CN1125247A - Snow-removing ice-melting agent - Google Patents
Snow-removing ice-melting agent Download PDFInfo
- Publication number
- CN1125247A CN1125247A CN 94112694 CN94112694A CN1125247A CN 1125247 A CN1125247 A CN 1125247A CN 94112694 CN94112694 CN 94112694 CN 94112694 A CN94112694 A CN 94112694A CN 1125247 A CN1125247 A CN 1125247A
- Authority
- CN
- China
- Prior art keywords
- snow
- agent
- parts
- chloride
- ice
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002844 melting Methods 0.000 title description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 32
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims abstract description 26
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 13
- 239000001110 calcium chloride Substances 0.000 claims abstract description 13
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 13
- 229910001629 magnesium chloride Inorganic materials 0.000 claims abstract description 13
- 150000003839 salts Chemical group 0.000 claims abstract description 9
- 239000000126 substance Substances 0.000 claims abstract description 4
- 239000003513 alkali Substances 0.000 claims abstract description 3
- 239000000843 powder Substances 0.000 claims abstract description 3
- 239000013535 sea water Substances 0.000 claims abstract description 3
- 238000010257 thawing Methods 0.000 claims description 14
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 claims description 9
- 239000004615 ingredient Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- 239000011592 zinc chloride Substances 0.000 claims description 2
- 235000005074 zinc chloride Nutrition 0.000 claims description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 4
- 239000011780 sodium chloride Substances 0.000 abstract description 4
- 238000002156 mixing Methods 0.000 abstract description 3
- 241001131796 Botaurus stellaris Species 0.000 abstract 1
- 235000019738 Limestone Nutrition 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 239000006028 limestone Substances 0.000 abstract 1
- 235000002639 sodium chloride Nutrition 0.000 description 7
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- ICLYJLBTOGPLMC-KVVVOXFISA-N (z)-octadec-9-enoate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCC\C=C/CCCCCCCC(O)=O ICLYJLBTOGPLMC-KVVVOXFISA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000881 depressing effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229940117013 triethanolamine oleate Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Abstract
A snow-removing deicing agent is prepared by mixing calcium chloride, which is the by-product of producing alkali by using seawater and limestone, and bittern powder, which contains magnesium chloride as main component, with salt residue or high-low temperature salt as main component, wherein the calcium chloride is 1-4 parts, the magnesium chloride is 1-3 parts, the sodium chloride is 5-50 parts, and the contents of the calcium chloride, the magnesium chloride and the sodium chloride are calculated according to pure substances. Its advantages are low cost, high snow dissolving effect, and high utilization rate of snow-removing agent (1/2-1/5 of that of existing agent).
Description
The present invention is a kind of snow-removing and ice-thawing agent that is used for municipal highway, bridge snow-removing and ice-thawing.
Using the snow-melting agent snow removing is the widely used technology of modern city, not only can improve snow removing efficient but also can save manpower with its snow removing, but its major ingredient of snow-melting agent mostly is sea salt at present, this snow-melting agent defrost weak effect, only suit under subzero 15 ℃-subzero 17 ℃ of conditions, to use, as be lower than said temperature and just be difficult to use, this also is the major cause of severe cold areas without snow-melting agent, because the snow-melting agent major ingredient is a sea salt, cost is higher, and under the bigger situation of year sprinkling amount, fund input is surprising, just used 252570 tons of salt in 1 year as Wisconsin, USA, 552570 tons of salt have then been used in the Bin Xiniya state.Also have the salt of employing to add the snow-melting agent that the sand prescription is made, just use this kind snow-melting agent as Los Angeles, USA city, Chicago city, the disadvantage of this snow-melting agent is that the easily stifled outfall sewer that stagnates of sand is logical, the clear very difficulty of washing in a pan.In addition, existing snow-melting agent does not all contain covering agent, to bridge and vehicular traffic seriously corroded.
At the deficiency that above-mentioned prior art exists, it is low to the purpose of this invention is to provide a kind of cost, the few and snow-removing and ice-thawing agent that can use at severe cold areas of consumption.
The object of the present invention is achieved like this: it is that the halogen powder of magnesium chloride and salt quarrel that major ingredient is sodium-chlor or high and tow temperature salt are mixed by pay product calcium chloride and the major ingredient of producing alkali with seawater and Wingdale, wherein, calcium chloride is 1-4 parts, 1-3 parts in magnesium chloride, 5-50 parts in sodium-chlor, the content of above-mentioned calcium chloride, magnesium chloride and sodium-chlor is all by pure substance.
In order to make this snow-removing and ice-thawing agent be reduced to minimum level to the corrosion of bridge and vehicular traffic, in above-mentioned prescription, also can add micro-covering agent, this covering agent is a metal rust preventing water.
The invention has the advantages that: 1, raw material sources are extensive, and price is low, so its cost is corresponding lower; 2, owing to contain the magnesium chloride of the very strong calcium chloride of pour-point depressing process and the pour point depression moisture absorption effect of prewetting in the prescription, so its defrost is effective, can use being lower than under the subzero 20 ℃ condition, suitable severe cold areas snow-removing and ice-thawing, usage quantity is to have 1/2-1/5 of snow-melting agent now; 3, water-insoluble can prevent that less water drain is stifled stagnant; 4, the corrosion to bridge and vehicular traffic can be reduced to minimum level.
Below in conjunction with embodiment the present invention is specified.
This snow-removing and ice-thawing agent uses according to condition of different temperatures can be divided into two kinds of models.
First kind of model I type: temperature is used 1 part in calcium chloride, 1 part in magnesium chloride, 20-50 parts in sodium-chlor subzero more than 17 ℃.This snow-removing and ice-thawing agent is made grain.
Second kind of model II type: temperature subzero 17 ℃ with down to subzero 30 ℃ of uses, 3 parts in calcium chloride, 2 parts in magnesium chloride, 6-20 parts in sodium-chlor, this kind snow-removing and ice-thawing agent is made grain.
All can add the thousandth that accounts for total amount in the snow-removing and ice-thawing agent of above-mentioned two kinds of models to centesimal metal rust preventing water, i.e. urotropine and triethanolamine oleate.
In order further to improve the defrost effect, in above-mentioned prescription, also can add 1-4 parts zinc chloride.Making it still can defrost under subzero 40 ℃ of conditions.
Production technique of the present invention is as follows:
One, supplied materials analysis is measured the content of calcium chloride, magnesium chloride, sodium-chlor with general chemical process, is converted into each material component in the prescription by pure substance.
Two, 20 orders of pulverizing, sieve are following to get final product.
Three, weighing is put into the drum mixer mixing by ratio of components.
Four, spray adds covering agent, and mixing stirring is above-mentioned two times, makes its film degree attenuation become even.
Five, packing packs the above-mentioned mixed snow-removing and ice-thawing agent that gets or the special-purpose snow-eliminating agent spraying car of packing into.
Claims (3)
1, a kind of snow-removing and ice-thawing agent, it is characterized in that, pay product calcium chloride and major ingredient that it produces alkali by seawater and Wingdale are that the halogen powder major ingredient of magnesium chloride is that salt quarrel of sodium-chlor or high and tow temperature salt are mixed, wherein, calcium chloride is 1-4 parts, 1-3 parts in magnesium chloride, 5-50 parts in sodium-chlor, the content of above-mentioned calcium chloride, magnesium chloride and sodium-chlor is all by pure substance.
2, snow-removing and ice-thawing agent as claimed in claim 1 is characterized in that also adding micro-covering agent in above-mentioned prescription, and this covering agent is a metal rust preventing water.
3, ask 1 described snow-removing and ice-thawing agent as right, it is characterized in that in above-mentioned prescription, also can adding 1-4 parts of zinc chloride.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 94112694 CN1125247A (en) | 1994-12-20 | 1994-12-20 | Snow-removing ice-melting agent |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 94112694 CN1125247A (en) | 1994-12-20 | 1994-12-20 | Snow-removing ice-melting agent |
Publications (1)
Publication Number | Publication Date |
---|---|
CN1125247A true CN1125247A (en) | 1996-06-26 |
Family
ID=5036365
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 94112694 Pending CN1125247A (en) | 1994-12-20 | 1994-12-20 | Snow-removing ice-melting agent |
Country Status (1)
Country | Link |
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CN (1) | CN1125247A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003042323A1 (en) * | 2001-11-13 | 2003-05-22 | Tianjinshi Changluprecisebioche Mistry Co., Ltd. | Snow-melting and antifreezing agent and a method for produce the agent |
CN100357386C (en) * | 2006-04-06 | 2007-12-26 | 潍坊昌大化工有限公司 | Antifreezing agent composition and its production process |
CN101230246B (en) * | 2007-12-19 | 2010-06-02 | 保定天威集团有限公司 | Leakage testing liquid preventing low-temperature icing and preparation method |
CN104893663A (en) * | 2015-04-23 | 2015-09-09 | 长安大学 | Snow-melting agent having corrosion inhibition effect |
CN105062422A (en) * | 2015-09-06 | 2015-11-18 | 温州泓呈祥科技有限公司 | Environment-friendly snow-melting agent and preparation method thereof |
CN108003837A (en) * | 2018-01-30 | 2018-05-08 | 辽宁好利置业有限公司 | Environment-friendly novel deicing salt |
-
1994
- 1994-12-20 CN CN 94112694 patent/CN1125247A/en active Pending
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003042323A1 (en) * | 2001-11-13 | 2003-05-22 | Tianjinshi Changluprecisebioche Mistry Co., Ltd. | Snow-melting and antifreezing agent and a method for produce the agent |
CN100357386C (en) * | 2006-04-06 | 2007-12-26 | 潍坊昌大化工有限公司 | Antifreezing agent composition and its production process |
CN101230246B (en) * | 2007-12-19 | 2010-06-02 | 保定天威集团有限公司 | Leakage testing liquid preventing low-temperature icing and preparation method |
CN104893663A (en) * | 2015-04-23 | 2015-09-09 | 长安大学 | Snow-melting agent having corrosion inhibition effect |
CN105062422A (en) * | 2015-09-06 | 2015-11-18 | 温州泓呈祥科技有限公司 | Environment-friendly snow-melting agent and preparation method thereof |
CN108003837A (en) * | 2018-01-30 | 2018-05-08 | 辽宁好利置业有限公司 | Environment-friendly novel deicing salt |
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C01 | Deemed withdrawal of patent application (patent law 1993) | ||
WD01 | Invention patent application deemed withdrawn after publication |