CN112341713A - Processing technology of environment-friendly wear-resistant high polymer material - Google Patents

Processing technology of environment-friendly wear-resistant high polymer material Download PDF

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CN112341713A
CN112341713A CN202010845078.9A CN202010845078A CN112341713A CN 112341713 A CN112341713 A CN 112341713A CN 202010845078 A CN202010845078 A CN 202010845078A CN 112341713 A CN112341713 A CN 112341713A
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silicone oil
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carboxyl silicone
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许建勇
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Ningbo Jutaiyuan Polymer Material Co ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/14Copolymers of propene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/74Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/0001Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/10Polymers of propylene
    • B29K2023/12PP, i.e. polypropylene
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
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  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
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  • Polymers & Plastics (AREA)
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Abstract

The invention discloses a processing technology of an environment-friendly wear-resistant high polymer material, which comprises the following steps: raw material preparation → premixing → secondary premixing → granule hot melting → raw material mixing → molding; the invention utilizes the moisture absorption performance of the fiber and the premixing structure to form stable mixing, and leads the fiber to have a dispersing solvent inside, thus leading the plastic after being limited and contacted with the molten plastic to be rapidly dispersed inside the plastic, and improving the overall performance of the wear-resistant polymer material; mix then mould plastics through hot melt after and form stable filling and mix the effect, through adding high strength fibers improve the whole wear resistance of device, ensure that the inside whole wear-resisting experience when using of material, compare in prior art adopt solid mix then the flow of hot melt, carry out the preliminary treatment to the interpolation material, can be so that the interpolation material diffuses fast when raw materials hot melt, avoid the production of fibre reunion phenomenon.

Description

Processing technology of environment-friendly wear-resistant high polymer material
Technical Field
The invention relates to the technical field of high polymer material processing technology, in particular to a processing technology of an environment-friendly wear-resistant high polymer material.
Background
The polymer material is a material based on a polymer compound, the polymer material is a material formed by compounds with relatively high molecular mass, and comprises rubber, plastics, fibers, paint, an adhesive and a polymer-based composite material, the polymer is a life existing form, all living bodies can be regarded as a polymer set, the polymer material is divided into a natural polymer material and a synthetic polymer material according to sources, and the natural polymer material is a polymer substance existing in animals, plants and organisms and can be divided into natural fibers, natural resin, natural rubber, animal glue and the like; the synthetic polymer material mainly refers to three synthetic materials of plastic, synthetic rubber and synthetic fiber, and also comprises an adhesive, a coating and various functional polymer materials, and the synthetic polymer material has the properties which are not possessed by natural polymer materials or are superior to the natural polymer materials, namely, lower density, higher mechanical property and wear resistance, excellent corrosion resistance and electrical insulation property and the like; the polymer material can be divided into rubber, fiber, plastic, polymer adhesive, polymer detergent, polymer-based composite material and the like according to the characteristics, wherein the plastic is prepared by taking synthetic resin or chemically modified natural polymer as a main component and adding filler, plasticizer and other additives, the intermolecular valence force, modulus, deformation and the like of the plastic are between those of the rubber and the fiber, and the plastic is generally divided into thermosetting plastic and thermoplastic plastic according to the characteristics of the synthetic resin; and is divided into general plastics and engineering plastics according to the application.
Chinese patent publication No. CN 107501848A and 2017, 12 and 22 months, disclose a method for preparing an environment-friendly wear-resistant polymer material, comprising the steps of: (1) the environment-friendly wear-resistant high polymer material is prepared from the following components in parts by weight: 30-60 parts of ABS material, 20-40 parts of glass fiber, 4-6 parts of wear-resisting agent, 2-3 parts of coupling agent, 1-2 parts of antioxidant and 0.5-1.5 parts of lubricant; wherein the coupling agent is a mixture of a coupling agent KH550 and a coupling agent KH560, and the lubricant is a mixture of calcium stearate, zinc stearate and stearic acid amide; (2) dry-mixing the raw materials of the wear-resistant high polymer material in the step (1) in a high-speed mixer for 6-12min to obtain mixed raw materials; (3) adding the mixed raw materials obtained in the step (2) into a double screw, performing melt extrusion, and then cooling and granulating; above-mentioned comparison file provides new thinking for environment-friendly wear-resisting macromolecular material's granulation preparation, but current environment-friendly wear-resisting macromolecular material still exists and adopts solid mixture then hot melt's flow to go on usually in the manufacturing process, but this flow makes the inside uneven phenomenon that produces of dispersion of macromolecular material easily to lead to the production of reunion phenomenon, influence whole use and experience.
Disclosure of Invention
The invention aims to provide a processing technology of an environment-friendly wear-resistant high polymer material, which has the advantages that stable filling and mixing effects are formed by mixing after hot melting and then injection molding, the integral wear resistance of a device is improved by adding high-strength fibers, the integral wear-resistant experience in the use process of the interior of the material is ensured, and compared with the process of mixing with solids and then hot melting in the prior art, the pretreatment is carried out on the added material, so that the added material can be quickly diffused when the raw materials are hot melted, and the fiber agglomeration phenomenon is avoided.
In order to achieve the purpose, the invention provides the following technical scheme: the processing technology of the environment-friendly wear-resistant polymer material comprises plastic granules and mixed medicine granules, wherein each 100 parts by mass of the processing technology of the environment-friendly wear-resistant polymer material comprises the following raw materials in parts by mass:
22.45-22.55 parts of ethylene propylene diene monomer, 14.95-15.05 parts of olefin block copolymer, 37.45-37.55 parts of ethylene-vinyl acetate copolymer, 114.95-15.05 parts of polyolefin elastomer, 7.45-7.55 parts of hydrogenated styrene-butadiene block copolymer, 4.45-4.55 parts of wear-resistant oil, 0.95-1.05 parts of zinc oxide, 0.25-0.35 part of stearic acid, 0.7-0.8 part of petroleum resin, 1.45-1.55 parts of AC foaming agent and 0.35-0.45 part of odorless BIBP.
Wherein, every 100 parts of the environment-friendly wear-resistant polymer material comprises the following raw materials in parts by mass:
22.5 parts of ethylene propylene diene monomer, 15 parts of olefin block copolymer, 37.5 parts of ethylene-vinyl acetate copolymer, 15 parts of polyolefin elastomer, 7.5 parts of hydrogenated styrene-butadiene block copolymer, 4.45 parts of wear-resistant oil, 1 part of zinc oxide, 0.3 part of stearic acid, 0.75 part of petroleum resin, 1.5 parts of AC foaming agent and 0.45 part of odorless BIBP.
The hydrogenated styrene-butadiene block copolymer is used for modification.
Compared with the prior art, the invention has the following beneficial effects:
1. according to the processing technology of the environment-friendly wear-resistant polymer material, the moisture absorption performance and the premixing structure of the fiber are utilized to form stable mixing, and the dispersion solvent is arranged in the fiber, so that the fiber can be rapidly dispersed in the plastic after being limited in contact with the molten plastic, a stable diffusion effect is formed, the defect that part of the fiber is poor due to accumulation is avoided, and the overall performance of the wear-resistant polymer material is improved.
2. According to the processing technology of the environment-friendly wear-resistant polymer material, stable filling and mixing effects are formed by mixing after hot melting and then injection molding, the overall wear resistance of the device is improved by adding high-strength fibers, the overall wear resistance experience of the interior of the material in use is ensured, and compared with the process of mixing solids and then hot melting in the prior art, the processing technology of the environment-friendly wear-resistant polymer material has the advantages that the added material is pretreated, the added material can be rapidly diffused when the raw materials are hot melted, and the phenomenon of fiber agglomeration is avoided.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1:
the processing technology of the environment-friendly wear-resistant high polymer material is characterized by comprising the following steps of:
step one, raw material preparation: preparing raw materials for preparing an environment-friendly wear-resistant high polymer material, wherein the raw materials comprise 30 parts of RP2400 random copolymerization polypropylene, 10 parts of T700 polyacrylonitrile carbon fiber, 6 parts of SP50 nano silicon dioxide, 20 parts of 1000-mesh superfine high-white quartz powder, 3 parts of PMX-350 dimethyl carboxyl silicone oil, 3 parts of YZSG calcium stearate, 6 parts of 3mm PBO chopped polyparaphenylene benzobisoxazole fiber, 6 parts of GB-209 carboxyl silicone oil and 5 parts of IRGAFOS168 liquid phosphite ester;
step two, premixing: taking 70% of the total amount of the carboxyl silicone oil prepared in the step one, pouring all the selected carboxyl silicone oil into a heating furnace, preheating the carboxyl silicone oil to 65 ℃, after preheating is completed, taking 45% of the heated carboxyl silicone oil, placing the heated carboxyl silicone oil into a stirring device, rotating the stirring device at a rotating speed of 250r/min, taking all the T700 polyacrylonitrile carbon fibers prepared in the step one in the rotating process, placing the T700 polyacrylonitrile carbon fibers into the stirring device, stirring the T700 polyacrylonitrile carbon fibers and the carboxyl silicone oil together, after stirring for 2 minutes, adjusting the rotating speed to 340r/min, and continuing stirring for 3 minutes to obtain the premixed T700 polyacrylonitrile carbon fibers;
step three, secondary premixing: taking the residual preheated carboxyl silicone oil in the step two, placing the carboxyl silicone oil in a stirring device, taking all the poly-p-phenylene benzobisoxazole fibers prepared in the step one, stirring the mixture for 3 minutes at the rotating speed of the stirring device of 340r/min, adding all the calcium stearate prepared in the step one, and stirring the mixture for 2 minutes to obtain the pre-mixed poly-p-phenylene benzobisoxazole fibers;
step four, hot melting of the particles: placing the premixed T700 polyacrylonitrile carbon fiber obtained in the second step into a heating and stirring device, then taking 10% of the total amount of the random copolymerization polypropylene prepared in the first step and the carboxyl silicone oil prepared in the first step, placing the random copolymerization polypropylene and part of the carboxyl silicone oil into the heating and stirring device together, heating the heating and stirring device to 200 ℃, enabling the heating and stirring device to heat and stir the random copolymerization polypropylene at the rotating speed of 48r/min, stirring for 4min and keeping the constant temperature for 10min, and obtaining a melted random copolymerization polypropylene mixture;
step five, mixing the raw materials: adding the T700 polyacrylonitrile carbon fiber premixed in the second step into the stirring device in the fourth step, keeping the heating temperature at 60 ℃, continuously stirring for 5min at the rotating speed of 45r/min, adding the dimethyl carboxyl silicone oil in the first step, adjusting the original rotating speed, and continuously stirring for 5min to obtain a mixed high polymer material raw material;
step six, forming: and D, adding the phosphite ester prepared in the step one into the polymer material raw material obtained in the step five, then pushing the polymer material raw material obtained in the step five to pass through a nozzle at the end part of a charging barrel by a plunger or a screw when the polymer material raw material obtained in the step five is in a flowing state, injecting the mixture into a closed die at 45 ℃, and cooling and demoulding the melt filled with the die to form the formed environment-friendly wear-resistant polymer material A under the condition of pressure.
Example 2:
the processing technology of the environment-friendly wear-resistant high polymer material is characterized by comprising the following steps of:
step one, raw material preparation: preparing raw materials for preparing an environment-friendly wear-resistant high polymer material, wherein the raw materials comprise 35 or 38 parts of random copolymer polypropylene, 15 parts of T700 polyacrylonitrile carbon fiber, 8 parts of SP50 nano silicon dioxide, 2 parts of quartz powder, 5 parts of dimethyl carboxyl silicone oil, 4 parts of calcium stearate, 8 parts of poly-p-phenylene benzobisoxazole fiber, 8 parts of carboxyl silicone oil and 6 parts of liquid phosphite ester; the calcium stearate is used as a stabilizer; the carboxyl silicone oil is used as a dispersant; the dimethyl carboxyl silicone oil is used as a reinforcing agent; the phosphite ester is used as a heat stabilizer;
step two, premixing: taking 70% of the total amount of the carboxyl silicone oil prepared in the step one, pouring all the selected carboxyl silicone oil into a heating furnace, preheating the carboxyl silicone oil to 67 ℃, after preheating is completed, taking 60% of the heated carboxyl silicone oil to be placed in a stirring device, rotating the stirring device at a rotating speed of 265r/min, taking all the T700 polyacrylonitrile carbon fibers prepared in the step one in the rotating process, placing the T700 polyacrylonitrile carbon fibers into the stirring device to be stirred together with the carboxyl silicone oil, stirring for 3 minutes, adjusting the rotating speed to 343r/min, and continuing stirring for 5 minutes to obtain the premixed T700 polyacrylonitrile carbon fibers;
step three, secondary premixing: taking the residual preheated carboxyl silicone oil in the step two, placing the carboxyl silicone oil in a stirring device, taking all the poly-p-phenylene benzobisoxazole fibers prepared in the step one, stirring the mixture for 3 minutes at the rotating speed of the stirring device of 340r/min, adding all the calcium stearate prepared in the step one, and stirring the mixture for 2 minutes to obtain the pre-mixed poly-p-phenylene benzobisoxazole fibers;
step four, hot melting of the particles: placing the premixed T700 polyacrylonitrile carbon fiber obtained in the second step into a heating and stirring device, then taking 15% of the total amount of the random copolymerization polypropylene prepared in the first step and the carboxyl silicone oil prepared in the first step, placing the random copolymerization polypropylene and part of the carboxyl silicone oil into the heating and stirring device together, heating the heating and stirring device to 220 ℃, enabling the heating and stirring device to heat and stir the random copolymerization polypropylene at the rotating speed of 48r/min, stirring for 5min and keeping the constant temperature for 10min, and obtaining a melted random copolymerization polypropylene mixture;
step five, mixing the raw materials: adding the T700 polyacrylonitrile carbon fiber premixed in the second step into the stirring device in the fourth step, keeping the heating temperature at 60 ℃, continuously stirring for 5min at the rotating speed of 45r/min, adding the dimethyl carboxyl silicone oil in the first step, adjusting the rotating speed to 45r/min or 50r/min, and continuously stirring for 6min or 7min to obtain a mixed polymer material raw material;
step six, forming: and D, adding the phosphite ester prepared in the step one into the polymer material raw material obtained in the step five, then pushing the polymer material raw material obtained in the step five to pass through a nozzle at the end part of a charging barrel by a plunger or a screw when the polymer material raw material obtained in the step five is in a flowing state, injecting the mixture into a closed die at 45 ℃, and cooling and demoulding the melt filled with the die to form the formed environment-friendly wear-resistant polymer material B under the condition of pressure.
Example 3:
the processing technology of the environment-friendly wear-resistant high polymer material is characterized by comprising the following steps of:
step one, raw material preparation: preparing raw materials for preparing an environment-friendly wear-resistant high polymer material, wherein the raw materials comprise 40 parts of random copolymerization polypropylene, 15 parts of T700 polyacrylonitrile carbon fiber, 8 parts of SP50 nano silicon dioxide, 2 parts of quartz powder, 5 parts of dimethyl carboxyl silicone oil, 4 parts of calcium stearate, 8 parts of poly-p-phenylene benzobisoxazole fiber, 8 parts of carboxyl silicone oil and 6 parts of liquid phosphite ester;
step two, premixing: taking 45% of the total amount of the carboxyl silicone oil prepared in the step one, pouring all the selected carboxyl silicone oil into a heating furnace, preheating the carboxyl silicone oil to 68 ℃, after preheating is completed, taking 60% of the heated carboxyl silicone oil to be placed in a stirring device, rotating the stirring device at a rotating speed of 270r/min, taking all the T700 polyacrylonitrile carbon fibers prepared in the step one in the rotating process, placing the T700 polyacrylonitrile carbon fibers into the stirring device to be stirred together with the carboxyl silicone oil, stirring for 2 minutes, adjusting the rotating speed to 343r/min, and continuing stirring for 4 minutes to obtain the premixed T700 polyacrylonitrile carbon fibers;
step three, secondary premixing: taking the residual preheated carboxyl silicone oil in the step two, placing the carboxyl silicone oil in a stirring device, taking all the poly-p-phenylene benzobisoxazole fibers prepared in the step one, stirring the mixture for 3 minutes at the rotating speed of the stirring device of 340r/min, adding all the calcium stearate prepared in the step one, and stirring the mixture for 2 minutes to obtain the pre-mixed poly-p-phenylene benzobisoxazole fibers;
step four, hot melting of the particles: placing the premixed T700 polyacrylonitrile carbon fiber obtained in the second step into a heating and stirring device, then taking 15% of the total amount of the random copolymerization polypropylene prepared in the first step and the carboxyl silicone oil prepared in the first step, placing the random copolymerization polypropylene and part of the carboxyl silicone oil into the heating and stirring device together, heating the heating and stirring device to 220 ℃, enabling the heating and stirring device to heat and stir the random copolymerization polypropylene at the rotating speed of 48r/min, stirring for 5min and keeping the constant temperature for 10min, and obtaining a melted random copolymerization polypropylene mixture;
step five, mixing the raw materials: adding the T700 polyacrylonitrile carbon fiber premixed in the second step into the stirring device in the fourth step, keeping the heating temperature at 65 ℃, continuously stirring for 5min at the rotating speed of 45r/min, adding the dimethyl carboxyl silicone oil in the first step, adjusting the rotating speed to 45r/min or 50r/min, and continuously stirring for 6min or 7min to obtain a mixed polymer material raw material;
step six, forming: and D, adding the phosphite ester prepared in the step one into the polymer material raw material obtained in the step five, then pushing the polymer material raw material obtained in the step five to pass through a nozzle at the end part of a charging barrel by a plunger or a screw when the polymer material raw material obtained in the step five is in a flowing state, injecting the mixture into a closed die at 45 ℃, and cooling and demoulding the melt filled with the die to form the formed environment-friendly wear-resistant polymer material C under the condition of pressure.
Comparative example 1:
the environment-friendly wear-resistant polymer material D is prepared by mixing 30 parts of random copolymer polypropylene, 10 parts of T700 polyacrylonitrile carbon fiber, 6 parts of SP50 nano silica, 20 parts of quartz powder and 3 parts of calcium stearate in a high-speed mixer, then putting all the raw materials in a hot melting machine, pushing the raw materials by a plunger or a screw rod to pass through a nozzle at the end of a charging barrel when the raw materials are in a flowing state, injecting the raw materials into a closed die at 45 ℃, cooling and demolding the molten materials filled in the die under the pressure condition, and thus obtaining the molded environment-friendly wear-resistant polymer material D.
Comparative example 2:
the environment-friendly wear-resistant polymer material E is prepared by mixing 35 parts of random copolymer polypropylene, 13 parts of T700 polyacrylonitrile carbon fiber, 6 parts of SP50 nano silica, 21 parts of quartz powder and 3.5 parts of calcium stearate in a high-speed mixer, then putting all the raw materials in a hot melting machine, pushing the raw materials by a plunger or a screw rod to pass through a nozzle at the end of a charging barrel when the raw materials are in a flowing state, injecting the raw materials into a closed die at 45 ℃, cooling and demolding and molding a molten material filled in the die under a pressed condition to obtain the molded environment-friendly wear-resistant polymer material E.
The same mechanical properties and aging properties as in comparative example 1 and comparative example 2 were measured in examples 1, 2 and 3, and the results are shown in table 1:
Figure RE-GDA0002785946740000081
Figure RE-GDA0002785946740000091
TABLE 1
In summary, the following steps: this wear-resisting type macromolecular material's of environmental protection processing technology, mix after through the hot melt then mould plastics and form stable packing and mixed effect, through adding high strength fiber improve device's whole wear resistance, ensure the inside whole wear-resisting experience when using of material, compare in prior art adopt the solid mix then the flow of hot melt, carry out the preliminary treatment to the additional material, can be so that the additional material diffuses fast when raw materials hot melt, avoid the production of fibre reunion phenomenon.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (10)

1. The processing technology of the environment-friendly wear-resistant high polymer material is characterized by comprising the following steps of:
step one, raw material preparation: preparing raw materials for preparing an environment-friendly wear-resistant high polymer material, wherein the raw materials comprise 30-40 parts of random copolymerization polypropylene, 10-15 parts of T700 polyacrylonitrile carbon fiber, 6-8 parts of SP50 nano silicon dioxide, 20-23 parts of quartz powder, 3-5 parts of dimethyl carboxyl silicone oil, 3-4 parts of calcium stearate, 6-8 parts of poly-p-phenylene benzobisoxazole fiber, 6-8 parts of carboxyl silicone oil and 5-6 parts of liquid phosphite ester;
step two, premixing: taking part of the carboxyl silicone oil prepared in the first step, placing the carboxyl silicone oil in a heating furnace, preheating the carboxyl silicone oil to 65-68 ℃, after preheating is completed, taking part of the preheated carboxyl silicone oil and placing the part of the preheated carboxyl silicone oil in a stirring device, rotating the stirring device at the rotating speed of 250r/min-275r/min, putting the T700 polyacrylonitrile carbon fiber prepared in the first step into the stirring device in the rotating process, stirring the T700 polyacrylonitrile carbon fiber and the carboxyl silicone oil together, after stirring for 2-3 minutes, adjusting the rotating speed to 340r/min-345r/min, and continuously stirring for 3-5 minutes to obtain the premixed T700 polyacrylonitrile carbon fiber;
step three, secondary premixing: placing the preheated carboxyl silicone oil in the second step into a stirring device, then taking the poly-p-phenylene benzobisoxazole fiber prepared in the first step, stirring for 3-5min at the rotating speed of 340-345 r/min by the stirring device, adding the calcium stearate prepared in the first step, and stirring for 2-3 min to obtain the pre-mixed poly-p-phenylene benzobisoxazole fiber;
step four, hot melting of the particles: placing the premixed T700 polyacrylonitrile carbon fiber obtained in the second step into a heating and stirring device, then taking the random copolymer polypropylene prepared in the first step and part of the carboxyl silicone oil prepared in the first step, placing the random copolymer polypropylene and part of the carboxyl silicone oil into the heating and stirring device together, heating the heating and stirring device to 200-260 ℃, enabling the heating and stirring device to heat and stir the random copolymer polypropylene at the rotating speed of 45-55r/min, and keeping the constant temperature for 10-20min after heating to obtain a melted random copolymer polypropylene mixture;
step five, mixing the raw materials: adding the T700 polyacrylonitrile carbon fiber premixed in the second step into the stirring device in the fourth step, keeping the heating temperature at 60-70 ℃, continuously stirring for 5min at the original rotation speed in the fourth step, adding the dimethyl carboxyl silicone oil in the first step, adjusting the original rotation speed, and continuously stirring for 5-8min to obtain a mixed high polymer material raw material;
step six, forming: and D, adding the phosphite ester prepared in the step one into the polymer material obtained in the step five, then pushing the polymer material obtained in the step five to pass through a nozzle at the end part of a charging barrel by a plunger or a screw when the polymer material is in a flowing state, injecting the polymer material into a closed die at 45 ℃, cooling and demoulding the melt filled with the die under a pressed condition to form the environment-friendly wear-resistant polymer material.
2. The processing technology of the environment-friendly wear-resistant polymer material according to claim 1, characterized in that: the raw materials comprise 35 parts of random copolymerization polypropylene, 13 parts of T700 polyacrylonitrile carbon fiber, 7 parts of SP50 nano silicon dioxide, 21 parts of quartz powder, 4 parts of dimethyl carboxyl silicone oil, 3.5 parts of calcium stearate, 7 parts of poly-p-phenylene benzobisoxazole fiber, 7 parts of carboxyl silicone oil and 5.5 parts of liquid phosphite ester.
3. The processing technology of the environment-friendly wear-resistant polymer material according to claim 1, characterized in that: the raw materials comprise 38 parts of random copolymer polypropylene, 13 parts of T700 polyacrylonitrile carbon fiber, 7 parts of SP50 nano silicon dioxide, 21 parts of quartz powder, 4 parts of dimethyl carboxyl silicone oil, 3.5 parts of calcium stearate, 7 parts of poly-p-phenylene benzobisoxazole fiber, 7 parts of carboxyl silicone oil and 5.5 parts of liquid phosphite ester.
4. The processing technology of the environment-friendly wear-resistant polymer material according to claim 1, characterized in that: in the second step, the using amount of the carboxyl silicone oil used for preheating is not more than 70 percent of the total amount of the carboxyl silicone oil; preheating carboxyl silicone oil in the second step to 67 ℃; in the second step, the rotation speed of the first rotation of the first stirring device is 265r/min, and the first stirring time is 3 min; in the second step, the rotating speed of the second rotation is 343r/min, and the time of the second stirring is 5 min.
5. The processing technology of the environment-friendly wear-resistant polymer material according to claim 1, characterized in that: the amount of the carboxyl silicone oil used for preheating in the second step is not more than 50% of the total amount of the carboxyl silicone oil; preheating carboxyl silicone oil in the second step to 68 ℃; in the second step, the first-time stirring device rotates for the first time at the rotating speed of 270r/min, and the first-time stirring time is 2 min; in the second step, the rotating speed of the second rotation is 343r/min, and the time of the second stirring is 4 min.
6. The processing technology of the environment-friendly wear-resistant polymer material according to claim 1, characterized in that: the total amount of the carboxyl silicone oil used in the step four is at least 10 percent of the total amount of the carboxyl silicone oil; the heating temperature of the heating and stirring device is 220 ℃; the rotating speed of the heating and stirring device is 48 r/min; the heating and stirring time in the fourth step is 4-5 min.
7. The processing technology of the environment-friendly wear-resistant polymer material according to claim 1 or 6, characterized in that: and the heating and stirring time in the fourth step is 5 min.
8. The processing technology of the environment-friendly wear-resistant polymer material according to claim 1, characterized in that: the heating temperature in the step five is 65 ℃, and the rotating speed after the adjustment in the step five is 45r/min-50 r/min; and fifthly, adjusting the stirring time after the rotating speed is adjusted to be any one of 6min or 7 min.
9. The processing technology of the environment-friendly wear-resistant polymer material according to claim 1, characterized in that: and in the fifth step, the rotating speed is adjusted to be 48 r/min.
10. The processing technology of the environment-friendly wear-resistant polymer material according to claim 1, 2 or 3, characterized in that: the random copolymerization polypropylene adopts RP2400 polypropylene; the quartz powder is 1000-mesh superfine high-white quartz powder; the dimethyl carboxyl silicone oil is PMX-350 dimethyl carboxyl silicone oil; the calcium stearate is YZSG calcium stearate; poly (p-phenylene benzobisoxazole) fiber 3mmPBO chopped fiber; carboxyl silicone oil GB-209 carboxyl silicone oil; the liquid phosphite is IRGAFOS168 liquid phosphite.
CN202010845078.9A 2020-08-20 2020-08-20 Processing technology of environment-friendly wear-resistant high polymer material Pending CN112341713A (en)

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CN102675740A (en) * 2012-05-17 2012-09-19 北京纳盛通新材料科技有限公司 Long-fiber enhanced thermoplastic composite material vane used for wind energy generator
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