CN112358919A - Organic solvent type cleaning agent - Google Patents
Organic solvent type cleaning agent Download PDFInfo
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- CN112358919A CN112358919A CN202010965333.3A CN202010965333A CN112358919A CN 112358919 A CN112358919 A CN 112358919A CN 202010965333 A CN202010965333 A CN 202010965333A CN 112358919 A CN112358919 A CN 112358919A
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- Prior art keywords
- organic
- cleaning agent
- solvent
- alcohol
- epoxy compound
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/261—Alcohols; Phenols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/24—Hydrocarbons
- C11D7/248—Terpenes
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/267—Heterocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5004—Organic solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5004—Organic solvents
- C11D7/5022—Organic solvents containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5004—Organic solvents
- C11D7/5027—Hydrocarbons
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses an organic solvent type cleaning agent, which comprises organic alcohol, organic alkyl, a pH value regulator, pinene, limonene, an epoxy compound and ionized water, wherein the organic alcohol is ethanol, methanol, butanol, 1, 2-dodecanediol, isoamylol or n-propanol, the organic alcohol accounts for 30 percent, the organic alkyl is mono-organic trialkoxysilane, di-organic dialkoxysilane and tri-organic-alkoxysilane, the organic alkyl accounts for 15 to 30 percent, the pinene and limonene accounts for 5 to 8 percent respectively, the epoxy compound is propylene oxide, 1, 2-epoxybutane, 1, 2-epoxyhexane, 1, 2-epoxyheptane, 1, 2-epoxynonane, allyl glycidyl ether, propyl glycidyl ether and 2-ethylhexyl glycidyl ether, the method has high cleaning yield and greatly reduces the production cost.
Description
Technical Field
The invention relates to the technical field of organic solvent type cleaning agents, in particular to an organic solvent type cleaning agent.
Background
Solvent-based cleaners refer to organic solvents that are insoluble in water. The nonaqueous cleaning agent used for precision industrial cleaning is mainly an organic solvent such as hydrocarbon (petroleum), chlorinated hydrocarbon, fluorinated hydrocarbon, brominated hydrocarbon, alcohol, silicone oil, terpene, or the like. Therefore, we improve this problem and propose an organic solvent type cleaning agent, the solvent type generally refers to a cleaning agent using an organic solvent substance formed by organic compounds as a solvent, that is, a reagent capable of dissolving other substances, such as water, which can dissolve sugar and salt, but water cannot dissolve oil, at this time, some organic compounds can dissolve oil directly, and it can dissolve oil directly like water dissolving sugar, but the existing organic solvent cleaning agent generally adopts halogen cleaning agent and some phosphorus-free cleaning agents, which causes great pollution and harm to the environment, and is not beneficial to long-term use.
Disclosure of Invention
In order to solve the technical problems, the invention provides the following technical scheme:
the invention relates to an organic solvent type cleaning agent, which comprises the following raw materials of organic alcohol, organic alkane, a pH value regulator, pinene, limonene, an epoxy compound and ionized water.
As a preferable technical scheme of the invention, the organic alcohol is ethanol, methanol, butanol, 1, 2-dodecanediol, isoamyl alcohol or n-propanol, wherein the percentage of the organic alcohol is 30%.
As a preferable technical scheme of the invention, the organic alkyl is mono-organic radical trialkoxy silane, di-organic radical dialkoxy silane and tri-organic radical-alkoxy silane, wherein the percentage of the organic alkyl is 15 to 30 percent.
As a preferable technical scheme of the invention, the percentages of the pinene and the limonene are respectively 5% and 8%.
As a preferred embodiment of the present invention, the epoxy compound includes propylene oxide, 1, 2-butylene oxide, 1, 2-epoxyhexane, 1, 2-epoxyheptane, 1, 2-epoxynonane, allyl glycidyl ether, propyl glycidyl ether, 2-ethylhexyl glycidyl ether, 2, 6-di-t-butyl-p-cresol, 2, 6-di-t-butyl-4-ethylphenol, and 1-methylcyclohexene oxide and 4-methylcyclohexene oxide. .
In a preferred embodiment of the present invention, the epoxy compound is mixed at a concentration of 0.01 to 5% by mass.
A preparation method of an organic solvent type cleaning agent comprises the following steps:
step one, selecting each component according to the proportion to finish the batching;
step two, respectively weighing and preparing 30% of organic alcohol, 15% of organic alkane and 5% and 8% of pinene and limonene in percentage by weight, simultaneously adding the obtained mixture into ionized water in sequence, heating to 18 ℃, stirring for 60min, uniformly standing, and cooling to obtain a first mixed solution;
and step three, adding 4% of epoxy compound into the obtained first mixed solution, then heating to 18 ℃, uniformly stirring and cooling to obtain a second mixed solution.
In a preferred embodiment of the present invention, the second mixed solution obtained in step three is stored at 30 ℃ in a sealed and ventilated manner.
In a preferred embodiment of the present invention, in the second step and the third step, the stirring temperature of the organic solvent-based cleaning agent should be lower than 20 ℃.
The invention has the beneficial effects that: by adopting plant organic matters as main components of the cleaning agent, the harm to the environment is reduced on the basis of not reducing the cleaning capability, and the cleaning agent has strong cleaning capability, small corrosiveness, safety and harmlessness; by adopting the organic alcohol as the solvent of the plant organic matter, the solubility of the organic matter is greatly improved, the use of the cleaning agent at low temperature is controlled, the volatility of the organic matter is reduced, and the cleaning agent is safe and practical.
Detailed Description
The following description of the preferred embodiments of the present invention is provided for the purpose of illustration and description, and is in no way intended to limit the invention.
Example (b): the invention relates to an organic solvent type cleaning agent, which comprises the following raw materials of organic alcohol, organic alkane, a pH value regulator, pinene, limonene, an epoxy compound and ionized water.
Wherein the organic alcohol is ethanol, methanol, butanol, 1, 2-dodecanediol, isopropanol or n-propanol, and the percentage of the organic alcohol is 30%.
Wherein the organic alkyl is mono-organic trialkoxy silane, di-organic dialkoxy silane and tri-organic alkoxy silane, wherein the percentage of the organic alkyl is 15 to 30 percent.
Wherein, the percentage of pinene and limonene is 5% and 8% respectively.
Wherein the epoxy compound includes propylene oxide, 1, 2-butylene oxide, 1, 2-hexylene oxide, 1, 2-heptylene oxide, 1, 2-epoxynonane, allyl glycidyl ether, propyl glycidyl ether, 2-ethylhexyl glycidyl ether, 2, 6-di-t-butyl-p-cresol, 2, 6-di-t-butyl-4-ethylphenol, and 1-methylcyclohexene oxide and 4-methylcyclohexene oxide.
Wherein the epoxy compound is mixed at a concentration of 0.01 to 5% by mass and the epoxy compound is mixed at a concentration of less than 0.01% by mass, the predetermined effect will not be obtained, and on the other hand, a concentration of more than 5% by mass may cause strong odor or skin irritation.
A preparation method of an organic solvent type cleaning agent comprises the following steps:
step one, selecting each component according to the proportion to finish the batching;
step two, respectively weighing and preparing 30% of organic alcohol, 15% of organic alkane and 5% and 8% of pinene and limonene in percentage by weight, simultaneously adding the obtained mixture into ionized water in sequence, heating to 18 ℃, stirring for 60min, uniformly standing, and cooling to obtain a first mixed solution;
and step three, adding 4% of epoxy compound into the obtained first mixed solution, then heating to 18 ℃, uniformly stirring and cooling to obtain a second mixed solution.
And in the third step, the obtained second mixed solution is sealed, ventilated and stored at 30 ℃. Temperatures in excess of 30 ℃ can result in poor cleaning efficiency of organic solvent-based cleaners.
In the second step and the third step, the stirring temperature of the organic solvent type cleaning agent is lower than 20 ℃, and if the organic solvent type cleaning agent is stirred at high temperature, the internal solvent is volatilized at high temperature, and harmful gas is generated.
The working principle is as follows: an organic solvent type cleaning agent comprises the following raw materials of organic alcohol, organic alkyl, pH value regulator, pinene, limonene, epoxy compound and ionized water, wherein the organic alcohol is ethanol, methanol, butanol, 1, 2-dodecanediol, isoamylol or n-propanol, the organic alcohol accounts for 30 percent, the organic alkyl is mono-organic trialkoxysilane, di-organic dialkoxysilane and tri-organic alkoxy silane, the organic alkyl accounts for 15 to 30 percent, the pinene and the limonene accounts for 5 to 8 percent respectively, the epoxy compound comprises propylene oxide, 1, 2-epoxybutane, 1, 2-epoxyhexane, 1, 2-epoxyheptane, 1, 2-epoxynonane, allyl glycidyl ether, propyl glycidyl ether, 2-ethylhexyl glycidyl ether, The preparation method comprises the following steps of selecting 2, 6-di-tert-butyl-p-cresol, 2, 6-di-tert-butyl-4-ethylphenol, 1-methylcyclohexene oxide and 4-methylcyclohexene oxide according to a ratio, after the ingredients are mixed, respectively weighing and preparing 30% by weight of organic alcohol, 15% by weight of organic alkane and 5% by weight and 8% by weight of pinene and limonene, simultaneously sequentially adding the organic alcohol and the pinene into ionized water, heating to 18 ℃, stirring for 60min, uniformly standing, cooling to obtain a first mixed solution, adding 4% of epoxy compound into the obtained first mixed solution, heating to 18 ℃, uniformly stirring, and cooling to obtain a second mixed solution.
In the description of the present invention, it should also be noted that, unless otherwise explicitly specified or limited, the terms "disposed," "mounted," "connected," and "connected" are to be construed broadly, e.g., as meaning either a fixed connection, a removable connection, or an integral connection; can be mechanically or electrically connected; the two elements can be directly connected with each other or indirectly connected with each other through an intermediate medium, and the two elements can be communicated with each other. The specific meanings of the above terms in the present invention can be understood by those skilled in the art according to specific situations.
Although the present invention has been described in detail with reference to the foregoing embodiments, it will be apparent to those skilled in the art that changes may be made in the embodiments and/or equivalents thereof without departing from the spirit and scope of the invention. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (9)
1. An organic solvent type cleaning agent is characterized by comprising the following raw materials of organic alcohol, organic alkyl, a pH value regulator, pinene, limonene, an epoxy compound and ionized water.
2. The solvent-based cleaning agent according to claim 1, wherein the organic alcohol is ethanol, methanol, butanol, 1, 2-dodecanediol, isoamyl alcohol or n-propanol, and the percentage of the organic alcohol is 30%.
3. The solvent-based cleaning agent according to claim 1, wherein the organic alkane is selected from the group consisting of a mono-organotrialkoxysilane, a di-organodialkoxysilane, and a tri-organoalkoxysilane, and the percentage of the organic alkane is 15% to 30%.
4. The solvent-based organic solvent-based cleaning agent according to claim 1, wherein the percentages of pinene and limonene are 5% and 8%, respectively.
5. The organic solvent-based cleaning agent according to claim 1, wherein the epoxy compound comprises propylene oxide, 1, 2-butylene oxide, 1, 2-epoxyhexane, 1, 2-epoxyheptane, 1, 2-epoxynonane, allyl glycidyl ether, propyl glycidyl ether, 2-ethylhexyl glycidyl ether, 2, 6-di-tert-butyl-p-cresol, 2, 6-di-tert-butyl-4-ethylphenol, and 1-methylcyclohexene oxide and 4-methylcyclohexene oxide.
6. The solvent-based organic cleaning agent according to claim 1, wherein the concentration of the epoxy compound is controlled to 0.01-5% by mass.
7. The preparation method of the organic solvent type cleaning agent is characterized by comprising the following steps:
step one, selecting each component according to the proportion to finish the batching;
step two, respectively weighing and preparing 30% of organic alcohol, 15% of organic alkane and 5% and 8% of pinene and limonene, simultaneously adding the obtained mixture into ionized water in sequence, heating to 18 ℃, stirring for 60min, uniformly standing, and cooling to obtain a first mixed solution;
and step three, adding 4% by mass of epoxy compound into the obtained first mixed solution, then heating to 18 ℃, uniformly stirring and cooling to obtain a second mixed solution.
8. The organic solvent-based cleaning agent according to claim 7, wherein the second mixed solution obtained in the third step is stored at 30 ℃ in a closed state under ventilation.
9. The solvent-based cleaner according to claim 7, wherein the stirring temperature of the solvent-based cleaner in the second and third steps is less than 20 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010965333.3A CN112358919A (en) | 2020-09-15 | 2020-09-15 | Organic solvent type cleaning agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010965333.3A CN112358919A (en) | 2020-09-15 | 2020-09-15 | Organic solvent type cleaning agent |
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| Publication Number | Publication Date |
|---|---|
| CN112358919A true CN112358919A (en) | 2021-02-12 |
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ID=74516563
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010965333.3A Pending CN112358919A (en) | 2020-09-15 | 2020-09-15 | Organic solvent type cleaning agent |
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| Country | Link |
|---|---|
| CN (1) | CN112358919A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1159478A (en) * | 1995-11-13 | 1997-09-17 | 株式会社日本能源 | Lowly corrosive cleaner composition |
| CN101368145A (en) * | 2007-08-16 | 2009-02-18 | 江苏海迅实业集团股份有限公司 | Organic solvent emulsifying detergent |
| CN104789387A (en) * | 2015-04-28 | 2015-07-22 | 苏州永创达电子有限公司 | Organic-solvent detergent |
-
2020
- 2020-09-15 CN CN202010965333.3A patent/CN112358919A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1159478A (en) * | 1995-11-13 | 1997-09-17 | 株式会社日本能源 | Lowly corrosive cleaner composition |
| CN101368145A (en) * | 2007-08-16 | 2009-02-18 | 江苏海迅实业集团股份有限公司 | Organic solvent emulsifying detergent |
| CN104789387A (en) * | 2015-04-28 | 2015-07-22 | 苏州永创达电子有限公司 | Organic-solvent detergent |
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