CN112374464A - Method and equipment for preparing hypochlorous acid by combining ion exchange method with electrolysis method - Google Patents
Method and equipment for preparing hypochlorous acid by combining ion exchange method with electrolysis method Download PDFInfo
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- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 title claims abstract description 125
- 238000000034 method Methods 0.000 title claims abstract description 79
- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 50
- 238000005342 ion exchange Methods 0.000 title claims abstract description 38
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims abstract description 184
- 239000000243 solution Substances 0.000 claims abstract description 144
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 81
- 150000002500 ions Chemical class 0.000 claims abstract description 63
- 239000008399 tap water Substances 0.000 claims abstract description 54
- 235000020679 tap water Nutrition 0.000 claims abstract description 54
- 229910001385 heavy metal Inorganic materials 0.000 claims abstract description 47
- 239000011259 mixed solution Substances 0.000 claims abstract description 36
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 34
- 238000011045 prefiltration Methods 0.000 claims abstract description 30
- 239000008213 purified water Substances 0.000 claims abstract description 26
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims abstract description 20
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 17
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 17
- 238000006243 chemical reaction Methods 0.000 claims abstract description 15
- 238000002156 mixing Methods 0.000 claims abstract description 15
- 239000002253 acid Substances 0.000 claims abstract description 11
- 230000008569 process Effects 0.000 claims abstract description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 48
- 239000012535 impurity Substances 0.000 claims description 45
- 230000002378 acidificating effect Effects 0.000 claims description 44
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 37
- 239000003729 cation exchange resin Substances 0.000 claims description 37
- 229920000742 Cotton Polymers 0.000 claims description 24
- 239000007788 liquid Substances 0.000 claims description 24
- 239000005708 Sodium hypochlorite Substances 0.000 claims description 17
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 17
- 239000011347 resin Substances 0.000 claims description 16
- 229920005989 resin Polymers 0.000 claims description 16
- 150000001768 cations Chemical class 0.000 claims description 14
- 244000005700 microbiome Species 0.000 claims description 13
- 239000002245 particle Substances 0.000 claims description 13
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 claims description 11
- 238000004519 manufacturing process Methods 0.000 claims description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 8
- 238000005273 aeration Methods 0.000 claims description 8
- 239000007789 gas Substances 0.000 claims description 8
- SATVIFGJTRRDQU-UHFFFAOYSA-N potassium hypochlorite Chemical compound [K+].Cl[O-] SATVIFGJTRRDQU-UHFFFAOYSA-N 0.000 claims description 8
- 239000008055 phosphate buffer solution Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- 239000003929 acidic solution Substances 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 4
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims description 4
- 229910000403 monosodium phosphate Inorganic materials 0.000 claims description 4
- 235000019799 monosodium phosphate Nutrition 0.000 claims description 4
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 2
- XTEGARKTQYYJKE-UHFFFAOYSA-N chloric acid Chemical compound OCl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-N 0.000 claims description 2
- 229940005991 chloric acid Drugs 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- 238000000746 purification Methods 0.000 claims 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract description 4
- 238000001514 detection method Methods 0.000 description 15
- 239000000645 desinfectant Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 230000006872 improvement Effects 0.000 description 8
- 239000000460 chlorine Substances 0.000 description 7
- 229910052801 chlorine Inorganic materials 0.000 description 7
- -1 chlorine ions Chemical class 0.000 description 5
- 238000003860 storage Methods 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- 241000282414 Homo sapiens Species 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 208000035473 Communicable disease Diseases 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000005341 cation exchange Methods 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- 230000000249 desinfective effect Effects 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 229910000397 disodium phosphate Inorganic materials 0.000 description 1
- 235000019800 disodium phosphate Nutrition 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 235000012055 fruits and vegetables Nutrition 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000036737 immune function Effects 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 244000000010 microbial pathogen Species 0.000 description 1
- 210000004877 mucosa Anatomy 0.000 description 1
- 210000000440 neutrophil Anatomy 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/04—Hypochlorous acid
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/24—Halogens or compounds thereof
- C25B1/26—Chlorine; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Treatment Of Water By Ion Exchange (AREA)
Abstract
The invention discloses a method and equipment for preparing hypochlorous acid by combining an ion exchange method with an electrolysis method, wherein the preparation method comprises the following steps: s1, treating tap water by adopting a pre-filter to obtain purified water; s2, adding hypochlorite solution and purified water into the hypochlorite solution diluter to obtain hypochlorite diluted solution; s3, adding the hypochlorite solution and the acid solution into a mixer for mixing reaction; or carbon dioxide gas is conveyed into the mixer through a pipeline to carry out mixing reaction; s4, carrying out ion exchange on the hypochlorous acid mixed solution through an ion exchanger; and S5, introducing the hypochlorous acid mixed solution into an electrolysis device for electrolysis to convert chloride ions in the solution into hypochlorous acid molecules, so as to reduce the content of the chloride ions in the solution and remove heavy metal ions. The method has simple process, can effectively remove heavy metal ions in the hypochlorous acid, effectively reduce the content of chloride ions in the solution, and improve the concentration of the hypochlorous acid, thereby effectively improving the concentration and stability of the hypochlorous acid.
Description
Technical Field
The invention relates to a method for preparing hypochlorous acid by combining an ion exchange method with an electrolytic method, and also relates to equipment for the preparation method.
Background
The disinfectant is used for killing pathogenic microorganisms on the transmission medium, so that the transmission medium meets the harmless requirement, and meanwhile, the disinfectant can cut off the transmission path of infectious diseases, so that the purpose of controlling the infectious diseases is achieved. At present, the disinfectants used on the surfaces of objects mainly comprise ozone disinfectants, alcohol disinfectants and chlorine disinfectants, wherein the chlorine disinfectants have wide application range and can be used for disinfecting human skin mucosa, drinking water, tableware, fruits and vegetables, environment and the like.
Chlorine disinfectant among the prior art is mainly sodium hypochlorite or calcium hypochlorite, and sodium hypochlorite or calcium hypochlorite can not directly be regarded as the disinfectant and use, need dilute sodium hypochlorite or calcium hypochlorite with water, utilize the hypochlorous acid that exists in sodium hypochlorite solution or the calcium hypochlorite solution to disinfect, and the hypochlorous acid molecule can permeate to the bacterium surface of taking the burden electricity to penetrate the cell wall and get into inside the cell, and the strong oxidizing property of hypochlorous acid can destroy the enzyme system of bacterium and make the bacterium die. For example, Chinese patent application No. 201010192336.4 discloses a method for preparing a long-acting sodium hypochlorite aqueous solution, which comprises the steps of taking 221g of sodium hypochlorite solid with 2 molecules of crystal water, adding water to prepare 1000mL of a solution with the molar concentration of 2mol/L, then adding 2.21g of a stabilizing agent into the solution, stirring for 15 minutes, standing and clarifying the stirred solution for 30 minutes, removing precipitates in the standing solution, and collecting the clarified solution to obtain 1151g of the long-acting sodium hypochlorite aqueous solution with the mass concentration of 7.72%.
Hypochlorous acid has been demonstrated internationally as one of the highly effective disinfecting and sterilizing products. The slightly acidic hypochlorous acid water is colorless and odorless electrolytic water with pH value of 4.0-6.8 and high bactericidal effect, and is also called slightly acidic electrolyzed water, SAEW for short and slightly acidic electrolyzed oxidizing water. Weakly acidic hypochlorous acid water is a weakly acidic water containing hypochlorous acid as a main component, and neutrophils, which are responsible for human immune functions, generate hypochlorous acid, which dominates biological immunity and is an indispensable active molecule even for human beings.
The existing methods for producing hypochlorous acid mainly comprise an electrolysis method and a two-liquid method. However, the supply of slightly acidic hypochlorous acid water is limited due to the electrolysis efficiency, and the electrolysis requires an electrolytic cell apparatus, which results in a very high maintenance cost. In addition, electrodes are required, the cost is too high, and only low-concentration hypochlorous acid can be produced by an electrolytic method. The two-solution method is to combine a sodium hypochlorite solution with a strong acid solution such as hydrochloric acid to prepare hypochlorous acid with an acidic pH value. This method is a process of adjusting the pH value with the acidity of hydrochloric acid or the like and mixing sodium hypochlorite with an acid, and thus a potential safety hazard occurs. In particular, chlorine gas is generated after sodium hypochlorite and acid are fused.
Therefore, the existing preparation method of hypochlorous acid is to be further improved.
Disclosure of Invention
The invention aims to overcome the defects in the prior art and provide the method for preparing the hypochlorous acid by combining the ion exchange method with the electrolysis method, which has simple process, can effectively remove heavy metal ions in the hypochlorous acid, effectively reduce the content of chloride ions in the solution and improve the concentration of the hypochlorous acid so as to effectively improve the concentration and stability of the hypochlorous acid.
Another object of the invention is to provide a production apparatus for carrying out the above method.
In the method for preparing hypochlorous acid by combining an ion exchange method with an electrolysis method, the invention adopts the following scheme in order to achieve the aim:
a method for preparing hypochlorous acid by combining an ion exchange method with an electrolysis method is characterized by comprising the following steps:
s1, treating tap water by adopting a pre-filter to obtain purified water;
s2, adding hypochlorite solution and purified water in the step S1 into a hypochlorite solution diluter to obtain hypochlorite diluted solution;
s3, adding the hypochlorite solution and the acid solution in the step S2 into a mixer for mixing reaction to obtain a hypochlorous acid mixed solution; or adding the hypochlorite solution obtained in the step S2 into a mixer, and conveying carbon dioxide gas into the mixer through a pipeline for mixing reaction to obtain a hypochlorous acid mixed solution with the pH value of 4.0-8.0;
s4, carrying out ion exchange on the hypochlorous acid mixed solution in the step S3 through an ion exchanger to remove heavy metal ions, and obtaining hypochlorous acid with the heavy metal ions removed;
s5, feeding the hypochlorous acid mixed solution in the step S4 into an electrolysis device, and electrolyzing at a current of 0.05-1.0A to convert chloride ions in the solution into hypochlorous acid molecules, so that the content of the chloride ions in the solution is reduced, and heavy metal ions are removed at the same time, and a hypochlorous acid product is obtained.
As another improvement of the method for preparing hypochlorous acid by combining the ion exchange method and the electrolysis method, the volume concentration of the carbon dioxide gas in the step S3 is 1-99%, and a hypochlorous acid mixed solution with the concentration of 10ppm-5000ppm and the PPMPH of 4.0-8.0 is finally obtained.
As another improvement of the method for preparing hypochlorous acid by combining the ion exchange method with the electrolysis method, the water flow in the step S1 is adjusted to be 5-100L/min, and the water pressure is 0.01-0.5 MPa.
As another improvement of the method for preparing hypochlorous acid by combining the ion exchange method with the electrolysis method, the pre-filter in the step S1 is a three-stage filter device, the three-stage filter device comprises a 1 micron microporous PP cotton filter, a second-stage activated carbon filter and an acidic cation exchange resin filter which are sequentially connected, and large-particle impurities in tap water are filtered by the 1 micron microporous PP cotton filter; adsorbing organic matters and microorganism impurities in the tap water through a second-stage activated carbon filter; heavy metal impurities and cations in tap water are filtered out by an acidic cation exchange resin filter.
As another improvement of the method for preparing hypochlorous acid by combining the ion exchange method and the electrolysis method, the hypochlorite solution in the step S2 is one or a mixture of more than two of sodium hypochlorite, calcium hypochlorite and potassium hypochlorite.
As another improvement of the method for preparing hypochlorous acid by combining the ion exchange method with the electrolysis method, the concentration of the hypochlorite solution in the step S2 is 4-15%, and the concentration of the hypochlorite diluted solution is 10-5000 ppm.
As another improvement of the method for preparing hypochlorous acid by combining the ion exchange method with the electrolysis method, the concentration of the acid solution in the step S3 is 1-37%.
As another modification of the method for preparing hypochlorous acid by combining the ion exchange method with the electrolysis method according to the present invention, the acidic solution in step S3 is one of hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid, chloric acid, a disodium hydrogen phosphate buffer solution, or a sodium dihydrogen phosphate buffer solution.
As another improvement of the method for preparing hypochlorous acid by combining the ion exchange method with the electrolysis method, an acidic cation exchange resin is contained in the ion exchanger in the step S4.
As another improvement of the method for preparing hypochlorous acid by combining the ion exchange method with the electrolysis method, in step S4, the ion exchanger contains acidic cation exchange resin which is resin sulfonic acid group resin or/and carboxylic acid group resin.
In order to achieve the above object, the present invention adopts the following scheme with respect to a manufacturing apparatus:
the hypochlorous acid production apparatus for carrying out the method is characterized in that: the hypochlorite solution diluter is provided with a hypochlorite solution inlet pipe and an acid solution inlet pipe respectively, a carbon dioxide aeration pipe is arranged in the mixer, the air inlet end of the carbon dioxide aeration pipe extends out of the mixer.
In summary, compared with the prior art, the invention has the beneficial effects that:
the tap water is filtered through three stages, the first stage is filtered through a 1 micron microporous PP cotton filter to remove large-particle impurities, the second stage is used for adsorbing impurities such as organic matters and microorganisms through an activated carbon filter, and the third stage is used for filtering heavy metal impurities and cations through an acidic cation exchange resin filter to effectively reduce the impurities such as the impurities and the heavy metals in the treated tap water, so that the subsequent proper hypochlorous acid is effectively guaranteed, and the stability of the synthesized hypochlorous acid is effectively improved.
Secondly, in the preparation method, the hypochlorite solution is diluted to a proper concentration and then mixed with the acid solution or the carbon dioxide gas, so that the residual amount of hypochlorite in the hypochlorous acid water is effectively controlled, the prepared hypochlorous acid water is safer and more reliable, and the safety threat to people and livestock is avoided.
Thirdly, after the hypochlorous acid is synthesized, the impurity removal treatment is further carried out through cation exchange resin, heavy metal ions in the hypochlorous acid water are effectively removed, and therefore a purer slightly-acidic hypochlorous acid product with the pH value of 4.0-6.8 is obtained.
Fourthly, the weakly acidic hypochlorous acid solution passes through the electrolysis device, the electrode can achieve the purpose by using a common inert electrode, the chlorine ions in the solution can be converted into hypochlorous acid molecules in the electrolysis process under the current of 0.05A-1.0A, the content of the chlorine ions in the solution can be greatly reduced, the hypochlorous acid concentration is improved, and meanwhile, impurity gold such as copper ions and iron ions is precipitated as a metal simple substance by a cathode to achieve the impurity removal effect.
Drawings
FIG. 1 is a schematic view of a manufacturing apparatus of the present invention.
FIG. 2 is a schematic view of another embodiment of the manufacturing apparatus of the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the specification of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
The invention relates to a method for preparing hypochlorous acid by combining an ion exchange method with an electrolysis method, which comprises the following steps:
s1, treating tap water by using a pre-filter 1 to obtain purified water; wherein the water flow is regulated to 5L/min, and the water pressure is 0.5 MPa. The pre-filter 1 is a three-stage filter device which comprises a 1 micron microporous PP cotton filter 11, a second-stage activated carbon filter 12 and an acidic cation exchange resin filter 13 which are sequentially connected, and large particle impurities in tap water are filtered by the 1 micron microporous PP cotton filter 11; adsorbing organic matters and microorganism impurities in the tap water through a second-stage activated carbon filter 12; heavy metal impurities and cations in the tap water are filtered off by an acidic cation exchange resin filter 13.
S2, adding hypochlorite solution and purified water in the step S1 into the hypochlorite solution diluter 2 to obtain hypochlorite diluted solution; wherein the hypochlorite solution is sodium hypochlorite with the mass concentration of 4%, and the concentration of the hypochlorite dilution solution is 10 ppm.
S3, adding the hypochlorite solution and the hydrochloric acid solution in the step S2 into a mixer 3 for mixing reaction to obtain a hypochlorous acid mixed solution; wherein the concentration of the hydrochloric acid solution is 1 percent, and a hypochlorous acid mixed solution with the concentration of 10ppm and the pH value of 4.0 is obtained;
s4, removing heavy metal ions by carrying out ion exchange on the hypochlorous acid mixed solution in the step S3 through an ion exchanger 4 to obtain hypochlorous acid with pH of 4.0 and without heavy metal ions; the ion exchanger 4 contains a sulfonic acid resin.
And S5, feeding the hypochlorous acid mixed solution in the step S4 into an electrolysis device 4, and electrolyzing at the current of 0.05A, wherein a general inert electrode is used as the electrode, the electrolysis time is 30S, the chlorine ions in the solution are converted into hypochlorous acid molecules, the content of the chlorine ions in the solution is reduced, and meanwhile, heavy metal ions are removed, so that the heavy metal ion-removed hypochlorous acid with the pH value of 4.5 is obtained.
Example 2
The invention relates to a method for preparing hypochlorous acid by combining an ion exchange method with an electrolysis method, which comprises the following steps:
s1, treating tap water by using a pre-filter 1 to obtain purified water; wherein the water flow is regulated to be 100L/min, and the water pressure is 0.1 MPa. The pre-filter 1 is a three-stage filter device which comprises a 1 micron microporous PP cotton filter 11, a second-stage activated carbon filter 12 and an acidic cation exchange resin filter 13 which are sequentially connected, and large particle impurities in tap water are filtered by the 1 micron microporous PP cotton filter 11; adsorbing organic matters and microorganism impurities in the tap water through a second-stage activated carbon filter 12; heavy metal impurities and cations in the tap water are filtered off by an acidic cation exchange resin filter 13.
S2, adding hypochlorite solution and purified water in the step S1 into the hypochlorite solution diluter 2 to obtain hypochlorite diluted solution; wherein the hypochlorite solution is calcium hypochlorite with the mass concentration of 15%, and the concentration of the hypochlorite diluted solution is 5000 ppm.
S3, adding the hypochlorite solution and the disodium hydrogen phosphate buffer solution in the step S2 into a mixer 3 for mixing reaction to obtain a hypochlorous acid mixed solution; wherein the concentration of the disodium phosphate buffer is 37%; obtain a hypochlorous acid mixed solution with 5000ppmPH of 8.0;
s4, carrying out ion exchange on the hypochlorous acid mixed solution in the step S3 by an ion exchanger 4 to remove heavy metal ions, and obtaining hypochlorous acid with pH of 6.8 and without heavy metal ions; wherein the ion exchanger 4 contains a sulfonic resin.
And S5, feeding the hypochlorous acid mixed solution in the step S4 into an electrolysis device 4, electrolyzing at the current of 1.0A for 5min by using a general inert electrode, converting chloride ions in the solution into hypochlorous acid molecules, reducing the content of the chloride ions in the solution, and removing heavy metal ions to obtain a hypochlorous acid product.
Example 3
The invention relates to a method for preparing hypochlorous acid by combining an ion exchange method with an electrolysis method, which comprises the following steps:
s1, treating tap water by using a pre-filter 1 to obtain purified water; wherein the water flow is regulated to 50L/min, and the water pressure is 0.3 MPa. The pre-filter 1 is a three-stage filter device which comprises a 1 micron microporous PP cotton filter 11, a second-stage activated carbon filter 12 and an acidic cation exchange resin filter 13 which are sequentially connected, and large particle impurities in tap water are filtered by the 1 micron microporous PP cotton filter 11; adsorbing organic matters and microorganism impurities in the tap water through a second-stage activated carbon filter 12; heavy metal impurities and cations in the tap water are filtered off by an acidic cation exchange resin filter 13.
S2, adding hypochlorite solution and purified water in the step S1 into the hypochlorite solution diluter 2 to obtain hypochlorite diluted solution; wherein the hypochlorite solution is a potassium hypochlorite solution. The concentration of the potassium hypochlorite solution is 10 percent, and the concentration of the hypochlorite diluted solution is 2000 ppm.
S3, adding the hypochlorite solution and the phosphoric acid solution in the step S2 into a mixer 3 for mixing reaction to obtain a hypochlorous acid mixed solution; wherein the concentration of the phosphoric acid solution is 15%.
S4, the hypochlorous acid mixed solution in the step S3 is ion-exchanged by the ion exchanger 4 to remove heavy metal ions, and hypochlorous acid with pH of 6.0 is obtained as heavy metal ions. The ion exchanger 4 contains a carboxylic acid-based resin.
And S5, feeding the hypochlorous acid mixed solution in the step S4 into an electrolysis device 4, electrolyzing at the current of 0.2A for 2min by using a general inert electrode, converting chloride ions in the solution into hypochlorous acid molecules, reducing the content of the chloride ions in the solution, and removing heavy metal ions to obtain a hypochlorous acid product.
Example 4
The invention relates to a method for preparing hypochlorous acid by combining an ion exchange method with an electrolysis method, which comprises the following steps:
s1, treating tap water by using a pre-filter 1 to obtain purified water; wherein the water flow is adjusted to 80L/min, and the water pressure is 0.2 MPa. The pre-filter 1 is a three-stage filter device which comprises a 1 micron microporous PP cotton filter 11, a second-stage activated carbon filter 12 and an acidic cation exchange resin filter 13 which are sequentially connected, and large particle impurities in tap water are filtered by the 1 micron microporous PP cotton filter 11; adsorbing organic matters and microorganism impurities in the tap water through a second-stage activated carbon filter 12; heavy metal impurities and cations in the tap water are filtered off by an acidic cation exchange resin filter 13.
S2, adding hypochlorite solution and purified water in the step S1 into the hypochlorite solution diluter 2 to obtain hypochlorite diluted solution; wherein the hypochlorite solution is one or a mixture of more than two of sodium hypochlorite, calcium hypochlorite and potassium hypochlorite. The concentration of the hypochlorite solution is 8%, and the concentration of the hypochlorite diluted solution is 1000 ppm.
S3, adding the hypochlorite solution and the sodium dihydrogen phosphate buffer solution in the step S2 into a mixer 3 for mixing reaction to obtain a hypochlorous acid mixed solution; wherein the concentration of the sodium dihydrogen phosphate buffer solution is 20%.
S4, the hypochlorous acid mixed solution in the step S3 is ion exchanged by the ion exchanger 4 to remove heavy metal ions, so as to obtain the heavy metal ion-removed solution. The ion exchanger 4 contains an acidic cation exchange resin. The acidic cation exchange resin is sulfonic resin or/and carboxylic resin.
And S5, feeding the hypochlorous acid mixed solution in the step S4 into an electrolysis device 4, and electrolyzing at the current of 0.8A for 4min by using a general inert electrode to convert chloride ions in the solution into hypochlorous acid molecules, so that the content of the chloride ions in the solution is reduced, and heavy metal ions are removed at the same time, thereby obtaining a hypochlorous acid product.
Example 5
The invention relates to a method for preparing hypochlorous acid by combining an ion exchange method with an electrolysis method, which comprises the following steps:
s1, treating tap water by using a pre-filter 1 to obtain purified water; wherein the water flow is adjusted to 80L/min, and the water pressure is 0.2 MPa. The pre-filter 1 is a three-stage filter device which comprises a 1 micron microporous PP cotton filter 11, a second-stage activated carbon filter 12 and an acidic cation exchange resin filter 13 which are sequentially connected, and large particle impurities in tap water are filtered by the 1 micron microporous PP cotton filter 11; adsorbing organic matters and microorganism impurities in the tap water through a second-stage activated carbon filter 12; heavy metal impurities and cations in the tap water are filtered off by an acidic cation exchange resin filter 13.
S2, adding hypochlorite solution and purified water in the step S1 into the hypochlorite solution diluter 2 to obtain hypochlorite diluted solution; wherein the hypochlorite solution is one or a mixture of more than two of sodium hypochlorite, calcium hypochlorite and potassium hypochlorite. The concentration of the hypochlorite solution is 8%, and the concentration of the hypochlorite diluted solution is 1000 ppm.
S3, adding the hypochlorite solution obtained in the step S2 into a mixer 3, and conveying carbon dioxide gas with the volume concentration of 1% into the mixer 3 through a pipeline for mixing reaction to obtain a hypochlorous acid mixed solution with the pH value of 4.0;
s4, the hypochlorous acid mixed solution in the step S3 is ion exchanged by the ion exchanger 4 to remove heavy metal ions, so as to obtain the heavy metal ion-removed solution. The ion exchanger 4 contains an acidic cation exchange resin. The acidic cation exchange resin is sulfonic resin or/and carboxylic resin.
And S5, feeding the hypochlorous acid mixed solution in the step S4 into an electrolysis device 4, electrolyzing at the current of 0.1A for 1min by using a general inert electrode, converting chloride ions in the solution into hypochlorous acid molecules, reducing the content of the chloride ions in the solution, and removing heavy metal ions to obtain a hypochlorous acid product.
Example 6
The invention relates to a method for preparing hypochlorous acid by combining an ion exchange method with an electrolysis method, which comprises the following steps:
s1, treating tap water by using a pre-filter 1 to obtain purified water; wherein the water flow is adjusted to 80L/min, and the water pressure is 0.2 MPa. The pre-filter 1 is a three-stage filter device which comprises a 1 micron microporous PP cotton filter 11, a second-stage activated carbon filter 12 and an acidic cation exchange resin filter 13 which are sequentially connected, and large particle impurities in tap water are filtered by the 1 micron microporous PP cotton filter 11; adsorbing organic matters and microorganism impurities in the tap water through a second-stage activated carbon filter 12; heavy metal impurities and cations in the tap water are filtered off by an acidic cation exchange resin filter 13.
S2, adding hypochlorite solution and purified water in the step S1 into the hypochlorite solution diluter 2 to obtain hypochlorite diluted solution; wherein the hypochlorite solution is one or a mixture of more than two of sodium hypochlorite, calcium hypochlorite and potassium hypochlorite. The concentration of the hypochlorite solution is 8%, and the concentration of the hypochlorite diluted solution is 1000 ppm.
S3, adding the hypochlorite solution obtained in the step S2 into a mixer 3, and conveying carbon dioxide gas with the volume concentration of 99% into the mixer 3 through a pipeline for mixing reaction to obtain a hypochlorous acid mixed solution with the pH value of 7.0;
s4, the hypochlorous acid mixed solution in the step S3 is ion exchanged by the ion exchanger 4 to remove heavy metal ions, so as to obtain the heavy metal ion-removed solution. The ion exchanger 4 contains an acidic cation exchange resin. The acidic cation exchange resin is sulfonic resin or/and carboxylic resin.
And S5, feeding the hypochlorous acid mixed solution in the step S4 into an electrolysis device 4, electrolyzing at the current of 0.6A for 3min by using a general inert electrode, converting chloride ions in the solution into hypochlorous acid molecules, reducing the content of the chloride ions in the solution, and removing heavy metal ions to obtain a hypochlorous acid product.
Example 7
The invention relates to a method for preparing hypochlorous acid by combining an ion exchange method with an electrolysis method, which comprises the following steps:
s1, treating tap water by using a pre-filter 1 to obtain purified water; wherein the water flow is adjusted to 80L/min, and the water pressure is 0.2 MPa. The pre-filter 1 is a three-stage filter device which comprises a 1 micron microporous PP cotton filter 11, a second-stage activated carbon filter 12 and an acidic cation exchange resin filter 13 which are sequentially connected, and large particle impurities in tap water are filtered by the 1 micron microporous PP cotton filter 11; adsorbing organic matters and microorganism impurities in the tap water through a second-stage activated carbon filter 12; heavy metal impurities and cations in the tap water are filtered off by an acidic cation exchange resin filter 13.
S2, adding hypochlorite solution and purified water in the step S1 into the hypochlorite solution diluter 2 to obtain hypochlorite diluted solution; wherein the hypochlorite solution is one or a mixture of more than two of sodium hypochlorite, calcium hypochlorite and potassium hypochlorite. The concentration of the hypochlorite solution is 8%, and the concentration of the hypochlorite diluted solution is 1000 ppm.
S3, adding the hypochlorite solution obtained in the step S2 into a mixer 3, and conveying carbon dioxide gas with the volume concentration of 1-99% into the mixer 3 through a pipeline for mixing reaction to obtain a hypochlorous acid mixed solution with the pH value of 4.0-8.0;
s4, the hypochlorous acid mixed solution in the step S3 is ion exchanged by the ion exchanger 4 to remove heavy metal ions, so as to obtain the heavy metal ion-removed solution. The ion exchanger 4 contains an acidic cation exchange resin. The acidic cation exchange resin is sulfonic resin or/and carboxylic resin.
And S5, feeding the hypochlorous acid mixed solution in the step S4 into an electrolysis device 4, and electrolyzing at the current of 0.8A for 3min by using a general inert electrode to convert chloride ions in the solution into hypochlorous acid molecules, so that the content of the chloride ions in the solution is reduced, and heavy metal ions are removed at the same time, thereby obtaining a hypochlorous acid product.
The method for preparing hypochlorous acid by combining the ion exchange method with the electrolysis method in examples 1 to 4 of the present invention can be carried out by the manufacturing apparatus of example 8 or 9.
Example 8
The invention provides hypochlorite manufacturing equipment, which comprises a mixer 3, wherein the liquid inlet end of the mixer 3 is connected with a hypochlorite solution diluter 2, the liquid outlet end of the mixer 3 is connected with the liquid inlet end of an ion exchanger 4, a first pH value detection device 7 and a second pH value detection device 9 are arranged on a liquid outlet pipe 8 of the ion exchanger 4 at intervals, an electrolytic tank is arranged on the liquid outlet pipe 8 between the first pH value detection device 7 and the second pH value detection device 9, the first pH value detection device 7 and the second pH value detection device 9 are connected with a controller 10 in different parts, a purified water conveying pipe 5 is arranged on one side of the hypochlorite solution diluter 2, the water inlet end of the purified water conveying pipe 5 is connected with the water outlet end of a pre-filter 1, the water inlet end of the pre-filter 1 is connected with a tap water pipe 14, and a hypochlorite solution pipe 30 and an acidic solution liquid inlet pipe 40 are respectively arranged on the hypochlorite solution diluter 2 And a carbon dioxide aeration pipe 50 is arranged in the mixer 3, and the air inlet end of the carbon dioxide aeration pipe 50 extends out of the mixer 3.
The pre-filter 1 is a three-stage filter device which comprises a 1 micron microporous PP cotton filter 11, a second-stage activated carbon filter 12 and an acidic cation exchange resin filter 13 which are sequentially connected, and large particle impurities in tap water are filtered by the 1 micron microporous PP cotton filter 11; adsorbing organic matters and microorganism impurities in the tap water through a second-stage activated carbon filter 12; heavy metal impurities and cations in the tap water are filtered off by an acidic cation exchange resin filter 13.
Example 9
The invention provides hypochlorite manufacturing equipment, which comprises a mixer 3, wherein the liquid inlet end of the mixer 3 is connected with a hypochlorite solution diluter 2, the liquid outlet end of the mixer 3 is connected with the liquid inlet end of an ion exchanger 4, a first pH value detection device 7 and a second pH value detection device 9 are arranged on a liquid outlet pipe 8 of the ion exchanger 4 at intervals, an electrolytic tank is arranged on the liquid outlet pipe 8 between the first pH value detection device 7 and the second pH value detection device 9, the first pH value detection device 7 and the second pH value detection device 9 are connected with a controller 10 in different parts, a purified water conveying pipe 5 is arranged on one side of the hypochlorite solution diluter 2, the water inlet end of the purified water conveying pipe 5 is connected with the water outlet end of a pre-filter 1, the water inlet end of the pre-filter 1 is connected with a tap water pipe 14, and a hypochlorite solution pipe 30 and an acidic solution liquid inlet pipe 40 are respectively arranged on the hypochlorite solution diluter 2 And a carbon dioxide aeration pipe 50 is arranged in the mixer 3, and the air inlet end of the carbon dioxide aeration pipe 50 extends out of the mixer 3.
A first flow control valve 15 is arranged on the tap water pipe 14, a second flow control valve 16 is arranged on a pipeline connecting the hypochlorite solution diluter 2 and the mixer 3, a third flow control valve 17 is arranged on the purified water delivery pipe 5, a first electromagnetic control valve 18 is arranged on the liquid outlet pipe 8 of the ion exchanger 4, the second pH detection device 9 is arranged on the outlet pipe 8 between the ion exchanger 4 and the first electromagnetic control valve 18, a liquid return pipe 19 is arranged on the liquid outlet pipe 8 between the ion exchanger 4 and the first electromagnetic control valve 18, the liquid outlet end of the liquid return pipe 19 is connected with the liquid inlet pipe 6 of the ion exchanger 4, a second electromagnetic control valve 20 is arranged on the liquid return pipe 19, and the first flow control valve 15, the second flow control valve 16, the third flow control valve 17, the first electromagnetic control valve 18 and the second electromagnetic control valve 20 are respectively connected with the controller 10.
The pre-filter 1 is a three-stage filter device which comprises a 1 micron microporous PP cotton filter 11, a second-stage activated carbon filter 12 and an acidic cation exchange resin filter 13 which are sequentially connected, and large particle impurities in tap water are filtered by the 1 micron microporous PP cotton filter 11; adsorbing organic matters and microorganism impurities in the tap water through a second-stage activated carbon filter 12; heavy metal impurities and cations in the tap water are filtered off by an acidic cation exchange resin filter 13.
In the invention, a first flow control valve 15 is controlled to be opened, so that tap water enters a pre-filter 1, and the tap water is filtered from the pre-filter 1 through a 1 micron microporous PP cotton filter 11 to remove large-particle impurities in the tap water; then adsorbing organic matters and microorganism impurities in the tap water by a second-stage activated carbon filter 12; then passes through an acidic cation exchange resin filter 13 to filter out heavy metal impurities and cations in the tap water. And then into the hypochlorite solution diluter 2, the amount of which entering may be controlled by the first flow control valve 15. The diluted hypochlorite solution and the acid solution are added into the mixer 3 in proportion for mixing reaction, and the mixed solution is sent into the ion exchanger 4 for cation exchange after the reaction is finished, so that the heavy metal impurities and cations in the hypochlorous acid water are further removed, and the hypochlorous acid water is more stable and has a wider concentration range.
The mixer 3 of the invention can be provided with a stirring device and a heating device, so that the solution in the mixer 3 can be mixed more uniformly, and the mixed solution can be ensured to react at normal temperature or at a specific temperature.
In the invention, in order to improve the productivity, a water storage tank is arranged between the pre-filter 1 and the hypochlorite solution diluter 2, the water inlet end of the water storage tank is connected with the water outlet end of the pre-filter 1, the water outlet end of the water storage tank is connected with the water inlet end of the hypochlorite solution diluter 2, a water feeding pump and a flow meter are respectively arranged on a connecting pipeline between the water outlet end of the water storage tank and the water inlet end of the hypochlorite solution diluter 2, the water feeding pump and the flow meter are respectively connected with the controller 10, and the flow meter can accurately detect the amount of purified water input into the hypochlorite solution diluter 2, so that hypochlorite solution with preset concentration can be accurately prepared.
In the invention, the first pH value detection device 7 and the second pH value detection device 9 can respectively monitor the pH values of the liquid inlet end and the liquid outlet end of the ion exchanger, and when the pH value of the liquid outlet end is lower than a preset value, the controller 10 controls the second electromagnetic control valve 20 to be opened and controls the first electromagnetic control valve 18 to be closed, so that the hypochlorous acid water is subjected to secondary cation exchange treatment.
The foregoing shows and describes the general principles and features of the present invention, together with the advantages thereof. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are described in the specification and illustrated only to illustrate the principle of the present invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the present invention, which fall within the scope of the invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (10)
1. A method for preparing hypochlorous acid by combining an ion exchange method with an electrolysis method is characterized by comprising the following steps:
s1, treating tap water by adopting a pre-filter (1) to obtain purified water;
s2, adding hypochlorite solution and purified water in the step S1 into a hypochlorite solution diluter (2) to obtain hypochlorite diluted solution;
s3, adding the hypochlorite solution and the acid solution in the step S2 into a mixer (3) for mixing reaction to obtain a hypochlorous acid mixed solution; or adding the hypochlorite solution obtained in the step S2 into a mixer (3), and conveying carbon dioxide gas into the mixer (3) through a pipeline for mixing reaction to obtain a hypochlorous acid mixed solution with the pH value of 4.0-8.0;
s4, carrying out ion exchange on the hypochlorous acid mixed solution in the step S3 through an ion exchanger (4) to remove heavy metal ions, and obtaining hypochlorous acid with the heavy metal ions removed;
s5, feeding the hypochlorous acid mixed solution in the step S4 into an electrolysis device (4), and electrolyzing at a current of 0.05-1.0A to convert chloride ions in the solution into hypochlorous acid molecules, so that the content of the chloride ions in the solution is reduced, and heavy metal ions are removed to obtain a hypochlorous acid product.
2. The ion exchange method combined with electrolysis for preparing hypochlorous acid as claimed in claim 1, wherein the volume concentration of carbon dioxide gas in step S3 is 1-99%.
3. The method for preparing hypochlorous acid by combining an ion exchange method and an electrolysis method according to claim 1, wherein the water flow rate in step S1 is adjusted to 5-100L/min, and the water pressure is 0.01-0.5 MPa.
4. The method for preparing hypochlorous acid by combining an ion exchange method and an electrolysis method according to claim 1 or 2, wherein the prefilter (1) in step S1 is a three-stage filter device comprising a 1-micron microporous PP cotton filter (11), a second-stage activated carbon filter (12) and an acidic cation exchange resin filter (13) which are connected in sequence, and the large-particle impurities in tap water are filtered by the 1-micron microporous PP cotton filter (11); organic matters and microorganism impurities in the tap water are adsorbed by a second-stage activated carbon filter (12); heavy metal impurities and cations in the tap water are filtered out by an acidic cation exchange resin filter (13).
5. The method for preparing hypochlorous acid by combining an ion exchange method and an electrolysis method according to claim 1, wherein the hypochlorite solution in step S2 is one or a mixture of more than two of sodium hypochlorite, calcium hypochlorite and potassium hypochlorite.
6. The method for preparing hypochlorous acid by combining an ion exchange process with an electrolysis process as claimed in claim 1 or 5, wherein the concentration of said hypochlorite solution in step S2 is 4-15%, and the concentration of said hypochlorite diluted solution is 10-5000 ppm.
7. The method for preparing hypochlorous acid by combining an ion exchange method and an electrolysis method according to claim 1, wherein the concentration of the acidic solution in step S3 is 1-37%.
8. The method for preparing hypochlorous acid by ion exchange combined electrolysis according to claim 1 or 7, wherein the acidic solution is one of hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid, chloric acid, disodium hydrogen phosphate buffer solution, and sodium dihydrogen phosphate buffer solution in step S3.
9. The method for preparing hypochlorous acid by combining an ion exchange method and an electrolysis method according to claim 1, wherein the ion exchanger (4) in step S4 contains acidic cation exchange resin, and the acidic cation exchange resin is resin sulfonate or/and carboxylic acid resin.
10. The hypochlorous acid production apparatus for performing the method according to claim 1, wherein: including blender (3), the inlet end of blender (3) is connected with hypochlorite solution diluter (2), the play liquid end of blender (3) is connected with the inlet end of ion exchanger (4) be provided with first pH value check out test set (7) and second pH value check out test set (9) on drain pipe (8) of ion exchanger (4) the interval be equipped with electrolysis trough (60) on drain pipe (8) between first pH value check out test set (7) and second pH value check out test set (9), first pH value check out test set (7), second pH value check out test set (9) subsection are connected with controller (10) be equipped with purification water conveyer pipe (5) on hypochlorite solution diluter (2) one side, the end of intaking of purification water conveyer pipe (5) is connected with the outlet end of leading filter (1), the water inlet end of the pre-filter (1) is connected with a tap water pipe (14), a hypochlorite solution inlet pipe (30) and an acid solution inlet pipe (40) are respectively arranged on the hypochlorite solution diluter (2), a carbon dioxide aeration pipe (50) is arranged in the mixer (3), and the air inlet end of the carbon dioxide aeration pipe (50) extends out of the mixer (3).
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113213593A (en) * | 2021-05-28 | 2021-08-06 | 淄博瀚泓环保科技有限公司 | Subacid electrolyzed water generating device with concentration automatic regulating function |
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