CN112337290A - Water electrolysis disinfection system for livestock and poultry breeding - Google Patents

Water electrolysis disinfection system for livestock and poultry breeding Download PDF

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Publication number
CN112337290A
CN112337290A CN202011085845.7A CN202011085845A CN112337290A CN 112337290 A CN112337290 A CN 112337290A CN 202011085845 A CN202011085845 A CN 202011085845A CN 112337290 A CN112337290 A CN 112337290A
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water
tank
electrolytic
automatic control
passage
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台明栋
刘慧林
池天能
向华
莫树艺
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Guangdong Yuanzhisheng Agricultural Technology Co ltd
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Guangdong Yuanzhisheng Agricultural Technology Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; CARE OF BIRDS, FISHES, INSECTS; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K1/00Housing animals; Equipment therefor
    • A01K1/0047Air-conditioning, e.g. ventilation, of animal housings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; CARE OF BIRDS, FISHES, INSECTS; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K1/00Housing animals; Equipment therefor
    • A01K1/0047Air-conditioning, e.g. ventilation, of animal housings
    • A01K1/0052Arrangement of fans or blowers
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; CARE OF BIRDS, FISHES, INSECTS; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K1/00Housing animals; Equipment therefor
    • A01K1/0047Air-conditioning, e.g. ventilation, of animal housings
    • A01K1/0082Water misting or cooling systems
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; CARE OF BIRDS, FISHES, INSECTS; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K29/00Other apparatus for animal husbandry
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; CARE OF BIRDS, FISHES, INSECTS; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K39/00Feeding or drinking appliances for poultry or other birds
    • A01K39/02Drinking appliances
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; CARE OF BIRDS, FISHES, INSECTS; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K45/00Other aviculture appliances, e.g. devices for determining whether a bird is about to lay
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; CARE OF BIRDS, FISHES, INSECTS; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K7/00Watering equipment for stock or game
    • A01K7/02Automatic devices ; Medication dispensers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/02Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using physical phenomena
    • A61L2/03Electric current
    • A61L2/035Electrolysis
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/16Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
    • A61L2/22Phase substances, e.g. smokes, aerosols or sprayed or atomised substances
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/26Accessories or devices or components used for biocidal treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2202/00Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
    • A61L2202/10Apparatus features
    • A61L2202/11Apparatus for generating biocidal substances, e.g. vaporisers, UV lamps
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2202/00Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
    • A61L2202/10Apparatus features
    • A61L2202/14Means for controlling sterilisation processes, data processing, presentation and storage means, e.g. sensors, controllers, programs
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2202/00Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
    • A61L2202/10Apparatus features
    • A61L2202/15Biocide distribution means, e.g. nozzles, pumps, manifolds, fans, baffles, sprayers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/91Bacteria; Microorganisms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0266Other waste gases from animal farms
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/463Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrocoagulation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/465Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electroflotation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4672Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
    • C02F1/4674Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation with halogen or compound of halogens, e.g. chlorine, bromine
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/20Nature of the water, waste water, sewage or sludge to be treated from animal husbandry
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/04Disinfection

Abstract

The invention discloses an electrolytic water disinfection system for livestock and poultry breeding, which comprises a spraying disinfection system, an air treatment system, a wastewater treatment system, a drinking water treatment system and an automatic control system. By adopting the invention, the spray disinfection system, the air treatment system, the wastewater treatment system and the drinking water treatment system can be controlled by the automatic control system, so that comprehensive automatic spray disinfection treatment in a farm is realized, air in the farm is effectively purified, the farm is cooled, wastewater is purified and disinfected, and drinking water is effectively sterilized and disinfected, thereby providing safe and healthy drinking water for livestock and poultry.

Description

Water electrolysis disinfection system for livestock and poultry breeding
Technical Field
The invention relates to the field of livestock and poultry breeding, in particular to an electrolytic water disinfection system for livestock and poultry breeding.
Background
With the economic development and the technical progress, the breeding industry in China is continuously developed vigorously, however, with the continuous expansion of the breeding scale of livestock and poultry, the problems of bacterial killing, air purification, wastewater treatment, drinking water treatment and the like in the breeding of livestock and poultry need to be solved urgently.
A large amount of bacteria and viruses existing in livestock and poultry farms are easy to induce livestock and poultry diseases, and further cause economic loss. At present, more and more livestock and poultry farms begin to attach importance to the problem of breeding of bacteria, however in actual operation, the farm adopts the operation of manual spraying more, and the disinfectant fluid of adoption is also manual preparation, and such operation is very troublesome, work efficiency is low, has the problem that produces sanitary dead angle easily, and the water consumption is big. In addition, the current livestock and poultry farms do not systematically sterilize the entire plant area, vehicles and personnel, which also creates a risk of disease.
Often have the too high condition of gas content such as ammonia nitrogen, hydrogen sulfide in the beasts and birds plant, present plant adopts fan system more, does the ventilation treatment to the plant, however these waste gases are all directly to discharge among the atmosphere untreated, have resulted in the peripheral air pollution of beasts and birds plant, have destroyed ecological environment. The current ventilation treatment method does not fundamentally solve the problem of air purification. Moreover, the air in livestock and poultry farms may also carry bacteria and viruses, which easily cause health problems of livestock and poultry, and are discharged into the atmosphere without being treated, thus easily causing the diffusion of viruses.
The wastewater of the livestock and poultry farm has the conditions of high organic matter concentration, high COD value, high ammonia nitrogen content, high organic phosphorus content and many suspended matters, wherein the COD value is as high as 3000-plus 12000mg/L, the ammonia nitrogen content is as high as 800-plus 2200mg/L, and moreover, the wastewater of the livestock and poultry farm also contains a large amount of bacteria, and if the wastewater is directly discharged, the environment can be seriously polluted. At present, corresponding treatment technologies are provided for wastewater of a farm, but bacteria and viruses in the water are not killed, and the obtained water still has the problem that the bacteria exceed the standard.
The drinking water for livestock and poultry breeding mainly takes well water as main water, the management and disinfection of the well water are closely related to livestock and poultry, and the water quality extracted from a water well into a water pool needs to be sterilized and disinfected. Because well water is taken from underground, water sources can be influenced by underground pollutants, surface dirt, rainfall and the like, and various bacteria and viruses or microorganisms such as red worms, algae and the like are easy to breed. In order to prevent diseases transmitted by water from occurring and spreading, ensure the health of livestock and poultry, the livestock and poultry farms disinfect drinking water, however, more than 90% of livestock and poultry drinking water in China still adopt a conventional treatment process, the conventional treatment process can only remove about 30% of organic matters in the water, and the treatment effect on some pollutants, especially chemical pollution, is very limited.
Therefore, a system capable of simultaneously treating bacterial killing, air, wastewater and drinking water in livestock and poultry breeding is an urgent need for breeding.
Disclosure of Invention
The technical problem to be solved by the invention is to provide an electrolyzed water disinfection system for livestock and poultry cultivation, which can realize comprehensive automatic spraying disinfection treatment in a cultivation plant area, effectively purify air of the cultivation plant, cool the cultivation plant, purify and disinfect waste water and effectively sterilize and disinfect drinking water, and provide safe and healthy livestock and poultry drinking water.
In order to solve the technical problem, the invention provides an electrolytic water disinfection system for livestock and poultry breeding, which comprises a spraying disinfection system, an air treatment system, a wastewater treatment system, a drinking water treatment system and an automatic control system;
the spraying sterilization system comprises an electrolyzed water generation system and a spraying pipeline system for conveying electrolyzed water; the electrolyzed water generation system comprises a filtering device, a first reservoir, an electrolysis device and a second reservoir which are sequentially connected through pipelines; the spraying pipeline system comprises a spraying generating device, a spraying pipeline and an atomizing nozzle, wherein the spraying pipeline and the atomizing nozzle are connected with the spraying generating device; the spraying pipeline is used for conveying the sterilized water to a farm, a personnel sterilization area and a vehicle sterilization area;
the air treatment system comprises an air draft device, an air supply device, a reaction tower, a conveying pipeline and a sterilized water circulation system; the system comprises a farm, a reaction tower, an air supply device, a gas pipeline; a plurality of layers of water curtains for sterilizing air are arranged in the reaction tower;
the wastewater treatment system comprises a solid-liquid separation tank, a sedimentation tank, a first water pump, an electric flocculation module, an electric floating flocculation tank, a second water pump, an electrolysis module and a purified water sedimentation tank which are sequentially connected through a pipeline; the electric air flotation flocculation tank is connected with a first impurity bubble collecting tank, and the purified water sedimentation tank is connected with a second impurity bubble collecting tank; the purified water sedimentation tank is connected with an external water pump;
the drinking water treatment system comprises a water inlet pipe, a drinking water treatment device and a water outlet pipe; the drinking water treatment device comprises a first electrolytic tank;
the automatic control system is connected with the spraying sterilization system, the air treatment system, the wastewater treatment system and the drinking water treatment system.
As an improvement of the scheme, the first reservoir and the second reservoir are respectively provided with a first reservoir liquid level sensor and a second reservoir liquid level sensor; the electrolysis device comprises a water inlet passage, a salt adding passage, a second electrolysis bath, a first water outlet passage, a second water outlet passage, a cleaning liquid passage and a cleaning liquid backflow passage;
when the data of the first liquid level sensor is smaller than a low water level threshold value, the automatic control system starts a filtering device, and the filtering device filters source water to generate purified water which is stored in the first water storage tank; when the data of the first liquid level sensor is higher than a high water level threshold value, the automatic control system closes the filtering device;
when the data of the second liquid level sensor is smaller than a low water level threshold value, the automatic control system sends an electrolysis starting signal to an electrolysis device, and the purified water in the first water reservoir is processed by the electrolysis device to generate electrolyzed water which is stored in the second water reservoir; and when the data of the second liquid level sensor is higher than a high water level threshold value, the automatic control system turns off the electrolysis device.
As an improvement of the above scheme, the water inlet passage consists of a water inlet pump, a water flow switch and a first water inlet valve; the water inlet pump is connected with the first reservoir through a pipeline; the first water inlet valve is connected with the second electrolytic tank through a pipeline; the salt adding passage consists of a brine barrel and a peristaltic pump, and the brine barrel is connected with the first water inlet valve through the peristaltic pump; the brine is mixed with the purified water in the water inlet passage through the brine adding passage and is introduced into the second electrolytic tank; the first water outlet passage consists of a first water outlet valve, and the second electrolytic tank is connected with the second reservoir through the first water outlet valve; the second water outlet passage consists of a second water outlet valve, a drainage pump, a third water outlet valve and a waste discharge port; the cleaning liquid passage consists of a cleaning liquid barrel, a cleaning liquid pump and a second water inlet valve; the cleaning liquid return flow path is composed of a fourth water outlet valve, and the draining pump is connected with the cleaning liquid barrel through the fourth water outlet valve.
As an improvement of the scheme, an effective chlorine concentration meter is arranged in the second electrolytic tank; when the data of the second liquid level sensor is smaller than the low water level threshold, the automatic control system sends an electrolysis starting signal to the electrolysis device, so that a water inlet passage and a salt adding passage are opened, and purified water in the first reservoir enters a second electrolysis tank; when the data of the effective chlorine concentration meter accords with the effective chlorine threshold, the automatic control system opens a first water outlet passage to lead the electrolyzed water in the second electrolytic tank to be led into a second reservoir;
when the automatic control system sends a starting drainage signal to the electrolysis device, the water inlet passage and the first water outlet passage are closed, the second water outlet passage is opened, and water in the second electrolysis bath is drained to the waste discharge port through the second water outlet valve, the drainage pump and the third water outlet valve in sequence; when the water in the second electrolytic tank is emptied, closing the second water outlet valve;
when the automatic control system sends a cleaning starting signal to the electrolytic device, only the cleaning liquid passage is opened in the electrolytic device, the cleaning liquid in the cleaning liquid barrel is quantitatively introduced into the second electrolytic tank through the cleaning liquid pump and a second water inlet valve, and the second electrolytic tank is cleaned after the cleaning liquid passage is closed; and after the cleaning treatment of the second electrolytic tank is finished, opening the cleaning liquid backflow passage, and allowing the cleaning liquid in the second electrolytic tank to flow back to the cleaning liquid barrel through the second water outlet valve, the drainage pump and the cleaning liquid backflow passage.
As an improvement of the above scheme, the disinfection water circulation system in the air treatment system comprises a water collecting tank arranged below the reaction tower and used for collecting disinfection water, an electrolytic tank connected with the water collecting tank, a water suction pump arranged above the electrolytic tank and a spray device arranged above the water curtain, wherein the water suction pump is connected with the spray device through a pipeline; an electrolytic cell electrolysis device for electrolyzing the generated disinfectant water is arranged in the electrolytic cell; the spraying device comprises a disinfection water pipeline and a spraying head arranged on the disinfection water pipeline.
As an improvement of the scheme, an electrolytic cell liquid level sensor, an effective chlorine sensor and an automatic water adding device are arranged in the electrolytic cell; when the numerical value of the electrolytic cell liquid level sensor is lower than a low water level threshold value, the automatic control system starts an automatic water adding device, and the automatic water adding device conveys source water into the electrolytic cell;
when the numerical value of the electrolytic cell liquid level sensor meets a water level threshold value, the automatic control system closes the automatic water adding device and starts the electrolytic cell electrolytic device, and the electrolytic cell electrolytic device electrolyzes source water to generate electrolytic water;
when the data of the effective chlorine sensor accords with the effective chlorine threshold value, the automatic control system sends a starting signal to a disinfection water circulation system, the water suction pump conveys the electrolyzed water in the electrolytic cell to the spray pipeline, the electrolyzed water is sprayed onto the water curtain through the spray header, and the electrolyzed water flows into the water collecting tank through the water curtain and flows back to the electrolytic cell.
As an improvement of the scheme, a first overflow outlet is arranged on the side wall of the electric floatation flocculation tank, the electric floatation flocculation tank is communicated with the first impurity bubble collection tank through the first overflow outlet, and the lower surface of the first overflow outlet is an inclined surface inclined towards the first impurity bubble collection tank;
a second overflow outlet is arranged on the side wall of the purified water sedimentation tank, and the purified water sedimentation tank is communicated with the second impurity bubble collecting tank through the second overflow outlet; the lower surface of the second overflow port is an inclined plane inclined towards the second impurity bubble pool.
As an improvement of the scheme, a flocculation tank liquid level sensor and a sedimentation tank liquid level sensor are respectively arranged in the electric floating flocculation tank and the purified water sedimentation tank, and a water quality detector is arranged in the purified water sedimentation tank; when the numerical value of the water quality monitor does not accord with the water quality threshold value, the automatic control system sends an electrolysis strengthening signal to the electric flocculation module and the electrolysis module to strengthen the current; when the numerical value of the flocculation tank liquid level sensor is higher than the highest threshold value, the automatic control system closes the first water suction pump and the electric flocculation module, and then water inflow to the electric floatation flocculation tank is stopped; when the numerical value of the sedimentation tank liquid level sensor is higher than the highest threshold value, the automatic control system closes the second water suction pump and the electrolysis module, and then water inflow to the purified water sedimentation tank is stopped; and when the numerical value of the sedimentation tank liquid level sensor is lower than the lowest threshold value, the automatic control system closes the external water pump to avoid dry pumping of the external water pump.
As an improvement of the scheme, an ammonia nitrogen sensor is arranged in the farm; when the numerical value of the ammonia nitrogen sensor in the farm is not in accordance with the air quality threshold value or the numerical value of the temperature sensor in the farm is not in accordance with the temperature threshold value, the automatic control system sends a starting signal of the air treatment system, and then the disinfection water circulation system is started.
As a modification of the above, the first electrolytic tank includes a case, an anode electrode and a cathode electrode; the anode electrode and the cathode electrode are respectively arranged on two sides of the shell; the anode electrode and the cathode electrode respectively comprise a conductive plate arranged outside the shell and a plurality of electrode plates arranged on the conductive plate.
The implementation of the invention has the following beneficial effects:
1. the automatic control system controls the spraying sterilization system, the air treatment system, the wastewater treatment system and the drinking water treatment system, so that comprehensive automatic spraying sterilization treatment in a breeding plant area is realized, air in the breeding plant is effectively purified, the breeding plant is cooled, wastewater is purified and sterilized, drinking water is effectively sterilized, and safe and healthy livestock drinking water is provided.
2. The spraying sterilization system has high safety and good sterilization effect, and can realize comprehensive automatic spraying sterilization treatment in a breeding plant area, thereby achieving the effects of sterilizing and disinfecting and reducing the breeding risk of diseases; the system of disinfecting and sterilizing sprays the pipeline system and controls electrolytic water generating system and spraying through automatic control system, automatic control system can control opening and closing of filter equipment and electrolytic device through the water level that detects the cistern, can also control the operation of spraying the pipeline system according to the sensor in plant, personnel disinfection district and the vehicle disinfection district to realize that the plant area is comprehensively disinfected and sterilized. In the invention, raw water passes through a filtering device to generate purified water, and the purified water is electrolyzed with saline water in an electrolysis device to generate the sterilized water containing hypochlorite and chlorite, and the sterilized water is healthy, harmless, green and environment-friendly.
3. The wastewater treatment system adopts the electric flocculation, the electric air flotation and the electrolysis technology to treat the livestock and poultry breeding wastewater, and the electrolysis treatment is carried out again after the electric flocculation and the electric air flotation treatment, so as to obtain the purified water which is thoroughly sterilized and meets the discharge standard. The livestock and poultry breeding wastewater treatment system is simple in structure, convenient to operate and good in sterilization effect, and can clarify water quality and disinfect wastewater, so that the effects of saving energy, reducing emission and purifying wastewater are achieved.
4. The drinking water treatment system adopts the electrolysis technology to carry out sterilization and disinfection treatment on the livestock and poultry breeding drinking water, and the drinking water meeting the regulations of GB 5749 and 2006 is obtained. The drinking water treatment system comprises a water inlet pipe, a drinking water treatment device and a water outlet pipe; the drinking water treatment system is convenient to operate, has remarkable effect, can disinfect water sources with different water qualities, meets the drinking water supply requirements of most farms, and provides safe and healthy livestock and poultry drinking water
Drawings
FIG. 1 is a block diagram of an electrolytic water disinfection system for livestock and poultry farming according to the present invention;
FIG. 2 is a schematic structural view of the spray killing system of the present invention;
FIG. 3 is a schematic structural view of an embodiment of the spray pipe system of the present invention;
FIG. 4 is a flow diagram of an electrolysis apparatus of the present invention;
FIG. 5 is a schematic structural view of an air handling system of the present invention;
FIG. 6 is a schematic view of the structure of a wastewater treatment system of the present invention;
FIG. 7 is a schematic structural diagram of an electro-flotation flocculation tank of the invention;
FIG. 8 is a schematic view of the structure of the purified water sedimentation tank of the present invention;
fig. 9 is a schematic structural view of a first embodiment of the drinking water treatment system of the present invention;
FIG. 10 is a schematic view of the structure of a first electrolytic cell of the present invention;
fig. 11 is a schematic structural view of a second embodiment of the drinking water treatment system of the present invention;
fig. 12 is a schematic configuration diagram of a third embodiment of the drinking water treatment system of the present invention.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention will be described in further detail with reference to the accompanying drawings.
Referring to fig. 1, the invention provides an electrolytic water disinfection system for livestock and poultry breeding, which comprises a spray disinfection system 1, an air treatment system 2, a wastewater treatment system 3, a drinking water treatment system 4 and an automatic control system 5; the automatic control system 5 adopts a PLC controller.
The air treatment system comprises an air draft device, an air supply device, a reaction tower, a conveying pipeline and a sterilized water circulation system; the system comprises a farm, a reaction tower, an air supply device, a gas pipeline; a plurality of layers of water curtains for sterilizing air are arranged in the reaction tower;
the wastewater treatment system comprises a solid-liquid separation tank, a sedimentation tank, a first water pump, an electric flocculation module, an electric floating flocculation tank, a second water pump, an electrolysis module and a purified water sedimentation tank which are sequentially connected through a pipeline; the electric air flotation flocculation tank is connected with a first impurity bubble collecting tank, and the purified water sedimentation tank is connected with a second impurity bubble collecting tank; the purified water sedimentation tank is connected with an external water pump;
the drinking water treatment system comprises a water inlet pipe, a drinking water treatment device and a water outlet pipe; the drinking water treatment device comprises a first electrolytic tank;
the automatic control system 5 is connected with the spraying sterilization system, the air treatment system, the wastewater treatment system and the drinking water treatment system.
Referring to fig. 2, the spray sterilizing system 1 includes an electrolyzed water generating system and a spray piping system for conveying electrolyzed water; the electrolyzed water generation system comprises a filtering device 11, a first reservoir 12, an electrolysis device 13 and a second reservoir 14 which are connected in sequence through pipelines; the first reservoir 12 and the second reservoir 14 are respectively provided with a first reservoir liquid level sensor and a second reservoir liquid level sensor; the spray pipeline system comprises a spray generating device 15, a spray pipeline 16 and an atomizing nozzle 17, wherein the spray pipeline 16 and the atomizing nozzle 17 are connected with the spray generating device 15; the spray pipeline 16 comprises a main pipeline 161 for conveying the sterilized water to the farm 6, the personnel sterilization area 7 and the vehicle sterilization area 8, and branch pipelines 162 arranged in the farm 6, the personnel sterilization area 7 and the vehicle sterilization area 8; the branch pipe 162 is communicated with the main pipe 161; the atomizing nozzle 17 is arranged on the branch pipeline 162; the number of branch pipelines 162 in the farm 6, the personnel disinfection area 7 and the vehicle disinfection area 8 is more than or equal to 2;
the first reservoir 12 and the second reservoir 14 are respectively provided with a first reservoir liquid level sensor and a second reservoir liquid level sensor; an ammonia nitrogen sensor is arranged in the farm 6; when the data of the first liquid level sensor is smaller than the low water level threshold, the automatic control system 5 starts a filtering device, and the filtering device 11 filters source water to generate purified water which is stored in the first water storage tank 12; when the data of the first level sensor is higher than the high water level threshold, the automatic control system 5 turns off the filtering device 11;
when the data of the second liquid level sensor is smaller than the low water level threshold, the automatic control system 5 sends an electrolysis starting signal to an electrolysis device 13, and the purified water in the first reservoir 12 is processed by the electrolysis device 13 to generate electrolyzed water which is stored in the second reservoir 14; when the data of the second level sensor is higher than the high water level threshold, the automatic control system 5 turns off the electrolysis device 13.
A timing and quantitative controller is arranged in the farm 6, and an infrared sensor, a radar sensor or a geomagnetic sensor is arranged in the personnel disinfection area 7 and the vehicle disinfection area 8; the timing and quantitative controller, the infrared sensor, the radar sensor and the geomagnetic sensor are connected with the spraying pipeline system and the automatic control system 5; the timing and quantitative controller can realize timing and quantitative spraying on the farm 6; the sensors of the personnel and vehicle disinfection zones 7, 8 can automatically initiate spray disinfection of personnel and vehicles entering the disinfection zones.
A water source forms purified water through the filtering device 11 and is stored in the first reservoir 12, the purified water in the first reservoir 12 passes through the electrolysis device 13 to generate electrolyzed water and is stored in the second reservoir 14, and the electrolyzed water in the second reservoir 14 forms spray through the spray generating device 15 and is pressurized and pressed out; the filtering device 11 comprises a filter element and a backwashing module (not shown in the figure), and the backwashing module is used for backwashing the filtering device, so that the filter element can be effectively cleaned, and the service life of the filter element is prolonged.
Referring to fig. 3, an embodiment of the present invention provides a schematic structural diagram of the spray piping system located in the farm 6, the distance between the branch pipes 162 is 1.5-2.5m, and the laying scheme of the branch pipes 162 is adjusted according to the area of the area and the coverage of the atomizing nozzles 17; the distance between the branch pipeline 162 at the outermost layer and the edge of the area is 0.5-1m, so that dead angles of disinfection are reduced, the disinfection effect is improved, and full-coverage disinfection of the area is realized; the main pipeline 161 is connected with the branch pipelines 162 through a three-way joint, and the tail ends of the branch pipelines 162 are connected with each other through a three-way joint to form a closed loop; a plurality of atomizing nozzles 17 are arranged on the branch pipeline 162, and the distance between the atomizing nozzles 17 on the same branch pipeline 162 is 1-2 m; preferably, a plurality of four-way joints are arranged on the branch pipeline 162, the atomizing nozzles 17 are symmetrically arranged at two opposite interfaces of the four-way joints, further, the atomizing nozzles 17 are adjusted to horizontal spraying positions, and the distance between the four-way joints on the same branch pipeline 162 is 1-2 m; preferably, the pipe diameter of the main pipe 161 is 10-20 mm; the pipe diameter of the branch pipeline 162 is 8-12mm, and the spray pipeline 16 is a PE pipe; preferably, the main pipe 161 is a quartering pipe, and the branch pipe 162 is a trisection pipe.
As shown in fig. 4, the electrolysis device 13 includes a water inlet passage 131, a salt adding passage 132, a second electrolysis bath 133, a first water outlet passage 134, a second water outlet passage 135, a cleaning solution passage 136 and a cleaning solution return passage 137; an effective chlorine concentration meter is arranged in the second electrolytic tank 133;
the water inlet passage 131 consists of a water inlet pump 131a, a water flow switch 131b and a first water inlet valve 131 c; the water inlet pump 131a is connected with the first reservoir 12 through a pipeline; the first water inlet valve 131c is connected with the electrolytic bath 133 through a pipeline; the water inlet channel 131 is used for introducing the purified water in the first reservoir 12 into the electrolytic cell 133, and the water flow switch 131b can control the rate of the purified water introduced into the electrolytic cell 133, and collect the information of the water flow into the automatic control system 5, thereby setting the electrolysis time and the current of the electrolytic cell 133 according to the data;
the salting passage 132 is composed of a brine tank 132a and a peristaltic pump 132b, the brine tank 132a being connected to the first water inlet valve 131c by the peristaltic pump 132 b; the brine is mixed with the purified water in the water inlet passage 131 through a brine adding passage 132 and is introduced into the electrolytic bath 133; the peristaltic pump 131b is connected with the automatic control system 5;
in the electrolytic bath 133, the saline water and the purified water are mixed and electrolyzed to generate sterilized water with hypochlorite and chlorite as main components;
the first water outlet passage 134 is composed of a first water outlet valve 134a, and the electrolytic bath 133 is connected with the second reservoir 14 through the first water outlet valve 134 a; an effective chlorine concentration meter is arranged in the electrolytic cell 133, and when the effective chlorine concentration reaches 50-250mg/L, the automatic control system 5 opens the first water outlet passage 134 to lead the electrolyzed water in the electrolytic cell 133 to be led into the second reservoir;
the second water outlet passage 135 is composed of a second water outlet valve 135a, a drainage pump 135b, a third water outlet valve 135c and a waste outlet 135 d; before the electrolytic cell 133 is subjected to the washing step, the water in the electrolytic cell 133 is drained through the second water outlet passage 135;
the cleaning liquid path 136 is composed of a cleaning liquid barrel 136a, a cleaning liquid pump 136b and a second water inlet valve 136 c; the cleaning liquid channel 136 can input cleaning liquid into the electrolytic cell 133, and the cleaning liquid can effectively remove the scale of the electrolytic cell 133, thereby prolonging the service life of the electrolytic cell 133;
the cleaning solution backflow passage 137 is composed of a fourth water outlet valve 137a, and the drainage pump 135b is connected to the cleaning solution tank 136a through the fourth water outlet valve 137 a; after the cleaning step of the electrolytic bath 133 is completed, the cleaning solution flows back to the cleaning solution tank 136a through the cleaning solution return passage 137, so that the cleaning solution is recycled, and the purposes of energy conservation and environmental protection are achieved.
When the data of the second liquid level sensor is smaller than the low water level threshold, the automatic control system 5 sends an electrolysis starting signal to the electrolysis device 13, so as to open the water inlet passage 131 and the salt adding passage 132, and the purified water in the first reservoir 12 enters the second electrolysis bath 133; when the data of the available chlorine concentration meter meets the available chlorine threshold, the automatic control system 5 opens a first water outlet passage 134, so that the electrolyzed water in the second electrolytic tank 133 is introduced into the second water reservoir 14;
when the automatic control system 5 sends a starting water discharge signal to the electrolysis device 13, the water inlet passage 131 and the first water outlet passage 134 are closed, the second water outlet passage 135 is opened, and the water in the second electrolysis tank 133 passes through the second water outlet valve 135a, the drainage pump 135b and the third water outlet valve 135c in sequence and is discharged to the drainage port 135 d; when the water in the second electrolytic tank 133 is empty, the second water outlet valve 135a is closed;
when the automatic control system 5 sends a cleaning start signal to the electrolysis device, only the cleaning solution passage 136 is opened in the electrolysis device 13, the cleaning solution in the cleaning solution barrel 136a is quantitatively introduced into the second electrolysis bath 133 through the cleaning solution pump 136b and the second water inlet valve 136c, and the cleaning treatment is performed on the second electrolysis bath 133 after the cleaning solution passage 136 is closed; when the cleaning process of the second electrolytic tank 133 is completed, the cleaning solution backflow passage 137 is opened, and the cleaning solution in the second electrolytic tank 133 flows back to the cleaning solution tank through the second water outlet valve 135a, the drain pump 135b and the cleaning solution backflow passage 137.
The working flow of the spraying sterilization system is as follows:
and (3) filtering: introducing a water source into a filtering device for filtering, and storing the filtered purified water in a first reservoir;
the water source enters a filtering device, a filter element of the filtering device filters the water source to form purified water, and the purified water is introduced into the first reservoir through a pipeline to be stored;
an electrolysis step: purified water in the first reservoir is led into an electrolysis device to be electrolyzed to generate sterilized water, and the sterilized water is led into the second reservoir through a pipeline to be stored;
introducing purified water in the first reservoir into the electrolysis device; the water inlet passage is opened, purified water is introduced into the electrolytic cell to be electrolyzed to generate disinfectant water with main components of hypochlorite and chlorite, when the effective chlorine concentration meter detects that the electrolytic water in the electrolytic cell reaches the standard, the automatic control system closes the electrolytic treatment of the electrolytic cell and opens the first water outlet passage, and the disinfectant water reaching the standard is conveyed to the second reservoir through a pipeline to be stored;
spraying: the electrolyzed water in the second reservoir is pressurized by the spray generating device and is conveyed to the atomizing nozzle through the spraying pipeline to be sprayed out;
the electrolyzed water in the second reservoir forms spray through a spray generating device, is pressurized and extruded out, is conveyed by a spray pipeline and is sprayed out by an atomizing nozzle, so that the disinfection of a farm, a personnel disinfection area and a vehicle disinfection area is realized; the electrolyzed water is collected into a solid-liquid separation tank through a drainage channel after being disinfected and is discharged after being treated by a wastewater treatment system.
Referring to fig. 5, the air treatment system 2 includes an air draft device 21, an air supply device 22, a reaction tower 23, a conveying pipeline 24 and a sterilized water circulation system; the farm 6 is provided with an air suction opening 61 and an air supply opening 62, and the air suction opening 61, the air draft device 21, the reaction tower 23, the air supply device 22 and the air supply opening 62 are sequentially connected through the conveying pipeline 24; preferably, the suction opening 61 and the air supply opening 62 are respectively arranged on opposite or adjacent walls of the farm 6; the air draft device 21 is arranged at the bottom of the reaction tower 23, and the air supply device 22 is arranged at the top of the reaction tower 23; a plurality of layers of water curtains 231 for sterilizing air are arranged in the reaction tower 23; the water curtain 231 is installed on the inner wall of the reaction tower 23, the number of the water curtains 231 is 4-8, preferably, an installation hole for installing the water curtain 231 is formed in the reaction tower 23, and the water curtain 231 is fixed with the installation hole through a bolt, so that the connection with the inner wall of the reaction tower 23 is realized;
an ammonia nitrogen sensor (not shown in the figure) is arranged in the farm 6, when the ammonia nitrogen sensor detects that the ammonia nitrogen content exceeds the standard, the ammonia nitrogen sensor transmits data to the automatic control system 5, and the automatic control system 5 starts an air draft device 21, an air supply device 22 and a sterilized water circulation system; further, when the ammonia nitrogen sensor detects that the ammonia nitrogen content belongs to the normal range, the automatic control system 5 can automatically close the air draft device 21, the air supply device 22 and the disinfection water circulation system, so that electricity is saved; preferably, a temperature sensor is further arranged inside the farm 6, and the temperature sensor is connected with the automatic control system 5; when the temperature exceeds the standard, the automatic control system 5 starts the air draft device 21, the air supply device 22 and the sterilized water circulating system, so that the temperature in the farm 6 is reduced;
an external air inflow channel 232 is arranged at the bottom of the reaction tower 23, and a purified air discharge channel 233 is arranged at the top of the reaction tower; the conveying pipeline 24 between the reaction tower 23 and the air supply device 22, the external air inflow passage 232 and the purified air discharge passage 233 are all provided with a one-way air valve 234;
the one-way air valve 234 on the conveying pipeline 24 between the reaction tower and the air supply device 22 limits the air flowing towards the farm 6, thereby preventing the waste gas in the farm 6 from returning to the reaction tower 23 and polluting the purified air in the reaction tower 23; the one-way air valve 234 of the external air inflow passage 232 restricts the flow of air toward the reaction tower 23, preventing the non-sterilized exhaust gas from being discharged to the atmosphere; the one-way air valve 234 on the external air inflow channel 232 is opened periodically according to requirements, so that fresh external air can be input into the reaction tower 23, enters the reaction tower 23 at the bottom, is sterilized by the water curtain 231 and then is sent into the farm 6, and therefore air carrying bacterial viruses outside is prevented from polluting the farm 6, and the risk of air-borne diseases is reduced; the one-way air valve 234 of the purified air discharging passage 233 restricts the flow of air to the outside of the reaction tower 23, thereby preventing the non-sterilized air from entering the reaction tower 23 through the purified air discharging passage 233 to contaminate the sterilized purified air; the one-way air valve 234 of the purified air discharging passage 233 can be opened periodically according to the demand to discharge the purified and sterilized purified air to the atmosphere, thereby accelerating the replacement speed of the fresh air.
The sterilizing water circulating system comprises a water collecting tank 25 arranged below the reaction tower 23 and used for collecting sterilizing water, an electrolytic tank 26 connected with the water collecting tank 25, a water suction pump 27 arranged above the electrolytic tank 26 and a spraying device 28 arranged above the water curtain 231, wherein the water suction pump 27 is connected with the spraying device 28 through a pipeline; an electrolytic cell electrolysis device 261 for electrolyzing generated sterilized water is arranged in the electrolytic cell 26; the disinfectant circulating system can automatically electrolyze to generate disinfectant, and is matched with the reaction tower 23 to treat waste gas, so that disinfectant is not required to be additionally added into the system, manual operation is not required, and the automatic air purification effect of a farm can be realized;
the spraying device 28 comprises a sterilized water pipeline 281 and spraying heads 282 arranged on the sterilized water pipeline 281, the number of the spraying heads 282 is 5-8, and the intervals between the spraying heads 282 are equal; the spraying device 28 uniformly sprays the sterilizing water onto the highest water curtain 231, the sterilizing water flows downwards from the highest water curtain to the lowest water curtain step by step and is finally recycled into the water collecting tank 25, and the sterilizing water flowing downwards from top to bottom can effectively bring bacteria and viruses into the water collecting tank 25; the waste gas enters the reaction tower 23 from the bottom and passes through the multiple layers of water curtains 231, so that the waste gas is fully contacted with the disinfectant to be disinfected to form purified air, bacterial viruses in the waste gas are oxidized and killed by the electrolyzed disinfectant, and along with degradation of ammonia nitrogen in the waste gas, the odor of the waste gas is eliminated, thereby meeting the actual requirement of green cultivation; in addition, the water curtain 231 takes away heat in the exhaust gas while purifying and disinfecting, and purified air with low heat obtained by disinfection is sent into the farm 6, so that the space of the farm 6 can be cooled;
the collecting tank 25 is communicated with the electrolytic tank 26, and the electrolytic tank electrolysis device 261 in the electrolytic tank 26 can electrolyze to generate sterilized water, so that the used sterilized water in the collecting tank 25 is electrolyzed again for recycling, and the effect of energy conservation is achieved; preferably, a proper amount of salt can be added into the electrolytic cell 26 to improve the electrolytic effect, so that sterilized water meeting the standard is generated; the electrolytic cell 26 is provided with an effective chlorine sensor (not shown in the figure), the automatic control system 5 can set the electrolysis time of the electrolytic cell electrolysis device 261 according to the effective chlorine content, when the data of the effective chlorine sensor accords with the effective chlorine threshold value, the automatic control system 5 sends a starting signal to a disinfection water circulation system, the water suction pump conveys the electrolyzed water in the electrolytic cell to the spray pipeline, the electrolyzed water is sprayed to the water curtain through the spray head, and the electrolyzed water flows into the water collecting tank through the water curtain and flows back to the electrolytic cell.
The electrolytic cell 26 is also provided with a liquid level sensor and an automatic water adding device, when the numerical value of the liquid level sensor of the electrolytic cell is lower than a low water level threshold value, the automatic control system 5 starts the automatic water adding device, and the automatic water adding device conveys source water into the electrolytic cell; when the numerical value of the electrolytic cell liquid level sensor meets the water level threshold value, the automatic control system 5 closes the automatic water adding device and starts the electrolytic cell electrolytic device, and the electrolytic cell electrolytic device electrolyzes source water to generate electrolytic water.
The working flow of the air treatment system is as follows:
when the numerical value of an ammonia nitrogen sensor in the farm does not accord with the air quality threshold value or the numerical value of a temperature sensor in the farm does not accord with the temperature threshold value, the automatic control system sends a starting signal of a sterilized water circulation system;
electrolyzing the electrolytic cell to generate disinfectant fluid, conveying the disinfectant fluid to a spray head through a water pump and a spray pipeline, and spraying the disinfectant fluid to a water curtain in the reaction tower;
the automatic control system sends starting signals of the air draft device and the air supply device;
the exhaust device is used for pumping the waste gas in the farm to the reaction tower, the waste gas reaches the top of the reaction tower through the water curtain and is sent back to the farm through the air supply device;
and when the numerical values of the ammonia nitrogen sensor and the temperature sensor in the farm meet the threshold value, the automatic control system sends a stop signal of the air treatment system.
As shown in fig. 6, the wastewater treatment system 3 includes a solid-liquid separation tank 31, a sedimentation tank 32, a first water pump 33, an electric flocculation module 34, an electric floating flocculation tank 35, a second water pump 36, an electrolysis module 37 and a purified water sedimentation tank 38; the solid-liquid separation tank 31, the sedimentation tank 32, the first water pump 33, the electric flocculation module 34, the electric floating flocculation tank 35, the second water pump 36, the electrolysis module 37 and the purified water sedimentation tank 38 are sequentially connected through pipelines; an electric air flotation electrode and an electric flocculation electrode are arranged in the electric air flotation flocculation tank 35, and an electric air flotation electrode is arranged in the purified water sedimentation tank 38; preferably, the number of the electric flocculation module 34 and the electrolysis module 37 is more than two.
As shown in fig. 7 and 8, the electro-flotation flocculation tank 35 is connected to a first impurity bubble collecting tank 351, and the purified water sedimentation tank 38 is connected to a second impurity bubble collecting tank 381; preferably, a first overflow outlet 352 is arranged on the side wall of the electric floatation flocculation tank 35, and the electric floatation flocculation tank 35 is communicated with the first impurity bubble collection tank 351 through the first overflow outlet 352; a second overflow port 382 is arranged on the side wall of the purified water sedimentation tank 38, and the purified water sedimentation tank 38 is communicated with the second impurity bubble collecting tank 381 through the second overflow port 382; the lower surface of the first overflow outlet 352 is a slope inclined toward the first impurity bubble collecting tank 351, and the lower surface of the second overflow outlet 382 is a slope inclined toward the second impurity bubble collecting tank 381; preferably, the inclined angle of the first overflow outlet 352 is not less than 30 degrees, so that the impurities in the first impurity bubble collecting tank 351 are prevented from flowing back to the electric floating flocculation tank 35; foam scraping plates (not shown in the figure) for defoaming are arranged above the first impurity bubble collecting tank 351 and the second impurity bubble collecting tank 381; bubbles overflow from the overflow outlet and enter the impurity bubble collecting tank, the bubbles are scraped by the bubble scraping plate, and the impurities can be further processed into organic fertilizers; the bottom of the first impurity bubble collecting tank 351 is higher than the bottom of the electric floating flocculation tank 35, the bottom of the second impurity bubble collecting tank 381 is higher than the bottom of the purified water sedimentation tank 38, and compared with the electric floating flocculation tank 35 and the purified water sedimentation tank 38, the depths of the first impurity bubble collecting tank 351 and the second impurity bubble collecting tank 381 are relatively shallow, and the volumes are relatively small, so that the operation of the defoaming plate and the sufficient collection of impurities can be facilitated, and the impurity bubbles can be prevented from falling and splashing through an overflow port to cause pollution;
the bottom of the electric floatation flocculation tank 35 is provided with an electric floatation flocculation tank water inlet 353, and the electric floatation flocculation tank water inlet 353 is connected with the electric flocculation module 34 through a pipeline; an electric air flotation flocculation tank water outlet 354 is formed in the side wall of the electric air flotation flocculation tank 35, and the electric air flotation flocculation tank water outlet 354 is connected with the second water suction pump 36 through a pipeline; the bottom of the electric floating flocculation tank 35 is provided with an electric floating flocculation tank drain outlet 355, and the electric floating flocculation tank drain outlet 355 is provided with a drain valve; preferably, the sewage discharge outlet 355 of the electric floating flocculation tank is connected with the solid-liquid separation tank 31 through a pipeline, a sewage discharge valve of the sewage discharge outlet 355 of the electric floating flocculation tank is opened, and the settled floccule of the electric floating flocculation tank 35 can be discharged into the solid-liquid separation tank 31, so that the wastewater is subjected to solid-liquid separation again and is treated again;
the bottom of the purified water sedimentation tank 38 is provided with a purified water sedimentation tank water inlet 383, and the purified water sedimentation tank water inlet 383 is connected with the electrolysis module 37 through a pipeline; a purified water outlet 384 is formed in the side wall of the purified water sedimentation tank, and the purified water outlet 384 is connected with an external water pump (not shown in the figure); a sewage discharge port 385 of the purified water sedimentation tank is arranged at the bottom of the purified water sedimentation tank 38, and a sewage discharge valve is arranged at the sewage discharge port 385 of the purified water sedimentation tank; preferably, the sewage discharge outlet 385 of the purified water sedimentation tank is connected with the solid-liquid separation tank 31 through a pipeline, and a sewage discharge valve of the sewage discharge outlet 385 of the purified water sedimentation tank is opened, so that bottom-layer turbid liquid in the purified water sedimentation tank 38 can be discharged into the solid-liquid separation tank 31 for repeated treatment of wastewater;
a flocculation tank liquid level sensor and a sedimentation tank liquid level sensor are respectively arranged in the electric floating flocculation tank 35 and the purified water sedimentation tank 38, and a water quality detector is arranged in the purified water sedimentation tank 38; when the value of the water quality monitor does not accord with the water quality threshold value, the automatic control system 5 sends an electrolysis strengthening signal to the electric flocculation module 34 and the electrolysis module 37 to strengthen the current;
when the value of the flocculation tank liquid level sensor is higher than the highest threshold value, the automatic control system 5 closes the first water pump 33 and the electric flocculation module 34, and then stops water inflow to the electric floating flocculation tank 35;
when the value of the sedimentation tank liquid level sensor is higher than the highest threshold value, the automatic control system 5 closes the second water pump 36 and the electrolysis module 37, and then stops water inflow to the purified water sedimentation tank 38; and when the numerical value of the sedimentation tank liquid level sensor is lower than the lowest threshold value, the automatic control system 5 closes the external water pump to avoid dry pumping of the external water pump.
The working flow of the wastewater treatment system is as follows:
introducing the wastewater into a solid-liquid separation tank, and introducing the supernatant of the solid-liquid separation tank into a sedimentation tank through a pipeline;
introducing the wastewater into the solid-liquid separation tank, and naturally precipitating solid impurities in the wastewater; the supernatant of the solid-liquid separation tank enters the sedimentation tank through a pipeline, and the sedimentation tank can further remove insoluble impurities in the wastewater, so that the biodegradability of the wastewater is improved, and the operation load of subsequent processes is reduced;
pumping the supernatant of the sedimentation tank into an electric flocculation module by using a first water pump for electric flocculation treatment;
first suction pump will the supernatant of sedimentation tank is taken out extremely in the electric flocculation module, the electric flocculation module can be equipped with a plurality ofly by actual conditions, the electric flocculation module can electrolyze and produce Fe2+And Al3+With OH produced by electrolysis of the solution-The flocculating group with high activity is generated by combination, the adsorption capacity is extremely strong, the flocculating effect is superior to that of a common flocculating agent, and the effects of adsorption bridging, net catching, rolling, sweeping and the like are utilized, so that granular impurities in the wastewater are precipitated and organic pigments are decomposed, and the water body is clarified;
the wastewater after the electric flocculation treatment enters an electric floating flocculation tank through a pipeline, the wastewater is treated by adopting electric floating and electric flocculation technologies, and light impurities in the wastewater float upwards through bubbles generated by electrolysis and enter an impurity bubble collecting tank through an overflow outlet;
the electric flocculation module is connected with a water inlet of the electric floatation flocculation tank through a pipeline, the electric floatation and electric flocculation technology is adopted in the electric floatation flocculation tank to treat the wastewater, and bubbles generated by electrolysis enable light impurities in the wastewater to float upwards and enter the impurity bubble collecting tank through an overflow outlet, so that the ammonia nitrogen content and the phosphorus content in the wastewater are reduced;
the supernatant of the electric floating flocculation tank flows into an electrolysis module through a pipeline for electrolysis treatment;
the supernatant of the electric floating flocculation tank flows into the electrolysis modules through pipelines, and the electrolysis modules can be arranged according to actual conditions, so that bacteria and viruses in water can be effectively killed and eliminated; the electrolysis module is used for carrying out oxidation treatment on the wastewater so as to remove residual heavy metal, COD (chemical oxygen demand) and ammonia nitrogen substances in the water body, and can also be used for carrying out sterilization treatment on bacteria and viruses on the water body;
the water source treated by the electrolysis module enters a purified water sedimentation tank through a pipeline, the purified water sedimentation tank carries out electric floatation treatment on the water body again, and impurities are collected in a second impurity collecting tank;
the electrolysis module is connected with the bottom of the purified water sedimentation tank through a pipeline, the purified water sedimentation tank carries out electric floatation treatment on the water body again and collects impurities into the second impurity collecting tank 11;
discharging the supernatant in the purified water sedimentation tank through an external water pump; the supernatant of the purified water sedimentation tank can reach the standard of natural discharge.
As shown in fig. 9, the first embodiment of the drinking water treatment system 4 comprises an inlet pipe 41, a drinking water treatment device 42 and an outlet pipe 43; the drinking water treatment device 42 comprises a first electrolytic tank 421 and a water tank 422; the first electrolytic tank 421 is arranged in the water tank 422, and the water outlet pipe 43 is provided with a water outlet valve 431;
preferably, a chlorine ion detector is arranged in the water outlet pipe 43, and the chlorine ion detector is used for monitoring the residual chlorine content of the drinking water in the water outlet pipe 43 in real time; preferably, a liquid level controller and a TDS detector (not shown in the figure) are arranged inside the water tank 422, and the liquid level controller can monitor the water level in the water tank in real time to ensure the use of drinking water; the electrolytic current of the first electrolytic tank is set according to the water level collected by the liquid level controller and the TDS detector and the TDS value of the water source, so that large-batch sterilization and disinfection of the drinking water are realized; preferably, the first electrolytic cell 421 can be configured to perform sterilization and disinfection by first using large current electrolysis and then using small current electrolysis.
As shown in fig. 10, the first electrolytic tank 421 includes a case 421a, an anode electrode, and a cathode electrode; the anode electrode comprises an anode conductive plate 421b and a plurality of anode electrode plates 421c arranged on the anode conductive plate 421b, and the cathode electrode comprises a cathode conductive plate 421d and a plurality of cathode electrode plates 421e arranged on the cathode conductive plate 421 d; a plurality of mounting holes 421f for inserting the anode electrode plate 421b and the cathode electrode plate 421d are formed in two opposite side walls of the shell 421a, and the anode electrode plate 421b and the cathode electrode plate 421d are respectively inserted into the mounting holes 421f on two sides of the shell 421a, so that the replacement and maintenance of the electrodes can be facilitated; the number of the electrode plates on the same conductive plate is 4-8; the conductive plate is connected with a power supply; preferably, the first electrolytic bath 421 is an open electrolytic bath, and the number of the first electrolytic bath 421 is two or more.
As shown in fig. 11, the second embodiment of the drinking water treatment system 4 comprises an inlet pipe 41, a drinking water treatment device 42 and an outlet pipe 43; the drinking water treatment device 42 comprises a first electrolytic tank 421, a water flow detector 423 and an electrolytic pipeline 424; the water flow detector 423 is arranged on the water inlet pipe 41; the first electrolytic cells 421 are connected through the electrolytic pipes 424; the first electrolytic cells 421 are connected in series through electrolytic pipes 424; preferably, the number of the first electrolytic cells 421 is set to be two or more; preferably, a chlorine ion detector is arranged in the water outlet pipe 43, and the chlorine ion detector is used for monitoring the residual chlorine content of the drinking water in the water outlet pipe 43 in real time. When the water flow detector detects that water flows in the pipeline, the first electrolytic tank 421 is opened, and the water source completes real-time sterilization and disinfection treatment in the flowing process.
As shown in fig. 12, the third embodiment of the drinking water treatment system 4 comprises an inlet pipe 41, a drinking water treatment device 42 and an outlet pipe 43; the drinking water treatment device 42 comprises a first electrolytic tank 421, a water tank 422, a water flow detector 423 and an electrolytic pipeline 424; the first electrolytic tank 421 is arranged inside the water tank 422 and on the electrolytic pipeline 424; preferably, the electrolytic cell 421 is an open electrolytic cell, and the number of the electrolytic cells 421 is two or more;
the water inlet pipe 421 is respectively connected with the water tank 422 and the water flow detector 423; the water outlet pipe 43 is provided with a water outlet valve 431, and the water outlet valve 431 is respectively connected with the water tank 422 and the electrolysis pipeline 424, so that the inlet water diversion is realized; preferably, a chlorine ion detector is arranged in the water outlet pipe 43, and the chlorine ion detector is used for monitoring the residual chlorine content of the drinking water in the water outlet pipe 43 in real time;
in this embodiment, a plurality of electromagnetic valves are provided, a first electromagnetic valve 426 is provided between the water tank 422 and the three-way pipe, and a second electromagnetic valve 427 is provided between the electrolysis pipeline 424 and the three-way pipe; a third electromagnetic valve 428 is arranged between the water tank and the water outlet valve. In the embodiment, under the condition that the water quantity of the water tank is insufficient or the electrolytic treatment is not completed, the electrolytic pipelines can be connected in time and the drinking water is supplied.
While the foregoing is directed to the preferred embodiment of the present invention, it will be understood by those skilled in the art that various changes and modifications may be made without departing from the spirit and scope of the invention.

Claims (10)

1. An electrolytic water disinfection system for livestock and poultry breeding is characterized by comprising a spraying disinfection system, an air treatment system, a wastewater treatment system, a drinking water treatment system and an automatic control system;
the spraying sterilization system comprises an electrolytic water generation system and a spraying pipeline system for conveying electrolytic water; the electrolyzed water generation system comprises a filtering device, a first reservoir, an electrolysis device and a second reservoir which are sequentially connected through pipelines; the spraying pipeline system comprises a spraying generating device, a spraying pipeline and an atomizing nozzle, wherein the spraying pipeline and the atomizing nozzle are connected with the spraying generating device; the spraying pipeline is used for conveying the sterilized water to a farm, a personnel sterilization area and a vehicle sterilization area;
the air treatment system comprises an air draft device, an air supply device, a reaction tower, a conveying pipeline and a sterilized water circulation system; the system comprises a farm, a reaction tower, an air supply device, a gas pipeline; a plurality of layers of water curtains for sterilizing air are arranged in the reaction tower;
the wastewater treatment system comprises a solid-liquid separation tank, a sedimentation tank, a first water pump, an electric flocculation module, an electric floating flocculation tank, a second water pump, an electrolysis module and a purified water sedimentation tank which are sequentially connected through a pipeline; the electric air flotation flocculation tank is connected with a first impurity bubble collecting tank, and the purified water sedimentation tank is connected with a second impurity bubble collecting tank; the purified water sedimentation tank is connected with an external water pump;
the drinking water treatment system comprises a water inlet pipe, a drinking water treatment device and a water outlet pipe; the drinking water treatment device comprises a first electrolytic tank;
the automatic control system is connected with the spraying sterilization system, the air treatment system, the wastewater treatment system and the drinking water treatment system.
2. The system for disinfecting electrolyzed water for livestock and poultry breeding according to claim 1, wherein said first reservoir and said second reservoir are provided with a first reservoir level sensor and a second reservoir level sensor, respectively; the electrolysis device comprises a water inlet passage, a salt adding passage, a second electrolysis bath, a first water outlet passage, a second water outlet passage, a cleaning liquid passage and a cleaning liquid backflow passage;
when the data of the first liquid level sensor is smaller than a low water level threshold value, the automatic control system starts a filtering device, and the filtering device filters source water to generate purified water which is stored in the first water storage tank; when the data of the first liquid level sensor is higher than a high water level threshold value, the automatic control system closes the filtering device;
when the data of the second liquid level sensor is smaller than a low water level threshold value, the automatic control system sends an electrolysis starting signal to an electrolysis device, and the purified water in the first water reservoir is processed by the electrolysis device to generate electrolyzed water which is stored in the second water reservoir; and when the data of the second liquid level sensor is higher than a high water level threshold value, the automatic control system turns off the electrolysis device.
3. The electrolyzed water sterilization system for livestock and poultry breeding according to claim 2, wherein the water inlet path is composed of a water inlet pump, a water flow switch and a first water inlet valve; the water inlet pump is connected with the first reservoir through a pipeline; the first water inlet valve is connected with the second electrolytic tank through a pipeline; the salt adding passage consists of a brine barrel and a peristaltic pump, and the brine barrel is connected with the first water inlet valve through the peristaltic pump; the brine is mixed with the purified water in the water inlet passage through the brine adding passage and is introduced into the second electrolytic tank; the first water outlet passage consists of a first water outlet valve, and the second electrolytic tank is connected with the second reservoir through the first water outlet valve; the second water outlet passage consists of a second water outlet valve, a drainage pump, a third water outlet valve and a waste discharge port; the cleaning liquid passage consists of a cleaning liquid barrel, a cleaning liquid pump and a second water inlet valve; the cleaning liquid return flow path is composed of a fourth water outlet valve, and the draining pump is connected with the cleaning liquid barrel through the fourth water outlet valve.
4. The system for disinfecting electrolyzed water for livestock and poultry cultivation according to claim 3, wherein an effective chlorine concentration meter is arranged in the second electrolytic tank; when the data of the second liquid level sensor is smaller than the low water level threshold, the automatic control system sends an electrolysis starting signal to the electrolysis device, so that a water inlet passage and a salt adding passage are opened, and purified water in the first reservoir enters a second electrolysis tank; when the data of the effective chlorine concentration meter accords with the effective chlorine threshold, the automatic control system opens a first water outlet passage to lead the electrolyzed water in the second electrolytic tank to be led into a second reservoir;
when the automatic control system sends a starting drainage signal to the electrolysis device, the water inlet passage and the first water outlet passage are closed, the second water outlet passage is opened, and water in the second electrolysis bath is drained to the waste discharge port through the second water outlet valve, the drainage pump and the third water outlet valve in sequence; when the water in the second electrolytic tank is emptied, closing the second water outlet valve;
when the automatic control system sends a cleaning starting signal to the electrolytic device, only the cleaning liquid passage is opened in the electrolytic device, the cleaning liquid in the cleaning liquid barrel is quantitatively introduced into the second electrolytic tank through the cleaning liquid pump and a second water inlet valve, and the second electrolytic tank is cleaned after the cleaning liquid passage is closed; and after the cleaning treatment of the second electrolytic tank is finished, opening the cleaning liquid backflow passage, and allowing the cleaning liquid in the second electrolytic tank to flow back to the cleaning liquid barrel through the second water outlet valve, the drainage pump and the cleaning liquid backflow passage.
5. The system for disinfecting electrolyzed water for livestock and poultry breeding according to claim 1, wherein the disinfection water circulation system in the air treatment system comprises a collecting tank arranged below the reaction tower for collecting disinfection water, an electrolytic tank connected with the collecting tank, a water suction pump arranged above the electrolytic tank and a spray device arranged above the water curtain, and the water suction pump and the spray device are connected through a pipeline; an electrolytic cell electrolysis device for electrolyzing the generated disinfectant water is arranged in the electrolytic cell; the spraying device comprises a disinfection water pipeline and a spraying head arranged on the disinfection water pipeline.
6. The system for disinfecting electrolyzed water for livestock and poultry cultivation according to claim 5, wherein an electrolytic bath liquid level sensor, an effective chlorine sensor and an automatic water adding device are arranged in the electrolytic bath; when the numerical value of the electrolytic cell liquid level sensor is lower than a low water level threshold value, the automatic control system starts an automatic water adding device, and the automatic water adding device conveys source water into the electrolytic cell;
when the numerical value of the electrolytic cell liquid level sensor meets a water level threshold value, the automatic control system closes the automatic water adding device and starts the electrolytic cell electrolytic device, and the electrolytic cell electrolytic device electrolyzes source water to generate electrolytic water;
when the data of the effective chlorine sensor accords with the effective chlorine threshold value, the automatic control system sends a starting signal to a disinfection water circulation system, the water suction pump conveys the electrolyzed water in the electrolytic cell to the spray pipeline, the electrolyzed water is sprayed onto the water curtain through the spray header, and the electrolyzed water flows into the water collecting tank through the water curtain and flows back to the electrolytic cell.
7. The system for disinfecting electrolyzed water for livestock and poultry breeding according to claim 1, wherein a first overflow outlet is arranged on the side wall of the electro-flotation flocculation tank, the electro-flotation flocculation tank is communicated with the first impurity bubble collecting tank through the first overflow outlet, and the lower surface of the first overflow outlet is an inclined surface inclined towards the first impurity bubble collecting tank;
a second overflow outlet is arranged on the side wall of the purified water sedimentation tank, and the purified water sedimentation tank is communicated with the second impurity bubble collecting tank through the second overflow outlet; the lower surface of the second overflow port is an inclined plane inclined towards the second impurity bubble pool.
8. The system for disinfecting electrolyzed water for livestock and poultry cultivation according to claim 1, wherein a flocculation tank liquid level sensor and a sedimentation tank liquid level sensor are respectively arranged in the electro-flotation flocculation tank and the purified water sedimentation tank, and a water quality detector is arranged in the purified water sedimentation tank; when the numerical value of the water quality monitor does not accord with the water quality threshold value, the automatic control system sends an electrolysis strengthening signal to the electric flocculation module and the electrolysis module to strengthen the current; when the numerical value of the flocculation tank liquid level sensor is higher than the highest threshold value, the automatic control system closes the first water suction pump and the electric flocculation module, and then water inflow to the electric floatation flocculation tank is stopped; when the numerical value of the sedimentation tank liquid level sensor is higher than the highest threshold value, the automatic control system closes the second water suction pump and the electrolysis module, and then water inflow to the purified water sedimentation tank is stopped; and when the numerical value of the sedimentation tank liquid level sensor is lower than the lowest threshold value, the automatic control system closes the external water pump to avoid dry pumping of the external water pump.
9. The system for disinfecting electrolyzed water for livestock and poultry breeding according to claim 1, wherein an ammonia nitrogen sensor is arranged inside the farm; when the numerical value of the ammonia nitrogen sensor in the farm is not in accordance with the air quality threshold value or the numerical value of the temperature sensor in the farm is not in accordance with the temperature threshold value, the automatic control system sends a starting signal of the air treatment system, and then the disinfection water circulation system is started.
10. The system for disinfecting electrolyzed water for livestock and poultry breeding according to claim 1, wherein said first electrolytic tank comprises a housing, an anode electrode and a cathode electrode; the anode electrode and the cathode electrode are respectively arranged on two sides of the shell; the anode electrode and the cathode electrode respectively comprise a conductive plate arranged outside the shell and a plurality of electrode plates arranged on the conductive plate.
CN202011085845.7A 2020-10-12 2020-10-12 Water electrolysis disinfection system for livestock and poultry breeding Pending CN112337290A (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6773594B1 (en) * 1999-09-20 2004-08-10 Adriaan Johannes Hubertus van der Wijngaart Waste-water purification in cattle-breeding systems
CN102631835A (en) * 2012-04-19 2012-08-15 浙江大学 Spray deodorizing method and device of mixture of ozone and electrolyzed water
CN104743727A (en) * 2015-03-27 2015-07-01 山东大学 System and method for cooperatively removing mercury with desulfurization waste water
CN107759009A (en) * 2017-09-30 2018-03-06 重庆融极环保工程有限公司 A kind of livestock breeding wastewater handling process
CN111252992A (en) * 2020-03-25 2020-06-09 大连理工大学 Device and method for emergency disinfection and continuous disposal of infectious disease waste liquid
CN111318133A (en) * 2018-12-14 2020-06-23 广东美的白色家电技术创新中心有限公司 Air purifier
CN214261335U (en) * 2020-10-12 2021-09-24 广东原之生农业科技有限公司 Water electrolysis disinfection system for livestock and poultry breeding

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6773594B1 (en) * 1999-09-20 2004-08-10 Adriaan Johannes Hubertus van der Wijngaart Waste-water purification in cattle-breeding systems
CN102631835A (en) * 2012-04-19 2012-08-15 浙江大学 Spray deodorizing method and device of mixture of ozone and electrolyzed water
CN104743727A (en) * 2015-03-27 2015-07-01 山东大学 System and method for cooperatively removing mercury with desulfurization waste water
CN107759009A (en) * 2017-09-30 2018-03-06 重庆融极环保工程有限公司 A kind of livestock breeding wastewater handling process
CN111318133A (en) * 2018-12-14 2020-06-23 广东美的白色家电技术创新中心有限公司 Air purifier
CN111252992A (en) * 2020-03-25 2020-06-09 大连理工大学 Device and method for emergency disinfection and continuous disposal of infectious disease waste liquid
CN214261335U (en) * 2020-10-12 2021-09-24 广东原之生农业科技有限公司 Water electrolysis disinfection system for livestock and poultry breeding

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