CN112545440A - Mouth mirror and preparation method thereof - Google Patents

Mouth mirror and preparation method thereof Download PDF

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Publication number
CN112545440A
CN112545440A CN202011388087.6A CN202011388087A CN112545440A CN 112545440 A CN112545440 A CN 112545440A CN 202011388087 A CN202011388087 A CN 202011388087A CN 112545440 A CN112545440 A CN 112545440A
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China
Prior art keywords
hydrophobic
substrate
stomatoscope
lens
etching
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CN202011388087.6A
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CN112545440B (en
Inventor
赵秉
曲磊
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BOE Technology Group Co Ltd
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BOE Technology Group Co Ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61BDIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B1/00Instruments for performing medical examinations of the interior of cavities or tubes of the body by visual or photographical inspection, e.g. endoscopes; Illuminating arrangements therefor
    • A61B1/24Instruments for performing medical examinations of the interior of cavities or tubes of the body by visual or photographical inspection, e.g. endoscopes; Illuminating arrangements therefor for the mouth, i.e. stomatoscopes, e.g. with tongue depressors; Instruments for opening or keeping open the mouth
    • A61B1/247Instruments for performing medical examinations of the interior of cavities or tubes of the body by visual or photographical inspection, e.g. endoscopes; Illuminating arrangements therefor for the mouth, i.e. stomatoscopes, e.g. with tongue depressors; Instruments for opening or keeping open the mouth with means for viewing areas outside the direct line of sight, e.g. dentists' mirrors
    • A61B1/253Instruments for performing medical examinations of the interior of cavities or tubes of the body by visual or photographical inspection, e.g. endoscopes; Illuminating arrangements therefor for the mouth, i.e. stomatoscopes, e.g. with tongue depressors; Instruments for opening or keeping open the mouth with means for viewing areas outside the direct line of sight, e.g. dentists' mirrors with means for preventing fogging

Abstract

The embodiment of the application provides a stomatoscope and a preparation method thereof, wherein an array consisting of a plurality of hydrophobic structures is arranged on the stomatoscope, the size of each first hydrophobic structure close to the first substrate part is smaller than the size of each first hydrophobic structure far away from the first substrate part, the whole structure is an inverted suspension structure, the inverted suspension structure can suspend liquid in the air, the contact angle between the liquid and the inverted suspension structure is increased, and the hydrophobic effect is achieved. Therefore, the oral lens can achieve the antifogging and hydrophobic effects through the first hydrophobic structure on the lens, and is low in cost, simple in structure and easy to use. And can disposable, avoid the disinfection procedure, avoided the mouth mirror to be difficult to disinfect completely and the bacterial infection problem that causes to can adjust the degree of defogging through the density degree that changes first hydrophobic structure array.

Description

Mouth mirror and preparation method thereof
Technical Field
The application relates to the field of medical instruments, in particular to a mouth mirror and a preparation method thereof.
Background
Many people have oral diseases, but when the oral diseases are treated, doctors cannot observe partial areas in the oral cavity easily, and the occurrence of the mouth mirror brings great convenience to examination and treatment in the oral cavity. With the help of the mouth mirror, doctors can clearly and intuitively find the focus in the oral cavity of a patient so as to take various corresponding treatment measures in time. However, the conventional stomatoscope lens is easy to fog or splash water when being put into the oral cavity, and in order to solve the technical problem, the stomatoscope needs to be subjected to antifogging and hydrophobizing treatment.
In the prior art, the defogging effect is poor and the material research and development cost is high due to the fact that the defogging is mostly carried out in a mode of coating on the surface of a lens; the stomatoscope adopting the defogging mode of adding the air source outside is difficult to disinfect and clean due to the hollow design of the handle and the repeated flow of the air in the oral cavity; and the temperature adjusting mode can introduce additional temperature control equipment, so that the structural space and the cost are increased.
Disclosure of Invention
The application aims at the defects of the prior art and provides a mouth mirror and a preparation method thereof, which are used for solving the technical problems of poor defogging effect, high research and development cost, difficulty in disinfection or high structural space cost and the like of the mouth mirror in the prior art.
In a first aspect, an embodiment of the present application provides a mouth mirror, including: a lens and a frame;
the lens includes: a first substrate and at least two first hydrophobic structures;
the backlight side of the first substrate is fixedly connected with the bracket;
the at least two first hydrophobic structures are arranged in an array and are connected with the light-facing side of the first substrate;
the dimension of the at least one first hydrophobic structure near the first substrate portion is smaller than the dimension of the first hydrophobic structure away from the first substrate portion.
In a second aspect, embodiments of the present application provide another stomatoscope, including: lenses, hydrophobic membranes and scaffolds;
the hydrophobic membrane includes: a second substrate and at least two second hydrophobic structures;
the at least two second hydrophobic structures are arranged in an array and are connected with one side of the second substrate;
the size of the at least one second hydrophobic structure close to the second substrate part is smaller than the size of the second hydrophobic structure far away from the first substrate part;
the other side of the second substrate is connected with the light-facing side of the lens;
the backlight side of the lens is fixedly connected with the bracket.
In a third aspect, an embodiment of the present application provides a method for preparing a mouth mirror, including:
depositing a first material layer on a substrate, and patterning the first material layer to obtain a first-state material structure;
carrying out first etching on at least part of the base material which is not covered with the first-state material structure, so that a first-state blind hole is formed in the base material;
depositing a second material layer on the first-state material structure, the substrate and the first-state blind holes, and patterning the second material layer to expose at least part of the substrate at the bottoms of the first-state blind holes to obtain a second-state material structure;
performing second etching on at least part of the first-state blind holes exposed out of the substrate, so that the first-state blind holes form second-state blind holes, and obtaining a first hydrophobic structure or a second hydrophobic structure; the second etching is wet etching.
The beneficial technological effect that a mouth mirror that this application embodiment provided brought includes: the array that has a plurality of hydrophobic structures to constitute on the mouth mirror lens, every first hydrophobic structure is less than the size that first hydrophobic structure kept away from first base portion near the size of first base portion, wholly is an underslung structure, and the underslung structure can make liquid unsettled, makes the contact angle increase of liquid and underslung structure, plays hydrophobic effect. Therefore, the oral lens can achieve the antifogging and hydrophobic effects through the first hydrophobic structure on the lens, and is low in cost, simple in structure and easy to use. And can disposable, avoid the disinfection procedure, avoided the mouth mirror to be difficult to disinfect completely and the bacterial infection problem that causes to can adjust the degree of defogging through the density degree that changes first hydrophobic structure array.
The beneficial technological effect that another kind of mouth mirror that this application embodiment provided brought includes: the hydrophobic membrane is provided with an array consisting of a plurality of second hydrophobic structures, the size of each second hydrophobic structure close to the second substrate part is smaller than the size of each second hydrophobic structure far away from the second substrate part, the whole structure is an inverted suspension structure, the inverted suspension structure can suspend liquid in the air, so that the contact angle of the liquid and the inverted suspension structure is increased, and the hydrophobic effect is achieved. Therefore, the hydrophobic film is attached to the lens, so that the mouth mirror can play the antifogging and hydrophobic effects when in use, and the mouth mirror is low in cost, simple in structure and easy to use. Because the hydrophobic membrane is attached to the lens, the used hydrophobic membrane is taken down after the stomatoscope is used, and the structure of the remaining stomatoscope is disinfected, so that the disinfection process is simplified. And the degree of defogging can be adjusted by changing the density degree of the second hydrophobic structure array.
The preparation method of the mouth mirror provided by the embodiment of the application brings beneficial technical effects that: by changing the base material, the hydrophobic film or the hydrophobic lens can be prepared by using the same set of preparation method, the method is suitable for two different stomatoscopes, the application scenes of the hydrophobic structure are enlarged, the cost is low, and the prepared hydrophobic film and the prepared hydrophobic lens have good antifogging and hydrophobic effects.
Additional aspects and advantages of the present application will be set forth in part in the description which follows and, in part, will be obvious from the description, or may be learned by practice of the present application.
Drawings
The foregoing and/or additional aspects and advantages of the present application will become apparent and readily appreciated from the following description of the embodiments, taken in conjunction with the accompanying drawings of which:
FIG. 1 is a schematic structural view of a mouth mirror provided in an embodiment of the present application;
FIG. 2 is a schematic cross-sectional structure diagram of a first implementation method of a first hydrophobic structure provided in an embodiment of the present application;
fig. 3 is a schematic cross-sectional structure diagram of a second implementation method of a first hydrophobic structure provided in an embodiment of the present application;
fig. 4 is a schematic cross-sectional structure diagram of a third implementation method of the first hydrophobic structure provided in the examples of the present application;
FIG. 5 is a schematic structural view of another stomatoscope provided by the embodiment of the application;
FIG. 6 is a schematic cross-sectional structure of a method of implementing a second hydrophobic structure provided in an example herein;
FIG. 7 is a schematic flow chart of a method for manufacturing a mouth mirror according to an embodiment of the present disclosure;
fig. 8 is a schematic structural diagram of a method for manufacturing a mouth mirror according to an embodiment of the present application, in which a first material layer is deposited on a substrate and patterned to obtain a first-state material structure.
Fig. 9 is a schematic structural diagram of a stomatoscope according to an embodiment of the present application after at least a portion of a substrate not covered with a first-state material structure is subjected to a first etching process, so that a first-state blind hole is formed in the substrate.
Fig. 10 is a schematic structural diagram of a stomatoscope according to an embodiment of the present application after depositing a second material layer on the first-state material structure, on the substrate, and in the first-state blind holes.
Fig. 11 is a schematic structural diagram of a method for manufacturing a mouth mirror according to an embodiment of the present application, in which a second material layer is patterned to expose at least a portion of a substrate at the bottom of a first-state blind via, and a second-state material structure is obtained.
Fig. 12 is a schematic structural diagram of a method for manufacturing a mouth mirror according to an embodiment of the present application, in which at least a portion of first-state blind holes exposed on a substrate is etched for a second time, so that second-state blind holes are formed in the first-state blind holes, and a first hydrophobic structure or a second hydrophobic structure is obtained.
In the figure:
1-a mouth mirror;
11 a lens; 12 a hydrophobic membrane; 13-a scaffold;
110-a first substrate;
111-a first hydrophobic structure; 112-a first cylinder; 113-a first cover; 1131 — first top; 1132 — a first extension;
120-a second substrate;
121-a second hydrophobic structure; 122-a second cylinder; 123-a second cover body; 1231-second top; 1232-a second stretch;
2-a substrate; 21-first state blind hole; 22-second state blind hole;
3-a first material layer; 31-first state material structure;
4-a second material layer; 41-second-state material structure.
Detailed Description
Reference will now be made in detail to the present application, examples of which are illustrated in the accompanying drawings, wherein like reference numerals refer to the same or similar parts or parts having the same or similar functions throughout. In addition, if a detailed description of the known art is not necessary for illustrating the features of the present application, it is omitted. The embodiments described below with reference to the drawings are exemplary only for the purpose of explaining the present application and are not to be construed as limiting the present application.
It will be understood by those within the art that, unless otherwise defined, all terms (including technical and scientific terms) used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this application belongs. It will be further understood that terms, such as those defined in commonly used dictionaries, should be interpreted as having a meaning that is consistent with their meaning in the context of the prior art and will not be interpreted in an idealized or overly formal sense unless expressly so defined herein.
As used herein, the singular forms "a", "an", "the" and "the" are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the terms "comprises" and/or "comprising," when used in this specification, specify the presence of stated features, integers, steps, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, and/or groups thereof. As used herein, the term "and/or" includes all or any element and all combinations of one or more of the associated listed items.
The terms referred to in this application will first be introduced and explained:
the light-facing side: refers to the front side of the mirror, i.e. the side of the mirror that is capable of reflecting light.
Backlight side: refers to the back of the mirror, i.e. the side of the mirror that is not transparent to light.
The inventor of the application researches and discovers that the stomatoscope cannot avoid not contacting water in the using process, in order to normally observe the oral cavity of a patient through the lens in the using process, the defogging effect is poor and the material research and development cost is high mostly through a mode of coating on the surface of the lens; the stomatoscope using the mode of adding the air source externally has simple structure, but the stomatoscope is difficult to disinfect and clean due to the hollow design of the handle and the repeated flow of the air through the oral cavity; the temperature regulation mode can introduce additional temperature control equipment, and the structure space and the cost are increased.
The application provides a mouth mirror and a preparation method thereof, which aim to solve the technical problems in the prior art.
The following describes the technical solutions of the present application and how to solve the above technical problems with specific embodiments.
The embodiment of the application provides a mouth mirror 1, include: a lens 11 and a holder 13.
The lens 11 includes: a first substrate 110 and at least two first hydrophobic structures 111.
The backlight side of the first substrate 110 is fixedly connected to the bracket 13.
At least the first hydrophobic structures 111 are arranged in an array and are all connected with the light-facing side of the first substrate 110.
A size of a portion of the at least one first hydrophobic structure 111 close to the first substrate 110 is smaller than a size of a portion of the first hydrophobic structure 111 far from the first substrate 110.
The inventor of the application researches and discovers that in order to enable the mouth mirror 1 to have the defogging and dewatering effects, the lens 11 of the mouth mirror 1 can be treated, and the lens 11 can be in contact with water but can not leave water stains. The suspension structure can suspend liquid in the air, so that the contact angle between the liquid and the suspension structure is increased, and the hydrophobic effect is achieved.
In this embodiment, the first hydrophobic structure 111 on the lens 11 enables the lens 11 of the mouth mirror 1 to achieve the antifogging and hydrophobic effects, the cost is low, the whole structure of the mouth mirror 1 is simple, the use is easy, a temperature control device with large occupied space is not needed, and the macro structure is as shown in fig. 1.
Optionally, the mouth mirror 1 provided by the embodiment can be used for one time, so that a disinfection procedure is omitted, and the problem of bacterial infection caused by difficulty in complete disinfection of the mouth mirror 1 is avoided. And the degree of the defogging effect can be adjusted by changing the density of the first hydrophobic structures 111.
Optionally, the bracket 13 may be made of a plastic material, so that the mouth mirror 1 is disposable, and cost is saved.
The inventors of the present application consider that when a liquid is in contact with the surface of an object, a contact angle is generated, and when the contact angle is less than 90 °, we consider it hydrophilic; less than 5 ° we consider superhydrophilic; when the contact angle is greater than 90 °, we consider the surface hydrophobic; especially when the surface contact angle is greater than 150 °, it is called superhydrophobic. To obtain the defogging effect, the super first hydrophobic structure 111 needs to be designed. The suspended microstructure can ensure that liquid is suspended, so that the contact angle between the liquid and the microstructure is increased, and the hydrophobic effect is obtained. Therefore, the application provides the following possible implementation manner for the lens 11 of the mouth mirror 1:
as shown in fig. 3, the first hydrophobic structure 111 of the lens 11 of the embodiment of the present application includes: a first cylinder 112 and a first cover 113.
One end of the first pillar 112 is connected to the light-facing side of the first base 110, and the other end is connected to the first cover 113.
The radial dimension of the first cap 113 is at least greater than the radial dimension of the other end of the first cylinder 112.
In this embodiment, the first hydrophobic structure 111 on the light-facing side of the lens 11 includes a first cylinder 112 and a first cover 113, a radial dimension of the first cover 113 may be larger than a radial dimension of the first cylinder 112, the first cylinder 112 is located between the first substrate 110 of the lens 11 and the first cover 113 of the first hydrophobic structure 111, and the first cover 113 is an overhanging structure with respect to the first substrate 110, and may have a hydrophobic effect. Namely, the mouth mirror 1 achieves the effect of defogging and dewatering in use by using the lens 11 with the dewatering effect. The present application provides several implementations of the first hydrophobic structure 111:
in one embodiment, the first cover 113 includes: a first top portion 1131 and a first extension 1132.
The first top 1131 is connected to the other end of the first cylinder 112, and the radial dimension of the first top 1131 is at least larger than the radial dimension of the other end of the first cylinder 112.
The first extension 1132 is connected to an edge of the first top 1131, and the first extension 1132 extends toward the first substrate 110.
In the present embodiment, in order to develop a hydrophobic surface with high contact angle, low adhesion, and low flow resistance suitable for various liquids, the first cover 113 of the first hydrophobic structure 111 is made to include a first top 1131 and a first extension 1132. Through the design of the first extension 1132, the first cover 113 is covered on the first cylinder 112 like a cap, and the first hydrophobic structure 111 is more delicate, so that the low surface energy liquid (i.e. the liquid that is difficult to adhere) can be effectively suspended without contacting the first substrate 110, and the lens 11 itself achieves the effect of defogging and hydrophobicity, as shown in fig. 2.
Optionally, the ratio between the size of the first cover 113 of at least one first hydrophobic structure 111 and the distance between two adjacent first hydrophobic structures 111 is not less than 1:2 and not more than 3: 5.
The inventor of the present application has found that, in order to achieve a better hydrophobic effect, the ratio of the size of the first cover 113 of the first hydrophobic structure 111 to the distance between two adjacent first hydrophobic structures 111 is 3: 5.
Optionally, the ratio of the size of the first cover 113 of the first hydrophobic structure 111 to the distance between two adjacent first hydrophobic structures 111 is 1:2, which may also play a role in hydrophobic.
In the second implementation method, the radial dimension of the end of the first hydrophobic structure 111 close to the light-facing side is smaller than the radial dimension of the end far away from the light-facing side.
In the present embodiment, by providing different radial sizes of the two ends of the first hydrophobic structure 111, a plurality of kinds of overhanging structures capable of hydrophobic property, such as an inverted trapezoid, a lower semicircle, etc., are provided, please refer to fig. 3, but the present invention is not limited to the shapes provided in the figure, and irregular shapes according to the present embodiment are also included.
In the third embodiment, the radial dimension of the end of the first hydrophobic structure 111 close to the light-facing side and the radial dimension of the end far from the light-facing side are both smaller than the radial dimension of the middle portion of the first hydrophobic structure 111.
While the foregoing analysis has mentioned that the overhang structure can achieve a good hydrophobic effect, this embodiment provides a structure that can also increase the contact angle of the liquid with the surface to achieve a hydrophobic effect. Referring to fig. 4, such a structure with two small ends and a large middle can also suspend liquid, thereby achieving the hydrophobic effect.
Based on the same inventive concept, the present application provides another stomatoscope 1, comprising: a lens 11, a hydrophobic membrane 12 and a support 13.
The hydrophobic membrane 12 includes: a second substrate 120 and at least two second hydrophobic structures 121.
At least two second hydrophobic structures 121 are arranged in an array, and are connected to one side of the second substrate 120.
The dimension of the portion of the at least one second hydrophobic structure 121 close to the second substrate 120 is smaller than the dimension of the portion of the overhanging structure away from the first substrate 110.
The other side of the second substrate 120 is connected to the light-facing side of the lens 11.
The backlight side of the lens 11 is fixedly connected to the holder 13.
In order to disinfect the mouth mirror 1 easily, and make convenient lens 11 and support 13 reuse of disinfecting, this embodiment provides a hydrophobic membrane 12, and hydrophobic membrane 12 itself can play the hydrophobic effect of defogging, again with hydrophobic membrane 12 and the laminating of ordinary lens 11, and hydrophobic membrane 12 uses transparent material to make, then can make ordinary lens 11 defogging hydrophobic and can see the inside mirror image in oral cavity clearly under the cooperation of transparent hydrophobic membrane 12.
In this embodiment, please refer to fig. 5 for the macro structure of the mouth mirror 1, the light-facing side of the lens 11 itself is attached with the hydrophobic film 12, so that the mouth mirror 1 can have the antifogging and hydrophobic effects while being used, and has the advantages of low cost, simple structure and easy use. Because the hydrophobic membrane 12 is attached to the lens 11, the hydrophobic membrane 12 is taken down after the mouth mirror 1 is used, and the rest structure of the mouth mirror 1 is disinfected, so that the disinfection process is simplified. And the degree of defogging can be adjusted by the density of the array of the second hydrophobic structures 121.
Optionally, the other side of the second substrate 120 is connected to the light-facing side of the lens 11, the hydrophobic film 12 and the lens 11 may be bonded in an oxygen ion bonding manner, after use, the stomatoscope 1 is placed into an oxygen plasma machine to be released from bonding, the hydrophobic film 12 is used for one time, and the bonding-released stomatoscope 1 can be directly sterilized by alcohol or by high temperature.
Alternatively, the hydrophobic film 12 may be made of glass or a flexible transparent film.
In one possible embodiment, the material of the hydrophobic membrane 12 is glass, and the size of the hydrophobic membrane 12 is comparable to the size of existing stomatoscope lenses. The material of the stomatoscope handle can be stainless steel. Hydrophobic membrane 12 may be a disposable material and the rest of the stomatoscope may be recycled. When the hydrophobic membrane 12 is needed to be used, the hydrophobic membrane 12 and the mouth mirror without the hydrophobic membrane 12 are placed into an oxygen plasma machine, and then the hydrophobic membrane 12 and the mouth mirror lens are pressed and bonded to obtain the mouth mirror with the hydrophobic membrane 12. When the lens is used, the hydrophobic membrane and the lens are only needed to be bonded, wherein the bonding can be achieved through heating, blowing and the like. The hydrophobic membrane 12 can be directly discarded as a disposable material, and then the stomatoscope body is sterilized, so that the operation is convenient, the cost is low, and the defogging effect of the stomatoscope can be realized without complicated structural improvement.
Optionally, the support 13 of the stomatoscope 1 is made of stainless steel material to improve the reuse rate.
In one possible embodiment, the second hydrophobic structure 121 comprises: a second post 122 and a second cover 123.
One end of the second pillar 122 is connected to one side of the second substrate 120, and the other end is connected to the second cover 123.
The radial dimension of the second cap 123 is at least larger than the radial dimension of the other end of the second cylinder 122. The specific implementation method can be seen in fig. 6.
In a possible embodiment, the second cover 123 comprises: a second top 1231 and a second extension 1232.
The second top 1231 is connected to the other end of the second cylinder 122, and the radial dimension of the second top 1231 is at least greater than the radial dimension of the other end of the second cylinder 122.
The second extension 1232 is connected to an edge of the second top 1231, and the second extension 1232 extends toward the second base 120.
In a possible embodiment, the ratio between the size of the second cover 123 of at least one second hydrophobic structure 121 and the distance between two adjacent second hydrophobic structures 121 is not less than 1:2 and not more than 3: 5.
The second hydrophobic structure 121 in the above embodiments is the same as the first hydrophobic structure 111 of the lens 11 in the previous embodiments, and is not described herein again.
The second hydrophobic structure 121 provided in the foregoing embodiment can make the lens 11 or the hydrophobic membrane 12 have the effect of defogging and hydrophobicity, and this embodiment provides a method for manufacturing the mouth mirror 1 to manufacture the hydrophobic lens 11 or the hydrophobic membrane 12.
Based on the same inventive concept, the present application provides a method for manufacturing a mouth mirror 1, as shown in fig. 7, comprising steps S1-S4:
s1, depositing the first material layer 3 on the substrate 2, and patterning the first material layer 3 to obtain the first-state material structure 31.
Alternatively, the substrate 2 is glass. Since the hydrophobic film 12 and the lens 11 both have hydrophobic structures, a set of manufacturing methods can be used to obtain the lens 11 or the hydrophobic film 12 having hydrophobic structures by changing the substrate 2. The substrate 2 can be made of different materials according to the actual situation of the hydrophobic lens 11 or the hydrophobic membrane 12. For example, the glass with a metal reflective film plated on one side can be used as the substrate 2 for preparing the lens 11, and the transparent glass can be used for preparing the hydrophobic film 12.
In this step, the first material layer 3 is a material for preparing the first top 1131 of the first hydrophobic structure 111 or the second top 1231 of the second hydrophobic structure 121, the step is an initial state before etching, the substrate 2 is selected, and etching is performed to prepare for obtaining the first hydrophobic structure 111 or the second hydrophobic structure 121, and the structure obtained after step S1 is shown in fig. 8.
And S2, performing first etching on at least a part of the substrate 2 not covered with the first-state material structure 31, so that the substrate 2 forms a first-state blind hole 21.
In the present embodiment, after the first material layer 3 is patterned, some gaps are formed to expose a portion of the substrate 2. At least a portion of the substrate 2 not covered by the first-state material structure 31 is subjected to a first etching process, so that the substrate 2 forms a first-state blind via 21. The remaining first material layer 3, i.e. the first-state material structure 31, is used as the first top 1131 of the first hydrophobic structure 111 or the second top 1231 of the second hydrophobic structure 121, and the structure obtained after the step S2 is shown in fig. 9.
Alternatively, the etching method may include, but is not limited to, dry etching and wet etching. The dry etching includes light volatilization, gas phase etching, plasma etching and the like. Wet etching is a pure chemical reaction process, which means that chemical reaction between solution and pre-etching material is used to remove the part not masked by the masking film material for etching purpose. Because wet etching may etch away a little part of the substrate 2 masked by the masking film, if dry etching is adopted for the first etching, the thickness of the second etching is smaller than that of the first etching; if the first etching is wet etching, the thickness of the second etching may be equal to that of the first etching.
S3, depositing a second material layer 4 on the first-state material structure 31, on the substrate 2 and in the first-state blind via 21, and patterning the second material layer 4 to expose at least a portion of the substrate 2 at the bottom of the first-state blind via 21, and obtaining a second-state material structure 41.
In this step, a second material layer 4 is deposited on the second-state material structure 41 obtained in step S2, please refer to fig. 10. And patterning the second material layer 4 until at least a portion of the substrate 2 at the bottom of the first-state blind via 21 is exposed, and obtaining a second-state material structure 41, see fig. 11.
Alternatively, when the second etch completely etches away the corresponding second material layer 4 on the first-state material structure 31, the second-state material structure 41 may include the first-state material structure 31 and the second material layer 4 perpendicular to the first-state material structure 31.
Alternatively, when the second etch completely etches away the corresponding second material layer 4 on the first-state material structure 31 and etches part of the first-state material structure 31, the second-state material structure 41 may include part of the first-state material structure 31 and the second material layer 4 perpendicular to the first-state material structure 31.
Optionally, when the second etching is performed to etch only the second material layer 4 corresponding to the first-state blind hole 21 without etching the corresponding second material layer 4 on the first-state material structure 31, the second-state material structure 41 may include the first-state material structure 31, the second material layer 4 covering the first-state material structure 31, and the second material layer 4 perpendicular to the first-state material structure 31.
Alternatively, when the second etching etches the corresponding second material layer 4 on the first-state material structure 31 partially, the second-state material structure 41 may include the first-state material structure 31, a portion of the second material layer 4 covering the first-state material structure 31, and the second material layer 4 perpendicular to the first-state material structure 31.
This step is to prepare the first extension 1132 or the third extension 1232, and the structure obtained after the step S3 is shown in fig. 10.
And S4, performing second etching on at least part of the first-state blind holes 21 exposed on the substrate 2 to form second-state blind holes 22 in the first-state blind holes 21, and obtaining the first hydrophobic structure 111 or the second hydrophobic structure 121. The second etching is wet etching.
In this step, at least a portion of the first-state blind via 21 exposed in the substrate 2 obtained in step S3 is subjected to second etching, so that the second-state blind via 22 is formed in the first-state blind via 21, and the first hydrophobic structure 111 or the second hydrophobic structure 121 is obtained. Since the etching is not one-direction etching, the etching needs to be performed in two directions, namely, vertical and horizontal directions, and the second etching is wet etching.
In one possible embodiment, the depth of the first etching is less than the depth of the second etching.
Specifically, the first etching is to prepare the first extension 1132 or the third extension 1232, and the etching depth of the second etching needs to be greater than the first etching depth so as to penetrate the depth of the first extension 1132, thereby etching the substrate 2.
By applying the embodiment of the application, at least the following beneficial effects can be realized:
1. by preparing the lens 11 with the first hydrophobic structure 111, the lens 11 has the defogging hydrophobic effect, and is simple in structure, easy to operate and use, low in space cost and capable of being produced in a large scale. Disposable, avoid the difficult sterile problem of lens 11.
2. The hydrophobic membrane 12 with the second hydrophobic structure 121 is connected with the lens 11, so that the lens 11 achieves the defogging and hydrophobic effects, and the lens is simple in structure, easy to operate and use, low in space cost and capable of being produced in a large scale. The hydrophobic membrane 12 is disposable, the problem that a hydrophobic structure is difficult to disinfect is solved away, and the stomatoscope 1 with the hydrophobic membrane 12 is directly disinfected in the later stage.
3. The defogging performance is adjusted by adjusting the density degree of the microarrays with a plurality of hydrophobic structures, so that the method is suitable for various application scenes.
Those of skill in the art will appreciate that the various operations, methods, steps in the processes, acts, or solutions discussed in this application can be interchanged, modified, combined, or eliminated. Further, other steps, measures, or schemes in various operations, methods, or flows that have been discussed in this application can be alternated, altered, rearranged, broken down, combined, or deleted. Further, steps, measures, schemes in the prior art having various operations, methods, procedures disclosed in the present application may also be alternated, modified, rearranged, decomposed, combined, or deleted.
In the description of the present application, it is to be understood that the terms "center", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outer", and the like indicate orientations or positional relationships based on those shown in the drawings, and are only for convenience in describing the present application and simplifying the description, but do not indicate or imply that the referred device or element must have a particular orientation, be constructed in a particular orientation, and be operated, and thus should not be construed as limiting the present application.
The terms "first", "second" and "first" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defined as "first" or "second" may explicitly or implicitly include one or more of that feature. In the description of the present application, "a plurality" means two or more unless otherwise specified.
In the description of the present application, it is to be noted that, unless otherwise explicitly specified or limited, the terms "mounted," "connected," and "connected" are to be construed broadly, e.g., as meaning either a fixed connection, a removable connection, or an integral connection; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meaning of the above terms in the present application can be understood in a specific case by those of ordinary skill in the art.
In the description herein, particular features, structures, materials, or characteristics may be combined in any suitable manner in any one or more embodiments or examples.
It should be understood that, although the steps in the flowcharts of the figures are shown in order as indicated by the arrows, the steps are not necessarily performed in order as indicated by the arrows. The steps are not performed in the exact order shown and may be performed in other orders unless explicitly stated herein. Moreover, at least a portion of the steps in the flow chart of the figure may include multiple sub-steps or multiple stages, which are not necessarily performed at the same time, but may be performed at different times, which are not necessarily performed in sequence, but may be performed alternately or alternately with other steps or at least a portion of the sub-steps or stages of other steps.
The foregoing is only a partial embodiment of the present application, and it should be noted that, for those skilled in the art, several modifications and decorations can be made without departing from the principle of the present application, and these modifications and decorations should also be regarded as the protection scope of the present application.

Claims (12)

1. A mouth mirror, comprising: a lens and a frame;
the lens includes: a first substrate and at least two first hydrophobic structures;
the backlight side of the first substrate is fixedly connected with the bracket;
at least two first hydrophobic structures are arranged in an array and are connected with the light-facing side of the first substrate;
at least one of the first hydrophobic structures has a dimension proximate to the first substrate portion that is smaller than a dimension of the first hydrophobic structure distal to the first substrate portion.
2. The stomatoscope of claim 1, wherein the first hydrophobic structure comprises: a first column and a first cover;
one end of the first column is connected with the light-facing side of the first substrate, and the other end of the first column is connected with the first cover body;
the radial dimension of the first cover body is at least larger than that of the other end of the first column body.
3. The stomatoscope of claim 2, wherein the first cover comprises: a first top portion and a first extension;
the first top is connected with the other end of the first column, and the radial dimension of the first top is at least larger than that of the other end of the first column;
the first extension is connected with an edge of the first top, and the first extension extends toward the first base.
4. The stomatoscope of any one of claims 2-3, wherein the ratio of the size of the first cover of at least one first hydrophobic structure to the distance between two adjacent first hydrophobic structures is not less than 1:2 and not more than 3: 5.
5. The stomatoscope of claim 1, wherein the first hydrophobic structure has a smaller radial dimension at an end proximal to the light-facing side than at an end distal to the light-facing side.
6. The stomatoscope of claim 1, wherein the first hydrophobic structure has a radial dimension at an end near the light-facing side and a radial dimension at an end far from the light-facing side that are smaller than the radial dimension of the middle portion of the first hydrophobic structure.
7. A mouth mirror, comprising: lenses, hydrophobic membranes and scaffolds;
the hydrophobic membrane includes: a second substrate and at least two second hydrophobic structures;
at least two second hydrophobic structures are arranged in an array and are connected with one side of the second substrate;
at least one of the second hydrophobic structures has a dimension closer to the second substrate portion smaller than a dimension of the second hydrophobic structure farther from the second substrate portion;
the other side of the second substrate is connected with the light-facing side of the lens;
the backlight side of the lens is fixedly connected with the bracket.
8. The stomatoscope of claim 7, wherein the second hydrophobic structure comprises: a second column and a second cover;
one end of the second column is connected with one side of the second substrate, and the other end of the second column is connected with the second cover body;
the radial dimension of the second cover body is at least larger than that of the other end of the second cylinder body.
9. The stomatoscope of claim 8, wherein the second cover comprises: a second top portion and a second extension;
the second top part is connected with the other end of the second cylinder, and the radial size of the second top part is at least larger than that of the other end of the second cylinder;
the second extension is connected to an edge of the second top, and the second extension extends toward the second base.
10. The stomatoscope of any one of claims 8-9, wherein the ratio of the size of the second cover of at least one second hydrophobic structure to the distance between two adjacent second hydrophobic structures is not less than 1:2 and not more than 3: 5.
11. A preparation method of a mouth mirror is characterized by comprising the following steps:
depositing a first material layer on a substrate, and patterning the first material layer to obtain a first-state material structure;
carrying out first etching on at least part of the base material which is not covered with the first-state material structure, so that a first-state blind hole is formed in the base material;
depositing a second material layer on the first-state material structure, the substrate and the first-state blind holes, patterning the second material layer to expose at least part of the substrate at the bottoms of the first-state blind holes, and obtaining a second-state material structure;
performing second etching on at least part of the first-state blind holes exposed out of the substrate, so that the first-state blind holes form second-state blind holes, and a first hydrophobic structure or a second hydrophobic structure is obtained; the second etching is wet etching.
12. The method for preparing a mouth mirror as claimed in claim 11, wherein the depth of the first etching is less than the depth of the second etching.
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CN102525389A (en) * 2011-11-30 2012-07-04 复旦大学 Anti-mist mouth mirror
CN104015431A (en) * 2014-06-20 2014-09-03 苏州苏大维格光电科技股份有限公司 Protective glass with nanometer self-cleaning and active antifogging functions and preparation method of protective glass
CN104470712A (en) * 2013-03-14 2015-03-25 Sdc科技有限公司 Anti-fog nanotextured surfaces and articles containing the same
CN204293123U (en) * 2014-12-02 2015-04-29 天津市双利医疗器械有限责任公司 A kind of Novel dental mirror
CN109957345A (en) * 2017-12-26 2019-07-02 清华大学 Hydrophobic membrane
CN109959980A (en) * 2017-12-26 2019-07-02 清华大学 Hydrophobic mirror and the automobile for using the hydrophobic mirror
US20200131083A1 (en) * 2017-06-21 2020-04-30 Nikon Corporation Nanostructured Transparent Article with Both Hydrophobic and Antifog Properties and Methods for Making It
JP2020106752A (en) * 2018-12-28 2020-07-09 ホヤ レンズ タイランド リミテッドHOYA Lens Thailand Ltd Spectacle lens
CN213517624U (en) * 2020-11-13 2021-06-22 中山市骏锐光学器材科技有限公司 Hydrophobic stain-resistant lens

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102525389A (en) * 2011-11-30 2012-07-04 复旦大学 Anti-mist mouth mirror
CN104470712A (en) * 2013-03-14 2015-03-25 Sdc科技有限公司 Anti-fog nanotextured surfaces and articles containing the same
CN104015431A (en) * 2014-06-20 2014-09-03 苏州苏大维格光电科技股份有限公司 Protective glass with nanometer self-cleaning and active antifogging functions and preparation method of protective glass
CN204293123U (en) * 2014-12-02 2015-04-29 天津市双利医疗器械有限责任公司 A kind of Novel dental mirror
US20200131083A1 (en) * 2017-06-21 2020-04-30 Nikon Corporation Nanostructured Transparent Article with Both Hydrophobic and Antifog Properties and Methods for Making It
CN109957345A (en) * 2017-12-26 2019-07-02 清华大学 Hydrophobic membrane
CN109959980A (en) * 2017-12-26 2019-07-02 清华大学 Hydrophobic mirror and the automobile for using the hydrophobic mirror
JP2020106752A (en) * 2018-12-28 2020-07-09 ホヤ レンズ タイランド リミテッドHOYA Lens Thailand Ltd Spectacle lens
CN213517624U (en) * 2020-11-13 2021-06-22 中山市骏锐光学器材科技有限公司 Hydrophobic stain-resistant lens

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