CN112574618A - Chlorine-containing water-based ink and preparation method and application thereof - Google Patents
Chlorine-containing water-based ink and preparation method and application thereof Download PDFInfo
- Publication number
- CN112574618A CN112574618A CN202011372362.5A CN202011372362A CN112574618A CN 112574618 A CN112574618 A CN 112574618A CN 202011372362 A CN202011372362 A CN 202011372362A CN 112574618 A CN112574618 A CN 112574618A
- Authority
- CN
- China
- Prior art keywords
- chlorine
- water
- ink
- based ink
- defoaming agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 48
- 229910052801 chlorine Inorganic materials 0.000 title claims abstract description 33
- 239000000460 chlorine Substances 0.000 title claims abstract description 33
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title abstract description 7
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 20
- 239000006184 cosolvent Substances 0.000 claims abstract description 15
- 239000000049 pigment Substances 0.000 claims abstract description 15
- 239000000839 emulsion Substances 0.000 claims abstract description 14
- 150000001805 chlorine compounds Chemical class 0.000 claims abstract description 12
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 4
- JBIJLHTVPXGSAM-UHFFFAOYSA-N 2-naphthylamine Chemical compound C1=CC=CC2=CC(N)=CC=C21 JBIJLHTVPXGSAM-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000004698 Polyethylene Substances 0.000 claims description 22
- 239000004743 Polypropylene Substances 0.000 claims description 22
- 229920000573 polyethylene Polymers 0.000 claims description 22
- 229920001155 polypropylene Polymers 0.000 claims description 22
- -1 acetylene glycol Chemical compound 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 14
- 238000002156 mixing Methods 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 239000006229 carbon black Substances 0.000 claims description 3
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- YOBAEOGBNPPUQV-UHFFFAOYSA-N iron;trihydrate Chemical compound O.O.O.[Fe].[Fe] YOBAEOGBNPPUQV-UHFFFAOYSA-N 0.000 claims description 2
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract description 6
- 239000000853 adhesive Substances 0.000 abstract description 6
- 230000001070 adhesive effect Effects 0.000 abstract description 6
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 abstract description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract description 3
- 239000002985 plastic film Substances 0.000 abstract description 3
- 229920006255 plastic film Polymers 0.000 abstract description 3
- 229920003023 plastic Polymers 0.000 abstract description 2
- 239000004033 plastic Substances 0.000 abstract description 2
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 12
- 239000002390 adhesive tape Substances 0.000 description 8
- 239000006185 dispersion Substances 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000005096 rolling process Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000005303 weighing Methods 0.000 description 4
- UICXTANXZJJIBC-UHFFFAOYSA-N 1-(1-hydroperoxycyclohexyl)peroxycyclohexan-1-ol Chemical compound C1CCCCC1(O)OOC1(OO)CCCCC1 UICXTANXZJJIBC-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- OMOVVBIIQSXZSZ-UHFFFAOYSA-N [6-(4-acetyloxy-5,9a-dimethyl-2,7-dioxo-4,5a,6,9-tetrahydro-3h-pyrano[3,4-b]oxepin-5-yl)-5-formyloxy-3-(furan-3-yl)-3a-methyl-7-methylidene-1a,2,3,4,5,6-hexahydroindeno[1,7a-b]oxiren-4-yl] 2-hydroxy-3-methylpentanoate Chemical compound CC12C(OC(=O)C(O)C(C)CC)C(OC=O)C(C3(C)C(CC(=O)OC4(C)COC(=O)CC43)OC(C)=O)C(=C)C32OC3CC1C=1C=COC=1 OMOVVBIIQSXZSZ-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001804 chlorine Chemical class 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses chlorine-containing water-based ink. The ink consists of the following components: 45% -60% of A, 1% -10% of B, 1% -5% of cosolvent, 10% -35% of pigment, 3% -10% of defoaming agent, 1% -2% of trimethylamine and 10% -20% of water; b is 5-R naphthalene-2-ol or 5-R naphthalene-2-amine, wherein R is an alkyl group of 1 to 18 carbon atoms; a is the synthetic product of cyclohexanone, vinyl chloride and acrylic acid. The preparation method comprises the following steps: a, B and trimethylamine are mixed to obtain chlorine compound emulsion, and the chlorine compound emulsion is mixed with other components and dispersed evenly to obtain the chlorine water-based ink. The printing ink is used for PE or PP printing, has strong tinting strength and adhesive force and good wettability, and can be uniformly attached to a PP/PE film; the affinity between the ink and paper and the flow-coated plastic is good, and the paper, the ink layer and the plastic film are not easy to separate or fall off.
Description
Technical Field
The invention belongs to the field of water-based ink, and particularly relates to chlorine-containing water-based ink as well as a preparation method and application thereof.
Background
Polyethylene (PE) and polypropylene (PP) films are the main printing materials because of their tasteless, non-toxic, corrosion resistant, rust resistant, lightweight, high temperature resistant, aging resistant, long service life, excellent surface finish, sufficient thermal stability, low heat fusion rate, and excellent surface smoothness. However, PP and PE are materials which are difficult to adhere to each other, and have small surface tension and low polarity. The general material is difficult to react with PP and PE to generate binding force. Particularly, after the ink is made into water, the water ink is difficult to wet the surface due to the high surface tension of water, and the water ink is difficult to spread on the surface, so that the printing and coating are difficult.
It is common practice to form polar groups on the surface of a layer of PP and PE by some physical means to modify the surface tension and the printing and coating effects. However, this approach has certain limitations. And the water-based ink in the prior art has the technical defects of poor abrasion resistance and heat resistance, large color difference, easy separation or falling among the base material, the ink layer and the plastic film and the like when being used in a curtain coating process.
Disclosure of Invention
The invention aims to provide chlorine-containing water-based ink. The specific technical scheme is as follows:
the chlorine-containing water-based ink comprises the following components in percentage by mass: 45% -60% of A, 1% -10% of B, 1% -5% of cosolvent, 10% -35% of pigment, 3% -10% of defoaming agent, 1% -2% of trimethylamine and 10% -20% of water; b is 5-R naphthalene-2-alcohol or 5-R naphthalene-2-amine, wherein R is alkyl with 1-18 carbon atoms; the structure of A is as follows:
wherein x and y are 50-100: 1.
Preferably, the co-solvent is a monohydric alcohol, a dihydric alcohol, or an alcohol ether.
Preferably, the pigment is carbon black, iron yellow, iron red, phthalocyanine blue or phthalocyanine green.
Preferably, the defoamer is acetylene glycol.
The invention also aims to provide a preparation method of the chlorine-containing water-based ink. The specific technical scheme is as follows:
the preparation method of the chlorine-containing water-based ink comprises the following steps:
(1) a, B is weighed according to the mass percentage, stirred and mixed, and then trimethylamine is added and mixed evenly to obtain the emulsion containing the chlorine compound;
(2) mixing the chlorine-containing compound emulsion, the cosolvent, the pigment, water and part of the defoaming agent, dispersing at 500-1500 rpm for 10-60 min, reducing the rotating speed to 150-450 rpm, adding the rest defoaming agent, and dispersing for 10-60 min to obtain the chlorine-containing water-based ink.
The invention also aims to provide application of the chlorine-containing water-based ink. The specific technical scheme is as follows:
the chlorine-containing water-based ink is applied to printing of Polyethylene (PE) or polypropylene (PP) materials.
The preparation method of A is as follows:
adding cyclohexanone and vinyl chloride in sequence into a reaction container (the mass ratio of the cyclohexanone to the vinyl chloride is 1:50), adding cyclohexanone peroxide (the mass ratio of the cyclohexanone peroxide to the vinyl chloride is 1:50) after the vinyl chloride is dissolved, then dropwise adding acrylic acid (the molar ratio of the vinyl chloride to the acrylic acid is 50-100: 1) at the speed of 20 drops/min, reacting for 5 hours at the temperature of 80-85 ℃, and then distilling to obtain a substance A.
The structure of B is as follows:
wherein R is an alkyl group of 1 to 18 carbon atoms and X is-NH2、-OH。
When the chlorine-containing water-based ink is prepared, the structure of a chlorine-containing compound generated by the reaction of A, B and trimethylamine is as follows:
wherein x and y are 50-100: 1, and L is a substance B.
The invention has the advantages of
(1) The invention synthesizes the chlorine-containing water-based ink which contains chlorine-containing compounds as regulators, so that the ink is used for printing Polyethylene (PE) or polypropylene (PP), has strong tinting strength and adhesive force, has good ink wettability (the wetting angle can reach 30 degrees), and can be uniformly attached to a PP/PE film; the affinity between the ink and paper and the flow-coated plastic is good, and the paper, the ink layer and the plastic film are not easy to separate or fall off.
(2) The invention reduces the printing difficulty of the water-based ink on the PP/PE film and is beneficial to the popularization of the printing of the PP/PE film.
Detailed Description
The invention will be further illustrated with reference to the following specific examples. It is to be understood that these examples are for illustrative purposes only and are not intended to limit the scope of the present invention. Further, it should be understood that various changes and modifications of the present invention may be made by those skilled in the art after reading the teachings of the present invention, and such equivalents may fall within the scope of the present invention as defined in the appended claims.
Example 1
Formula of composition
Preparing the following components in percentage by mass:
A：56％，
B：10％，
co-solvent (methanol): 3 percent of the total weight of the mixture,
pigment (carbon black): 10 percent of
Defoaming agent (acetylene glycol): 10 percent of
Trimethylamine (c): 1 percent of
Deionized water: 10 percent of
Second, methods of making and using
(1) Weighing A, B according to the formula, adding into a dispersion tank, stirring and mixing, then adding trimethylamine, and mixing uniformly to obtain chlorine compound emulsion;
(2) and adding the defoaming agent containing the chlorine compound emulsion, the cosolvent, the pigment, the water and 2/3 into a dispersion tank, dispersing for 15min at 800rpm, reducing the rotating speed to 300rpm, adding the rest 1/3 defoaming agent, and dispersing for 10min to obtain the chlorine-containing water-based ink.
When in use, the prepared water-based ink is printed on PP and PE films and naturally dried.
Third, test
Printing the prepared chlorine-containing water-based ink test sample on PP and PE films, naturally drying, adhering a 3M adhesive tape on the printing surface of the ink, rolling for 3 times by using a press roller with a certain load, standing for 5 minutes, pulling at the speed of 0.6-1.0M/s according to a method for testing 180-degree peel strength, uncovering the adhesive tape, and calculating the adhesive force grade to be 2 grade.
The surface tension was measured to be 33 dynes by the pendant drop method.
Example 2
Formula of composition
Preparing the following components in percentage by mass:
A：57％
B：10％，
co-solvent (ethylene glycol): 2 percent of the total weight of the mixture,
pigment (iron yellow): 15 percent of
Defoaming agent (acetylene glycol): 5 percent of
Trimethylamine (c): 1 percent of
Deionized water: 10 percent of
Second, methods of making and using
(1) Weighing A, B according to the formula, adding into a dispersion tank, stirring and mixing, then adding trimethylamine, and mixing uniformly to obtain chlorine compound emulsion;
(2) and adding the defoaming agent containing the chlorine compound emulsion, the cosolvent, the pigment, the water and 2/3 into a dispersion tank, dispersing for 15min at 800rpm, reducing the rotating speed to 300rpm, adding the rest 1/3 defoaming agent, and dispersing for 10min to obtain the chlorine-containing water-based ink.
When in use, the prepared water-based ink is printed on PP and PE films and naturally dried.
Third, test
Printing the prepared chlorine-containing water-based ink test sample on PP and PE films, naturally drying, adhering a 3M adhesive tape on the printing surface of the ink, rolling for 3 times by using a press roller with a certain load, standing for 5 minutes, pulling at the speed of 0.6-1.0M/s according to a method for testing 180-degree peel strength, uncovering the adhesive tape, and calculating the adhesive force grade to be 2 grade.
The surface tension was 32 dynes by the pendant drop method.
Example 3
Formula of composition
Preparing the following components in percentage by mass:
A：52％
B：5％，
cosolvent (ethanol): 2 percent of the total weight of the mixture,
pigment (iron oxide red): 20 percent of
Defoaming agent (acetylene glycol): 5 percent of
Trimethylamine (c): 1 percent of
Deionized water: 15 percent of
Second, methods of making and using
(1) Weighing A, B according to the formula, adding into a dispersion tank, stirring and mixing, then adding trimethylamine, and mixing uniformly to obtain chlorine compound emulsion;
(2) and adding the defoaming agent containing the chlorine compound emulsion, the cosolvent, the pigment, the water and 2/3 into a dispersion tank, dispersing for 15min at 800rpm, reducing the rotating speed to 300rpm, adding the rest 1/3 defoaming agent, and dispersing for 10min to obtain the chlorine-containing water-based ink.
When in use, the prepared water-based ink is printed on PP and PE films and naturally dried.
Third, test
Printing the prepared chlorine-containing water-based ink test sample on PP and PE films, naturally drying, adhering a 3M adhesive tape on the printing surface of the ink, rolling for 3 times by using a press roller with a certain load, standing for 5 minutes, pulling at the speed of 0.6-1.0M/s according to a method for testing 180-degree peel strength, uncovering the adhesive tape, and calculating the adhesive force grade to be 1 grade.
The surface tension was measured by the pendant drop method to be 36 dynes.
Example 4
Formula of composition
Preparing the following components in percentage by mass:
A：47％，
B：2％，
co-solvent (methanol): 2 percent of the total weight of the mixture,
pigment (phthalocyanine blue): 35 percent of
Defoaming agent (acetylene glycol): 3 percent of
Trimethylamine (c): 1 percent of
Deionized water: 10 percent of
Second, methods of making and using
(1) Weighing A, B according to the formula, adding into a dispersion tank, stirring and mixing, then adding trimethylamine, and mixing uniformly to obtain chlorine compound emulsion;
(2) and adding the defoaming agent containing the chlorine compound emulsion, the cosolvent, the pigment, the water and 2/3 into a dispersion tank, dispersing for 15min at 800rpm, reducing the rotating speed to 300rpm, adding the rest 1/3 defoaming agent, and dispersing for 10min to obtain the chlorine-containing water-based ink.
When in use, the prepared water-based ink is printed on PP and PE films and naturally dried.
Third, test
Printing the prepared chlorine-containing water-based ink test sample on PP and PE films, naturally drying, adhering a 3M adhesive tape on the printing surface of the ink, rolling for 3 times by using a press roller with a certain load, standing for 5 minutes, pulling at the speed of 0.6-1.0M/s according to a method for testing 180-degree peel strength, uncovering the adhesive tape, and calculating the adhesive force grade to be 1 grade.
The surface tension was measured by the pendant drop method to be 35 dyne.
Claims (6)
1. The chlorine-containing water-based ink is characterized by comprising the following components in percentage by mass: 45% -60% of A, 1% -10% of B, 1% -5% of cosolvent, 10% -35% of pigment, 3% -10% of defoaming agent, 1% -2% of trimethylamine and 10% -20% of water; b is 5-R naphthalene-2-alcohol or 5-R naphthalene-2-amine, wherein R is alkyl with 1-18 carbon atoms; the structure of A is as follows:
wherein x and y are 50-100: 1.
2. The chlorine-containing aqueous ink according to claim 1, wherein the co-solvent is a monohydric alcohol, a dihydric alcohol, or an alcohol ether.
3. The aqueous chlorine-containing ink according to claim 1, wherein the pigment is carbon black, iron yellow, iron red, phthalocyanine blue or phthalocyanine green.
4. The chlorine-containing aqueous ink according to claim 1, wherein the defoaming agent is acetylene glycol.
5. The process for producing the chlorine-containing aqueous ink according to any one of claims 1 to 4, comprising the steps of:
(1) a, B is weighed according to the mass percentage, stirred and mixed, and then trimethylamine is added and mixed evenly to obtain the emulsion containing the chlorine compound;
(2) mixing the chlorine-containing compound emulsion, the cosolvent, the pigment, water and part of the defoaming agent, dispersing at 500-1500 rpm for 10-60 min, reducing the rotating speed to 150-450 rpm, adding the rest defoaming agent, and dispersing for 10-60 min to obtain the chlorine-containing water-based ink.
6. The chlorine-containing aqueous ink according to any one of claims 1 to 4, which is applied to printing of Polyethylene (PE) or polypropylene (PP) materials.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011372362.5A CN112574618A (en) | 2020-11-30 | 2020-11-30 | Chlorine-containing water-based ink and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011372362.5A CN112574618A (en) | 2020-11-30 | 2020-11-30 | Chlorine-containing water-based ink and preparation method and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112574618A true CN112574618A (en) | 2021-03-30 |
Family
ID=75126656
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202011372362.5A Pending CN112574618A (en) | 2020-11-30 | 2020-11-30 | Chlorine-containing water-based ink and preparation method and application thereof |
Country Status (1)
| Country | Link |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01252606A (en) * | 1987-12-21 | 1989-10-09 | Sakata Corp | Modified chlorinated polypropylene and application thereof |
| CN101717596A (en) * | 2009-12-08 | 2010-06-02 | 杭华油墨化学有限公司 | Water-based ink for package printing of high-adhesion film and manufacturing method thereof |
| CN103865351A (en) * | 2014-02-21 | 2014-06-18 | 中科院广州化学有限公司 | UV (Ultraviolet) photocuring polyacrylate-chlorinated polypropylene compound aqueous emulsion for BOPP (Biaxially-oriented Polypropylene) coating and preparation method and application thereof |
| CN110317298A (en) * | 2019-05-31 | 2019-10-11 | 深圳市嘉卓成科技发展有限公司 | Watersoluble chlorinated polypropylerie for PP plastics coating is acrylic resin modified and preparation method, coating and preparation method for coating |
-
2020
- 2020-11-30 CN CN202011372362.5A patent/CN112574618A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01252606A (en) * | 1987-12-21 | 1989-10-09 | Sakata Corp | Modified chlorinated polypropylene and application thereof |
| CN101717596A (en) * | 2009-12-08 | 2010-06-02 | 杭华油墨化学有限公司 | Water-based ink for package printing of high-adhesion film and manufacturing method thereof |
| CN103865351A (en) * | 2014-02-21 | 2014-06-18 | 中科院广州化学有限公司 | UV (Ultraviolet) photocuring polyacrylate-chlorinated polypropylene compound aqueous emulsion for BOPP (Biaxially-oriented Polypropylene) coating and preparation method and application thereof |
| CN110317298A (en) * | 2019-05-31 | 2019-10-11 | 深圳市嘉卓成科技发展有限公司 | Watersoluble chlorinated polypropylerie for PP plastics coating is acrylic resin modified and preparation method, coating and preparation method for coating |
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Application publication date: 20210330 |