CN112401219A - Compound cooling agent composition based on menthol and preparation method thereof - Google Patents
Compound cooling agent composition based on menthol and preparation method thereof Download PDFInfo
- Publication number
- CN112401219A CN112401219A CN202011370070.8A CN202011370070A CN112401219A CN 112401219 A CN112401219 A CN 112401219A CN 202011370070 A CN202011370070 A CN 202011370070A CN 112401219 A CN112401219 A CN 112401219A
- Authority
- CN
- China
- Prior art keywords
- menthol
- cooling agent
- agent composition
- compound cooling
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 title claims abstract description 51
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 title claims abstract description 50
- 229940041616 menthol Drugs 0.000 title claims abstract description 50
- 239000002826 coolant Substances 0.000 title claims abstract description 39
- 239000000203 mixture Substances 0.000 title claims abstract description 35
- 150000001875 compounds Chemical class 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- RWAXQWRDVUOOGG-UHFFFAOYSA-N N,2,3-Trimethyl-2-(1-methylethyl)butanamide Chemical compound CNC(=O)C(C)(C(C)C)C(C)C RWAXQWRDVUOOGG-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229920002472 Starch Polymers 0.000 claims abstract description 7
- 235000019698 starch Nutrition 0.000 claims abstract description 7
- 239000008107 starch Substances 0.000 claims abstract description 7
- 238000002844 melting Methods 0.000 claims abstract description 5
- 230000008018 melting Effects 0.000 claims abstract description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 238000001816 cooling Methods 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 4
- 238000004026 adhesive bonding Methods 0.000 claims description 3
- 239000011363 dried mixture Substances 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000010992 reflux Methods 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 abstract description 3
- 238000002425 crystallisation Methods 0.000 abstract description 2
- 230000008025 crystallization Effects 0.000 abstract description 2
- 238000010828 elution Methods 0.000 abstract description 2
- 230000005496 eutectics Effects 0.000 abstract description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 230000035597 cooling sensation Effects 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 125000004172 4-methoxyphenyl group Chemical group [H]C1=C([H])C(OC([H])([H])[H])=C([H])C([H])=C1* 0.000 description 1
- 206010006784 Burning sensation Diseases 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000019658 bitter taste Nutrition 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002500 effect on skin Effects 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- ZHNUHDYFZUAESO-UHFFFAOYSA-N formamide Substances NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 1
- 210000000214 mouth Anatomy 0.000 description 1
- 210000002200 mouth mucosa Anatomy 0.000 description 1
- 235000019633 pungent taste Nutrition 0.000 description 1
- 235000019640 taste Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/03—Organic compounds
- A23L29/035—Organic compounds containing oxygen as heteroatom
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/30—Foods or foodstuffs containing additives; Preparation or treatment thereof containing carbohydrate syrups; containing sugars; containing sugar alcohols, e.g. xylitol; containing starch hydrolysates, e.g. dextrin
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Nutrition Science (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Molecular Biology (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a compound cooling agent composition based on menthol, which comprises 80-95% of menthol and 5-20% of cooling agent A; wherein the cooling agent A is one or two selected from WS-3, WS-5, WS-12 and WS-23. The invention uses the menthol which has pure cool feeling, strong impact force and long duration. The preparation process is simple to operate, a certain amount of soluble starch is added to form a powder state at normal temperature, eutectic melting at low temperature is avoided, and the addition purity is up to more than 99% by using a step of elution crystallization.
Description
Technical Field
The invention relates to the field of food, in particular to a compound cooling agent composition based on menthol and a preparation method thereof.
Background
Menthol is a natural cooling agent, has the advantages of strong cooling degree, low threshold value, low price and the like, and can generate cooling effect on skin and oral cavity, so the menthol is widely applied to edible essence and tobacco essence for a long time, and can provide fresh and cool feeling for consumers in the consumption process. Meanwhile, the use of the tea is limited by the defects of strong pungent smell, bitter taste, burning sensation when the concentration is high, strong volatility and the like. Then, people have made extensive research on the derivatives of menthol, and have developed a WS series of cooling agents, which have the following characteristics: compared with menthol, the product has no strong pungent taste, strong impact, low volatility and good compatibility; the product has pure smell, freshness and naturalness, lasting cool feeling and good tolerance for human body; the lower threshold value is adopted, and the cool feeling intensity is high; has strong cool feeling to the skin and the oral mucosa, thereby having wide application field; compared with the traditional cooling agent, the addition amount of the cooling agent is small.
However, the single WS-series cooling agents have many disadvantages, such as strong impact force on WS-5, too concentrated cooling sensation, and less lasting than menthol.
Disclosure of Invention
The invention provides a compound cooling agent composition based on menthol and a preparation method thereof, and the cooling agent composition is reasonably prepared, so that the cooling threshold value of the cooling agent is moderate, the matching performance is good, and the impact force durability is reasonably controlled.
In order to achieve the purpose, the invention adopts the following technical scheme:
the compound cooling agent composition based on menthol is characterized by comprising 80-95% of menthol and 5-20% of cooling agent A; wherein the cooling agent A is one or two selected from WS-3, WS-5, WS-12 and WS-23.
Preferably, the menthol and the WS-3 are mixed according to the following proportion, wherein the content of the menthol is 85-95%, the content of the WS-3 is 5-15%, further, the content of the menthol is 92-95%, and the content of the WS-3 is 5-8%.
Preferably, the menthol and the WS-5 are mixed according to the following proportion, wherein the content of the menthol is 90-95%, and the content of the WS-5 is 5-10%.
Preferably, the menthol and the WS-12 are mixed according to the following proportion, wherein the content of the menthol is 85-90%, and the content of the WS-12 is 10-15%.
Preferably, the menthol and the WS-23 are mixed according to the following proportion, wherein the content of the menthol is 88-95%, and the content of the WS-23 is 5-12%.
Preferably, the cooling agent A comprises WS-5 and WS-23, wherein the content of the WS-5 is 5-8%, and the content of the WS-23 is 2-5%.
A method for preparing a compound cooling agent composition based on menthol comprises the following steps,
dissolving weighed menthol in ethanol, adding 5-20% of cooling agent A after dissolving, and heating to reflux temperature for 1-3 hours;
adding sufficient water into the solution, filtering out the solvent after the mixture is separated out, and pushing the mixture into a drying room for drying;
step three, hot melting the dried mixture, adding soluble starch into the hot melted mixture for gluing, and then cooling to room temperature; grinding the mixture into micropowder with a grinder to obtain the composition.
Further, in the first step and the second step, the ratio of the ethanol to the water is 1: 5-10.
Further, the mass content of the soluble starch is 0.1-0.5%.
The invention has the beneficial effects that: the invention uses the menthol which has pure cool feeling, strong impact force and long duration. The preparation process is simple to operate, a certain amount of soluble starch is added to form a powder state at normal temperature, eutectic melting at low temperature is avoided, and the addition purity is up to more than 99% by using a step of elution crystallization.
Detailed Description
The technical solution of the present invention is further explained by the following embodiments.
Example 1, a menthol-based compound cooling agent composition comprises menthol and a cooling agent a, wherein the menthol content is 80-95%, and the cooling agent a content is 5-20%; the cooling agent A is selected from one or two of WS-3, WS-5, WS-12 and WS-23, wherein WS-3, WS-5, WS-12 and WS-23 respectively refer to N-ethyl-p-menthyl-3-formamide, acetic acid (N-ethyl-p-menthyl-3-carboxamide) ethyl ester, (1R,2S,5R) -N- (4-methoxyphenyl) -p-menthyl-3-carboxamide and N, 2, 3-trimethyl-2-isopropyl butanamide.
Embodiment the compositions are formulated as in table 1:
TABLE 1
Dissolving menthol weighed by the components in the table 1 in ethanol, adding 5-20% of cooling agent A after dissolving, and heating to reflux temperature for 1-3 hours; adding sufficient water into the solution, filtering out the solvent after the mixture is separated out, and pushing the mixture into a drying room for drying; hot melting the dried mixture, adding 0.1-0.5% of soluble starch into the hot-melted mixture for gluing, and then cooling to room temperature; grinding the mixture into micropowder with a grinder to obtain the composition.
The powder prepared from the components is prepared into a concentration of 100ppm, different groups of people are aged from 12 to 60 years, cool feeling tests are carried out, and the test results are averaged as shown in table 2:
TABLE 2
As can be seen from Table 2 above, the cooling agent composition based on menthol of the present invention not only has a higher cooling value than menthol, but also has an extended duration and a reduced threshold, resulting in a moderate cooling sensation, an enhanced impact force, and a pure taste.
The technical principle of the present invention is described above in connection with specific embodiments. The description is made for the purpose of illustrating the principles of the invention and should not be construed in any way as limiting the scope of the invention. Based on the explanations herein, those skilled in the art will be able to conceive of other embodiments of the present invention without inventive effort, which would fall within the scope of the present invention.
Claims (9)
1. The compound cooling agent composition based on menthol is characterized by comprising 80-95% of menthol and 5-20% of cooling agent A; wherein the cooling agent A is one or two selected from WS-3, WS-5, WS-12 and WS-23.
2. The menthol-based compound cooling agent composition according to claim 1, wherein the menthol and the WS-3 are mixed in a proportion of 85-95% of menthol, 5-15% of WS-3, 92-95% of menthol and 5-8% of WS-3.
3. The menthol-based compound cooling agent composition according to claim 1, wherein the menthol is mixed with WS-5 in a proportion of 90-95% of menthol and 5-10% of WS-5.
4. The menthol-based compound cooling agent composition according to claim 1, wherein the menthol is mixed with WS-12 in a proportion of 85-90% in menthol and 10-15% in WS-12.
5. The menthol-based compound cooling agent composition according to claim 1, wherein the menthol is mixed with WS-23 in a proportion of 88-95% and 5-12% respectively.
6. The menthol-based compound cooling agent composition as claimed in claim 1, wherein the cooling agent A comprises WS-5 and WS-23, the content of the WS-5 is 5-8%, and the content of the WS-23 is 2-5%.
7. A preparation method of a compound cooling agent composition based on menthol is characterized by comprising the following steps,
dissolving weighed menthol in ethanol, adding 5-20% of cooling agent A after dissolving, and heating to reflux temperature for 1-3 hours;
adding sufficient water into the solution, filtering out the solvent after the mixture is separated out, and pushing the mixture into a drying room for drying;
step three, hot melting the dried mixture, adding soluble starch into the hot melted mixture for gluing, and then cooling to room temperature; grinding the mixture into micropowder with a grinder to obtain the composition.
8. The method for preparing a menthol-based compound cooling agent composition according to claim 7, wherein the ratio of the ethanol to the water in the first step and the second step is 1: 5-10.
9. The method for preparing a menthol-based compound cooling agent composition according to claim 7, wherein the mass content of the soluble starch is 0.1-0.5%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011370070.8A CN112401219A (en) | 2020-11-30 | 2020-11-30 | Compound cooling agent composition based on menthol and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011370070.8A CN112401219A (en) | 2020-11-30 | 2020-11-30 | Compound cooling agent composition based on menthol and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112401219A true CN112401219A (en) | 2021-02-26 |
Family
ID=74830503
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202011370070.8A Withdrawn CN112401219A (en) | 2020-11-30 | 2020-11-30 | Compound cooling agent composition based on menthol and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112401219A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115956705A (en) * | 2022-12-12 | 2023-04-14 | 深圳市吉迩科技有限公司 | Cooling agent special for atomized liquid and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104146194A (en) * | 2014-08-11 | 2014-11-19 | 安徽丰乐香料有限责任公司 | Preparation method for powdery compound cooling agent |
| CN104642983A (en) * | 2015-03-11 | 2015-05-27 | 昆山市亚香日用香料有限公司 | Compound cooling agent composition and preparation technology thereof |
| CN105166835A (en) * | 2015-09-11 | 2015-12-23 | 安徽爱迪香料股份有限公司 | Preparation method for water soluble compound cooling agent |
| CN107950983A (en) * | 2017-11-27 | 2018-04-24 | 昆山亚香香料股份有限公司 | A kind of compounding coolant agent composition based on menthol and preparation method thereof |
-
2020
- 2020-11-30 CN CN202011370070.8A patent/CN112401219A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104146194A (en) * | 2014-08-11 | 2014-11-19 | 安徽丰乐香料有限责任公司 | Preparation method for powdery compound cooling agent |
| CN104642983A (en) * | 2015-03-11 | 2015-05-27 | 昆山市亚香日用香料有限公司 | Compound cooling agent composition and preparation technology thereof |
| CN105166835A (en) * | 2015-09-11 | 2015-12-23 | 安徽爱迪香料股份有限公司 | Preparation method for water soluble compound cooling agent |
| CN107950983A (en) * | 2017-11-27 | 2018-04-24 | 昆山亚香香料股份有限公司 | A kind of compounding coolant agent composition based on menthol and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115956705A (en) * | 2022-12-12 | 2023-04-14 | 深圳市吉迩科技有限公司 | Cooling agent special for atomized liquid and preparation method thereof |
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| SE01 | Entry into force of request for substantive examination | ||
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| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20210226 |
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| WW01 | Invention patent application withdrawn after publication |