CN112562887B - Nano silver wire transparent conductive film with excellent bending resistance - Google Patents
Nano silver wire transparent conductive film with excellent bending resistance Download PDFInfo
- Publication number
- CN112562887B CN112562887B CN202011293050.5A CN202011293050A CN112562887B CN 112562887 B CN112562887 B CN 112562887B CN 202011293050 A CN202011293050 A CN 202011293050A CN 112562887 B CN112562887 B CN 112562887B
- Authority
- CN
- China
- Prior art keywords
- parts
- coating
- microgel
- conductive film
- bending resistance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B5/00—Non-insulated conductors or conductive bodies characterised by their form
- H01B5/14—Non-insulated conductors or conductive bodies characterised by their form comprising conductive layers or films on insulating-supports
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
Abstract
The invention relates to the field of conductive films, in particular to a nano silver wire transparent conductive film with excellent bending resistance. The transparent conductive film comprises a hardening layer, a flexible substrate, a conductive layer and a transparent protective layer which are sequentially stacked from bottom to top, wherein: the coating component of the hardened layer contains microgel oligomer, the conductive ink component of the conductive layer contains hydrogel, and the coating component of the transparent protective layer contains microgel. According to the invention, the crosslinking structure of the microgel and the hydrogel is fully utilized, the tensile property of each film layer is effectively improved, and the integral bending resistance of the transparent conductive film is further improved.
Description
Technical Field
The invention relates to the field of conductive films, in particular to a nano silver wire transparent conductive film with excellent bending resistance.
Background
With the rapid development of flexible electronics, flexible conductive materials are receiving more and more attention. The difficulty with flexible electronic displays is the flexible materials and flexible electronics. In the research on conductive materials, nano silver is always a research hotspot due to the high conductivity of the nano silver. The nano silver wire has incomparable high light transmittance, high conductivity and high flexibility compared with Indium Tin Oxide (ITO), and particularly has outstanding advantages in the field of flexible touch control. At present, due to the increasingly high requirements of the market on the flexible transparent conductive film, especially the bending resistance of the flexible transparent conductive film, the flexible transparent conductive film is easy to produce creases and even break in the folding and bending processes, which is a difficult problem to be solved urgently at present.
Disclosure of Invention
In view of the above technical problems, the present invention provides a silver nanowire transparent conductive film having excellent bending resistance.
The invention adopts the following technical scheme:
the utility model provides a nanometer silver line transparent conductive film that bending resistance is excellent, includes by lower supreme sclerosis layer, flexible substrate, conducting layer, the transparent protective layer that stacks gradually the setting, wherein:
the coating component of the hardened layer contains microgel oligomer, the conductive ink component of the conductive layer contains hydrogel, and the coating component of the transparent protective layer contains microgel.
Further, the conductive ink of the conductive layer comprises the following components in parts by weight: 5-50 wt% of nano silver wire dispersion liquid, 1-20 wt% of hydrogel, 0.1-5 wt% of adhesive, 0.0001-1 wt% of dispersing agent and the balance of water and solvent.
Furthermore, the hydrogel is polyvinyl alcohol hydrogel, polyacrylamide hydrogel, poly (N-isopropylacrylamide) hydrogel or hybrid double-network hydrogel and multi-network hydrogel which take polyvinyl alcohol, polyacrylamide and poly (N-isopropylacrylamide) as basic structures.
Furthermore, the content of the nano silver wires in the nano silver wire dispersion liquid is 0.001-2 wt%, the diameter of the nano silver wires is 5-50nm, and the length of the nano silver wires is 1-50 μm.
Further, the adhesive is one or more of acrylate, polyurethane, polyester, epoxy resin and cellulose; the dispersant is a surfactant; the conductive layer solvent is alcohol solvent such as ethanol, isopropanol, n-propanol, ethylene glycol, propylene glycol, diethylene glycol, etc., or ester solvent such as propylene glycol methyl ether acetate, dicarboxylic acid ester, etc.
The conductive layer improves the adhesive force of the coating by adding hydrogel into the nano silver wire conductive ink, the hydrogel is a hydrophilic three-dimensional network cross-linked structure and is a special soft substance capable of absorbing water and keeping cross-linking density, and the conductive material prepared by doping the hydrogel can effectively improve the bending resistance of the material, so that the tensile property of the coating after thermosetting film forming is improved.
Further, the coating of the hardened layer comprises the following components in parts by weight: 10-30 parts of light-cured oligomer, 5-20 parts of light-cured monomer, 0.1-5 parts of microgel oligomer, 0.5-3 parts of auxiliary agent, 0.5-5 parts of photoinitiator and 30-80 parts of solvent.
Further, the light-cured oligomer is one or more of unsaturated polyester, epoxy acrylate, polyurethane acrylate, polyester acrylate, polyether acrylate, pure acrylate, organic silicon oligomer and epoxy resin; the light-cured monomer is any one or more of alkyl acrylate, hydroxy (meth) acrylate, glycidyl methacrylate, isobornyl methacrylate, tetrahydrofuryl acrylate, diol diacrylate, trimethylolpropane triacrylate, pentaerythritol triacrylate and dipentaerythritol pentaacrylate.
Further, the microgel oligomer is styrene-divinylbenzene microgel.
Further, the auxiliary agent is a flatting agent, a light stabilizer, an anti-ultraviolet aging agent, an antioxidant and the like; the photoinitiator is 2-hydroxy-2-methyl-phenyl acetone-1, 1-hydroxy-cyclohexyl benzophenone or 2,4, 6-trimethyl benzoyl-ethoxy-phenyl phosphine oxide; the hardening layer solvent is alcohol or ester solvent.
According to the invention, the microgel oligomer is added into the coating to improve the bending resistance of the material, so that the flexible transparent conductive film has certain toughness. The microgel is a polymer microsphere with internal crosslinking, is a novel functional polymer, can be well dispersed in a medium, and can effectively improve the stretchability of a hardened layer when being added into a coating.
Further, the paint of the transparent protective layer comprises the following components in parts by weight: 2-20 parts of acrylate, 0.01-1 part of microgel, 0.02-2 parts of nano silicon dioxide and 80-99 parts of solvent.
Further, the microgel is styrene-divinylbenzene microgel; the transparent protective layer solvent is alcohol or ester solvent and/or water.
The transparent protective layer is mainly used for improving the wiping resistance and the chemical resistance of a protective coating by adding the nano silicon dioxide in the coating, and simultaneously improves the bending resistance of the material by adding the microgel oligomer, so that the flexible transparent conductive film is ensured to have certain toughness.
Further, the flexible substrate is a polyimide, polyester or polyolefin substrate; preferably, the flexible substrate is polyimide or polyethylene terephthalate.
The nano silver wire transparent conductive film with excellent bending resistance is prepared by three different processes by using a roll-to-roll coating mode on the basis of a flexible base material. Specifically, the preparation method comprises the following steps:
(1) preparing raw materials: respectively preparing a hardening coating, nano silver wire conductive ink and a transparent protective coating according to the raw material component proportion, and fully stirring and uniformly mixing for later use;
(2) coating a hardening layer: coating the hardened coating on the back surface of the flexible substrate, and performing photocuring to form a film;
(3) coating a conductive layer: coating the front surface of the flexible substrate with the nano silver wire conductive ink, and thermally curing to form a film through a series of temperature gradients;
(4) coating a transparent protective layer: and coating the transparent protective coating on the conductive layer, and performing thermal curing to form a film through a series of temperature gradients to obtain the nano silver wire transparent conductive film.
Further, the hardened layer is coated in a micro-concave coating mode, pre-dried at the temperature of a gradient oven at 80/100/120/120/100/80 ℃, the machine speed is 1-20m/min, and then cured into a film by an ultraviolet curing device in the nitrogen atmosphere; coating the conductive layer by adopting a slit coating mode, drying and curing at 80/100/120/120/100/80 ℃ at the machine speed of 1-10m/min to form a film; the transparent protective layer is dried and solidified into a film by adopting a slit coating mode at the machine speed of 1-5m/min and the gradient temperature of 80/100/120/120/100/80 ℃, and the nano silver wire conductive film is prepared.
According to the nano silver wire transparent conductive film with excellent bending resistance, the flexible substrate is used as the base material, the microgel oligomer is added into the hardened layer, the hydrogel is added into the conductive layer, and the microgel is added into the transparent protective layer, so that the cross-linking structure of the microgel and the hydrogel is fully utilized, the tensile property of each film layer is effectively improved, and the integral bending resistance of the transparent conductive film is further improved.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, it is obvious that the drawings in the following description are only some embodiments of the present invention, and for those skilled in the art, other drawings can be obtained according to the drawings without creative efforts.
FIG. 1 is a schematic structural diagram of a silver nanowire transparent conductive film according to the present invention;
in the figure: 1-a hardened layer, 2-a flexible substrate, 3-a conductive layer and 4-a transparent protective layer.
Detailed Description
The technical solutions in the embodiments of the present invention will be described clearly and completely with reference to the accompanying drawings in the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
A transparent conductive film of silver nanowires with excellent bending resistance is provided, as shown in figure 1, with a hardened layer 1, a flexible substrate 2, a conductive layer 3, and a transparent protective layer 4, which are stacked in this order from bottom to top. The preparation method comprises the following steps:
(1) preparing raw materials: the hardening coating, the nano silver wire conductive ink and the transparent protective coating are respectively prepared according to the raw material component proportion, and specifically:
preparing a hardening coating: uniformly dispersing 15 parts of light-cured oligomer urethane acrylate CN8000NS (sartomer), 5 parts of light-cured monomer pentaerythritol triacrylate SR444 (sartomer), 10 parts of light-cured monomer di-trimethylolpropane tetraacrylate SR355 (sartomer), 2 parts of photoinitiator 2-hydroxy-2-methyl-phenyl acetone-1, 5 parts of styrene-divinylbenzene microgel, 1 part of light stabilizer Tinuvin329, 1 part of flatting agent BYK-333 and 61 parts of solvent butyl acetate in a shading solvent for 3 hours to prepare a hardened coating for later use;
preparing nano silver wire conductive ink: uniformly dispersing 30 parts of nano silver wire dispersion liquid containing 0.25 wt% of nano silver wires, 3 parts of polyvinyl alcohol hydrogel, 0.8 part of adhesive hydroxymethyl cellulose, 0.2 part of dispersing agent BYK-349, 10 parts of n-propyl alcohol and 56 parts of deionized water in a container for 48 hours to prepare nano silver wire conductive ink for later use;
preparing a transparent protective coating: uniformly dispersing 10 parts of polyurethane modified acrylate emulsion, 2 parts of nano silicon dioxide, 1 part of styrene-divinylbenzene microgel, 5 parts of propylene glycol methyl ether acetate, 80 parts of deionized water and 1 part of BYK-346 in a container for 4 hours to prepare a transparent protective coating for later use;
(2) coating a hardening layer: coating the hardened coating on the back of the polyimide substrate in a micro-concave coating mode, pre-drying at 80/100/120/120/100/80 ℃ in a gradient oven at the machine speed of 1-20m/min, and performing photocuring film formation by using an ultraviolet curing device in a nitrogen atmosphere to prepare a transparent polyimide film with a hardened layer;
(3) coating a conductive layer: coating the nano silver wire conductive ink on the front surface of the flexible substrate in a slit coating mode, drying and curing at a gradient temperature of 80/100/120/120/100/80 ℃ to form a film, wherein the machine speed is 1-10 m/min;
(4) coating a transparent protective layer: and coating the transparent protective coating on the conductive layer by adopting a slit coating mode, drying and curing at a machine speed of 1-5m/min and a gradient temperature of 80/100/120/120/100/80 ℃ to form a film, and obtaining the nano silver wire transparent conductive film.
Example 2
A nano silver wire transparent conductive film with excellent bending resistance comprises a hardening layer, a flexible substrate, a conductive layer and a transparent protective layer which are sequentially stacked from bottom to top. The preparation method comprises the following steps:
(1) preparing raw materials: the hardening coating, the nano silver wire conductive ink and the transparent protective coating are respectively prepared according to the raw material component proportion, and specifically:
preparing a hardening coating: uniformly dispersing 10 parts of light-cured oligomer polyester acrylate CN710 (sartomer), 10 parts of light-cured monomer alkyl acrylate, 10 parts of light-cured monomer isobornyl methacrylate, 0.5 part of photoinitiator 2-hydroxy-2-methyl-phenyl acetone-1, 3 parts of styrene-divinylbenzene microgel, 0.5 part of flatting agent and 66 parts of solvent isopropanol in a shading solvent for 3 hours to prepare a hardened coating for later use;
preparing nano silver wire conductive ink: uniformly dispersing 47 parts of nano silver wire dispersion liquid containing 0.001 wt% of nano silver wires, 1.2 parts of polyacrylamide hydrogel, 0.1007 parts of adhesive polyurethane, 0.0003 part of dispersing agent BYK-349, 21.699 parts of n-propyl alcohol and 30 parts of deionized water in a container for 48 hours to prepare nano silver wire conductive ink for later use;
preparing a transparent protective coating: uniformly dispersing 2 parts of polyurethane modified acrylate emulsion, 0.02 part of nano silicon dioxide, 0.8 part of styrene-divinylbenzene microgel, 7.18 parts of propylene glycol methyl ether and 90 parts of deionized water in a container for 4 hours to prepare a transparent protective coating for later use;
(2) coating a hardening layer: coating the hardened coating on the back of the polyimide substrate in a micro-concave coating mode, pre-drying at 80/100/120/120/100/80 ℃ in a gradient oven at the machine speed of 1-20m/min, and performing photocuring film formation by using an ultraviolet curing device in a nitrogen atmosphere to prepare a transparent polyimide film with a hardened layer;
(3) coating a conductive layer: coating the front surface of the flexible substrate with the nano silver wire conductive ink in a slit coating mode, drying and curing at 80/100/120/120/100/80 ℃ to form a film at the machine speed of 1-10 m/min;
(4) coating a transparent protective layer: and coating the transparent protective coating on the conductive layer by adopting a slit coating mode, drying and curing at 80/100/120/120/100/80 ℃ at the machine speed of 1-5m/min to form a film, and thus obtaining the nano silver wire transparent conductive film.
Example 3
A nano silver wire transparent conductive film with excellent bending resistance comprises a hardening layer, a flexible substrate, a conductive layer and a transparent protective layer which are sequentially stacked from bottom to top. The preparation method comprises the following steps:
(1) preparing raw materials: the hardening coating, the nano silver wire conductive ink and the transparent protective coating are respectively prepared according to the raw material component ratio, and specifically:
preparing a hardening coating: uniformly dispersing 20 parts of light-cured oligomer urethane acrylate CN965NS (sartomera), 10 parts of light-cured monomer pentaerythritol triacrylate SR454 (sartomera), 4.9 parts of a photoinitiator 2-hydroxy-2-methyl-phenyl acetone-1, 0.1 part of styrene-divinylbenzene microgel, 3 parts of a flatting agent BYK-333 and 62 parts of solvent diformate in a light-shielding solvent for 3 hours to prepare a hardened coating for later use;
preparing nano silver wire conductive ink: uniformly dispersing 6 parts of nano silver wire dispersion liquid containing 2 wt% of nano silver wires, 20 parts of poly (N-isopropylacrylamide) hydrogel, 0.1 part of adhesive epoxy resin, 0.1 part of dispersant BYK-349, 7.8 parts of N-propanol and 66 parts of deionized water in a container for 48 hours to prepare nano silver wire conductive ink for later use;
preparing a transparent protective coating: uniformly dispersing 18 parts of polyurethane modified acrylate emulsion, 1.5 parts of nano silicon dioxide, 0.02 part of styrene-divinylbenzene microgel, 10.48 parts of propylene glycol and 70 parts of deionized water in a container for 4 hours to prepare a transparent protective coating for later use;
(2) coating a hardening layer: coating the hardened coating on the back of the polyimide substrate in a micro-concave coating mode, pre-drying at the temperature of a gradient oven of 80/100/120/120/100/80 ℃ at the machine speed of 1-20m/min, and performing photocuring film forming through an ultraviolet curing device in nitrogen atmosphere to prepare a transparent polyimide film with a hardened layer;
(3) coating a conductive layer: coating the nano silver wire conductive ink on the front surface of the flexible substrate in a slit coating mode, drying and curing at a gradient temperature of 80/100/120/120/100/80 ℃ to form a film, wherein the machine speed is 1-10 m/min;
(4) coating a transparent protective layer: and coating the transparent protective coating on the conductive layer by adopting a slit coating mode, drying and curing at 80/100/120/120/100/80 ℃ at the machine speed of 1-5m/min to form a film, and thus obtaining the nano silver wire transparent conductive film.
Example 4
A nano silver wire transparent conductive film with excellent bending resistance comprises a hardening layer, a flexible substrate, a conductive layer and a transparent protective layer which are sequentially stacked from bottom to top. The preparation method comprises the following steps:
(1) preparing raw materials: the hardening coating, the nano silver wire conductive ink and the transparent protective coating are respectively prepared according to the raw material component proportion, and specifically:
preparing a hardening coating: uniformly dispersing 15 parts of light-cured oligomer urethane acrylate CN8000NS (sartomer), 15 parts of light-cured oligomer epoxy acrylate CN-104A80 NS (sartomer), 5 parts of light-cured monomer di-trimethylolpropane tetraacrylate SR355 (sartomer), 3 parts of photoinitiator 1-hydroxy-cyclohexyl benzophenone, 2 parts of styrene-divinylbenzene microgel, 1 part of light stabilizer Tinuvin329 and 59 parts of solvent ethylene glycol in a shading solvent for 3 hours to prepare a hardened coating for later use;
preparing nano silver wire conductive ink: uniformly dispersing 20 parts of nano silver wire dispersion liquid containing 0.25 wt% of nano silver wires, 8 parts of polyvinyl alcohol hydrogel, 4.8 parts of adhesive hydroxymethyl cellulose, 0.9 part of dispersant BYK-349, 6.3 parts of n-propyl alcohol and 60 parts of deionized water in a container for 48 hours to prepare nano silver wire conductive ink for later use;
preparing a transparent protective coating: uniformly dispersing 6 parts of polyurethane modified acrylate emulsion, 0.9 part of nano silicon dioxide, 0.16 part of styrene-divinylbenzene microgel, 12.94 parts of propylene glycol and 80 parts of deionized water in a container for 4 hours to prepare a transparent protective coating for later use;
(2) coating a hardening layer: coating the hardened coating on the back of the polyimide substrate in a micro-concave coating mode, pre-drying at the temperature of a gradient oven of 80/100/120/120/100/80 ℃ at the machine speed of 1-20m/min, and performing photocuring film forming through an ultraviolet curing device in nitrogen atmosphere to prepare a transparent polyimide film with a hardened layer;
(3) coating a conductive layer: coating the nano silver wire conductive ink on the front surface of the flexible substrate in a slit coating mode, drying and curing at a gradient temperature of 80/100/120/120/100/80 ℃ to form a film, wherein the machine speed is 1-10 m/min;
(4) coating a transparent protective layer: and coating the transparent protective coating on the conductive layer by adopting a slit coating mode, drying and curing at a machine speed of 1-5m/min and a gradient temperature of 80/100/120/120/100/80 ℃ to form a film, and obtaining the nano silver wire transparent conductive film.
Comparative example 1
This comparative example is substantially identical to example 1 except that no microgel oligomer is contained in the hardened layer coating.
Comparative example 2
This comparative example is essentially identical to example 1 except that the conductive ink of the conductive layer does not contain a hydrogel.
Comparative example 3
This comparative example is substantially identical to example 1 except that no microgel oligomer is contained in the hardened layer coating.
The transparent conductive films prepared in examples 1 to 4 and comparative examples 1 to 3 were subjected to bending property tests, and the specific test procedures were as follows: the conductive films prepared in the examples and the comparative examples are tested by adopting a repeated bending machine of XHS-ZW-03A, which is produced by Shenzhen Xinhensen apparatus Limited, and the experimental conditions are as follows: one end of a conductive film to be tested is clamped by a clamping plate, one end of the clamping plate is respectively a semi-circular angle with the radius of 1mm, 3mm and 5mm, the other end of the clamping plate is clamped on a crank shaft, the conductive film is repeatedly bent under the driving of a motor, and the bending frequency is once per second. The appearance of the different conductive films after 50 ten thousand folds was recorded, and the results are shown in table 1. The method for detecting the appearance of the bending resistance test comprises the following steps: the strong light/searchlight is held by hand, the front side/the back side is irradiated and light-transmitting observed, the angle of a light source and the film surface form an angle of 45 degrees, and the observation is carried out at a distance of 30-35cm from the film surface. The resistance change of each conductive film after different bending tests was tested at the same time, and the results are shown in table 2.
TABLE 1 film surface State test results of transparent conductive film
Table 2 resistance value variation test results of transparent conductive film
As can be seen from the results of the bending resistance tests of the conductive films in tables 1-2, examples 1-4, and comparative examples 1-3, the microgel oligomer, the hydrogel and the microgel are added into the hardened layer, the conductive layer and the transparent protective layer respectively by using the flexible substrate as a substrate, and the crosslinking structures of the microgel and the hydrogel are fully utilized, so that the tensile property of each film layer is effectively improved, and the overall bending resistance of the transparent conductive film is further improved. After 50 ten thousand times of bending, the film surface appearance is good, and no crack appears; meanwhile, the resistance change rate of the conductive film is within 1%, and the excellent performance is still maintained. As can be seen from the analysis of the film surface state and the resistance value change in comparison with those of the comparative examples, the bending resistance of the conductive film of the present invention is obtained by the combined action between the layers, and is not indispensable.
The present invention has been further described with reference to specific embodiments, but it should be understood that the specific description herein should not be construed as limiting the spirit and scope of the invention, and that various modifications to the above-described embodiments, which would occur to persons skilled in the art upon reading this description, are within the scope of the invention.
Claims (9)
1. The utility model provides a resistant excellent nanometer silver line transparent conducting film of bending property which characterized in that includes sclerosis layer, flexible substrate, conducting layer, the transparent protective layer that stacks gradually the setting by lower supreme, wherein:
the coating component of the hardened layer contains microgel oligomer, the conductive ink component of the conductive layer contains hydrogel, and the coating component of the transparent protective layer contains microgel;
the conductive ink of the conductive layer comprises the following components in percentage by mass: 5-50 wt% of nano silver wire dispersion liquid, 1-20 wt% of hydrogel, 0.1-5 wt% of adhesive, 0.0001-1 wt% of dispersant, and the balance of water and solvent.
2. The transparent conductive film of silver nanowires with excellent bending resistance as claimed in claim 1, wherein the hydrogel is a polyvinyl alcohol hydrogel, a polyacrylamide hydrogel, a poly (N-isopropylacrylamide) hydrogel, or a hybrid dual-network hydrogel or a multi-network hydrogel having a basic structure of polyvinyl alcohol, polyacrylamide or poly (N-isopropylacrylamide).
3. The transparent conductive film of silver nanowires with excellent bending resistance as claimed in claim 1, wherein the silver nanowires are contained in the silver nanowire dispersion in an amount of 0.001 to 2 wt%, and the silver nanowires have a diameter of 5 to 50nm and a length of 1 to 50 μm.
4. The transparent conductive film of silver nanowires with excellent bending resistance according to claim 1, wherein the coating of the hardened layer comprises the following components in parts by weight: 10-30 parts of light-cured oligomer, 5-20 parts of light-cured monomer, 0.1-5 parts of microgel oligomer, 0.5-3 parts of auxiliary agent, 0.5-5 parts of photoinitiator and 30-80 parts of solvent.
5. The transparent conductive film of silver nanowires with excellent bending resistance of claim 4, wherein the photo-curable oligomer is one or more of unsaturated polyester, epoxy acrylate, polyurethane acrylate, polyester acrylate, polyether acrylate, pure acrylate, silicone oligomer and epoxy resin;
the light-cured monomer is any one or more of alkyl acrylate, hydroxy (meth) acrylate, glycidyl methacrylate, isobornyl methacrylate, tetrahydrofuran methyl acrylate, glycol diacrylate, trimethylolpropane triacrylate, pentaerythritol triacrylate and dipentaerythritol pentaacrylate.
6. The transparent conductive film of silver nanowires with excellent bending resistance according to claim 1 or 4, wherein the microgel oligomer is styrene-divinylbenzene microgel.
7. The transparent conductive film of silver nanowires with excellent bending resistance of claim 1, wherein the coating of the transparent protective layer comprises the following components in parts by weight: 2-20 parts of acrylic ester, 0.01-1 part of microgel, 0.02-2 parts of nano silicon dioxide and 80-99 parts of solvent.
8. The transparent conductive film of silver nanowires with excellent bending resistance as claimed in claim 1 or 7, wherein the microgel is styrene-divinylbenzene microgel.
9. The transparent conductive film of silver nanowires with excellent bending resistance according to claim 1, wherein the flexible substrate is a polyimide, polyester or polyolefin substrate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011293050.5A CN112562887B (en) | 2020-11-18 | 2020-11-18 | Nano silver wire transparent conductive film with excellent bending resistance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011293050.5A CN112562887B (en) | 2020-11-18 | 2020-11-18 | Nano silver wire transparent conductive film with excellent bending resistance |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN112562887A CN112562887A (en) | 2021-03-26 |
| CN112562887B true CN112562887B (en) | 2022-07-15 |
Family
ID=75043833
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202011293050.5A Active CN112562887B (en) | 2020-11-18 | 2020-11-18 | Nano silver wire transparent conductive film with excellent bending resistance |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112562887B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113185944B (en) * | 2021-04-24 | 2022-08-05 | 深圳市撒比斯科技有限公司 | UV adhesive and electric control PDLC functional film containing UV adhesive |
Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012141058A1 (en) * | 2011-04-14 | 2012-10-18 | 富士フイルム株式会社 | Conductive member, method for producing conductive member, touch panel, and solar cell |
| CN104134484A (en) * | 2014-07-31 | 2014-11-05 | 中国电子科技集团公司第五十五研究所 | Flexible transparent conductive film based on silver nanowires and preparation method |
| CN104380394A (en) * | 2012-06-18 | 2015-02-25 | 乐金华奥斯有限公司 | Transparent conductive film having bending resistance, and method for manufacturing same |
| CN105161315A (en) * | 2015-09-16 | 2015-12-16 | 中国科学院电工研究所 | Hydrogel electrolyte thin film, and preparation method and application therefor |
| CN106046943A (en) * | 2016-07-26 | 2016-10-26 | 珠海纳金科技有限公司 | Conductive printing ink for inkjet printing and method for preparing conductive printing ink |
| CN106794666A (en) * | 2015-02-19 | 2017-05-31 | 积水化学工业株式会社 | Light transmitting conductive film, its film roll and the touch panel with it |
| CN107274793A (en) * | 2017-08-23 | 2017-10-20 | 合肥同诺文化科技有限公司 | Flexible display screen and the electronic equipment with the display screen |
| CN107840982A (en) * | 2017-11-09 | 2018-03-27 | 合肥乐凯科技产业有限公司 | A kind of anti-dazzle optical hardening film of fine definition |
| CN207425393U (en) * | 2017-06-23 | 2018-05-29 | 张家港康得新光电材料有限公司 | A kind of nano-silver conductive film |
| CN109799555A (en) * | 2018-12-28 | 2019-05-24 | 张家港康得新光电材料有限公司 | A kind of peep-proof film resistant to bending |
| CN110444318A (en) * | 2019-08-21 | 2019-11-12 | 合肥微晶材料科技有限公司 | A kind of nano-silver thread flexible transparent conducting film with high overlap joint efficiency and excellent resistance to bend(ing) energy |
| CN111423536A (en) * | 2020-02-29 | 2020-07-17 | 湖南大学 | High-tensile conductive hydrogel for photocuring 3D printing and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100556924C (en) * | 2007-04-02 | 2009-11-04 | 东华大学 | The preparation method of temperature and pH value valve sensitive nano microgel |
| CN106782769B (en) * | 2016-11-22 | 2018-06-29 | 华中科技大学 | Flexible and transparent conductive laminated film of low roughness low square resistance and preparation method thereof |
-
2020
- 2020-11-18 CN CN202011293050.5A patent/CN112562887B/en active Active
Patent Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012141058A1 (en) * | 2011-04-14 | 2012-10-18 | 富士フイルム株式会社 | Conductive member, method for producing conductive member, touch panel, and solar cell |
| CN103493147A (en) * | 2011-04-14 | 2014-01-01 | 富士胶片株式会社 | Conductive member, method for producing conductive member, touch panel, and solar cell |
| CN104380394A (en) * | 2012-06-18 | 2015-02-25 | 乐金华奥斯有限公司 | Transparent conductive film having bending resistance, and method for manufacturing same |
| CN104134484A (en) * | 2014-07-31 | 2014-11-05 | 中国电子科技集团公司第五十五研究所 | Flexible transparent conductive film based on silver nanowires and preparation method |
| CN106794666A (en) * | 2015-02-19 | 2017-05-31 | 积水化学工业株式会社 | Light transmitting conductive film, its film roll and the touch panel with it |
| CN105161315A (en) * | 2015-09-16 | 2015-12-16 | 中国科学院电工研究所 | Hydrogel electrolyte thin film, and preparation method and application therefor |
| CN106046943A (en) * | 2016-07-26 | 2016-10-26 | 珠海纳金科技有限公司 | Conductive printing ink for inkjet printing and method for preparing conductive printing ink |
| CN207425393U (en) * | 2017-06-23 | 2018-05-29 | 张家港康得新光电材料有限公司 | A kind of nano-silver conductive film |
| CN107274793A (en) * | 2017-08-23 | 2017-10-20 | 合肥同诺文化科技有限公司 | Flexible display screen and the electronic equipment with the display screen |
| CN107840982A (en) * | 2017-11-09 | 2018-03-27 | 合肥乐凯科技产业有限公司 | A kind of anti-dazzle optical hardening film of fine definition |
| CN109799555A (en) * | 2018-12-28 | 2019-05-24 | 张家港康得新光电材料有限公司 | A kind of peep-proof film resistant to bending |
| CN110444318A (en) * | 2019-08-21 | 2019-11-12 | 合肥微晶材料科技有限公司 | A kind of nano-silver thread flexible transparent conducting film with high overlap joint efficiency and excellent resistance to bend(ing) energy |
| CN111423536A (en) * | 2020-02-29 | 2020-07-17 | 湖南大学 | High-tensile conductive hydrogel for photocuring 3D printing and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 可拉伸超韧水凝胶的制备和应用;盛卉等;《高等学校化学学报》;20200630;第41卷(第6期);第56-65页 * |
| 强韧型凝胶及其功能化研究进展;郭坤等;《西南民族大学学报(自然科学版)》;20190131;第45卷(第1期);第1194-1207页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN112562887A (en) | 2021-03-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US9854670B2 (en) | Transparent electrode and method for producing same | |
| KR102543985B1 (en) | Conductive films and electronic decives including the same | |
| CN108022669B (en) | Special ultralow-temperature curing laser etching conductive silver paste for mobile phone touch screen | |
| TWI550637B (en) | Transparent conductor, composition for transparent conductive film, and optical display apparatus | |
| CN104637570A (en) | Flexible transparent conductive thin film and preparation method thereof | |
| US20110133134A1 (en) | Crosslinkable and Crosslinked Compositions of Olefin Polymers and Graphene Sheets | |
| US20120097903A1 (en) | Inks and coatings containing multi-chain lipids | |
| CN105670394A (en) | Coatings containing functionalized graphene sheets and articles coated therewith | |
| TW201435005A (en) | Ultraviolet-curable conductive ink and dielectric ink compositions having a common binding medium, with manufactures and fabrication methods | |
| KR20100088155A (en) | Method for producing carbon nanotube-containing conductor | |
| JP6124099B1 (en) | Conductive laminate, molded body using the same, capacitive touch sensor and planar heating element, and method for manufacturing molded body | |
| CN112562887B (en) | Nano silver wire transparent conductive film with excellent bending resistance | |
| TWI671766B (en) | Conductive film and method for producing conductive film | |
| KR20130062176A (en) | Substrate films for transparent electrode films | |
| US9777171B1 (en) | Graphene compositions | |
| WO2017170795A1 (en) | Resin composition and electronic element | |
| CN106574137A (en) | Conductive transparent coating for rigid and flexible substrates | |
| KR101675887B1 (en) | Flexible multilayer sheet for transparent electrode and manufacturing method thereof | |
| KR20060051523A (en) | Transparent conducting material and transparent conductor | |
| KR101233241B1 (en) | Ultra Violet Curing Conductive Paste Composition for Touch Panels, Touch Panels Containing the Composition and Manufacturing Process of the Composition | |
| CN109074917B (en) | Method for forming transparent conductive pattern | |
| CN113501989B (en) | Transparent polyimide composite conductive film | |
| CN109337560B (en) | Thermosetting protective liquid for nano silver wire transparent conductive film and flexible transparent conductive film based on thermosetting protective liquid | |
| CN108977205B (en) | Special liquid crystal composition for handwriting board and flexible handwriting film based on special liquid crystal composition | |
| KR20130000803A (en) | Conducting ink composition for printing and manufacturing method of the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |