CN112495590A - Magnesium-containing silicate mineral inhibitor and application thereof - Google Patents
Magnesium-containing silicate mineral inhibitor and application thereof Download PDFInfo
- Publication number
- CN112495590A CN112495590A CN202110012491.1A CN202110012491A CN112495590A CN 112495590 A CN112495590 A CN 112495590A CN 202110012491 A CN202110012491 A CN 202110012491A CN 112495590 A CN112495590 A CN 112495590A
- Authority
- CN
- China
- Prior art keywords
- magnesium
- silicate mineral
- inhibitor
- containing silicate
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003112 inhibitor Substances 0.000 title claims abstract description 52
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 239000011777 magnesium Substances 0.000 title claims abstract description 40
- 229910052749 magnesium Inorganic materials 0.000 title claims abstract description 40
- 229910052604 silicate mineral Inorganic materials 0.000 title claims abstract description 38
- 239000000454 talc Substances 0.000 claims abstract description 40
- 229910052623 talc Inorganic materials 0.000 claims abstract description 40
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 32
- 239000011707 mineral Substances 0.000 claims abstract description 32
- 238000005188 flotation Methods 0.000 claims abstract description 29
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229910052802 copper Inorganic materials 0.000 claims abstract description 27
- 239000010949 copper Substances 0.000 claims abstract description 27
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000011733 molybdenum Substances 0.000 claims abstract description 25
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 25
- 238000000034 method Methods 0.000 claims abstract description 23
- WUUZKBJEUBFVMV-UHFFFAOYSA-N copper molybdenum Chemical compound [Cu].[Mo] WUUZKBJEUBFVMV-UHFFFAOYSA-N 0.000 claims abstract description 22
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 18
- 239000011593 sulfur Substances 0.000 claims abstract description 18
- 230000008569 process Effects 0.000 claims abstract description 12
- 239000000725 suspension Substances 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 12
- WYTGDNHDOZPMIW-RCBQFDQVSA-N alstonine Natural products C1=CC2=C3C=CC=CC3=NC2=C2N1C[C@H]1[C@H](C)OC=C(C(=O)OC)[C@H]1C2 WYTGDNHDOZPMIW-RCBQFDQVSA-N 0.000 claims description 10
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 10
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 10
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 10
- 229920002907 Guar gum Polymers 0.000 claims description 8
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 8
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 8
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 8
- 229910001919 chlorite Inorganic materials 0.000 claims description 8
- 229910052619 chlorite group Inorganic materials 0.000 claims description 8
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 claims description 8
- 239000000665 guar gum Substances 0.000 claims description 8
- 229960002154 guar gum Drugs 0.000 claims description 8
- 235000010417 guar gum Nutrition 0.000 claims description 8
- 229920005610 lignin Polymers 0.000 claims description 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 7
- 239000004088 foaming agent Substances 0.000 claims description 7
- 239000011133 lead Substances 0.000 claims description 7
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims description 7
- 239000000391 magnesium silicate Substances 0.000 claims description 7
- 229910052919 magnesium silicate Inorganic materials 0.000 claims description 7
- 235000019792 magnesium silicate Nutrition 0.000 claims description 7
- 239000011701 zinc Substances 0.000 claims description 7
- 229910052725 zinc Inorganic materials 0.000 claims description 7
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 6
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 6
- TUZCOAQWCRRVIP-UHFFFAOYSA-N butoxymethanedithioic acid Chemical group CCCCOC(S)=S TUZCOAQWCRRVIP-UHFFFAOYSA-N 0.000 claims description 6
- OIGPMFVSGDDYHS-UHFFFAOYSA-N copper sulfanylidenemolybdenum Chemical compound [S].[Cu].[Mo] OIGPMFVSGDDYHS-UHFFFAOYSA-N 0.000 claims description 6
- 239000004571 lime Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 239000012141 concentrate Substances 0.000 abstract description 10
- 230000002401 inhibitory effect Effects 0.000 abstract description 10
- 238000002156 mixing Methods 0.000 abstract description 7
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 abstract description 7
- 229910052961 molybdenite Inorganic materials 0.000 abstract description 6
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 238000010438 heat treatment Methods 0.000 abstract description 3
- 229910052951 chalcopyrite Inorganic materials 0.000 description 4
- DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 description 4
- 239000003814 drug Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 229910052569 sulfide mineral Inorganic materials 0.000 description 2
- 230000004075 alteration Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052626 biotite Inorganic materials 0.000 description 1
- 229910052947 chalcocite Inorganic materials 0.000 description 1
- 229910001779 copper mineral Inorganic materials 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052889 tremolite Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/018—Mixtures of inorganic and organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/02—Froth-flotation processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/06—Depressants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
- B03D2203/04—Non-sulfide ores
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
The invention discloses a magnesium-containing silicate mineral inhibitor and application thereof. The application is the application of the magnesium-containing silicate mineral inhibitor in the flotation process of magnesium-containing silicate minerals. The talc inhibitor suspension can inhibit talc alone without inhibiting molybdenite, and compared with the traditional method for inhibiting talc alone without inhibiting sulfur, the method has the advantages that the grade of copper concentrate is improved by 5-8%, the grade of molybdenum in copper-molybdenum bulk concentrate is improved by 5-10%, the content of MgO is reduced by 50-80%, and the gangue mineral mixing rate in copper-molybdenum bulk concentrate is reduced by 40%. The method has the advantages of simple process, less raw material consumption, low cost, no need of heating, environmental friendliness and no pollution, and effectively solves the problem that the magnesium-containing silicate minerals such as talc and the like are difficult to separate from the useful minerals such as copper, molybdenum and the like by flotation.
Description
Technical Field
The invention belongs to the technical field of chemical industry, and particularly relates to a magnesium-containing silicate mineral inhibitor and application thereof.
Background
Along with the continuous development and utilization of copper and molybdenum resources, the resource amount of easily-selected copper and molybdenum sulfide ores is gradually reduced, the ores are poor, fine and hybridized more and more serious, and the ore dressing difficulty is increased more and more. Some foreign high-talc copper-molybdenum ore contains multiple metals such as copper, molybdenum, lead, zinc and the like, most of copper mainly exists in chalcopyrite, copper blue and chalcocite in the form of independent minerals, and part of copper exists in biotite, serpentine, chlorite, talc and tremolite in the form of homogeneous phases or mechanical mixing. The gangue minerals such as talc and the like are easy to argillize in the ore grinding process, so that the gangue minerals such as talc and the like are easy to adsorb the surface of copper molybdenum sulfide minerals, the action of agents such as collecting agents, foaming agents and the like and the copper molybdenum sulfide minerals is prevented, the floatability of the talc is close to that of chalcopyrite and molybdenite, the floatability is good, a small amount of foaming agents can float to copper molybdenum mixed concentrate, the recovery of copper and molybdenum is influenced, and the flotation difficulty is increased continuously.
Therefore, there is a need to develop a talc flotation inhibitor and a suitable separation method for separating talc-type copper-molybdenum sulfide ores containing copper, sulfur, molybdenum, lead, zinc and the like from magnesium-containing silicate minerals such as talc, serpentine and chlorite, so as to maximize the resource utilization rate.
Disclosure of Invention
The invention provides a method for inhibiting gangue minerals such as talc and the like and improving the grade of copper-molybdenum bulk concentrates in the flotation separation process of copper, molybdenum and sulfur, aiming at the problem that the flotation of useful minerals is influenced because the floatability of magnesium-containing silicate easy-to-float gangue minerals such as talc, serpentine and chlorite is similar to that of useful minerals such as chalcopyrite and molybdenite in the flotation process.
The invention relates to an inhibitor capable of selectively reducing floatability of magnesium-containing silicate minerals such as talc and the like, which reduces floatability of gangue minerals such as talc and the like without reducing floatability of copper minerals and molybdenum minerals by the contact action of a medicament and the surface of the ores in an ore pulp system in which minerals such as chalcopyrite, molybdenite and the like coexist, thereby achieving the purpose of separating the magnesium-containing silicate minerals such as talc and the like from useful minerals such as copper, molybdenum and the like.
The first purpose of the invention is to provide a magnesium-containing silicate mineral inhibitor; the second purpose is to provide the application of the magnesium silicate mineral inhibitor.
The first purpose of the invention is realized by that the magnesium silicate mineral inhibitor consists of DH and sodium hexametaphosphate, and the DH consists of guar gum, carboxymethyl cellulose CMC and lignin.
The second purpose of the invention is realized by the application of the magnesium-containing silicate mineral inhibitor in the flotation process of magnesium-containing silicate minerals.
The invention has the beneficial effects that:
1. under the condition that suspension prepared by using DH and sodium hexametaphosphate according to the ratio of 1: 1-1: 3 is used as a talc inhibitor and butyl xanthate or Z-200 is used as a copper-molybdenum flotation collector, compared with the traditional method for simply inhibiting sulfur and not inhibiting talc, the method has the advantages that the grade of copper concentrate is improved by 5-8%, the grade of molybdenum in the copper concentrate is improved by 5-10%, the content of MgO is reduced by 50-80%, and the gangue mineral mixing rate is reduced by 40%.
2. Under the condition that suspension prepared from DH and sodium hexametaphosphate according to the ratio of 1: 1-1: 3 is used as a talc inhibitor and butyl xanthate or Z-200 is used as a copper-molybdenum collecting agent, the using amount of lime as a sulfur inhibitor is reduced by 30-50%.
3. The talc inhibitor suspension can independently inhibit talc without inhibiting molybdenite, and solves the problem that the molybdenum mineral enters flotation tailings because the floatability of the molybdenum mineral is reduced while the gangue is inhibited by a conventional inhibitor.
4. The method has the advantages of simple process, less raw material consumption, low cost, no need of heating, environmental friendliness, no pollution and capability of effectively solving the problem that the magnesium-containing silicate minerals such as talc and the like are difficult to separate from the useful minerals such as copper, molybdenum and the like by flotation.
Drawings
FIG. 1 is a schematic roughing diagram of an overall embodiment of the present invention.
Detailed Description
The present invention is further illustrated by the following examples, which are not intended to be limiting in any way, and any modifications or alterations based on the teachings of the present invention are intended to fall within the scope of the present invention.
The magnesium-containing silicate mineral inhibitor consists of DH and sodium hexametaphosphate, wherein the DH consists of guar gum, carboxymethyl cellulose (CMC) and lignin.
The mass ratio of DH to sodium hexametaphosphate is 1: 1-1: 3.
The mass ratio of the guar gum to the carboxymethyl cellulose CMC to the lignin is (3-5): (2-4): (1-2).
The application of the magnesium-containing silicate mineral inhibitor is the application of the magnesium-containing silicate mineral inhibitor in a magnesium-containing silicate mineral flotation process.
The application specific operation of the magnesium-containing silicate mineral inhibitor in the magnesium-containing silicate mineral flotation process comprises the steps of ore treatment, magnesium-containing silicate mineral inhibitor preparation and flotation, and specifically comprises the following steps:
A. ore treatment: crushing raw material ores, adding water, grinding the ores until the ore pulp with the particle size of-20 mu m accounts for 75-80%, and adjusting the pH value of the ore pulp to 7-9 to obtain a material a;
B. preparing a magnesium silicate mineral inhibitor: adding water into a magnesium-containing silicate mineral inhibitor to prepare a suspension with the mass percentage concentration of 8-15% to obtain a material b;
C. flotation: adding 4000-6000 g of sulfur inhibitor, 300-1000 g of material b, 200-500 g of copper-molybdenum collecting agent and 20-50 g of foaming agent into each ton of raw material ore, fully and uniformly stirring, aerating, and floating copper and molybdenum ore under the condition that the pH value of ore pulp is 7-9.
The magnesium-containing silicate mineral is high-talc copper-molybdenum sulfide ore containing copper, sulfur, molybdenum, lead and zinc, talc, serpentine or chlorite.
The magnesium-containing silicate mineral is copper-molybdenum sulfide ore containing useful minerals such as copper, molybdenum, lead, zinc and the like with high content of magnesium-containing silicate gangue minerals such as talc, serpentine, chlorite and the like.
The sulfur inhibitor is lime.
The copper molybdenum collector is butyl xanthate or Z-200.
The DH consists of guar gum, carboxymethyl cellulose CMC and lignin. The application method comprises the steps of grinding ore pulp, preparing a talc inhibitor suspension from DH and sodium hexametaphosphate according to the proportion of 1: 1-1: 3 under the condition that the pH value is = 7-9, adding a proper amount of foaming agent into lime serving as a sulfur inhibitor and butyl xanthate or Z-200 serving as a copper-molybdenum flotation collector, fully and uniformly stirring, inflating, and carrying out flotation separation on copper, molybdenum and sulfur.
The talc inhibitor suspension can inhibit talc alone without inhibiting molybdenite, and compared with the traditional method for inhibiting talc alone without inhibiting sulfur, the method has the advantages that the grade of copper concentrate is improved by 5-8%, the grade of molybdenum in copper-molybdenum bulk concentrate is improved by 5-10%, the content of MgO is reduced by 50-80%, and the gangue mineral mixing rate in copper-molybdenum bulk concentrate is reduced by 40%. The method has the advantages of simple process, less raw material consumption, low cost, no need of heating, environmental friendliness and no pollution, and effectively solves the problem that the magnesium-containing silicate minerals such as talc and the like are difficult to separate from the useful minerals such as copper, molybdenum and the like by flotation.
The invention is further illustrated by the following specific examples:
example 1
The ore is mixed copper-molybdenum ore in Yunnan province, non-ferrous metal mineral containing copper, molybdenum, lead, zinc, etc., and gangue mineral containing talc, serpentine, etc.
(1) The inhibitor is mixed by DH and sodium hexametaphosphate in a ratio of 1:2, and the mass concentration is 10%;
(2) the DH medicament formula is formed by mixing 40 percent of guar gum, 40 percent of carboxymethyl cellulose (CMC) and 20 percent of lignin by mass percent respectively;
(3) ore treatment: crushing copper-molybdenum ore containing talc and serpentine, and adding water to grind the ore until the ore pulp with the particle size of-20 mu m accounts for 79%;
(4) flotation: adding 4000 g of sulfur inhibitor, 500g of talc inhibitor suspension, 200 g of copper-molybdenum flotation collector and 20 g of foaming agent into each ton of ore, fully and uniformly stirring, aerating, and floating copper and molybdenum ores under the condition that the pH value of ore pulp is 7.0. The sulfur inhibitor is lime, and the copper molybdenum flotation collector is butyl xanthate.
Example 2
The ore is high talc type copper molybdenum ore, non-ferrous metal mineral containing copper, molybdenum, lead, zinc, etc., and gangue mineral containing talc, serpentine, chlorite, etc.
(1) The talc inhibitor is prepared by mixing DH and sodium hexametaphosphate in a ratio of 1:3, and the mass concentration is 15%;
(2) the DH medicament formula is formed by mixing 50 percent of guar gum, 40 percent of carboxymethyl cellulose (CMC) and 10 percent of lignin by mass percent respectively;
(3) ore treatment: crushing copper-molybdenum ore containing talc, serpentine and chlorite, and adding water to grind the ore until the ore pulp with the particle size of-20 mu m accounts for 78%;
(4) flotation: 5000 g of sulfur inhibitor, 600 g of talc inhibitor suspension, 300 g of copper-molybdenum flotation collector and 30 g of foaming agent are added into each ton of ore, the mixture is fully stirred uniformly and aerated, and copper and molybdenum ores are floated under the condition that the pH value of ore pulp is 8.0. The sulfur inhibitor is lime, and the copper-molybdenum flotation collector is Z-200.
Claims (8)
1. The magnesium-containing silicate mineral inhibitor is characterized by consisting of DH and sodium hexametaphosphate, wherein the DH consists of guar gum, carboxymethyl cellulose (CMC) and lignin.
2. The magnesium silicate mineral inhibitor as claimed in claim 1, wherein the mass ratio of DH to sodium hexametaphosphate is 1: 1-1: 3.
3. The magnesium-containing silicate mineral inhibitor as claimed in claim 1, wherein the mass ratio of guar gum, carboxymethyl cellulose CMC and lignin is (3-5): (2-4): (1-2).
4. The application of the magnesium-containing silicate mineral inhibitor as defined in any one of claims 1 to 3, wherein the magnesium-containing silicate mineral inhibitor is applied to a flotation process of magnesium-containing silicate minerals.
5. The application of the magnesium-containing silicate mineral inhibitor in the magnesium-containing silicate mineral flotation process is characterized in that the specific operation of the magnesium-containing silicate mineral inhibitor in the magnesium-containing silicate mineral flotation process comprises ore treatment, magnesium-containing silicate mineral inhibitor configuration and flotation steps, and specifically comprises the following steps:
A. ore treatment: crushing raw material ores, adding water, grinding the ores until the ore pulp with the particle size of-20 mu m accounts for 75-80%, and adjusting the pH value of the ore pulp to 7-9 to obtain a material a;
B. preparing a magnesium silicate mineral inhibitor: adding water into a magnesium-containing silicate mineral inhibitor to prepare a suspension with the mass percentage concentration of 8-15% to obtain a material b;
C. flotation: adding 4000-6000 g of sulfur inhibitor, 300-1000 g of material b, 200-500 g of copper-molybdenum collecting agent and 20-50 g of foaming agent into each ton of raw material ore, fully and uniformly stirring, aerating, and floating copper and molybdenum ore under the condition that the pH value of ore pulp is 7-9.
6. The use of the magnesium-containing silicate mineral inhibitor as claimed in claim 4 or 5, wherein the magnesium-containing silicate mineral is copper-molybdenum sulfide ore of high talc type containing copper, sulfur, molybdenum, lead and zinc, talc, serpentine or chlorite.
7. The use of the magnesium silicate mineral inhibitor as claimed in claim 5, wherein the sulfur inhibitor is lime.
8. The use of the magnesium silicate mineral inhibitor as claimed in claim 5, wherein the copper molybdenum collector is butyl xanthate or Z-200.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110012491.1A CN112495590A (en) | 2021-01-06 | 2021-01-06 | Magnesium-containing silicate mineral inhibitor and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110012491.1A CN112495590A (en) | 2021-01-06 | 2021-01-06 | Magnesium-containing silicate mineral inhibitor and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112495590A true CN112495590A (en) | 2021-03-16 |
Family
ID=74952135
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110012491.1A Pending CN112495590A (en) | 2021-01-06 | 2021-01-06 | Magnesium-containing silicate mineral inhibitor and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112495590A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114367376A (en) * | 2022-01-10 | 2022-04-19 | 中南大学 | Method for recovering copper-molybdenum minerals through flotation |
| CN114832948A (en) * | 2022-03-13 | 2022-08-02 | 中南大学 | Flotation depressor, preparation and application thereof |
| CN115672559A (en) * | 2022-11-10 | 2023-02-03 | 昆明理工大学 | Application of inhibitor in reverse flotation removal of calcite from fluorite |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103301948A (en) * | 2013-06-28 | 2013-09-18 | 中南大学 | Method for improving flotation recovery rate of copper and nickel and reducing content of magnesium oxide in concentrates of copper-nickel sulfide ores |
| CN104084314A (en) * | 2014-07-03 | 2014-10-08 | 四川省地质矿产勘查开发局成都综合岩矿测试中心 | Gangue inhibitor for flotation of high-magnesium and low-nickel polymetallic ores |
| CN104874484A (en) * | 2015-04-28 | 2015-09-02 | 中国地质科学院郑州矿产综合利用研究所 | Method for reducing content of magnesium oxide in concentrate in copper-nickel sulfide ore flotation |
| JP2018162509A (en) * | 2017-03-27 | 2018-10-18 | Ｊｘ金属株式会社 | Molybdenum concentrate separation method |
| CN111330740A (en) * | 2020-03-05 | 2020-06-26 | 中南大学 | Method for improving flotation separation efficiency of magnesium-containing layered silicate minerals and copper sulfide minerals |
| CN111359782A (en) * | 2018-12-26 | 2020-07-03 | 有研工程技术研究院有限公司 | Combined flotation reagent for inhibiting magnesium-containing silicate gangue minerals |
| CN111451003A (en) * | 2020-03-05 | 2020-07-28 | 铜陵有色金属集团股份有限公司 | Beneficiation method for copper-containing talc-serpentine ore easy to argillize and float |
-
2021
- 2021-01-06 CN CN202110012491.1A patent/CN112495590A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103301948A (en) * | 2013-06-28 | 2013-09-18 | 中南大学 | Method for improving flotation recovery rate of copper and nickel and reducing content of magnesium oxide in concentrates of copper-nickel sulfide ores |
| CN104084314A (en) * | 2014-07-03 | 2014-10-08 | 四川省地质矿产勘查开发局成都综合岩矿测试中心 | Gangue inhibitor for flotation of high-magnesium and low-nickel polymetallic ores |
| CN104874484A (en) * | 2015-04-28 | 2015-09-02 | 中国地质科学院郑州矿产综合利用研究所 | Method for reducing content of magnesium oxide in concentrate in copper-nickel sulfide ore flotation |
| JP2018162509A (en) * | 2017-03-27 | 2018-10-18 | Ｊｘ金属株式会社 | Molybdenum concentrate separation method |
| CN111359782A (en) * | 2018-12-26 | 2020-07-03 | 有研工程技术研究院有限公司 | Combined flotation reagent for inhibiting magnesium-containing silicate gangue minerals |
| CN111330740A (en) * | 2020-03-05 | 2020-06-26 | 中南大学 | Method for improving flotation separation efficiency of magnesium-containing layered silicate minerals and copper sulfide minerals |
| CN111451003A (en) * | 2020-03-05 | 2020-07-28 | 铜陵有色金属集团股份有限公司 | Beneficiation method for copper-containing talc-serpentine ore easy to argillize and float |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114367376A (en) * | 2022-01-10 | 2022-04-19 | 中南大学 | Method for recovering copper-molybdenum minerals through flotation |
| CN114832948A (en) * | 2022-03-13 | 2022-08-02 | 中南大学 | Flotation depressor, preparation and application thereof |
| CN115672559A (en) * | 2022-11-10 | 2023-02-03 | 昆明理工大学 | Application of inhibitor in reverse flotation removal of calcite from fluorite |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN112495590A (en) | Magnesium-containing silicate mineral inhibitor and application thereof | |
| CN102371212B (en) | Technology of enhanced-dispersion partial selective and bulk flotation of lead and zinc sulfide ores under low and high alkalinity | |
| CN110548592B (en) | Beneficiation method for improving comprehensive recovery index of complex low-grade molybdenum multi-metal ore | |
| CN102698878A (en) | Pyrite inhibitor used under low-alkalinity condition | |
| CN106540816A (en) | Suppress the flotation composite inhibitor and its using method of pyrite under a kind of low alkalinity | |
| CN110465411B (en) | Preferential flotation method for copper-lead sulfide minerals | |
| CN111715411A (en) | Beneficiation method for high-sulfur lead-zinc ore | |
| CN105312160A (en) | Novel collecting agent and application thereof to low-alkaline flotation separation beneficiation of lead zinc sulfide minerals | |
| CN110918263A (en) | Non-copper sulfide ore inhibitor and application thereof | |
| CN112317135B (en) | Combined inhibitor for flotation separation of copper-lead sulfide ore and application thereof | |
| CN111298982B (en) | High-efficiency collecting agent for copper and gold in copper smelting slag by pyrometallurgy and application of high-efficiency collecting agent | |
| CN111229451B (en) | Flotation separation method of talc and chalcopyrite | |
| CN113856911B (en) | Beneficiation method for high-sulfur copper gold and silver ore | |
| CN109967262B (en) | Noble metal ore flotation reagent and application thereof | |
| CN115155824A (en) | Beneficiation method for recovering tin from tin-containing fine mud | |
| CN101003029A (en) | Method for floating inhibited iron sulfide minerals | |
| CN107899755B (en) | Synergist for flotation of refractory copper oxide ore | |
| CN117181451A (en) | Enhanced activation flotation method for carbonate copper oxide ore | |
| CN114011582B (en) | Flotation method for improving beneficiation index of gold-bearing copper sulfide ore | |
| CN116441058A (en) | Method for reducing magnesium oxide content of concentrate in copper-nickel sulfide ore floatation | |
| CN113617532A (en) | Combined inhibitor for lead-sulfur sulfide ore flotation separation and application | |
| CN113333177A (en) | Combined inhibitor for separating copper sulfide ore containing secondary copper and separation method | |
| CN109731692A (en) | A kind of efficient flotation separation separation method of copper-sulphide ores | |
| CN113210137B (en) | Combined inhibitor for separation of kaolin-containing copper sulfide ore and separation method | |
| CN115318446B (en) | Flotation reagent system for refractory low-grade nickel-cobalt sulfide ores and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20210316 |