 organophosphates: prothioconazole, profenofos, chlorpyrifos, triazophos, phoxim and methidathion;
b3 pyrethroids: s-fenvalerate, beta-cypermethrin, tefluthrin, pyrethrin, lambda-cyhalothrin, lambda-cyhalothrin, bifenthrin, cyhalothrin, cypermethrin, beta-cypermethrin;
b4 neonicotinoids: imidacloprid, acetamiprid, dinotefuran, sulfoxaflor, clothianidin, thiacloprid, thiamethoxam, nitenpyram and trifluoro-benzene pyrimidine;
b5 benzoylureas: diflubenzuron, flufenoxuron, chlorfluazuron, hexaflumuron, triflumuron, lufenuron, bistrifluron;
b6 juvenile hormone mimics: pyriproxyfen, methoprene;
b7 nereistoxin analogue: thiocyclam, dimehypo, cartap hydrochloride;
b8 avermectin: abamectin and emamectin benzoate;
b9 biological substances, hormones or pheromones: bacillus thuringiensis, Verticillium species;
b10 pyrazoles: butynitrile, fipronil, ethiprole;
b11 oxadiazines: indoxacarb;
b12 organochlorine compound: chlordane;
b13 bisamides: flubendiamide, chlorantraniliprole, cyantraniliprole, flubendiamide, chlorofluorobisphenol and fluorochlorfonamide;
b14 bishydrazides: tebufenozide, chromafenozide, methoxyfenozide, chlorfenozide;
b15 other heterocycles: pymetrozine, butryprole, fipronil, ethiprole, flonicamid, tolfenpyrad, chlorfenapyr and pyridalyl;
b16 biological insecticide: spinosyns, spinetorams;
b17 acaricide: fenpyroximate, pyridaben, bifenazate, propargite, buprofezin, spirotetramat, spiromesifen, spirodiclofen, pyridaben, etoxazole, cyflumetofen and cyenopyrafen.
3. A pesticidal composition according to claim 1 or 2, characterised in that at least one component B of the composition is selected from abamectin, pyriproxyfen, imidacloprid, pymetrozine, profenofos, tebufenozide, diflubenzuron, butafenapyr, cyflumetofen, acetamiprid, dinotefuran, flufenoxuron, flonicamid, fluazinam, fluazuron, flucycloxuron, lambda-cyhalothrin, emamectin benzoate, methoxyfenozide, cyenopyrafen, pirimicarb, bifenazate, bifenthrin, spirotetramat, chlorantraniliprole, propargite, clothianidin, thiamethoxam, trifloxystrobin, pyraflufen, triazophos, dimehypo, triflumuron, lufenuron, nites-nites, nites-acetamiprid, ethiprole, ethylpolycin, etoxazole, isoprocarb, indoxacarb, tolanilide, tebufenpyrad, and tebufenozide.
4. A pesticidal composition according to any one of claims 1-3, characterised in that the weight ratio of component a to component B is 0.1:100 to 100:0.1, preferably 1:12 to 100:0.1, more preferably 1:4 to 100:1.
5. The pesticide composition according to any one of claims 1 to 3, wherein the mass ratio of the active component A to abamectin is 25: 1-100: 1, the mass ratio of the active component A to pyriproxyfen is 1: 2-2: 1, the mass ratio of the active component A to imidacloprid is 2: 5-50: 1, the mass ratio of the active component A to pymetrozine is 5: 2-10: 1, the mass ratio of the active component A to profenofos is 1: 1-50: 1, the mass ratio of the active component A to tebufenozide is 1: 4-1: 1, the mass ratio of the active component A to diflubenzuron is 1: 8-1: 2, the mass ratio of the active component A to butafenapyr is 5: 2-10: 1, the mass ratio of the active component A to cyflumetofen is 5: 1-20: 1, the mass ratio of the active component A to acetamiprid is 25: 3-100: 3, and the mass ratio of the active component A to dinotefuran is 1: 20:1, the mass ratio of the active component A to the flubendiamide is 1: 12-1: 4, the mass ratio of the active component A to the flonicamid is 1: 5-50: 1, the mass ratio of the active component A to the flonicamid is 2: 5-2: 1, the mass ratio of the active component A to the fluazuron is 10: 1-50: 1, the mass ratio of the active component A to the hexaflumuron is 10: 1-40: 1, the mass ratio of the active component A to the flubendiamide is 100: 0.5-100: 0.1, the mass ratio of the active component A to the lambda-cyhalothrin is 25: 4-25: 1, the mass ratio of the active component A to the emamectin benzoate is 50: 1-100: 0.5, the mass ratio of the active component A to the methoxyfenozide is 1: 2-2: 1, the mass ratio of the active component A to the cyenopyrafen-5 is 25: 0.2-50: 0.1, the mass ratio of the active component A to the pirimicarb-10: 2:1, the mass ratio of the active component A to the bifenthrin is 2: 1-100: 0.1, the mass ratio of the active component A to the spirotetramat is 25: 2-50: 1, the mass ratio of the active component A to the chlorantraniliprole is 25: 1-100: 1, the mass ratio of the active component A to the propargite is 5: 2-10: 1, the mass ratio of the active component A to the clothianidin is 1: 2-20: 1, the mass ratio of the active component A to the thiamethoxam is 5: 1-20: 1, the mass ratio of the active component A to the trifluorinated pyrimidine is 4: 1-50: 1, the mass ratio of the active component A to the triflumizole ether is 5: 1-20: 1, the mass ratio of the active component A to the triazophos is 1: 1-4: 1, the mass ratio of the active component A to the dimehypothiobac-sodium is 1: 1-4: 1, the mass ratio of the active component A to the triflumilast-rate is 5: 1-20: 1, and the mass ratio of the active component A to the lufenuron is 5: 1-10: 1, the mass ratio of the active component A to the bistrifluron is 1: 4-10: 1, the mass ratio of the active component A to the nitenpyram is 2: 1-20: 1, the mass ratio of the active component A to the ethiprole is 2: 1-10: 1, the mass ratio of the active component A to the spinetoram is 25: 2-50: 1, the mass ratio of the active component A to the etoxazole is 25: 1-100: 1, the mass ratio of the active component A to the isoprocarb is 2: 5-5: 2, the mass ratio of the active component A to the indoxacarb is 5: 2-50: 1, the mass ratio of the active component A to the tolfenpyrad is 1: 2-2: 1, and the mass ratio of the active component A to the fenpyroximate is 25: 1-100: 1.
6. Pesticidal composition according to any of claims 1 to 5, characterized in that the sum of the weights of component A and component B is comprised between 1% and 90%, preferably between 10% and 70% of the total composition.
7. Pesticide composition according to any one of claims 1 to 6, characterized in that the pesticide composition further comprises a pesticidally acceptable adjuvant, carrier.
8. A pesticidal composition containing the pyrazole carboxamide pesticide according to any of claims 1 to 7, which is useful in a method for the therapeutic or prophylactic control of pests.
9. The method as claimed in claim 8, characterized in that the pesticide composition can be applied to the seed, the plant and/or to the fruit of the plant by seed treatment, foliar application or drip application.
CN202011515865.3A 2020-12-21 2020-12-21 Pesticide composition containing pyrazole formamide insecticide and application thereof Pending CN112616845A (en)

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