CN112430474A - Preparation device of high-hydrogen biological fuel oil - Google Patents
Preparation device of high-hydrogen biological fuel oil Download PDFInfo
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- CN112430474A CN112430474A CN202011453177.9A CN202011453177A CN112430474A CN 112430474 A CN112430474 A CN 112430474A CN 202011453177 A CN202011453177 A CN 202011453177A CN 112430474 A CN112430474 A CN 112430474A
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- 239000001257 hydrogen Substances 0.000 title claims abstract description 19
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- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 84
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- 108090000790 Enzymes Proteins 0.000 claims abstract description 21
- 239000003054 catalyst Substances 0.000 claims abstract description 19
- 235000015112 vegetable and seed oil Nutrition 0.000 claims abstract description 16
- 239000008158 vegetable oil Substances 0.000 claims abstract description 16
- 238000003756 stirring Methods 0.000 claims description 83
- 239000002551 biofuel Substances 0.000 claims description 17
- 230000006835 compression Effects 0.000 claims description 11
- 238000007906 compression Methods 0.000 claims description 11
- 230000001954 sterilising effect Effects 0.000 claims description 11
- 238000004659 sterilization and disinfection Methods 0.000 claims description 11
- 238000001914 filtration Methods 0.000 claims description 10
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- 239000011032 tourmaline Substances 0.000 claims description 10
- 239000000919 ceramic Substances 0.000 claims description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
- 239000002131 composite material Substances 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
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- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
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- 230000002708 enhancing effect Effects 0.000 claims description 5
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- 229910052570 clay Inorganic materials 0.000 claims description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 4
- 238000002203 pretreatment Methods 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- 238000005245 sintering Methods 0.000 claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 230000001133 acceleration Effects 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 abstract description 2
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- 238000012986 modification Methods 0.000 description 5
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- 239000000376 reactant Substances 0.000 description 4
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- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 238000005882 aldol condensation reaction Methods 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005842 biochemical reaction Methods 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
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- 230000007547 defect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000004136 fatty acid synthesis Effects 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
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- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000010747 number 6 fuel oil Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002468 redox effect Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000011345 viscous material Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention discloses a preparation device of high-hydrogen biological fuel oil, which comprises: control system, heating system and reaction system, reaction system includes: the device comprises an activated water generation device, a carbide storage tank, a vegetable oil enzyme catalyst storage tank, a fuel oil storage tank, a first reaction kettle, a second reaction kettle, a third reaction kettle, a finished oil treatment device and a finished oil storage tank, wherein outlets of the carbide storage tank and the vegetable oil enzyme catalyst storage tank are respectively connected with an inlet of the first reaction kettle through a pipeline, an outlet of the first reaction kettle and an outlet of the activated water generation device are respectively connected with an inlet of the second reaction kettle through a pipeline, an outlet of the second reaction kettle and an outlet of the fuel oil storage tank are respectively connected with an inlet of the third reaction kettle through a pipeline, and an outlet of the third reaction kettle is sequentially connected with the finished oil treatment device and the finished oil storage tank. By adopting the device provided by the invention, the increase (30% -50%) is achieved under the premise of not changing the molecular structure of the raw oil.
Description
Technical Field
The invention relates to the technical field of energy preparation, in particular to a preparation device of high-hydrogen bio-fuel oil.
Background
At present, in order to solve the problem of high use cost of fossil fuel, some techniques for reducing the production cost of fossil fuel have been developed. Among them, emulsified oil fuels, which are formed by adding water to oil, have been put to practical use in some fields. In recent years, a proposal has been made to mix enzyme water with oil and to convert the oil water into water-added fuel by using a special device. However, these methods have a lower calorific value than the raw oil, and the oil and water are separated again after a certain storage period, so that the fuel needs to be increased to compensate for the above problem, and the fuel saving effect is not achieved as a whole. Further, a technique called BDF using a vegetable oil refined fuel oil has also appeared, but has not been established as a general fuel oil because of the rise in market price of vegetable raw materials.
Therefore, in order to solve the problem of shortage of fuel resources, it is necessary to develop a new fuel oil preparation apparatus by which fuel oil can be increased to solve the problems of shortage of fuel and practical use.
Disclosure of Invention
In order to solve the defects in the prior art, the invention provides the following technical scheme.
The invention provides a preparation device of high-hydrogen biological fuel oil, which comprises: the system comprises a control system, a heat supply system and a reaction system, wherein the control system is used for automatically controlling the heat supply system and the reaction system, and the heat supply system is used for supplying heat to a reaction kettle and fuel oil of the reaction system; the reaction system comprises:
activated water generates device, carbide storage tank, vegetable oil enzyme catalyst storage tank, fuel oil storage tank, first reation kettle, second reation kettle, third reation kettle, finished product oil processing apparatus and finished product oil storage tank, the export of carbide storage tank and vegetable oil enzyme catalyst storage tank respectively through the pipeline with first reation kettle's entry linkage, the export of first reation kettle and the export of activated water formation device respectively through the pipeline with second reation kettle's entry linkage, second reation kettle's export with the export of fuel oil storage tank respectively through the pipeline with third reation kettle's entry linkage, third reation kettle's export connects gradually finished product oil processing apparatus and finished product oil storage tank.
Preferably, the activated water generating apparatus comprises, connected in series: the device comprises a first sterilization and filtration device, a first water pretreatment device, a second water pretreatment device, an electrolytic water device, a stability enhancement device, a second sterilization and filtration device, a nanometer acceleration device and an activated water storage tank.
Preferably, obsidian is filled in the first water pretreatment device, tourmaline is filled in the second water pretreatment device, and a metal aluminum and ceramic ball composite material is filled in the stability enhancement device, wherein the ceramic ball composite material is formed by sintering tourmaline micropowder, clay, silicon and aluminum oxide at 800-1000 ℃.
Preferably, the product oil treatment device comprises: a solid-liquid separator, an oil-water separator and a filter element.
Preferably, the second reaction kettle comprises a kettle body and a stirring device arranged in the kettle body, the stirring device comprises a stirring shaft, the upper part of the stirring shaft is provided with a stirring paddle, the lower part of the stirring shaft is provided with a support, the upper part of the support is rotatably connected with a stirring pressure plate, the lower part of the support is rotatably connected with a compression roller, two ends of the compression roller are provided with connecting plates, and the connecting plates are rotatably connected with stirring pressure plates.
Preferably, the stirring shaft is a telescopic stirring shaft.
Preferably, the support comprises three branch supports uniformly arranged along the circumference, the upper part of each branch support is rotatably connected with a stirring pressing plate, the lower part of each branch support is rotatably connected with a pressing roller, two ends of each pressing roller are provided with connecting plates, and the connecting plates are rotatably connected with stirring pressing sheets.
Preferably, two ends of the stirring pressure plate are respectively rotatably connected with the branch frame through first connecting shafts, one end of each first connecting shaft is fixedly connected with the branch frame, and the other end of each first connecting shaft is rotatably connected with the stirring pressure plate.
Preferably, two ends of the press roller are respectively rotatably connected with the sub-frame through a second connecting shaft, one end of the second connecting shaft is fixedly connected with the sub-frame, and the other end of the second connecting shaft is rotatably connected with the press roller.
Preferably, one end of the connecting plate is fixed on the second connecting shaft, the other end of the connecting plate is fixedly connected with one end of a third connecting shaft, and the other end of the third connecting shaft is rotatably connected with the stirring pressing sheet. The invention has the beneficial effects that:
by adopting the device provided by the invention, water is electronegatively activated to form activated water, the activated water and carbide react under the condition of vegetable oil enzyme catalyst, and finally the reactant is mixed with fuel oil (including diesel oil, aviation diesel oil, bunker fuel oil and naphtha) to obtain the high-hydrogen bio-fuel oil, so that the aim of increment (30% -50%) can be achieved on the premise of not changing the molecular structure of the raw oil. Greatly contributes to greatly saving fuel cost for enterprises. Meanwhile, 30% of petroleum import amount in China can be reduced, so that the risk of petroleum import is greatly reduced, in addition, haze treatment is realized, carbon dioxide emission is reduced, the overall air quality in China is improved, the ecological environment is protected, and all the effects of constructivity are achieved.
Drawings
FIG. 1 is a schematic structural diagram of a high hydrogen bio-fuel oil preparation device according to the present invention;
FIG. 2 is a schematic structural diagram of a second reaction vessel according to the present invention.
In the figure, the meaning of each symbol is as follows:
the device comprises a first sterilization and filtration device 1, a first pretreatment water device 2, a second pretreatment water device 3, an electrolytic water device 4, a stability enhancing device 5, a second sterilization and filtration device 6, a nanometer accelerating device 7, an activated water storage tank 8, a carbide storage tank 9, a vegetable oil enzyme catalyst storage tank 10, a first reaction kettle 11, a second reaction kettle 12, a fuel oil storage tank 13, a third reaction kettle 14, a solid-liquid separator 15, an oil-water separator 16, a filter element 17 and a finished oil storage tank 18.
Detailed Description
In order to better understand the technical solution, the technical solution will be described in detail with reference to the drawings and the specific embodiments.
As shown in fig. 1, an embodiment of the present invention provides a device for preparing high hydrogen bio-fuel oil, including: the system comprises a control system, a heat supply system and a reaction system, wherein the control system is used for automatically controlling the heat supply system and the reaction system, and the heat supply system is used for supplying heat to a reaction kettle and fuel oil of the reaction system; the reaction system comprises:
the device comprises an activated water generating device, a carbide storage tank 9, a vegetable oil enzyme catalyst storage tank 10, a fuel oil storage tank 13, a first reaction tank 11, a second reaction tank 12, a third reaction tank 14, a finished oil treatment device and a finished oil storage tank 18, wherein outlets of the carbide storage tank 9 and the vegetable oil enzyme catalyst storage tank 10 are respectively connected with an inlet of the first reaction tank 11 through a pipeline, an outlet of the first reaction tank 11 and an outlet of the activated water generating device are respectively connected with an inlet of the second reaction tank 12 through pipelines, an outlet of the second reaction tank 12 and an outlet of the fuel oil storage tank 13 are respectively connected with an inlet of the third reaction tank 14 through a pipeline, and an outlet of the third reaction tank 14 is sequentially connected with the finished oil treatment device and the finished oil storage tank 18.
In the device provided by the embodiment of the invention, the control system can control the reaction and the heating process to be automatically carried out through a preset control program, an actuator and the like, so that the labor cost is saved. The heat supply system can supply heat to the part needing to be heated in the reaction system by connecting a heat source so as to meet the requirement of reaction temperature. The reaction system completes the reaction under the coordination of the control system and the heat supply system to prepare the high-hydrogen bio-fuel oil. Wherein, the working process of the reaction system is as follows:
in the reaction system, the carbide stored in the carbide storage tank can be industrial carbide, and the particle size distribution of the carbide is uniform. The vegetable oil enzyme catalyst stored in the vegetable oil enzyme catalyst storage tank may be an enzyme catalyst extracted from vegetable oil such as coconut oil or linseed oil.
The working process of the reaction system is as follows: firstly, feeding an enzyme catalyst and carbide into a first reaction kettle, mixing and uniformly stirring to enable the enzyme catalyst to be adsorbed in the carbide, namely implanting the enzyme catalyst into the carbide to generate an embryo; then, the produced embryo and activated water are sent into a second reaction kettle to be mixed and stirred uniformly, the activated water and carbide are subjected to chemical reaction, and free radicals of the water and the activated water are subjected to aldol condensation reaction to obtain the basic fatty acid. Wherein, the hydrogen element required for basic fatty acid synthesis comes from water, and is decomposed by biological enzyme to cut off water molecular groups (deoxidized O, dehydro-oxo-OH). At this time, the remaining oxygen in the activated water reacts with the carbide by oxidation, resulting in carbonization. The obtained basic fatty acid and the added biological enzyme catalyst are activated to generate addition reaction, long-chain fatty acid such as palmitic acid, oleic acid and the like is synthesized along with repeated synthesis, the synthesized palmitic acid is separated from free radical OH by virtue of the activation reaction, and the synthesized palmitic acid is converted into petroleum alkane from grease; then, the reactant obtained in the second reaction kettle and the fuel oil in the fuel oil storage tank are sent into a third reaction kettle, and the alkane and the mineral oil (such as C16H32) are mixed to obtain the high-hydrogen bio-fuel oil with the same molecular structure and molecular weight as the raw oil.
In a preferred embodiment of the present invention, the activated water generating apparatus comprises, connected in series: the device comprises a first sterilization and filtration device 1, a first pre-treatment water device 2, a second pre-treatment water device 3, an electrolytic water device 4, a stability enhancement device 5, a second sterilization and filtration device 6, a nanometer acceleration device 7 and an activated water storage tank 8.
Wherein the first water pretreatment device 2 is filled with obsidian, the second water pretreatment device 3 is filled with tourmaline, the stability enhancement device 5 is filled with metal aluminum and ceramic ball composite material, and the ceramic ball composite material is formed by sintering tourmaline micropowder, clay, silicon and aluminum oxide at 800-1000 ℃.
The process of preparing the activated water by adopting the device with the structure can be as follows:
step 1: tap water or underground water contains substances such as sand, rust and the like, so that the tap water firstly passes through the first sterilization and filtration device to obtain clean water, and then the clean water can be stored in a water tank and directly taken from the water tank when in use.
The method comprises the steps of pressurizing clean tap water and underground water through a booster water pump to enable the tap water and the underground water to have large fall, sequentially passing through a first water pretreatment device and a second water pretreatment device, namely sequentially passing through obsidian and tourmaline (the obsidian and the tourmaline have certain redox effect) in natural ore, and further enhancing the reduction power by using the pressure of the tap water or the pressure of the booster water pump. (the water pressure of tap water is generally 0.14 MPa 0.1Mpa corresponding to 10M drop height), the secondary pressurization of the booster water pump reaches 3 to 5 Mpa, so that 300 to 500M drop height is formed between obsidian and tourmaline, which is the same as the environment of natural waterfall.
The water molecules collide with the negatively charged obsidian violently, so that the water molecule groups are changed and the high-energy state is achieved.
Step 2: and (3) connecting the water treated in the step (1) with a water electrolysis device. The active water with the reduction potential more than negative 800mV, the PH value more than 12 and the active hydrogen content more than 1.2PPM is obtained by electrolysis.
And step 3: and (3) connecting the active water obtained after the electrolysis treatment with a stability enhancing device, improving the stability of the reduction potential of the active water obtained in the step (2), and enabling the metal aluminum and ceramic ball composite material added in the enhancing device to achieve the purpose of stably maintaining the reduction potential unchanged. In order to enhance the interfacial tension of the reduced water and stabilize the reinforcing device, a metal aluminum foil is used as a material, and the characteristics of the metal aluminum foil that the metal aluminum foil reflects electric waves and the ceramic ball composite material can emit far infrared rays with the size of 4-14 microns are utilized (the ceramic ball used in the stabilization reinforcing device is formed by mixing tourmaline micro powder with clay, silicon, aluminum oxide and the like and then sintering at 800-1000 ℃). The micro current generated by the mutual collision of the electrons enables the surface tension of the water to be 2.3 times of that of the raw material water, and the micro current has certain energy to enable the molecular group to reach 75 HZ.
And 4, step 4: and (3) sequentially passing the water treated in the step (3) through a second sterilization and filtration device, such as an ultraviolet sterilization device and a filter with the diameter of 0.3mm, and removing impurities, microorganisms affecting biochemical reactions and other substances in the water.
And 5: the nano-accelerator is connected with the filter in step 4 (the jet speed of the nano-accelerator can reach 340(m/sec) ≈ 1224(km/hour), and as a result, the collision speed is 2 times of the sound speed, and reaches 2448(km/hour), and the molecular chain of water can be broken and pulverized instantly by the speed.
The activated water is prepared by the above treatment.
In a preferred embodiment of the present invention, the product oil treatment device comprises, connected in sequence: a solid-liquid separator 15, an oil-water separator 16 and a filter element 17.
The solid-liquid separator is used for separating solid and liquid in the mixture to obtain liquid, the liquid contains water in addition to oil to be prepared, the water is removed by adopting an oil-water separator to obtain oil, and finally the oil is filtered by a filter element to prepare the final high-hydrogen bio-fuel oil.
As shown in fig. 2, in a preferred embodiment of the present invention, the second reaction vessel 12 includes a vessel body and a stirring device disposed in the vessel body, the stirring device includes a stirring shaft 20, an upper portion of the stirring shaft 20 is provided with a stirring paddle 21, a lower portion of the stirring shaft 20 is provided with a support 22, an upper portion of the support 22 is rotatably connected with a stirring pressure plate 23, a lower portion of the support 22 is rotatably connected with a pressing roller 24, two ends of the pressing roller 24 are provided with connecting plates, and the connecting plates are rotatably connected with stirring pressure plates 25.
Wherein, the stirring shaft rotates and can drive stirring rake and support rotation, and the support rotation can drive stirring clamp plate, compression roller and stirring preforming on it and rotate. In addition, the stirring pressing plate, the pressing roller and the stirring pressing sheet can rotate around the shaft of the stirring pressing plate, the pressing roller and the stirring pressing sheet under the action of the materials. Therefore, materials are stirred for many times from different angles, and viscous substances or porous substances with reaction groups in holes can be fully contacted to react. As an example, for example, the reactant of the carbide and the vegetable oil enzyme catalyst and the activated water are mixed in the second reaction kettle, and the stirring device can realize that the activated water molecules enter the pores of the carbide, fully contact with the carbide, the vegetable oil enzyme catalyst and the reactant thereof, and react.
Wherein the stirring shaft 20 is a telescopic stirring shaft.
Adopt above-mentioned structure, can adjust the height of stirring rake and support to satisfy the stirring demand to the not co-altitude material, and the stirring demand of different stirring degree.
In this embodiment, the support 22 includes three sub-supports uniformly arranged along the circumference, the upper portion of each sub-support is rotatably connected with a stirring pressing plate 23, the lower portion of each sub-support is rotatably connected with a pressing roller 24, two ends of each pressing roller 24 are provided with connecting plates, and the connecting plates are rotatably connected with stirring pressing plates 25.
Wherein the structure of all the branch frames and the arrangement on the branch frames are the same.
As can be appreciated by those skilled in the art, the number of the branch racks can be set artificially according to actual needs, and the branch racks are generally uniformly arranged in order to achieve uniform stirring.
In this embodiment, three sub-frames are provided, and each sub-frame may have a structure that: including a horizontal pole and two montants, the one end of horizontal pole is connected in the axis of rotation, two montant parallel arrangement, and its one end is connected on the horizontal pole, and stirring clamp plate, compression roller and stirring preforming all directly or indirectly connect on two montants. The included angle between the three cross rods of the three branch brackets is 120 degrees.
In a preferred embodiment of the present invention, the stirring blade 25 is disposed in parallel with the stirring platen 23.
Adopt above-mentioned structure, can be so that stirring preforming and stirring clamp plate cooperation work, to the better stirring of material. Stirring clamp plate is last, and the stirring preforming is under, can increase the stirring dynamics to the material, makes the contact between the material more abundant, for example can make one of them material can enter into the downthehole of another kind of material, thereby adsorbed reaction group in downthehole or the contact hole takes place to react.
In this embodiment, two ends of the stirring platen 23 are rotatably connected to the sub-frame through first connecting shafts, respectively, one end of each first connecting shaft is fixedly connected to the sub-frame, and the other end of each first connecting shaft is rotatably connected to the stirring platen 23.
Wherein, first coupling shaft is connected immovably on the feeder pillar, and stirring clamp plate can rotate around first coupling shaft under the flow effect of material, and first coupling shaft can install on stirring clamp plate's axis. The stirring clamp plate pivoted in-process has realized the regulation to its angle to the realization is to the stirring of different angles of material.
In this embodiment, two ends of the pressing roller 24 are respectively rotatably connected to the sub-frame through a second connecting shaft, one end of the second connecting shaft is fixedly connected to the sub-frame, and the other end of the second connecting shaft is rotatably connected to the pressing roller 24.
The second connecting shaft is fixedly connected to the branch frame, the press roller can rotate around the second connecting shaft under the flowing action of materials, and the second connecting shaft can be installed on the axis of the press roller. The compression roller pivoted in-process has realized the regulation to its angle to the realization is to the stirring of different angles of material.
In this embodiment, one end of the connecting plate is fixed to the second connecting shaft, the other end of the connecting plate is fixedly connected to one end of a third connecting shaft, and the other end of the third connecting shaft is rotatably connected to the stirring blade 25.
Wherein, the second connecting axle is connected immovably on the feeder pillar, and the one end of connecting plate is connected immovably on the second connecting axle, and the other end immovably at the connecting plate is connected to the third connecting axle, and the stirring preforming can rotate around the third connecting axle under the mobile effect of material, and the third connecting axle can be installed on the axis of stirring preforming. The stirring preforming pivoted in-process has realized the regulation to its angle to the realization is to the stirring of the different angles of material.
The stirring device provided by the invention further comprises a motor 19, and a rotating shaft of the motor 19 is connected with the stirring shaft 20.
By using the structure, the motor is started to drive the stirring shaft to rotate, and the rotating speed of the stirring shaft can be adjusted by adjusting the rotating speed of the motor.
While preferred embodiments of the present invention have been described, additional variations and modifications in those embodiments may occur to those skilled in the art once they learn of the basic inventive concepts. Therefore, it is intended that the appended claims be interpreted as including preferred embodiments and all such alterations and modifications as fall within the scope of the invention. It will be apparent to those skilled in the art that various changes and modifications may be made in the present invention without departing from the spirit and scope of the invention. Thus, if such modifications and variations of the present invention fall within the scope of the claims of the present invention and their equivalents, the present invention is also intended to include such modifications and variations.
Claims (10)
1. A preparation facilities of high hydrogen biofuel oil, characterized by includes: the system comprises a control system, a heat supply system and a reaction system, wherein the control system is used for automatically controlling the heat supply system and the reaction system, and the heat supply system is used for supplying heat to a reaction kettle and fuel oil of the reaction system; the reaction system comprises:
activated water generates device, carbide storage tank, vegetable oil enzyme catalyst storage tank, fuel oil storage tank, first reation kettle, second reation kettle, third reation kettle, finished product oil processing apparatus and finished product oil storage tank, the export of carbide storage tank and vegetable oil enzyme catalyst storage tank respectively through the pipeline with first reation kettle's entry linkage, the export of first reation kettle and the export of activated water formation device respectively through the pipeline with second reation kettle's entry linkage, second reation kettle's export with the export of fuel oil storage tank respectively through the pipeline with third reation kettle's entry linkage, third reation kettle's export connects gradually finished product oil processing apparatus and finished product oil storage tank.
2. The apparatus for producing a high hydrogen bio-fuel oil according to claim 1, wherein said activated water generating means comprises, connected in sequence: the device comprises a first sterilization and filtration device, a first water pretreatment device, a second water pretreatment device, an electrolytic water device, a stability enhancement device, a second sterilization and filtration device, a nanometer acceleration device and an activated water storage tank.
3. The apparatus for preparing high-hydrogen bio-fuel oil according to claim 2, wherein the first pre-treatment water device contains obsidian, the second pre-treatment water device contains tourmaline, and the stability enhancing device contains a composite material of metal aluminum and ceramic balls, wherein the composite material of ceramic balls is prepared by sintering tourmaline micropowder, clay, silicon and aluminum oxide at 800-1000 ℃.
4. The apparatus for preparing high hydrogen bio-fuel oil according to claim 1, wherein the product oil treatment apparatus comprises: a solid-liquid separator, an oil-water separator and a filter element.
5. The device for preparing high-hydrogen biofuel oil according to claim 1, wherein the second reaction kettle comprises a kettle body and a stirring device arranged in the kettle body, the stirring device comprises a stirring shaft, the upper part of the stirring shaft is provided with a stirring paddle, the lower part of the stirring shaft is provided with a support, the upper part of the support is rotatably connected with a stirring pressure plate, the lower part of the support is rotatably connected with a compression roller, two ends of the compression roller are provided with connecting plates, and the connecting plates are rotatably connected with stirring pressure plates.
6. The apparatus for preparing high hydrogen bio-fuel oil according to claim 5, wherein said stirring shaft is a retractable stirring shaft.
7. The apparatus for preparing biofuel oil of claim 5, wherein the support comprises three sub-supports uniformly arranged along the circumference, each sub-support has an upper portion rotatably connected with a stirring platen and a lower portion rotatably connected with a compression roller, the compression roller has two ends provided with connection plates, and the connection plates are rotatably connected with stirring blades.
8. The apparatus for preparing biofuel oil according to claim 7, wherein both ends of the stirring platen are rotatably connected to the sub-frame by a first connecting shaft, respectively, one end of the first connecting shaft is fixedly connected to the sub-frame, and the other end of the first connecting shaft is rotatably connected to the stirring platen.
9. The apparatus for preparing biofuel oil according to claim 7, wherein both ends of the compression roller are rotatably connected to the sub-frame by a second connecting shaft, respectively, one end of the second connecting shaft is fixedly connected to the sub-frame, and the other end of the second connecting shaft is rotatably connected to the compression roller.
10. The apparatus for preparing biofuel oil of claim 9, wherein one end of the connecting plate is fixed to the second connecting shaft, and the other end of the connecting plate is fixedly connected to one end of a third connecting shaft, and the other end of the third connecting shaft is rotatably connected to the stirring blade.
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| CN202011453177.9A CN112430474A (en) | 2020-12-11 | 2020-12-11 | Preparation device of high-hydrogen biological fuel oil |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101475824A (en) * | 2009-01-22 | 2009-07-08 | 王立 | Wash-free, energy-saving and environment friendly technological process and system apparatus for producing clean fuel oil |
| CN214142197U (en) * | 2020-12-11 | 2021-09-07 | 辽宁中瀛科技有限公司 | Preparation device of high-hydrogen biological fuel oil |
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2020
- 2020-12-11 CN CN202011453177.9A patent/CN112430474A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101475824A (en) * | 2009-01-22 | 2009-07-08 | 王立 | Wash-free, energy-saving and environment friendly technological process and system apparatus for producing clean fuel oil |
| CN214142197U (en) * | 2020-12-11 | 2021-09-07 | 辽宁中瀛科技有限公司 | Preparation device of high-hydrogen biological fuel oil |
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