CN112399884B - 用于静电除尘器的吸附剂组合物 - Google Patents

用于静电除尘器的吸附剂组合物 Download PDF

Info

Publication number
CN112399884B
CN112399884B CN201980044391.8A CN201980044391A CN112399884B CN 112399884 B CN112399884 B CN 112399884B CN 201980044391 A CN201980044391 A CN 201980044391A CN 112399884 B CN112399884 B CN 112399884B
Authority
CN
China
Prior art keywords
calcium
magnesium compound
sorbent composition
flue gas
calcium magnesium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201980044391.8A
Other languages
English (en)
Chinese (zh)
Other versions
CN112399884A (zh
Inventor
罗德尼·傅
大卫·里昂斯
伊恩·萨拉托夫斯基
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lhoist Recherche et Developpement SA
Original Assignee
Lhoist Recherche et Developpement SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US16/032,152 external-priority patent/US10874975B2/en
Application filed by Lhoist Recherche et Developpement SA filed Critical Lhoist Recherche et Developpement SA
Publication of CN112399884A publication Critical patent/CN112399884A/zh
Application granted granted Critical
Publication of CN112399884B publication Critical patent/CN112399884B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/041Oxides or hydroxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/06Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/06Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
    • B01D53/10Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds with dispersed adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057Surface area, e.g. B.E.T specific surface area
    • B01J20/28059Surface area, e.g. B.E.T specific surface area being less than 100 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28069Pore volume, e.g. total pore volume, mesopore volume, micropore volume
    • B01J20/28071Pore volume, e.g. total pore volume, mesopore volume, micropore volume being less than 0.5 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/40Alkaline earth metal or magnesium compounds
    • B01D2251/402Alkaline earth metal or magnesium compounds of magnesium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/40Alkaline earth metal or magnesium compounds
    • B01D2251/404Alkaline earth metal or magnesium compounds of calcium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/112Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
    • B01D2253/1124Metal oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases
CN201980044391.8A 2018-07-11 2019-07-11 用于静电除尘器的吸附剂组合物 Active CN112399884B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US16/032,152 US10874975B2 (en) 2018-07-11 2018-07-11 Sorbent composition for an electrostatic precipitator
EP2018068770 2018-07-11
US16/032,152 2018-07-11
EPPCT/EP2018/068770 2018-07-11
PCT/EP2019/068758 WO2020011953A1 (en) 2018-07-11 2019-07-11 Sorbent composition for an electrostatic precipitator

Publications (2)

Publication Number Publication Date
CN112399884A CN112399884A (zh) 2021-02-23
CN112399884B true CN112399884B (zh) 2023-09-15

Family

ID=69141582

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201980044391.8A Active CN112399884B (zh) 2018-07-11 2019-07-11 用于静电除尘器的吸附剂组合物

Country Status (11)

Country Link
EP (1) EP3820607A1 (ja)
JP (1) JP7358405B2 (ja)
KR (1) KR20210031934A (ja)
CN (1) CN112399884B (ja)
BR (1) BR112021000247B1 (ja)
CA (1) CA3103171A1 (ja)
CL (1) CL2020003203A1 (ja)
CO (1) CO2020015349A2 (ja)
SG (1) SG11202100180XA (ja)
WO (1) WO2020011953A1 (ja)
ZA (1) ZA202100069B (ja)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1113613A (en) * 1964-05-20 1968-05-15 Oetker Rudolf August Adsorption or anti-caking agent and its preparation and use
US5145815A (en) * 1989-08-10 1992-09-08 Uop Regeneration of zeolitic molecular sieves with sulfur oxide absorption on soda-lime bed
PL336355A1 (en) * 1999-10-28 2001-05-07 Politechnika Wroclawska Dry method of removing impurities and pollutants from flue gas
CN1438914A (zh) * 2000-06-08 2003-08-27 清洁燃烧公司 降低酸气排放和改善静电除尘器性能的氢氧化钾烟道气注射技术
CN103240098A (zh) * 2012-02-09 2013-08-14 中国石油化工股份有限公司 一种脱除烟气中硫氧化物和氮氧化物的催化剂组合物及方法
CN104395261A (zh) * 2012-07-12 2015-03-04 勒瓦研究开发股份有限公司 混合的钙和镁化合物及其生产方法
CN105339070A (zh) * 2013-03-15 2016-02-17 Noxii国际有限公司 降低煤燃烧时的环境污染和结垢

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5087961A (ja) * 1973-12-10 1975-07-15
US4439351A (en) 1982-07-06 1984-03-27 Calgon Corporation Use of anionic or cationic polymers to lower the electrical resistivity of fly ash
US4502872A (en) 1983-03-31 1985-03-05 Combustion Engineering, Inc. Discharge electrode wire assembly for electrostatic precipitator
DE3620024A1 (de) 1986-06-13 1987-12-17 Fels Werke Peine Salzgitter Verfahren zur herstellung von feinkoernigem calciumhydroxid
US4861568A (en) * 1988-09-16 1989-08-29 Robinson Jr Melville W Process for removing sulfur dioxide from flue gases
US5223239A (en) 1990-07-24 1993-06-29 Research Corporation Technologies, Inc. Method of preparing hydrated lime
US5173279A (en) 1990-11-21 1992-12-22 Lhoist Recherche Et Developpement S.A. Method and composition for treating flue or exhaust gases utilizing modified calcium hydroxide
US5705141A (en) 1990-11-21 1998-01-06 Lhoist Researche Et Developpement S.A. Calcium and/or magnesium hydroxide, and preparation and use thereof
BE1009692A3 (fr) * 1995-10-19 1997-07-01 Lhoist Rech & Dev Sa PARTICULES DE Ca(OH)2.
EP0836878A1 (en) * 1996-10-15 1998-04-22 Dravo Lime Company Method for removing sulfur dioxide and nitrogen oxides from combustion gases
US6126910A (en) 1997-10-14 2000-10-03 Wilhelm; James H. Method for removing acid gases from flue gas
JPH11197445A (ja) * 1998-01-06 1999-07-27 Yoshizawa Lime Industry Co Ltd 排ガス処理剤およびその製造方法
US6797035B2 (en) 2002-08-30 2004-09-28 Ada Environmental Solutions, Llc Oxidizing additives for control of particulate emissions
US6803025B2 (en) 2002-12-05 2004-10-12 Frank B. Meserole Process for removing SO3/H2SO4 from flue gases
BE1016661A3 (fr) * 2005-06-28 2007-04-03 Lhoist Rech & Dev Sa Composition de chaux pulverulente, son procede de fabrication et son utilisation.
EP1967276B1 (en) 2007-03-05 2019-05-08 General Electric Technology GmbH A method of estimating the dust load of an esp, and a method and a device of controlling the rapping of an esp
US9802154B2 (en) * 2012-03-30 2017-10-31 Fuel Tech, Inc. Process for sulfur dioxide, hydrochloric acid and mercury mediation
WO2015119880A1 (en) 2014-02-04 2015-08-13 Novinda Corporation Flue-gas treatment aid

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1113613A (en) * 1964-05-20 1968-05-15 Oetker Rudolf August Adsorption or anti-caking agent and its preparation and use
US5145815A (en) * 1989-08-10 1992-09-08 Uop Regeneration of zeolitic molecular sieves with sulfur oxide absorption on soda-lime bed
PL336355A1 (en) * 1999-10-28 2001-05-07 Politechnika Wroclawska Dry method of removing impurities and pollutants from flue gas
CN1438914A (zh) * 2000-06-08 2003-08-27 清洁燃烧公司 降低酸气排放和改善静电除尘器性能的氢氧化钾烟道气注射技术
CN103240098A (zh) * 2012-02-09 2013-08-14 中国石油化工股份有限公司 一种脱除烟气中硫氧化物和氮氧化物的催化剂组合物及方法
CN104395261A (zh) * 2012-07-12 2015-03-04 勒瓦研究开发股份有限公司 混合的钙和镁化合物及其生产方法
CN105339070A (zh) * 2013-03-15 2016-02-17 Noxii国际有限公司 降低煤燃烧时的环境污染和结垢

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Fly-ash/calcium hydroxide mixtures for SO2 removal: structural properties and maximum yield;A. Garea et al.;《Chemical Engineering Journal》;19971231;第66卷;第171-179页 *
提升管内熟石灰浆液雾化脱除烟气中SO2过程的研究;高继慧等;《中国电机工程学报》;20071031;第27卷(第29期);第40-44页 *

Also Published As

Publication number Publication date
CN112399884A (zh) 2021-02-23
JP2021524374A (ja) 2021-09-13
CL2020003203A1 (es) 2021-04-16
BR112021000247B1 (pt) 2024-02-27
ZA202100069B (en) 2022-08-31
JP7358405B2 (ja) 2023-10-10
CA3103171A1 (en) 2020-01-16
BR112021000247A2 (pt) 2021-04-06
EP3820607A1 (en) 2021-05-19
CO2020015349A2 (es) 2021-03-19
WO2020011953A1 (en) 2020-01-16
KR20210031934A (ko) 2021-03-23
SG11202100180XA (en) 2021-02-25

Similar Documents

Publication Publication Date Title
RU2474762C2 (ru) Способ (варианты) и система снижения загрязнения воздуха
CN111465587A (zh) 同时进行废气清洁和补充胶结材料制造的方法
EA014304B1 (ru) Способ удаления soи soиз потока дымового газа
US20220105523A1 (en) Hydrated lime with reduced resistivity and method of manufacture
US10898876B2 (en) Sorbent composition for an electrostatic precipitator
WO2014080373A2 (en) Method for controlling the emission of polluting substances in a gaseous effluent produced by a combustion process
CN112399884B (zh) 用于静电除尘器的吸附剂组合物
CN107002994B (zh) 使用钙基材料稳定f类型的含钠粉煤灰
Sethupathi et al. Preliminary study of sulfur dioxide removal using calcined egg shell
WO2019020609A1 (en) SORBENT COMPOSITION FOR AN ELECTROSTATIC PRECIPITATOR
US10874975B2 (en) Sorbent composition for an electrostatic precipitator
US20200230570A1 (en) Sorbent composition for an electrostatic precipitator
US10974195B2 (en) Process for treating flue gases in CDS flue gas treatment
CN110997129A (zh) 用于静电除尘器的吸附剂组合物
KR101787418B1 (ko) 제련공정에서 염기도 효율 향상과 소결 배가스의 탈황 및 이산화탄소 배출 저감 기능의 저품위 생석회 조성물 및 그 제조방법
Zhang et al. Preparation and characterization of a new desulfurizer and its performance on removal of SO2
CN1031106C (zh) 用于从气流中除去氧化硫的组合物的制备方法
Yoo et al. Jong-Hyeon Jung1, Jae-Jeong Lee2, Gang-Woo Lee2
PL209613B1 (pl) Sposób suchego odsiarczania gazów spalinowych, zwłaszcza w kotłach opalanych pyłem węglowym
Kumar Investigations on the Influence of Flue Gas Conditioning on Fly Ash Characteristics

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant