CN112457773A - Anti-dazzle nano coating and preparation method and application method thereof - Google Patents
Anti-dazzle nano coating and preparation method and application method thereof Download PDFInfo
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
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- C03C17/001—General methods for coating; Devices therefor
- C03C17/002—General methods for coating; Devices therefor for flat glass, e.g. float glass
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- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/68—Particle size between 100-1000 nm
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/29—Mixtures
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
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- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
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- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/118—Deposition methods from solutions or suspensions by roller-coating
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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Abstract
The invention discloses an anti-dazzle nano coating and a preparation method and an application method thereof, the anti-dazzle nano coating is prepared from a mixed solvent, organosilane, a silane coupling agent, a tackifier and inorganic particles, and the average particle size of the inorganic particles in the length dimension direction is more than 400 nm. According to the anti-glare nano coating and the preparation method and the application method thereof, the anti-glare coating is prepared by spraying and the like and is applied to the photovoltaic module, so that glare is avoided, and the light transmittance and the power generation efficiency of glass and the like are not influenced; organosilane and silane coupling agent with specific chain length are added into the coating, an organic nano convex structure with the thickness of 1-5 mu m and the average particle diameter of 20-120nm is constructed on the surface of the glass through crosslinking and hydrolytic condensation, inorganic particles with the average diameter of more than 400nm are added into the coating, and the light refraction difference generated by two types of nano particles with different particle diameters is utilized to generate diffuse reflection so as to eliminate the glare on the surface of the photovoltaic glass.
Description
Technical Field
The invention belongs to the technical field of anti-glare coatings, and particularly relates to an anti-glare nano coating as well as a preparation method and an application method thereof.
Background
Glare refers to the presence of a high-brightness light source in the field of vision due to inadequate brightness distribution, causing visual discomfort. The front surface of the photovoltaic module is made of glass, and the photovoltaic module can be used on large scale on roofs, curtain walls and the like of urban buildings, and can generate light pollution due to the existence of glare.
The anti-glare treatment of the photovoltaic glass generally adopts pattern treatment on the surface of the glass or doping treatment on the glass to form diffuse reflection so as to obtain the anti-glare glass. The use of these processes requires handling during glass sintering, which is not possible with photovoltaic modules already in use.
Disclosure of Invention
In order to solve the technical problems in the prior art, the invention aims to provide an anti-glare nano coating, and a preparation method and an application method thereof.
In order to achieve the purpose and achieve the technical effect, the invention adopts the technical scheme that:
the anti-dazzle nano coating is characterized by comprising the following components in parts by weight:
82-95 parts of mixed solvent
2-5 parts of organosilane
1-3 parts of silane coupling agent
1-5 parts of tackifier
1-5 parts of inorganic particles
The average particle diameter of the inorganic particles in the long dimension direction is more than 400 nm.
Further, the silane coupling agent also comprises a catalyst, wherein the catalyst accounts for 0.1-5 multiplied by 10 of the total mass of the organosilane and the silane coupling agent-4The catalyst is selected from stannous chloride, toluene sulfonic acid-dibutyl tin oxide, Pt-N (C)2H5)3And stannous octoate.
Further, the inorganic particles are spherical, rod-shaped or ellipsoidal, and are selected from any one of silicon dioxide, titanium dioxide, barium sulfate, aluminum oxide, calcium carbonate, zinc oxide and tin dioxide.
Further, the mixed solvent is a mixed solution of deionized water and an organic solvent, and the organic solvent is selected from one or more of methanol, ethanol, isopropanol, acetone, butane and hexane.
Further, the organosilane is a long-chain alkyl silane, the carbon number of the long-chain alkyl silane is more than 3, and the long-chain alkyl silane is selected from one or more of dodecyl trisilane, hexadecyl dimethyl chlorosilane, heptadecafluorodecyl trimethoxy silane, n-octyl trimethoxy silane, dodecyl trimethoxy silane and octadecyl trimethoxy silane.
Further, the silane coupling agent is selected from any one of aminosilane coupling agent, carboxyl silane coupling agent, isocyanate silane and methacryloxy silane coupling agent.
Further, the tackifier is selected from one or more of polyvinyl alcohol, polyvinyl butyral, ethylene-vinyl acetate copolymer and polyurethane.
The invention discloses a preparation method of an anti-dazzle nano coating, which comprises the following steps:
adding organosilane into the mixed solvent, adjusting the pH value to be 4-5, stirring for 2-4h at the temperature of 25-45 ℃, adding a silane coupling agent, continuing to react for 2-4h, adding a tackifier and inorganic particles, and stirring to react for 8-24h until the reaction is finished to obtain the required anti-dazzle nano-coating.
The invention discloses an application method of an anti-dazzle nano coating, which comprises the following steps:
the anti-glare nano coating is coated on the surface of the glass in a spraying or rolling coating mode, and is placed at room temperature for 12-24 hours or heated at the temperature of 120-150 ℃ for 10-20min to obtain the anti-glare photovoltaic glass.
Further, the thickness of the anti-dazzle nano coating is 1-5 mu m, and the average particle size of the organic nano particles on the surface of the glass is 10-200 nm.
Compared with the prior art, the invention has the beneficial effects that:
the invention discloses an anti-glare nano coating, a preparation method and an application method thereof, the anti-glare nano coating can be prepared into an anti-glare coating by spraying and the like, and is applied to a photovoltaic assembly, so that glare is avoided, and the light transmittance and the power generation efficiency of glass and the like are not influenced; organic nano convex structures with the thickness of 1-5 mu m and the average particle diameter of 20-120nm are constructed on the surface of the glass by adding organosilane and silane coupling agents with specific chain lengths into the coating and by crosslinking and hydrolytic condensation, a certain amount of spherical, rod-like or ellipsoidal inorganic particles are added into the coating, the average diameter of the inorganic particles in the long dimension direction is more than 400nm, and the refractive indexes of the two types of nano particles with different particle diameters are different, so that the generated light rays are refracted differently, diffuse reflection is generated, and glare on the surface of the photovoltaic glass is eliminated.
Detailed Description
The following detailed description of the embodiments of the present invention is provided to enable those skilled in the art to more easily understand the advantages and features of the present invention, and to clearly and clearly define the scope of the present invention.
Example 1
A preparation method of an anti-dazzle nano coating comprises the following steps:
adding 85g of mixed solvent into a reaction kettle, adding 2g of organosilane dodecyl trisilane, adding 0.001g of stannous dimethyl catalyst, adjusting the pH to 4-5, and stirring at 25-45 ℃ for 4 hours; then, 3g of silane coupling agent vinyl trimethoxy silane is added to continue to react for 4 hours; sequentially adding 1g of tackifier polyvinyl alcohol and 1g of inorganic particle silicon dioxide, wherein the silicon dioxide is spherical inorganic particles with the average particle size of 500nm, and stirring for reacting for 24 hours until the reaction is finished to obtain the anti-dazzle nano coating.
The adopted mixed solvent is a mixed solvent of water and ethanol, and the volume ratio of the water to the ethanol is 1: 4.
example 2
A preparation method of an anti-dazzle nano coating comprises the following steps:
adding 82g of mixed solvent into a reaction kettle, adding 3g of organosilane dodecyl trisilane, adding 0.001g of stannous dimethyl catalyst, adjusting the pH to 4-5, and stirring at 25-45 ℃ for 4 hours; 2g of silane coupling agent vinyl trimethoxy silane is added to continue to react for 4 hours; sequentially adding 2g of tackifier polyvinyl alcohol and 2g of inorganic particle silicon dioxide, wherein the silicon dioxide is spherical inorganic particles with the average particle size of 200nm, and stirring and reacting for 24 hours until the reaction is finished to obtain the anti-dazzle nano coating.
The adopted mixed solvent is a mixed solvent of water and ethanol, and the volume ratio of the water to the ethanol is 1: 4.
the same as in example 1.
Example 3
A preparation method of an anti-dazzle nano coating comprises the following steps:
adding 82g of mixed solvent into a reaction kettle, adding 3g of organosilane dodecyl trisilane, adjusting the pH to 4-5, and stirring at the temperature of 25-45 ℃ for 4 hours; 2g of silane coupling agent vinyl trimethoxy silane is added to continue to react for 4 hours; sequentially adding 2g of tackifier polyvinyl alcohol and 2g of inorganic particle silicon dioxide, wherein the silicon dioxide is a rod-shaped inorganic particle with the average particle size of 500nm in the long dimension, and stirring for reacting for 24 hours until the reaction is finished to obtain the anti-dazzle nano coating.
The adopted mixed solvent is a mixed solvent of water and ethanol, and the volume ratio of the water to the ethanol is 1: 4.
the same as in example 1.
Example 4
A preparation method of an anti-dazzle nano coating comprises the following steps:
adding 95g of mixed solvent into a reaction kettle, adding 5g of organosilane dodecyl trisilane, adjusting the pH to 4-5, and stirring at 25-45 ℃ for 4 hours; 1g of silane coupling agent vinyl trimethoxy silane is added to continue to react for 4 hours; and sequentially adding 5g of tackifier polyvinyl alcohol and 5g of inorganic particle silicon dioxide, wherein tin dioxide is spherical inorganic particles with the average particle size of 550nm, and stirring for reacting for 24 hours until the reaction is finished to obtain the anti-dazzle nano coating.
The adopted mixed solvent is a mixed solvent of water and ethanol, and the volume ratio of the water to the ethanol is 1: 4.
the same as in example 1.
Comparative example 1
Photovoltaic module glass is commercially available.
Comparative example 2
The preparation method of the anti-dazzle nano coating comprises the following steps:
adding 85g of mixed solvent into a reaction kettle, adding 2g of organosilane dodecyl trisilane, adding 0.001g of stannous dimethyl catalyst, adjusting the pH to 4-5, and stirring at 25-45 ℃ for 4 hours. Adding 3g of silane coupling agent vinyl trimethoxy silane, continuing to react for 4h, adding 1g of tackifier polyvinyl alcohol, and stirring to react for 24h until the reaction is finished. Comparative example 2 is different from example 1 in that no inorganic particles are used in comparative example 2.
The adopted mixed solvent is a mixed solvent of water and ethanol, and the volume ratio of the water to the ethanol is 1: 4.
the commercially available photovoltaic assembly glass is selected for the examples 1-4 and the comparative example 2, the coatings prepared in the examples 1-4 and the comparative example 2 are respectively coated on the surface of the commercially available photovoltaic assembly glass in a roll coating mode, the surface of the glass is heated at 120 ℃ for 20min to obtain the anti-glare photovoltaic glass, the thickness of the coating is 3 mu m, and the average particle size of the organic nanoparticles on the surface of the coating is 120 nm.
The light transmittance is tested by a Beijing Pueutralization TU-1801 spectrophotometer, and the wavelength range is 400-1100 nm. The xenon lamp is used for simulating sunlight, and a Konica minolta DOI tester (model IQ-S) is used for testing the distinctness of image. The test results are given in table 1 below:
TABLE 1
As can be seen from Table 1, the distinctness of image of examples 1, 3 and 4 is obviously reduced compared with that of comparative examples 1-2, which shows that the diffuse reflection is improved, and the anti-glare effect is improved; and the anti-glare effect is not changed after ultraviolet aging. Comparative example 2 no inorganic particles were added, and the inorganic particles used in example 2 had an average particle size of 200nm and had no anti-glare effect, compared to other comparative examples. In conclusion, the anti-dazzle effect is formed by utilizing the different light refraction generated by the two types of nano particles with different particle sizes, and the anti-dazzle effect is not achieved under the condition that no inorganic particles are added or the particle size of the added inorganic particles is smaller.
The parts of the invention not specifically described can be realized by adopting the prior art, and the details are not described herein.
The above description is only an embodiment of the present invention, and not intended to limit the scope of the present invention, and all modifications of equivalent structures and equivalent processes, which are made by the present specification, or directly or indirectly applied to other related technical fields, are included in the scope of the present invention.
Claims (10)
1. The anti-dazzle nano coating is characterized by comprising the following components in parts by weight:
82-95 parts of mixed solvent
2-5 parts of organosilane
1-3 parts of silane coupling agent
1-5 parts of tackifier
1-5 parts of inorganic particles
The average particle diameter of the inorganic particles in the long dimension direction is more than 400 nm.
2. The anti-glare nano-coating according to claim 1, further comprising a catalyst selected from stannous dimethyl, dibutyltin tosylate, Pt-N (C)2H5)3And stannous octoate.
3. The anti-glare nano-coating according to claim 1, wherein the inorganic particles are spherical, rod-like or ellipsoidal, and are selected from any one of silicon dioxide, titanium dioxide, barium sulfate, aluminum oxide, calcium carbonate, zinc oxide and tin dioxide.
4. The anti-glare nano-coating according to claim 1, wherein the mixed solvent is a mixed solution of deionized water and an organic solvent, and the organic solvent is selected from one or more of methanol, ethanol, isopropanol, acetone, butane and hexane.
5. The anti-glare nanocoating according to claim 1, wherein the organosilane is a long chain alkyl silane having a carbon number greater than 3, and the long chain alkyl silane is selected from the group consisting of dodecyltrisilane, hexadecyldimethylchlorosilane, heptadecafluorodecyltrimethoxysilane, n-octyltrimethoxysilane, dodecyltrimethoxysilane, octadecyltrimethoxysilane, and combinations thereof.
6. The anti-glare nano-coating according to claim 1, wherein the silane coupling agent is selected from any one of aminosilane coupling agents, carboxyl silane coupling agents, isocyanato silanes, and methacryloxy silane coupling agents.
7. The anti-glare nanocoating according to claim 1, wherein the adhesion promoter is selected from the group consisting of one or more of polyvinyl alcohol, polyvinyl butyral, ethylene vinyl acetate copolymer, and polyurethane.
8. A method for preparing the anti-glare nano-coating according to any one of claims 1 to 7, comprising the steps of:
adding organosilane into the mixed solvent, adjusting the pH value to be 4-5, stirring for 2-4h at the temperature of 25-45 ℃, adding a silane coupling agent, continuing to react for 2-4h, adding a tackifier and inorganic particles, and stirring to react for 8-24h until the reaction is finished to obtain the required anti-dazzle nano-coating.
9. A method of applying the anti-glare nano-coating according to any one of claims 1 to 7, comprising the steps of:
the anti-glare nano coating is coated on the surface of the glass in a spraying or rolling coating mode, and is placed at room temperature for 12-24 hours or heated at the temperature of 120-150 ℃ for 10-20min to obtain the anti-glare photovoltaic glass.
10. The method of claim 9, wherein the thickness of the anti-glare nano-coating is 1 to 5 μm, and the average particle diameter of the organic nano-particles on the surface of the glass is 10 to 200 nm.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114873933A (en) * | 2022-06-13 | 2022-08-09 | 深圳市东方硅源科技有限公司 | Anti-glare AG glass and preparation process thereof |
| CN115109481A (en) * | 2022-08-02 | 2022-09-27 | 广东晟毅新材料科技有限公司 | Anti-glare coating and preparation method and application thereof |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1263354A (en) * | 1999-02-12 | 2000-08-16 | 同济大学 | Wide band antireflective nano-coating layer for glass display screen and its production method |
| CN1493889A (en) * | 2002-08-28 | 2004-05-05 | �յÿ���ʽ���� | Anti-glare hard coating film |
| US20060092495A1 (en) * | 2004-10-28 | 2006-05-04 | Fuji Photo Film Co., Ltd. | Anti-glare anti-reflection film, polarizing plate, and image display device |
| CN102211435A (en) * | 2010-04-02 | 2011-10-12 | 素塔电子科技(上海)有限公司 | Anti-dazzling film |
| CN102676004A (en) * | 2012-05-18 | 2012-09-19 | 中国科学院宁波材料技术与工程研究所 | Composition for anti-glaring film |
| CN105566963A (en) * | 2015-12-25 | 2016-05-11 | 佛山佛塑科技集团股份有限公司 | Non-glare coating and non-glare membrane |
| CN106030349A (en) * | 2014-04-23 | 2016-10-12 | 大日本印刷株式会社 | Method for producing laminate, laminate, polarizing plate, image display device, and method for improving readability of image display device |
| CN107739159A (en) * | 2017-09-28 | 2018-02-27 | 深圳航天科技创新研究院 | A kind of haze low-luster anti-dazzling film and preparation method thereof |
| CN110058337A (en) * | 2019-04-25 | 2019-07-26 | 汕头万顺包装材料股份有限公司 | A kind of high definition antiglare film |
-
2020
- 2020-11-24 CN CN202011328561.6A patent/CN112457773B/en active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1263354A (en) * | 1999-02-12 | 2000-08-16 | 同济大学 | Wide band antireflective nano-coating layer for glass display screen and its production method |
| CN1493889A (en) * | 2002-08-28 | 2004-05-05 | �յÿ���ʽ���� | Anti-glare hard coating film |
| US20060092495A1 (en) * | 2004-10-28 | 2006-05-04 | Fuji Photo Film Co., Ltd. | Anti-glare anti-reflection film, polarizing plate, and image display device |
| CN102211435A (en) * | 2010-04-02 | 2011-10-12 | 素塔电子科技(上海)有限公司 | Anti-dazzling film |
| CN102676004A (en) * | 2012-05-18 | 2012-09-19 | 中国科学院宁波材料技术与工程研究所 | Composition for anti-glaring film |
| CN106030349A (en) * | 2014-04-23 | 2016-10-12 | 大日本印刷株式会社 | Method for producing laminate, laminate, polarizing plate, image display device, and method for improving readability of image display device |
| CN105566963A (en) * | 2015-12-25 | 2016-05-11 | 佛山佛塑科技集团股份有限公司 | Non-glare coating and non-glare membrane |
| CN107739159A (en) * | 2017-09-28 | 2018-02-27 | 深圳航天科技创新研究院 | A kind of haze low-luster anti-dazzling film and preparation method thereof |
| CN110058337A (en) * | 2019-04-25 | 2019-07-26 | 汕头万顺包装材料股份有限公司 | A kind of high definition antiglare film |
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| CN114873933A (en) * | 2022-06-13 | 2022-08-09 | 深圳市东方硅源科技有限公司 | Anti-glare AG glass and preparation process thereof |
| CN114873933B (en) * | 2022-06-13 | 2024-01-16 | 深圳市东方硅源科技有限公司 | Anti-glare AG glass and preparation process thereof |
| CN115109481A (en) * | 2022-08-02 | 2022-09-27 | 广东晟毅新材料科技有限公司 | Anti-glare coating and preparation method and application thereof |
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